CN108410064A - A kind of High-impact Polypropylene and preparation method and application of amion acetic acid modification - Google Patents
A kind of High-impact Polypropylene and preparation method and application of amion acetic acid modification Download PDFInfo
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- CN108410064A CN108410064A CN201810280733.3A CN201810280733A CN108410064A CN 108410064 A CN108410064 A CN 108410064A CN 201810280733 A CN201810280733 A CN 201810280733A CN 108410064 A CN108410064 A CN 108410064A
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- acetic acid
- polypropylene
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/04—Oxygen-containing compounds
- C08K5/09—Carboxylic acids; Metal salts thereof; Anhydrides thereof
- C08K5/098—Metal salts of carboxylic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/17—Amines; Quaternary ammonium compounds
- C08K5/175—Amines; Quaternary ammonium compounds containing COOH-groups; Esters or salts thereof
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/49—Phosphorus-containing compounds
- C08K5/51—Phosphorus bound to oxygen
- C08K5/53—Phosphorus bound to oxygen bound to oxygen and to carbon only
- C08K5/5317—Phosphonic compounds, e.g. R—P(:O)(OR')2
- C08K5/5333—Esters of phosphonic acids
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/38—Boron-containing compounds
- C08K2003/387—Borates
Abstract
The High-impact Polypropylene and preparation method and application being modified the invention discloses a kind of amion acetic acid.The High-impact Polypropylene includes the component of following parts by weight：90 135 parts of polypropylene, 10 15 parts of amion acetic acid, 10 14 parts of trithiocarbonic acid sodium, 58 parts of potassium oleate, 6 15 parts of phenyl-phosphonic acid diethylester, 49 parts of hydroxy stearic acid ethylhexyl, 38 parts of line borate.The High-impact Polypropylene that the amion acetic acid of the present invention is modified has higher shock resistance, toughness and rigid there has also been increasing substantially, and can preferably be used in the technical fields such as electric power, chemical industry, medical treatment；Preparation process is simple, is conducive to promote.
Description
Technical field
The present invention relates to a kind of polypropylene material, High-impact Polypropylene and system that specifically a kind of amion acetic acid is modified
Preparation Method and application.
Background technology
A kind of thermoplastic resin of prepared by polypropylene is by propylene polymerization.It is divided into isotactic poly- third by methyl arrangement position
Alkene (isotactic polypropylene), random polypropylene (atactic polypropylene) and syndiotactic polypropylene
Three kinds of (syndiotactic polypropylene).Polypropylene is the highly crystalline polymerization of nontoxic, odorless, tasteless milky
Object, density only have 0.90-0.91g/cm3, it is one of kind most light in current all plastics.It is particularly stable to water, in water
In water absorption rate be only 0.01%, molecular weight about 8-15 ten thousand.But existing polypropylene material has the shortcomings that shock resistance is poor,
Limit its use scope.Therefore, the present invention provides a kind of High-impact Polypropylene and preparation method of amion acetic acid modification
And application.
Invention content
The purpose of the present invention is to provide a kind of High-impact Polypropylene of amion acetic acid modification and preparation method and answer
With to solve the problems mentioned in the above background technology.
To achieve the above object, the present invention provides the following technical solutions：
A kind of High-impact Polypropylene that amion acetic acid is modified, the High-impact Polypropylene includes following parts by weight
Several components：90-135 parts of polypropylene, 10-15 parts of amion acetic acid, 10-14 parts of trithiocarbonic acid sodium, 5-8 parts of potassium oleate, phenyl
6-15 parts of diethyl phosphonate, 4-9 parts of hydroxy stearic acid ethylhexyl, 3-8 parts of line borate.
As a further solution of the present invention：The High-impact Polypropylene includes the component of following parts by weight：It is poly-
100-125 parts of propylene, 12-14 parts of amion acetic acid, 11-13 parts of trithiocarbonic acid sodium, 6-8 parts of potassium oleate, phenyl-phosphonic acid diethylester
8-13 parts, 5-8 parts of hydroxy stearic acid ethylhexyl, 4-7 parts of line borate.
As a further solution of the present invention：The High-impact Polypropylene includes the component of following parts by weight：It is poly-
115 parts of propylene, 13 parts of amion acetic acid, 12 parts of trithiocarbonic acid sodium, 7 parts of potassium oleate, 11 parts of phenyl-phosphonic acid diethylester, hydroxy stearate
7 parts of sour ethylhexyl, 6 parts of line borate.
