CN108373759A - A kind of radiation protection ultraviolet curable optical fiber coating and preparation method thereof - Google Patents
A kind of radiation protection ultraviolet curable optical fiber coating and preparation method thereof Download PDFInfo
- Publication number
- CN108373759A CN108373759A CN201611017513.9A CN201611017513A CN108373759A CN 108373759 A CN108373759 A CN 108373759A CN 201611017513 A CN201611017513 A CN 201611017513A CN 108373759 A CN108373759 A CN 108373759A
- Authority
- CN
- China
- Prior art keywords
- optical fiber
- ultraviolet curable
- minutes
- curable optical
- radiation protection
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
- C09D163/10—Epoxy resins modified by unsaturated compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Surface Treatment Of Glass Fibres Or Filaments (AREA)
Abstract
The invention discloses a kind of radiation protection ultraviolet curable optical fiber coatings, are made of the raw material of following parts by weight：Bisphenol A epoxy acrylate 40 47, trimethylolpropane trimethacrylate 14 19, tripropylene glycol double methacrylate 47, photoinitiator 1,173 24, five acrylate 9 13 of dipentaerythrityl ether, dibatyl phithalate 69, ureidopropyltriethoxysilane 12, p-hydroxyanisole 12, nano phase ag_2 o 58,4 methyl guaiacol and 4s 12, auxiliary agent 68.The ultraviolet curable optical fiber coating of the present invention has the advantages that film is plentiful, smooth, hardness is high, anti-radiation performance is strong simultaneously.
Description
Technical field
The present invention relates to a kind of fibre coating material, more particularly to a kind of radiation protection ultraviolet curable optical fiber coating and its system
Preparation Method.
Background technology
Optical fiber abbreviation optical fiber（opticalfiber）, it is a kind of fine-fibrous material made of plastics or glass,
Total reflection can be formed when light is passed through and is transmitted.Compared to loss of the electricity in electric wire transmission, light is in fiber optic transmission
In loss it is much lower, therefore, optical fiber low, small, bandwidth, anti-interference, light-weight, efficient with loss that it has
Many advantages, such as be widely used as long range information transmission material.The rapid development for being produced as modern communication technology of optical fiber is established
Solid foundation is determined.Common optical fiber type has silica fibre, fluorine-doped optical fiber, infrared optical fiber, composite fiber and fluorine chlorination
Object light fibre etc..The material of making optical fiber is mainly based on glass fibre.
In the production process of optical fiber, since the fibre diameter drawn out out of optical fiber furnace is small, matter is crisp easily broken, contact is empty
Oxidation and absorption dust, moisture are easy after gas to influence the using effect of optical fiber.It therefore, will be at once after fibre-optical drawing forming
Painting coats to be protected, and moreover, optical fiber coatings can also enhance the mechanical strength of optical fiber and improve the transporting of optical fiber
Energy.Therefore optical fiber coatings are most important in the application of optical fiber, are the important components of optical fiber.Coating for optical fiber coatings
Mode mainly has single layer coating and the double-deck coating, wherein the double-deck coating application is more.
Due to the complicated technology condition of optical fiber production and to the particular/special requirement of coating, the selection for coating type
It is particularly important.Traditional coating type has：Solvent based coating, thermoplastic coating, heat curing coating and ultraviolet-curing paint
Etc. types.The all types of coating of Integrated comparative, ultraviolet-curing paint is volatilized with it without a large amount of solvents, curing rate is fast, applies film property
The excellent equal excellent performances of energy have become the first choice of optical fiber coatings.The ultraviolet curable optical fiber coating occurred currently on the market is deposited
In the deficiency of anti-radiation performance and solidification effect difference, the performance of optical fiber has been seriously affected.
Invention content
It is an object of the invention to overcome the above-mentioned deficiency of not radiation protection in the presence of existing ultraviolet curable optical fiber coating,
A kind of radiation protection ultraviolet curable optical fiber coating is provided.The present invention ultraviolet curable optical fiber coating have film it is plentiful, it is smooth,
The advantage that hardness is high, anti-radiation performance is strong, the present invention additionally provide the preparation method of the ultraviolet curable optical fiber coating simultaneously.
