CN106675475A - Adhesive for automobile part processing - Google Patents
Adhesive for automobile part processing Download PDFInfo
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- CN106675475A CN106675475A CN201611066180.9A CN201611066180A CN106675475A CN 106675475 A CN106675475 A CN 106675475A CN 201611066180 A CN201611066180 A CN 201611066180A CN 106675475 A CN106675475 A CN 106675475A
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- parts
- oleum
- binding agent
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- phosphate
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J161/00—Adhesives based on condensation polymers of aldehydes or ketones; Adhesives based on derivatives of such polymers
- C09J161/20—Condensation polymers of aldehydes or ketones with only compounds containing hydrogen attached to nitrogen
- C09J161/32—Modified amine-aldehyde condensates
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/04—Non-macromolecular additives inorganic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/02—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group
- C08L2205/025—Polymer mixtures characterised by other features containing two or more polymers of the same C08L -group containing two or more polymers of the same hierarchy C08L, and differing only in parameters such as density, comonomer content, molecular weight, structure
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention relates to an adhesive for automobile part processing. The adhesive consists of the following components: methylated amino resin, polyvinyl acetate, isoprene rubber, chlorinated polyethylene, hydrogenated butadiene-acrylonitrile rubber, polypropylene glycol, rose essential oil, grape seed oil, linseed oil, camphorated oil, vancomycin, ketoconazole, aluminum phosphide, silthiopham, copper 8-hydroxyquinoline, disodium hydrogen phosphate, diethylene glycol dibenzoate, dibasic lead phosphate, nanometer titanium dioxide, sodium tetraborate, triphenyl phosphate, sodium stannate, ammonium polyphosphate, ethanol amine, N-methyl-2-pyrrolidone, coconut fatty acid, glyceryl monostearate, sodium citrate, tert-butylbenzoic acid and diethylene glycol butyl ether acetate. The raw materials have the synergistic effect, so the ageing resistance of the adhesive is greatly improved, the temperature adaptive range of the adhesive is increased and the temperature adaptive range is -80 to 250 DEG C.
Description
Technical field
The present invention relates to a kind of auto parts processed binding agent, belongs to auto parts processing technique field.
Background technology
In auto parts process of manufacture, it is sometimes necessary to glued different parts using suitable binding agent
Knot, to improve its bonding using effect, is easy to use as needed.General Binder Properties are poor, particularly cannot expire
Sufficient high temperature or cryogenic property, cause to cause performance not good during use, so as to affect to use auto parts processing bonding effect
Really, subsequent treatment function is affected.
The content of the invention
It is an object of the invention to provide a kind of auto parts processed binding agent, so that automobile zero is better achieved
The use function of part processed binding agent, makes product have preferable adhesive property, improves product performance.
To achieve these goals, technical scheme is as follows.
A kind of auto parts processed binding agent, is made up of the component of following mass fraction：Amino resin
28~32 parts, 26~30 parts of polyvinyl acetate, 26~30 parts of isoprene rubber, 24~28 parts of chlorinated polyethylene, hydrogenated butyronitrile rubber
26~30 parts of glue, 26~30 parts of glycol polypropylene, 24~28 parts of rose ethereal oil, 26~30 parts of Oleum Vitis viniferae, oleum lini 26
~30 parts, 24~28 parts of Oleum Camphora, 24~28 parts of vancomycin, 24~28 parts of Ketoconazole, 26~30 parts of aluminum phosphate, Silthiopham
24~28 parts, 22~26 parts of copper 8-quinolinolate, 26~30 parts of disodium hydrogen phosphate, 24~28 parts of diethylene glycol dibenzoate, two
22~26 parts of alkali formula lead phosphite, 24~28 parts of nanometer titanium dioxide, 22~26 parts of sodium tetraborate, 22~26 parts of triphenyl phosphate,
22~26 parts of sodium stannate, 20~24 parts of ammonium polyphosphate, 16~20 parts of ethanolamine, 14~18 parts of METHYLPYRROLIDONE, coconut palm
14~18 parts of seed oil acid, 14~18 parts of glyceryl monostearate, 14~18 parts of sodium citrate, p-tert-butyl benzoic acid 14~18
Part, 14~18 parts of butyl acetate.
