CN108420145A - A kind of preparation method of bradyseism type insole - Google Patents
A kind of preparation method of bradyseism type insole Download PDFInfo
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- CN108420145A CN108420145A CN201810314590.3A CN201810314590A CN108420145A CN 108420145 A CN108420145 A CN 108420145A CN 201810314590 A CN201810314590 A CN 201810314590A CN 108420145 A CN108420145 A CN 108420145A
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- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B17/00—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined
- A43B17/003—Insoles for insertion, e.g. footbeds or inlays, for attachment to the shoe after the upper has been joined characterised by the material
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Abstract
The invention discloses a kind of preparation methods of bradyseism type insole, belong to sock field of material technology.It counts in parts by weight,50~70 parts of pretreatment cork oak granulated corks are weighed successively,80~100 parts of impregnating agent,12~20 parts of pretreatment adhesives,5~10 parts of water and 5~12 parts of calcium bicarbonates,By pretreatment cork oak granulated cork with impregnating agent after mixing 1~2h of immersion under room temperature,Filtering,Cork oak granulated cork must be modified,Modified cork oak granulated cork and pretreatment adhesive are mixed in blender,And water and calcium bicarbonate are added into blender,In temperature be 40~45 DEG C,After rotating speed is stirred 20~30min under conditions of being 200~300r/min,Obtain mixture,Mixture is moved into hot press,In temperature be 180~220 DEG C,Pressure is hot-forming under conditions of being 1.5~3.0MPa,Obtain blank,Blank is cut,Up to bradyseism type insole.Gained bradyseism type insole of the invention has excellent damping effect, elasticity and comfort.
Description
Technical field
The invention discloses a kind of preparation methods of bradyseism type insole, belong to sock field of material technology.
Background technology
Insole is widely used in shoe industry, health care, specifically functional；It is generally divided into the applied insole of the applied Shoes Factory of shoe industry
With marketing type both of which.The insole of shoe industry application mainly coordinates shoes outsole, midsole, makes corresponding type body；
Size plate is made according to last carving bottom plate or panel, and produces corresponding shape.Marketing type insole is mainly that insole is straight
It connects as a kind of commodity selling, by developing teacher's design, the product to circulate on the market.
Important component of the insole as shoes has large effect, the design of a pair of thickness to the comfort that wears of shoes
Rational insole can make biped healthy, comfortable.And with the development of science and technology, the material and manufacture craft of insole are obtained for pole
The earth develops, it can not only change the interior environment of shoes, moreover it is possible to change the distribution of force of sole, so if can be according to the physiology of foot
The characteristic distributions of the difference and Plantar Pressure when Walking of structure and shoe cavity space size select the insole of suitable thickness, then can
Properly increase the comfort property of shoes.
When people are when jogging, certain impact can be generated to foot, the damping performance for insole of jogging refers to when slow
When runner moves, the falling impact power of a large amount of excess loads is born by foot, and in this process, insole can pass through its damping
The variation of material internal structure or the special construction of insole design occur physical deformation and generate certain confrontation falling impact power
Resistance, play the role of shock-absorbing buffering, the impact force suffered by human body made in movement to reduce, make to play protection to jogging
Performance.In short, the shock-absorbing function of insole, which refers to just insole, absorbs or reduces the ability of Sasser.Current traditional sock
There is also the bad problems of damping effect, elasticity, comfort, therefore also need to study it.
Invention content
The present invention solves the technical problem of：It is asked for traditional sock damping effect, elasticity, comfort are bad
Topic, provides a kind of preparation method of bradyseism type insole.
In order to solve the above-mentioned technical problem, the technical solution adopted in the present invention is：
（1）By cork oak granulated cork and hydrochloric acid in mass ratio 1：2~1：3 mixing, filtering obtain 1 processing granulated cork, by 1
Secondary processing granulated cork and sodium hydroxide solution in mass ratio 1：4~1：5 mixing, filtering obtain 2 processing granulated corks, by 2 times
Granulated cork washing is handled, and 2 times after washing are handled into granulated corks and calcium chloride solution in mass ratio 1：3~1：5 mixing,
And the cellulase of 2 0.1~0.2 times of processing granulated cork quality is added, stirring is impregnated, and is filtered, dry, obtains pretreatment cork
Oak granulated cork；
（2）By ethyl orthosilicate and isocyanates in mass ratio 1：2~1：1 mixing, and be added ethyl orthosilicate quality 0.2~
0.5 times of hercolyn D after being stirred, obtains impregnating agent；
（3）It will（N- amidino groups）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 2：1~4：1 mixing, and be added
Two cyclopentadienyls of 0.12~0.18 times of the paracide and polyethyleneglycol derivative quality that 0.2~0.4 times of polyethyleneglycol derivative quality
Iron is stirred, and obtains inorganic agent；
（4）By inorganic agent and organic siliconresin in mass ratio 1：4~1：5 mixing, and flax of 5~8 times of inorganic agent quality is added
The ethylene-vinyl acetate copolymer of 2~3 times of oil and inorganic agent quality, after being stirred, obtains silicone resin mixture, will have
Machine silicone compound and gelatin solution in mass ratio 1：10~1：12 mixing, must pre-process micro-capsule blank, will pre-process micro-capsule
Blank and metabisulfite solution in mass ratio 3：1~3：2 are stirred, and obtain Pretreatment Mixed Liauid, after Pretreatment Mixed Liauid is cooled down,
The formalin of 0.02~0.08 times of Pretreatment Mixed Liauid quality is added into Pretreatment Mixed Liauid, is stirred, obtains micro-capsule base
Material, after adjusting micro-capsule blank pH, solidification obtains pretreatment micro-capsule, after pretreatment micro-capsule is filtered washing, obtains micro-capsule to get pre- place
Manage adhesive；
（5）Count in parts by weight, weigh successively 50~70 parts pretreatment cork oak granulated corks, 80~100 parts of impregnating agent, 12~
20 parts of pretreatment adhesives, 5~10 parts of water and 5~12 parts of calcium bicarbonates, pretreatment cork oak granulated cork is mixed with impregnating agent
It closes and impregnates, filtering obtains modified cork oak granulated cork, and modified cork oak granulated cork is mixed with pretreatment adhesive, and adds
Enter water and calcium bicarbonate, after being stirred, obtains mixture, mixture is hot-forming, blank is obtained, blank is cut to get slow
Shake type insole.
