CN108358721A - A kind of preparation method of environment-friendly pesticide - Google Patents
A kind of preparation method of environment-friendly pesticide Download PDFInfo
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- CN108358721A CN108358721A CN201810173658.0A CN201810173658A CN108358721A CN 108358721 A CN108358721 A CN 108358721A CN 201810173658 A CN201810173658 A CN 201810173658A CN 108358721 A CN108358721 A CN 108358721A
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- preparation
- environment
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- friendly pesticide
- gum
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
- C05G3/60—Biocides or preservatives, e.g. disinfectants, pesticides or herbicides; Pest repellants or attractants
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05B—PHOSPHATIC FERTILISERS
- C05B7/00—Fertilisers based essentially on alkali or ammonium orthophosphates
-
- C—CHEMISTRY; METALLURGY
- C05—FERTILISERS; MANUFACTURE THEREOF
- C05G—MIXTURES OF FERTILISERS COVERED INDIVIDUALLY BY DIFFERENT SUBCLASSES OF CLASS C05; MIXTURES OF ONE OR MORE FERTILISERS WITH MATERIALS NOT HAVING A SPECIFIC FERTILISING ACTIVITY, e.g. PESTICIDES, SOIL-CONDITIONERS, WETTING AGENTS; FERTILISERS CHARACTERISED BY THEIR FORM
- C05G3/00—Mixtures of one or more fertilisers with additives not having a specially fertilising activity
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- Life Sciences & Earth Sciences (AREA)
- Pest Control & Pesticides (AREA)
- Chemical & Material Sciences (AREA)
- Organic Chemistry (AREA)
- Plant Pathology (AREA)
- Fertilizers (AREA)
Abstract
The present invention provides a kind of preparation method of environment-friendly pesticide, including following preparation process:A, ammonium polyphosphate, potassium dihydrogen phosphate, urea and filler are mixed, are blended into distilled water, saturated solution is made in stirring;B, biological adsorption agent is added in organic solvent, heated and stirred, filtered, filtration product is ground, material one is obtained;C, natural plant gum is mixed with deionized water, obtains solution one;D, material one, trace-element fertilizer and emulsifier are added in solution one, stir to get material two;E, dispersant is added into material two, after polycondensation reaction, heats, is cooled to room temperature.The preparation method of the present invention is simple, reasonable, and energy consumption is low, suitable for large-scale industrialized production.
Description
Technical field
The invention belongs to agricultural plantation technology fields, and in particular to a kind of preparation method of environment-friendly pesticide.
Background technology
Pesticide can be used for killing the biology of insect, fungi and the growth of other damages to crops.The pesticide used earliest has drop
DDT, six six six etc., they can largely eliminate pest.But their stability is good, can long-term existence in the environment, and planted dynamic
It constantly accumulates in object and human body, is eliminated thus.It used organophosphorus pesticide, such as DDVP instead later, and substituted initial pesticide.So
And they contain P elements, be easy to cause aquatic organism eutrophication.
Chinese patent CN104472480A discloses a kind of composition of degrading pesticide residues, and active constituent is by following heavy
The group of amount part is grouped as:1 part of algal polysaccharides, 0.05~20 part of rare earth:0.05~20 part of gibberellic acid.Degrading pesticide residues of the present invention
Composition can stablize under the premise of not influencing pesticide efficacy, the agriculture in crop products before harvest is greatly reduced
Medicine residual quantity, and surface of agricultural products pesticide residue can be removed and reduce the residual quantity that agricultural product include pesticide, in guarantee
The food security of city's crop products;And be prepared using convenient source, preparation method is simple, of low cost.
