CN108384499A - A kind of plastics adhesive - Google Patents
A kind of plastics adhesive Download PDFInfo
- Publication number
- CN108384499A CN108384499A CN201810218612.6A CN201810218612A CN108384499A CN 108384499 A CN108384499 A CN 108384499A CN 201810218612 A CN201810218612 A CN 201810218612A CN 108384499 A CN108384499 A CN 108384499A
- Authority
- CN
- China
- Prior art keywords
- weight
- parts
- propyl alcohol
- poly
- synthesis
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J11/00—Features of adhesives not provided for in group C09J9/00, e.g. additives
- C09J11/02—Non-macromolecular additives
- C09J11/06—Non-macromolecular additives organic
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J133/00—Adhesives based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Adhesives based on derivatives of such polymers
- C09J133/24—Homopolymers or copolymers of amides or imides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J171/00—Adhesives based on polyethers obtained by reactions forming an ether link in the main chain; Adhesives based on derivatives of such polymers
- C09J171/02—Polyalkylene oxides
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09J—ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
- C09J4/00—Adhesives based on organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond ; adhesives, based on monomers of macromolecular compounds of groups C09J183/00 - C09J183/16
- C09J4/06—Organic non-macromolecular compounds having at least one polymerisable carbon-to-carbon unsaturated bond in combination with a macromolecular compound other than an unsaturated polymer of groups C09J159/00 - C09J187/00
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Chemical And Physical Treatments For Wood And The Like (AREA)
- Adhesives Or Adhesive Processes (AREA)
Abstract
The invention discloses a kind of plastics adhesives, are prepared using the following raw material：12 25 weight parts of methacrylic acid butyl esters, 5 18 part by weight of cellulose xylan, the poly- Synthesis of Oligo Ethylene Glycol of 14 22 parts by weight, 6 15 parts by weight pentaerythrites, 27 parts by weight Diacetone Acrylamide, 27 parts by weight resorcinols, 12 17 parts by weight of lemon acid tributyls, 7 13 weight parts of polymer gels, 12 18 parts by weight tackifying resins, 25 parts by weight propyl alcohol, 16 30 parts by weight water.The present invention is using butyl methacrylate, cellulose xylan, poly- Synthesis of Oligo Ethylene Glycol, pentaerythrite, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, tackifying resin, propyl alcohol as raw material, each ingredient interaction influences each other, adhesive adhesive strength obtained is high, securely, not easy to crack.
Description
Technical field
The present invention relates to building material technical fields, and in particular to a kind of plastics adhesive.
Background technology
Adhesive is also known as adhesive, is the nonmetallic media material for making object be closely connected as one with another object.
Adhesive only accounts for one layer of very thin volume between two adherend faces, but is completed after being glued construction using adhesive, gained glue
Fitting can meet the requirements of actual needs in terms of mechanical performance and physical and chemical performance, can be effectively by materials from bonding
Together.Plastic products need scrappy plastic items to be spliced at present, and used adhesive is in use
Often there is the generation of problems of crack.
Invention content
For above-mentioned present situation, the object of the present invention is to provide a kind of plastics adhesive, intensity is big, gluing is secured, is not easy
Cracking.
The technical solution adopted by the present invention is that：
A kind of plastics adhesive, is prepared using the following raw material：12-25 weight parts of methacrylic acid butyl ester, 5-18 parts by weight
Cellulose xylan, the poly- Synthesis of Oligo Ethylene Glycol of 14-22 parts by weight, 6-15 parts by weight pentaerythrite, 2-7 parts by weight diacetone acrylamide acyls
Amine, 2-7 parts by weight resorcinol, 12-17 parts by weight of lemon acid tributyl, 7-13 weight parts of polymer gel, 12-18 parts by weight increase
Viscosity resin, 2-5 parts by weight propyl alcohol, 16-30 parts by weight water.
