CN108424705A - A kind of high dispersion modified graphene oxide, preparation method and its anticorrosive paint - Google Patents
A kind of high dispersion modified graphene oxide, preparation method and its anticorrosive paint Download PDFInfo
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- CN108424705A CN108424705A CN201810214204.3A CN201810214204A CN108424705A CN 108424705 A CN108424705 A CN 108424705A CN 201810214204 A CN201810214204 A CN 201810214204A CN 108424705 A CN108424705 A CN 108424705A
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- graphene oxide
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- anticorrosive paint
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D127/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers
- C09D127/02—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment
- C09D127/12—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Coating compositions based on derivatives of such polymers not modified by chemical after-treatment containing fluorine atoms
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/08—Anti-corrosive paints
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
- C09D7/62—Additives non-macromolecular inorganic modified by treatment with other compounds
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- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Inorganic Chemistry (AREA)
- Paints Or Removers (AREA)
Abstract
The invention discloses a kind of high dispersion modified graphene oxide, preparation method and its anticorrosive paints, and graphene oxide and 3 aminobenzene acid reactions are obtained the boric acid modified graphene oxide of 3 aminobenzenes；Isocyanuric acid three-glycidyl ester and the boric acid modified graphene oxide of 3 aminobenzenes are obtained by the reaction high dispersion modified graphene oxide, stability is good, dispersed height；The high dispersion modified graphene oxide is uniformly dispersed with matrix resin, levelling agent, antifoaming agent, dispersant, coalescents, diluent further, obtains anticorrosive paint, antiseptic property is good, and service life is long.Present invention process is simple, environment-friendly high-efficiency, is suitable for industrialized production.
Description
Technical field
The invention belongs to the technical field of coating preparation, a kind of high dispersion modified graphene oxide, its preparation side are provided
Method and its anticorrosive paint.
Background technology
Corrosion protection plays outstanding role in contemporary metal processing industry.Mass data indicate, corrosion to national economy with
And industrialization development causes heavy losses.Wherein marine ship corrosion accounts for very big one side, and marine corrosion causes very hull
Big waste, and become potential security risk.Graphene causes as a kind of New Two Dimensional material, excellent physicochemical property
Extensive concern.The performances such as the bigger serface of graphene, excellent electricity, optics enable it all be presented in every field tempting
Foreground, when graphene is applied in anticorrosive paint, graphene have the function of physical isolation and electronics conduction.Graphene
The conjugated structure of lamella is layering to form fine and close isolation layer in the coating, barrier moisture to the infiltration of film with ooze
Thoroughly --- play physical preservation, graphene surface hydrophobic property strengthens moisture penetration.
Application No. is 201610878263.1 Chinese patent applications to make stone by carrying out secondary oxidation modification to graphene
The stability of black alkene increases, and is conducive to the corrosion resistance for utmostly playing graphene itself, the coating prepared is made to have
Excellent adhesive force, hardness, wearability and resistance to Neutral Salt Spray Corrosion, but this method material requested is more, and preparation process is complicated,
Cost is higher, and dispersibility and resistance to acid and alkali are bad.
The mode majority that graphene is applied to coating at present is added graphene as functional filler, thus band
Come a critical issue is how to solve the dispersion stabilization problem of graphene, needs to be modified graphene.
Invention content
It is an object of the invention to overcome prior art defect, a kind of high dispersion modified graphene oxide, its preparation are provided
Method and its anticorrosive paint.
One of the technical solution adopted by the present invention to solve the technical problems is：
A kind of preparation method of high dispersion modified graphene oxide, includes the following steps：
1) by graphene oxide and 3- amino phenyl boric acids with 1~10:1 quality in the first solvent, rises than ultrasonic disperse
Temperature is separated by solid-liquid separation to 60~120 DEG C of 4~10h of back flow reaction, obtains the boric acid modified graphene oxide of 3- aminobenzenes；
2) the boric acid modified graphene oxide of 3- aminobenzenes for obtaining isocyanuric acid three-glycidyl ester and step 1) with 1~
15:1 quality in the second solvent, is warming up to 80~180 DEG C of back flow reactions 12~for 24 hours than ultrasonic disperse, is separated by solid-liquid separation, obtains
The modified graphene oxide.
In a preferred embodiment of the invention, first solvent is at least one of water, toluene.
In a preferred embodiment of the invention, second solvent is n,N-Dimethylformamide, N- methyl pyrroles
At least one of pyrrolidone.