Step（1）The grain size of the cork oak granulated cork is 40~80 mesh.
Step（2）The isocyanates is any one in monoisocyanates or diisocyanate.
Step（3）The polyethyleneglycol derivative is in polyethylene glycol-p-methyl benzenesulfonic acid ester or polyethylene glycol salicylate
Any one.
Step（4）The organic siliconresin is poly- methylsiloxane resin, and poly- ethyl organic siliconresin or poly- aryl are organic
Any one in silicones.
The beneficial effects of the invention are as follows：
（1）The present invention uses granulated cork when preparing bradyseism type insole, and granulated cork is carried out impregnation, first, makees
There is excellent elasticity and pliability appropriate for the granulated cork of insole raw material, it is preferable to make insole obtained have
Bradyseism performance and comfort level, secondly, after the pre-treatment, the permeability of cell improves granulated cork in granulated cork, is being soaked
After stain processing, granulated cork intracellular deposits have isocyanates, ethyl orthosilicate and hercolyn D, isocyanates can be in heat
It reacts with water during pressure and generates carbon dioxide and amine substance, the carbon dioxide of generation and can make granulated cork cell interior
Calcium chloride form calcium carbonate, to make the compression strength of product improve, and the amine substance of generation can be used as curing agent and promote
The solidification of organic siliconresin, to improve the mechanical property of product, ethyl orthosilicate can meet water hydrolysis, generate silica and alcohol
Substance, silica can further improve the compression strength of product, and the alcohols generated can be used as greasing substance and promote cell
Interior hercolyn D is combined with adhesive, to make product toughness can bradyseism performance further increase；
（2）The present invention uses pretreatment adhesive when preparing bradyseism type insole, on the one hand, contains ethylene-vinegar in adhesive
Sour ethylene copolymer can melt in a heated condition, to make adhesive liquefy completely in hot pressing, and then make cork
Contact area increases between grain and adhesive, and the mechanical property of product is made to improve, and on the other hand, pre-processes in adhesive and contains flax
Oil and inorganic agent, linseed oil can make the adhesive after solidification have certain toughness after hardening, to make the bradyseism performance of product
It further increases, and the active ingredient of inorganic agent has imitated vesicle structure, and ethylene-vinyl acetate copolymer can be coordinated to form foaming material
Material, bradyseism performance and toughness to make product further increase.
Specific implementation mode
The hydrochloric acid in mass ratio 1 for being 30~35% by cork oak granulated cork and mass fraction：2~1：3 mixing, in room temperature
Under the conditions of impregnate 30~50min after filter, obtain 1 processing granulated cork, by 1 processing granulated cork and mass fraction be 8~
12% sodium hydroxide solution in mass ratio 1：4~1：5 mixing, after impregnating 30~45min under conditions of being 20~35 DEG C in temperature
Filtering obtains 2 processing granulated corks, 2 processing granulated corks is washed with deionized 3~6 times, and by 2 times after washing
Handle the calcium chloride solution in mass ratio 1 that granulated cork is 10~15% with mass fraction：3~1：5 are mixed in beaker, and to
The cellulases of 2 0.1~0.2 times of processing granulated cork quality are added in beaker, in temperature be 30~38 DEG C, rotating speed 250
Under conditions of~350r/min stirring impregnate 25~55min after, filtering, obtain filter cake, filter cake moved into drying box, in temperature be 75
Under conditions of~85 DEG C after dry 20~25min, cork oak granulated cork must be pre-processed；Ethyl orthosilicate and isocyanates are pressed
Mass ratio 1：2~1：1 is mixed in flask, and the hydrogenated rosin first of 0.2~0.5 times of ethyl orthosilicate quality is added into flask
Ester is 25~30 DEG C in temperature, after rotating speed is stirred under conditions of being 200~320r/min after 20~40min, must impregnate
Agent；It will（N- amidino groups）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 2：1~4：1 is mixed in reaction kettle,
And the paracide and polyethyleneglycol derivative quality of 0.2~0.4 times of polyethyleneglycol derivative quality are added into reaction kettle
0.12~0.18 times of ferrocene is 32~45 DEG C in temperature, rotating speed is stirred 50 under conditions of being 200~280r/min~
After 80min, inorganic agent is obtained；By inorganic agent and organic siliconresin in mass ratio 1：4~1：5 mixing, and to inorganic agent and organosilicon
The ethene-vinyl acetate of 2~3 times of linseed oil and inorganic agent quality that 5~8 times of inorganic agent quality is added in the mixture of resin is total
Polymers is 45~55 DEG C in temperature, after rotating speed is stirred 25~35min under conditions of being 220~350r/min, obtains organosilicon
Resin compound, the gelatin solution in mass ratio 1 for being 3~5% by silicone resin mixture and mass fraction：10~1：12 is mixed
It closes, is 35~45 DEG C in temperature, under conditions of rotating speed is 200~300r/min, is stirred 10~20min, must pre-process micro-
Capsule blank will pre-process the metabisulfite solution in mass ratio 3 that micro-capsule blank and mass fraction are 25~35%：1~3：2 mixing, in
Temperature is 30~45 DEG C, under conditions of rotating speed is 250~350r/min, after being stirred 15~25min, must pre-process mixing
Liquid, after Pretreatment Mixed Liauid is cooled to 10~18 DEG C, be added into Pretreatment Mixed Liauid Pretreatment Mixed Liauid quality 0.02~
The formalin that 0.08 times of mass fraction is 30~40% is 12~18 DEG C in temperature, and rotating speed is the item of 220~300r/min
After being stirred 20~35min under part, obtain micro-capsule blank, adjust micro-capsule blank pH to 7~9, and in temperature be 10~15 DEG C