Further, the plastics adhesive, is prepared using the following raw material：17-20 weight parts of methacrylic acid butyl ester,
10-13 part by weight of cellulose xylan, the poly- Synthesis of Oligo Ethylene Glycol of 17-19 parts by weight, 9-12 parts by weight pentaerythrite, 4-5 parts by weight
Diacetone Acrylamide, 4-5 parts by weight resorcinol, 14-15 parts by weight of lemon acid tributyl, 9-11 weight parts of polymer gel,
14-16 parts by weight tackifying resin, 3-4 parts by weight propyl alcohol, 21-25 parts by weight water.
Further, the plastics adhesive, is prepared using the following raw material：18.5 weight parts of methacrylic acid fourth
Ester, 11.5 part by weight of cellulose xylan, the poly- Synthesis of Oligo Ethylene Glycol of 18 parts by weight, 10.5 parts by weight pentaerythrites, 4.5 parts by weight are double
Acetone acrylamide, 4.5 parts by weight resorcinols, 14.5 parts by weight of lemon acid tributyls, 10 weight parts of polymer gels, 15 weight
Part tackifying resin, 3.5 parts by weight propyl alcohol, 23 parts by weight water.
The present invention also provides the preparation methods of above-mentioned plastics adhesive, specially：By butyl methacrylate, cellulose
Xylan, poly- Synthesis of Oligo Ethylene Glycol, pentaerythrite, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, increasing
Viscosity resin, propyl alcohol, water are uniformly mixed, and are warming up to 75-85 DEG C, are stirred to react 3-4h, are cooled to room temperature up to timber adhesive.
It is an advantage of the invention that：The present invention is with butyl methacrylate, cellulose xylan, poly- Synthesis of Oligo Ethylene Glycol, season penta
Tetrol, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, tackifying resin, propyl alcohol are raw material, Ge Gecheng
Split-phase interaction influences each other, and adhesive adhesive strength obtained is high, securely, not easy to crack.
Specific implementation mode
For a further understanding of the present invention, the preferred embodiment of the invention is described with reference to embodiment, still
It should be appreciated that these descriptions are only the feature and advantage further illustrated the present invention, rather than to the claims in the present invention
Limitation.
Embodiment 1
A kind of plastics adhesive, is prepared using the following raw material：12 weight parts of methacrylic acid butyl esters, 5 part by weight of cellulose
Xylan, the poly- Synthesis of Oligo Ethylene Glycol of 14 parts by weight, 6 parts by weight pentaerythrites, 2 parts by weight Diacetone Acrylamide, 2 parts by weight isophthalic
Diphenol, 12 parts by weight of lemon acid tributyls, 7 weight parts of polymer gels, 12 parts by weight tackifying resins, 2 parts by weight propyl alcohol, 16 weight
Part water.
The preparation method of above-mentioned plastics adhesive, specially：By butyl methacrylate, cellulose xylan, polycyclic oxygen
Glycerin ether, pentaerythrite, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, tackifying resin, propyl alcohol,
Water is uniformly mixed, and is warming up to 75 DEG C, is stirred to react 3h, is cooled to room temperature up to timber adhesive.
Embodiment 2
A kind of plastics adhesive, is prepared using the following raw material：17 weight parts of methacrylic acid butyl esters, 10 part by weight of cellulose
Xylan, the poly- Synthesis of Oligo Ethylene Glycol of 17 parts by weight, 9 parts by weight pentaerythrites, 4 parts by weight Diacetone Acrylamide, 4 parts by weight isophthalic
Diphenol, 14 parts by weight of lemon acid tributyls, 9 weight parts of polymer gels, 14 parts by weight tackifying resins, 3 parts by weight propyl alcohol, 21 weight
Part water.
The preparation method of above-mentioned plastics adhesive, specially：By butyl methacrylate, cellulose xylan, polycyclic oxygen
Glycerin ether, pentaerythrite, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, tackifying resin, propyl alcohol,
Water is uniformly mixed, and is warming up to 78 DEG C, is stirred to react 3.5h, is cooled to room temperature up to timber adhesive.
