CN108373836A - A kind of infrared/radar multi-Functional Camouflage coating and preparation method thereof - Google Patents

A kind of infrared/radar multi-Functional Camouflage coating and preparation method thereof Download PDF

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Publication number
CN108373836A
CN108373836A CN201611063313.7A CN201611063313A CN108373836A CN 108373836 A CN108373836 A CN 108373836A CN 201611063313 A CN201611063313 A CN 201611063313A CN 108373836 A CN108373836 A CN 108373836A
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CN
China
Prior art keywords
coating
added
infrared
method described
diluent
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Pending
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CN201611063313.7A
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Chinese (zh)
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不公告发明人
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Luoyang Institute Of Jianduan Technology
Luoyang Advanced Technology Research Institute
Luoyang Advanced Equipment Technology Co Ltd
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Luoyang Institute Of Jianduan Technology
Luoyang Advanced Equipment Technology Co Ltd
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Priority to CN201611063313.7A priority Critical patent/CN108373836A/en
Publication of CN108373836A publication Critical patent/CN108373836A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D175/00Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
    • C09D175/04Polyurethanes

Abstract

The present invention provides a kind of infrared/radar multi-Functional Camouflage coating and preparation method thereof, including:Aluminum paste is added to polyurethane lacquer, diluent is added in stirring;Polytetrafluoroethylene (PTFE) is added, is disperseed by dispersion machine, is stood;Curing agent and diluent are added later, stirring adjusts viscosity, obtains mixture;And mixture is sprayed on PI films, surface drying cures to obtain the coating of coating.This method significantly reduces the dielectric constant of infrared stealth coating using polytetrafluoroethylene (PTFE), avoids the screening to aluminum paste, greatly reduces the difficulty for preparing infrared stealth coating, and improves the compatible camouflage performance of infrared stealth coating and radar-wave absorbing plate.

