CN108393041A - A kind of abatement equipment and its application method of indoor decoration pollution gas - Google Patents
A kind of abatement equipment and its application method of indoor decoration pollution gas Download PDFInfo
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- CN108393041A CN108393041A CN201710080288.1A CN201710080288A CN108393041A CN 108393041 A CN108393041 A CN 108393041A CN 201710080288 A CN201710080288 A CN 201710080288A CN 108393041 A CN108393041 A CN 108393041A
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J3/00—Processes of utilising sub-atmospheric or super-atmospheric pressure to effect chemical or physical change of matter; Apparatus therefor
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B65—CONVEYING; PACKING; STORING; HANDLING THIN OR FILAMENTARY MATERIAL
- B65B—MACHINES, APPARATUS OR DEVICES FOR, OR METHODS OF, PACKAGING ARTICLES OR MATERIALS; UNPACKING
- B65B31/00—Packaging articles or materials under special atmospheric or gaseous conditions; Adding propellants to aerosol containers
- B65B31/04—Evacuating, pressurising or gasifying filled containers or wrappers by means of nozzles through which air or other gas, e.g. an inert gas, is withdrawn or supplied
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J2219/00—Chemical, physical or physico-chemical processes in general; Their relevant apparatus
- B01J2219/00049—Controlling or regulating processes
Abstract
The present invention relates to a kind of abatement equipments and its application method of indoor decoration pollution gas, belong to the field of environment protection that house decoration, use and Furniture manufacture use.The present invention is removed indoor polluted gas using the method for reduced vacuum according to the low boiling point property of finishing pollution gas.The abatement equipment is made of the attachment device between bleeding point on vacuum pump, the sealing device with bleeding point and vacuum pump and sealing device；Pollution sources are sealed first when administering indoor polluted gas using this equipment, secondly connect vacuum pump and sealing device, vacuum pump is opened and carries out decompression vacuum pumping, polluted gas closes vacuum pump after administering.Abatement equipment of the present invention is novel, and the method is a kind of using pollution sources as target, the administering method of high-efficiency environment friendly.
Description
Technical field：
The present invention relates to a kind of abatement equipments and its application method of indoor decoration pollution gas, belong to house decoration, make
With and the field of environment protection that uses of Furniture manufacture, more particularly to it is a kind of by the way of reduced vacuum to interior decoration dirt
(polluted gas includes dye：Formaldehyde, ammonia, benzene and substituted benzene, total volatile organic compounds, radon gas and other volatility
Pernicious gas) equipment administered, while being related to the application method of the equipment, to realize removing interior dress rapidly and efficiently
Repair pollution.
Background technology：
In recent years, air pollution problem inside rooms caused by house fitting are on the rise.Popularity rate is presented in modern room finishing
High, the features such as finishing is increasingly sophisticated, furniture is numerous, simultaneously because Home Decoration Profession economic interests drive and technical barrier
In the presence of a large amount of deleterious materials are constantly used for interior decoration, and more serious Community health is caused to endanger.It is each in indoor decoration pollution
Kind organic gas ranks the first to the injury of human body.
(1) type, property of indoor decoration pollution gas and harm
Current main indoor decoration pollution gas includes formaldehyde, ammonia, benzene and substituted benzene, general volatile organic
It closes one or more in object, radon gas and other volatile harmful gases.
1, formaldehyde
(1) physical property
Formaldehyde, colourless gas have special penetrating odor；Molecular formula is HCHO, and relative molecular weight 30.03, boiling point exists
It is -19.5 DEG C under 101.3kPa, fusing point is -92 DEG C, relative air density 1.067；Soluble easily in water and ether is dense in aqueous solution
Degree reaches as high as 55%, and industrial goods are typically the aqueous solution of 40% (containing 8% methanol), are commonly called as formalin.
Formaldehyde monomers are at normal temperatures gaseous state, but it typically occurs as an aqueous solution, thus are largely reduced
The volatility of formaldehyde extends the time of formaldehyde volatilization.
(2) main source of indoor formaldehyde after fitting up
The main source for occupying indoor formaldehyde is；First in the finishing materials such as artificial board, composite floor board, furniture, coating, glue
Aldehyde is high, especially binder, and particieboard, density board, coating, paint, multiply-plywood used in house ornamentation etc. were producing
It can all be used in journey and arrive binder, traditional binder inevitably contains a large amount of first using formaldehyde and urea as raw material
Aldehyde.Formaldehyde gas cannot be evaporated completely in a short time after interior decoration, and the volatilization phase is up to 3~15 years.
(3) to the harm of human body
The World Health Organization (WHO) issued No. 153 bulletin on June 15th, 2004, and bulletin claims, the research aircraft of WHO
Structure " international cancer research institution " (abbreviation IARC) has confirmed that formaldehyde is human carcinogen.Existing ample evidence shows first
Aldehyde can cause the mankind to suffer from CARCINOMA OF THE NASAL CAVITY and nasal sinus cancer, but the hair in terms of being also only limitted to epidemiology for the evidence of leukaemia
It is existing, not yet analyze the Carcinogenesis Mechanism of leukaemia.
Formaldehyde has stimulation, sensitization and mutagenesis.Formaldehyde is magma noxious material, can be combined with protein, high concentration
Occur the serious stimulation of respiratory tract and oedema, Eye irritation, headache when sucking.Formaldehyde can lead to sensitization, direct skin contact
Formaldehyde can cause allergic dermatitis, color spot, necrosis.Formaldehyde has mutagenesis, high-concentration formaldehyde or a kind of genotoxicity
Substance.(Chen Xuemin, Yankee enemy.Modern environment hygiene [M], second edition.Beijing：People's Health Publisher, 2008,535-
542。)
Formaldehyde has intense irritation to eyes, respiratory tract and skin.Formaldehyde Exposed steam causes conjunctivitis, keratitis, nose
Inflammation, bronchitis etc..Laryngospasm, glottic oedema, pneumonia, pulmonary edema occur for emphasis.There are primary sexual stimulus and sensitization to make skin
With.It can cause dermatitis.Concentrated solution can cause skin coagulation necrosis.Oral burn oral cavity and alimentary canal, can occur gastrointestinal perforation,
Shock and hepatorenal damage.Long Term Contact low concentration formaldehyde can have slight eye and upper respiratory tract irritation, dry skin, chap.
Noxious material maximum permissible concentration is 0.5mg/m in workplace air3。
(4) limit value of Indoor Air Quality standards
According to GB/T18883-2002's《Indoor Air Quality standards》, formaldehyde (1 small hourly value) limit value is 0.10mg/
m3。
2, benzene and substituted benzene
(1) physical property
Benzene, colourless transparent liquid have the distinctive smell of aromatic series；Molecular formula is C6H6, relative molecular weight 78.11, boiling point
It it is 80.1 DEG C at 101.3kPa, fusing point is 5.533 DEG C, relative air density 0.87372；Benzene is insoluble in water.Except glycerine, second
Outside the polyalcohols such as glycol, diethylene glycol (DEG), 1,4-butanediol, can with ethyl alcohol, chloroform, ether, carbon tetrachloride, carbon disulfide, glacial acetic acid,
Most of organic solvents such as acetone, toluene, dimethylbenzene and aliphatic hydrocarbon are miscible.In addition to iodine and sulphur slightly dissolve, inorganic matter is in benzene
In do not dissolve.
Substituted benzene includes toluene, dimethylbenzene, ethylbenzene etc., and colourless transparent liquid, boiling spread is 110 DEG C~145 DEG C.
Dissolubility is similar to benzene.
Benzene and substituted benzene can be used as the original of synthetic fuel, medicine, pesticide, photographic film and petrochemical industry product
Material, varnish, the diluent of nitrocellulose lacquer, paint stripper, lubricating oil, grease, wax, celluloid, resin, artificial leather equal solvent.
(2) main source of benzene and benzene homologues in rear chamber is fitted up
Paint, solvent, the binder that benzene and substituted benzene in room air use in furniture in finishing,
Wall finiss, the wallpaper class ornament materials used when wall plaster simultaneously also includes a large amount of benzene and benzene homologues.
Compared with formaldehyde, benzene and substituted benzene are shorter deenergized period.Under preference temperature and ventilation condition, filling
Repair superficial layer benzene and substituted benzene substantially at 3 months it is releasable completely, but in the profound level of furniture or metope partially due to
Benzene and benzene homologues molecule effusion speed are slower, thus wave except the time is long.
(3) to the harm of human body
Benzene and substituted benzene toxicity show as the injury to nervous system, while to skin, eyes and the upper respiratory tract
There is stimulation.It can be entered in vivo by respiratory tract, cause to be poisoned.Calomel poisoning will appear drowsiness, dizzy, headache, nausea, vomit
The symptoms such as spit, be uncomfortable in chest；Severe intoxication may occur in which blurred vision, tremble, breathe shallow and fast, twitch, is stupor, even dead.When long
Between contact may occur in which the neurasthenia symptoms such as apathetic, failure of memory, or even cause genetic damage, make one carcinogenic and disable,
Pregnant woman's sucking can cause miscarry or cause fetal anomaly (Li Sujin, Zhang Tie and Hou Yunxia.Brief talk indoor hardware fitting harmful substance
On the harm of human body and influence [J].Heilungkiang medical science, 2007,30 (03)：43.).
(4) limit value of Indoor Air Quality standards
According to GB/T18883-2002's《Indoor Air Quality standards》, benzene (1 small hourly value) limit value is 0.11mg/
m3；Toluene (1 small hourly value) limit value is 0.20mg/m3；Dimethylbenzene (1 small hourly value) limit value is 0.20mg/m3。
3, ammonia
(1) physical property
Ammonia, colourless gas have strong impulse smell；Molecular formula is NH3, relative molecular weight 17.031, boiling point be-
33.5 DEG C, fusing point is -77.75 DEG C, relative air density 0.7710；Ammonia is dissolved in water, ethyl alcohol and ether, and when high temperature can decompose
At nitrogen and hydrogen, there is reduction.28% aqueous solutions boiling point is 34.5 DEG C, and fusing point is -77 DEG C.
(2) main source of ammonia in rear chamber is fitted up
The materials such as fast freezing agent of the indoor ammonia pollution during underproof concrete admixture, lid building
In material.Ammonia is exceeded to be primarily due in north of china in winter construction, and temperature is low, and construction party has added fast freezing during lid building
Agent, ammonia are discharged by wall.Further, since the ammonia that the urea element itself in the adhesive that wood-based planet uses contains easily is released
It is put into air, such as thick china, glued board, face artificial board are all the main sources of ammonia.Furniture is used when covering with paint, lacquer, colour wash, etc. to be added
Add agent and brightening agent most of all with ammonium hydroxide, can also affect to the concentration of indoor ammonia.
(3) to the harm of human body
It is viscous to be often attracted to human skin mucous membrane, eye conjunctiva and respiratory tract throat because soluble easily in water for ammonia in room air
Film.Stimulation and verification are generated to epithelial tissue, respiratory tract cilium and damage mucous epithelium tissue can be benumbed.Keep pathogenic microorganism easy
In intrusion, weaken resistance of the body to disease.Ammonia in air can suck Human Lung by breathing pattern.Then pass through lung
Bubble is into blood and being combined with hemoglobin makes it transport oxygen function generation obstacle or even destroy.