Further, above-mentioned auto parts processed binding agent, is made up of the component of following mass fraction：Methyl-etherified
It is 28 parts of amino resins, 26 parts of polyvinyl acetate, 26 parts of isoprene rubber, 24 parts of chlorinated polyethylene, 26 parts of hydrogenated nitrile-butadiene rubber, poly-
26 parts of propyleneglycoles, 24 parts of rose ethereal oil, 26 parts of Oleum Vitis viniferae, 26 parts of oleum lini, 24 parts of Oleum Camphora, vancomycin 24
Part, 24 parts of Ketoconazole, 26 parts of aluminum phosphate, 24 parts of Silthiopham, 22 parts of copper 8-quinolinolate, 26 parts of disodium hydrogen phosphate, diethylene glycol
24 parts of dibenzoate, 22 parts of dibasic lead phosphite, 24 parts of nanometer titanium dioxide, 22 parts of sodium tetraborate, 22 parts of triphenyl phosphate,
22 parts of sodium stannate, 20 parts of ammonium polyphosphate, 16 parts of ethanolamine, 14 parts of METHYLPYRROLIDONE, 14 parts of cocinic acid, glycerol
14 parts of monostearate, 14 parts of sodium citrate, 14 parts of p-tert-butyl benzoic acid, 14 parts of butyl acetate.
Further, above-mentioned auto parts processed binding agent, is made up of the component of following mass fraction：Methyl-etherified
It is 30 parts of amino resins, 28 parts of polyvinyl acetate, 28 parts of isoprene rubber, 26 parts of chlorinated polyethylene, 28 parts of hydrogenated nitrile-butadiene rubber, poly-
28 parts of propyleneglycoles, 26 parts of rose ethereal oil, 28 parts of Oleum Vitis viniferae, 28 parts of oleum lini, 26 parts of Oleum Camphora, vancomycin 26
Part, 26 parts of Ketoconazole, 28 parts of aluminum phosphate, 26 parts of Silthiopham, 24 parts of copper 8-quinolinolate, 28 parts of disodium hydrogen phosphate, diethylene glycol
26 parts of dibenzoate, 24 parts of dibasic lead phosphite, 26 parts of nanometer titanium dioxide, 24 parts of sodium tetraborate, 24 parts of triphenyl phosphate,
24 parts of sodium stannate, 22 parts of ammonium polyphosphate, 18 parts of ethanolamine, 16 parts of METHYLPYRROLIDONE, 16 parts of cocinic acid, glycerol
16 parts of monostearate, 16 parts of sodium citrate, 16 parts of p-tert-butyl benzoic acid, 16 parts of butyl acetate.
Further, above-mentioned auto parts processed binding agent, is made up of the component of following mass fraction：Methyl-etherified
It is 32 parts of amino resins, 30 parts of polyvinyl acetate, 30 parts of isoprene rubber, 28 parts of chlorinated polyethylene, 30 parts of hydrogenated nitrile-butadiene rubber, poly-
30 parts of propyleneglycoles, 28 parts of rose ethereal oil, 30 parts of Oleum Vitis viniferae, 30 parts of oleum lini, 28 parts of Oleum Camphora, vancomycin 28
Part, 28 parts of Ketoconazole, 30 parts of aluminum phosphate, 28 parts of Silthiopham, 26 parts of copper 8-quinolinolate, 30 parts of disodium hydrogen phosphate, diethylene glycol
28 parts of dibenzoate, 26 parts of dibasic lead phosphite, 28 parts of nanometer titanium dioxide, 26 parts of sodium tetraborate, 26 parts of triphenyl phosphate,
26 parts of sodium stannate, 24 parts of ammonium polyphosphate, 20 parts of ethanolamine, 18 parts of METHYLPYRROLIDONE, 18 parts of cocinic acid, glycerol
18 parts of monostearate, 18 parts of sodium citrate, 18 parts of p-tert-butyl benzoic acid, 18 parts of butyl acetate.
