CN108428749A - A kind of production method of the light anode of solar cell - Google Patents
A kind of production method of the light anode of solar cell Download PDFInfo
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- CN108428749A CN108428749A CN201810277284.7A CN201810277284A CN108428749A CN 108428749 A CN108428749 A CN 108428749A CN 201810277284 A CN201810277284 A CN 201810277284A CN 108428749 A CN108428749 A CN 108428749A
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- Prior art keywords
- zinc oxide
- reaction solution
- substrate
- molar concentration
- zinc
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- 238000004519 manufacturing process Methods 0.000 title claims abstract description 12
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 claims abstract description 106
- 238000006243 chemical reaction Methods 0.000 claims abstract description 52
- 239000011787 zinc oxide Substances 0.000 claims abstract description 46
- 239000002105 nanoparticle Substances 0.000 claims abstract description 38
- 239000000758 substrate Substances 0.000 claims abstract description 30
- ORILYTVJVMAKLC-UHFFFAOYSA-N adamantane Chemical compound C1C(C2)CC3CC1CC2C3 ORILYTVJVMAKLC-UHFFFAOYSA-N 0.000 claims abstract description 18
- ZOIORXHNWRGPMV-UHFFFAOYSA-N acetic acid;zinc Chemical compound [Zn].CC(O)=O.CC(O)=O ZOIORXHNWRGPMV-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000004246 zinc acetate Substances 0.000 claims abstract description 16
- 239000013078 crystal Substances 0.000 claims abstract description 8
- 238000007747 plating Methods 0.000 claims abstract description 8
- PTFCDOFLOPIGGS-UHFFFAOYSA-N Zinc dication Chemical compound [Zn+2] PTFCDOFLOPIGGS-UHFFFAOYSA-N 0.000 claims description 14
- 238000003756 stirring Methods 0.000 claims description 14
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 7
- 238000000149 argon plasma sintering Methods 0.000 claims description 7
- 230000005611 electricity Effects 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
Classifications
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/02—Details
- H01L31/0224—Electrodes
- H01L31/022408—Electrodes for devices characterised by at least one potential jump barrier or surface barrier
- H01L31/022425—Electrodes for devices characterised by at least one potential jump barrier or surface barrier for solar cells
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01L—SEMICONDUCTOR DEVICES NOT COVERED BY CLASS H10
- H01L31/00—Semiconductor devices sensitive to infrared radiation, light, electromagnetic radiation of shorter wavelength or corpuscular radiation and specially adapted either for the conversion of the energy of such radiation into electrical energy or for the control of electrical energy by such radiation; Processes or apparatus specially adapted for the manufacture or treatment thereof or of parts thereof; Details thereof
- H01L31/18—Processes or apparatus specially adapted for the manufacture or treatment of these devices or of parts thereof
- H01L31/1884—Manufacture of transparent electrodes, e.g. TCO, ITO
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E10/00—Energy generation through renewable energy sources
- Y02E10/50—Photovoltaic [PV] energy
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P70/00—Climate change mitigation technologies in the production process for final industrial or consumer products
- Y02P70/50—Manufacturing or production processes characterised by the final manufactured product
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- Engineering & Computer Science (AREA)
- Computer Hardware Design (AREA)
- Physics & Mathematics (AREA)
- Condensed Matter Physics & Semiconductors (AREA)
- Electromagnetism (AREA)
- General Physics & Mathematics (AREA)
- Microelectronics & Electronic Packaging (AREA)
- Power Engineering (AREA)
- Manufacturing & Machinery (AREA)
- Life Sciences & Earth Sciences (AREA)
- Sustainable Development (AREA)
- Sustainable Energy (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
A kind of production method of the light anode of solar cell, including：Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle are equal to 8 nanometers, and the Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；Step 2：The substrate is placed in one first reaction solution, first reaction solution includes zinc acetate, hexa and adamantane, and wherein zinc acetate is 0.01 to 0.03 molar concentration, hexa is 0.01 to 0.03 molar concentration, and adamantane is 0.005 to 0.015 molar concentration.
