CN108402074A - A kind of composition pesticide containing chloramine phos and ring tebufenozide - Google Patents
A kind of composition pesticide containing chloramine phos and ring tebufenozide Download PDFInfo
- Publication number
- CN108402074A CN108402074A CN201810464486.2A CN201810464486A CN108402074A CN 108402074 A CN108402074 A CN 108402074A CN 201810464486 A CN201810464486 A CN 201810464486A CN 108402074 A CN108402074 A CN 108402074A
- Authority
- CN
- China
- Prior art keywords
- ring tebufenozide
- chloramine phos
- composition pesticide
- phos
- chloramine
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N57/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds
- A01N57/26—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds
- A01N57/28—Biocides, pest repellants or attractants, or plant growth regulators containing organic phosphorus compounds having phosphorus-to-nitrogen bonds containing acyclic or cycloaliphatic radicals
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N25/00—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests
- A01N25/02—Biocides, pest repellants or attractants, or plant growth regulators, characterised by their forms, or by their non-active ingredients or by their methods of application, e.g. seed treatment or sequential application; Substances for reducing the noxious effect of the active ingredients to organisms other than pests containing liquids as carriers, diluents or solvents
- A01N25/04—Dispersions, emulsions, suspoemulsions, suspension concentrates or gels
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N43/00—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds
- A01N43/02—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms
- A01N43/04—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom
- A01N43/14—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings
- A01N43/16—Biocides, pest repellants or attractants, or plant growth regulators containing heterocyclic compounds having rings with one or more oxygen or sulfur atoms as the only ring hetero atoms with one hetero atom six-membered rings with oxygen as the ring hetero atom
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Health & Medical Sciences (AREA)
- General Health & Medical Sciences (AREA)
- Dentistry (AREA)
- Plant Pathology (AREA)
- Engineering & Computer Science (AREA)
- Pest Control & Pesticides (AREA)
- Agronomy & Crop Science (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Chemical & Material Sciences (AREA)
- Dispersion Chemistry (AREA)
- Toxicology (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a kind of composition pesticide containing chloramine phos and ring tebufenozide, the composition pesticide contain active constituent chloramine phos and ring tebufenozide, and the mass fraction ratio of chloramine phos and ring tebufenozide is 7:1~1:1, it is preferably in a proportion of 4:1~1:2, chloramine phos and ring tebufenozide have synergistic effect to the toxicity of bollworm in the proportional region, chloramine phos and ring tebufenozide can be processed into pesticidal preparations, the percentage that chloramine phos and ring tebufenozide quality summation account for pesticidal preparations gross mass is 0.1%~40%, remaining is insecticides adjuvant, and the composition can be used for preventing cotton boll worm, paddy rice rice leaf roller.
Description
Technical field
The invention belongs to synergetic pesticide composition field, the specific one kind that provides contains active constituent chloramine phos and ring tebufenozide
Synergetic pesticide composition.
Background technology
Chloramine phos (chloramine phosphate) are a kind of medium poison of China's independent intellectual property right, broad spectrum organic phosphorus
Insecticide, chemical name：O, S- dimethyl (2,2,2- trichloro-1-hydroxy-ethyl) thio-phosphamide inhibits insect bodies
Interior acetylcholinesterase has stomach toxicity to pest, tags, fumigates and certain systemic action, to biting mouthparts and piercing and sucking
Formula mouthpart insect has control action.
Ring tebufenozide (hromafenozide), chemical name：2'- tertiary butyl -5- methyl -2'- (3,5- dimethyl benzene first
Acyl group) chroman -6- formylhydrazines, bishydrazide insecticide inhibits feed after pests, while pest being caused to shift to an earlier date in a few houres
Husking leads to death.Ring tebufenozide is not only less toxic to mammal, birds, aquatic organism, but also to arthropod class, predatism tick
Mite, spider, Semiptera, coleoptera (beetle), parasite and environment are without influence.Therefore, it is that comprehensive evil object administers system
In an ideal medicament.Ring tebufenozide inhibits insect to feed after insect absorbs while insect being caused to shift to an earlier date within a few hours
Husking causes dead.It causes the mistake of insect by the molting process of adjusting young hormone and moulting hormone moving obstacle insect
Early husking is dead.Because it can quickly inhibit the feed of insect, for other common 1GR, can reduce to crop
Harm.To noctuid and other caterpillars, no matter in which, ring tebufenozide has very strong insecticidal activity in period.