The technical solution adopted by the present invention to solve the technical problems second is that：
A kind of high dispersion modified graphene oxide prepared by above-mentioned preparation method.
The three of the technical solution adopted by the present invention to solve the technical problems are：
A kind of anticorrosive paint includes following component according to the mass fraction：
Described matrix resin is epoxy resin, fluorocarbon resin, amino resins, acrylic resin, polyurethane resin, alkyd tree
At least one of fat, polyester resin.
The levelling agent is at least one of organosilicon, acrylic compounds, only son's ethers.
The antifoaming agent is organic silicon antifoaming agent, inorganic silicon class antifoaming agent, at least one of antifoaming agent of non-silicone,
As BYK302, BYK065 of German Bi Ke companies production, BYK20, BYK011, BYK053, Efka company produce
At least one of Efka2018.
The dispersant is at least one of self-fluxing nature dispersant, wetting dispersing agent, as Bi Ke companies of Germany produce
At least one of the Efka5044 that BYK101, BYK161, BYK163, Efka company produce.
The coalescents are butyl Bian alcohol acetic ester, butyl glycol ether alkyd fat, ethylene glycol phenyl ether, dibasic acid dimethyl ester
At least one of class, propylene glycol propyl ether, binary acids diethyl esters class.
The diluent is 1,4- butanediol diglycidyl ethers, ethylene glycol diglycidylether, acetone, dimethylbenzene, just
At least one of butanol, methyl iso-butyl ketone (MIBK), absolute ethyl alcohol, ethyl acetate, butyl acetate.
The four of the technical solution adopted by the present invention to solve the technical problems are：
The preparation method of the anticorrosive paint：
The method comprises the steps of firstly, preparing a kind of high dispersion modified graphene oxides, and 0.5~2 part is taken by anticorrosive paint component proportioning
Modified graphene oxide, 40~80 parts of matrix resins, 0.2~1.0 part of levelling agent, 0.05~1.0 part of antifoaming agent, 0.1~1.0 part
Dispersant, 0.2~1.0 part of coalescents, 5~35 parts of diluents.2000~5000r/min of rotating speed is used on high speed dispersor
Evenly dispersed 2~6h can be obtained anticorrosive paint after filtering.
High dispersion modified graphene oxide anti-corrosive aids preparation principle in the present invention：Graphene oxide progress surface is changed
Property, 3- amino phenyl boric acids are incorporated in surface of graphene oxide by way of covalent bond, and then modify isocyanuric acid three shrink it is sweet
Grease makes it enhance with matrix resin compatibility.
The beneficial effects of the invention are as follows：
1. the operating procedure of the present invention is simple, environment-friendly high-efficiency, it is suitable for industrialized production.
2. the present invention is directly prepared for high dispersion modified graphene oxide as anti-corrosive aids, phenyl boric acid has rust inhibition
Can, graphene has antiseptic property, can utilize inhibition and the antiseptic property of phenyl boric acid and graphene simultaneously, play composite anti-corrosive
Effect.Isocyanuric acid three-glycidyl ester makes graphene and matrix resin have good compatibility simultaneously, and can participate in resin
Co-curing process.
3. high dispersion modified graphene oxide provided by the invention, stability is good, dispersed height, can be by simply mixed
Modified graphene is added in finished product coating by conjunction process, very convenient.
4. high dispersion modified graphene oxide anti-corrosive aids provided by the invention dispersibility enhancing in coating, graphene
Good dispersion makes its interface binding power with coating matrix with regard to stronger, and the antiseptic property of coating is with regard to more preferable, and coating weatherability
More preferably, the service life is longer.
Description of the drawings
Fig. 1 is high dispersion modified graphene oxide preparation process schematic diagram in the present invention.
Fig. 2 is the optical photograph figure of high dispersion modified graphite oxide anti-corrosive aids dispersion liquid made from the embodiment of the present invention 1.
Left figure is the common graphene oxide dispersion placed one week, will produce many precipitations, and right figure is that the present invention of placement one week is real
High dispersion modified graphene oxide made from example 1 is applied, it is still well dispersed.
Fig. 3 is the scanning electron microscope of high dispersion modified graphene oxide anti-corrosive aids made from the embodiment of the present invention 1
(SEM) figure.
Specific implementation mode
Present disclosure is illustrated below by embodiment：
Technical scheme of the present invention is further detailed and is described below by way of specific implementation mode combination attached drawing.