Description
Technical field
The present invention relates to a kind of production methods of the light anode of solar cell.
Background technology
The light anode electricity conversion prepared in the prior art is not high, and production technology is complicated, is unfavorable for industrialization.
Invention content
The present invention provides a kind of production methods of the light anode of solar cell, including：
Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle be equal to 8 nanometers, and
The Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；
Step 2：The substrate is placed in one first reaction solution, which includes zinc acetate, hexa
And adamantane, wherein zinc acetate is 0.01 to 0.03 molar concentration, and hexa is 0.01 to 0.03 molar concentration, Buddha's warrior attendant
Alkane is 0.005 to 0.015 molar concentration；
Step 3：First reaction solution is heated to 95 DEG C, makes to form a zinc oxide nano-wire array on the seed layer；
Step 4：The substrate is taken out and is down to room temperature from first reaction solution, is then placed in one second reaction solution,
In second reaction solution include zinc ion and highly basic, wherein zinc ion concentration be 0.4 to 0.7 molar concentration, strong base concentrations 3
To 5 molar concentrations, a stirring action is carried out to second reaction solution, rotating speed per minute is that 600rpm is stirred 5 minutes；
Step 5：It is coated with several Zinc oxide nanoparticles on the zinc oxide nano-wire array as a light scattering layer, then should
Substrate is placed in again in second reaction solution, carries out the stirring action, is stirred 4 minutes with rotating speed 700rpm per minute, is made this
Attachment between Zinc oxide nanoparticle increases, and forms final products.
The said goods can be applied in satellite battery product.
The inventive point of the present invention is 1) technological process；2) raw material needed for；3) specific proportioning.
Specific implementation mode
Embodiment 1
A kind of production method of the light anode of solar cell, including：
Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle be equal to 8 nanometers, and
The Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；
Step 2：The substrate is placed in one first reaction solution, which includes zinc acetate, hexa
And adamantane, wherein zinc acetate is 0.01 to 0.03 molar concentration, and hexa is 0.01 to 0.03 molar concentration, Buddha's warrior attendant
Alkane is 0.005 to 0.015 molar concentration；
Step 3：First reaction solution is heated to 95 DEG C, makes to form a zinc oxide nano-wire array on the seed layer；
Step 4：The substrate is taken out and is down to room temperature from first reaction solution, is then placed in one second reaction solution,
In second reaction solution include zinc ion and highly basic, wherein zinc ion concentration be 0.4 to 0.7 molar concentration, strong base concentrations 3
To 5 molar concentrations, a stirring action is carried out to second reaction solution, rotating speed per minute is that 600rpm is stirred 5 minutes；
Step 5：It is coated with several Zinc oxide nanoparticles on the zinc oxide nano-wire array as a light scattering layer, then should
Substrate is placed in again in second reaction solution, carries out the stirring action, is stirred 4 minutes with rotating speed 700rpm per minute, is made this
Attachment between Zinc oxide nanoparticle increases, and forms final products.
The said goods can be applied in satellite battery product.
Embodiment 2
A kind of production method of the light anode of solar cell, including：
Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle be equal to 9 nanometers, and
The Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；
Step 2：The substrate is placed in one first reaction solution, which includes zinc acetate, hexa
And adamantane, wherein zinc acetate is 0.01 to 0.03 molar concentration, and hexa is 0.01 to 0.03 molar concentration, Buddha's warrior attendant
Alkane is 0.005 to 0.015 molar concentration；
Step 3：First reaction solution is heated to 95 DEG C, makes to form a zinc oxide nano-wire array on the seed layer；
Step 4：The substrate is taken out and is down to room temperature from first reaction solution, is then placed in one second reaction solution,
In second reaction solution include zinc ion and highly basic, wherein zinc ion concentration be 0.4 to 0.7 molar concentration, strong base concentrations 3
To 5 molar concentrations, a stirring action is carried out to second reaction solution, rotating speed per minute is that 600rpm is stirred 5 minutes；
Step 5：It is coated with several Zinc oxide nanoparticles on the zinc oxide nano-wire array as a light scattering layer, then should
Substrate is placed in again in second reaction solution, carries out the stirring action, is stirred 4 minutes with rotating speed 700rpm per minute, is made this
Attachment between Zinc oxide nanoparticle increases, and forms final products.
