CN108373558A - A kind of movable machinery non-slip mat - Google Patents

A kind of movable machinery non-slip mat Download PDF

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Publication number
CN108373558A
CN108373558A CN201810130006.9A CN201810130006A CN108373558A CN 108373558 A CN108373558 A CN 108373558A CN 201810130006 A CN201810130006 A CN 201810130006A CN 108373558 A CN108373558 A CN 108373558A
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China
Prior art keywords
antiseptic
zeolite
slip mat
tio
added
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CN201810130006.9A
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Chinese (zh)
Inventor
黄信文
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Shenzhen Shengda Machine Design Co Ltd
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Shenzhen Shengda Machine Design Co Ltd
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Priority to CN201810130006.9A priority Critical patent/CN108373558A/en
Publication of CN108373558A publication Critical patent/CN108373558A/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L21/00Compositions of unspecified rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/04Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material
    • B32B25/042Layered products comprising a layer of natural or synthetic rubber comprising rubber as the main or only constituent of a layer, which is next to another layer of the same or of a different material of natural rubber or synthetic rubber
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B25/00Layered products comprising a layer of natural or synthetic rubber
    • B32B25/10Layered products comprising a layer of natural or synthetic rubber next to a fibrous or filamentary layer
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B3/00Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form
    • B32B3/26Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer
    • B32B3/30Layered products comprising a layer with external or internal discontinuities or unevennesses, or a layer of non-planar shape; Layered products comprising a layer having particular features of form characterised by a particular shape of the outline of the cross-section of a continuous layer; characterised by a layer with cavities or internal voids ; characterised by an apertured layer characterised by a layer formed with recesses or projections, e.g. hollows, grooves, protuberances, ribs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B33/00Layered products characterised by particular properties or particular surface features, e.g. particular surface coatings; Layered products designed for particular purposes not covered by another single class
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B5/00Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts
    • B32B5/02Layered products characterised by the non- homogeneity or physical structure, i.e. comprising a fibrous, filamentary, particulate or foam layer; Layered products characterised by having a layer differing constitutionally or physically in different parts characterised by structural features of a fibrous or filamentary layer
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/02Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds
    • C08G63/12Polyesters derived from hydroxycarboxylic acids or from polycarboxylic acids and polyhydroxy compounds derived from polycarboxylic acids and polyhydroxy compounds
    • C08G63/16Dicarboxylic acids and dihydroxy compounds
    • C08G63/18Dicarboxylic acids and dihydroxy compounds the acids or hydroxy compounds containing carbocyclic rings
    • C08G63/181Acids containing aromatic rings
    • C08G63/183Terephthalic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
    • C08G63/00Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
    • C08G63/78Preparation processes
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • D01F1/103Agents inhibiting growth of microorganisms
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/88Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/92Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polycondensation products as major constituent with other polymers or low-molecular-weight compounds of polyesters
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/02Synthetic macromolecular fibres
    • B32B2262/0276Polyester fibres
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/714Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145Rot proof, resistant to bacteria, mildew, mould, fungi
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00Properties of the layers or laminate
    • B32B2307/70Other properties
    • B32B2307/744Non-slip, anti-slip
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B32LAYERED PRODUCTS
    • B32BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2471/00Floor coverings
    • B32B2471/04Mats
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2248Oxides; Hydroxides of metals of copper
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/14Polymer mixtures characterised by other features containing polymeric additives characterised by shape
    • C08L2205/16Fibres; Fibrils

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Artificial Filaments (AREA)

Abstract

The present invention relates to a kind of movable machinery non-slip mats, including non skid matting layer, middle composite layer, bottom surface layer three-decker, the non skid matting layer is made of rubber material, it is provided with multiple raised points on the non skid matting layer, the middle composite layer is mixed by complex fiber material as glue material is made, the composite fibre is provided projectingly described above glue material, and the bottom surface layer is made of polyester fiber mixed rubber material;The complex fiber material is antibacterial polyester fibre, and the antibacterial polyester fibre includes according to weight percent:One 0.7wt.% of antiseptic, two 0.3wt.% of antiseptic, polyester fiber surplus.

