CN108395016A - Purification method of saponification liquid wastewater - Google Patents
Purification method of saponification liquid wastewater Download PDFInfo
- Publication number
- CN108395016A CN108395016A CN201810117831.5A CN201810117831A CN108395016A CN 108395016 A CN108395016 A CN 108395016A CN 201810117831 A CN201810117831 A CN 201810117831A CN 108395016 A CN108395016 A CN 108395016A
- Authority
- CN
- China
- Prior art keywords
- saponification liquor
- waste water
- saponification
- purification method
- water
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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- 238000007127 saponification reaction Methods 0.000 title claims abstract description 42
- 239000002351 wastewater Substances 0.000 title claims abstract description 41
- 238000000034 method Methods 0.000 title claims abstract description 33
- 239000007788 liquid Substances 0.000 title claims abstract description 14
- 238000000746 purification Methods 0.000 title claims abstract description 11
- 238000001179 sorption measurement Methods 0.000 claims abstract description 15
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 15
- 238000003756 stirring Methods 0.000 claims abstract description 9
- 238000000926 separation method Methods 0.000 claims abstract description 5
- 238000004140 cleaning Methods 0.000 claims description 10
- 239000002250 absorbent Substances 0.000 claims description 8
- 230000002745 absorbent Effects 0.000 claims description 8
- 229910052782 aluminium Inorganic materials 0.000 claims description 8
- 239000004411 aluminium Substances 0.000 claims description 8
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical group [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims description 7
- 238000003825 pressing Methods 0.000 claims description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 6
- 239000000203 mixture Substances 0.000 claims description 6
- 239000003463 adsorbent Substances 0.000 claims description 5
- 238000000465 moulding Methods 0.000 claims description 5
- 239000000839 emulsion Substances 0.000 claims description 4
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 3
- -1 alchlor Chemical compound 0.000 claims description 3
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 3
- 238000004519 manufacturing process Methods 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000011347 resin Substances 0.000 claims description 3
- 229920005989 resin Polymers 0.000 claims description 3
- 239000000741 silica gel Substances 0.000 claims description 3
- 229910002027 silica gel Inorganic materials 0.000 claims description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 2
- BPQQTUXANYXVAA-UHFFFAOYSA-N Orthosilicate Chemical compound [O-][Si]([O-])([O-])[O-] BPQQTUXANYXVAA-UHFFFAOYSA-N 0.000 claims description 2
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- 239000000463 material Substances 0.000 claims description 2
- 238000004062 sedimentation Methods 0.000 claims description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims 2
- 238000010521 absorption reaction Methods 0.000 claims 1
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 230000005389 magnetism Effects 0.000 claims 1
- 238000005189 flocculation Methods 0.000 abstract description 4
- 230000016615 flocculation Effects 0.000 abstract description 4
- 239000008394 flocculating agent Substances 0.000 abstract 1
- 239000010808 liquid waste Substances 0.000 abstract 1
- 239000003921 oil Substances 0.000 description 10
- 239000000696 magnetic material Substances 0.000 description 6
- LPXPTNMVRIOKMN-UHFFFAOYSA-M sodium nitrite Chemical compound [Na+].[O-]N=O LPXPTNMVRIOKMN-UHFFFAOYSA-M 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 3
- 239000002202 Polyethylene glycol Substances 0.000 description 2
- GSEJCLTVZPLZKY-UHFFFAOYSA-N Triethanolamine Chemical compound OCCN(CCO)CCO GSEJCLTVZPLZKY-UHFFFAOYSA-N 0.000 description 2
- 230000000855 fungicidal effect Effects 0.000 description 2
- 239000000417 fungicide Substances 0.000 description 2
- 229920001223 polyethylene glycol Polymers 0.000 description 2
- 235000010482 polyoxyethylene sorbitan monooleate Nutrition 0.000 description 2
- 229920000053 polysorbate 80 Polymers 0.000 description 2
- 235000010288 sodium nitrite Nutrition 0.000 description 2
- UEUXEKPTXMALOB-UHFFFAOYSA-J tetrasodium;2-[2-[bis(carboxylatomethyl)amino]ethyl-(carboxylatomethyl)amino]acetate Chemical compound [Na+].[Na+].[Na+].[Na+].[O-]C(=O)CN(CC([O-])=O)CCN(CC([O-])=O)CC([O-])=O UEUXEKPTXMALOB-UHFFFAOYSA-J 0.000 description 2
- 238000004065 wastewater treatment Methods 0.000 description 2
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 description 1
- 241000288147 Meleagris gallopavo Species 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000005119 centrifugation Methods 0.000 description 1
- 230000000052 comparative effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000012717 electrostatic precipitator Substances 0.000 description 1
- 238000005265 energy consumption Methods 0.000 description 1
- 239000003546 flue gas Substances 0.000 description 1
- 239000007789 gas Substances 0.000 description 1
- 238000005461 lubrication Methods 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 238000004663 powder metallurgy Methods 0.000 description 1
- 239000012716 precipitator Substances 0.000 description 1
- 238000003672 processing method Methods 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000003860 storage Methods 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
- 238000003911 water pollution Methods 0.000 description 1