The said goods can be applied in satellite battery product.
Embodiment 3
A kind of production method of the light anode of solar cell, including：
Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle be equal to 10 nanometers, and
And the Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；
Step 2：The substrate is placed in one first reaction solution, which includes zinc acetate, hexa
And adamantane, wherein zinc acetate is 0.01 to 0.03 molar concentration, and hexa is 0.01 to 0.03 molar concentration, Buddha's warrior attendant
Alkane is 0.005 to 0.015 molar concentration；
Step 3：First reaction solution is heated to 95 DEG C, makes to form a zinc oxide nano-wire array on the seed layer；
Step 4：The substrate is taken out and is down to room temperature from first reaction solution, is then placed in one second reaction solution,
In second reaction solution include zinc ion and highly basic, wherein zinc ion concentration be 0.4 to 0.7 molar concentration, strong base concentrations 3
To 5 molar concentrations, a stirring action is carried out to second reaction solution, rotating speed per minute is that 600rpm is stirred 5 minutes；
Step 5：It is coated with several Zinc oxide nanoparticles on the zinc oxide nano-wire array as a light scattering layer, then should
Substrate is placed in again in second reaction solution, carries out the stirring action, is stirred 4 minutes with rotating speed 700rpm per minute, is made this
Attachment between Zinc oxide nanoparticle increases, and forms final products.
The said goods can be applied in satellite battery product.
Embodiment 4
A kind of production method of the light anode of solar cell, including：
Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle be equal to 11 nanometers, and
And the Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；
Step 2：The substrate is placed in one first reaction solution, which includes zinc acetate, hexa
And adamantane, wherein zinc acetate is 0.01 to 0.03 molar concentration, and hexa is 0.01 to 0.03 molar concentration, Buddha's warrior attendant
Alkane is 0.005 to 0.015 molar concentration；
Step 3：First reaction solution is heated to 95 DEG C, makes to form a zinc oxide nano-wire array on the seed layer；
Step 4：The substrate is taken out and is down to room temperature from first reaction solution, is then placed in one second reaction solution,
In second reaction solution include zinc ion and highly basic, wherein zinc ion concentration be 0.4 to 0.7 molar concentration, strong base concentrations 3
To 5 molar concentrations, a stirring action is carried out to second reaction solution, rotating speed per minute is that 600rpm is stirred 5 minutes；
Step 5：It is coated with several Zinc oxide nanoparticles on the zinc oxide nano-wire array as a light scattering layer, then should
Substrate is placed in again in second reaction solution, carries out the stirring action, is stirred 4 minutes with rotating speed 700rpm per minute, is made this
Attachment between Zinc oxide nanoparticle increases, and forms final products.
The said goods can be applied in satellite battery product.
Embodiment 5
A kind of production method of the light anode of solar cell, including：
Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle be equal to 12 nanometers, and
And the Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；
Step 2：The substrate is placed in one first reaction solution, which includes zinc acetate, hexa
And adamantane, wherein zinc acetate is 0.01 to 0.03 molar concentration, and hexa is 0.01 to 0.03 molar concentration, Buddha's warrior attendant
Alkane is 0.005 to 0.015 molar concentration；
Step 3：First reaction solution is heated to 95 DEG C, makes to form a zinc oxide nano-wire array on the seed layer；
Step 4：The substrate is taken out and is down to room temperature from first reaction solution, is then placed in one second reaction solution,
In second reaction solution include zinc ion and highly basic, wherein zinc ion concentration be 0.4 to 0.7 molar concentration, strong base concentrations 3
To 5 molar concentrations, a stirring action is carried out to second reaction solution, rotating speed per minute is that 600rpm is stirred 5 minutes；
Step 5：It is coated with several Zinc oxide nanoparticles on the zinc oxide nano-wire array as a light scattering layer, then should
Substrate is placed in again in second reaction solution, carries out the stirring action, is stirred 4 minutes with rotating speed 700rpm per minute, is made this
Attachment between Zinc oxide nanoparticle increases, and forms final products.