Description

A kind of movable machinery non-slip mat
Technical field
The present invention relates to move materials technical field more particularly to a kind of movable machinery non-slip mats.
Background technology
In recent years, sport and body-building increasingly by light people like that various sports equipments are required for using non-slip mat, non-slip mat It can ensure that the safety of body-building personnel, inferior non-slip mat can cause the pollution of environment in body-building pipe interior.
Invention content
The present invention is intended to provide a kind of movable machinery non-slip mat, set forth above to solve the problems, such as.
Provide a kind of movable machinery non-slip mat in the embodiment of the present invention, including non skid matting layer, middle composite layer, Bottom surface layer three-decker,
The non skid matting layer is made of rubber material, multiple raised points is provided on the non skid matting layer, in described Between composite layer mixed by complex fiber material and be made as glue material, the composite fibre is provided projectingly described as on glue material Side, the bottom surface layer are made of polyester fiber mixed rubber material;
The complex fiber material is antibacterial polyester fibre, and the antibacterial polyester fibre includes according to weight percent:It is anti- One 0.7wt.% of microbial inoculum, two 0.3wt.% of antiseptic, polyester fiber surplus.
Preferably, the antiseptic one is the TiO prepared using agglutinating nature yeast2/ zeolite antibacterial agent, zeolite are carrier, TiO2In doped with metal Ca2+Ion;TiO2The TiO in/zeolite2Load capacity be 35wt.%, Ca2+Ion is in TiO2Middle doping Mass fraction is 1.7wt.%.
Preferably, the antiseptic two is the Cu prepared using agglutinating nature yeast2O/ zeolite antibacterial agents, zeolite are carrier, Cu2Doped with metal Ag in O+Ion;Cu2The Cu in O/ zeolites2The load capacity of O is 27wt.%, Ag+Ion is in Cu2It is adulterated in O Mass fraction is 0.9wt.%.
The technical solution that the embodiment of the present invention provides can include the following benefits:
Movable machinery non-slip mat of the present invention can be used on sports apparatus, and easy to use, Environmental Safety, good antiskid effect is simultaneously And active force is lasting, has a good application prospect.
The additional aspect of the present invention and advantage will be set forth in part in the description, and will partly become from the following description Obviously, or practice through the invention is recognized.It should be understood that above general description and following detailed description are only It is exemplary and explanatory, the present invention can not be limited.
Description of the drawings
Using attached drawing, the invention will be further described, but the embodiment in attached drawing does not constitute any limit to the present invention System, for those of ordinary skill in the art, without creative efforts, can also obtain according to the following drawings Other attached drawings.
Fig. 1 is the structural schematic diagram of non-slip mat described in embodiment of the present invention.
Specific implementation mode
Example embodiments are described in detail here, and the example is illustrated in the accompanying drawings.Following description is related to When attached drawing, unless otherwise indicated, the same numbers in different drawings indicate the same or similar elements.Following exemplary embodiment Described in embodiment do not represent and the consistent all embodiments of the present invention.On the contrary, they be only with it is such as appended The example of the consistent device and method of some aspects being described in detail in claims, of the invention.
In conjunction with Fig. 1, the embodiment of the present invention is related to a kind of movable machinery non-slip mat, including:Non skid matting layer 1, centre Composite layer 2,3 three-decker of bottom surface layer, the non skid matting layer 1 are made of rubber material, are provided on the non skid matting layer 1 Multiple raised points 4, the middle composite layer 2 are mixed by complex fiber material and are made as glue material, and the composite fibre protrusion is set It sets described above glue material, the bottom surface layer 3 is made of polyester fiber mixed rubber material.
Among the above, complex fiber material described in middle composite layer 2 with as glue material mixed proportion be 3:5.
Further, the mixed proportion of polyester fiber and rubber material is 2 in the bottom surface layer:6.
Further, the thickness of the middle composite layer is within the scope of 3mm-5mm.
Further, the thickness of the bottom surface layer is in 2mm-6mm ranges.
In conclusion movable machinery non-slip mat of the present invention can be used on sports apparatus, easy to use, Environmental Safety is prevented Sliding effect is good and active force is lasting, has a good application prospect.