- 229910000859 α-Fe Inorganic materials 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F9/00—Multistage treatment of water, waste water or sewage
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/001—Processes for the treatment of water whereby the filtration technique is of importance
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/281—Treatment of water, waste water, or sewage by sorption using inorganic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/283—Treatment of water, waste water, or sewage by sorption using coal, charred products, or inorganic mixtures containing them
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/28—Treatment of water, waste water, or sewage by sorption
- C02F1/285—Treatment of water, waste water, or sewage by sorption using synthetic organic sorbents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/38—Treatment of water, waste water, or sewage by centrifugal separation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/5236—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using inorganic agents
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/52—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
- C02F1/54—Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities using organic material
- C02F1/56—Macromolecular compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F2001/007—Processes including a sedimentation step
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/10—Inorganic compounds
- C02F2101/16—Nitrogen compounds, e.g. ammonia
- C02F2101/166—Nitrites
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/34—Organic compounds containing oxygen
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/38—Organic compounds containing nitrogen
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Engineering & Computer Science (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Separation Of Suspended Particles By Flocculating Agents (AREA)
- Water Treatment By Sorption (AREA)
Abstract
A purification method of saponification liquid wastewater comprises the following steps: mixing the saponification liquid wastewater with a flocculating agent, stirring for 1-3.5 hours at a stirring speed of 30-65 r/min, standing for 1-24 hours in a constant temperature environment of 20-65 ℃, then performing centrifugal separation, standing the separated liquid in a constant temperature environment of 20-60 ℃ for 2-5 hours, and performing adsorption purification for 0.5-3.5 hours by using an adsorption component to obtain wastewater which reaches the standard and is discharged; the invention adopts the flocculation method to demulsify the saponified liquid wastewater, has simple and safe treatment process and low cost, and is suitable for industrially treating the saponified liquid wastewater on a large scale; the treated wastewater meets the national standard and can be discharged safely; the actual saponification liquid waste water operation needs a small area, and is economical and efficient.
Description
(1) technical field
The invention belongs to field of waste water treatment, and in particular to a kind of useless water purification method of saponification liquor.
(2) background technology
The application of today's society, magnetic material is very extensive, can be used in electroacoustic, telecommunications, ammeter, motor, can also make to remember
Element, microwave component etc..It can be used for record instruction, music, the tape of image information, the magnetic storage apparatus of computer, passenger
The magnetic card etc. of voucher and admission fee clearing by bus.
Zhejiang is the big province of magnetic material, produces 700000 tons of permanent-magnet ferrite materials per year.Have in the production process of magnetic material
One of wet method pressing mold molding procedure, this procedure, which needs to do medium with mineral oil, carries out pressing mold, in order to demould, while this road work
Sequence will produce serious saponification liquor water pollution.Saponification liquor is a kind of emulsion of white, seriously pollutes environment, this problem is also at present
It can not solve.There is also same problems for Powder Metallurgy Industry other than magnetic material industry.As long as using wet method pressing mold
Enterprise just will produce saponification liquor waste water, and the fields such as ecology, environment other than industry also will produce a large amount of emulsion.It is overall
On, it is domestic less in the commercial Application of saponification liquor wastewater treatment at present, and technique huge energy consumption, especially in field of magnetic material
It is particularly present blank.
(3) invention content
For the deficiencies in the prior art, the present invention provides flocculation adsorption methods to handle saponification liquor waste water, described
Flocculation adsorption method is easy to operate, processing cost is low, has good effect, and can meeting that treated, waste water reaches country's discharge mark
It is accurate.
Technical scheme is as follows:
A kind of useless water purification method of saponification liquor, the method are:
Saponification liquor waste water, flocculant are mixed, 1~3.5h is stirred under 30~65r/min stir speed (S.S.)s, is then placed in 20
In~65 DEG C of isoperibols stand 1~for 24 hours, centrifuge later, separating obtained liquid is placed in quiet in 20~60 DEG C of isoperibols
After setting 2~5h, 0.5~3.5h of adsorption cleaning is carried out by absorbent module, obtains the waste water of qualified discharge.