Under the conditions of solidification 30~45min after, obtain pretreatment micro-capsule, will pretreatment micro-capsule filter washing 5~10 times after, obtain micro-capsule to get
Pre-process adhesive；It counts in parts by weight, weighs 50~70 parts of pretreatment cork oak granulated corks, 80~100 parts of dippings successively
Agent, 12~20 parts of pretreatment adhesives, 5~10 parts of water and 5~12 parts of calcium bicarbonates, by pretreatment cork oak granulated cork and leaching
After 1~2h is impregnated in mixing under room temperature, filtering obtains modified cork oak granulated cork for stain agent, by modified cork oak cork
Grain is mixed in pretreatment adhesive in blender, and water and calcium bicarbonate are added into blender, in temperature be 40~45 DEG C,
After rotating speed is stirred 20~30min under conditions of being 200~300r/min, mixture is obtained, mixture is moved into hot press,
It it is 180~220 DEG C in temperature, pressure is hot-forming under conditions of being 1.5~3.0MPa, obtains blank, and blank is cut to get slow
Shake type insole.The grain size of the cork oak granulated cork is 40~80 mesh.The isocyanates is that monoisocyanates or two are different
Any one in cyanate.The polyethyleneglycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester or polyethylene glycol salicylate
In any one.The organic siliconresin is poly- methylsiloxane resin, poly- ethyl organic siliconresin or poly- aryl organosilicon tree
Any one in fat.
The hydrochloric acid in mass ratio 1 for being 35% by cork oak granulated cork and mass fraction：3 mixing, in impregnating under room temperature
It is filtered after 50min, obtains 1 processing granulated cork, the sodium hydroxide solution for being 12% with mass fraction by 1 processing granulated cork
In mass ratio 1：5 mixing are filtered after impregnating 45min under conditions of being 35 DEG C in temperature, 2 processing granulated corks are obtained, at 2 times
Reason granulated cork is washed with deionized 6 times, and the chlorination for being 15% with mass fraction by 2 processing granulated corks after washing
Calcium solution in mass ratio 1：5 are mixed in beaker, and the cellulose of 2 0.2 times of processing granulated cork quality is added into beaker
Enzyme is 38 DEG C in temperature, and after 55min is impregnated in stirring under conditions of rotating speed is 350r/min, filtering obtains filter cake, filter cake is moved into
Drying box must pre-process cork oak granulated cork under conditions of being 85 DEG C in temperature after dry 25min；By ethyl orthosilicate with
Isocyanates in mass ratio 1：1 is mixed in flask, and the hydrogenated rosin first of 0.5 times of ethyl orthosilicate quality is added into flask
Ester is 30 DEG C in temperature, after rotating speed is stirred rear 40min under conditions of being 320r/min, obtains impregnating agent；It will（N- amidino groups）Ten
Dialkylacrylamides and polyethyleneglycol derivative in mass ratio 4：1 is mixed in reaction kettle, and poly- second is added into reaction kettle
The ferrocene of 0.18 times of the paracide and polyethyleneglycol derivative quality that 0.4 times of diol, derivatives quality, in temperature be 45 DEG C,
After rotating speed is stirred 80min under conditions of being 280r/min, inorganic agent is obtained；By inorganic agent and organic siliconresin in mass ratio 1：
5 mix, and the linseed oil and inorganic agent quality 3 of 8 times of inorganic agent quality are added into the mixture of inorganic agent and organic siliconresin
Ethylene-vinyl acetate copolymer again is 55 DEG C in temperature, after rotating speed is stirred 35min under conditions of being 350r/min, obtains
Silicone resin mixture, the gelatin solution in mass ratio 1 for being 5% by silicone resin mixture and mass fraction：12 mixing,
It is 45 DEG C in temperature, under conditions of rotating speed is 300r/min, is stirred 20min, micro-capsule blank must be pre-processed, will pre-process micro-
The metabisulfite solution in mass ratio 3 that capsule blank is 35% with mass fraction：2 mixing, in temperature be 45 DEG C, rotating speed 350r/min
Under conditions of, after being stirred 25min, Pretreatment Mixed Liauid is obtained, it is mixed to pretreatment after Pretreatment Mixed Liauid is cooled to 18 DEG C
The formalin for being added that the mass fraction of 0.08 times of Pretreatment Mixed Liauid quality is 40% in liquid is closed, is 18 DEG C in temperature, rotating speed is
After being stirred 35min under conditions of 300r/min, obtain micro-capsule blank, adjust micro-capsule blank pH to 9, and in temperature be 15 DEG C
Under the conditions of solidification 45min after, obtain pretreatment micro-capsule, will pretreatment micro-capsule filter washing 10 times after, obtain micro-capsule to get pre-treating adhesive
Glutinous agent；It counts in parts by weight, weighs 70 parts of pretreatment cork oak granulated corks, 100 parts of impregnating agent, 20 parts of pretreatment gluings successively
Agent, 10 parts of water and 12 parts of calcium bicarbonates, will pretreatment cork oak granulated cork and impregnating agent in mixing immersion 2h under room temperature
Afterwards, it filters, obtains modified cork oak granulated cork, modified cork oak granulated cork and pretreatment adhesive are mixed in blender
In, and water and calcium bicarbonate are added into blender, it is 45 DEG C in temperature, rotating speed is stirred under conditions of being 300r/min
After 30min, mixture is obtained, mixture is moved into hot press, is 220 DEG C in temperature, pressure is hot pressing under conditions of 3.0MPa
Molding, obtains blank, and blank is cut to get bradyseism type insole.The grain size of the cork oak granulated cork is 80 mesh.It is described different
Cyanate is monoisocyanates.The polyethyleneglycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester.The organic siliconresin is
Poly- methylsiloxane resin.