A kind of embodiment is that the complex fiber material is antibacterial polyester fibre.It is given birth to the development of economy with the modern times The flat continuous improvement of running water, people increasingly pay attention to clean environment and self-protection.Microorganism and daily life contact Very close, people live among the encirclement of microorganism, however, some microorganisms are huge to people's harm, suitable Meeting mass propagation, leads to the propagation and sprawling of pathogenic bacteria under environment.Day, commonly used polyester fiber articles for use were due to porous Property, dampness etc., be particularly suitable for the breeding of bacterium, can not only give off an unpleasant smell, skin but will be stimulated to induce various diseases Disease, therefore, the antibiotic property of polyester fiber are particularly important.
Above-mentioned antibacterial polyester fibre forming process is:Antiseptic one, antiseptic two are mixed to form antimicrobial mix, so Pure PET is sliced afterwards and is blended with antimicrobial mix, prepares antibacterial modified PET slices, then resisted by melt spinning mode Bacterium antibacterial polyester fibre of good performance.
When it is implemented, the antiseptic one is a kind of TiO2/ zeolite antibacterial agent, the antiseptic two are a kind of Cu2O/ zeolites are anti- Microbial inoculum.In above-mentioned antibacterial polyester fibre, include according to weight percent:One 0.7wt.% of antiseptic, two 0.3wt.% of antiseptic, Polyester fiber surplus.By controlling the percentage of antiseptic, anti-microbial property can be maximumlly played.In antibiosis, nothing Machine antiseptic has that inorganic constituents stability, antibacterial wide spectrum, chemical stability is good, washing fastness is good, durable antibacterial effect, heat are steady The advantages that qualitative good.Inorganic antiseptic is combined with polyester fiber, good antibacterial effect can be played.Currently, inorganic antibacterial The exploitation and preparation of agent are the emphasis of antibacterial polyester fibre, in prior art, for antibacterial polyester fibre, typically in fibre Antiseptic is either directly appended in polyester by dimension table face electroless plating antibacterial metal, obtained polyester fiber anti-microbial property It is not ideal enough, and washability is poor.In technical solution of the present invention, by being modified to antiseptic, two kinds of antiseptics are mixed It closes and forms mixing antiseptic, then, mixing antiseptic is blended with PET slices, then remelted spinning obtains antibacterial polyester fibre Dimension.On the one hand, it uses zeolite as carrier in antiseptic, the dispersibility of antiseptic in the polyester can be enhanced, it on the other hand, will PET is sliced to be blended with mixing antiseptic, which can give full play to antibacterial effect, play unexpected technology Effect so that antibiotic property, the washability of polyester fiber are largely increased.
Antiseptic one is described below:
The antiseptic one is the TiO prepared using agglutinating nature yeast2/ zeolite antibacterial agent, zeolite are carrier, TiO2Middle doping There is metal Ca2+Ion.Specifically, antiseptic one, TiO2The TiO in/zeolite2Load capacity be 35wt.%, Ca2+Ion exists TiO2Middle doping mass fraction is 1.7wt.%, and the grain size of zeolite is 15 μm, and granularity is 800 mesh, density 2.19g/cm3, zeolite Industrial products selected from Lingchuan County Zeolite mineral.
Zeolite is a kind of natural carrier mass, has the characteristics that porous structure, have excellent absorption, ion exchange and Catalytic performance has application, zeolitic material to be used for work in water process, feed, Industrial Catalysis, building trade, pharmaceuticals industry etc. The research of industry catalysis it has been reported that but the research that is applied in polyester fiber have not been reported.Based on above-mentioned background, this hair It is bright in polyester fiber, it is creative using zeolite as carrier, so use TiO2/ zeolite increases as antiseptic, this kind of structure The strong dispersibility of antiseptic in the polyester, while doped with metal Ca in antiseptic one2+Ion, Ca2+Ion addition can make Antiseptic is obtained for visible wavelength range influx and translocation, anti-microbial property enhancing achieves unexpected technique effect.Pass through The restriction of above-mentioned each content of material and size so that antiseptic one is combined performance antibacterial effect to reach most with antiseptic two It is good, produce unexpected technique effect.