The quality dosage of the flocculant is calculated as 0.1~1g/mL, preferably 0.3~0.55g/ with the volume of saponification liquor waste water
mL。
The flocculant is selected from aluminium polychloride, polymeric aluminium ferrum silicate, ferric trichloride, polyacrylamide, alchlor, sulphur
The mixture of one or two kinds of any of the above ratio in sour aluminium, ferric sulfate.
Disc centrifuge, perforated wall centrifuge or sedimentation centrifuge may be used in the centrifugation.
The absorbent module by feed liquor component, adsorbing separation pipe group, go out liquid component and be sequentially connected to form, the adsorbing separation
Guan Zuzhong is filled with adsorbent;The adsorbent is silica gel, macroreticular resin, activated alumina, one kind in activated carbon or two
The mixture of kind any of the above ratio;The mass volume ratio of the adsorbent and saponification liquor waste water is 1:0.2~1.6 (w/v, g/
mL)。
Wet method pressing mold molding procedure of the saponification liquor waste water of the present invention from magnetic materials production process, in wet method pressing mold
Saponified oil is added in molding procedure to be helped to demould, and saponified oil is dissolved in water generation white during mold is rinsed with water after demoulding
Emulsion, i.e., heretofore described saponification liquor waste water;
Saponification oil content is in 0.1~20g/ml in usual saponification liquor waste water;
Specifically, for example, the saponification oil component (mass percentage) is:AS oiliness improvers (70%), triethanolamine
(4%), 400# polyethylene glycol (6%), sodium nitrite (4%), EDETATE SODIUM (2%), BK fungicide (2%), Tween 80
(12%).
The advantage of the invention is that:
(1) for the present invention using flocculence demulsification saponification liquor waste water, treatment process process is simple, safe, of low cost, is applicable in
In industrially handling the saponification liquor waste water on a large scale;
(2) waste water after processing meets the waste water of national standard discharge, can feel at ease to discharge;
(3) place needed for practical saponification liquor waste water operations is small, economical and efficient.
(4) it illustrates
Fig. 1:Saponification liquor waste water without any processing;
Fig. 2:It is embodiment 2 and 4 respectively using flocculation adsorption method treated waste water.
(5) specific implementation mode
Below by specific embodiment, the present invention is further illustrated, but protection scope of the present invention is not limited in
This.
Saponification liquor waste water in following embodiment is the simulated wastewater that laboratory is prepared, and is mixed by saponified oil, water, institute
Saponified oil is that multidimensional lubrication technology portion of Shenzhen produces, brand Ai Pute, model APT.MW-301, and proportion is
0.85g/ml, specific quality percentage composition are as follows:
AS oiliness improvers (70%), triethanolamine (4%), 400# polyethylene glycol (6%), sodium nitrite (4%), EDETATE SODIUM
(2%), BK fungicide (2%), Tween 80 (12%).
Embodiment 1
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 6g aluminium polychlorides are mixed, in 45r/min stir speed (S.S.)s
Lower stirring 2.5h is then placed in 35 DEG C of isoperibols and stands 7h, centrifuges later, and separating obtained liquid is placed in 50 DEG C of constant temperature
4h is stood in environment, and adsorption cleaning is carried out by absorbent module containing macroreticular resin, after adsorption cleaning 3h, obtains qualified discharge
Waste water.
Embodiment 2
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 8g polymeric aluminium ferrum silicates are mixed, speed is stirred in 45r/min
2.5h is stirred under rate, is then placed in 35 DEG C of isoperibols and stands 7h, centrifuge later, and separating obtained liquid is placed in 50 DEG C of perseverances
4h is stood in warm environment, adsorption cleaning is carried out by absorbent module containing activated carbon, after adsorption cleaning 3h, obtains qualified discharge
Waste water;
Embodiment 3
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 11g ferric trichlorides are mixed, under 45r/min stir speed (S.S.)s
2.5h is stirred, is then placed in 35 DEG C of isoperibols and stands 7h, centrifuge later, separating obtained liquid is placed in 50 DEG C of constant temperature rings
4h is stood in border, and adsorption cleaning is carried out by absorbent module containing activated alumina, after adsorption cleaning 3h, obtains qualified discharge
Waste water;
Embodiment 4
The saponification liquor waste water of 20ml 1.5g/ml containing saponified oil, 9g polyacrylamides are mixed, in 45r/min stir speed (S.S.)s
Lower stirring 2.5h is then placed in 35 DEG C of isoperibols and stands 7h, centrifuges later, and separating obtained liquid is placed in 50 DEG C of constant temperature
4h is stood in environment, and adsorption cleaning is carried out by absorbent module containing silica gel, after adsorption cleaning 3h, obtains the useless of qualified discharge
Water.