Bollworm (Helicoverpa armigera Hubner), Lepidoptera, Noctuidae belongs to one kind of insect, is cotton
The major pest of cotton buds and bolls phase.Be widely distributed in China and all over the world, Chinese cotton region and vegetables flake have generation.Yellow River basin
Cotton region, Yangtze river basin cotton region are aggrieved heavier.In recent years, Xinjiang cotton also happens occasionally.Host plant has section more than 20 more than 200 to plant.
Bollworm is cotton cotton buds and bolls phase important borer pest, main moth food flower bud, flower, bell, also feeding tender leaf.The worm is Chinese cotton region flower bud
The sociales of bell phase pest are caused harm very rampant in recent years.
Rice leaf roller is a kind of migratory pest, is distributed widely in each rice region.In addition to rice of causing harm, can also feeding it is big
The crops such as wheat, wheat, sugarcane, grain and barnyard grass, Leersia Sw, ditch millet, Paspalum distichum, lady's-grass, green bristlegrass, yard grass, cogongrass, reed etc.
Weeds.Caused harm rice with larva, sews leaf into vertical bud, hide wherein feeding epicuticle and mesophyll are only left white color lower epidermis.Seedling stage by
Evil influences rice normal growth or even withered；Tillering stage to the jointing stage is aggrieved, and tiller is reduced, and plant shortens, and breeding time postpones；
Especially heading is killed to full heading time sword-like leave after booting, influences to blossom and bear fruit, and Empty grain rate improves, and mass of 1000 kernel declines.From north and south-
In 1~11 generation, occurred for year；On the south one line of Nanling mountain, there are a certain number of pupas and a small amount of larva overwintering throughout the year, rice to the north of 30 ° of north latitude
Area cannot be overwintering, therefore the first worm sources of vast rice region move to come from south.Adult has phototaxis, inhabites concealment and oviposition becomes tender
Property, thermophilic high humidity egg laying amount is big, general per female oviposition 40~70；The more per unit area yields of ovum also have 2~5 to originate in together, and temperature 22~
28 DEG C, 80% or more relative humidity, egg hatching rate is up to 80~90% or more.Newly hatched larvae largely pierces lobus cardiacus and causes harm, into
After entering for 2 ages, then bud is tied on leaf, the booting later stage can pierce fringe bud feeding.Larva one eats 5~6, leaf, up to 9~10 raw, food
Amount increases with worm age and is increased, and for 1~3 age defoliation mount only within 10%, the aging majority of larva leaves old worm bud, in rice clump base portion
Full cocoon is tied in yellow leaf and ineffective tiller tender leaf to pupate.Weight occurs for rice leaf roller and weather conditions are closely related, thermophilic high humidity
In the case of, advantageous Adult worms producting eggs, hatching and larva survive, and therefore, in rainy day and the high humidity weather of more dew, it is vertical to be conducive to rice
Leaf roll snout moth's larva is rampant.
It is the effective way for solving resistance problem that the single use of pesticide, which can bring resistance risk, agriculture chemical compounding,.
It is one of prevention most effective chemical means of insect pest of the plant using chemical agent；With the novel pesticide of not cross resistance
It is a good solution to prevent insect pest of the plant；But one novel pesticide of exploitation needs to screen a chemical combination up to ten thousand at present
Object, hundred million dollars of cost 1.2-1.5, the development cycle is 5-10, it is difficult to the speed that the upper pest caught up with develops immunity to drugs；Others side
Method such as crop structure adjustment, different pesticide rotations etc., in actual mechanical process, it is difficult to play apparent effect.
Develop new product insecticide is expensive, the period is long, and in contrast, exploitation is efficient, less toxic, low-residual with research
Compounding have with mixture invest small, lead time it is short and by attention both domestic and external, it is numerous and confused to increase development dynamics.
The combination of chloramine phos and ring tebufenozide has not been reported.
Invention content
The present invention provides a kind of synergetic pesticide composition containing chloramine phos and ring tebufenozide, for prevent cotton boll worm,
Paddy rice rice leaf roller and other lepidoptera pests can be used for preventing other harmful insects.
The invention is realized by the following technical scheme：
A kind of composition pesticide containing chloramine phos and ring tebufenozide, contains active constituent chloramine phos and ring tebufenozide, chloramines
The mass fraction ratio of phosphorus and ring tebufenozide is 7:1~1:1.
The mass fraction ratio of preferred chloramine phos and ring tebufenozide is 4:1~2:1.
The mass fraction ratio of further preferred chloramine phos and ring tebufenozide is 4:1.
The mass fraction ratio of further preferred chloramine phos and ring tebufenozide is 3:1.
