CN108419803A - A kind of Herbicidal combinations and its application containing AC 263222 and prometryn - Google Patents

A kind of Herbicidal combinations and its application containing AC 263222 and prometryn Download PDF

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Publication number
CN108419803A
CN108419803A CN201810587634.XA CN201810587634A CN108419803A CN 108419803 A CN108419803 A CN 108419803A CN 201810587634 A CN201810587634 A CN 201810587634A CN 108419803 A CN108419803 A CN 108419803A
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China
Prior art keywords
prometryn
synergistic
compositions
active ingredient
grass
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CN201810587634.XA
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CN108419803B (en
Inventor
杜龙
曲明静
李晓
鞠倩
姜晓静
石程仁
白冬梅
曲春娟
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Shandong Peanut Research Institute
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Shandong Peanut Research Institute
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    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/64Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with three nitrogen atoms as the only ring hetero atoms
    • A01N43/661,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms
    • A01N43/681,3,5-Triazines, not hydrogenated and not substituted at the ring nitrogen atoms with two or three nitrogen atoms directly attached to ring carbon atoms
    • A01N43/70Diamino—1,3,5—triazines with only one oxygen, sulfur or halogen atom or only one cyano, thiocyano (—SCN), cyanato (—OCN) or azido (—N3) group directly attached to a ring carbon atom
    • AHUMAN NECESSITIES
    • A01AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
    • A01NPRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
    • A01N43/00Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
    • A01N43/48Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with two nitrogen atoms as the only ring hetero atoms
    • A01N43/501,3-Diazoles; Hydrogenated 1,3-diazoles

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  • Life Sciences & Earth Sciences (AREA)
  • Agronomy & Crop Science (AREA)
  • Pest Control & Pesticides (AREA)
  • Plant Pathology (AREA)
  • Health & Medical Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Dentistry (AREA)
  • General Health & Medical Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Environmental Sciences (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The invention discloses a kind of using AC 263222 and prometryn as the Synergistic herbicide compositions of active constituent and its application, belongs to pesticide herbicide field.Active ingredient AC 263222 and prometryn weight percent are 1: 50~1: 50, preferred 1: 20~1: 20 in the Synergistic herbicide compositions of the present invention;The active ingredient AC 263222 and prometryn account for the 1~90% of total composition, preferred 30~60%.Herbicidal combinations of the present invention can effectively prevent Peanut Fields major part weeds, and safety is good, and reduce the security risk to succession crop.