Chinese patent CN104342161A discloses a kind of degradating agent for residual agricultural chemicals, it is characterised in that:It contains following group
Point, 8 parts of butene dioic acid, 15 parts of butene dioic acid, 12 parts of alkyl benzene sulphonate, 15 parts of sodium carbonate, 10 parts of sodium sulphate, 56 parts of water, paddy Guang
5 parts of sweet peptide, 1 part of borax, 4 parts of calcium sulfate.The degradation agent further includes 6 parts of benzyl ring.The degradation agent further includes amino acid 18
Part.The degradating agent for residual agricultural chemicals of the invention can effectively improve soil, after the invention degradating agent for residual agricultural chemicals, on the one hand
Beneficial microbe in disinfectant generates a large amount of secondary metabolite in crop root mass propagation in reproductive process,
The formation of soil aggregate structure can thus be promoted.
Existing agricultural chemical insecticide is not degradable, or addition degradation of pesticide agent is needed to degrade pesticide residue, from
And cost is higher, and people often do not reprocess after applying pesticides, and pesticide is caused constantly to remain accumulation.
Invention content
The object of the present invention is to provide a kind of preparation methods of environment-friendly pesticide, and agricultural chemical insecticide prepared by the present invention is not only
There is desinsection, and degradation rate is high, and preparation method is simple, reasonable, energy consumption is low, suitable for the extensive life of industrialization
Production.
The present invention provides the following technical solutions:
A kind of preparation method of environment-friendly pesticide, including following preparation process:
A, ammonium polyphosphate, potassium dihydrogen phosphate, urea and filler are mixed, is imported in batch mixer, stir 20-30min, then be blended into steaming
Saturated solution is made in distilled water, stirring;
B, biological adsorption agent is added in organic solvent, 10-15min is heated and stirred at 100-130 DEG C, filtered, incited somebody to action
Filter product is ground, and is crossed 200-300 mesh sieve, is obtained material one;
C, natural plant gum is mixed with deionized water, is heated to dissolving at 80-100 DEG C, obtain solution one;
D, material one, trace-element fertilizer and emulsifier are added in solution one, at normal temperatures high-speed stirred 20-25min, stirring
Speed is 800-1000r/min, obtains material two;
E, dispersant is added into material two, after polycondensation reaction, 10-15min is heated at 60-70 DEG C, after being cooled to room temperature,
It can be obtained finished product.
Preferably, the filler of the step a is montmorillonite, diatomite, bentonite, kaolin, Attagel and attapulgite
The mixing of any one or more of.
Preferably, the biological adsorption agent of the step b is the mixed of cellulose, chitosan and sawdust any one or more of
It closes.
Preferably, the organic solvent of the step b is any in benzene,toluene,xylene, dichloromethane and ethyl acetate
Kind or a variety of mixing.
Preferably, the natural plant gum of the step c is any one of sesbania gum, guar gum, flax gum and fenugreek gum or more
The mixing of kind.
Preferably, the trace-element fertilizer of the step d is ammonium molybdate, copper nitrate, boric acid, borax, manganese sulfate, nitric acid
The mixing of manganese, zinc sulfate, zinc oxide and ferrous sulfate any one or more of.
Preferably, the emulsifier of the step d is poloxalkol, polyoxyethylene, detergent alkylate
Sulfoacid calcium, alkyl phenol polyoxyethylene ether, dibenzyl phenol polyoxyethylene ether, benzyl dimethyl phenol polyethenoxy ether, phenyl phenol are poly-
Ethylene oxide ether, phenylpropyl phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether, cumyl fluosite polycyclic
Oxygen ethylether, phenethyl phenol polyoxyethanyl polyoxyethyl propyl ether, disecoctylmaleate sodium sulfonate, di-2-ethylhexylphosphine oxide naphthalene sulfonic acids
Sodium, nonylphenol polyoxyethylene ether, polyoxyethylene sorbitan monooleate, double methyl naphthalene sulfonic acid sodium, diisobutyl naphthalene sulfonic acids
The mixing of sodium and polyvinyl alcohol any one or more of.