The mass fraction ratio of further preferred chloramine phos and ring tebufenozide is 2:1.
The total weight percentage composition of the composition pesticide, chloramine phos and ring tebufenozide in the composition is 5~50%,
Remaining is insecticides adjuvant；The total weight percentage composition of preferred chloramine phos and ring tebufenozide in the composition is 10~20%, remaining
For insecticides adjuvant；.
The dosage form of the composition pesticide can be aqueous suspension agent, can also be other formulations of pesticide such as water dispersible granules,
Suspension emulsion, microemulsion, aqueous emulsion, water dispersible granules, dispersible oil-suspending agent etc..
The composition pesticide is suitable for prevention cotton boll worm, can be used for preventing other kinds of Lepidoptera children
Worm and coleoptera, Homoptera, Hymenoptera, Diptera, hemipteran.
The aqueous suspension agent dosage form weight percent group becomes：Chloramine phos 1~25%, ring tebufenozide 1~25%, dispersion
Agent 1~35%, thickener 0.1~3%, antifreezing agent 0.1~5%, deionized water carrier complement to 100%.Specific production stage
For：Active ingredient and other auxiliary agents are mixed, after being sanded in high speed shear dispersion, sand mill, formed in water-medium high
Dispersion, the suspension system stablized, are made the suspending agent of corresponding weight percentage.
The micro-emulsion form weight percent group becomes：Chloramine phos 1~10%, ring tebufenozide 1~10%, dispersant
0.1~15%, emulsifier 1~15%, solvent 0.1~10%, antifreezing agent 0.1~5%, deionized water complements to 100%.Specifically
Production stage is：Active ingredient and other auxiliary agents are uniformly mixed, after active ingredient and auxiliary agent dissolving, are placed in container with shearing
Machine is sheared 5 minutes~2 hours, and the microemulsion of corresponding weight percentage is obtained.
The antifreezing agent can be one or more of in glycerine, propylene glycol, diethylene glycol (DEG), urea etc..
The wetting agent can be lauryl sodium sulfate, neopelex, sodium butylnaphthalenesulfonate, alkyl sulphur
One or more of sour sodium, tea seed cake powder, spaonin powder, spaonin powder, wheat bran, sorghum starch, buckwheat etc..
The emulsifier can be triphenoethyl benzene phenol polyethenoxy ether phosphate, epoxychloropropane, castor oil polyoxy second
One kind in alkene ether, fatty alcohol polyoxy ether, aliphatic acid polyethenoxy ether, isomery alcohol.
The dispersant can be APES formaldehyde condensation product, naphthalene sulfonate, benzene sulfonate, to methoxy
Base fatty acyl anilinesulfonic acid, lignosulfonates, polycarboxylate, aliphatic ester sulfate, alkyl phenol polyoxyethylene ether, fat
Alcohol polyoxyethylene ether, polyethylene glycol stearate, Oleate, empgen BB, nekal, phosphorus
One or more of acid esters etc..
The solvent can be solvent naphtha S-150, solvent naphtha S-200, ethyl alcohol, isopropanol, n-butanol, n-octyl alcohol, positive penta
Alcohol, acetone, cyclohexanone, hexane, dimethylformamide, N-Methyl pyrrolidone, ethyl acetate, methyl oleate, phthalic acid
Dibutyl ester, sec-Butyl Acetate.
The deionized water is industrial deionized water.
Compared with the prior art, the advantages of the present invention are as follows：
1, chloramine phos and ring tebufenozide compound within the scope of certain proportion has synergistic effect to cotton boll worm.
2, two kinds of active ingredient compoundings of chloramine phos and ring tebufenozide, reduce Pesticide use amount, reduce use cost, subtract
Light pollution to environment has delayed the generation of pest and disease damage drug resistance, has extended the service life of pesticide.
Specific implementation mode
(1), raw to survey embodiment
According to Sun Yunpei's Method, the synergistic effect of pharmacy mix is evaluated according to co-toxicity coefficient (CTC), i.e. CTC≤80 are association
Same antagonism, 80 ＜ CTC ＜ 120 are joint action of antagonism, and CTC >=120 are synergistic function.
Survey toxicity index (ATI)=(LC of standard agent50The LC of/reagent agent50)×100；
The virulence of the percentage composition+B medicaments of A medicaments refers in toxicity index × mixture of theoretical toxicity index TTI=A medicaments
The percentage composition of B medicaments in number × mixture；
Co-toxicity coefficient (CTC)=[mixture surveys toxicity index (ATI)/mixtures theoretical toxicity index (TTI)] × 100.