The part material for preparing the antiseptic one is as follows:
Preparation process is:
Cleaning, natural zeolite is washed repeatedly with distilled water, dries 12h after filtering at 100 DEG C;Salt is added into flask Acid, potassium hydroxide, sodium chloride solution, then distilled water is added to be diluted to 80ml, control hydrochloric acid, potassium hydroxide, sodium chloride concentration difference For 0.5,0.4,0.9mol/L, 8.9g zeolites are added, heating water bath at the uniform velocity stirs 6h at 94 DEG C, is washed with distilled water to nothing Cl-Then residual calcines 12h at 100 DEG C, obtains modified zeolite;By butyl titanate, absolute ethyl alcohol, nitric acid with 6:24:1 Volume ratio mixes, and calcium chloride powder is added, control doping metals calcium ion is in TiO2In mass fraction be 1.7wt.%, room temperature Lower magnetic agitation 30min, is added above-mentioned modified zeolite so that TiO2:The mass ratio of zeolite is 35wt.%, stirs 10min, It is added and obtains gel with the isometric distilled water of salpeter solution, stirring 30min, gel is dried for 24 hours at 110 DEG C so that its Middle organic matter volatilization is complete, then the calcination processing 4h at 200 DEG C, grinding obtain the TiO2/ zeolite antibacterial agent, i.e. antiseptic One.
Antiseptic two is described below:
The antiseptic two is the Cu prepared using agglutinating nature yeast2O/ zeolite antibacterial agents, zeolite are carrier, Cu2It is adulterated in O There is metal Ag+Ion.Specifically, antiseptic two, Cu2The Cu in O/ zeolites2The load capacity of O is 27wt.%, Ag+Ion is in Cu2O Middle doping mass fraction is 0.9wt.%, and the grain size of zeolite is 15 μm, and granularity is 800 mesh, density 2.19g/cm3, zeolite choosing From the industrial products of Lingchuan County Zeolite mineral.
The part material for preparing the antiseptic two is as follows:
Preparation process is:
Zeolite modifying, with reference to antiseptic one;It takes 2.5g cupric sulfate pentahydrates to be dissolved in the distilled water of 20ml, then continuously stirs It mixes, while chlorination silver powder and above-mentioned modified zeolite is added, the sodium hydroxide that 0.5mol/L, 40ml is then added forms hydroxide Copper precipitates, and hereafter, the ascorbic acid solution of 1.2g, 50ml is added in the case of continuously stirring at room temperature, stirs 60min, 20min is centrifuged under 2000rpm, is finally washed with distilled water and absolute ethyl alcohol, and 80 DEG C of dry 10h obtain the Cu2O/ zeolites are anti- Microbial inoculum, i.e. antiseptic two.
The mixing of antiseptic:Above-mentioned antiseptic one, antiseptic two are mixed according to mass ratio, 5h is ground, is mixed Then mixture E is put into the sodium bicarbonate solution that mass fraction is 1.2%, acidification 2h by object E, filtering, cleaning are done After dry 12h, antimicrobial mix is obtained.In technical solution of the present invention, by the way that antiseptic one and antiseptic two are mixed, at acidification Reason so that antiseptic one, antiseptic two can be adulterated mutually, play unexpected technique effect so that polyester fiber Anti-microbial property greatly increases.
Blending method prepares antibacterial polyester fibre:
First, antimicrobial mix and ethylene glycol are mixed, ultrasound 5h at room temperature after stirring obtains mixed liquor;Then Mixed liquor and p-phthalic acid, catalyst aid are esterified, polymerize, obtains polyester master particle;Wherein, esterification temperature 280 DEG C, pressure 400KPa carries out polycondensation reaction when esterification yield reaches more than 94.5%, condensation temperature is 300 DEG C, is evacuated to 50Mpa, when polycondensation to inherent viscosity is 0.65, discharging, blank;
Then, polyester master particle is melted, is then fed into filter and is filtered, after metering, into spinning pack, incited somebody to action The tow of ejection carries out cooling, oils, and preoriented yarn is wound into after deflector roll, wherein spinning temperature is 290 DEG C, spinning speed For 3200m/min;
Then, polyester preoriented yarn can be prepared into antibacterial polyester fibre after a roller, hot tank, two rollers, scroll tube, winding, Wherein, draft speed 570m/min, draw ratio 3.1, a roll temperature are 90 DEG C, and two roll temperatures are 140 DEG C.