(4) limit value of Indoor Air Quality standards
According to GB/T18883-2002's《Indoor Air Quality standards》, ammonia (1 small hourly value) limit value is 0.20mg/
m3。
4, total volatile organic compounds (TVOC, Total Volatile Organic Compounds)
GB/T18883-2002's《Indoor Air Quality standards》It is found that total volatile organic compounds (Total
Volatile Organic Compounds) refer to being sampled using Tenax GC or Tenax TA, nonpolar chromatographic column (polarity
10) index, which is less than, to be analyzed, volatile organic compounds of the retention time between n-hexane and hexadecane.And 2013
Year revised standard GB/T 50325-2010《Code for indoor environmental pollution control of civil building engineering》Middle general volatile has
Machine compound refers to, under testing conditions as defined in this specification, the total amount of volatile organic compounds in measured air, referred to as
TVOC。
(1) physical property
Total volatile organic compounds is similarly the aerial gas of dispersion, and the World Health Organization (WHO, 1989) is fixed
Justice：It is deposited in air with evaporated form under room temperature, saturated vapor pressure is more than 133.32Pa, boiling point between 50~260 DEG C
A kind of organic compound is volatile organic compounds.The collectively referred to as general volatile organic of these volatile organic compounds closes
Object.
(2) source of interior TVOC
Wood-based plate, foam heat insulating material, plastic plate, paint, coating, adhesive, wallpaper, carpet used in interior decoration
Deng all easy ting produce TVOC.
(3) to the harm of human body
Total volatile organism (TVOC) refers to the organic compound that can be volatilized in air.The lower high concentration TVOC of exposure
In the environment of pollution, central nervous system, liver, kidney and the septicemia of human body, usual symptom can be caused to be：Eyes, throat are not
It is suitable, feel from head to foot it is fervid, dizziness is tired, irritated etc..Wood-based plate, foam heat insulating material, plastic plate, oil used in interior decoration
Paint, coating, adhesive, wallpaper, carpet etc. all easy to produce TVOC.《Civil buildings contamination control specification》In, TVOC is
What room air was checked and accepted after being completed by cut-in house must survey project.
(4) limit value of Indoor Air Quality standards
According to GB/T18883-2002's《Indoor Air Quality standards》, total volatile organism TVOC (8 small hourly value)
Limit value is 0.60mg/m3。
5, radon gas
(1) physical property
Radon gas, it is colourless, odorless, tasteless.At standard temperature and pressure, radon gas is a kind of monoatomic gas, and density is
9.73kg/m3, about 8 times of sea level earth atmosphere density (1.217kg/m3).Radon gas is the highest rare gas of density,
It is one of highest gas of room temperature lower density.Although colourless at standard temperature and pressure, it be cooled to freezing point 202K with
It can shine because of radioactivity after lower, be reduced with temperature and gradually become Chinese red from yellow.After condensation, radon equally can be because of radiation
Property shine.
(2) source of radon gas in rear chamber is fitted up
Indoor radon gas is mainly derived from finishing granite used, brick sand and gypsum etc, especially contains radioactivity member
The lithotome of element is easiest to release radon gas.The horizontal height of radon gas depends primarily on the radioactive material of house foundation geologic structure
The influence of many factors such as the content height of radium and house leakproofness in matter content and construction material.
(3) to the harm of human body
Radon gas is the naturally radioactive inert gas generated by radium decay, it does not have color, is generation without any smell yet
One of the major environmental carcinogen object that boundary's health organization confirms is the second largest factor for causing lung cancer in addition to smoking.
(4) limit value of Indoor Air Quality standards
According to GB/T18883-2002's《Indoor Air Quality standards》, radon222Rn (annual mean) limit value is 400Bq/
m3。
6, other volatile harmful gases
There may be other harmful gases, such as nitrogen dioxide, sulfur dioxide for interior.
According to GB/T18883-2002's《Indoor Air Quality standards》, sulfur dioxide (1 hourly average value) limit value is
0.50mg/m3；Nitrogen dioxide (1 hourly average value) limit value is 0.24mg/m3。
(2) relationship of indoor decoration pollution and disease
Indoor decoration pollution seriously affects health, especially huge to Children Health Effect.China Association for Standardization
Investigation with Children in China health care disease prevention and cure instructing center is shown：The whole nation is every year because finishing pollution causes respiratory tract infection
And dead children are up to 2,100,000, the leukaemia caused by environmental quality, breathing problem, blood disease, fetal death, deformity
The incidence of the diseases such as youngster, skin disease is than 2% or more upper average annual growth rate.China increases 4~50,000 people of leukaemic newly every year,
About 50% is children.Counted according to certain hematology of children's hospital, in the leukemia children seen and treated patients, 90% family within half a year once
Through fitting up.Due to the deterioration of indoor environment, the lung cancer morbidity rate in China is more rapidly passed with annual 26.9% surprising speed
Increase ... the serious health of having encroached on of finishing pollution and even jeopardizes human life's safety, more seriously, dress
It is huge for the health effect of children to repair pollution, especially the finishing pollution that has occurred causes fetal anomaly, miscarriage at present, more
By the serious existence and procreation for influencing the mankind.Currently, finishing pollution has been put into endangers maximum five kinds of environment to the public
One of factor (falls the will skin of bamboo.Present situation and its legal cause analysis [J] of China's indoor decoration pollution, modern property, 2011,2：78-
81)。
Button spring a beautiful gem etc. research shows that：Family contacts most close, most frequent environment, all kinds of interior inhabitation rings as infant
There is certain influence (button spring a beautiful gem, Chunyan Luos and Wu Jingui etc. to infant's respiratory health for border and behavial factor.It is based on
The indoor living environment and behavial factor of questionnaire survey and the relationship [J] of infant's respiratory health.Environmental and occupational medicine,
2015,32 (9)：813-819).The researchs such as Jia Leina are drawn a conclusion, and the height of indoor formaldehyde concentration can make children asthma attack
It is dangerous increase, and there are dose-response relationships.(Jia Leina, cleer and peaceful Yang Sheng shows of fourth text etc..Formaldehyde Pollution of Indoor Air and children
The research [J] of asthma relationship.Scientific and technological information (clinical and medical treatment), 2012,35：436-437.)
Indoor decoration pollution has stimulation eyes, pharynx nasalis to the main influence of adult, leads to headache, dizzy, nausea, memory
Power decline etc., while asthma, pneumonia can be also induced, severe patient can lead to the disease in terms of nasopharyngeal carcinoma, lung cancer and blood, therefore
There is an urgent need to find the rapid and effective method for removing indoor pollution at present.
(3) method for commonly using removal interior decoration finishing pollution gas
1, plant null method
Indoor polluted gas is absorbed using flowers such as bracketplant, aloe, sansevieria trifasciatas.Plant carries out photosynthesis absorption two daytime
Carbonoxide discharges oxygen, but night absorbs oxygen, discharges carbon dioxide, unfavorable to human body, is especially easy to pollen, flowers
The effect of allergy sufferers, plant removes removing and harmful gas, is very limited, at most can only be as the supplementary means of Indoor Environment Treatment.Work as room
When interior air pollution is serious, the effect of plant purification is with regard to smaller.Improvement feature low, required time for removal polluted gas efficiency
Long, performance is unstable.
2, activated carbon adsorption
Activated carbon is a kind of porous carbon containing matter, it has highly developed pore structure, thus provides larger
Surface area, can be come into full contact with gas (impurity), to impart absorption property specific to activated carbon, make its be very easy to
Achieve the purpose that absorb and collects impurity.If but processing will be unable to not in time after activated carbon is to indoor polluted gas adsorption saturation
Normal use, if type discharge will cause secondary pollution indoors.Active carbon adsorption is the organic gas to evaporating naturally
With suction-operated, the organic solvent of pollution sources profound level can not be adsorbed.
Patent application CN103537167A discloses a kind of " pernicious gas vacuum adsorption machine ", including passes sequentially through pipeline company
Absorber, buffer and the vacuum pump group connect at.Filling filter and adsorbent inside the absorber, inside the buffer
Fill adsorbent, the adsorbent be magnesium and silicon chemical chelate, it is compound by the added multiple additives of natural mineral matter and
At being a kind of to realize the device that is adsorbed to the polluted gas to volatilize naturally in environment using high-efficiency adsorbent.But it is existing
Defect is that adsorbent equally will appear adsorption saturation, to cause the secondary pollution of pernicious gas；" absorption described in application simultaneously
Machine " is also to carry out Adsorption for the gas volatilized naturally in environment, still to the polluted gas of indoor pollution depth of origin level
It so cannot achieve efficient removal.
3, finishing pollution scavenger
Current miscellaneous formaldehyde scavenger is to remove formaldehyde, but in fact, first using method physically or chemically
Aldehyde scavenger can only temporary closure pollution sources, in a short time prevent formaldehyde volatilize, formaldehyde pollution can not be thoroughly removed at all, this
After layer protective film failure, formaldehyde still can largely release pollution room air；Some formaldehyde scavengers claim with formaldehyde to occur
Chemical reaction, but can only also be reacted with the formaldehyde evaporated naturally on pollution sources surface layer, it is dirty that profound formaldehyde can not be solved
Dye, if while formaldehyde scavenger react incomplete with formaldehyde, it is also possible to generate other noxious materials and cause secondary pollution.
4, air purifier
Air purifier price is more expensive, and is just decreased obviously using effect after some months, does not have effect finally.
And air purifier substantially carries out taste removal using activated carbon, goes mould, and air purifier can not solve enclosure space
Formaldehyde pollution, such as in cabinet, drawer.Simultaneously because air purifier mainly to the indoor polluted gas that volatilizes naturally into
Row purification can not carry out purified treatment to the gas of pollution sources profound level, thus equally can not fundamentally solve room air
Pollution.
Patent CN2808151Y discloses a kind of air purifier of removal finishing pollution, by will be polluted in room air
Gas be absorbed into air purifier and handled, to effectively remove the pollutants such as formaldehyde therein, ammonia, benzene homologues,
To achieve the purpose that purify air, since air purifier is just for the organic matter that has evaporated of interior, thus still without
Method fundamentally solves room air pollution.
5, nano-catalytic oxidizing process
Quantum effect caused by nano-photocatalyst makes it have unique physicochemical property, such as special optical property,
Larger specific surface area, stronger photocatalytic activity etc..The material applied in terms of air purification indoors at present is mainly nanometer
TiO2With nano-ZnO etc..
Photocatalyst is a kind of using Nano titanium dioxide as the total of the photosemiconductor material with photo-catalysis function of representative
Claim, it is coated on substrate surface, and under the action of illumination, photo-generated carrier moves to rapidly the surface of material, active material table
The oxygen and moisture of face absorption, generate the hydroxyl free radical and superoxide anion for having oxidability extremely strong, and oxidation reaction occurs, makes
Organic matter, bacterium, virus etc. are thoroughly decomposed into carbon dioxide and water.Since photocatalyst needs under the photocatalysis of specific wavelength
The ozone that catalysis reaction and reaction generate, which can occur, can have human body certain injury, while the grain size of photocatalyst material is in nanometer
Rank, the dust particles of generation are adsorbed on skin and mucous membrane and can equally can cause human body compared with major injury；Though in addition, photocatalyst
The concentration of indoor pernicious gas can be so reduced in a short time, but before polluted gas can be restored to after a certain period of time again
It is horizontal.Thus limit its application in terms of household pollution.
Patent CN101831207B discloses a kind of improvement finishing pollution all-weather nano photocatalyst product, in patent
The micropore of unglazed matchmaker's ingredient ceramic crystal there is extremely strong adsorption capacity, pollutant that can be in efficient absorption surrounding air, together
Shi Liyong photocatalysts are in the pollutant for having optical time division removal to be adsorbed.Such photocatalyst product is in addition to above-described limitation
Outside, simultaneously because this method is simply possible to use in the indoor organic compound evaporated, the deep layer of pollution sources can not be polluted
It is purged, therefore can not fundamentally reduce room air pollution.