A kind of preparation method for the High-impact Polypropylene that amion acetic acid is modified, includes the following steps：
(1) amion acetic acid, phenyl-phosphonic acid diethylester and hydroxy stearic acid ethylhexyl are put into reactor and are mixed, be added
80-150 parts of ethanol solution is placed at 40-65 DEG C and is stirred to react 40-60min；
(2) trithiocarbonic acid sodium, potassium oleate and line borate are sequentially added in above-mentioned reactor, is placed at 50-70 DEG C and stirs
Mix reaction 25-40min；Vacuum distillation recycling ethyl alcohol；
(3) polypropylene is mixed with upper step gains, is placed at 155-170 DEG C and is stirred 30-50min, then passes through
Extruder squeezes out to get finished product.
As a further solution of the present invention：Step (1) uses mass fraction for the ethanol solution of 50-80%.
A kind of application of the High-impact Polypropylene that amion acetic acid is modified in electric power, chemical industry, field of medical technology.
Compared with prior art, the beneficial effects of the invention are as follows：
The High-impact Polypropylene that the amion acetic acid of the present invention is modified passes through polypropylene, amion acetic acid, trithiocarbonic acid
Sodium, potassium oleate, phenyl-phosphonic acid diethylester, hydroxy stearic acid ethylhexyl and line borate are prepared for primary raw material, play
Synergistic effect has higher shock resistance, toughness and rigid there has also been increasing substantially, and can preferably be used for electric power, change
In the technical fields such as work, medical treatment；Preparation process is simple, is conducive to promote.
Raising
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of High-impact Polypropylene that amion acetic acid is modified, the High-impact Polypropylene includes following parts by weight
Several components：90 parts of polypropylene, 15 parts of amion acetic acid, 10 parts of trithiocarbonic acid sodium, 5 parts of potassium oleate, phenyl-phosphonic acid diethylester 6
Part, 4 parts of hydroxy stearic acid ethylhexyl, 3 parts of line borate.
A kind of preparation method for the High-impact Polypropylene that amion acetic acid is modified, includes the following steps：(1) by amino second
Acid, phenyl-phosphonic acid diethylester and hydroxy stearic acid ethylhexyl are put into reactor and mix, and the second that mass fraction is 50% is added
80 parts of alcoholic solution is placed at 40 DEG C and is stirred to react 40min；(2) trithiocarbonic acid sodium, potassium oleate and line borate are sequentially added
It states in reactor, is placed at 50 DEG C and is stirred to react 25min；Vacuum distillation recycling ethyl alcohol；(3) polypropylene and upper step gains are mixed
It closes, is placed at 155 DEG C and is stirred 30min, then squeezed out to get finished product by extruder.
Embodiment 2
A kind of High-impact Polypropylene that amion acetic acid is modified, the High-impact Polypropylene includes following parts by weight
Several components：135 parts of polypropylene, 10 parts of amion acetic acid, 14 parts of trithiocarbonic acid sodium, 8 parts of potassium oleate, phenyl-phosphonic acid diethylester 15
Part, 9 parts of hydroxy stearic acid ethylhexyl, 8 parts of line borate.
A kind of preparation method for the High-impact Polypropylene that amion acetic acid is modified, includes the following steps：(1) by amino second
Acid, phenyl-phosphonic acid diethylester and hydroxy stearic acid ethylhexyl are put into reactor and mix, and the second that mass fraction is 80% is added
150 parts of alcoholic solution is placed at 65 DEG C and is stirred to react 60min；(2) trithiocarbonic acid sodium, potassium oleate and line borate are sequentially added
In above-mentioned reactor, it is placed at 70 DEG C and is stirred to react 40min；Vacuum distillation recycling ethyl alcohol；(3) by polypropylene and upper step gains
Mixing, is placed at 170 DEG C and is stirred 50min, is then squeezed out to get finished product by extruder.
Embodiment 3
A kind of High-impact Polypropylene that amion acetic acid is modified, the High-impact Polypropylene includes following parts by weight
Several components：115 parts of polypropylene, 13 parts of amion acetic acid, 12 parts of trithiocarbonic acid sodium, 7 parts of potassium oleate, phenyl-phosphonic acid diethylester 11
Part, 7 parts of hydroxy stearic acid ethylhexyl, 6 parts of line borate.
A kind of preparation method for the High-impact Polypropylene that amion acetic acid is modified, includes the following steps：(1) by amino second
Acid, phenyl-phosphonic acid diethylester and hydroxy stearic acid ethylhexyl are put into reactor and mix, and the second that mass fraction is 70% is added
120 parts of alcoholic solution is placed at 55 DEG C and is stirred to react 50min；(2) trithiocarbonic acid sodium, potassium oleate and line borate are sequentially added
In above-mentioned reactor, it is placed at 60 DEG C and is stirred to react 30min；Vacuum distillation recycling ethyl alcohol；(3) by polypropylene and upper step gains
Mixing, is placed at 160 DEG C and is stirred 40min, is then squeezed out to get finished product by extruder.