Preferably, the dispersant of the step e is calgon, potassium pyrophosphate, yellow acyl group calcium succinate, polyoxyethylene
Poiyoxypropylene copolymer, polyoxyethylene, alkyl sulfonates compound, nonionic hydroxyl polyethylene oxide block copolymer and
The mixing of alkylnaphthalene sulfonate formaldehyde condensation products block copolymer any one or more of.
The beneficial effects of the invention are as follows:
Agricultural chemical insecticide prepared by the present invention not only plays the role of desinsection, but also degradation rate is high, and preparation method is simple, closes
Reason, energy consumption is low, suitable for large-scale industrialized production.
Insecticide prepared by the present invention by pest control, nutrient necessary to plant be provided unite, it can be ensured that sterilization,
Apply fertilizer double effects, improves drug effect and pesticide utilization rate, reduces the waste of pesticide, fertilizer, effectively, science, rationally utilizes resource,
It having great significance to environmental protection, fertilising dispenser integration can effectively reduce agricultural production labour cost and time cost,
Positive impetus is also functioned to reducing the countryside tax system of user and the increasing both production and income of agricultural.
The degradation rate of insecticide stability prepared by the present invention, homogeneity, good fluidity, insecticide is high, and insecticidal effect is aobvious
It writes.
Specific implementation mode
Embodiment 1
A kind of preparation method of environment-friendly pesticide, including following preparation process:
A, ammonium polyphosphate, potassium dihydrogen phosphate, urea and filler are mixed, is imported in batch mixer, stir 30min, then be blended into distillation
Saturated solution is made in water, stirring;
B, biological adsorption agent is added in organic solvent, 10min is heated and stirred at 130 DEG C, filter, by filtration product into
Row grinding crosses 200 mesh sieve, obtains material one;
C, natural plant gum is mixed with deionized water, is heated to dissolving at 100 DEG C, obtain solution one;
D, material one, trace-element fertilizer and emulsifier are added in solution one, at normal temperatures high-speed stirred 20min, stirring speed
Degree is 1000r/min, obtains material two;
E, dispersant is added into material two, after polycondensation reaction, 10min is heated at 70 DEG C, after being cooled to room temperature, you can
To finished product.
The filler of step a is the mixing of montmorillonite, diatomite, bentonite, kaolin, Attagel and attapulgite.
The biological adsorption agent of step b is the mixing of cellulose, chitosan and sawdust.
The organic solvent of step b is the mixing of benzene,toluene,xylene, dichloromethane and ethyl acetate.
The natural plant gum of step c is the mixing of sesbania gum, guar gum, flax gum and fenugreek gum.
The trace-element fertilizer of step d is the mixing of ammonium molybdate, copper nitrate, boric acid, borax, manganese sulfate and ferrous sulfate.
The emulsifier of step d is poloxalkol, polyoxyethylene, calcium dodecyl benzene sulfonate, alkyl
Phenol polyethenoxy ether, dibenzyl phenol polyoxyethylene ether, benzyl dimethyl phenol polyethenoxy ether, phenyl phenol polyethenoxy ether, benzene
Propyl phenethyl phenol polyethenoxy ether, polyoxyethylene sorbitan monooleate, double methyl naphthalene sulfonic acid sodium, diisobutyl naphthalene sulphur
The mixing of sour sodium and polyvinyl alcohol.
The dispersant of step e is that calgon, potassium pyrophosphate, yellow acyl group calcium succinate, polyoxyethylene polyoxypropylene are total
The mixing of polymers, polyoxyethylene, alkyl sulfonates compound and alkylnaphthalene sulfonate formaldehyde condensation products block copolymer.