In order to achieve the above-mentioned object of the invention, the present invention provides following technical schemes：
A kind of radiation protection ultraviolet curable optical fiber coating is made of the raw material of following parts by weight：Bisphenol A epoxy acrylate
40-47, trimethylolpropane trimethacrylate 14-19, tripropylene glycol double methacrylate 4-7,1173 2-4 of photoinitiator, two
Five acrylate 9-13 of contracting pentaerythrite, dibatyl phithalate 6-9, ureidopropyltriethoxysilane 1-2, para hydroxybenzene first
Ether 1-2, nano phase ag_2 o 5-8,4- methyl guaiacol and 4 1-2, auxiliary agent 6-8；
The auxiliary agent is made from the following raw materials in parts by weight：Zircon 6-9, nano silicon dioxide 4-6, benzoin dimethylether 3-5,
Three (2- ethoxys) isocyanuric acid ester 2-4, poly- methylol siloxanes 1-3, ethylene bottom oil 30-34；Preparation method is by zircon
It is put into calcining furnace and is calcined 2-4 hours at 450-490 DEG C, take out, 50-100 purposes are ground into together with nano silicon dioxide
Mixed-powder；Remaining residual components is mixed, is heated to 60-70 DEG C, mixed-powder is added after 20-30 minutes in stirring, and heat preservation is ground
Mill 1-2 hours to get.
Another object of the present invention is to provide the preparation methods of above-mentioned ultraviolet curable optical fiber coating, by walking in detail below
It is rapid to be made：
（1）Bisphenol A epoxy acrylate, trimethylolpropane trimethacrylate, tripropylene glycol double methacrylate are put into instead
It answers in kettle and stirs, be heated to 75-85 DEG C, stir 15-20 minutes；
（2）Remaining residual components in addition to photoinitiator 1173 are added, continue to be stirred to react 30-40 minutes, it is equal to be allowed to dispersion
It is even；（3）It is finally cooled to 45-55 DEG C, photoinitiator 1173 is added, is stirred to react 20-25 minutes, after cooling, grinding obtains 20-
40 μm of slurries to get.
Compared with prior art, beneficial effects of the present invention：
The radiation protection ultraviolet curable optical fiber coating of the present invention is through microwave prepolymerization and photocuring by hydrophobic dura mater and coating Central Plains
The SiO that position generates2Nano-particle is combined, and be ensure that inorganic nanoparticles in the coating evenly dispersed, is improved coating
Shielding property；The ultraviolet curable optical fiber coating of the present invention has that film is plentiful, smooth, hardness is high, anti-radiation performance is strong simultaneously
The advantages of.
Specific implementation mode
With reference to test example and specific implementation mode, the present invention is described in further detail.But this should not be understood
It is only limitted to embodiment below for the range of the above-mentioned theme of the present invention, it is all that this is belonged to based on the technology that the content of present invention is realized
The range of invention.
Embodiment 1
A kind of radiation protection ultraviolet curable optical fiber coating is made of the raw material of following parts by weight：Bisphenol A epoxy acrylate
43, trimethylolpropane trimethacrylate 16, tripropylene glycol double methacrylate 5, photoinitiator 1,173 3, dipentaerythrityl ether
Five acrylate 11, dibatyl phithalate 7, ureidopropyltriethoxysilane 1.5, p-hydroxyanisole 1, nano phase ag_2 o
6,4- methyl guaiacol and 4s 2, auxiliary agent 7；
The auxiliary agent is made from the following raw materials in parts by weight：Zircon 8, nano silicon dioxide 5, benzoin dimethylether 4, three (2-
Ethoxy) isocyanuric acid ester 3, poly- methylol siloxanes 2, ethylene bottom oil 32；Preparation method is that zircon is put into calcining furnace
It is calcined 3 hours at 470 DEG C, takes out, the mixed-powder of 70 mesh is ground into together with nano silicon dioxide；By remaining residual components
Mixing, is heated to 65 DEG C, and stirring is added mixed-powder after 25 minutes, heat preservation grinding 1.5 hours to get.
The preparation method of above-mentioned safety and environmental protection radiation protection ultraviolet curable optical fiber coating, includes the following steps：
（1）Bisphenol A epoxy acrylate, trimethylolpropane trimethacrylate, tripropylene glycol double methacrylate are put into instead
It answers in kettle and stirs, be heated to 79 DEG C, stir 15 minutes；
（2）Remaining residual components in addition to photoinitiator 1173 are added, continues to be stirred to react 32 minutes, is allowed to be uniformly dispersed；
（3）46 DEG C are finally cooled to, photoinitiator 1173 is added, is stirred to react 22 minutes, after cooling, grinding obtains 25 μm of slurries, i.e.,
.