Description

A kind of infrared/radar multi-Functional Camouflage coating and preparation method thereof
Technical field
The present invention relates to technical field of function materials, more particularly, to a kind of infrared/radar multi-Functional Camouflage coating and its Preparation method.
Background technology
In Military Application, for FJ, DD, ships and land relevant device, it is to reduce target and detected by enemy The possibility that system is found improves the fight capability and survival ability of tip equipment, and Infrared/Radar Compatible Stealth Materials, which become, to be studied Hot spot.
Currently, the means of most common radar invisible and infrared stealth compatibility are using the double-deck painting method, i.e., in radar Camouflage coating surface coats one layer of infrared stealth coating, real by the infrared emittance and microwave reflection rate that reduce target object Existing infrared/radar multi-Functional Camouflage.And for radar-wave absorbing plate, the Aluminum Pigment for infrared stealth coating is needed by screening, Reduce the reflectivity to microwave, to increase the compatible camouflage of infrared stealth coating and radar-wave absorbing plate, but in this method It is larger and limited to the performance of coating raising space that aluminium powder screens difficulty.
Meanwhile the dielectric constant of material and the microwave reflection rate of material are positively correlated, the small material of dielectric constant is more suitable for Therefore how material as infrared stealth coating in infrared/radar multi-Functional Camouflage coating reduces the dielectric of infrared stealth coating Constant, improving the compatibling problem of existing aluminium powder base infrared stealth coating and radar-wave absorbing plate becomes research hotspot.
Invention content
To solve the above-mentioned problems, the present invention reduces the dielectric of infrared coating using the excellent dielectric properties of polytetrafluoroethylene (PTFE) Constant.Polytetrafluoroethylene (PTFE) dielectric loss is small, breakdown voltage is high, is fabulous dielectric material, while can in the coating well Dispersion.By the way that polytetrafluoroethylene (PTFE) is added in the aluminum paste with special two-dimension plane structure, aluminum paste is significantly reduced The dielectric constant of infrared stealth coating, while the screening to aluminum paste is avoided, it greatly reduces and prepares infrared stealth coating Difficulty, and improve the compatible camouflage performance of infrared stealth coating and radar-wave absorbing plate.
The present invention provides a kind of methods preparing infrared/radar multi-Functional Camouflage coating, including:Aluminum paste is added to poly- Diluent is added in urethane varnish, stirring;Polytetrafluoroethylene (PTFE) is added, is disperseed by dispersion machine, stands;Curing agent and dilution is added Agent, stirring adjust viscosity, obtain mixture;And mixture is sprayed on polyimides (PI) film, surface drying, which cures, to be applied The coating of material.
In the above-mentioned methods, the mass ratio of aluminum paste, polyurethane lacquer and polytetrafluoroethylene (PTFE) is 3~4:1~2:1~2.
In the above-mentioned methods, the rotating speed of dispersion machine is 400~600rpm;The jitter time of dispersion machine is 5-10min.
In the above-mentioned methods, curing agent is isocyanates.
In the above-mentioned methods, diluent is toluene, dimethylbenzene, ethyl acetate, butyl acetate and propylene glycol methyl ether acetate It is one or more.
In the above-mentioned methods, viscosity is adjusted to 17~19s.
In the above-mentioned methods, it sprays as Air spraying.
In the above-mentioned methods, the thickness of coating is 30-40 μm.
In the above-mentioned methods, the cured temperature of surface drying is room temperature;The surface drying cured time is 10-14h.
The present invention also provides a kind of infrared/radar multi-Functional Camouflage coating prepared according to above method.
The present invention significantly reduces infrared stealth coating by polytetrafluoroethylene (PTFE) of the addition with excellent dielectric performance Dielectric constant effectively raises infrared stealth coating and thunder on the basis of maintaining the original infrared emittance of coating (< 0.2) Up to the multi-Functional Camouflage performance for inhaling wave plate.
Description of the drawings
Fig. 1 is the schematic diagram of infrared/radar multi-Functional Camouflage coating, wherein 1 is radar-wave absorbing plate, and 2 apply for infrared stealth Layer.
Specific implementation mode
The following examples can make those skilled in the art that the present invention be more fully understood, but not limit in any way The present invention.
Aluminum paste is added into polyurethane lacquer, 300~400rpm stirs 10-20min, and diluent is added;It is added poly- Tetrafluoroethene disperses 5-10min by the dispersion machine that rotating speed is 400~600rpm, stands 1-2h;Wherein, aluminum paste, polyurethane The mass ratio of varnish and polytetrafluoroethylene (PTFE) is 3~4:1~2:1~2.
Curing agent and diluent is added, 800~1000r/min stirs 15-20min, and adjustment viscosity is 17~19s, is obtained Mixture;Wherein, curing agent is isocyanates;Diluent is toluene, dimethylbenzene, ethyl acetate, butyl acetate and propylene glycol first Ether acetate it is one or more.
By mixture Air spraying on clean PI (polyimides) film, control coating layer thickness is 30-40 μm, at room temperature Surface drying cures 10-14h.
Coating after solidification is attached to progress microwave reflection rate test on radar-wave absorbing plate, then coating is taken off and uses IR-2 Type emissivity measurement instrument carries out infrared emittance test, while being situated between to coating with DP-ZJDB types dielectrometer Electric constant is tested.
Embodiment one
30g aluminum pastes are added into 70g polyurethane lacquers, 300r/min stirs 20min, and ethyl alcohol appropriate is added;Again 30g polytetrafluoroethylene (PTFE) is added, 5min is disperseed by the dispersion machine that rotating speed is 600rpm, stands 2h;
Later, isocyanates and toluene is added, 1000r/min stirs 15min, and adjustment viscosity is 17s, obtains mixture;
By mixture Air spraying on clean PI films, control coating layer thickness is 30 μm, and surface drying solidification 10h is obtained at room temperature To the coating of coating.
Embodiment two
20g aluminum pastes are added into 60g polyurethane lacquers, 400r/min stirs 15min, and normal propyl alcohol appropriate is added; 20g polytetrafluoroethylene (PTFE) is added, 8min is disperseed by the dispersion machine that rotating speed is 500rpm, stands 1.5h;
Later, isocyanates and dimethylbenzene is added, 900r/min stirs 18min, and adjustment viscosity is 18s, obtains mixture;
By mixture Air spraying on clean PI films, control coating layer thickness is 30 μm, and surface drying solidification 12h is obtained at room temperature To the coating of coating.
Embodiment three
40g aluminum pastes are added into 80g polyurethane lacquers, 350r/min stirs 10min, and isopropanol appropriate is added; 40g polytetrafluoroethylene (PTFE) is added, 10min is disperseed by the dispersion machine that rotating speed is 400rpm, stands 1h;
Later, isocyanates and dimethylbenzene is added, 950r/min stirs 16min, and adjustment viscosity is 18s, obtains mixture;
By mixture Air spraying on clean PI films, control coating layer thickness is 35 μm, and surface drying solidification 12h is obtained at room temperature To the coating of coating.
Example IV
30g aluminum pastes are added into 70g polyurethane lacquers, 400r/min stirs 15min, and ethyl alcohol appropriate is added;Again 30g polytetrafluoroethylene (PTFE) is added, 8min is disperseed by the dispersion machine that rotating speed is 500rpm, stands 1.5h;
Later, isocyanates, toluene and propylene glycol methyl ether acetate is added, 800r/min stirs 20min, and adjustment viscosity is 19s obtains mixture;
By mixture Air spraying on clean PI films, control coating layer thickness is 35 μm, and surface drying solidification 14h is obtained at room temperature To the coating of coating.
Embodiment five
30g aluminum pastes are added into 70g polyurethane lacquers, 320r/min stirs 18min, and normal propyl alcohol appropriate is added; 30g polytetrafluoroethylene (PTFE) is added, 9min is disperseed by the dispersion machine that rotating speed is 600rpm, stands 1.5h;
Later, isocyanates and dimethylbenzene is added, 950r/min stirs 20min, and adjustment viscosity is 18s, obtains mixture;
By mixture Air spraying on clean PI films, control coating layer thickness is 40 μm, and surface drying solidification 13h is obtained at room temperature To the coating of coating.
Embodiment six
30g aluminum pastes are added into 70g polyurethane lacquers, 350r/min stirs 15min, and isopropanol appropriate is added; 30g polytetrafluoroethylene (PTFE) is added, 9min is disperseed by the dispersion machine that rotating speed is 550rpm, stands 1h;
Later, isocyanates and toluene is added, 900r/min stirs 15min, and adjustment viscosity is 17s, obtains mixture;
By mixture Air spraying on clean PI films, control coating layer thickness is 40 μm, and surface drying solidification 10h is obtained at room temperature To the coating of coating.
Comparative example one
It is identical as embodiment one other than polytetrafluoroethylene (PTFE) is not added.
By the reflectivity difference of the above-mentioned data of measurement and the radar-wave absorbing plate for not spraying infrared stealth coating, infrared emission Rate and the measurement result of dielectric constant are as follows:
Table 1, test result:
By table 1 as it can be seen that the present invention is significantly reduced infrared by polytetrafluoroethylene (PTFE) of the addition with excellent dielectric performance The dielectric constant of camouflage coating reduces S-band (2~4GHz), C-band (4 on the basis of ensureing infrared emittance < 0.2 ~8GHz), the microwave reflection rate difference of X-band (8~12GHz) and Ku wave bands (12~18GHz), illustrate normal by reducing dielectric Several methods reduces the influence to radar invisible performance, increases the compatible camouflage of infrared stealth coating and radar-wave absorbing plate.
It will be understood by those skilled in the art that above example is only exemplary embodiment, in the spirit without departing substantially from the present invention In the case of range, a variety of variations can be carried out, replaced and changed.