Embodiment 1
In the present embodiment, antiseptic one, antiseptic two are mixed to form mixing by a kind of good polyester fiber of anti-microbial property Then pure PET is sliced and is blended with mixing antiseptic by antiseptic, prepare antibacterial modified PET slices, then pass through melt spinning mode Obtain the good polyester fiber of anti-microbial property.
In above-mentioned polyester fiber, include according to weight percent:One 0.7wt.% of antiseptic, two 0.3wt.% of antiseptic, Polyester fiber surplus.
Wherein, which is the TiO prepared using agglutinating nature yeast2/ zeolite antibacterial agent, zeolite are carrier, TiO2 In doped with metal Ca2+Ion.TiO2The TiO in/zeolite2Load capacity be 35wt.%, Ca2+Ion doping in TiO2 Amount score is 1.7wt.%.
The antiseptic two is the Cu prepared using agglutinating nature yeast2O/ zeolite antibacterial agents, zeolite are carrier, Cu2It is adulterated in O There is metal Ag+Ion.Cu2The Cu in O/ zeolites2The load capacity of O is 27wt.%, Ag+Ion is in Cu2Mass fraction is adulterated in O is 0.9wt.%.
The grain size of zeolite is 15 μm, and granularity is 800 mesh, density 2.19g/cm3, zeolite is selected from Lingchuan County Zeolite mineral Industrial products.
The polyester fiber obtained for embodiment 1 carries out antibacterial test using concussion method, is carried out the following table is fiber sample After oscillating contact 30h, test result of the polyester fiber to Escherichia coli and staphylococcus aureus antibacterial effect:
According to GB 20944.3-2008-T it is found that when fiber or fabric are to Escherichia coli and staphylococcus aureus Fiber or fabric can be evaluated when bacteriostasis rate >=70% has antibacterial effect.
It can be seen that in embodiment 1, by adding antiseptic one, antiseptic two and forming antimicrobial mix, polyester Fiber has excellent antibacterial effect.
Using FZ/T73023-2006《Antibiosis knitting product》The simplification wash conditions and program of middle appendix C, in embodiment 1 Polyester fiber carries out standard wash, and wash conditions and step are:2g/L standard synthetic detergents, bath raio 1:30, water temperature 40 ± 3 DEG C, sample is put into, 5min is washed, then cleans 2min with tap water at normal temperatures, is calculated as washing 1 time.
Anti-microbial property after being washed 300 times the following table is polyester fiber in embodiment 1:
It can be seen that, by 100 times washing after, the bacteriostasis rate of antibacterial polyester fibre is declined slightly, but still have compared with Good antibacterial effect, anti-scourability are good.
The foregoing is merely the preferred modes of the present invention, are not intended to limit the invention, all spirit and original in the present invention Within then, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.

Claims (9)

1. a kind of movable machinery non-slip mat, which is characterized in that including non skid matting layer, middle composite layer, bottom surface layer three-layered node Structure,
The non skid matting layer is made of rubber material, and multiple raised points are provided on the non skid matting layer, and the centre is multiple It closes layer and is mixed for complex fiber material and is made as glue material, the composite fibre is provided projectingly above the picture glue material, institute Bottom surface layer is stated to be made of polyester fiber mixed rubber material;
The complex fiber material is antibacterial polyester fibre, and the antibacterial polyester fibre includes according to weight percent:Antiseptic One 0.7wt.%, two 0.3wt.% of antiseptic, polyester fiber surplus.
2. a kind of movable machinery non-slip mat according to claim 1, which is characterized in that the antiseptic one is using solidifying TiO prepared by glue-sol method2/ zeolite antibacterial agent, zeolite are carrier, TiO2In doped with metal Ca2+Ion;TiO2In/zeolite The TiO2Load capacity be 35wt.%, Ca2+Ion is in TiO2Middle doping mass fraction is 1.7wt.%.