Embodiment 2
A kind of preparation method of environment-friendly pesticide, including following preparation process:
A, ammonium polyphosphate, potassium dihydrogen phosphate, urea and filler are mixed, is imported in batch mixer, stir 20min, then be blended into distillation
Saturated solution is made in water, stirring;
B, biological adsorption agent is added in organic solvent, 15min is heated and stirred at 100 DEG C, filter, by filtration product into
Row grinding crosses 200 mesh sieve, obtains material one;
C, natural plant gum is mixed with deionized water, is heated to dissolving at 80 DEG C, obtain solution one;
D, material one, trace-element fertilizer and emulsifier are added in solution one, at normal temperatures high-speed stirred 20min, stirring speed
Degree is 800r/min, obtains material two;
E, dispersant is added into material two, after polycondensation reaction, 10min is heated at 60 DEG C, after being cooled to room temperature, you can
To finished product.
The filler of step a is the mixing of montmorillonite, diatomite, bentonite, kaolin, Attagel and attapulgite.
The biological adsorption agent of step b is the mixing of cellulose, chitosan and sawdust.
The organic solvent of step b is the mixing of benzene,toluene,xylene, dichloromethane and ethyl acetate.
The natural plant gum of step c is the mixing of sesbania gum, guar gum, flax gum and fenugreek gum.
The trace-element fertilizer of step d is the mixing of ammonium molybdate, copper nitrate, boric acid, zinc oxide and ferrous sulfate.
The emulsifier of step d is poloxalkol, cumyl fluosite polycyclic oxygen ethylether, benzene second
Base phenol polyoxyethanyl polyoxyethyl propyl ether, disecoctylmaleate sodium sulfonate, sodium methylene bis-naphthalene sulfonate, polyoxyethylene nonyl phenyl second
Alkene ether, polyoxyethylene sorbitan monooleate, double methyl naphthalene sulfonic acid sodium, diisobutyl sodium naphthalene sulfonate and polyvinyl alcohol it is mixed
It closes.
The dispersant of step e is that calgon, potassium pyrophosphate, yellow acyl group calcium succinate, polyoxyethylene polyoxypropylene are total
Polymers, polyoxyethylene, alkyl sulfonates compound, nonionic hydroxyl polyethylene oxide block copolymer and alkyl naphthalene sulfonic acid
The mixing of salt formaldehyde condensation products block copolymer.
Embodiment 3
A kind of preparation method of environment-friendly pesticide, including following preparation process:
A, ammonium polyphosphate, potassium dihydrogen phosphate, urea and filler are mixed, is imported in batch mixer, stir 30min, then be blended into distillation
Saturated solution is made in water, stirring;
B, biological adsorption agent is added in organic solvent, 15min is heated and stirred at 130 DEG C, filter, by filtration product into
Row grinding crosses 300 mesh sieve, obtains material one;
C, natural plant gum is mixed with deionized water, is heated to dissolving at 100 DEG C, obtain solution one;
D, material one, trace-element fertilizer and emulsifier are added in solution one, at normal temperatures high-speed stirred 25min, stirring speed
Degree is 1000r/min, obtains material two;
E, dispersant is added into material two, after polycondensation reaction, 15min is heated at 70 DEG C, after being cooled to room temperature, you can
To finished product.
The filler of step a is the mixing of montmorillonite, diatomite, bentonite, kaolin, Attagel and attapulgite.
The biological adsorption agent of step b is the mixing of cellulose, chitosan and sawdust.
The organic solvent of step b is the mixing of benzene,toluene,xylene, dichloromethane and ethyl acetate.
The natural plant gum of step c is the mixing of sesbania gum, guar gum, flax gum and fenugreek gum.
The trace-element fertilizer of step d is ammonium molybdate, copper nitrate, boric acid, borax, manganese sulfate, manganese nitrate, zinc sulfate, oxygen
Change the mixing of zinc and ferrous sulfate.