Embodiment 3
A kind of plastics adhesive, is prepared using the following raw material：18.5 weight parts of methacrylic acid butyl esters, 11.5 parts by weight are fine
The plain xylan of dimension, the poly- Synthesis of Oligo Ethylene Glycol of 18 parts by weight, 10.5 parts by weight pentaerythrites, 4.5 parts by weight Diacetone Acrylamide,
4.5 parts by weight resorcinols, 14.5 parts by weight of lemon acid tributyls, 10 weight parts of polymer gels, 15 parts by weight tackifying resins,
3.5 parts by weight propyl alcohol, 23 parts by weight water.
The preparation method of above-mentioned plastics adhesive, specially：By butyl methacrylate, cellulose xylan, polycyclic oxygen
Glycerin ether, pentaerythrite, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, tackifying resin, propyl alcohol,
Water is uniformly mixed, and is warming up to 80 DEG C, is stirred to react 3.5h, is cooled to room temperature up to timber adhesive.
Embodiment 4
A kind of plastics adhesive, is prepared using the following raw material：20 weight parts of methacrylic acid butyl esters, 13 part by weight of cellulose
Between xylan, the poly- Synthesis of Oligo Ethylene Glycol of 19 parts by weight, 12 parts by weight pentaerythrites, 5 parts by weight Diacetone Acrylamide, 5 parts by weight
Benzenediol, 15 parts by weight of lemon acid tributyls, 11 weight parts of polymer gels, 16 parts by weight tackifying resins, 4 parts by weight propyl alcohol, 25
Parts by weight water.
The preparation method of above-mentioned plastics adhesive, specially：By butyl methacrylate, cellulose xylan, polycyclic oxygen
Glycerin ether, pentaerythrite, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, tackifying resin, propyl alcohol,
Water is uniformly mixed, and is warming up to 82 DEG C, is stirred to react 3.5h, is cooled to room temperature up to timber adhesive.
Embodiment 5
A kind of plastics adhesive, is prepared using the following raw material：25 weight parts of methacrylic acid butyl esters, 18 part by weight of cellulose
Between xylan, the poly- Synthesis of Oligo Ethylene Glycol of 22 parts by weight, 15 parts by weight pentaerythrites, 7 parts by weight Diacetone Acrylamide, 7 parts by weight
Benzenediol, 17 parts by weight of lemon acid tributyls, 13 weight parts of polymer gels, 18 parts by weight tackifying resins, 5 parts by weight propyl alcohol, 30
Parts by weight water.
The preparation method of above-mentioned plastics adhesive, specially：By butyl methacrylate, cellulose xylan, polycyclic oxygen
Glycerin ether, pentaerythrite, Diacetone Acrylamide, resorcinol, tributyl citrate, polymeric gel, tackifying resin, propyl alcohol,
Water is uniformly mixed, and is warming up to 85 DEG C, is stirred to react 4h, is cooled to room temperature up to timber adhesive.
Claims (4)
1. a kind of plastics adhesive, it is characterised in that prepared using the following raw material：12-25 weight parts of methacrylic acid butyl ester, 5-
18 part by weight of cellulose xylan, the poly- Synthesis of Oligo Ethylene Glycol of 14-22 parts by weight, 6-15 parts by weight pentaerythrite, 2-7 parts by weight double third
Ketone acrylamide, 2-7 parts by weight resorcinol, 12-17 parts by weight of lemon acid tributyl, 7-13 weight parts of polymer gel, 12-18
Parts by weight tackifying resin, 2-5 parts by weight propyl alcohol, 16-30 parts by weight water.
2. plastics adhesive according to claim 1, it is characterised in that prepared using the following raw material：17-20 parts by weight first
Base butyl acrylate, 10-13 part by weight of cellulose xylan, the poly- Synthesis of Oligo Ethylene Glycol of 17-19 parts by weight, 9-12 parts by weight Ji Wusi
Alcohol, 4-5 parts by weight Diacetone Acrylamide, 4-5 parts by weight resorcinol, 14-15 parts by weight of lemon acid tributyl, 9-11 weight
Part polymeric gel, 14-16 parts by weight tackifying resin, 3-4 parts by weight propyl alcohol, 21-25 parts by weight water.