1 chloramine phos of table measure (stomach poison activity, use with ring tebufenozide to the toxicity of cotton boll worm (2 instar larvae)
Leaf stomach toxicity method is soaked, 72 hours after medicine, test method is killed with reference to NY/T 1154.14-2008 farm-chemical indoor determination test rules
The 14th part of worm agent：Leaf dipping method).
The data result that table 1 is recorded shows chloramine phos and ring tebufenozide mass fraction ratio 7:1~1:It is right in 1 range
There is the stomach poison activity of cotton boll worm (2 instar larvae) synergistic effect, co-toxicity coefficient to be more than 120；Chloramine phos and ring tebufenozide matter
Number ratio is measured 4:1~2:There is synergistic effect to the stomach poison activity of cotton boll worm (2 instar larvae) in 1 range, altogether poison system
Number is more than 140；And chloramine phos and ring tebufenozide mass fraction ratio are 40:1~10:1 and 1:3~1:50 pairs of cotton boll worms (2
Instar larvae) stomach poison activity there is no a synergistic effect, co-toxicity coefficient is less than 120.
(2), example of formulations
10% chloramine phos ring tebufenozide aqueous suspension agent
Take 2% ring tebufenozide, 8% chloramine phos, 3% empgen BB, 3% urea, 6% castor oil polyoxyethylene
Ether is added deionized water and complements to 100%, active ingredient and other auxiliary agents are mixed, through sand in high speed shear dispersion, sand mill
After mill, high dispersive, the suspension system of stabilization are formed in water-medium, obtains 10% ring tebufenozide chloramine phos aqueous suspension
Agent.
9% chloramine phos chromafenozide micron emulsion
Chloramine phos 6%, ring tebufenozide 3%, phosphate 4%, n-butanol 8%, glycerine 3%, deionized water is supplied
100%；Active ingredient is completely dissolved with solvent, emulsifier, stabilizer, bleeding agent, antifreezing agent is then added and is uniformly mixed,
It is eventually adding deionized water, after being sufficiently stirred, you can 9% chloramine phos chromafenozide micron emulsion is made.
(3), Application Example
2 10% chloramine phos ring tebufenozide aqueous suspension agent of table prevents cotton boll worm field control effectiveness test (96 hours after medicine
Investigation, is watered 45 kilograms per acre)
Table 2 the result shows that, 5% 60 grams/ha of chloramine phos ring tebufenozide aqueous suspension agent effective ingredient consumption prevent cotton
96 hours investigation prevention effects are preferably and better than 60 grams/ha of 5% chromafenozide suspending agent effective ingredient consumption after bollworm medicine.
3 5% chloramine phos ring tebufenozide aqueous suspension agent of table prevents paddy rice rice leaf roller field control effectiveness test (96 after medicine
Hour investigation, is watered 45 kilograms per acre)
Table 3 the result shows that, 5% 60 grams/ha of chloramine phos ring tebufenozide aqueous suspension agent effective ingredient consumption prevent rice
After rice leaf roller medicine 96 hours investigation prevention effects preferably and better than 60 grams of 5% chromafenozide suspending agent effective ingredient consumption/
Hectare.
Claims (10)
1. a kind of composition pesticide containing chloramine phos and ring tebufenozide, it is characterised in that：Contain active constituent chloramine phos and ring worm
The mass fraction ratio of hydrazides, chloramine phos and ring tebufenozide is 7:1~1:1.
2. composition pesticide according to claim 1, it is characterised in that：The mass fraction ratio of chloramine phos and ring tebufenozide
It is 4:1~2:1.
3. composition pesticide according to claim 1, it is characterised in that：The mass fraction ratio of chloramine phos and ring tebufenozide
It is 4:1.
4. composition pesticide according to claim 1, it is characterised in that：The mass fraction ratio of chloramine phos and ring tebufenozide
It is 3:1.
5. composition pesticide according to claim 1, it is characterised in that：The mass fraction ratio of chloramine phos and ring tebufenozide
It is 2:1.
6. composition pesticide according to claim 1, it is characterised in that：Chloramine phos and ring tebufenozide in the composition total
Weight percentage is 5~50%, remaining is insecticides adjuvant.
7. composition pesticide according to claim 1, it is characterised in that：Chloramine phos and ring tebufenozide in the composition total
Weight percentage is 10~20%, remaining is insecticides adjuvant.
8. composition pesticide according to claim 1, it is characterised in that：The dosage form of composition pesticide is aqueous suspension agent.