Embodiment antiseptic property is as shown in table 1
Embodiment 1
(1) high dispersion modified graphene oxide is prepared：
A) 0.2g graphene oxides is taken in toluene, to be warming up to 100 DEG C of reflux with 0.2g 3- amino phenyl boric acid ultrasonic disperses
6h is reacted, filters and washs to obtain the boric acid modified graphene oxide of 3- aminobenzenes；
B) the boric acid modified graphene oxide 0.1g of the 3- aminobenzenes that step a) is obtained and 1g isocyanuric acid three-glycidyls are taken
Ester is heated to 150 DEG C of back flow reactions for 24 hours in 100mL n,N-Dimethylformamide, filters and washs to obtain high dispersion modified
Graphene oxide.
(2) high dispersion modified graphene oxide composite anticorrosion coating is prepared
High dispersion modified graphene oxide, 50g epoxy resin, 0.5g organosilicons, 0.2g prepared by 1g steps (1) is taken to defoam
Agent BYK302,0.5g dispersant B YK101,0.5g ethylene glycol phenyl ether, the mixing of 20g 1,4-butanediol diglycidyl ether, in height
The evenly dispersed 4h of 2000~5000r/min of rotating speed are used on fast dispersion machine, and high dispersion modified graphite oxide is can be obtained after filtering
Alkene composite anticorrosion coating.
Embodiment 2
(1) high dispersion modified graphene oxide is prepared；
With embodiment 1.
(2) high dispersion modified graphene oxide composite anticorrosion coating is prepared；
It is 0.5g by the Mass adjust- ment of high dispersion modified graphene oxide in embodiment 1.
Embodiment 3
(1) high dispersion modified graphene oxide is prepared；
With embodiment 1.
(2) high dispersion modified graphene oxide composite anticorrosion coating is prepared；
It is 1.5g by the Mass adjust- ment of high dispersion modified graphene oxide in embodiment 1.
Embodiment 4
(1) high dispersion modified graphene oxide is prepared；
With embodiment 1.
(2) high dispersion modified graphene oxide composite anticorrosion coating is prepared；
It is 80g by the Mass adjust- ment of 1 epoxy resin of embodiment.
Embodiment 5
(1) high dispersion modified graphene oxide is prepared；
A) 2g graphene oxides is taken in water, to be warming up to 120 DEG C of back flow reactions with 0.2g 3- amino phenyl boric acid ultrasonic disperses
4h is filtered and is washed to obtain the boric acid modified graphene oxide of 3- aminobenzenes；
B) the boric acid modified graphene oxide 0.1g and 0.1g isocyanuric acids of the 3- aminobenzenes that step a) is obtained three are taken to shrink sweet
Grease is heated to 80 DEG C of back flow reaction 18h in 100mL n,N-Dimethylformamide, filters and washs to obtain high dispersion modified
Graphene oxide.
(2) high dispersion modified graphene oxide composite anticorrosion coating is prepared；
Take high dispersion modified graphene oxide, 75g acrylic resins, 0.8g organosilicons, 0.05g prepared by 2g steps (1)
Antifoaming agent Efka2018,0.9g dispersant Efka5044,0.3g butyl Bian alcohol acetic ester, the mixing of 8g acetone, in high speed dispersor
It is upper to use the rotating speed evenly dispersed 6h of 2000~5000r/min, it is compound anti-that high dispersion modified graphene oxide is can be obtained after filtering
Rotten coating.
Embodiment 6
(1) high dispersion modified graphene oxide is prepared；
A) it takes 1g graphene oxides with 0.2g 3- amino phenyl boric acid ultrasonic disperses in toluene, it is anti-to be warming up to 60 DEG C of reflux
10h is answered, filter and washs to obtain the boric acid modified graphene oxide of 3- aminobenzenes；
B) the boric acid modified graphene oxide 0.1g and 1.5g isocyanuric acids of the 3- aminobenzenes that step a) is obtained three are taken to shrink sweet
Grease is heated to 180 DEG C of back flow reaction 12h in 100mL N-Methyl pyrrolidones, filters and washs to obtain high dispersion modified
Graphene oxide.
(2) high dispersion modified graphene oxide composite anticorrosion coating is prepared；
High dispersion modified graphene oxide, 45g fluorocarbon resins, 0.3g organosilicons, 0.9g prepared by 0.8g steps (1) is taken to disappear
Infusion BYK011,0.05g dispersant B YK163,0.9g propylene glycol propyl ether, the mixing of 30g methyl iso-butyl ketone (MIBK)s, in high speed dispersor
It is upper to use the rotating speed evenly dispersed 10h of 2000~5000r/min, it is compound anti-that high dispersion modified graphene oxide is can be obtained after filtering
Rotten coating.