3. a kind of movable machinery non-slip mat according to claim 1, which is characterized in that the antiseptic two is using solidifying Cu prepared by glue-sol method2O/ zeolite antibacterial agents, zeolite are carrier, Cu2Doped with metal Ag in O+Ion;Cu2In O/ zeolites The Cu2The load capacity of O is 27wt.%, Ag+Ion is in Cu2It is 0.9wt.% that mass fraction is adulterated in O.
4. a kind of movable machinery non-slip mat according to claim 2, any one of 3, which is characterized in that the zeolite Grain size is 15 μm, and granularity is 800 mesh, density 2.19g/cm3
5. a kind of movable machinery non-slip mat according to claim 1, which is characterized in that one preparation process of the antiseptic For:
Cleaning, natural zeolite is washed repeatedly with distilled water, dries 12h after filtering at 100 DEG C;Hydrochloric acid, hydrogen are added into flask Potassium oxide, sodium chloride solution, then distilled water is added to be diluted to 80ml, control hydrochloric acid, potassium hydroxide, sodium chloride concentration be respectively 0.5, 0.4,0.9mol/L, is added 8.9g zeolites, and heating water bath at the uniform velocity stirs 6h at 94 DEG C, is washed with distilled water to no Cl-It is residual It stays, 12h is then calcined at 100 DEG C, obtains modified zeolite;By butyl titanate, absolute ethyl alcohol, nitric acid with 6:24:1 volume ratio Calcium chloride powder is added in mixing, and control doping metals calcium ion is in TiO2In mass fraction be 1.7wt.%, at room temperature magnetic force 30min is stirred, above-mentioned modified zeolite is added so that TiO2:The mass ratio of zeolite be 35wt.%, stir 10min, be added with The isometric distilled water of salpeter solution stirs 30min, obtains gel, gel is dried for 24 hours at 110 DEG C so that wherein organic Object volatilization is complete, then the calcination processing 4h at 200 DEG C, and grinding obtains the TiO2/ zeolite antibacterial agent, i.e. antiseptic one;
Two preparation process of the antiseptic is:
Zeolite modifying, with reference to antiseptic one;It takes 2.5g cupric sulfate pentahydrates to be dissolved in the distilled water of 20ml, then continuously stirs, Chlorination silver powder and above-mentioned modified zeolite is added simultaneously, the sodium hydroxide that 0.5mol/L, 40ml is then added forms Kocide SD Hereafter the ascorbic acid solution of 1.2g, 50ml is added in precipitation in the case of continuously stirring at room temperature, stir 60min, 2000rpm Lower centrifugation 20min, is finally washed with distilled water and absolute ethyl alcohol, and 80 DEG C of dry 10h obtain the Cu2O/ zeolite antibacterial agents, i.e., Antiseptic two.
6. a kind of movable machinery non-slip mat according to claim 1, which is characterized in that compound described in middle composite layer Fibrous material with as glue material mixed proportion be 3:5.
7. a kind of movable machinery non-slip mat according to claim 1, which is characterized in that polyester fiber in the bottom surface layer Mixed proportion with rubber material is 2:6.
8. a kind of movable machinery non-slip mat according to claim 1, which is characterized in that the thickness of the middle composite layer Within the scope of 3mm-5mm.
9. a kind of movable machinery non-slip mat according to claim 1, which is characterized in that the thickness of the bottom surface layer exists 2mm-6mm ranges.
CN201810130006.9A 2018-02-08 2018-02-08 A kind of movable machinery non-slip mat Pending CN108373558A (en)

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CN205395309U (en) * 2016-03-09 2016-07-27 安庆市嘉欣医疗用品科技有限公司 Antibiotic textile non -woven fabrics
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CN1442518A (en) * 2002-03-06 2003-09-17 青岛大学 Manufacturing method of antibacteria fiber containing nano particles
CN101322497A (en) * 2008-07-08 2008-12-17 西南科技大学 Active stephanoporate mineral TiO2-doped composite catalytic antimicrobial material preparation and using method
CN104437443A (en) * 2014-10-10 2015-03-25 宁夏宝塔石化科技实业发展有限公司 Activation method for improving performance of adsorbing material in storage of natural gas
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Application publication date: 20180807