Embodiment 4
A kind of High-impact Polypropylene that amion acetic acid is modified, the High-impact Polypropylene includes following parts by weight
Several components：100 parts of polypropylene, 12 parts of amion acetic acid, 13 parts of trithiocarbonic acid sodium, 6 parts of potassium oleate, phenyl-phosphonic acid diethylester 8
Part, 5 parts of hydroxy stearic acid ethylhexyl, 4 parts of line borate.
A kind of preparation method for the High-impact Polypropylene that amion acetic acid is modified, includes the following steps：(1) by amino second
Acid, phenyl-phosphonic acid diethylester and hydroxy stearic acid ethylhexyl are put into reactor and mix, and the second that mass fraction is 55% is added
95 parts of alcoholic solution is placed at 50 DEG C and is stirred to react 45min；(2) trithiocarbonic acid sodium, potassium oleate and line borate are sequentially added
It states in reactor, is placed at 55 DEG C and is stirred to react 32min；Vacuum distillation recycling ethyl alcohol；(3) polypropylene and upper step gains are mixed
It closes, is placed at 165 DEG C and is stirred 35min, then squeezed out to get finished product by extruder.
Embodiment 5
A kind of High-impact Polypropylene that amion acetic acid is modified, the High-impact Polypropylene includes following parts by weight
Several components：125 parts of polypropylene, 14 parts of amion acetic acid, 11 parts of trithiocarbonic acid sodium, 8 parts of potassium oleate, phenyl-phosphonic acid diethylester 13
Part, 8 parts of hydroxy stearic acid ethylhexyl, 7 parts of line borate.
A kind of preparation method for the High-impact Polypropylene that amion acetic acid is modified, includes the following steps：(1) by amino second
Acid, phenyl-phosphonic acid diethylester and hydroxy stearic acid ethylhexyl are put into reactor and mix, and the second that mass fraction is 70% is added
140 parts of alcoholic solution is placed at 62 DEG C and is stirred to react 55min；(2) trithiocarbonic acid sodium, potassium oleate and line borate are sequentially added
In above-mentioned reactor, it is placed at 65 DEG C and is stirred to react 38min；Vacuum distillation recycling ethyl alcohol；(3) by polypropylene and upper step gains
Mixing, is placed at 165 DEG C and is stirred 45min, is then squeezed out to get finished product by extruder.
Comparative example 1
In addition to not containing amion acetic acid in raw material, preparation process is same as Example 5.
Comparative example 2
In addition to not containing trithiocarbonic acid sodium in raw material, preparation process is same as Example 5.
Comparative example 3
In addition to not containing phenyl-phosphonic acid diethylester in raw material, preparation process is same as Example 5.
Comparative example 4
In addition to not containing amion acetic acid, trithiocarbonic acid sodium and phenyl-phosphonic acid diethylester in raw material, preparation process and reality
It is identical to apply example 5.
Experimental example
Embodiment 1-5 and comparative example the 1-4 polypropylene material prepared are tested for the property, it is as a result as follows：
Table
| Project | Impact strength KJ/m2 | Tensile strength KJ/m2 | Bending strength KJ/m2 | MFR g/10min |
| Embodiment 1 | 89.3 | 34.6 | 49.6 | 6.4 |
| Embodiment 2 | 91.3 | 31.1 | 50.3 | 26.5 |
| Embodiment 3 | 85.9 | 35.4 | 51.4 | 10.3 |
| Embodiment 4 | 92.6 | 32.7 | 45.6 | 16.3 |
| Embodiment 5 | 90.4 | 30.6 | 47.9 | 8.6 |
| Comparative example 1 | 56.8 | 18.9 | 30.4 | 65.3 |
| Comparative example 2 | 70.1 | 23.5 | 33.5 | 51.3 |
| Comparative example 3 | 62.3 | 27.6 | 34.8 | 42.8 |
| Comparative example 4 | 35.6 | 11.7 | 22.5 | 112.5 |
The High-impact Polypropylene that the amion acetic acid of the present invention is modified passes through polypropylene, amion acetic acid, trithiocarbonic acid
Sodium, potassium oleate, phenyl-phosphonic acid diethylester, hydroxy stearic acid ethylhexyl and line borate are prepared for primary raw material, play
Synergistic effect has higher shock resistance, toughness and rigid there has also been increasing substantially, and can preferably be used for electric power, change
In the technical fields such as work, medical treatment；And preparation process is simple, is conducive to promote.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective
It makes a variety of changes.