3. plastics adhesive according to claim 1, it is characterised in that prepared using the following raw material：18.5 parts by weight methyl
Butyl acrylate, 11.5 part by weight of cellulose xylan, the poly- Synthesis of Oligo Ethylene Glycol of 18 parts by weight, 10.5 parts by weight pentaerythrites, 4.5
Parts by weight Diacetone Acrylamide, 4.5 parts by weight resorcinols, 14.5 parts by weight of lemon acid tributyls, 10 weight parts of polymer are solidifying
Glue, 15 parts by weight tackifying resins, 3.5 parts by weight propyl alcohol, 23 parts by weight water.
4. the preparation method of plastics adhesive according to claim 1 or 2 or 3, it is characterised in that be specially：By methyl-prop
Olefin(e) acid butyl ester, cellulose xylan, poly- Synthesis of Oligo Ethylene Glycol, pentaerythrite, Diacetone Acrylamide, resorcinol, citric acid three
Butyl ester, polymeric gel, tackifying resin, propyl alcohol, water are uniformly mixed, and are warming up to 75-85 DEG C, are stirred to react 3-4h, are cooled to room temperature
Up to timber adhesive.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810218612.6A CN108384499A (en) | 2018-03-16 | 2018-03-16 | A kind of plastics adhesive |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810218612.6A CN108384499A (en) | 2018-03-16 | 2018-03-16 | A kind of plastics adhesive |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108384499A true CN108384499A (en) | 2018-08-10 |
Family
ID=63068010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810218612.6A Withdrawn CN108384499A (en) | 2018-03-16 | 2018-03-16 | A kind of plastics adhesive |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108384499A (en) |
-
2018
- 2018-03-16 CN CN201810218612.6A patent/CN108384499A/en not_active Withdrawn
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN101781536B (en) | Thermosetting acrylic structural adhesive and preparation method | |
| CN103320075B (en) | One-component ultraviolet-light-anaerobic dual-curing adhesive | |
| CN103725206A (en) | Two-component high-temperature-resisting adhesive for assembling loudspeaker and preparation method thereof | |
| CN101805564A (en) | Novel low-odor acrylate structural adhesive and preparation method thereof | |
| CN103756599B (en) | A kind of high temperature resistant high bonding force adhering resin | |
| CN108384499A (en) | A kind of plastics adhesive | |
| CN106497484A (en) | A kind of one-component thermosetting pre-coat adhesive and preparation method thereof | |
| CN106520031A (en) | Environment-friendly acrylate adhesive and preparation process thereof | |
| CN105925216A (en) | Solid adhesive | |
| CN108384464A (en) | A kind of timber adhesive | |
| CN106967378A (en) | A kind of soybean available for fiberboard is without aldehyde adhesive | |
| CN104441098A (en) | Cold-pressed rapid gluing method for wood | |
| CN103881637A (en) | Plastic binder | |
| CN103555252B (en) | Fixing adhesive for cutting ceramic glass | |
| CN103074014A (en) | Wood adhesion agent | |
| CN103320020A (en) | High-performance acrylate-structured adhesive production process | |
| CN108084932A (en) | A kind of sawdust bonding glue | |
| CN103770253A (en) | Preparation method for high efficiency demoulding material | |
| CN106634628B (en) | Water glass-based adhesive for straw artificial board and preparation method thereof | |
| CN107586507A (en) | A kind of wood furniture anti-flaming dope | |
| CN108559444A (en) | A kind of environment-friendly building materials bonding building adhesive | |
| CN105017995A (en) | Metallocene polyethylene wood adhesive | |
| CN104974698A (en) | Novel plastic adhesive | |
| RU2446044C2 (en) | Method of gluing wood materials | |
| CN105017974A (en) | Low-viscosity wood adhesive |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180810 |