Claims (2)
1. a kind of radiation protection ultraviolet curable optical fiber coating, which is characterized in that be made of the raw material of following parts by weight：Bis-phenol
It is A epoxy acrylates 40-47, trimethylolpropane trimethacrylate 14-19, tripropylene glycol double methacrylate 4-7, light-initiated
1173 2-4 of agent, five acrylate 9-13 of dipentaerythrityl ether, dibatyl phithalate 6-9, ureidopropyltriethoxysilane
1-2, p-hydroxyanisole 1-2, nano phase ag_2 o 5-8,4- methyl guaiacol and 4 1-2, auxiliary agent 6-8；
The auxiliary agent is made from the following raw materials in parts by weight：Zircon 6-9, nano silicon dioxide 4-6, benzoin dimethylether 3-5,
Three (2- ethoxys) isocyanuric acid ester 2-4, poly- methylol siloxanes 1-3, ethylene bottom oil 30-34；Preparation method is by zircon
It is put into calcining furnace and is calcined 2-4 hours at 450-490 DEG C, take out, 50-100 purposes are ground into together with nano silicon dioxide
Mixed-powder；Remaining residual components is mixed, is heated to 60-70 DEG C, mixed-powder is added after 20-30 minutes in stirring, and heat preservation is ground
Mill 1-2 hours to get.
2. a kind of radiation protection ultraviolet curable optical fiber coating according to claim 1, which is characterized in that by walking in detail below
Suddenly it is made：
（1）Bisphenol A epoxy acrylate, trimethylolpropane trimethacrylate, tripropylene glycol double methacrylate are put into instead
It answers in kettle and stirs, be heated to 75-85 DEG C, stir 15-20 minutes；
（2）Remaining residual components in addition to photoinitiator 1173 are added, continue to be stirred to react 30-40 minutes, it is equal to be allowed to dispersion
It is even；（3）It is finally cooled to 45-55 DEG C, photoinitiator 1173 is added, is stirred to react 20-25 minutes, after cooling, grinding obtains 20-
40 μm of slurries to get.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611017513.9A CN108373759A (en) | 2016-11-21 | 2016-11-21 | A kind of radiation protection ultraviolet curable optical fiber coating and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201611017513.9A CN108373759A (en) | 2016-11-21 | 2016-11-21 | A kind of radiation protection ultraviolet curable optical fiber coating and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108373759A true CN108373759A (en) | 2018-08-07 |
Family
ID=63016170
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201611017513.9A Withdrawn CN108373759A (en) | 2016-11-21 | 2016-11-21 | A kind of radiation protection ultraviolet curable optical fiber coating and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108373759A (en) |
-
2016
- 2016-11-21 CN CN201611017513.9A patent/CN108373759A/en not_active Withdrawn
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN102070981B (en) | Ultraviolet curing paint and preparation method and application thereof | |
| KR101910202B1 (en) | Resin system comprising dispersed multimodel surface-modified nanoparticles | |
| CN101466807B (en) | Bonding method with flowable adhesive composition | |
| CN103436111B (en) | A kind of preparation method of the water-based ultraviolet shielded coating based on ZnO quantum dot | |
| CN107236425B (en) | Self-cleaning ultraviolet curing transparent heat-insulating coating and preparation method thereof | |
| TW201240822A (en) | Containing material containing organic-inorganic composite, organic-inorganic composite film and antireflective member | |
| CN110964416B (en) | Weather-resistant wear-resistant polyester resin, powder coating and preparation method thereof | |
| CN102492320B (en) | Quick-curing polyimide coating for high-temperature-resistant optical fiber | |
| CN109321188B (en) | Preparation method of UV-heat dual-curing adhesive with low thermal expansion coefficient and low moisture permeability | |
| CN103342947B (en) | Novel two-dimensional nano paint | |
| CN113414081B (en) | Coating composition of colorful material, colorful material and preparation method of colorful material | |
| CN110128855A (en) | A kind of preparation method containing silicon dioxide hollow particle anti-reflective coating composition | |
| CN105566962A (en) | Photo-curable paint with low refractive index | |
| CN105121564A (en) | Coating composition | |
| CN106243988A (en) | High solid content water ultraviolet curing transparent insulating moulding coating and preparation method thereof | |
| CN112920691B (en) | High-strength anti-aging optical fiber outer coating and preparation method thereof | |
| CN108531047B (en) | Water-based epoxy resin fire-resistant paint, preparation method and application thereof | |
| CN108373759A (en) | A kind of radiation protection ultraviolet curable optical fiber coating and preparation method thereof | |
| CN113122094A (en) | Temperature-sensitive color-changing artistic coating and preparation method thereof | |
| CN108373619A (en) | A kind of ageing-resistant anti-flaming ultraviolet radiation solidifying optical fiber coatings and preparation method thereof | |
| CN109796917A (en) | A kind of preparation method of UV cured polyurethane acrylate adhesive | |
| CN106519755A (en) | Wear-resistant ultraviolet-cured coating for optical fiber and preparation method thereof | |
| CN108373730A (en) | A kind of antibacterial flame-retardant ultraviolet curable optical fiber coating and preparation method thereof | |
| CN106832089B (en) | A kind of nano silica-acrylic acid composite fluorescence resin and preparation method thereof | |
| CN104945985A (en) | UV-curable environment-friendly coating |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180807 |