By ethyl orthosilicate and isocyanates in mass ratio 1：1 is mixed in flask, and positive silicic acid second is added into flask
The hercolyn D that 0.5 times of ester quality is 30 DEG C in temperature, and rotating speed is stirred rear 40min under conditions of being 320r/min
Afterwards, impregnating agent is obtained；It will（N- amidino groups）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 4：1 is mixed in reaction kettle
In, and the paracide and polyethyleneglycol derivative quality 0.18 of 0.4 times of polyethyleneglycol derivative quality is added into reaction kettle
Ferrocene again is 45 DEG C in temperature, after rotating speed is stirred 80min under conditions of being 280r/min, obtains inorganic agent；It will processing
Agent and organic siliconresin in mass ratio 1：5 mixing, and inorganic agent quality 8 is added into the mixture of inorganic agent and organic siliconresin
The ethylene-vinyl acetate copolymer of 3 times of linseed oil and inorganic agent quality again is 55 DEG C in temperature, and rotating speed is 350r/min's
Under the conditions of be stirred 35min after, obtain silicone resin mixture, by silicone resin mixture and mass fraction be 5% it is bright
Sol solution in mass ratio 1：12 mixing are 45 DEG C in temperature, under conditions of rotating speed is 300r/min, is stirred 20min, obtains pre-
Micro-capsule blank is handled, the metabisulfite solution in mass ratio 3 that micro-capsule blank and mass fraction are 35% will be pre-processed：2 mixing, Yu Wen
Degree is 45 DEG C, under conditions of rotating speed is 350r/min, after being stirred 25min, Pretreatment Mixed Liauid is obtained, by Pretreatment Mixed Liauid
After being cooled to 18 DEG C, the formaldehyde that the mass fraction of 0.08 times of Pretreatment Mixed Liauid quality is 40% is added into Pretreatment Mixed Liauid
Solution is 18 DEG C in temperature, after rotating speed is stirred 35min under conditions of being 300r/min, obtains micro-capsule blank, adjust micro-capsule base
Expect pH to 9, and in temperature be 15 DEG C under conditions of solidification 45min after, obtain pretreatment micro-capsule, will pretreatment micro-capsule filter washing 10
After secondary, micro-capsule is obtained to get pretreatment adhesive；It counts in parts by weight, weighs 70 parts of cork oak granulated corks, 100 parts of leachings successively
Stain agent, 20 parts of pretreatment adhesives, 10 parts of water and 12 parts of calcium bicarbonates, by cork oak granulated cork and impregnating agent in room temperature condition
After 2h is impregnated in lower mixing, filtering obtains modified cork oak granulated cork, and modified cork oak granulated cork and pretreatment adhesive are mixed
Together in blender, and water and calcium bicarbonate are added into blender, in temperature be 45 DEG C, under conditions of rotating speed is 300r/min
After being stirred 30min, mixture is obtained, mixture is moved into hot press, is 220 DEG C in temperature, pressure is the item of 3.0MPa
It is hot-forming under part, blank is obtained, blank is cut to get bradyseism type insole.The grain size of the cork oak granulated cork is 80
Mesh.The isocyanates is monoisocyanates.The polyethyleneglycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester.It is described to have
Machine silicones is poly- methylsiloxane resin.