Claims (6)
1. the High-impact Polypropylene that a kind of amion acetic acid is modified, which is characterized in that the High-impact Polypropylene includes
The component of following parts by weight：90-135 parts of polypropylene, 10-15 parts of amion acetic acid, 10-14 parts of trithiocarbonic acid sodium, potassium oleate
5-8 parts, 6-15 parts of phenyl-phosphonic acid diethylester, 4-9 parts of hydroxy stearic acid ethylhexyl, 3-8 parts of line borate.
2. the High-impact Polypropylene that amion acetic acid according to claim 1 is modified, which is characterized in that the high-impact
Polypropylene material includes the component of following parts by weight：100-125 parts of polypropylene, 12-14 parts of amion acetic acid, trithiocarbonic acid sodium
11-13 parts, 6-8 parts of potassium oleate, 8-13 parts of phenyl-phosphonic acid diethylester, 5-8 parts of hydroxy stearic acid ethylhexyl, 4-7 parts of line borate.
3. the High-impact Polypropylene that amion acetic acid according to claim 1 is modified, which is characterized in that the high-impact
Polypropylene material includes the component of following parts by weight：115 parts of polypropylene, 13 parts of amion acetic acid, 12 parts of trithiocarbonic acid sodium, oil
7 parts of sour potassium, 11 parts of phenyl-phosphonic acid diethylester, 7 parts of hydroxy stearic acid ethylhexyl, 6 parts of line borate.
4. a kind of preparation method for the High-impact Polypropylene that amion acetic acid as described in any one of claims 1-3 is modified,
It is characterized in that, includes the following steps：
（1）Amion acetic acid, phenyl-phosphonic acid diethylester and hydroxy stearic acid ethylhexyl are put into reactor and are mixed, ethyl alcohol is added
80-150 parts of solution is placed at 40-65 DEG C and is stirred to react 40-60min；
（2）Trithiocarbonic acid sodium, potassium oleate and line borate are sequentially added in above-mentioned reactor, is placed at 50-70 DEG C and stirs instead
Answer 25-40min；Vacuum distillation recycling ethyl alcohol；
（3）Polypropylene is mixed with upper step gains, is placed at 155-170 DEG C and is stirred 30-50min, then pass through extrusion
Machine squeezes out to get finished product.
5. the preparation method for the High-impact Polypropylene that amion acetic acid as claimed in claim 4 is modified, which is characterized in that step
Suddenly（1）Use mass fraction for the ethanol solution of 50-80%.
6. a kind of High-impact Polypropylene that amion acetic acid as described in any one of claims 1-3 is modified is in electric power, chemical industry, doctor
Treat the application in technical field.
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810280733.3A CN108410064A (en) | 2018-04-02 | 2018-04-02 | A kind of High-impact Polypropylene and preparation method and application of amion acetic acid modification |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201810280733.3A CN108410064A (en) | 2018-04-02 | 2018-04-02 | A kind of High-impact Polypropylene and preparation method and application of amion acetic acid modification |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768310A (en) * | 2009-12-28 | 2010-07-07 | 上海金发科技发展有限公司 | Beta-crystal polypropylene composition for inner container of water heater and preparation method thereof |
| CN101798423A (en) * | 2010-03-25 | 2010-08-11 | 从化市聚赛龙工程塑料有限公司 | Modified composite material with waste polypropylene plastic as raw material and preparation method thereof |
| US20130324646A1 (en) * | 2011-02-24 | 2013-12-05 | Rhodia (China) Co, Ltd | Flame retardant polymer compositions comprising stabilized hypophosphite salts |
-
2018
- 2018-04-02 CN CN201810280733.3A patent/CN108410064A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101768310A (en) * | 2009-12-28 | 2010-07-07 | 上海金发科技发展有限公司 | Beta-crystal polypropylene composition for inner container of water heater and preparation method thereof |
| CN101798423A (en) * | 2010-03-25 | 2010-08-11 | 从化市聚赛龙工程塑料有限公司 | Modified composite material with waste polypropylene plastic as raw material and preparation method thereof |
| US20130324646A1 (en) * | 2011-02-24 | 2013-12-05 | Rhodia (China) Co, Ltd | Flame retardant polymer compositions comprising stabilized hypophosphite salts |
Non-Patent Citations (3)
| Title |
|---|
| 吴世敏等主编: "《简明精细化工大辞典》", 30 June 1999, 辽宁科学技术出版社 * |
| 裘炳毅等编: "《现代化妆品科学与技术 中》", 31 March 2016, 中国轻工业出版社 * |
| 詹益兴主编: "《精细化工新产品（第1集）》", 30 June 2007, 科学技术文献出版社 * |
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Application publication date: 20180817 |