The emulsifier of step d is poloxalkol, polyoxyethylene, calcium dodecyl benzene sulfonate, alkyl
Phenol polyethenoxy ether, dibenzyl phenol polyoxyethylene ether, benzyl dimethyl phenol polyethenoxy ether, phenyl phenol polyethenoxy ether, benzene
Propyl phenethyl phenol polyethenoxy ether, alkyl phenol formaldehyde resin polyoxyethylene ether, cumyl fluosite polycyclic oxygen ethylether, benzene
Ethyl phenol polyoxyethanyl polyoxyethyl propyl ether, disecoctylmaleate sodium sulfonate, sodium methylene bis-naphthalene sulfonate, polyoxyethylene nonyl phenyl
Vinethene, polyoxyethylene sorbitan monooleate, double methyl naphthalene sulfonic acid sodium, diisobutyl sodium naphthalene sulfonate and polyvinyl alcohol
Mixing.
The dispersant of step e is that calgon, potassium pyrophosphate, yellow acyl group calcium succinate, polyoxyethylene polyoxypropylene are total
Polymers, polyoxyethylene, alkyl sulfonates compound, nonionic hydroxyl polyethylene oxide block copolymer and alkyl naphthalene sulfonic acid
The mixing of salt formaldehyde condensation products block copolymer.
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to aforementioned reality
Applying example, invention is explained in detail, for those skilled in the art, still can be to aforementioned each implementation
Technical solution recorded in example is modified or equivalent replacement of some of the technical features.All essences in the present invention
With within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention god.
Claims (8)
1. a kind of preparation method of environment-friendly pesticide, which is characterized in that including following preparation process:
A, ammonium polyphosphate, potassium dihydrogen phosphate, urea and filler are mixed, is imported in batch mixer, stir 20-30min, then be blended into steaming
Saturated solution is made in distilled water, stirring;
B, biological adsorption agent is added in organic solvent, 10-15min is heated and stirred at 100-130 DEG C, filtered, incited somebody to action
Filter product is ground, and is crossed 200-300 mesh sieve, is obtained material one;
C, natural plant gum is mixed with deionized water, is heated to dissolving at 80-100 DEG C, obtain solution one;
D, material one, trace-element fertilizer and emulsifier are added in solution one, at normal temperatures high-speed stirred 20-25min, stirring
Speed is 800-1000r/min, obtains material two;
E, dispersant is added into material two, after polycondensation reaction, 10-15min is heated at 60-70 DEG C, after being cooled to room temperature,
It can be obtained finished product.
2. a kind of preparation method of environment-friendly pesticide according to claim 1, which is characterized in that the filler of the step a
For the mixing of montmorillonite, diatomite, bentonite, kaolin, Attagel and attapulgite any one or more of.
3. a kind of preparation method of environment-friendly pesticide according to claim 1, which is characterized in that the biology of the step b
Adsorbent is the mixing of cellulose, chitosan and sawdust any one or more of.
4. a kind of preparation method of environment-friendly pesticide according to claim 1, which is characterized in that the step b's is organic
Solvent is the mixing of benzene,toluene,xylene, dichloromethane and ethyl acetate any one or more of.
5. a kind of preparation method of environment-friendly pesticide according to claim 1, which is characterized in that the plant of the step c
Glue is the mixing of sesbania gum, guar gum, flax gum and fenugreek gum any one or more of.
6. a kind of preparation method of environment-friendly pesticide according to claim 1, which is characterized in that the step d's is micro
Element fertilizer is appointing in ammonium molybdate, copper nitrate, boric acid, borax, manganese sulfate, manganese nitrate, zinc sulfate, zinc oxide and ferrous sulfate
One or more mixing.