The hydrochloric acid in mass ratio 1 for being 35% by cork oak granulated cork and mass fraction：3 mixing, in impregnating under room temperature
It is filtered after 50min, obtains 1 processing granulated cork, the sodium hydroxide solution for being 12% with mass fraction by 1 processing granulated cork
In mass ratio 1：5 mixing are filtered after impregnating 45min under conditions of being 35 DEG C in temperature, 2 processing granulated corks are obtained, at 2 times
Reason granulated cork is washed with deionized 6 times, and the chlorination for being 15% with mass fraction by 2 processing granulated corks after washing
Calcium solution in mass ratio 1：5 are mixed in beaker, and the cellulose of 2 0.2 times of processing granulated cork quality is added into beaker
Enzyme is 38 DEG C in temperature, and after 55min is impregnated in stirring under conditions of rotating speed is 350r/min, filtering obtains filter cake, filter cake is moved into
Drying box must pre-process cork oak granulated cork under conditions of being 85 DEG C in temperature after dry 25min；By ethyl orthosilicate with
Isocyanates in mass ratio 1：1 is mixed in flask, in temperature be 30 DEG C, rotating speed be 320r/min under conditions of be stirred after
After 40min, impregnating agent is obtained；It will（N- amidino groups）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 4：1 is mixed in
In reaction kettle, and the paracide and polyethyleneglycol derivative matter of 0.4 times of polyethyleneglycol derivative quality is added into reaction kettle
The ferrocene of 0.18 times of amount is 45 DEG C in temperature, after rotating speed is stirred 80min under conditions of being 280r/min, obtains inorganic agent；
By inorganic agent and organic siliconresin in mass ratio 1：5 mixing, and handled to addition in the mixture of inorganic agent and organic siliconresin
The ethylene-vinyl acetate copolymer of 3 times of the linseed oil and inorganic agent quality that 8 times of agent quality is 55 DEG C in temperature, and rotating speed is
After being stirred 35min under conditions of 350r/min, silicone resin mixture is obtained, by silicone resin mixture and quality point
The gelatin solution in mass ratio 1 that number is 5%：12 mixing are 45 DEG C in temperature, under conditions of rotating speed is 300r/min, are stirred
20min must pre-process micro-capsule blank, will pre-process the metabisulfite solution in mass ratio 3 that micro-capsule blank and mass fraction are 35%：2
Mixing is 45 DEG C in temperature, under conditions of rotating speed is 350r/min, after being stirred 25min, obtains Pretreatment Mixed Liauid, will be pre-
After processing mixed liquor is cooled to 18 DEG C, the mass fraction that 0.08 times of Pretreatment Mixed Liauid quality is added into Pretreatment Mixed Liauid is
40% formalin is 18 DEG C in temperature, after rotating speed is stirred 35min under conditions of being 300r/min, obtains micro-capsule blank,
Adjust micro-capsule blank pH to 9, and in temperature be 15 DEG C under conditions of solidification 45min after, obtain pretreatment micro-capsule, micro-capsule will be pre-processed
It filters after washing 10 times, obtains micro-capsule to get pretreatment adhesive；It counts in parts by weight, weighs 70 parts of pretreatment cork oaks successively
Granulated cork, 100 parts of impregnating agent, 20 parts of pretreatment adhesives, 10 parts of water and 12 parts of calcium bicarbonates, will pre-process cork oak cork
For particle with impregnating agent after mixing immersion 2h under room temperature, filtering obtains modified cork oak granulated cork, and modified cork oak is soft
The wooden particle is mixed in pretreatment adhesive in blender, and water and calcium bicarbonate are added into blender, in temperature be 45 DEG C,
After rotating speed is stirred 30min under conditions of being 300r/min, mixture is obtained, mixture is moved into hot press, is in temperature
220 DEG C, pressure is hot-forming under conditions of being 3.0MPa, obtains blank, and blank is cut to get bradyseism type insole.The bolt
The grain size of skin oak granulated cork is 80 mesh.The isocyanates is monoisocyanates.The polyethyleneglycol derivative is poly- second two
Alcohol-p-methyl benzenesulfonic acid ester.The organic siliconresin is poly- methylsiloxane resin.
The hydrochloric acid in mass ratio 1 for being 35% by cork oak granulated cork and mass fraction：3 mixing, in impregnating under room temperature
It is filtered after 50min, obtains 1 processing granulated cork, the sodium hydroxide solution for being 12% with mass fraction by 1 processing granulated cork
In mass ratio 1：5 mixing are filtered after impregnating 45min under conditions of being 35 DEG C in temperature, 2 processing granulated corks are obtained, at 2 times
Reason granulated cork is washed with deionized 6 times, and the chlorination for being 15% with mass fraction by 2 processing granulated corks after washing
Calcium solution in mass ratio 1：5 are mixed in beaker, and the cellulose of 2 0.2 times of processing granulated cork quality is added into beaker
Enzyme is 38 DEG C in temperature, and after 55min is impregnated in stirring under conditions of rotating speed is 350r/min, filtering obtains filter cake, filter cake is moved into
Drying box must pre-process cork oak granulated cork under conditions of being 85 DEG C in temperature after dry 25min；By ethyl orthosilicate with
Isocyanates in mass ratio 1：1 is mixed in flask, and the hydrogenated rosin first of 0.5 times of ethyl orthosilicate quality is added into flask
Ester is 30 DEG C in temperature, after rotating speed is stirred rear 40min under conditions of being 320r/min, obtains impregnating agent；It will（N- amidino groups）Ten
Dialkylacrylamides and polyethyleneglycol derivative in mass ratio 4：1 is mixed in reaction kettle, and poly- second is added into reaction kettle
The ferrocene of 0.18 times of the paracide and polyethyleneglycol derivative quality that 0.4 times of diol, derivatives quality, in temperature be 45 DEG C,
After rotating speed is stirred 80min under conditions of being 280r/min, inorganic agent is obtained；By inorganic agent and organic siliconresin in mass ratio 1：
5 mix, and the ethylene-vinyl acetate copolymer of 3 times of inorganic agent quality is added into the mixture of inorganic agent and organic siliconresin,
It is 55 DEG C in temperature, after rotating speed is stirred 35min under conditions of being 350r/min, obtains silicone resin mixture, it will be organic
The gelatin solution in mass ratio 1 that silicone compound is 5% with mass fraction：12 mixing, in temperature be 45 DEG C, rotating speed 300r/
Under conditions of min, it is stirred 20min, micro-capsule blank must be pre-processed, will pre-process micro-capsule blank with mass fraction is 35%
Metabisulfite solution in mass ratio 3：2 mixing are 45 DEG C in temperature, under conditions of rotating speed is 350r/min, are stirred 25min
Afterwards, Pretreatment Mixed Liauid is obtained, after Pretreatment Mixed Liauid is cooled to 18 DEG C, Pretreatment Mixed Liauid is added into Pretreatment Mixed Liauid
The formalin that the mass fraction that 0.08 times of quality is 40% is 18 DEG C in temperature, and rotating speed stirs mixed under conditions of being 300r/min
After closing 35min, micro-capsule blank is obtained, adjust micro-capsule blank pH to 9, and obtained pre- after solidification 45min under conditions of being 15 DEG C in temperature
Micro-capsule is handled, pretreatment micro-capsule is filtered after washing 10 times, obtains micro-capsule to get pretreatment adhesive；It counts in parts by weight, successively
Weigh 70 parts of pretreatment cork oak granulated corks, 100 parts of impregnating agent, 20 parts of pretreatment adhesives, 10 parts of water and 12 parts of bicarbonates
Calcium, by pretreatment cork oak granulated cork with impregnating agent after mixing immersion 2h under room temperature, it is soft to obtain modified cork oak for filtering
Modified cork oak granulated cork is mixed in pretreatment adhesive in blender by the wooden particle, and be added into blender water and
Calcium bicarbonate is 45 DEG C in temperature, after rotating speed is stirred 30min under conditions of being 300r/min, mixture is obtained, by mixture
It moves into hot press, is 220 DEG C in temperature, pressure is hot-forming under conditions of being 3.0MPa, obtains blank, blank is cut, i.e.,
Obtain bradyseism type insole.The grain size of the cork oak granulated cork is 80 mesh.The isocyanates is monoisocyanates.It is described poly-
Ethylene glycol derivative is polyethylene glycol-p-methyl benzenesulfonic acid ester.The organic siliconresin is poly- methylsiloxane resin.