Description

A kind of Herbicidal combinations and its application containing AC 263222 and prometryn
Technical field
The present invention relates to a kind of pesticide herbicide fields, and in particular to a kind of weeding containing AC 263222 and prometryn Composition and its application.
Background technology
Peanut is the main oil crops in China, in recent years, long-term cultivated area at 70,000,000 mu or so, with Henan, Shandong, Hebei, Anhui are major production areas.China's Weed in peanut field occurrence quantity is big and type is various, seriously affects the yield of peanut And quality.According to incompletely statistics, peanut because weeds caused by the underproduction in 6%-15%, serious plot may be up to 50% with On.
AC 263222 (imazapic) is a kind of imidazolone type wide spectrum, ultra high efficiency Peanut Fields herbicides special, is inhibited Weeds acetolactate synthestase prevents branched-chain amino acid from synthesizing, and in turn results in weeds death.Prevent and kill off annual and perennial grass Section weeds and broad leaved weed, to rhizome of nutgrass flatsedge special efficacy.But it is longer that the ingredient imitates the phase in the soil, if dosage Gao Shiqi is in soil In residual quantity be easy injury succession crop, cause the different degrees of underproduction.
Prometryn (prometryn) is a kind of inhibitor of photosynthesis, blocks electron transfer process in photosynthesis of plant, In turn result in weeds death.Can be used for the crop fields such as paddy and wheat, cotton, peanut, soybean, vegetables, fruit tree prevent and kill off 1 year raw broad leaved weed, Dogstail, nutgrass flatsedge and certain perennial weeds.
It is means the most economical and effective during farmland weed is prevented and kill off using herbicide chemical weed control.But long-term continuous high agent The problems such as using to amount single variety or the chemical herbicide of the single mode of action, be easy to causeing weeds drug resistance and resistance evolution. The reasonable compounding or mixture of herbicidal compounds, which have, to be expanded weeds spectrum, improves preventive effect, delays weeds drug resistance and anti-medicine The advantages that generation and development of property, be one of the most effective methods to solve the above problems.
Invention content
Technical problem to be solved by the invention is to provide a kind of Herbicidal compositions, are reducing AC 263222 dosage situation Under still can prevent and kill off Peanut Fields major part weeds, and reduce the security risk to succession crop.
In order to solve the above technical problems, the present invention realizes by following technical solution:
A kind of Synergistic herbicide compositions, containing active ingredient AC 263222 and prometryn, the active ingredient first imidazoles Niacin is 1: 50~1: 50 with prometryn weight percent.
On the basis of said program, the active ingredient AC 263222 is 1: 20~1 with prometryn weight percent: 20。
On the basis of said program, the active ingredient AC 263222 and prometryn account for total composition 1~ 90%.
On the basis of said program, the active ingredient AC 263222 and prometryn account for total composition 30%~ 60%.
On the basis of said program, the specific preparation of the Herbicidal combinations is missible oil, suspending agent, microemulsion, outstanding breast Agent, aqueous emulsion, dispersible oil-suspending agent, wettable powder or water dispersible granules.
Application of the above-mentioned Synergistic herbicide compositions in preventing Peanut Fields injurious weed.
On the basis of said program, the Peanut Fields injurious weed is lady's-grass, barnyard grass, lamb's-quarters, purslane.
Herbicidal synergistic wettable powder containing AC 263222 and prometryn, prepared in parts by weight by following components and At:The active ingredient AC 263222 accounts for the 30%~60% of weeding wettable powder total amount with prometryn, inert filler 10%~90%, wetting agent 1%~5%, dispersant 1%~10%, stabilizer 1%~3%, synergist 1%~5%.
On the basis of said program, the inert filler is kaolin, diatomite, attapulgite, bentonite or hard charcoal One or more compositions in black;
The wetting agent be one kind in neopelex, pull open powder, pungent (nonyl) base phenol polyethenoxy ether etc. or Numerous compositions;
The dispersant is lignin and its derivative sulfonate, naphthalene or alkyl naphthalene formaldehyde condensate sulfonate, polyoxy second One in alkene polyoxypropylene base ether block copolymers, alkylphenol-polyethenoxy base ether phosphate, carboxymethyl cellulose, polyvinyl alcohol Kind or numerous compositions;
The stabilizer is one kind in tbp, disodium hydrogen phosphate;
Synergist is one or more compositions in Escin, capsaicine, Butacide.
The above-mentioned Herbicidal synergistic wettable powder containing AC 263222 and prometryn is in preventing Peanut Fields injurious weed Application.
On the basis of said program, the Peanut Fields injurious weed is lady's-grass, barnyard grass, lamb's-quarters, purslane.
Beneficial effects of the present invention:Present invention is mainly used for soil treatments, have significant synergies, and can effectively prevent Peanut Fields major part weeds are controlled, safety is good, and reduces the security risk to succession crop.
Specific implementation mode
Term as used in the present invention generally has those of ordinary skill in the art usual unless otherwise specified The meaning of understanding.
With reference to specific embodiment, and with reference to the data further detailed description present invention.Following embodiment only be It illustrates the present invention, rather than limits the scope of the invention in any way.
Embodiment
One, indoor proportioning joint toxicity measuring
For trying weeds:Lady's-grass (Digitaria sanguinalis), barnyard grass (Echinochloa crusgalli), lamb's-quarters (Chenopodium album), purslane (Portulaca oleracea).
Experimental condition and the culture for trying material:The culture of experiment examination material, 25~35 DEG C of temperature are carried out in illumination cultivation room.It will Quantitative lady's-grass, barnyard grass, lamb's-quarters, purslane presprouting of seeds are sowed at after showing money or valuables one carries unintentionally in the plastic tub of diameter 8cm, and 1~2mm of earthing is put into In pallet equipped with water, water is allowed gradually to penetrate into, it is for use that illumination cultivation room is transferred to after waiting water to be seeped into native table.
Reagent agent:98% AC 263222 active compound, Weifang CYNDA Chemical Engineering Co., Ltd provide;95% prometryn active compound, Shandong Weifang Rainbow Chemical Co., Ltd. provides.
Reagent agent drug solution preparing:Weigh quantitative AC 263222 and prometryn active compound, diformazan respectively with electronic balance Base formamide (DMF) dissolves, and required concentration is diluted to 0.1% Tween-80 aqueous solution.
Test dose designs:
1 reagent agent management of weeds test dose of table designs (dosage g.a.i./hm2)
Application method:Test in weed seed show money or valuables one carries unintentionally after planting soil even spraying processing.Weeds are uniformly placed in face Product 1m2Platform on, with ASS-4 type automatic rations spraying system (National agricultural information project Technical Research Center) spray, Teejet9503EVS Fan spray heads, spouting liquid 450L/hm2, atomisation pressure 0.275MPa, 4 repetitions.
Weedy rices method, time:It weighs each processing weeds aerial part fresh weight within 20 days after dispenser, calculates fresh weight preventive effect.
Drug effect computational methods:Theoretical fresh weight inhibition rate (the E of each processing blend compositions is calculated with Gowing methods0=X+Y- X*Y/100), then compared with actual measurement inhibiting rate (E), the mixed synergy type to weeds of both evaluations works as E-E0Value It is synergistic effect more than 10%, be antagonism less than -10%, is addition between -10%~10%.
2 AC 263222 of table is mixed with prometryn to grassy weed control effect
3 AC 263222 of table is mixed with prometryn to broad leaved weed control effect
By composition provided by the invention it can be seen from upper table 2,3 to grass family and broad-leaved under suitably proportioning dosage Weeds have outstanding preventive effect, and can significantly improve preventive effect of the AC 263222 to lamb's-quarters, and synergistic effect is apparent. Peanut Fields major part weeds still can be prevented and kill off in the case that reducing AC 263222 dosage, and reduce the safety to succession crop Risk.
Two, field control effectiveness test:
Each ingredient of each composition and content according to the form below correct amount obtain composition wettable powder through Ultrafine Jet Milling Agent 1~6, is shown in Table 4.Comparison medicament is:240g/L AC 263222s aqua (German BASF), 40% prometryn wettable powder (Zhejiang Zhong Shan chemical industry).Soil moisture is moderate, and soil moisture content is good, and soil treatment, spouting liquid 450L/ are immediately carried out after peanut seeding hm2.Fresh weight preventive effect is investigated after 40 days.
4 composition of table, 1~6 each component content
Project Composition 1 Composition 2 Composition 3 Composition 4 Composition 5 Composition 6
Active constituent content/% 40 40 40 60 60 60
A AC 263222s/g 6.7 3.6 1.9 10 5.5 2.9
B prometryns/g 33.3 36.4 38.1 50 54.5 57.1
A:B 1:5 1:10 1:20 1:5 1:10 1:20
Neopelex/g 5 5 5 5 5 5
Sodium lignin sulfonate/g 8 8 8 8 8 8
Tbp/g 2 2 2 2 2 2
Escin/g 2 2 2 2 2 2
Kaolin/g 43 43 43 23 23 23
5 each composition field efficacy of table
Field control effectiveness test shows that AC 263222 is mixed with prometryn under less than crop field recommended dose and can get well Herbicidal effect, half measures the AC 263222 integrated control effect to weeds mixed with constant prometryn up to 93%, and grass is flutterred with partly measuring Only mixed preventive effect is also 82% or more.The low dosage of AC 263222 is applied, and the residual risk to second stubble crop can be reduced.
The above described is only a preferred embodiment of the present invention, being not that the invention has other forms of limitations, appoint What those skilled in the art changed or be modified as possibly also with the technology contents of the disclosure above equivalent variations etc. Imitate embodiment.But it is every without departing from technical solution of the present invention content, according to the technical essence of the invention to above example institute Any simple modification, equivalent variations and the remodeling made, still fall within the protection domain of technical solution of the present invention.

