CN1083831A - The new method for extracting of capsanthin - Google Patents
The new method for extracting of capsanthin Download PDFInfo
- Publication number
- CN1083831A CN1083831A CN 92112171 CN92112171A CN1083831A CN 1083831 A CN1083831 A CN 1083831A CN 92112171 CN92112171 CN 92112171 CN 92112171 A CN92112171 A CN 92112171A CN 1083831 A CN1083831 A CN 1083831A
- Authority
- CN
- China
- Prior art keywords
- extracting
- solvent
- capsanthin
- add
- pigment
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09B—ORGANIC DYES OR CLOSELY-RELATED COMPOUNDS FOR PRODUCING DYES, e.g. PIGMENTS; MORDANTS; LAKES
- C09B61/00—Dyes of natural origin prepared from natural sources, e.g. vegetable sources
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- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Coloring Foods And Improving Nutritive Qualities (AREA)
- Fats And Perfumes (AREA)
- Seasonings (AREA)
Abstract
With the red chili is raw material, 6
#Solvent oil extraction pigment removes pungent with aqueous ethanol, adds V
EDeng protection, and add solubilizing agent and make water-soluble red colouring matter.
Description
The invention belongs to the preparation (International Classification of Patents A23L) of natural foodstuff (additive)
Natural pigment, because tight security is subjected to the countries in the world attention, some developed countries, law-making stipulation in foods and cosmetics, is not filled the pigment of being permitted to use chemosynthesis.The haematochrome that wherein extracts from red chili is in great demand, and the annual requirement of American market is 800 tons at present, 180,000 dollars of prices per ton.
At present, extracting method mostly adopts acetone both at home and abroad, ethanol, dioxane are solvent, and cost is higher, solvent recuperation and remove difficulty, residual quantity reaches more than the 50ppm, and the assorted matter of raw material Semi-polarity is as capsicine, organic acids etc. also are extracted simultaneously, purify and remove the pungent difficulty, some traditional technologys are handled with highly basic (as NaOH), and post layer folding fractionation by adsorption is also arranged, the former efficient is not high, and makes pigment failure loss in the product, has reduced the look valency.Latter's operational difficulty, the time is long, and especially scale effect is remarkable, can not scale operation.
The present invention solves an above-mentioned difficult problem.
Gordian technique of the present invention has two:
One is to adopt the degree of safety height, and selectivity is strong, and No. six solvent oils of wide, cheap industry of originating are extraction solvent.No. six solvent oils are industrial petroleum cuts, and it is to the security of human body, have obtained countries in the world and have generally acknowledged, and be used in for a long time in the industry such as grease, because it is nonpolar, selectivity is strong, preferentially extracts pigment.
Two of gordian technique is to take off the pungent technology, utilizes the polarity of pigment and spicy substance different, with 6# solvent oil and aqueous ethanol, constitutes immiscible two-phase, presses the following formula extracting and separating.K (C
S)/(C
L) K is a partition ratio in the formula, C
SAnd C
LBe the C of material in two phase liquid
LConcentration.
Through n extraction
ω
n=ω
o( (KV
S)/(KV
S+V
C) )
n
ω in the formula
0Be substances content in the original solution
V
SBe the original solution volume
V
OBe solvent volume
Experiment showed, n=3, promptly three extractions can be removed pungent fully, because capsanthin belongs to carotenoid, contain a plurality of pairs of keys in the molecule, and to light, oxygen instability, the present invention adds V
E, to strengthen resistance of oxidation.
In food, medicine, often need be water-soluble, it is that HLB is higher than 15 tween and sucrose ester SE that the present invention adds non-ionic solubilizer
15Reach water-soluble purpose.
Example: with the goat's horn red pepper, clean, flood is done, get 50 kilograms and wear into 40 order powder, join stainless steel, have in the extractor of the topped filter cloth of sieve plate with Universalpulverizer, No. six solvent oils of industry, added by the header tank spray, extracting solution flows into the low level jar by filter cloth, when visor is observed effluent liquid not redly, promptly stop spray, collect extracting solution, be concentrated into extract content about 50% in No. six solvent oils, about 10 kilograms of total amount.
Add 75% ethanol of 10 kilograms of total amounts, divide to add to for three times to contain in No. six solvent oils of enriched material, add 30 kilograms at every turn, stirred 10 minutes, standing demix is told lower floor's ethanolic extract.Solvent oil is sloughed in the upper strata decompression No. six, added 0.1～0.5%V
E, packing is finished product, as required, can add 10～20% solubilizing agent tweens and make water-soluble finished product.Lower floor's ethanolic extract also can be concentrated recovery ethanol, gets spicy substance, mainly is capsicine, can make medicine or pungent oil and pay product.