7. a kind of preparation method of environment-friendly pesticide according to claim 1, which is characterized in that the emulsification of the step d
Agent is poloxalkol, polyoxyethylene, calcium dodecyl benzene sulfonate, alkyl phenol polyoxyethylene ether, dibenzyl
Phenol polyoxyethylene ether, benzyl dimethyl phenol polyethenoxy ether, phenyl phenol polyethenoxy ether, phenylpropyl phenethyl phenol polyoxyethylene
Ether, alkyl phenol formaldehyde resin polyoxyethylene ether, cumyl fluosite polycyclic oxygen ethylether, phenethyl phenol polyoxyethanyl polyoxy third
Base ether, disecoctylmaleate sodium sulfonate, sodium methylene bis-naphthalene sulfonate, nonylphenol polyoxyethylene ether, polyoxyethylene
Sorbitol monooleate, double methyl naphthalene sulfonic acid sodium, diisobutyl sodium naphthalene sulfonate and polyvinyl alcohol any one or more of it is mixed
It closes.
8. a kind of preparation method of environment-friendly pesticide according to claim 1, which is characterized in that the dispersion of the step e
Agent is calgon, potassium pyrophosphate, yellow acyl group calcium succinate, poloxalkol, polyoxyethylene, alkyl sulphur
Barbiturates compound, nonionic hydroxyl polyethylene oxide block copolymer and alkylnaphthalene sulfonate formaldehyde condensation products block copolymerization
The mixing of object any one or more of.
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CN201810173658.0A CN108358721A (en) | 2018-03-02 | 2018-03-02 | A kind of preparation method of environment-friendly pesticide |
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Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105076129A (en) * | 2014-04-22 | 2015-11-25 | 广东华润涂料有限公司 | Insecticide microcapsules and preparation method thereof |
CN105622272A (en) * | 2016-02-15 | 2016-06-01 | 中国农业大学 | Suspension-type bactericide liquid medicine fertilizer and preparation method thereof |
CN105732199A (en) * | 2016-02-15 | 2016-07-06 | 中国农业大学 | Insecticide microcapsule suspension type liquid medicine fertilizer and preparation method and application thereof |
CN106719637A (en) * | 2016-11-25 | 2017-05-31 | 北京明德立达农业科技有限公司 | A kind of microcapsule suspension suspending agent containing fenoxanil and Prochloraz and preparation method thereof |
CN107232225A (en) * | 2017-05-31 | 2017-10-10 | 北京明德立达农业科技有限公司 | A kind of microcapsules suspension suspending agent containing gamma cyhalothrin and sulfoxaflor and preparation method thereof |
CN107258777A (en) * | 2017-06-21 | 2017-10-20 | 北京明德立达农业科技有限公司 | A kind of seed treatment microcapsules suspension suspending agent of pyraclostrobin-containing and fluorine azoles bacterium aniline and preparation method thereof |
-
2018
- 2018-03-02 CN CN201810173658.0A patent/CN108358721A/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN105076129A (en) * | 2014-04-22 | 2015-11-25 | 广东华润涂料有限公司 | Insecticide microcapsules and preparation method thereof |
CN105622272A (en) * | 2016-02-15 | 2016-06-01 | 中国农业大学 | Suspension-type bactericide liquid medicine fertilizer and preparation method thereof |
CN105732199A (en) * | 2016-02-15 | 2016-07-06 | 中国农业大学 | Insecticide microcapsule suspension type liquid medicine fertilizer and preparation method and application thereof |
CN106719637A (en) * | 2016-11-25 | 2017-05-31 | 北京明德立达农业科技有限公司 | A kind of microcapsule suspension suspending agent containing fenoxanil and Prochloraz and preparation method thereof |
CN107232225A (en) * | 2017-05-31 | 2017-10-10 | 北京明德立达农业科技有限公司 | A kind of microcapsules suspension suspending agent containing gamma cyhalothrin and sulfoxaflor and preparation method thereof |
CN107258777A (en) * | 2017-06-21 | 2017-10-20 | 北京明德立达农业科技有限公司 | A kind of seed treatment microcapsules suspension suspending agent of pyraclostrobin-containing and fluorine azoles bacterium aniline and preparation method thereof |
Non-Patent Citations (1)
Title |
---|
侯惠民等: "《药用辅料应用技术 第2版》", 31 July 2002, 中国医药科技出版社 * |
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