Further, above-mentioned auto parts processed is as follows with binding agent preparation method step：
(1) by the Amino resin of the mass fraction, polyvinyl acetate, isoprene rubber, chlorinated polyethylene, hydrogen
Change nitrile rubber, glycol polypropylene, rose ethereal oil, Oleum Vitis viniferae, oleum lini, Oleum Camphora, vancomycin, Ketoconazole, phosphorus
Change aluminum, Silthiopham, copper 8-quinolinolate, disodium hydrogen phosphate, diethylene glycol dibenzoate, dibasic lead phosphite, nano-titanium
White lead, sodium tetraborate are mixed, and ultrasound is disperseed at a high speed, and ultrasonic frequency is 20~40KHz, 5000~5400r/ of rate of dispersion
Min or so, jitter time is 30~60min；
(2) triphenyl phosphate, sodium stannate, ammonium polyphosphate, ethanolamine, the N- methyl -2- pyrroles of the mass fraction are added
Pyrrolidone, ultrasound is disperseed at a high speed, and ultrasonic frequency is 20~35KHz, 4800~5200r/min of rate of dispersion or so, during dispersion
Between be 30~50min；
(3) add the cocinic acid of the mass fraction, glyceryl monostearate, sodium citrate, p-tert-butyl benzoic acid,
Butyl acetate, ultrasound is disperseed at a high speed, and ultrasonic frequency is 20~30KHz, 4600~4800r/min of rate of dispersion
Left and right, jitter time is 20~40min；This product is obtained after mix homogeneously.
The beneficial effect of the invention is：Auto parts processed binding agent in the present invention, by following components group
Into：Amino resin, polyvinyl acetate, isoprene rubber, chlorinated polyethylene, hydrogenated nitrile-butadiene rubber, glycol polypropylene,
Rose ethereal oil, Oleum Vitis viniferae, oleum lini, Oleum Camphora, vancomycin, Ketoconazole, aluminum phosphate, Silthiopham, 8-hydroxyquinoline
Copper, disodium hydrogen phosphate, diethylene glycol dibenzoate, dibasic lead phosphite, nanometer titanium dioxide, sodium tetraborate, triphenyl phosphate,
Sodium stannate, ammonium polyphosphate, ethanolamine, METHYLPYRROLIDONE, cocinic acid, glyceryl monostearate, sodium citrate,
P-tert-butyl benzoic acid, butyl acetate.Product of the present invention is made between each component by rational proportioning and mixing
Synergism is produced, deficiency when being each used alone is overcome, is defined with excellent high temperature resistant, anticorrosive, high bonding
The cross-linked structure of the performances such as property, mechanicalness.The room temperature down cut intensity that the present invention is provided can reach more than 45MPa, when 250 DEG C
Shear strength be more than 18MPa, disclosure satisfy that the requirement of glued part long-term work at 250 DEG C.It is of the present invention
Raw material produces synergism, the ageing resistace for greatly improving binding agent, the temperature adaptation scope for improving binding agent, its temperature
Degree subject range is -80~250 DEG C；The product has preferable anti-mildew anti-microbial property.
Specific embodiment
The specific embodiment of the present invention is described with reference to embodiment, to be better understood from the present invention.
Embodiment 1
Auto parts processed binding agent in the present embodiment, is made up of the component of following mass fraction：Methyl-etherified
It is 28 parts of amino resins, 26 parts of polyvinyl acetate, 26 parts of isoprene rubber, 24 parts of chlorinated polyethylene, 26 parts of hydrogenated nitrile-butadiene rubber, poly-
26 parts of propyleneglycoles, 24 parts of rose ethereal oil, 26 parts of Oleum Vitis viniferae, 26 parts of oleum lini, 24 parts of Oleum Camphora, vancomycin 24
Part, 24 parts of Ketoconazole, 26 parts of aluminum phosphate, 24 parts of Silthiopham, 22 parts of copper 8-quinolinolate, 26 parts of disodium hydrogen phosphate, diethylene glycol
24 parts of dibenzoate, 22 parts of dibasic lead phosphite, 24 parts of nanometer titanium dioxide, 22 parts of sodium tetraborate, 22 parts of triphenyl phosphate,
22 parts of sodium stannate, 20 parts of ammonium polyphosphate, 16 parts of ethanolamine, 14 parts of METHYLPYRROLIDONE, 14 parts of cocinic acid, glycerol
14 parts of monostearate, 14 parts of sodium citrate, 14 parts of p-tert-butyl benzoic acid, 14 parts of butyl acetate.