6, other methods
Anion fine-purification generates anion using high voltage, by condensation and suction-operated, is adhered to solid phase or liquid phase is dirty
It contaminates on object particle, forms big particle and settle down.Anion in air can not only make with fresh air, moreover it is possible to have sterilization except different
The effect of taste, but the ion pair human body generated has larger harm.In addition there are the biological enzyme using biocatalytic reaction, ventilation
The combination etc. of ventilation and above-mentioned various methods, can not efficiently remove indoor polluted gas, some methods are also easy to band
Carry out secondary pollution.
To sum up, the method for commonly using removal indoor decoration pollution gas is for metope, furniture, floor, ceramic tile after finishing
It waits the pernicious gas that natures evaporate and carries out, be a kind of passive method for administering room air pollution, not from interior
The source of pollution is set out, fundamentally reduce source pollutant, thus using the above method processing after polluted gas residual still compared with
It is more；Further, since indoor fit-up harmful gas volatilizees naturally needs the long period, had using the corresponding device processing of the above method
Evil gas also needs for a long time, to which the injury caused by human body is also lasting.
Invention content
(1) present invention solves the technical problem that
1, it is the pernicious gas volatilized to Indoor Natural to administer indoor decoration pollution gas main target in the prior art
It is cleared up, is the passive improvement of room air pollution, reduce not from pollution source or fundamentally indoor decoration pollution
The concentration of gas；Most administering method (such as activated carbon adsorption, nano-catalytic oxidizing process and other in the prior art simultaneously
The method etc. chemically reacted) secondary pollution can be caused to room air；In addition the polluted gas that the prior art mainly uses
It is the principles such as absorption, nano-catalytic oxidation and anion fine-purification to administer principle, cannot achieve the efficient place to indoor polluted gas
Reason.So as to cause indoor harmful gas still can long-term existence, and persistently human body is damaged.Thus the prior art is administered indoor
There are larger defects for finishing pollution.
2, the defect of indoor decoration pollution is administered in view of the prior art." a kind of improvement of indoor decoration pollution is set the present invention
Standby and its application method ", from the source of indoor decoration pollution, (i.e. there may be the metope of polluted gas, furniture, floor, ceramic tiles
Deng) set out, boiling point reduction, the increased principle of volatility, use under negative pressure or vacuum state according to indoor decoration pollution gas
Locking device seals indoor decoration pollution source, and to finishing pollution gas, (polluted gas includes by way of reduced vacuum：First
Aldehyde, ammonia, benzene and substituted benzene, total volatile organic compounds, radon gas and other volatile harmful gases) it is administered；
Provide a kind of abatement equipment and its application method of indoor decoration pollution simultaneously.
Technique effect：
(1) polluted gas abatement equipment structure and principle of the present invention are novel；The technical solution is a kind of profit
With the low boiling point property of indoor decoration pollution gas, be removed using the method for depressurizing or vacuumizing, be a kind of principle it is novel,
The method of the improvement finishing pollution gas of high-efficiency environment friendly；
(2) compared with prior art, the present invention is not introduced into any chemical constituent during administering finishing pollution, will not
Secondary pollution is caused to room air.
(3) technical scheme of the present invention realizes the active efficient process of indoor decoration pollution gas, overcomes existing skill
The passive improvement defect of indoor decoration pollution, realizes the target of active process indoor decoration pollution in art.
To sum up, compared with the existing technology, technical solution of the present invention has significant advantage.
(2) technical solution
Technical solution of the present invention is as follows：
A kind of indoor decoration pollution master gas equipment, it is characterised in that：By vacuum pump, the sealing dress with bleeding point
It sets, the attachment device composition between the bleeding point on vacuum pump and sealing device.
Vacuum pump and sealing device are connected by attachment device, to realize that vacuum pump subtracts sealing device
Press vacuum suction.The bleeding point of sealing device can be arranged as required to one or more bleeding points.
Wherein the vacuum pump refers to using machinery, physics, chemically or physically chemical method to being carried out by pumping container
It is evacuated and obtains the device or equipment of vacuum.Vacuum pump used in the present invention include dry screw vacuum pump, water ring pump, reciprocating pump,
Slide valve pump, sliding vane rotary pump, lobe pump and diffusion pump etc..
Wherein the indoor decoration pollution refers to harmful gas componant, including：The homology of formaldehyde, benzene and benzene
It is one or more in object, ammonia, radon gas, total volatile organic compounds and other volatile harmful gases.Volatile harmful
Gas refers to the volatile organic compound in harmful interior.
Wherein the sealing device refers to the device for being sealed indoor pollution source, this device includes two kinds of realization sides
Formula：One is indoor pollution source can be carried out to integral sealing, another kind is that a closed system can be collectively formed with indoor pollution source
System.
The wherein described indoor pollution source includes the one or more of metope, furniture, floor, ceramic tile after interior decoration etc..
Wherein furniture includes other interiors such as bed, mattress, wardrobe, bookcase, computer desk, carpet, office furniture, laboratory related experiment platform
It is volatilizable go out polluted gas facility.In furniture, floor, the ceramic tile etc. of each furniture manufacturer's production are also included within simultaneously.
For the dismountable furniture of pollution sources small volume or uninstalled floor or ceramic tile etc., sealing device may be used
Including its whole environmental sealing；For the larger non-detachable furniture of pollution volume source, metope, mounted floor or ceramic tile
Deng sealing device can be used and form closed system together.
The control damper communicated with outside air can be further installed on the wherein described sealing device.Adjust air-flow control
Air can be flowed into sealing device by valve processed.
Heating element can be further carried on the wherein described sealing device.The main purpose of installation heating element is to improve
Temperature inside sealing device makes finishing pollution gas be easier to volatilize.Heating element can be heating wire or circulator bath, electricity
Heated filament can be distributed in any position inside sealing device, or be lining in the inner shell sections of sealing device；Circulator bath refers to certain
At a temperature of recirculated water to sealing device inside heat.
The material for preparing of " sealing device " of the present invention is the material not deformed in vacuum and/or generation
The material moderately deformed, material can be organic synthesis object, natural organic matter, metal or glass, and wherein organic synthesis object can make
With polyester, polyethers, polypropylene, polyethylene, polyvinyl chloride, polyether sulfone, polyvinylidene fluoride acid, polyurethane, polyamide, rubber and silica gel
Deng one or more be made, natural organic matter is made of using natural organic matters such as natural rubbers, and metal material includes stainless
Material made of the materials such as steel, iron, aluminium, titanium, lithium or mixed metal；The shape of " sealing device " can be according to sealing pollution sources
Shape is changed, and can be any geometry；" sealing device " similar " bag when integral sealing is carried out to finishing pollution source
Shape " structure, due to needing to carry out vacuum suction, " sealing device " shell used in the present invention is indeformable and/or with suitable
The structure of deformability is spent, such as certain thickness is lined with using shell, inside made of the mixed materials such as polypropylene and polyethylene
Using trepanning gas permeable material made of polyurethane or plant fiber etc., protect pollution sources not to be damaged while realizing vacuum suction
The proper flow of gas in middle sealing device；" sealing device " that closed system is formed with finishing pollution source is similar to sucker knot
Structure, sucker structure equally has certain degree of hardness, such as corresponding knot is made with the usage ratio of polyethylene by adjusting polypropylene
Structure realizes the improvement to pernicious gas to form closed system with pollution sources；In addition, since pollution sources sometimes do not advise by shape
Then, then " sealing device " can accordingly be changed according to the concrete condition of pollution sources, to reach the sealing to pollution sources, be reached
Vacuum decompression removes the purpose of pernicious gas." sealing device " is divided into " detachable " and " non-dismountable (fixation) " two kinds of structure,
I.e. " detachable " structure refers to sealing device can carry out assembling splicing to be sealed to it according to the concrete shape of pollution sources；" no
Detachably (fixation) " structure refers to that sealing device is sealed pollution sources in the form of fixed structure, and such situation is basis
The structure of sealing device come determine can to those pollution sources carry out pernicious gas removal.The connection closing section of " sealing device "
The materials such as natural rubber, silicon rubber, nitrile rubber, Viton, polypropylene, polyethylene can be used to be sealed.
The attachment device between bleeding point on the wherein described vacuum pump and sealing device refers to can be by vacuum pump and close
Seal apparatus is attached the component of ventilation.Attachment device is divided into softwood matter and hard material, and it can be polyethylene, polychlorostyrene second to prepare material
Alkene, polyether sulfone, Kynoar, polypropylene, metal, glass and silica gel etc. can ensure the positive normal open of the air-flow when vacuumizing
It crosses, wherein it is preferred that silicone tube and polyvinyl chloride pipe.
Wherein described attachment device overdraught by position can control damper be further installed and adjust air-flow.This
The control damper function at place is consistent with vacuum breaker, is for controlling the big of air flow between vacuum pump and sealing device
It is small, to control the vacuum degree of sealing device.
Gas-filtering device can be further installed between the wherein described vacuum pump and the bleeding point of sealing device.Gas is installed
The position of body filter device can in attachment device, between vacuum pump and attachment device or attachment device and bleeding point it
Between；Gas-filtering device herein mainly removes various dust, filter device caused by finishing pollution source in sealing device
Aperture can be 1 micron, 0.8 micron, 0.45 micron, 0.22 micron etc., material can be polyethylene, polyvinyl chloride, polyether sulfone,
Kynoar and polypropylene etc..
The wherein described indoor decoration pollution master gas equipment can further install pressure vacuum gauge on sealing device.
By this pressure vacuum gauge, the vacuum pressure situation in sealing device can be monitored in real time.
The wherein described indoor decoration pollution master gas equipment can further install temperature control dress on sealing device
It sets.Temperature control equipment includes temperature indicator and temperature-adjusting device, and the reality in device can be observed by temperature indicator
By temperature-adjusting device control can be adjusted to the temperature in sealing device in Shi Wendu.
The method for administering indoor pollution using indoor decoration pollution master gas equipment of the present invention, it is characterized in that：
(1) indoor objects pollution sources are sealed using the sealing device with bleeding point；
(2) bleeding point on vacuum pump and sealing device is attached by attachment device；
(3) vacuum pump is opened, to being vacuumized in sealing device；
(4) indoor decoration pollution after treatment closes vacuum pump.
The wherein described indoor objects pollution sources include one kind or several of metope, furniture, floor, ceramic tile after interior decoration etc.
Kind.Wherein furniture includes that bed, mattress, wardrobe, bookcase, computer desk, carpet, office furniture, laboratory related experiment platform etc. are other
It is indoor it is volatilizable go out polluted gas facility.Furniture, floor, the ceramic tile etc. of each furniture manufacturer's production are also included within simultaneously
It is interior.
The method polluted in the wherein described process chamber, in process chamber in pollution course, relative vacuum inside sealing device
Ranging from zero Mpa to -0.1Mpa is spent, zero Mpa is not included；It is further defined to -0.04Mpa to -0.1Mpa；Further limit
For -0.07Mpa to -0.1Mpa.Relative degree of vacuum in the method sealing device of processing indoor pollution of the present invention is free of
Zero Mpa, but include -0.1Mpa, -0.04Mpa and -0.07Mpa.
The method polluted in the wherein described process chamber is in one during handling indoor pollution inside sealing device
At fixed temperature.Sealing device internal temperature range be room temperature to 200 DEG C, be further defined to room temperature to 100 DEG C, further
Room temperature can be limited to 60 DEG C, be further limited to room temperature to 45 DEG C." room temperature " as defined in herein refers to the temperature of indoor environment
Degree refers to without the environment temperature under any extraneous heating or refrigeration, when being more than 200 DEG C inside sealing device in room
Pollution sources occur the risk of damage.