Examples 1 to 4 antiseptic property test result is as shown in table 1, and floating coat resistance to salt water, which measures, presses GB/T 9274-
88 execute test, and the test of coating salt spray corrosion resistance executes test according to GB/T 1771-2007.
Table 1
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| Salt water resistance h | 2520 | 2352 | 2616 | 2256 |
| Salt spray resistance h | 1944 | 1800 | 1992 | 1848 |
The above, only present pre-ferred embodiments, therefore cannot limit the scope of implementation of the present invention according to this, i.e., according to
Equivalent changes and modifications made by the scope of the claims of the present invention and description all should still belong in the range of the present invention covers.
Claims (10)
1. a kind of preparation method of modified graphene oxide, it is characterised in that：Including：
1) by graphene oxide and 3- amino phenyl boric acids with 1~10:1 quality in the first solvent, is warming up to than ultrasonic disperse
60~120 DEG C of 4~10h of back flow reaction are separated by solid-liquid separation, obtain the boric acid modified graphene oxide of 3- aminobenzenes；
2) the boric acid modified graphene oxide of 3- aminobenzenes for obtaining isocyanuric acid three-glycidyl ester and step 1) is with 1~15:1
Quality than ultrasonic disperse in the second solvent, be warming up to 80~180 DEG C of back flow reactions 12~for 24 hours, be separated by solid-liquid separation, obtain described
Modified graphene oxide.
2. preparation method according to claim 1, it is characterised in that：First solvent is at least one in water, toluene
Kind；Second solvent is at least one of N,N-dimethylformamide, N-Methyl pyrrolidone.
3. the modified graphene oxide prepared by a kind of preparation method according to claim 1 or 2.
4. a kind of anticorrosive paint, it is characterised in that：Include following component according to the mass fraction：
5. anticorrosive paint according to claim 4, it is characterised in that：Described matrix resin be epoxy resin, fluorocarbon resin,
At least one of amino resins, acrylic resin, polyurethane resin, alkyd resin, polyester resin.
6. anticorrosive paint according to claim 4, it is characterised in that：The levelling agent is organosilicon, acrylic compounds, only son
At least one of ethers.
7. anticorrosive paint according to claim 4, it is characterised in that：The antifoaming agent is organic silicon antifoaming agent, inorganic
At least one of silicon class antifoaming agent, antifoaming agent of non-silicone；The dispersant is in self-fluxing nature dispersant, wetting dispersing agent
It is at least one.
8. anticorrosive paint according to claim 7, it is characterised in that：The antifoaming agent be BYK302, BYK065, BYK20,
At least one of BYK011, BYK053, Efka2018；The dispersant is BYK101, BYK161, BYK163, Efka5044
At least one of.
9. anticorrosive paint according to claim 4, it is characterised in that：The coalescents are butyl Bian alcohol acetic ester, second
At least one in glycol butyl ether alkyd fat, ethylene glycol phenyl ether, dibasic acid dimethyl ester, propylene glycol propyl ether, binary acids diethyl esters class
Kind；The diluent be 1,4- butanediol diglycidyl ethers, ethylene glycol diglycidylether, acetone, dimethylbenzene, n-butanol,
At least one of methyl iso-butyl ketone (MIBK), absolute ethyl alcohol, ethyl acetate, butyl acetate.
10. the preparation method of the anticorrosive paint described in a kind of any one of claim 4 to 9, it is characterised in that：By the quality
Number takes each component, the evenly dispersed 2~6h of 2000~5000r/min of rotating speed, filtering to obtain the anticorrosive paint.