Above-mentioned auto parts processed is as follows with binding agent preparation method step：
(1) by the Amino resin of the mass fraction, polyvinyl acetate, isoprene rubber, chlorinated polyethylene, hydrogen
Change nitrile rubber, glycol polypropylene, rose ethereal oil, Oleum Vitis viniferae, oleum lini, Oleum Camphora, vancomycin, Ketoconazole, phosphorus
Change aluminum, Silthiopham, copper 8-quinolinolate, disodium hydrogen phosphate, diethylene glycol dibenzoate, dibasic lead phosphite, nano-titanium
White lead, sodium tetraborate are mixed, and ultrasound is disperseed at a high speed, and ultrasonic frequency is 20kHz, rate of dispersion 5400r/min or so, point
The scattered time is 60min；
(2) triphenyl phosphate, sodium stannate, ammonium polyphosphate, ethanolamine, the N- methyl -2- pyrroles of the mass fraction are added
Pyrrolidone, ultrasound is disperseed at a high speed, and ultrasonic frequency is 20kHz, rate of dispersion 5200r/min or so, and jitter time is 50min；
(3) add the cocinic acid of the mass fraction, glyceryl monostearate, sodium citrate, p-tert-butyl benzoic acid,
Butyl acetate, ultrasound is disperseed at a high speed, and ultrasonic frequency is 20kHz, rate of dispersion 4800r/min or so, dispersion
Time is 40min；This product is obtained after mix homogeneously.
Embodiment 2
Auto parts processed binding agent in the present embodiment, is made up of the component of following mass fraction：Methyl-etherified
It is 30 parts of amino resins, 28 parts of polyvinyl acetate, 28 parts of isoprene rubber, 26 parts of chlorinated polyethylene, 28 parts of hydrogenated nitrile-butadiene rubber, poly-
28 parts of propyleneglycoles, 26 parts of rose ethereal oil, 28 parts of Oleum Vitis viniferae, 28 parts of oleum lini, 26 parts of Oleum Camphora, vancomycin 26
Part, 26 parts of Ketoconazole, 28 parts of aluminum phosphate, 26 parts of Silthiopham, 24 parts of copper 8-quinolinolate, 28 parts of disodium hydrogen phosphate, diethylene glycol
26 parts of dibenzoate, 24 parts of dibasic lead phosphite, 26 parts of nanometer titanium dioxide, 24 parts of sodium tetraborate, 24 parts of triphenyl phosphate,
24 parts of sodium stannate, 22 parts of ammonium polyphosphate, 18 parts of ethanolamine, 16 parts of METHYLPYRROLIDONE, 16 parts of cocinic acid, glycerol
16 parts of monostearate, 16 parts of sodium citrate, 16 parts of p-tert-butyl benzoic acid, 16 parts of butyl acetate.
Above-mentioned auto parts processed is as follows with binding agent preparation method step：
(1) by the Amino resin of the mass fraction, polyvinyl acetate, isoprene rubber, chlorinated polyethylene, hydrogen
Change nitrile rubber, glycol polypropylene, rose ethereal oil, Oleum Vitis viniferae, oleum lini, Oleum Camphora, vancomycin, Ketoconazole, phosphorus
Change aluminum, Silthiopham, copper 8-quinolinolate, disodium hydrogen phosphate, diethylene glycol dibenzoate, dibasic lead phosphite, nano-titanium
White lead, sodium tetraborate are mixed, and ultrasound is disperseed at a high speed, and ultrasonic frequency is 30kHz, rate of dispersion 5200r/min or so, point
The scattered time is 45min；
(2) triphenyl phosphate, sodium stannate, ammonium polyphosphate, ethanolamine, the N- methyl -2- pyrroles of the mass fraction are added
Pyrrolidone, ultrasound is disperseed at a high speed, and ultrasonic frequency is 27kHz, rate of dispersion 5000r/min or so, and jitter time is 40min；
(3) add the cocinic acid of the mass fraction, glyceryl monostearate, sodium citrate, p-tert-butyl benzoic acid,
Butyl acetate, ultrasound is disperseed at a high speed, and ultrasonic frequency is 25kHz, rate of dispersion 4700r/min or so, dispersion
Time is 30min；This product is obtained after mix homogeneously.