The hydrochloric acid in mass ratio 1 for being 35% by cork oak granulated cork and mass fraction：3 mixing, in impregnating under room temperature
It is filtered after 50min, obtains 1 processing granulated cork, the sodium hydroxide solution for being 12% with mass fraction by 1 processing granulated cork
In mass ratio 1：5 mixing are filtered after impregnating 45min under conditions of being 35 DEG C in temperature, 2 processing granulated corks are obtained, at 2 times
Reason granulated cork is washed with deionized 6 times, and the chlorination for being 15% with mass fraction by 2 processing granulated corks after washing
Calcium solution in mass ratio 1：5 are mixed in beaker, and the cellulose of 2 0.2 times of processing granulated cork quality is added into beaker
Enzyme is 38 DEG C in temperature, and after 55min is impregnated in stirring under conditions of rotating speed is 350r/min, filtering obtains filter cake, filter cake is moved into
Drying box must pre-process cork oak granulated cork under conditions of being 85 DEG C in temperature after dry 25min；By ethyl orthosilicate with
Isocyanates in mass ratio 1：1 is mixed in flask, and the hydrogenated rosin first of 0.5 times of ethyl orthosilicate quality is added into flask
Ester is 30 DEG C in temperature, after rotating speed is stirred rear 40min under conditions of being 320r/min, obtains impregnating agent；It will（N- amidino groups）Ten
Dialkylacrylamides and polyethyleneglycol derivative in mass ratio 4：1 is mixed in reaction kettle, and poly- second is added into reaction kettle
The ferrocene of 0.18 times of the paracide and polyethyleneglycol derivative quality that 0.4 times of diol, derivatives quality, in temperature be 45 DEG C,
After rotating speed is stirred 80min under conditions of being 280r/min, inorganic agent is obtained；By inorganic agent and organic siliconresin in mass ratio 1：
5 mixing, and the linseed oil of 8 times of inorganic agent quality is added into the mixture of inorganic agent and organic siliconresin, in temperature be 55 DEG C,
Rotating speed be 350r/min under conditions of be stirred 35min after, obtain silicone resin mixture, by silicone resin mixture with
The gelatin solution in mass ratio 1 that mass fraction is 5%：12 mixing are 45 DEG C in temperature, under conditions of rotating speed is 300r/min, stir
Mixing 20min is mixed, micro-capsule blank must be pre-processed, the metabisulfite solution that micro-capsule blank is 35% with mass fraction will be pre-processed and press matter
Measure ratio 3：2 mixing are 45 DEG C in temperature, under conditions of rotating speed is 350r/min, after being stirred 25min, must pre-process mixing
After Pretreatment Mixed Liauid is cooled to 18 DEG C, the matter of 0.08 times of Pretreatment Mixed Liauid quality is added into Pretreatment Mixed Liauid for liquid
The formalin that score is 40% is measured, is 18 DEG C in temperature, after rotating speed is stirred 35min under conditions of being 300r/min, obtains micro-
Capsule blank, adjust micro-capsule blank pH to 9, and in temperature be 15 DEG C under conditions of solidification 45min after, obtain pretreatment micro-capsule, will be pre-
After processing micro-capsule suction filtration washing 10 times, micro-capsule is obtained to get pretreatment adhesive；It counts in parts by weight, weighs 70 parts of pre- places successively
Cork oak granulated cork, 100 parts of impregnating agent, 20 parts of pretreatment adhesives, 10 parts of water and 12 parts of calcium bicarbonates are managed, bolt will be pre-processed
With impregnating agent after mixing immersion 2h under room temperature, filtering obtains modified cork oak granulated cork, will be modified skin oak granulated cork
Cork oak granulated cork is mixed in pretreatment adhesive in blender, and water and calcium bicarbonate, Yu Wen are added into blender
Degree is 45 DEG C, after rotating speed is stirred 30min under conditions of being 300r/min, obtains mixture, mixture is moved into hot press,
It it is 220 DEG C in temperature, pressure is hot-forming under conditions of being 3.0MPa, obtains blank, and blank is cut to get bradyseism type insole.
The grain size of the cork oak granulated cork is 80 mesh.The isocyanates is monoisocyanates.The polyethyleneglycol derivative
For polyethylene glycol-p-methyl benzenesulfonic acid ester.The organic siliconresin is poly- methylsiloxane resin.