9. the composition pesticide described in claim 4, it is characterised in that the preparation method of aqueous suspension agent is as follows：Take 2% ring worm acyl
Hydrazine, 8% chloramine phos, 3% empgen BB, 3% urea, 6% castor oil polyoxyethylene ether are added deionized water and complement to
100%, active ingredient and other auxiliary agents are mixed, after being sanded in high speed shear dispersion, sand mill, formed in water-medium
High dispersive, the suspension system of stabilization obtain 10% ring tebufenozide chloramine phos aqueous suspension agent.
10. composition pesticide as described in any one of claim 1 to 9 is in prevention cotton boll worm, paddy rice rice leaf roller
Application.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810464486.2A CN108402074A (en) | 2018-05-15 | 2018-05-15 | A kind of composition pesticide containing chloramine phos and ring tebufenozide |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810464486.2A CN108402074A (en) | 2018-05-15 | 2018-05-15 | A kind of composition pesticide containing chloramine phos and ring tebufenozide |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108402074A true CN108402074A (en) | 2018-08-17 |
Family
ID=63139638
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810464486.2A Withdrawn CN108402074A (en) | 2018-05-15 | 2018-05-15 | A kind of composition pesticide containing chloramine phos and ring tebufenozide |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108402074A (en) |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103300054A (en) * | 2012-03-12 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and organic phosphorus |
-
2018
- 2018-05-15 CN CN201810464486.2A patent/CN108402074A/en not_active Withdrawn
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103300054A (en) * | 2012-03-12 | 2013-09-18 | 陕西韦尔奇作物保护有限公司 | Insecticidal composition containing chromafenozide and organic phosphorus |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101911943B (en) | Methoxyfenozide-containing insecticidal composition | |
| CN102771510B (en) | Insecticidal composition containing fosthiazate | |
| CN102440257A (en) | Pesticide composition compounded with part of nicotine compounds | |
| CN103125493A (en) | Insecticide composition mixed with amides pesticide | |
| CN101984828B (en) | Compound pesticide | |
| Garcia | Sublethal effects of pyrethroids on insect parasitoids: what we need to further know | |
| CN101773141A (en) | Compound pesticide of chlorantraniliprole and chlorpyrifos | |
| CN101999381B (en) | Emamectinbenzoate thiodicarb insecticide | |
| Nathala et al. | Biological effects of Caesalpinia crista seed extracts on Helicoverpa armigera (Lepidoptera: Noctuidae) and its Predator, Coccinella septumpunctata (Coleoptera: Coccinellidae) | |
| CN110583701A (en) | Beauveria bassiana and bacterium compound pesticide for killing spodoptera frugiperda | |
| CN109042715A (en) | One kind is containing double third ring worm esters and four chlorantraniliprole compositions | |
| CN103300035A (en) | Pesticide composition containing chromafenozide | |
| CN111374148A (en) | Insecticidal composition containing methoprene | |
| CN102027967B (en) | Pesticide composition containing pyriproxyfen and metaflumizone and application thereof | |
| CN108402074A (en) | A kind of composition pesticide containing chloramine phos and ring tebufenozide | |
| CN104855399B (en) | A kind of Pesticidal combination containing butene-fipronil and fluorobenzene insect amide | |
| CN102972421A (en) | Insecticidal composition containing emamectin benzoate and triflumuron | |
| CN101357909B (en) | 1,3, 4-thiadiazole aroyl urea compound and preparation method and application thereof | |
| CN108432785A (en) | A kind of composition pesticide for tieing up rhzomorph and thiodicarb containing day | |
| CN109169709A (en) | It is a kind of for preventing and treating the synergistic composition of Cruciferous Vegetable Pests | |
| CN108432757A (en) | A kind of composition pesticide containing sufluoxime and Meiling-mycin | |
| CN103004803A (en) | Insecticide composition containing fluorous cyantraniliprole and emamectin benzoate | |
| CN103734172B (en) | Plant insecticide suspending agent | |
| CN107455384B (en) | A kind of pesticide synergistic composition containing phenthoate dimephenthoate cidial | |
| CN105325450A (en) | Suspending agent of dinotefuran and efficient cyhalothrin compound pesticide and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| CB02 | Change of applicant information | ||
| CB02 | Change of applicant information |
Address after: 518000 Agriculturalization of Science Popularization Credit No. 157 Reservoir Road, Baoan District, Shenzhen City, Guangdong Province Applicant after: Zhang Youlan Address before: 516000 No. 2, No. 8 Lane, No. 24 District, Zhongkai High-tech Zone, Huizhou City, Guangdong Province Applicant before: Zhang Youlan |
|
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180817 |