Embodiment 3
Auto parts processed binding agent in the present embodiment, is made up of the component of following mass fraction：Methyl-etherified
It is 32 parts of amino resins, 30 parts of polyvinyl acetate, 30 parts of isoprene rubber, 28 parts of chlorinated polyethylene, 30 parts of hydrogenated nitrile-butadiene rubber, poly-
30 parts of propyleneglycoles, 28 parts of rose ethereal oil, 30 parts of Oleum Vitis viniferae, 30 parts of oleum lini, 28 parts of Oleum Camphora, vancomycin 28
Part, 28 parts of Ketoconazole, 30 parts of aluminum phosphate, 28 parts of Silthiopham, 26 parts of copper 8-quinolinolate, 30 parts of disodium hydrogen phosphate, diethylene glycol
28 parts of dibenzoate, 26 parts of dibasic lead phosphite, 28 parts of nanometer titanium dioxide, 26 parts of sodium tetraborate, 26 parts of triphenyl phosphate,
26 parts of sodium stannate, 24 parts of ammonium polyphosphate, 20 parts of ethanolamine, 18 parts of METHYLPYRROLIDONE, 18 parts of cocinic acid, glycerol
18 parts of monostearate, 18 parts of sodium citrate, 18 parts of p-tert-butyl benzoic acid, 18 parts of butyl acetate.
Above-mentioned auto parts processed is as follows with binding agent preparation method step：
(1) by the Amino resin of the mass fraction, polyvinyl acetate, isoprene rubber, chlorinated polyethylene, hydrogen
Change nitrile rubber, glycol polypropylene, rose ethereal oil, Oleum Vitis viniferae, oleum lini, Oleum Camphora, vancomycin, Ketoconazole, phosphorus
Change aluminum, Silthiopham, copper 8-quinolinolate, disodium hydrogen phosphate, diethylene glycol dibenzoate, dibasic lead phosphite, nano-titanium
White lead, sodium tetraborate are mixed, and ultrasound is disperseed at a high speed, and ultrasonic frequency is 40kHz, rate of dispersion 5000r/min, during dispersion
Between be 30min；
(2) triphenyl phosphate, sodium stannate, ammonium polyphosphate, ethanolamine, the N- methyl -2- pyrroles of the mass fraction are added
Pyrrolidone, ultrasound is disperseed at a high speed, and ultrasonic frequency is 35kHz, and rate of dispersion 4800r/min, jitter time is 30min；
(3) add the cocinic acid of the mass fraction, glyceryl monostearate, sodium citrate, p-tert-butyl benzoic acid,
Butyl acetate, ultrasound is disperseed at a high speed, and ultrasonic frequency is 30kHz, rate of dispersion 4600r/min or so, dispersion
Time is 20min；This product is obtained after mix homogeneously.
Comparative example 1
1) 25 parts of the thermoplastic acrylic resin that weight average molecular weight is 70000~75000 is weighed respectively, organic-silicon-modified third
20 parts of olefin(e) acid resin, in sequentially adding agitator tank, with the speed of 100rpm 40 minutes is sufficiently stirred for；
B) 10 parts of melmac is continuously added, 7 parts of phenyl trichlorosilane, 5 parts of vinyltrimethoxy silane, with
The speed of 100rpm is sufficiently stirred for 60 minutes；
C) 7 parts of titanium dioxide, 5 parts of attapulgite, 5 parts of dichlorotetra-fluoroethane, second are continuously added in the mixture of step b)
20 parts of glycol monobutyl ether, is sufficiently stirred for 60 minutes with the speed of 100rpm, obtains the binder product in this comparative example.
