CN108395016A - Purification method of saponification liquid wastewater - Google Patents

Purification method of saponification liquid wastewater Download PDF

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Publication number
CN108395016A
CN108395016A CN201810117831.5A CN201810117831A CN108395016A CN 108395016 A CN108395016 A CN 108395016A CN 201810117831 A CN201810117831 A CN 201810117831A CN 108395016 A CN108395016 A CN 108395016A
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CN
China
Prior art keywords
saponification liquor
waste water
saponification
purification method
water
Prior art date
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Pending
Application number
CN201810117831.5A
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Chinese (zh)
Inventor
李旺昌
戴纬综
冯叶佳
林滔滔
金晓盼
黄瑶
车声雷
应耀
乔梁
郑精武
余靓
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Zhejiang University of Technology ZJUT
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Zhejiang University of Technology ZJUT
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Priority to CN201810117831.5A priority Critical patent/CN108395016A/en
Publication of CN108395016A publication Critical patent/CN108395016A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/283Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/285Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/38Treatment of water, waste water, or sewage by centrifugal separation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/5236Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • C02F1/54Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
    • C02F1/56Macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/10Inorganic compounds
    • C02F2101/16Nitrogen compounds, e.g. ammonia
    • C02F2101/166Nitrites
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/34Organic compounds containing oxygen
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2101/00Nature of the contaminant
    • C02F2101/30Organic compounds
    • C02F2101/38Organic compounds containing nitrogen

Landscapes

  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Separation Of Suspended Particles By Flocculating Agents (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

A purification method of saponification liquid wastewater comprises the following steps: mixing the saponification liquid wastewater with a flocculating agent, stirring for 1-3.5 hours at a stirring speed of 30-65 r/min, standing for 1-24 hours in a constant temperature environment of 20-65 ℃, then performing centrifugal separation, standing the separated liquid in a constant temperature environment of 20-60 ℃ for 2-5 hours, and performing adsorption purification for 0.5-3.5 hours by using an adsorption component to obtain wastewater which reaches the standard and is discharged; the invention adopts the flocculation method to demulsify the saponified liquid wastewater, has simple and safe treatment process and low cost, and is suitable for industrially treating the saponified liquid wastewater on a large scale; the treated wastewater meets the national standard and can be discharged safely; the actual saponification liquid waste water operation needs a small area, and is economical and efficient.