The hydrochloric acid in mass ratio 1 for being 35% by cork oak granulated cork and mass fraction：3 mixing, in impregnating under room temperature
It is filtered after 50min, obtains 1 processing granulated cork, the sodium hydroxide solution for being 12% with mass fraction by 1 processing granulated cork
In mass ratio 1：5 mixing are filtered after impregnating 45min under conditions of being 35 DEG C in temperature, 2 processing granulated corks are obtained, at 2 times
Reason granulated cork is washed with deionized 6 times, and the chlorination for being 15% with mass fraction by 2 processing granulated corks after washing
Calcium solution in mass ratio 1：5 are mixed in beaker, and the cellulose of 2 0.2 times of processing granulated cork quality is added into beaker
Enzyme is 38 DEG C in temperature, and after 55min is impregnated in stirring under conditions of rotating speed is 350r/min, filtering obtains filter cake, filter cake is moved into
Drying box must pre-process cork oak granulated cork under conditions of being 85 DEG C in temperature after dry 25min；By ethyl orthosilicate with
Isocyanates in mass ratio 1：1 is mixed in flask, and the hydrogenated rosin first of 0.5 times of ethyl orthosilicate quality is added into flask
Ester is 30 DEG C in temperature, after rotating speed is stirred rear 40min under conditions of being 320r/min, obtains impregnating agent；It will（N- amidino groups）Ten
Dialkylacrylamides and polyethyleneglycol derivative in mass ratio 4：1 is mixed in reaction kettle, and poly- second is added into reaction kettle
The ferrocene of 0.18 times of the paracide and polyethyleneglycol derivative quality that 0.4 times of diol, derivatives quality, in temperature be 45 DEG C,
After rotating speed is stirred 80min under conditions of being 280r/min, inorganic agent is obtained；By inorganic agent and organic siliconresin in mass ratio 1：
5 mix, and the linseed oil and inorganic agent quality 3 of 8 times of inorganic agent quality are added into the mixture of inorganic agent and organic siliconresin
Ethylene-vinyl acetate copolymer again is 55 DEG C in temperature, after rotating speed is stirred 35min under conditions of being 350r/min, obtains
Silicone resin mixture, the gelatin solution in mass ratio 1 for being 5% by silicone resin mixture and mass fraction：12 mixing,
It is 45 DEG C in temperature, under conditions of rotating speed is 300r/min, is stirred 20min, micro-capsule blank must be pre-processed, will pre-process micro-
The metabisulfite solution in mass ratio 3 that capsule blank is 35% with mass fraction：2 mixing, in temperature be 45 DEG C, rotating speed 350r/min
Under conditions of, after being stirred 25min, Pretreatment Mixed Liauid is obtained, it is mixed to pretreatment after Pretreatment Mixed Liauid is cooled to 18 DEG C
The formalin for being added that the mass fraction of 0.08 times of Pretreatment Mixed Liauid quality is 40% in liquid is closed, is 18 DEG C in temperature, rotating speed is
After being stirred 35min under conditions of 300r/min, obtain micro-capsule blank, adjust micro-capsule blank pH to 9, and in temperature be 15 DEG C
Under the conditions of solidification 45min after, obtain pretreatment micro-capsule, will pretreatment micro-capsule filter washing 10 times after, obtain micro-capsule to get pre-treating adhesive
Glutinous agent；It counts in parts by weight, weighs 70 parts of pretreatment cork oak granulated corks, 100 parts of impregnating agent, 20 parts of pretreatment gluings successively
Agent, 10 parts of water, by pretreatment cork oak granulated cork with impregnating agent after mixing immersion 2h under room temperature, filtering obtains modification
Modified cork oak granulated cork and pretreatment adhesive are mixed in blender by cork oak granulated cork, and into blender
Water is added, is 45 DEG C in temperature, after rotating speed is stirred 30min under conditions of being 300r/min, obtains mixture, mixture is moved
Enter in hot press, in temperature be 220 DEG C, pressure be 3.0MPa under conditions of it is hot-forming, obtain blank, by blank cut to get
Bradyseism type insole.The grain size of the cork oak granulated cork is 80 mesh.The isocyanates is monoisocyanates.The poly- second
Diol, derivatives are polyethylene glycol-p-methyl benzenesulfonic acid ester.The organic siliconresin is poly- methylsiloxane resin.
Comparative example：The insole of Fujian footwear material Co., Ltd production.
1 to 6 gained insole of example and comparative example product are subjected to performance detection, specific detection method is as follows：
Flexibility Test Method：Each specimen size is 7mm × 7mm, thickness >=6mm.
Experiment is placed on resiliometer on horizontal, hard surface, and carries out the zeroing of instrument board pointer.
Due to using resiliometer measurement request sample thickness >=6mm, while most of detected materials used in this experiment
Thickness is less than 6mm, therefore test measurement is carried out by the way of multiple-level stack.Material is placed on pinch, release, which is fallen, rushes
Hammer, impact detected materials surface, then the numerical value on reading pointer, measures the elasticity number of 5 test points successively, and 5 points are surveyed
The average value of magnitude is the elasticity number of the detected materials.
Damping performance：Using the falling type jump bit of autonomous Design making and putting down for combination model Footscan USB2
Board-like sole pressure test instrument carries out dynamic analysis to the damping performance of material, measures and impacts above-mentioned insole using uniform impingement power
Different impact force peak values when surface received by data collector.