Comparative example
The existing mating electrostatic precipitator technology of saponification salkali waste burning boiler, i.e., handle saponification liquor waste water with burning method, and use is quiet
Electric precipitator handles incineration flue gas, and equipment requirement is high compared with the processing method provided by the present invention, and processing cost is high, and operation is not simple
Just, and it is susceptible to off-gas recovery insufficient the case where being polluted to air.
Claims (5)
- The water purification method 1. a kind of saponification liquor gives up, which is characterized in that the method is:Saponification liquor waste water, flocculant are mixed, 1~3.5h is stirred under 30~65r/min stir speed (S.S.)s, is then placed in 20~65 Stand 1 in DEG C isoperibol~for 24 hours, it centrifuging later, separating obtained liquid is placed in 20~60 DEG C of isoperibols and stands 2~ After 5h, 0.5~3.5h of adsorption cleaning is carried out by absorbent module, obtains the waste water of qualified discharge;The quality dosage of the flocculant is calculated as 0.1~1g/mL with the volume of saponification liquor waste water;The flocculant is selected from aluminium polychloride, polymeric aluminium ferrum silicate, ferric trichloride, polyacrylamide, alchlor, sulfuric acid The mixture of one or two kinds of any of the above ratio in aluminium, ferric sulfate.
- The water purification method 2. saponification liquor as described in claim 1 gives up, which is characterized in that the quality dosage of the flocculant with The volume of saponification liquor waste water is calculated as 0.3~0.55g/mL.
- The water purification method 3. saponification liquor as described in claim 1 gives up, which is characterized in that described centrifuge uses disc-type Centrifuge, perforated wall centrifuge or sedimentation centrifuge.
- The water purification method 4. saponification liquor as described in claim 1 gives up, which is characterized in that the absorbent module is by feed liquor group Part, adsorbing separation pipe group go out liquid component and are sequentially connected composition, and the adsorbing separation Guan Zuzhong is filled with adsorbent;The absorption Agent is the mixture of silica gel, macroreticular resin, activated alumina, one or two kinds of any of the above ratio in activated carbon;It is described The mass volume ratio of adsorbent and saponification liquor waste water is 1:0.2~1.6.
- The water purification method 5. saponification liquor as described in claim 1 gives up, which is characterized in that the saponification liquor waste water is from magnetism The wet method pressing mold molding procedure of Material Manufacturing Process, addition saponified oil helps to demould in wet method pressing mold molding procedure, demoulds After be rinsed with water saponified oil during mold and be dissolved in water and generate white emulsion, i.e. the saponification liquor waste water.
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CN201810117831.5A CN108395016A (en) | 2018-02-06 | 2018-02-06 | Purification method of saponification liquid wastewater |
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CN201810117831.5A CN108395016A (en) | 2018-02-06 | 2018-02-06 | Purification method of saponification liquid wastewater |
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Family
ID=63096384
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Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04322786A (en) * | 1991-01-14 | 1992-11-12 | Japan Organo Co Ltd | Treatment of dense waste liquid of detergent comprising alkali saponifying agent for printed circuit board |
CN105906132A (en) * | 2016-06-28 | 2016-08-31 | 中铝广西国盛稀土开发有限公司 | Rare-earth saponification wastewater comprehensive treatment system |
CN106565046A (en) * | 2016-08-31 | 2017-04-19 | 惠州市惠阳区力行环保有限公司 | Treatment method for waste cutting fluid |
CN106630246A (en) * | 2015-11-02 | 2017-05-10 | 张家港格林台科环保设备有限公司 | Waste emulsion demulsification processing method |
-
2018
- 2018-02-06 CN CN201810117831.5A patent/CN108395016A/en active Pending
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPH04322786A (en) * | 1991-01-14 | 1992-11-12 | Japan Organo Co Ltd | Treatment of dense waste liquid of detergent comprising alkali saponifying agent for printed circuit board |
CN106630246A (en) * | 2015-11-02 | 2017-05-10 | 张家港格林台科环保设备有限公司 | Waste emulsion demulsification processing method |
CN105906132A (en) * | 2016-06-28 | 2016-08-31 | 中铝广西国盛稀土开发有限公司 | Rare-earth saponification wastewater comprehensive treatment system |
CN106565046A (en) * | 2016-08-31 | 2017-04-19 | 惠州市惠阳区力行环保有限公司 | Treatment method for waste cutting fluid |
Non-Patent Citations (1)
Title |
---|
张均等: "《金属工艺与实训》", 31 August 2009 * |
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Application publication date: 20180814 |