In confined space, under the conditions of uniform pressure, temperature increases, and gas is more volatile, thus described close by changing
Temperature inside seal apparatus improves the volatility of finishing pollution gas, to further increase the effect for administering indoor decoration pollution
Rate.
The method polluted in the wherein described process chamber, during handling indoor pollution, when vacuum degree is higher, gas
Flowing velocity slows down, and can promote gas in sealing device by suitably opening and closing the control damper on sealing device
Flowing, accelerate pollutant volatilization removal.
During above-mentioned processing indoor pollution, the exhaust outlet of vacuum pump can also connect an exhaust pipe and discharge it spy
Determine in adsorbent equipment or outdoor.It when the concentration of polluted gas is larger, is adsorbed using adsorbent equipment, adsorbent equipment includes dress
The adsorbent equipment of active charcoal and adsorbent equipment etc. equipped with activated carbon fibre；When the concentration of polluted gas is smaller, decompression is true
When indoor decoration pollution is managed in vacancy, the concentration and mass rate of emission of polluted gas are smaller, meet atmosphere pollution comprehensive discharge mark
When accurate (GB16297-1996), exhaust pipe can be connected and be discharged in outdoor air.
" (4) indoor decoration pollution after treatment closes vacuum pump " described in the method for indoor pollution is handled, it is " indoor
Finishing pollution after treatment " refers to that processing method according to the invention is handled the pernicious gas of pollution sources using the predetermined time
Afterwards, processing time can be adjusted according to the initial concentration in finishing pollution source.
(3) advantageous effect
(1) the various principles of removal indoor decoration pollution gas are different from the prior art --- i.e. absorption, nano-catalytic oxygen
Change and principles, the principles of technical solution of the present invention such as anion fine-purification be the low boiling point property according to indoor decoration pollution gas,
Indoor decoration pollution source is sealed using sealing device, polluted gas is efficiently gone using the method for decompression vacuum pumping
It removes, any other chemical constituent is not introduced into entire processing procedure.Compared with the existing technology, technical solution of the present invention has work
The advantages that principle is novel, pollution control is with clearly defined objective, polluted gas processing is efficient, at the same it is new without introducing in finishing pollution improvement
Chemical constituent, the secondary pollution caused by without to room air is a kind of indoor pollution administering method of environmental protection.
(2) it is different from the prior art and only the finishing pollution gas that Indoor Natural evaporates is handled, it is of the invention
Technical solution from the source of indoor decoration pollution gas, to metope, furniture, floor, ceramic tile for generating polluted gas etc. into
Row sealing handles polluted gas using the method for decompression vacuum pumping, realizes the active to indoor decoration pollution gas and efficiently locate
Reason, overcomes the passive improvement defect of indoor decoration pollution in the prior art.
(3) being different from prior art processing, indoor decoration pollution gases cycle is long, efficiency is low, and technical solution of the present invention is from room
The source of interior decoration pollution is set out, and is removed polluted gas using decompression vacuum pumping, in addition can also be passed through raising on this basis
Temperature inside sealing device improves the temperature in finishing pollution source, to more effectively promoting gas in indoor decoration pollution source
Rate of volatilization, shorten polluted gas and administer the time, hence it is evident that improve the efficiency of removal indoor decoration pollution gas, i.e. this hair
It is short, efficient that Mingzhi manages indoor decoration pollution gas time.
(4) technical scheme of the present invention provides a kind of indoor decoration pollution master gas equipment and its application method, has
Effect solves in place of the deficiencies in the prior art.
To sum up, technical solutions according to the invention have significant progress compared with the existing technology.
Description of the drawings：
Fig. 1：The indoor decoration pollution master gas equipment connection diagram of the present invention；
(1) it is vacuum pump, (2) are attachment device, and (3) are bleeding point, and (4) are sealing device.
Fig. 2：The indoor decoration pollution master gas equipment of the present invention improves schematic diagram；
(1) it is vacuum pump, (2) are attachment device, and (3) are bleeding point, and (4) are sealing device, and (5) are on sealing device
Control damper, (6) are attachment device overdraught control valve, and (7) are heating element, and (8) pressure vacuum gauge, (9) are temperature control
Device processed.
Fig. 3：The indoor decoration pollution master gas equipment of the present invention improves schematic diagram；
(1) it is vacuum pump, (2) are attachment device, and (3) are bleeding point, and (4) are sealing device, and (5) are on sealing device
Control damper, (6) are attachment device overdraught control valve, and (7) are heating element, and (8) pressure vacuum gauge, (9) are temperature control
Device processed, (10) are gas-filtering device.
Fig. 4：The indoor decoration pollution master gas equipment of the present invention improves schematic diagram；
(1) it is vacuum pump, (2) are attachment device, and (3) are bleeding point, and (4) are sealing device, and (5) are on sealing device
Control damper, (6) are attachment device overdraught control valve.
Fig. 5：The indoor decoration pollution master gas equipment of the present invention improves schematic diagram；
(1) it is vacuum pump, (2) are attachment device, and (3) are bleeding point, and (4) are sealing device, and (5) are heating element.
Fig. 6：The indoor decoration pollution master gas equipment of the present invention improves schematic diagram；
(1) it is vacuum pump, (2) are attachment device, and (3) are bleeding point, and (4) are sealing device, and (5) are control damper,
(6) it is heating element.
Explanation：The indoor decoration pollution master gas equipment for being included by the claims in the present invention improve schematic diagram have it is more
Kind, it illustrates and only illustrates to part therein herein.
Specific implementation mode：
Embodiment 1：Compare the method for the present invention and improvement of the nano-catalytic oxidizing process to formaldehyde gas in same size wardrobe
Effect
(1) pollution sources：Wardrobe, wardrobe size are：Long 1000mm, wide 600mm, high 1700mm.
(2) assay method of formaldehyde：According to GB/T 18204.2-2014《Public places sanitary method of inspection part 2：
Chemical pollutant》In 7.3 formaldehyde detection method-gas chromatography.
Sample mode：It is acquired using activated carbon tube in wardrobe, is then extracted with carbon disulfide；Sampling quantity is 20L,
It is extracted with 1mL carbon disulfide.
(3) concrete operations：
1. the method for the present invention
A is assembled
Using the sealing device with bleeding point by wardrobe package and integral sealing, by bleeding point and silicone tube (as even
Connection device) connection, the other end of silicone tube and the rotary-vane vaccum pump (model outside holding chamber：2XZ-4) connect；Abatement equipment
Connection type is shown in attached drawing 1.After connection, power on, open vacuum pump, checks whether sealing device has direct gas leakage
Point, if no leak source preparation finishes.Polluted gas abatement equipment schematic diagram is shown in attached drawing 1.
B formaldehyde is administered
With reference to GB/T 18204.2-2014《Public places sanitary method of inspection part 2：Chemical pollutant》In 7.3 first
Detection method-gas chromatography of aldehyde is sampled detection to formaldehyde gas in wardrobe, and the initial concentration of formaldehyde is 0.82mg/
m3.Vacuum pump is opened, wardrobe is vacuumized, persistently vacuumizes 3 hours (without heating device, Indoor Temperature in sealing device
Degree meter is shown as 25.0 DEG C), according to 7.3 Analysis Methods for Formaldehyde in GB/T 18204.2-2014 to the gas in wardrobe after 3 hours
Immediately it is sampled, measures the formaldehyde amount after administering, concentration of formaldehyde in wardrobe is detected after continuing at 10 days and 2 months.Measure knot
Fruit see the table below 1.
2. nano-catalytic oxidizing process
Product is purified using the photocatalyst taste removal of certain producer available on the market production, according to operating instruction to identical size
Another wardrobe (initial concentration that formaldehyde is measured using gas chromatography in GB/T 18204.2-2014) carry out at spraying
Reason is sampled and measures concentration of formaldehyde after 3 hours according to gas in 7.3 pairs of wardrobes in GB/T 18204.2-2014, measures
As a result it see the table below, since effect after needing light reaction for a period of time after photocatalyst processing could be more preferable, respectively at 10 days and 2
Assay is carried out in the same way to the formaldehyde in wardrobe after a month, measurement result is shown in Table 1.
(4) measurement result：
The present invention and the content of formaldehyde result after nano-catalytic oxidative treatment under 1 different time of table
| Detection time | The method of the present invention-content of formaldehyde (mg/m3) | Nano-catalytic oxidizing process-content of formaldehyde (mg/m3) |
| 0 hour | 0.82 | 0.80 |
| After processing terminates 3 hours | 0.07 | 0.71 |
| 10 days | 0.05 | 0.54 |
| 2 months | 0.06 | 0.73 |
Explanation：(1) " after processing terminates 3 hours " sampling refer to by wardrobe close 3 hours post-samplings；(2) when above-mentioned each
Between the sampling quantity put and measuring carry out under the same conditions.
From list data it is found that administering method using the present invention, the content of formaldehyde drops after 3 hours after treatment in wardrobe
For 0.07mg/m3, 0.06mg/m is down to after 2 months3Range；And photocatalyst product treated wardrobe, the content of formaldehyde 3 hours
It slowly reduces afterwards, reached lower 0.54mg/m at 10 days3, rebounded again to 0.73mg/m after 2 months3。
Comparative analysis：3 months concentration of formaldehyde are 0.06mg/m after the method for the present invention processing3, at nano-catalytic oxidizing process
3 months concentration of formaldehyde are 0.73mg/m after reason3, the method for the invention is with respect to nano-catalytic oxidizing process in terms of removing formaldehyde
With apparent advantage；The concentration of formaldehyde has had reached 0.07mg/m after the method for the present invention processing terminates 3 hours3, processing effect
Rate is substantially better than nano-catalytic oxidizing process；Polluted gas administering method does not bring new chemical substance into the present invention indoors, not
Cause secondary pollution；The present invention administers pernicious gas from pollution source, is a kind of indoor decoration pollution improvement side of active
Method, opposite nano-catalytic oxidizing process have significant advantage.
Embodiment 2：Using the method for the invention with commonly use four kinds of finishing pollution processing methods to benzene in wardrobe, toluene,
Dimethylbenzene is handled and is compared.
(1) pollution sources：The wardrobe crossed using paint spraying, wardrobe size are：High 1900mm, deep 570mm, wide 850mm.
(2) assay method of benzene, toluene and dimethylbenzene：According to benzene,toluene,xylene in the air of the residential areas GB11737-89
Health test method --- gas chromatography.
Sampling mode：It is acquired using activated carbon tube in wardrobe, is then extracted with carbon disulfide；Sampling quantity is 20L,
It is extracted with 1mL carbon disulfide.
(3) sweep-out method of the invention refers to method of the present invention；" commonly use four kinds of methods " include plant null method,
Active carbon adsorption, anion fine-purification method and nano-catalytic oxidizing process.
(4) concrete operations of each method：
1. the method for the present invention：
Assembling：Using the sealing device with bleeding point by wardrobe package and integral sealing, bleeding point and silicone tube (are made
For attachment device) connection, the other end and the rotary-vane vaccum pump (model of silicone tube：It 2XZ-4) connects, vacuum pump gas outlet is used poly-
Four fluorine tube is connected to open air；Control damper, attachment device overdraught control valve on sealing device, heating element, vacuum pressure
The connection type of power table and temperature control equipment is shown in attached drawing 2.After connection, power on, opens vacuum pump, check vacuum pressure
Whether power table look-up has direct air leakage point, if no leak source preparation finishes.Polluted gas abatement equipment schematic diagram is shown in attached
Fig. 2.