Comparative example 2
1) 25 parts of epoxy modified hydroxyl acrylic resin is weighed respectively, and weight average molecular weight is 70000~75000 thermoplasticity
25 parts of acrylic resin, in sequentially adding agitator tank, with the speed of 100rpm 40 minutes is sufficiently stirred for；
2) 10 parts of melmac is continuously added, 7 parts of phenyl trichlorosilane, 5 parts of vinyltrimethoxy silane, with
The speed of 100rpm is sufficiently stirred for 60 minutes；
3) 7 parts of titanium dioxide, 5 parts of attapulgite, 5 parts of dichlorotetra-fluoroethane, second are continuously added in the mixture of step b)
20 parts of glycol monobutyl ether, is sufficiently stirred for 60 minutes with the speed of 100rpm, obtains binder product.
By the binding agent prepared by embodiment 1, embodiment 2, embodiment 3 and comparative example 1, comparative example 2 at -80~280 DEG C
Lower to test respective shear strength and tolerance time, the testing time is 360 days, and concrete outcome is as shown in following table 1-5：
Binder Properties test result at 1-80 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | Not fragmentation in 50 days, does not fall off | 15MPa |
| Embodiment 2 | Not fragmentation in 52 days, does not fall off | 18MPa |
| Embodiment 3 | Not fragmentation in 48 days, does not fall off | 16MPa |
| Comparative example 1 | 0 day, binding agent fragmentation came off | 0 |
| Comparative example 2 | 0 day, binding agent fragmentation came off | 0 |
Binder Properties test result at 20 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | Not fragmentation in 50 days, does not fall off | 25MPa |
| Embodiment 2 | Not fragmentation in 52 days, does not fall off | 28MPa |
| Embodiment 3 | Not fragmentation in 48 days, does not fall off | 26MPa |
| Comparative example 1 | Binding agent fragmentation after 30 days comes off | 10MPa |
| Comparative example 2 | Binding agent fragmentation after 20 days comes off | 8MPa |
Binder Properties test result at 3 20 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | Not fragmentation in 360 days, does not fall off | 45MPa |
| Embodiment 2 | Not fragmentation in 360 days, does not fall off | 48MPa |
| Embodiment 3 | Not fragmentation in 360 days, does not fall off | 47MPa |
| Comparative example 1 | Not fragmentation in 360 days, does not fall off | 18MPa |
| Comparative example 2 | Not fragmentation in 360 days, does not fall off | 16MPa |
Binder Properties test result at 4 150 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | 360 days not softening and sheddings | 22MPa |
| Embodiment 2 | 360 days not softening and sheddings | 24MPa |
| Embodiment 3 | 360 days not softening and sheddings | 23MPa |
| Comparative example 1 | Binding agent softens after 10 days | 10MPa |
| Comparative example 2 | Binding agent softens after 10 days | 8MPa |
Binder Properties test result at 5 250 DEG C of table
| Group | Tolerance time | Shear strength |
| Embodiment 1 | 280 days not softening and sheddings | 18MPa |
| Embodiment 2 | 280 days not softening and sheddings | 19MPa |
| Embodiment 3 | 280 days not softening and sheddings | 18MPa |
| Comparative example 1 | Binding agent softens after 3 days | 4MPa |
| Comparative example 2 | Binding agent softens after 3 days | 3MPa |
The above is the preferred embodiment of the present invention, it is noted that for those skilled in the art
For, under the premise without departing from the principles of the invention, some improvements and modifications can also be made, these improvements and modifications are also considered as
Protection scope of the present invention.
Claims (5)
1. a kind of auto parts processed binding agent, it is characterised in that：It is made up of the component of following mass fraction：Methyl-etherified
28~32 parts of amino resins, 26~30 parts of polyvinyl acetate, 26~30 parts of isoprene rubber, 24~28 parts of chlorinated polyethylene, hydrogen
Change 26~30 parts of nitrile rubber, 26~30 parts of glycol polypropylene, 24~28 parts of rose ethereal oil, 26~30 parts of Oleum Vitis viniferae,
26~30 parts of oleum lini, 24~28 parts of Oleum Camphora, 24~28 parts of vancomycin, 24~28 parts of Ketoconazole, 26~30 parts of aluminum phosphate,
24~28 parts of Silthiopham, 22~26 parts of copper 8-quinolinolate, 26~30 parts of disodium hydrogen phosphate, diethylene glycol dibenzoate 24~
28 parts, 22~26 parts of dibasic lead phosphite, 24~28 parts of nanometer titanium dioxide, 22~26 parts of sodium tetraborate, triphenyl phosphate 22
~26 parts, 22~26 parts of sodium stannate, 20~24 parts of ammonium polyphosphate, 16~20 parts of ethanolamine, METHYLPYRROLIDONE 14~
18 parts, 14~18 parts of cocinic acid, 14~18 parts of glyceryl monostearate, 14~18 parts of sodium citrate, p-tert-butyl benzoic acid
14~18 parts, 14~18 parts of butyl acetate.