Comfort：Subject is 20 female student enrollment, and 167.6 ± 4.3cm of height, 55.1 ± 4.6kg of weight, foot is long
24.4 ± 0.8cm, the wide 8.3 ± 0.4cm of foot, at 22.4 ± 1.3 years old age, lower limb are without injured history, and without flat foot, physical condition
And locomitivity is good.The selection of comfort evaluation scale has to follow at following 3 points：（1）9 all subjects must be right
The understanding of subjective assessment term semanteme is consistent.（2）Description is comfortably symmetrical with uncomfortable phrase.（3）Indicate comfortably with do not relax
Suitable phrase number wants equal.Based on the above principle, 5 methods of semantic difference scale have been selected, wherein minimum scale is 0.2, and
Take its average value.Shoe pressure comfort subjective assessment term is followed successively by：0 representative is very comfortable, and 1 represents comfortably, and 2 representatives are relatively relaxed
It is suitable, 3 represent it is uncomfortable, 4 represent it is very uncomfortable.
Specific testing result is as shown in table 1：
Table 1：Performance detection table
| Detection content | Example 1 | Example 2 | Example 3 | Example 4 | Example 5 | Example 6 | Comparative example |
| Elasticity/% | 26.05 | 20.46 | 18.40 | 21.42 | 19.28 | 20.38 | 13.80 |
| Impact force peak value/N | 14.5 | 23.8 | 24.8 | 20.2 | 23.4 | 26.3 | 39.3 |
| Comfort level score | 0.63 | 1.01 | 1.21 | 0.9 | 1.04 | 1.16 | 1.7 |
By 1 testing result of table it is found that present invention gained bradyseism type insole has excellent damping effect, elasticity and comfort.
Claims (5)
1. a kind of preparation method of bradyseism type insole, it is characterised in that specifically preparation process is：
（1）By cork oak granulated cork and hydrochloric acid in mass ratio 1：2~1：3 mixing, filtering obtain 1 processing granulated cork, by 1
Secondary processing granulated cork and sodium hydroxide solution in mass ratio 1：4~1：5 mixing, filtering obtain 2 processing granulated corks, by 2 times
Granulated cork washing is handled, and 2 times after washing are handled into granulated corks and calcium chloride solution in mass ratio 1：3~1：5 mixing,
And the cellulase of 2 0.1~0.2 times of processing granulated cork quality is added, stirring is impregnated, and is filtered, dry, obtains pretreatment cork
Oak granulated cork；
（2）By ethyl orthosilicate and isocyanates in mass ratio 1：2~1：1 mixing, and be added ethyl orthosilicate quality 0.2~
0.5 times of hercolyn D after being stirred, obtains impregnating agent；
（3）It will（N- amidino groups）Dodecylacrylamide and polyethyleneglycol derivative in mass ratio 2：1~4：1 mixing, and be added
Two cyclopentadienyls of 0.12~0.18 times of the paracide and polyethyleneglycol derivative quality that 0.2~0.4 times of polyethyleneglycol derivative quality
Iron is stirred, and obtains inorganic agent；
（4）By inorganic agent and organic siliconresin in mass ratio 1：4~1：5 mixing, and flax of 5~8 times of inorganic agent quality is added
The ethylene-vinyl acetate copolymer of 2~3 times of oil and inorganic agent quality, after being stirred, obtains silicone resin mixture, will have
Machine silicone compound and gelatin solution in mass ratio 1：10~1：12 mixing, must pre-process micro-capsule blank, will pre-process micro-capsule
Blank and metabisulfite solution in mass ratio 3：1~3：2 are stirred, and obtain Pretreatment Mixed Liauid, after Pretreatment Mixed Liauid is cooled down,
The formalin of 0.02~0.08 times of Pretreatment Mixed Liauid quality is added into Pretreatment Mixed Liauid, is stirred, obtains micro-capsule base
Material, after adjusting micro-capsule blank pH, solidification obtains pretreatment micro-capsule, after pretreatment micro-capsule is filtered washing, obtains micro-capsule to get pre- place
Manage adhesive；
（5）Count in parts by weight, weigh successively 50~70 parts pretreatment cork oak granulated corks, 80~100 parts of impregnating agent, 12~
20 parts of pretreatment adhesives, 5~10 parts of water and 5~12 parts of calcium bicarbonates, pretreatment cork oak granulated cork is mixed with impregnating agent
It closes and impregnates, filtering obtains modified cork oak granulated cork, and modified cork oak granulated cork is mixed with pretreatment adhesive, and adds
Enter water and calcium bicarbonate, after being stirred, obtains mixture, mixture is hot-forming, blank is obtained, blank is cut to get slow
Shake type insole.
2. a kind of preparation method of bradyseism type insole according to claim 1, it is characterised in that：Step（1）The bolt
The grain size of skin oak granulated cork is 40~80 mesh.
3. a kind of preparation method of bradyseism type insole according to claim 1, it is characterised in that：Step（2）The isocyanide
Acid esters is any one in monoisocyanates or diisocyanate.
4. a kind of preparation method of bradyseism type insole according to claim 1, it is characterised in that：Step（3）The poly- second
Diol, derivatives are any one in polyethylene glycol-p-methyl benzenesulfonic acid ester or polyethylene glycol salicylate.
5. a kind of preparation method of bradyseism type insole according to claim 1, it is characterised in that：Step（4）It is described organic
Silicones is poly- methylsiloxane resin, any one in poly- ethyl organic siliconresin or poly- aryl organic siliconresin.
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111885916A (en) * | 2018-01-11 | 2020-11-03 | 加法尔企业R&D公司 | Solid polymeric material impregnated with volatile organic substances and with specific esters and use thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111885916A (en) * | 2018-01-11 | 2020-11-03 | 加法尔企业R&D公司 | Solid polymeric material impregnated with volatile organic substances and with specific esters and use thereof |
| CN111885916B (en) * | 2018-01-11 | 2022-08-05 | 加法尔企业R&D公司 | Solid polymeric material impregnated with volatile organic substances and with specific esters and use thereof |
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