Concrete operations：Measure the initial concentration of benzene,toluene,xylene in wardrobe.The temperature of set temperature controller is 80
DEG C, after temperature reaches predetermined temperature, open vacuum pump；Open attachment device on control damper, vacuum pump just with wardrobe
Part connection ventilation；After steady air current, vacuum meter is shown as -0.095Mpa (being herein relative degree of vacuum), and continuous vacuum is taken out
Gas 3 hours, about at 2 hours it is intermittent open sealing device on control damper, flowed into device a small amount of gas from
And be easier to volatilize by benzene and benzene homologues, the control damper on sealing device is closed after ten minutes；Vacuum suction is disposed
Afterwards, the control damper in attachment device is closed, vacuum pump is closed, slowly unscrews the control damper on sealing device, it will be close
Seal apparatus restores to normal pressure and temperature, and the concentration of the benzene,toluene,xylene in wardrobe is measured by sampling.Equally divide after single treatment
Not after 3 hours, the 10th day and after 2 months be measured by sampling wardrobe in benzene,toluene,xylene concentration.Changed according to measurement result
Variable sampling volume, to the benzene of Accurate Determining various concentration and the concentration of benzene homologues.
Measurement result is shown in Table 2.
2. plant null method
Bracketplant, aloe, sansevieria trifasciata respectively put 5 basins in the room for placing wardrobe, ensure plant normal growth in 2 months.
Respectively at 0 hour, plant absorption pernicious gas 3 hours, and after 3 hours (with 3 hours of the present invention after sampling time point phase
Together), the 10 days and 2 months concentration for measuring benzene, toluene and dimethylbenzene, measurement result are shown in Table 2.
3. active carbon adsorption
The activated carbon charcoal for the 80g that the packing specification that 5 bags of 20-60 mesh are placed in wardrobe is 350mm × 200mm × 200mm
Packet, 2 months standing times are exposed to the sun 5~6 hours after 1st month after use and reuse.Respectively at 0 hour, using activated carbon
Absorption 3 hours, and (identical as sampling time point after 3 hours of the present invention), 10 days and 2 months measurement benzene, toluene after 3 hours
With the concentration of dimethylbenzene, measurement result is shown in Table 2.
4. anion fine-purification method
The purification efficiency of negative ion air-cleaner is 480m per hour3；The daily available machine time is 8 hours, and room is big
Small is 20m2, wardrobe indoors place by unlimited cabinet door.Continuous use handled 3 in 2 months respectively at 0 hour using air purifier
Hour, and (identical as the sampling time point after 3 hours of the invention), 10 days and 2 months measurement benzene, toluene, diformazans after 3 hours
The content of benzene, measurement result are shown in Table 2.
5. nano-catalytic oxidizing process
Measurement is sampled to the concentration of initial benzene and benzene homologues in wardrobe, using photocatalyst taste removal available on the market
Product is purified, spray treatment is carried out to wardrobe according to operating instruction.Respectively at 0 hour, single treatment it is complete after 3 hours, 10 days and 2
Referring to shown in (2), measurement result is shown in Table 2 for a month content for measuring benzene, toluene and dimethylbenzene, assay method and sampling.
Concentration (the mg/m of the different finishing pollution administering methods of table 2 benzene in different time points, toluene and dimethylbenzene3)
Explanation：(1) the above benzene, toluene and dimethylbenzene refer to concentration, and unit is mg/m3.(2) sampling is identical
Time, under the conditions of temperature and humidity；(3)) after " processing terminates 3 hours " sampling refer to by wardrobe close 3 hours post-samplings.
From list data it is found that using aforementioned present invention administering method, the concentration of benzene is reduced to 0.07mg/m after 3 hours3,
The concentration of toluene is reduced to 0.05mg/m3, the concentration of dimethylbenzene is reduced to 0.06mg/m3, have reached GB/T18883-2002's
《Indoor Air Quality standards》Requirement；Although the initial concentration of benzene, toluene and dimethylbenzene is close in wardrobe, other four are used
The concentration of kind administering method benzene is in 8.21mg/m3More than, the concentration of toluene is in 7.14mg/m3More than, the concentration of dimethylbenzene exists
7.09mg/m3More than, hence it is evident that it is higher than the requirement of national standard.In being handled using other four kinds of methods, anion purifier is kept
Unlatching is best to the regulation effect of benzene, toluene and dimethylbenzene daily, is secondly the nano-catalytic oxidizing process of single treatment, activated carbon
Absorption method also has certain effect, plant absorption method relatively poor.
Comparative analysis：From the above experiment it is found that other four kinds of methods in addition to the present invention are to be directed in air to have distributed
Benzene, toluene and the diformazan benzene gas gone out is handled, and is a kind of passive processing mode, is not reduced pernicious gas from the root cause；
And the present invention is from pollution sources source, using benzene and the low-boiling property of benzene homologues, in such a way that heating vacuumizes, compared with
The concentration of polluted gas is effectively reduced in short time, thus the present invention relatively other four kinds of processing method times are short, efficient.
Any chemical substance is not introduced into the improvement of indoor polluted gas of the present invention, because without to indoor generation secondary pollution, thus
It is a kind of administering method of environment-friendly high-efficiency.
Embodiment 3：Using the method for the invention and other common four kinds of finishing pollution administering methods (plant null method,
Active carbon adsorption, anion fine-purification method and nano-catalytic oxidizing process) treatment effect of formaldehyde in carpet and TVOC is compared.
(1) pollution sources：The identical carpet of certain producer three, size are：It is 2.3 meters long, 1.6 meters of money, weight 8.5kg.
(2) assay method of formaldehyde：GB/T 18204.2-2014《Public places sanitary method of inspection part 2：Chemistry
Pollutant》In 7.3 formaldehyde detection method-gas chromatography.Sampling quantity is 20L, is extracted with 1mL carbon disulfide.
The assay method of total volatile organic compounds TVOC：Using GB 50325-2010 (2013 editions) civil buildings work
Journey indoor environmental pollution controls in specification the measurement of total volatile organic compounds (TVOC) in room air in annex G.Sampling
Amount is 10L.
(3) administering method of formaldehyde and TVOC have in carpet：The method of the invention, plant null method, activated carbon adsorption
Method, anion fine-purification method and nano-catalytic oxidizing process.
(4) concrete operations of each method：
1. the method for the present invention：
Assembling：Using the sealing device with bleeding point by carpet package and integral sealing, bleeding point and silicone tube (are made
For attachment device) connection, the other end and the rotary-vane vaccum pump (model of silicone tube：It 2XZ-4) connects, vacuum pump gas outlet silicon
Sebific duct is connected to open air；Control damper, attachment device overdraught control valve, heating element, vacuum pressure on sealing device
Table, temperature control equipment and gas-filtering device connection type are shown in attached drawing 3.After connection, power on, open vacuum pump,
Check that pressure vacuum gauge checks whether there is direct air leakage point, if no leak source preparation finishes.Polluted gas abatement equipment
Schematic diagram is shown in attached drawing 3.
Concrete operations：Measure the initial concentration of formaldehyde and total volatile organism TVOC in carpet.Set temperature controller
Temperature be 60 DEG C, after temperature reaches predetermined temperature, open vacuum pump；Open the control damper in attachment device, vacuum
Pump just connect ventilation with wardrobe part；After steady air current, vacuum meter is shown as -0.1Mpa (being herein relative degree of vacuum), holds
Continuous vacuum suction 4 hours, the about intermittent control damper opened on sealing device at 2.5 hours, flow into few into device
Gas is measured to which volatile organic gases to be easier to volatilize, closes the control damper on sealing device after ten minutes；Vacuum
After pumping process, the control damper in attachment device is closed, closes vacuum pump, slowly unscrews the air-flow on sealing device
Sealing device is restored to normal pressure and temperature, the concentration of formaldehyde and TVOC in carpet is measured by sampling by control valve.It is same after single treatment
Sample after 4 hours, the 10th day and after 2 months be measured by sampling carpet in interior formaldehyde and TVOC concentration.
Measurement result is shown in Table 3.
2. plant null method
Bracketplant, aloe, sansevieria trifasciata respectively put 5 basins in the room for placing carpet, ensure plant normal growth in 2 months.
Respectively at 0 hour, plant absorption pernicious gas 4 hours, and after 4 hours (with the sampling time point phase after the present invention 4 hours
Together), the 10 days and 2 months concentration for measuring formaldehyde and TVOC, measurement result are shown in Table 3.
3. active carbon adsorption
The activated carbon for the 80g that the middle packing specification for placing 5 bags of 20-60 mesh is 350mm × 200mm × 200mm on carpet
Charcoal bag, 2 months standing times are exposed to the sun 5~6 hours after use after 1st month.Respectively at 0 hour, activated carbon adsorption 4 hours,
And (identical as the sampling time point after the present invention 4 hours), 10 days and 2 months measure the concentration of formaldehyde and TVOC after 4 hours,
Measurement result is shown in Table 3.
4. anion fine-purification method
The air quantity of negative ion air-cleaner is 500m3/ h, purification efficiency are 480m per hour3；The daily available machine time is
8 hours, room-size 10m2, wardrobe indoors place by unlimited cabinet door.Continuous use 2 months was respectively at 0 hour, air purification
Device is run 4 hours, and (identical as the sampling time point after 4 hours of the invention), 10 days and 2 months measurement formaldehyde after 4 hours
With the content of TVOC, measurement result is shown in Table 3.
5. nano-catalytic oxidizing process
Measurement is sampled to the concentration of initial formaldehyde and TVOC in carpet, using photocatalyst taste removal available on the market
Product is purified, spray treatment is carried out to carpet according to operating instruction.Respectively at 0 hour, after complete 4 hours of single treatment, 10 days and 2
A month content for measuring formaldehyde and TVOC, measurement result are shown in Table 3.
The different finishing pollution administering methods of table 3 formaldehyde in different time points and TVOC measured values (mg/m3)
Explanation：1. " TVOC " is total volatile organism, formaldehyde and TVOC concentration units are mg/m3.2. pollution processing 4
Concentration mensuration is all made of identical sampling and measuring method after hour；3. the above measuring point probe temperature and humidity all same；4. " place
Reason terminate 4 hours after " sampling refer to by carpet close 4 hours post-samplings.
From list data it is found that using aforementioned present invention administering method, the concentration of formaldehyde is reduced to 0.05mg/ after 4 hours
m3, the concentration of TVOC is reduced to 0.11mg/m3, have reached GB/T18883-2002's《Indoor Air Quality standards》Requirement；
But using other four kinds of administering methods treated formaldehyde and TVOC concentration comparables, formaldehyde is in 0.59mg/m3More than, TVOC is equal
In 8.16mg/m3More than, hence it is evident that it is higher than the requirement of national standard.According to the measurement result after 2 months, using other four kinds of methods
In processing, anion purifier keeps unlatching daily best to the regulation effect of benzene, toluene and dimethylbenzene, is secondly single treatment
Nano-catalytic oxidizing process, active carbon adsorption also has certain effect, plant absorption method relatively poor.
Comparative analysis：From data above it is found that other four kinds of methods in addition to the present invention are to be directed in carpet to have distributed
The formaldehyde and TVOC gases gone out is handled, and is a kind of passive processing mode, is not reduced pernicious gas from the root cause；And this hair
It is bright from pollution source, using formaldehyde and the low-boiling properties of TVOC, in such a way that heating vacuumizes, within a short period of time
The concentration of polluted gas is effectively reduced, thus the present invention relatively other four kinds of processing method times are short, efficient.Room of the present invention
It is not introduced into any chemical substance in the improvement of interior polluted gas, because without to indoor generation secondary pollution, thus is a kind of ring
Protect efficient administering method.