2. auto parts processed binding agent according to claim 1, it is characterised in that：The auto parts processing
Process binding agent is made up of the component of following mass fraction：28 parts of Amino resin, 26 parts of polyvinyl acetate, isoamyl
26 parts of rubber, 24 parts of chlorinated polyethylene, 26 parts of hydrogenated nitrile-butadiene rubber, 26 parts of glycol polypropylene, 24 parts of rose ethereal oil, Fructus Vitis viniferae
26 parts of seed oil, 26 parts of oleum lini, 24 parts of Oleum Camphora, 24 parts of vancomycin, 24 parts of Ketoconazole, 26 parts of aluminum phosphate, Silthiopham 24
Part, 22 parts of copper 8-quinolinolate, 26 parts of disodium hydrogen phosphate, 24 parts of diethylene glycol dibenzoate, 22 parts of dibasic lead phosphite, receive
24 parts of titanium dioxide of rice, 22 parts of sodium tetraborate, 22 parts of triphenyl phosphate, 22 parts of sodium stannate, 20 parts of ammonium polyphosphate, ethanolamine 16
Part, 14 parts of METHYLPYRROLIDONE, 14 parts of cocinic acid, 14 parts of glyceryl monostearate, 14 parts of sodium citrate, to tertiary fourth
14 parts of yl benzoic acid, 14 parts of butyl acetate.
3. the auto parts processed binding agent according to claim 1 to 2, it is characterised in that：The auto parts
Processed binding agent is made up of the component of following mass fraction：30 parts of Amino resin, 28 parts of polyvinyl acetate,
28 parts of isoprene rubber, 26 parts of chlorinated polyethylene, 28 parts of hydrogenated nitrile-butadiene rubber, 28 parts of glycol polypropylene, 26 parts of rose ethereal oil,
28 parts of Oleum Vitis viniferae, 28 parts of oleum lini, 26 parts of Oleum Camphora, 26 parts of vancomycin, 26 parts of Ketoconazole, 28 parts of aluminum phosphate, silicon thiophene bacterium
26 parts of amine, 24 parts of copper 8-quinolinolate, 28 parts of disodium hydrogen phosphate, 26 parts of diethylene glycol dibenzoate, dibasic lead phosphite 24
Part, 26 parts of nanometer titanium dioxide, 24 parts of sodium tetraborate, 24 parts of triphenyl phosphate, 24 parts of sodium stannate, 22 parts of ammonium polyphosphate, ethanol
It is 18 parts of amine, 16 parts of METHYLPYRROLIDONE, 16 parts of cocinic acid, 16 parts of glyceryl monostearate, 16 parts of sodium citrate, right
16 parts of p t butylbenzoic acid, 16 parts of butyl acetate.
4. the auto parts processed binding agent according to claims 1 to 3, it is characterised in that：The auto parts
Processed binding agent is made up of the component of following mass fraction：32 parts of Amino resin, 30 parts of polyvinyl acetate,
30 parts of isoprene rubber, 28 parts of chlorinated polyethylene, 30 parts of hydrogenated nitrile-butadiene rubber, 30 parts of glycol polypropylene, 28 parts of rose ethereal oil,
30 parts of Oleum Vitis viniferae, 30 parts of oleum lini, 28 parts of Oleum Camphora, 28 parts of vancomycin, 28 parts of Ketoconazole, 30 parts of aluminum phosphate, silicon thiophene bacterium
28 parts of amine, 26 parts of copper 8-quinolinolate, 30 parts of disodium hydrogen phosphate, 28 parts of diethylene glycol dibenzoate, dibasic lead phosphite 26
Part, 28 parts of nanometer titanium dioxide, 26 parts of sodium tetraborate, 26 parts of triphenyl phosphate, 26 parts of sodium stannate, 24 parts of ammonium polyphosphate, ethanol
It is 20 parts of amine, 18 parts of METHYLPYRROLIDONE, 18 parts of cocinic acid, 18 parts of glyceryl monostearate, 18 parts of sodium citrate, right
18 parts of p t butylbenzoic acid, 18 parts of butyl acetate.