Claims (10)

1. a kind of Synergistic herbicide compositions, it is characterised in that:Containing active ingredient AC 263222 and prometryn, it is described effectively at It is 1: 50~1: 50 to divide AC 263222 and prometryn weight percent.
2. Synergistic herbicide compositions according to claim 1, it is characterised in that:The active ingredient AC 263222 and flutter grass Nt wt net weight percentage is 1: 20~1: 20.
3. Synergistic herbicide compositions according to claim 1 or claim 2, it is characterised in that:The active ingredient AC 263222 with Prometryn accounts for the 1~90% of total composition, and preferred 30%~60%.
4. according to any one of claims 1 to 3 Synergistic herbicide compositions, it is characterised in that:The tool of the Herbicidal combinations Body preparation is missible oil, suspending agent, microemulsion, suspension emulsion, aqueous emulsion, dispersible oil-suspending agent, wettable powder or water-dispersible grain Agent.
5. application of any one of the claim 1-4 Synergistic herbicide compositions in preventing Peanut Fields injurious weed.
6. application according to claim 5, it is characterised in that:The Peanut Fields injurious weed is lady's-grass, barnyard grass, lamb's-quarters, horse Bitterroot.
7. the Herbicidal synergistic wettable powder containing AC 263222 and prometryn, it is characterised in that:By weight by following components Number is prepared:The active ingredient AC 263222 accounts for the 30%~60% of weeding wettable powder total amount with prometryn, Inert filler 10%~90%, wetting agent 1%~5%, dispersant 1%~10%, stabilizer 1%~3%, synergist 1%~ 5%.
8. the Herbicidal synergistic wettable powder containing AC 263222 and prometryn according to claim 7, it is characterised in that:
The inert filler is one or more compositions in kaolin, diatomite, attapulgite, bentonite or white carbon;
The wetting agent is one or more in neopelex, pull open powder, pungent (nonyl) base phenol polyethenoxy ether etc. Composition;
The dispersant is lignin and its derivative sulfonate, naphthalene or alkyl naphthalene formaldehyde condensate sulfonate, polyoxyethylene are poly- Oxypropylene group ether block copolymers, alkylphenol-polyethenoxy base ether phosphate, carboxymethyl cellulose, one kind in polyvinyl alcohol or Numerous compositions;
The stabilizer is one kind in tbp, disodium hydrogen phosphate;
Synergist is one or more compositions in Escin, capsaicine, Butacide.
9. claim 7 or the 8 Herbicidal synergistic wettable powders containing AC 263222 and prometryn are in prevention Peanut Fields Application in injurious weed.
10. application according to claim 9, it is characterised in that:The Peanut Fields injurious weed is lady's-grass, barnyard grass, lamb's-quarters, horse Bitterroot.
CN201810587634.XA 2018-06-08 2018-06-08 Herbicidal composition containing imazapic and prometryn and application thereof Active CN108419803B (en)

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