Embodiment 4：The method of the invention gives out desk with using activated carbon by the air purifier of adsorbing base
The removal effect of ammonia compares.
(1) pollution sources：Desk, size are：It is 1.40 meters long, it is 0.85 meter wide, it is 0.75 meter high；Left and right respectively have it is 0.60 meter high,
It is 0.35 meter wide, long 0.40 meter of chest.
(2) assay method of ammonia：HJ 534-2009《Measurement sodium hypochlorite-salicylic acid spectrophotometric of surrounding air ammonia
Method》.
The probe tube side of being placed on is sampled, absorbing liquid total volume is 10ml, and the flow of sampler is 1.0L/
The flow of min, sampling volume 4L.
(3) in desk ammonia administering method：The method of the invention, using activated carbon as the air purification of adsorbing base
Device.
(4) concrete operations of each method：
1. the method for the present invention：
Assembling：Using the sealing device with bleeding point by desk package and integral sealing, bleeding point and silicone tube (are made
For attachment device) connection, the other end and the rotary-vane vaccum pump (model of silicone tube：It 2XZ-4) connects, vacuum pump gas outlet silicon
Sebific duct is connected to open air；The connection type of control damper and attachment device overdraught control valve on sealing device is shown in attached drawing 4.
After connection, power on, open vacuum pump, check whether sealing device has direct air leakage point, if preparing without leak source
Work finishes.Polluted gas abatement equipment schematic diagram is shown in attached drawing 4.
Concrete operations：Measure the initial concentration of ammonia above desk.Vacuum pump is opened, the air-flow control in attachment device is opened
Valve processed, vacuum pump just connect ventilation with wardrobe part；After steady air current, continuous vacuum is evacuated 4 hours, and (nothing adds in sealing device
Thermal, indoor temperature meter are shown as 28.5 DEG C), about at 3 hours it is intermittent open sealing device on control damper,
A small amount of gas is flowed into device to which volatile organic gases to be easier to volatilize, and closes the gas on sealing device after ten minutes
Flow control valve；After vacuum suction is disposed, the control damper in attachment device is closed, vacuum pump is closed, slowly unscrews close
Control damper on seal apparatus restores sealing device to normal, the concentration of ammonia above sampling and measuring desk.After single treatment
Equally after 4 hours, the 10th day and after 1 month above desk be measured by sampling ammonia concentration.
Measurement result is shown in Table 4.
2. using activated carbon as the air purifier of adsorbing base
Air purifier is positioned over to position of 2~3 meters from desk, is opened 8 hours daily, before unlatching, air
Clarifier run 4 hours, and after 4 hours, the 10th day and after 1 month above desk be measured by sampling ammonia concentration.It measures
It the results are shown in Table 4.
The ammonia measured value of the different finishing pollution administering methods of table 4 in different time points
| Sample time | Measurement project | The method of the invention | Air purifier |
| 0 hour | Ammonia concentration (mg/m3) | 0.82 | 0.82 |
| 4 hours | Ammonia concentration (mg/m3) | 0.15 | 0.75 |
| 10 days | Ammonia concentration (mg/m3) | 0.12 | 0.54 |
| 1 month | Ammonia concentration (mg/m3) | 0.08 | 0.32 |
Explanation：(1) sample mode, sample interval and the condition all same of sample after distinct methods are handled；(2) " place
Reason terminate 4 hours after " sampling refer to by desk close 4 hours post-samplings.
From data above it is found that using ammonia after the method for the invention 4 hours a concentration of 0.14mg/m3, after 1 month
A concentration of 0.08mg/m3；And use activated carbon for the processing of the air purifier 4 hours of adsorbent after ammonia it is a concentration of
0.75mg/m3, it is 0.32mg/m after 1 month3。
It is found that the method for the invention relative atmospheric clarifier has in terms of removing ammonia, the time is short, imitates for comparative analysis
The high advantage of rate, what air purifier can only be passive handle existing ammonia in air, and the present invention is from pollution source
It sets out, using the low boiling point property of ammonia, by the way of vacuumizing, reduces the concentration of polluted gas within a short period of time；
In addition, be not introduced into any chemical substance in the improvement of indoor polluted gas of the present invention, because without to indoor generation secondary pollution,
It is a kind of administering method of environment-friendly high-efficiency.
Embodiment 5：The improvement of radon gas is carried out to kitchen wall surface ground using device and method of the present invention
The method for administering finishing pollution in the prior art is relatively low to the elimination efficiency of radon gas, the general side using windowing ventilation
Formula is purged, and method using the present invention using the kitchen wall surface and ground of marble finishing to having carried out the improvement of radon gas.
(1) pollution sources：The kitchen fitted up using natural marble, marble area are 8 square meters.
(2) assay method of radon gas：Using GBZ/T 155-2002《The scintillation vial assay method of Air Radon Concentration》, take
The method of quadrat method according to national standards is sampled by professional.
(3) radon gas is administered
Assembling：Closed system is collectively formed with kitchen surface using the sealing device with bleeding point of rectangle " sucked type "
System, while sealing system is formed using identical sealing device and metope, by respective bleeding point respectively with vacuum pump (model：
2XZ-4 rotary-vane vaccum pumps) it is connected, vacuum pump gas outlet is connected to open air with plastic tube；Gas flow optimized on sealing device
Valve, attachment device overdraught control valve, heating element, pressure vacuum gauge and temperature control equipment connection type see attached drawing 2.Even
After connecing, power on, open vacuum pump, shows whether table look-up has air leakage point by vacuum, if there is no leak source beam worker
It finishes.Polluted gas abatement equipment schematic diagram is shown in attached drawing 2.
Concrete operations：Measure the initial concentration of radon gas in kitchen.The temperature of temperature controller is room temperature without setting
30.2℃；Vacuum pump is opened, the control damper in attachment device is opened, vacuum pump just connect ventilation with sealing device, sets
Vacuum degree is -0.04Mpa (being herein relative degree of vacuum)；After steady air current, continuous vacuum is evacuated 4 hours；At vacuum suction
After reason, the control damper in attachment device is closed, closes vacuum pump, slowly unscrews the gas flow optimized on sealing device
Valve restores sealing device to normal pressure, and the concentration of radon gas is measured by sampling in the method after one day according to national standards.
(4) experimental result：The initial concentration of radon gas is 80Bq/m3, 1.0Bq/m is reduced to after present invention processing3.Illustrate this hair
It is bright to can be good at handling indoor existing radon gas, but since radon gas is a kind of radgas, it can be in finishing stone material
Or persistently generated in material, thus need periodically to handle it, reduce injury of the radon gas to human body.
Embodiment 6：Processing using the method for the invention to indoor wall formaldehyde gas
(1) pollution sources：It has scraped putty and has brushed the indoor wall of coating, not into furniture, it is 4.1 flat that metope, which faces window ara,
Rice, left and right sides area are respectively 10.0 square meters, and wall area of entering is 4.9 square meters, totally 29 square meter.
(2) assay method of formaldehyde：GB/T 18204.2-2014《Public places sanitary method of inspection part 2：Chemistry
Pollutant》In 7.3 formaldehyde detection method-gas chromatography.Sampling quantity is 20L, is extracted with 1mL carbon disulfide.
(3) formaldehyde of indoor wall is administered
Assembling：Closed system is formed with an indoor side wall using the sealing device with bleeding point of rectangle " sucked type "
System, bleeding point is connected with rotary-vane vaccum pump (model 2XZ-4), vacuum pump gas outlet is connected to open air with plastic tube；It is close
Heating element is carried inside seal apparatus, the specific connection type of polluted gas abatement equipment is shown in attached drawing 5.After connection, connect
Power supply opens vacuum pump, checks whether sealing device has direct air leakage point, if no leak source preparation finishes.Contamination gas
Body abatement equipment schematic diagram is shown in attached drawing 5.
Concrete operations：Measure the initial concentration of indoor formaldehyde gas.Sealing device inside is added using circulator bath method
Heat, bath temperature are set as 45 DEG C；Vacuum pump is opened, vacuum pump just connect ventilation with sealing device；After steady air current, continue
Vacuum suction 2 hours；After vacuum suction is disposed, vacuum pump is closed, sealing device restores to normal pressure, using same vacuum
Air-exhaust method handles indoor other metopes.
The concentration of indoor formaldehyde gas is measured by sampling in method after one day according to national standards.
(4) analysis of experimental results
The initial concentration of formaldehyde gas is 0.3mg/m3, after processed by the invention, indoor formaldehyde concentration 0.05mg/m3.It says
The bright present invention can be efficiently treated through indoor formaldehyde, since the present invention is from the source for generating pollution, effectively reduce
The concentration of formaldehyde in pollution sources, to make the content of indoor formaldehyde be reduced to a stable level；Simultaneously because institute of the present invention
Any other chemical substance is not used with method, because without there is generation secondary pollution, being at a kind of formaldehyde of environment-friendly high-efficiency
Reason method.
Embodiment 7：Formaldehyde improvement is carried out to solid wood granule plank bed using the present invention
(1) pollution sources：Solid wood granule plank bed, size are：It is 2.2 meters long, it is 1.8 meters wide, it is 0.6 meter high.
(2) assay method of formaldehyde：GB/T 18204.2-2014《Public places sanitary method of inspection part 2：Chemistry
Pollutant》In 7.3 formaldehyde detection method-gas chromatography.Sampling quantity is 20L, is extracted with 1mL carbon disulfide.
(3) the method for the present invention：
Assembling：Solid wood granule plank bed is carried out by integral sealing using the sealing device with bleeding point, by bleeding point and silicon
Sebific duct (as attachment device) connects, the other end and the vacuum pump using circulatory water (model of silicone tube：SHB-IIIS it) connects；Air-flow control
The layout type of valve and heating element processed is shown in Fig. 6.After connection, power on, open vacuum pump, checks that pressure vacuum gauge is examined
Whether have direct air leakage point, if no leak source preparation finishes if looking into.Polluted gas abatement equipment schematic diagram is shown in attached drawing 6.
Concrete operations：Measure the initial concentration for the indoor formaldehyde for placing bed.Under the conditions of 25.0 DEG C of room temperature, vacuum is opened
Pump, vacuum pump just connect ventilation with wardrobe part；Continuous vacuum is evacuated 4 hours, the about interval at the 2nd hour and the 3rd hour
Formula opens the control damper on sealing device, and a small amount of gas is flowed into device to which volatile organic gases to be easier to wave
Hair closes the control damper on sealing device after ten minutes；After vacuum suction is disposed, vacuum pump is closed, is slowly unscrewed
Control damper on sealing device restores sealing device to normal pressure, and indoor formaldehyde is measured by sampling in second day after treatment
Concentration.
(4) experimental result
Initial concentration of formaldehyde is ＜ 0.02mg/m in room when not putting bed3, solid wood granule plank bed is put into behind interior 5 days, first
The initial concentration of aldehyde is 0.32mg/m3；The method of the present invention treated concentration of formaldehyde is 0.06mg/m3.Using side of the present invention
Treated that concentration of formaldehyde has reached GB/T18883-2002 for method《The requirement of Indoor Air Quality standards》It is required that being less than
0.1mg/m3, it is a kind of time-consuming short, efficient finishing pollution gas processing method compared with the existing technology；And it is relatively existing
Technology does not introduce new chemical substance, is a kind of formaldehyde treated method of high-efficiency environment friendly.