Description

A kind of useless water purification method of saponification liquor
(1) technical field
The invention belongs to field of waste water treatment, and in particular to a kind of useless water purification method of saponification liquor.
(2) background technology
The application of today's society, magnetic material is very extensive, can be used in electroacoustic, telecommunications, ammeter, motor, can also make to remember Element, microwave component etc..It can be used for record instruction, music, the tape of image information, the magnetic storage apparatus of computer, passenger The magnetic card etc. of voucher and admission fee clearing by bus.
Zhejiang is the big province of magnetic material, produces 700000 tons of permanent-magnet ferrite materials per year.Have in the production process of magnetic material One of wet method pressing mold molding procedure, this procedure, which needs to do medium with mineral oil, carries out pressing mold, in order to demould, while this road work Sequence will produce serious saponification liquor water pollution.Saponification liquor is a kind of emulsion of white, seriously pollutes environment, this problem is also at present It can not solve.There is also same problems for Powder Metallurgy Industry other than magnetic material industry.As long as using wet method pressing mold Enterprise just will produce saponification liquor waste water, and the fields such as ecology, environment other than industry also will produce a large amount of emulsion.It is overall On, it is domestic less in the commercial Application of saponification liquor wastewater treatment at present, and technique huge energy consumption, especially in field of magnetic material It is particularly present blank.
(3) invention content
For the deficiencies in the prior art, the present invention provides flocculation adsorption methods to handle saponification liquor waste water, described Flocculation adsorption method is easy to operate, processing cost is low, has good effect, and can meeting that treated, waste water reaches country's discharge mark It is accurate.
Technical scheme is as follows:
A kind of useless water purification method of saponification liquor, the method are:
Saponification liquor waste water, flocculant are mixed, 1~3.5h is stirred under 30~65r/min stir speed (S.S.)s, is then placed in 20 In~65 DEG C of isoperibols stand 1~for 24 hours, centrifuge later, separating obtained liquid is placed in quiet in 20~60 DEG C of isoperibols After setting 2~5h, 0.5~3.5h of adsorption cleaning is carried out by absorbent module, obtains the waste water of qualified discharge.
The quality dosage of the flocculant is calculated as 0.1~1g/mL, preferably 0.3~0.55g/ with the volume of saponification liquor waste water mL。
The flocculant is selected from aluminium polychloride, polymeric aluminium ferrum silicate, ferric trichloride, polyacrylamide, alchlor, sulphur The mixture of one or two kinds of any of the above ratio in sour aluminium, ferric sulfate.
Disc centrifuge, perforated wall centrifuge or sedimentation centrifuge may be used in the centrifugation.
The absorbent module by feed liquor component, adsorbing separation pipe group, go out liquid component and be sequentially connected to form, the adsorbing separation Guan Zuzhong is filled with adsorbent;The adsorbent is silica gel, macroreticular resin, activated alumina, one kind in activated carbon or two The mixture of kind any of the above ratio;The mass volume ratio of the adsorbent and saponification liquor waste water is 1:0.2~1.6 (w/v, g/ mL)。
Wet method pressing mold molding procedure of the saponification liquor waste water of the present invention from magnetic materials production process, in wet method pressing mold Saponified oil is added in molding procedure to be helped to demould, and saponified oil is dissolved in water generation white during mold is rinsed with water after demoulding Emulsion, i.e., heretofore described saponification liquor waste water;
Saponification oil content is in 0.1~20g/ml in usual saponification liquor waste water;
Specifically, for example, the saponification oil component (mass percentage) is:AS oiliness improvers (70%), triethanolamine (4%), 400# polyethylene glycol (6%), sodium nitrite (4%), EDETATE SODIUM (2%), BK fungicide (2%), Tween 80 (12%).
The advantage of the invention is that:
(1) for the present invention using flocculence demulsification saponification liquor waste water, treatment process process is simple, safe, of low cost, is applicable in In industrially handling the saponification liquor waste water on a large scale;
(2) waste water after processing meets the waste water of national standard discharge, can feel at ease to discharge;
(3) place needed for practical saponification liquor waste water operations is small, economical and efficient.
(4) it illustrates
Fig. 1:Saponification liquor waste water without any processing;
Fig. 2:It is embodiment 2 and 4 respectively using flocculation adsorption method treated waste water.
(5) specific implementation mode
Below by specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited in This.
Saponification liquor waste water in following embodiment is the simulated wastewater that laboratory is prepared, and is mixed by saponified oil, water, institute Saponified oil is that multidimensional lubrication technology portion of Shenzhen produces, brand Ai Pute, model APT.MW-301, and proportion is 0.85g/ml, specific quality percentage composition are as follows:
AS oiliness improvers (70%), triethanolamine (4%), 400# polyethylene glycol (6%), sodium nitrite (4%), EDETATE SODIUM (2%), BK fungicide (2%), Tween 80 (12%).
Embodiment 1
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 6g aluminium polychlorides are mixed, in 45r/min stir speed (S.S.)s Lower stirring 2.5h is then placed in 35 DEG C of isoperibols and stands 7h, centrifuges later, and separating obtained liquid is placed in 50 DEG C of constant temperature 4h is stood in environment, and adsorption cleaning is carried out by absorbent module containing macroreticular resin, after adsorption cleaning 3h, obtains qualified discharge Waste water.
Embodiment 2
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 8g polymeric aluminium ferrum silicates are mixed, speed is stirred in 45r/min 2.5h is stirred under rate, is then placed in 35 DEG C of isoperibols and stands 7h, centrifuge later, and separating obtained liquid is placed in 50 DEG C of perseverances 4h is stood in warm environment, adsorption cleaning is carried out by absorbent module containing activated carbon, after adsorption cleaning 3h, obtains qualified discharge Waste water;
Embodiment 3
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 11g ferric trichlorides are mixed, under 45r/min stir speed (S.S.)s 2.5h is stirred, is then placed in 35 DEG C of isoperibols and stands 7h, centrifuge later, separating obtained liquid is placed in 50 DEG C of constant temperature rings 4h is stood in border, and adsorption cleaning is carried out by absorbent module containing activated alumina, after adsorption cleaning 3h, obtains qualified discharge Waste water;
Embodiment 4
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 9g polyacrylamides are mixed, in 45r/min stir speed (S.S.)s Lower stirring 2.5h is then placed in 35 DEG C of isoperibols and stands 7h, centrifuges later, and separating obtained liquid is placed in 50 DEG C of constant temperature 4h is stood in environment, and adsorption cleaning is carried out by absorbent module containing silica gel, after adsorption cleaning 3h, obtains the useless of qualified discharge Water.
Comparative example
The existing mating electrostatic precipitator technology of saponification salkali waste burning boiler, i.e., handle saponification liquor waste water with burning method, and use is quiet Electric precipitator handles incineration flue gas, and equipment requirement is high compared with the processing method provided by the present invention, and processing cost is high, and operation is not simple Just, and it is susceptible to off-gas recovery insufficient the case where being polluted to air.