Claims (4)
1, with No. six solvent oils pigment extraction solvent as capsicum
2, with aqueous ethanol separating pepper alkali, remove the product pungent
3, add V
EPerhaps BH7 etc. is a stablizer
4, add tween or high HLB value sucrose ester is that solubilizing agent is made water soluble capsanthin pigment
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92112171 CN1083831A (en) | 1992-10-21 | 1992-10-21 | The new method for extracting of capsanthin |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 92112171 CN1083831A (en) | 1992-10-21 | 1992-10-21 | The new method for extracting of capsanthin |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1083831A true CN1083831A (en) | 1994-03-16 |
Family
ID=4945786
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 92112171 Pending CN1083831A (en) | 1992-10-21 | 1992-10-21 | The new method for extracting of capsanthin |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1083831A (en) |
Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1318391C (en) * | 2005-07-08 | 2007-05-30 | 上海雷辣婆食品有限公司 | Method of extracting capsaicin and capsaithin from red pepper |
| CN100402609C (en) * | 2006-07-18 | 2008-07-16 | 天津晨光天然色素有限公司 | Process for producing water soluble capsanthin pigment |
| CN1740236B (en) * | 2004-08-23 | 2010-12-01 | 黄启强 | Production process of capsorubin and capsaicine |
| CN102181172A (en) * | 2011-03-09 | 2011-09-14 | 浙江大学 | Technique for preparing capsanthin pigment from chilies |
| CN102600294A (en) * | 2011-12-15 | 2012-07-25 | 武城县英潮经贸有限公司 | Novel process for extracting pepper phospholipid from pepper |
| CN103134711A (en) * | 2013-01-25 | 2013-06-05 | 湖南省蔬菜研究所（辣椒新品种技术研究推广中心） | Method of fast extracting and measuring capsanthin from dry red pepper |
| CN104629487A (en) * | 2013-11-15 | 2015-05-20 | 李锦梁 | Method for extracting capsanthin by using ethanol |
| CN105694528A (en) * | 2016-03-11 | 2016-06-22 | 广州华宝食品有限公司 | Preparation method of water-dispersible capsanthin |
| CN106912946A (en) * | 2017-01-22 | 2017-07-04 | 嵊州市派特普科技开发有限公司 | The extraction preparation method of Red Pigment from Strawberry |
| CN107418246A (en) * | 2017-07-25 | 2017-12-01 | 河北东之星生物科技股份有限公司 | A kind of water soluble capsanthin pigment |
| CN107501068A (en) * | 2017-09-01 | 2017-12-22 | 苏州农业职业技术学院 | A kind of method that capsaicine is sloughed in food-grade haematochrome production process |
-
1992
- 1992-10-21 CN CN 92112171 patent/CN1083831A/en active Pending
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1740236B (en) * | 2004-08-23 | 2010-12-01 | 黄启强 | Production process of capsorubin and capsaicine |
| CN1318391C (en) * | 2005-07-08 | 2007-05-30 | 上海雷辣婆食品有限公司 | Method of extracting capsaicin and capsaithin from red pepper |
| CN100402609C (en) * | 2006-07-18 | 2008-07-16 | 天津晨光天然色素有限公司 | Process for producing water soluble capsanthin pigment |
| CN102181172A (en) * | 2011-03-09 | 2011-09-14 | 浙江大学 | Technique for preparing capsanthin pigment from chilies |
| CN102600294A (en) * | 2011-12-15 | 2012-07-25 | 武城县英潮经贸有限公司 | Novel process for extracting pepper phospholipid from pepper |
| CN103134711A (en) * | 2013-01-25 | 2013-06-05 | 湖南省蔬菜研究所（辣椒新品种技术研究推广中心） | Method of fast extracting and measuring capsanthin from dry red pepper |
| CN104629487A (en) * | 2013-11-15 | 2015-05-20 | 李锦梁 | Method for extracting capsanthin by using ethanol |
| CN105694528A (en) * | 2016-03-11 | 2016-06-22 | 广州华宝食品有限公司 | Preparation method of water-dispersible capsanthin |
| CN106912946A (en) * | 2017-01-22 | 2017-07-04 | 嵊州市派特普科技开发有限公司 | The extraction preparation method of Red Pigment from Strawberry |
| CN107418246A (en) * | 2017-07-25 | 2017-12-01 | 河北东之星生物科技股份有限公司 | A kind of water soluble capsanthin pigment |
| CN107418246B (en) * | 2017-07-25 | 2019-05-24 | 河北东之星生物科技股份有限公司 | A kind of water soluble capsanthin pigment |
| CN107501068A (en) * | 2017-09-01 | 2017-12-22 | 苏州农业职业技术学院 | A kind of method that capsaicine is sloughed in food-grade haematochrome production process |
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| PB01 | Publication | ||
| C01 | Deemed withdrawal of patent application (patent law 1993) | ||
| WD01 | Invention patent application deemed withdrawn after publication |