Embodiment 8：Formaldehyde in furniture and benzene and substituted benzene are administered using the present invention
(1) pollution sources：Desk, size are：It is 1.5 meters long, it is 1.0 meters wide, it is 0.8 meter high；One 0.4 meter * 0.6 meter * 1.2 meters
Clothes closet, 0.4 meter of * 0.6 meter of * 0.75 meter of chest；Desk and chest and clothes closet are put in the interior of 5 square meters.
(2) assay method of formaldehyde：GB/T 18204.2-2014《Public places sanitary method of inspection part 2：Chemistry
Pollutant》In 7.3 formaldehyde detection method-gas chromatography.Sampling quantity is 20L.
The assay method of benzene, toluene and dimethylbenzene：It is defended according to benzene,toluene,xylene in the air of the residential areas GB11737-89
Raw test stone method --- gas chromatography.Sampling quantity is 20L.
Sampling method in reference standard is sampled measurement.
(3) administering method：
Assembling：Using the sealing device with bleeding point by desk and related cabinet package and integral sealing, by bleeding point
It is connect (as attachment device) with silicone tube, the other end and the rotary-vane vaccum pump (model of silicone tube：It 2XZ-4) connects, vacuum
It pumps out gas port and is connected to open air with plastic tube；Control damper, attachment device overdraught control valve on sealing device, heating part
Part, pressure vacuum gauge, temperature control equipment and gas-filtering device layout type are shown in attached drawing 3.After connection, power on,
Vacuum pump is opened, checks that pressure vacuum gauge checks whether there is direct air leakage point, if no leak source preparation finishes.Contamination gas
Body abatement equipment schematic diagram is shown in attached drawing 3.
Concrete operations：Measure the initial concentration of indoor formaldehyde, benzene, toluene and dimethylbenzene.The temperature of set temperature controller
It is 100 DEG C, after temperature reaches predetermined temperature, opens vacuum pump；Open attachment device on control damper, vacuum pump just with
The connection ventilation of wardrobe part；After steady air current, vacuum meter is shown as -0.06Mpa (being herein relative degree of vacuum), continuous vacuum
Pumping 3 hours；After vacuum suction is disposed, the control damper in attachment device is closed, vacuum pump is closed, slowly unscrews close
Control damper on seal apparatus restores sealing device to normal pressure and temperature, formaldehyde and benzene in desk is measured by sampling within second day
And the concentration of benzene homologue.
(4) experimental result：Initial concentration of formaldehyde is ＜ 0.02mg/m in room when not putting desk, clothes closet and chest3；Benzene it is dense
Degree is 0, toluene concentration 0, a concentration of the 0 of dimethylbenzene.Formaldehyde, benzene are measured after desk and other cabinets are placed 5 days indoors
And substituted benzene concentration, measurement result are shown in Table 5.
Table 5 places the concentration value (mg/m of indoor formaldehyde, benzene and benzene homologues before and after furniture3)
| Measurement project | Formaldehyde | Benzene | Toluene | Dimethylbenzene |
| Initial concentration before processing | 0.48 | 0.73 | 0.51 | 0.54 |
| Concentration that treated | 0.07 | 0.05 | ＜ 0.05 | ＜ 0.05 |
From the above experimental results, using the method for the invention, indoor formaldehyde, benzene and substituted benzene concentration are equal
It is up to standard, thus the mode of vacuum suction of the present invention can effectively reduce the polluted gas concentration in indoor pollution source, be one
The efficient polluted gas processing method of kind；Simultaneously without introducing new chemical substance, secondary pollution will not be caused, is a kind of environmental protection
Polluted gas processing mode.
Embodiment 9：Using the method for the present invention to the formaldehyde treated of indoor wall.
(1) pollution sources：The indoor wall of putty and brush emulsion paint is scraped, it is 5.1 square meters, left and right side that metope, which faces window ara,
Product is respectively 11.3 square meters, and 13.2 square meter of ceiling, door wall area is 6.2 square meters, totally 47.1 square meter, and interior is without other furniture.
(2) assay method of formaldehyde：GB/T 18204.2-2014《Public places sanitary method of inspection part 2：Chemistry
Pollutant》In 7.3 formaldehyde detection method-gas chromatography.Concentration of formaldehyde is measured by sampling according to standard declaration, sampling quantity is
20L。
(3) formaldehyde of indoor wall is administered
Assembling：Sealing system is formed with an indoor side wall using the sealing device with bleeding point of rectangle " sucked type "
System, by bleeding point and rotary-vane vaccum pump (model：X-100B) it is connected, vacuum pump gas outlet is connected to open air with plastic tube.
After connection, power on, open vacuum pump, check whether sealing device has direct air leakage point, if preparing without leak source
Work finishes.Schematic device is shown in attached drawing 3.
Concrete operations：Measure the initial concentration of indoor formaldehyde gas.Opening temperature control device, setting temperature are 40 DEG C；
After the temperature in sealing device reaches set temperature, vacuum pump is opened, opens the barometric damper in attachment device, vacuum pump
Ventilation is connect with sealing device；After steady air current, vacuum meter is shown as -0.07Mpa (being herein relative degree of vacuum), continuous vacuum
Pumping 3 hours；After vacuum suction is disposed, the control damper in attachment device is closed, closes vacuum pump, opens sealing dress
The control damper set makes system restore to normal pressure, using same vacuum suction method to indoor other metopes at
Reason.
The concentration of indoor formaldehyde gas is measured by sampling in method after one day according to national standards.
(4) analysis of experimental results
The initial concentration of formaldehyde gas is 0.25mg/m3, after processed by the invention, indoor formaldehyde concentration is ＜ 0.02mg/
m3.Illustrate that the present invention can be efficiently treated through indoor formaldehyde, since the present invention is from the source for generating pollution, effectively drops
The concentration of formaldehyde in low pollution sources, to make the content of indoor formaldehyde be reduced to a stable level；Simultaneously because this hair
Bright method therefor does not use any other chemical substance, because without there is generation secondary pollution, being a kind of first of environment-friendly high-efficiency
Aldehyde processing method.
Embodiment 10：The improvement of washing cabinet benzene and toluene has been installed using the method for the present invention to toilet
(1) pollution sources：Washing cabinet size：It is 1.17 meters long, 0.45 meter wide, 0.42 meter high, sidecar：It is 0.25 meter long, it is wide by 0.12
Rice, it is 0.80 meter high, contain two cabinets and two drawers；Toilet area is 4 square meters, without other furniture.
(2) assay method of benzene, toluene and dimethylbenzene：According to benzene,toluene,xylene in the air of the residential areas GB11737-89
Health test method --- gas chromatography.Sampling method in reference standard is sampled measurement, sampling quantity 20L.
(3) to the improvement of benzene and toluene in washing cabinet
Assembling：It is formed with one side wall of indoor location washing cabinet using the sealing device with bleeding point of " sucked type " close
System is closed, by bleeding point and circulating water type vacuum pump (model：SHB-IIIS) it is connected by silicone tube, vacuum pump gas outlet is used
Plastic tube is connected to open air；Control damper, attachment device overdraught control valve on sealing device, heating element, vacuum pressure
Power table, temperature control equipment and gas-filtering device layout type are shown in attached drawing 3.After connection, power on, opens vacuum and follow
Ring type water pump, checks whether sealing device has direct air leakage point, if no leak source preparation finishes.Schematic device is shown in attached
Fig. 3.
Concrete operations：The initial concentration of benzene and toluene gas in measuring cell.Opening temperature control device, setting temperature are
130℃；After the temperature in sealing device reaches set temperature, vacuum pump is opened, opens the barometric damper in attachment device,
Vacuum pump connect ventilation with sealing device；After steady air current, adjust the control damper of sealing device, make vacuum meter be shown as-
0.03Mpa (being herein relative degree of vacuum), continuous vacuum are evacuated 6 hours；After vacuum suction is disposed, close in attachment device
Control damper, close vacuum pump, open sealing device on control damper so that system is restored to normal pressure.It samples within second day
Measure the content of benzene and toluene gas therein.
(4) analysis of experimental results
The initial concentration of indoor benzene is 6.41mg/m3, the initial concentration of toluene is 2.39mg/m3, after processed by the invention,
A concentration of 0.05mg/m of benzene3, a concentration of ＜ 0.05mg/m of toluene3.Illustrate that the present invention can be to the benzene and first of indoor washing cabinet
Benzene is efficiently treated through, and since the present invention is from the source for generating pollution, effectively reduces the dense of benzene and toluene in pollution sources
Degree, to make the content of indoor benzene and toluene be reduced to a stable level；Simultaneously because method therefor of the present invention does not make
With any other chemical substance, because without there is generation secondary pollution, being a kind of polluted gas processing method of environment-friendly high-efficiency.
Embodiment 11：Formaldehyde in furniture is administered using the present invention
(1) pollution sources：Desk, size are：It is 1.5 meters long, it is 1.0 meters wide, it is 0.8 meter high；One 0.4 meter * 0.6 meter * 1.2 meters
Clothes closet, 0.4 meter of * 0.6 meter of * 0.75 meter of chest；Desk and chest and clothes closet are put in the interior of 5 square meters.
(2) assay method of formaldehyde：GB/T 18204.2-2014《Public places sanitary method of inspection part 2：Chemistry
Pollutant》In 7.3 formaldehyde detection method-gas chromatography.Sampling quantity is 20L.
Sampling method in reference standard is sampled measurement.
(3) administering method：
Assembling：Using the sealing device with bleeding point by desk and related cabinet package and integral sealing, by bleeding point
It is connect (as attachment device) with silicone tube, the other end and the circulating water type vacuum pump (model of silicone tube：SHB-IIIS it) connects,
Vacuum pump gas outlet is connected to open air with plastic tube；Control damper, attachment device overdraught control valve on sealing device plus
Thermal part, pressure vacuum gauge, temperature control equipment and gas-filtering device layout type are shown in attached drawing 3.After connection, electricity is connected
Vacuum cycle formula water pump is opened in source, checks whether sealing device has direct air leakage point, if no leak source preparation finishes.
Schematic device is shown in attached drawing 3.
Concrete operations：Measure the initial concentration of indoor formaldehyde.Opening temperature control device, setting temperature are 200 DEG C；When close
After temperature in seal apparatus reaches set temperature, open vacuum pump, open attachment device on barometric damper, vacuum pump with it is close
Seal apparatus connection ventilation；After steady air current, the control damper of sealing device is adjusted, vacuum meter is made to be shown as -0.03Mpa (this
Place is relative degree of vacuum), continuous vacuum is evacuated 7 hours；After vacuum suction is disposed, the gas flow optimized in attachment device is closed
Valve and temperature heater switch close vacuum pump, and the control damper opened on sealing device makes system restore to normal pressure.Second day
The content of formaldehyde gas therein is measured by sampling.
(4) experimental result：Initial concentration of formaldehyde is ＜ 0.02mg/m in room when not putting desk, clothes closet and chest3.By desk
Concentration of formaldehyde is measured after placing 5 days indoors, measurement result is shown in Table 6.
Concentration value (the mg/m of indoor formaldehyde before and after the placement of table 6 desk, clothes closet and chest3)
| Measurement project | Formaldehyde |
| Initial concentration before processing | 0.42 |
| Concentration that treated | 0.09 |
From the above experimental results, using the method for the invention, indoor concentration of formaldehyde can be up to standard, thus the present invention
The mode of the vacuum suction can effectively reduce the polluted gas concentration in indoor pollution source, be a kind of efficient polluted gas
Processing method；Simultaneously without introducing new chemical substance, secondary pollution will not be caused, is a kind of polluted gas processing side of environmental protection
Formula.