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Cited By (8)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749500A (en) * | 2018-12-29 | 2019-05-14 | 厦门大学 | A kind of graphene/azobenzene polymer composite anticorrosion coating auxiliary agent and preparation method thereof |
| CN110003776A (en) * | 2019-04-28 | 2019-07-12 | 苏州格瑞丰纳米科技有限公司 | A kind of water-thinned epoxy zinc-rich anticorrosive paint and the preparation method and application thereof |
| CN110067001A (en) * | 2019-05-13 | 2019-07-30 | 北京净油洁宝科技有限公司 | A kind of metal cleaner and preparation method thereof |
| CN111019479A (en) * | 2019-12-20 | 2020-04-17 | 佛山科学技术学院 | Coating and preparation method thereof |
| CN111978771A (en) * | 2019-05-21 | 2020-11-24 | 中车唐山机车车辆有限公司 | Modified graphene oxide, preparation method thereof, anticorrosive paint containing modified graphene oxide and preparation method |
| CN112812652A (en) * | 2020-12-31 | 2021-05-18 | 青岛鸿澜防水科技有限责任公司 | Resistance to HCl-H2S corrosion and high temperature resistant coating and preparation method thereof |
| CN115572518A (en) * | 2022-09-26 | 2023-01-06 | 厦门大学 | Water-based concrete protective coating composition and preparation method thereof |
| CN117070126A (en) * | 2023-09-28 | 2023-11-17 | 北京景泰消防科技有限公司 | Corrosion-resistant water-based fireproof paint and preparation method thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131178A (en) * | 2015-09-14 | 2015-12-09 | 江南大学 | Preparation method of molecularly imprinted composite material for enriching and separating glycoprotein |
| CN105419564A (en) * | 2015-12-24 | 2016-03-23 | 常州纳美生物科技有限公司 | Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof |
| CN106832534A (en) * | 2017-03-20 | 2017-06-13 | 厦门大学 | A kind of double-bond functionalized graphene oxide/polyethylene film of high barrier and preparation method thereof |
-
2018
- 2018-03-15 CN CN201810214204.3A patent/CN108424705B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105131178A (en) * | 2015-09-14 | 2015-12-09 | 江南大学 | Preparation method of molecularly imprinted composite material for enriching and separating glycoprotein |
| CN105419564A (en) * | 2015-12-24 | 2016-03-23 | 常州纳美生物科技有限公司 | Nano graphene oxide modified double-component aqueous epoxy anti-corrosion coating and preparation method thereof |
| CN106832534A (en) * | 2017-03-20 | 2017-06-13 | 厦门大学 | A kind of double-bond functionalized graphene oxide/polyethylene film of high barrier and preparation method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 雇双: "《硼酸及其衍生物修饰的碳材料合成及性质研究》", 《中国优秀硕士学位论文全文数据库》 * |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN109749500A (en) * | 2018-12-29 | 2019-05-14 | 厦门大学 | A kind of graphene/azobenzene polymer composite anticorrosion coating auxiliary agent and preparation method thereof |
| CN110003776A (en) * | 2019-04-28 | 2019-07-12 | 苏州格瑞丰纳米科技有限公司 | A kind of water-thinned epoxy zinc-rich anticorrosive paint and the preparation method and application thereof |
| CN110003776B (en) * | 2019-04-28 | 2020-11-20 | 苏州格瑞丰纳米科技有限公司 | Water-based epoxy zinc-rich anticorrosive paint and preparation method and application thereof |
| CN110067001A (en) * | 2019-05-13 | 2019-07-30 | 北京净油洁宝科技有限公司 | A kind of metal cleaner and preparation method thereof |
| CN111978771A (en) * | 2019-05-21 | 2020-11-24 | 中车唐山机车车辆有限公司 | Modified graphene oxide, preparation method thereof, anticorrosive paint containing modified graphene oxide and preparation method |
| CN111978771B (en) * | 2019-05-21 | 2022-03-01 | 中车唐山机车车辆有限公司 | Modified graphene oxide, preparation method thereof, anticorrosive paint containing modified graphene oxide and preparation method |
| CN111019479A (en) * | 2019-12-20 | 2020-04-17 | 佛山科学技术学院 | Coating and preparation method thereof |
| CN112812652A (en) * | 2020-12-31 | 2021-05-18 | 青岛鸿澜防水科技有限责任公司 | Resistance to HCl-H2S corrosion and high temperature resistant coating and preparation method thereof |
| CN112812652B (en) * | 2020-12-31 | 2022-02-25 | 中环涂层技术(广东)有限公司 | Resistance to HCl-H2S corrosion and high temperature resistant coating and preparation method thereof |
| CN115572518A (en) * | 2022-09-26 | 2023-01-06 | 厦门大学 | Water-based concrete protective coating composition and preparation method thereof |
| CN117070126A (en) * | 2023-09-28 | 2023-11-17 | 北京景泰消防科技有限公司 | Corrosion-resistant water-based fireproof paint and preparation method thereof |
| CN117070126B (en) * | 2023-09-28 | 2024-03-05 | 北京景泰消防科技有限公司 | Corrosion-resistant water-based fireproof paint and preparation method thereof |
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| CN108424705B (en) | 2019-10-25 |
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