The said goods can be applied in satellite battery product.
Claims (2)
1. a kind of production method of the light anode of solar cell, including：
Step 1：Previously prepared several Zinc oxide nanoparticles, the wherein grain size of the Zinc oxide nanoparticle be equal to 8 nanometers, and
The Zinc oxide nanoparticle is coated on substrate as zinc oxide crystal seed layer in a manner of sputter or rotation plating；
Step 2：The substrate is placed in one first reaction solution, which includes zinc acetate, hexa
And adamantane, wherein zinc acetate is 0.01 to 0.03 molar concentration, and hexa is 0.01 to 0.03 molar concentration, Buddha's warrior attendant
Alkane is 0.005 to 0.015 molar concentration；
Step 3：First reaction solution is heated to 95 DEG C, makes to form a zinc oxide nano-wire array on the seed layer；
Step 4：The substrate is taken out and is down to room temperature from first reaction solution, is then placed in one second reaction solution,
In second reaction solution include zinc ion and highly basic, wherein zinc ion concentration be 0.4 to 0.7 molar concentration, strong base concentrations 3
To 5 molar concentrations, a stirring action is carried out to second reaction solution, rotating speed per minute is that 600rpm is stirred 5 minutes；
Step 5：It is coated with several Zinc oxide nanoparticles on the zinc oxide nano-wire array as a light scattering layer, then should
Substrate is placed in again in second reaction solution, carries out the stirring action, is stirred 4 minutes with rotating speed 700rpm per minute, is made this
Attachment between Zinc oxide nanoparticle increases, and forms final products.
2. the said goods can be applied in satellite battery product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810277284.7A CN108428749A (en) | 2018-03-30 | 2018-03-30 | A kind of production method of the light anode of solar cell |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810277284.7A CN108428749A (en) | 2018-03-30 | 2018-03-30 | A kind of production method of the light anode of solar cell |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108428749A true CN108428749A (en) | 2018-08-21 |
Family
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810277284.7A Withdrawn CN108428749A (en) | 2018-03-30 | 2018-03-30 | A kind of production method of the light anode of solar cell |
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Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101800130A (en) * | 2010-04-19 | 2010-08-11 | 西安交通大学 | Method for preparing dye-sensitized solar cell compound light anode with zinc oxide nanometer structure |
| CN102881462A (en) * | 2012-09-20 | 2013-01-16 | 太原理工大学 | Preparation method of ZnO nano rod array/nano grain cluster microballoon sphere composite film |
| CN103730260A (en) * | 2013-12-30 | 2014-04-16 | 深圳大学 | Dye-sensitized solar cell and preparation method of ZnO composite photo-anode of dye-sensitized solar cell |
| CN107445199A (en) * | 2017-06-15 | 2017-12-08 | 中国科学院上海硅酸盐研究所 | Multilevel hierarchy titanium dioxide nanowire array and preparation method thereof |
-
2018
- 2018-03-30 CN CN201810277284.7A patent/CN108428749A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101800130A (en) * | 2010-04-19 | 2010-08-11 | 西安交通大学 | Method for preparing dye-sensitized solar cell compound light anode with zinc oxide nanometer structure |
| CN102881462A (en) * | 2012-09-20 | 2013-01-16 | 太原理工大学 | Preparation method of ZnO nano rod array/nano grain cluster microballoon sphere composite film |
| CN103730260A (en) * | 2013-12-30 | 2014-04-16 | 深圳大学 | Dye-sensitized solar cell and preparation method of ZnO composite photo-anode of dye-sensitized solar cell |
| CN107445199A (en) * | 2017-06-15 | 2017-12-08 | 中国科学院上海硅酸盐研究所 | Multilevel hierarchy titanium dioxide nanowire array and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 贾伟: ""ZnO纳米棒阵列/纳米颗粒团聚复合膜的制备及其光电性能"", 《人 工 晶 体 学 报》 * |
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Application publication date: 20180821 |