Embodiment 12：Indoor decoration pollution gas integrated is administered using the method for the invention
(1) pollution sources：Metope, furniture (including wardrobe, desk, carpet, bed, washing cabinet, dining table etc.) after interior decoration,
The improvement of polluted gas in floor, ceramic tile etc..Polluted gas includes：Formaldehyde, benzene,toluene,xylene, ammonia, radon gas and total
Volatile organic compounds (TVOC).
(2) detection method：
1. the assay method of formaldehyde：GB/T 18204.2-2014《Public places sanitary method of inspection part 2：It is chemical dirty
Contaminate object》In 7.3 formaldehyde detection method-gas chromatography.Concentration of formaldehyde is measured by sampling according to standard declaration.
2. the assay method of benzene, toluene and dimethylbenzene：According to benzene,toluene,xylene in the air of the residential areas GB11737-89
Health test method --- gas chromatography.Sampling method in reference standard is sampled measurement.
3. ammonia assay method：HJ 534-2009《Measurement sodium hypochlorite-salicylic acid spectrophotometric of surrounding air ammonia
Method》.It is sampled measurement according to sampling method in standard.
4. the detection method of radon gas：Using GBZ/T 155-2002《The scintillation vial assay method of Air Radon Concentration》, take
The method of quadrat method according to national standards is sampled by professional.
5. the assay method of total volatile organic compounds TVOC：Using GB 50325-2010 (2013 editions) civil buildings
Engineering indoor environmental pollution controls in specification the measurement of total volatile organic compounds (TVOC) in room air in annex G.
(3) the improvement operation of indoor polluted gas
Assembling：Using sealing device by pollution sources sealing (i.e. integral sealing or formed closed system), by its bleeding point and
Rotary-vane vaccum pump (model：X-100B it) is connected with silicone tube, the exhaust outlet of vacuum pump is connected to open air using plastic tube；Sealing
Control damper, attachment device overdraught control valve, heating element, pressure vacuum gauge, temperature control equipment on device is gentle
Body filter device layout type is shown in attached drawing 3.After connection, power on, open vacuum pump, checks whether sealing device has directly
The air leakage point connect, if no leak source preparation finishes.Schematic device is shown in attached drawing 3.
Concrete operations：The initial concentration of each polluted gas in measuring cell.Opening temperature control device, setting temperature are 40
℃；After the temperature in sealing device reaches set temperature, vacuum pump is opened, opens the barometric damper in attachment device, very
Sky pump connect ventilation with sealing device；After steady air current, adjust the control damper of sealing device, make vacuum meter be shown as-
0.06Mpa to -0.09Mpa (being herein relative degree of vacuum), continuous vacuum are evacuated 3 hours；After vacuum suction is disposed, close
Control damper in attachment device closes vacuum pump, and the control damper opened on sealing device makes system restore to normal pressure.
Each position is in the same manner handled indoor decoration pollution gas.
Second day content that indoor polluted gas is measured by sampling.
(4) the improvement result of indoor polluted gas
7 the method for the present invention of table is administered front and back indoor polluted gas concentration and is compared
Explanation：The unit of radon gas is Bq/m3。
From the above measurement result it is found that the present invention, which can be very good, reduces the content of indoor polluted gas, to reach
The purpose of efficient process polluted gas makes the content of indoor polluted gas be reduced in zone of reasonableness, reduces polluted gas pair
The whole injury of human body；Simultaneously because method therefor of the present invention does not use any other chemical substance, because without there is generation
Secondary pollution is a kind of polluted gas processing method of environment-friendly high-efficiency.
Embodiment 13：Formaldehyde removal is carried out to the bulk article of certain Ban Tai manufacturer using the method for the invention.
(1) pollution sources：10 groups of Ban Tai of Furniture manufacturing producer.
(2) assay method of formaldehyde：According to GB/T 18204.2-2014《Public places sanitary method of inspection part 2：
Chemical pollutant》In 7.3 formaldehyde detection method-gas chromatography.It is equal with reference to the method using measuring.
(3) concrete operations：
Assembling：Use shell that 10 groups of Ban Tai are carried out integral sealing for the sealing device of metal, by bleeding point and 3 groups of vacuum
Pump (model：2XZ-4 rotary-vane vaccum pumps) it is connected, gas outlet is connected to open air with silicone tube；Air-flow control on sealing device
The company of valve processed, attachment device overdraught control valve, heating element, pressure vacuum gauge, temperature control equipment and gas-filtering device
The mode of connecing is shown in attached drawing 3.After connection, power on, open vacuum pump, shows whether table look-up has air leakage point by vacuum,
If no leak source preparation finishes.Polluted gas abatement equipment schematic diagram is shown in attached drawing 3.
Concrete operations：Measure the initial concentration of formaldehyde inside sealing device.The temperature of temperature controller is set as 60 DEG C；It beats
Open vacuum pump, open the control damper in attachment device, vacuum pump just connect ventilation with sealing device, set vacuum degree as-
0.1Mpa (being herein relative degree of vacuum)；After steady air current, continuous vacuum is evacuated 4 hours；After vacuum suction is disposed, close
The control damper and heater switch in attachment device are closed, vacuum pump is closed, slowly unscrews the control damper on sealing device,
Sealing device is restored to normal pressure, it is dense that the assay method according to standard sample after 3 hours, and in reference standard measures pernicious gas
Degree, measurement result are as follows.
(5) measurement result：
The initial concentration of formaldehyde is 1.85mg/m3, treated, and concentration of formaldehyde is 0.04mg/m3, reach standard requirement.It says
Bright the method for the invention can be good at removing the formaldehyde gas in class's platform.
Embodiment 14：Formaldehyde removal is carried out to the bulk article of certain floor manufacturer using the method for the invention.
(1) pollution sources：500 square meter thickness of plant produced are 12mm composite floor boards.
(2) assay method of formaldehyde：According to GB/T 18204.2-2014《Public places sanitary method of inspection part 2：
Chemical pollutant》In 7.3 formaldehyde detection method-gas chromatography.It is equal with reference to the method using measuring.
(3) concrete operations：
Assembling：500 square meter floors are put into the sealing device that shell is metal (form for using integral sealing), and make ground
A fixed gap is kept between plate, this sealing device the right and left is respectively provided with a bleeding point, two bleeding points respectively with 2 groups of vacuum
Pump (model：X-100B rotary-vane vaccum pumps) it is connected by attachment device, gas outlet is connected to open air with silicone tube；Sealing device
On control damper, attachment device overdraught control valve, heating element, pressure vacuum gauge, temperature control equipment and gas mistake
The connection type for filtering device is identical as attached drawing 3.After connection, power on, opens vacuum pump, table look-up is shown by vacuum
Whether air leakage point is had, if no leak source preparation finishes.
Concrete operations：Measure the initial concentration of formaldehyde in sealing device.The temperature of temperature controller is set as 160 DEG C；It beats
Open vacuum pump, open the control damper in attachment device, vacuum pump just connect ventilation with sealing device, set vacuum degree as-
0.085Mpa (being herein relative degree of vacuum)；After steady air current, continuous vacuum is evacuated 2 hours；After vacuum suction is disposed,
The control damper and heater switch in attachment device are closed, vacuum pump is closed, slowly unscrews the gas flow optimized on sealing device
Valve restores sealing device to normal pressure, and the assay method according to standard sample after 3 hours, and in reference standard, which measures, is harmful to gas
Bulk concentration, measurement result are as follows.
(5) measurement result：
The initial concentration of formaldehyde is 2.03mg/m3, treated, and concentration of formaldehyde is 0.05mg/m3, reach standard requirement.It says
Bright the method for the invention can efficiently remove the formaldehyde in floor.
Claims (22)
1. a kind of abatement equipment of indoor decoration pollution gas, it is characterised in that：By vacuum pump, the sealing dress with bleeding point
It sets, the attachment device composition on vacuum pump and sealing device between bleeding point.
2. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that indoor decoration pollution gas is
Refer to harmful gas componant, including：Formaldehyde, benzene and substituted benzene, ammonia, radon gas, total volatile organic compounds
And it is one or more in other volatile harmful gases.
3. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that sealing device refers to interior
The device that pollution sources are sealed.
4. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that sealing device can will be indoor dirty
Dye source carries out integral sealing.
5. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that sealing device can be with interior dirt
A closed system is collectively formed in dye source.
6. the abatement equipment of indoor decoration pollution gas according to claim 3, it is characterized in that the indoor pollution source includes
Metope, furniture, floor, ceramic tile after interior decoration etc. it is one or more.
7. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that can be into one on sealing device
The control damper that step installation is communicated with outside air.
8. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that can be into inside sealing device
One step carries heating element.
9. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that on vacuum pump and sealing device
Attachment device between bleeding point refers to that vacuum pump and sealing device can be attached to the component of ventilation.
10. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that attachment device overdraught passes through
Position can control damper be further installed to adjust air-flow.
11. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that vacuum pump and sealing device
Gas-filtering device can be further installed between bleeding point.
12. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that can further be filled in sealing
Set installation pressure vacuum gauge.
13. the abatement equipment of indoor decoration pollution gas according to claim 1, it is characterized in that can further be filled in sealing
Set installation temperature control equipment.
14. using the method polluted in indoor decoration pollution master gas apparatus chamber described in claim 1, it is characterized in that：
(1) indoor objects pollution sources are sealed using the sealing device with bleeding point；
(2) bleeding point on vacuum pump and sealing device is attached by attachment device；
(3) vacuum pump is opened, to being vacuumized in sealing device；
(4) indoor decoration pollution after treatment closes vacuum pump.
15. according to the method for handling indoor pollution described in claim 14, it is characterized in that indoor objects pollution sources include indoor dress
The one or more of metope, furniture, floor, ceramic tile after repairing etc..
16. according to the method for handling indoor pollution described in claim 14, it is characterized in that in process chamber in pollution course, sealing dress
Internal relative degree of vacuum ranging from zero Mpa to -0.1Mpa is set, zero Mpa is not included.
17. according to the method for handling indoor pollution described in claim 14, it is characterized in that in process chamber in pollution course, sealing dress
It sets internal relative degree of vacuum range and is further defined to -0.04Mpa to -0.1Mpa.
18. according to the method for handling indoor pollution described in claim 14, it is characterized in that in process chamber in pollution course, sealing dress
It sets internal relative degree of vacuum value range and is further limited to -0.07Mpa to -0.1Mpa.
19. according to the method for handling indoor pollution described in claim 14, it is characterized in that during processing indoor pollution, sealing
Device internal temperature range is room temperature to 200 DEG C.
20. according to the method for handling indoor pollution described in claim 14, it is characterized in that during processing indoor pollution, sealing
Device internal temperature range is further defined to room temperature to 100 DEG C.
21. according to the method for handling indoor pollution described in claim 14, it is characterized in that during processing indoor pollution, sealing
Device internal temperature range is further defined to room temperature to 60 DEG C.
22. according to the method for handling indoor pollution described in claim 14, it is characterized in that during processing indoor pollution, sealing
Device internal temperature range is further limited to room temperature to 45 DEG C.
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| CN201710080288.1A CN108393041A (en) | 2017-02-08 | 2017-02-08 | A kind of abatement equipment and its application method of indoor decoration pollution gas |
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| CN201710080288.1A CN108393041A (en) | 2017-02-08 | 2017-02-08 | A kind of abatement equipment and its application method of indoor decoration pollution gas |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114049749A (en) * | 2021-11-18 | 2022-02-15 | 宝武集团鄂城钢铁有限公司 | Monitoring method and monitoring system for harmful gas |
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2017
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN114049749A (en) * | 2021-11-18 | 2022-02-15 | 宝武集团鄂城钢铁有限公司 | Monitoring method and monitoring system for harmful gas |
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