5. auto parts processed binding agent according to claim 1, it is characterised in that：The auto parts processing
Process as follows with binding agent preparation method step：
(1) by the Amino resin of the mass fraction, polyvinyl acetate, isoprene rubber, chlorinated polyethylene, hydrogenation fourth
Nitrile rubber, glycol polypropylene, rose ethereal oil, Oleum Vitis viniferae, oleum lini, Oleum Camphora, vancomycin, Ketoconazole, aluminum phosphate,
Silthiopham, copper 8-quinolinolate, disodium hydrogen phosphate, diethylene glycol dibenzoate, dibasic lead phosphite, nanometer titanium dioxide,
Sodium tetraborate is mixed, and ultrasound is disperseed at a high speed, and ultrasonic frequency is 20~40KHz, rate of dispersion about 5000~5400r/
Min, jitter time is 30~60min or so；
(2) triphenyl phosphate, sodium stannate, ammonium polyphosphate, ethanolamine, the N- methyl -2- pyrrolidines of the mass fraction are added
Ketone, ultrasound is disperseed at a high speed, and ultrasonic frequency is 20~35KHz, and rate of dispersion is for about 4800~5200r/min, and jitter time is
30~50min or so；
(3) cocinic acid, glyceryl monostearate, sodium citrate, p-tert-butyl benzoic acid, the diethyl of the mass fraction are added
Glycol monobutyl ether acetate, ultrasound is disperseed at a high speed, and ultrasonic frequency is 20~30KHz, and rate of dispersion is for about 4600~4800r/
Min, jitter time is 20~40min or so；This product is obtained after mix homogeneously.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611066180.9A CN106675475A (en) | 2016-11-28 | 2016-11-28 | Adhesive for automobile part processing |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611066180.9A CN106675475A (en) | 2016-11-28 | 2016-11-28 | Adhesive for automobile part processing |
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| Publication Number | Publication Date |
|---|---|
| CN106675475A true CN106675475A (en) | 2017-05-17 |
Family
ID=58866172
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611066180.9A Pending CN106675475A (en) | 2016-11-28 | 2016-11-28 | Adhesive for automobile part processing |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286904A (en) * | 2017-07-25 | 2017-10-24 | 安徽瑞泰汽车零部件有限责任公司 | A kind of auto parts adhesive |
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| Publication number | Priority date | Publication date | Assignee | Title |
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| CN103952112A (en) * | 2014-05-11 | 2014-07-30 | 马鞍山博诺环保科技有限公司 | High-performance PE adhesive for lid and preparation method of PE adhesive |
| CN104059570A (en) * | 2014-06-26 | 2014-09-24 | 中材高新成都能源技术有限公司 | Novel adhesive |
| CN105860871A (en) * | 2016-06-20 | 2016-08-17 | 王璐 | LED (light-emitting diode) display screen adhesive |
| CN106065302A (en) * | 2016-05-31 | 2016-11-02 | 王璐 | A kind of compunication power distribution cabinet installation fluid sealant |
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Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103952112A (en) * | 2014-05-11 | 2014-07-30 | 马鞍山博诺环保科技有限公司 | High-performance PE adhesive for lid and preparation method of PE adhesive |
| CN104059570A (en) * | 2014-06-26 | 2014-09-24 | 中材高新成都能源技术有限公司 | Novel adhesive |
| CN106065302A (en) * | 2016-05-31 | 2016-11-02 | 王璐 | A kind of compunication power distribution cabinet installation fluid sealant |
| CN105860871A (en) * | 2016-06-20 | 2016-08-17 | 王璐 | LED (light-emitting diode) display screen adhesive |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107286904A (en) * | 2017-07-25 | 2017-10-24 | 安徽瑞泰汽车零部件有限责任公司 | A kind of auto parts adhesive |
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