Claims (5)

  1. The water purification method 1. a kind of saponification liquor gives up, which is characterized in that the method is:
    Saponification liquor waste water, flocculant are mixed, 1~3.5h is stirred under 30~65r/min stir speed (S.S.)s, is then placed in 20~65 Stand 1 in DEG C isoperibol~for 24 hours, it centrifuging later, separating obtained liquid is placed in 20~60 DEG C of isoperibols and stands 2~ After 5h, 0.5~3.5h of adsorption cleaning is carried out by absorbent module, obtains the waste water of qualified discharge;
    The quality dosage of the flocculant is calculated as 0.1~1g/mL with the volume of saponification liquor waste water;
    The flocculant is selected from aluminium polychloride, polymeric aluminium ferrum silicate, ferric trichloride, polyacrylamide, alchlor, sulfuric acid The mixture of one or two kinds of any of the above ratio in aluminium, ferric sulfate.
  2. The water purification method 2. saponification liquor as described in claim 1 gives up, which is characterized in that the quality dosage of the flocculant with The volume of saponification liquor waste water is calculated as 0.3~0.55g/mL.
  3. The water purification method 3. saponification liquor as described in claim 1 gives up, which is characterized in that described centrifuge uses disc-type Centrifuge, perforated wall centrifuge or sedimentation centrifuge.
  4. The water purification method 4. saponification liquor as described in claim 1 gives up, which is characterized in that the absorbent module is by feed liquor group Part, adsorbing separation pipe group go out liquid component and are sequentially connected composition, and the adsorbing separation Guan Zuzhong is filled with adsorbent;The absorption Agent is the mixture of silica gel, macroreticular resin, activated alumina, one or two kinds of any of the above ratio in activated carbon;It is described The mass volume ratio of adsorbent and saponification liquor waste water is 1:0.2~1.6.
  5. The water purification method 5. saponification liquor as described in claim 1 gives up, which is characterized in that the saponification liquor waste water is from magnetism The wet method pressing mold molding procedure of Material Manufacturing Process, addition saponified oil helps to demould in wet method pressing mold molding procedure, demoulds After be rinsed with water saponified oil during mold and be dissolved in water and generate white emulsion, i.e. the saponification liquor waste water.
CN201810117831.5A 2018-02-06 2018-02-06 Purification method of saponification liquid wastewater Pending CN108395016A (en)

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CN201810117831.5A CN108395016A (en) 2018-02-06 2018-02-06 Purification method of saponification liquid wastewater

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Application Number Priority Date Filing Date Title
CN201810117831.5A CN108395016A (en) 2018-02-06 2018-02-06 Purification method of saponification liquid wastewater

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CN108395016A true CN108395016A (en) 2018-08-14

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04322786A (en) * 1991-01-14 1992-11-12 Japan Organo Co Ltd Treatment of dense waste liquid of detergent comprising alkali saponifying agent for printed circuit board
CN105906132A (en) * 2016-06-28 2016-08-31 中铝广西国盛稀土开发有限公司 Rare-earth saponification wastewater comprehensive treatment system
CN106565046A (en) * 2016-08-31 2017-04-19 惠州市惠阳区力行环保有限公司 Treatment method for waste cutting fluid
CN106630246A (en) * 2015-11-02 2017-05-10 张家港格林台科环保设备有限公司 Waste emulsion demulsification processing method

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPH04322786A (en) * 1991-01-14 1992-11-12 Japan Organo Co Ltd Treatment of dense waste liquid of detergent comprising alkali saponifying agent for printed circuit board
CN106630246A (en) * 2015-11-02 2017-05-10 张家港格林台科环保设备有限公司 Waste emulsion demulsification processing method
CN105906132A (en) * 2016-06-28 2016-08-31 中铝广西国盛稀土开发有限公司 Rare-earth saponification wastewater comprehensive treatment system
CN106565046A (en) * 2016-08-31 2017-04-19 惠州市惠阳区力行环保有限公司 Treatment method for waste cutting fluid

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
张均等: "《金属工艺与实训》", 31 August 2009 *

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Application publication date: 20180814