Claims (10)

1. a kind of method preparing infrared/radar multi-Functional Camouflage coating, which is characterized in that including:
Aluminum paste is added to polyurethane lacquer, diluent is added in stirring;
Polytetrafluoroethylene (PTFE) is added, is disperseed by dispersion machine, stands;
Curing agent and diluent is added, stirring adjusts viscosity, obtains mixture;And
The mixture is sprayed on polyimides (PI) film, surface drying cures to obtain the coating of coating.
2. according to the method described in claim 1, it is characterized in that, the aluminum paste, the polyurethane lacquer and described poly- The mass ratio of tetrafluoroethene is 3~4:1~2:1~2.
3. according to the method described in claim 1, it is characterized in that, the rotating speed of the dispersion machine is 400~600rpm;Described point The jitter time for dissipating machine is 5-10min.
4. according to the method described in claim 1, it is characterized in that, the curing agent is isocyanates.
5. according to the method described in claim 1, it is characterized in that, the diluent is toluene, dimethylbenzene, ethyl acetate, vinegar Acid butyl ester and propylene glycol methyl ether acetate it is one or more.
6. according to the method described in claim 1, it is characterized in that, the viscosity is adjusted to 17~19s.
7. according to the method described in claim 1, it is characterized in that, the spraying is Air spraying.
8. according to the method described in claim 1, it is characterized in that, the thickness of the coating is 30-40 μm.
9. according to the method described in claim 1, it is characterized in that, the cured temperature of the surface drying is room temperature;The surface drying is solid The time of change is 10-14h.
10. infrared/radar multi-Functional Camouflage coating prepared by a kind of method according to any one of claim 1-9.
CN201611063313.7A 2016-11-28 2016-11-28 A kind of infrared/radar multi-Functional Camouflage coating and preparation method thereof Pending CN108373836A (en)

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Application Number Priority Date Filing Date Title
CN201611063313.7A CN108373836A (en) 2016-11-28 2016-11-28 A kind of infrared/radar multi-Functional Camouflage coating and preparation method thereof

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116285518A (en) * 2023-03-30 2023-06-23 西安赛福斯材料防护有限责任公司 Preparation method of room-temperature self-curing low-infrared-emissivity superhydrophobic coating

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103980806A (en) * 2014-05-22 2014-08-13 电子科技大学 Method for coating infrared stealth coating on object surface coated with radar absorbing coating
CN104990459A (en) * 2015-07-06 2015-10-21 苏州工业园区高性能陶瓷纤维工程中心有限公司 Radar stealth and infrared stealth integrated stealth tarpaulin and making method thereof

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN103980806A (en) * 2014-05-22 2014-08-13 电子科技大学 Method for coating infrared stealth coating on object surface coated with radar absorbing coating
CN104990459A (en) * 2015-07-06 2015-10-21 苏州工业园区高性能陶瓷纤维工程中心有限公司 Radar stealth and infrared stealth integrated stealth tarpaulin and making method thereof

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
王成彪等: "《摩擦学材料及表面工程》", 29 February 2012, 国防工业出版社 *

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN116285518A (en) * 2023-03-30 2023-06-23 西安赛福斯材料防护有限责任公司 Preparation method of room-temperature self-curing low-infrared-emissivity superhydrophobic coating

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Application publication date: 20180807