CN108358389A - A kind of harmless processing of large-scale pig farm biogas slurry and utilization of resources technique - Google Patents

A kind of harmless processing of large-scale pig farm biogas slurry and utilization of resources technique Download PDF

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Publication number
CN108358389A
CN108358389A CN201810193880.7A CN201810193880A CN108358389A CN 108358389 A CN108358389 A CN 108358389A CN 201810193880 A CN201810193880 A CN 201810193880A CN 108358389 A CN108358389 A CN 108358389A
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China
Prior art keywords
biogas slurry
utilization
liquid
solid
pig farm
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CN201810193880.7A
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Chinese (zh)
Inventor
姚建明
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NANTONG HAUDUO PIG BREEDING CO Ltd
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NANTONG HAUDUO PIG BREEDING CO Ltd
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Priority to CN201810193880.7A priority Critical patent/CN108358389A/en
Publication of CN108358389A publication Critical patent/CN108358389A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C05FERTILISERS; MANUFACTURE THEREOF
    • C05FORGANIC FERTILISERS NOT COVERED BY SUBCLASSES C05B, C05C, e.g. FERTILISERS FROM WASTE OR REFUSE
    • C05F7/00Fertilisers from waste water, sewage sludge, sea slime, ooze or similar masses
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • C02F1/281Treatment of water, waste water, or sewage by sorption using inorganic sorbents
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/20Nature of the water, waste water, sewage or sludge to be treated from animal husbandry
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/34Biological treatment of water, waste water, or sewage characterised by the microorganisms used
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02ATECHNOLOGIES FOR ADAPTATION TO CLIMATE CHANGE
    • Y02A40/00Adaptation technologies in agriculture, forestry, livestock or agroalimentary production
    • Y02A40/10Adaptation technologies in agriculture, forestry, livestock or agroalimentary production in agriculture
    • Y02A40/20Fertilizers of biological origin, e.g. guano or fertilizers made from animal corpses
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E50/00Technologies for the production of fuel of non-fossil origin
    • Y02E50/30Fuel from waste, e.g. synthetic alcohol or diesel

Abstract

The present invention relates to a kind of harmless processing of large-scale pig farm biogas slurry and utilization of resources techniques, include the following steps:(1)Poultry swine manure is collected using dry cleaning up excrement and is separated by solid-liquid separation;(2)By step(1)Biogas slurry by sewage draining passage enter the special taper reaction kettle in pretreatment system carry out adsorption treatment;(3)By step(2)Biogas slurry that treated is sent into aerobic system and carries out biochemical treatment;(4)To step(3)The liquid of acquisition is detected, if meeting livestock breeding wastewater discharge standard GB18596 2001, COD≤150mg/l, BOD≤400mg/l, ammonia nitrogen≤80mg/l then recycle and carry out Fertilizer Transformed utilization.The advantage of the invention is that:The present invention uses taper reaction kettle and aerobic system, can greatly reduce facility investment;Meanwhile by absorption, removing the pollution factor in the biogas slurry of pig farm;Biogas slurry after the adsorption treatment, then biochemical treatment is carried out by aerobic system, treated, and liquid meets livestock breeding wastewater discharge standard, recyclable progress Fertilizer Transformed utilization.

Description

A kind of harmless processing of large-scale pig farm biogas slurry and utilization of resources technique
Technical field
The invention belongs to the field for the treatment of of water pollution of environmental project, more particularly to a kind of harmless processing of large-scale pig farm biogas slurry And utilization of resources technique.
Background technology
With the continuous improvement of people's living standards, China's livestock and poultry breeding industry is grown rapidly.Livestock and poultry breeding industry has become me One of the pillar industry of state's agricultural development, wherein pig, the sheep number of animals raised rank first in the world, large scale of pig farm have reached 40% with On.But the fast development of large-scale cultivation industry, cause breeding waste (solid, liquid) to increase significantly, problem of environmental pollution Also it becomes increasingly conspicuous.
Regulations modellings in China are looked into fowl feces of farm and are generally handled using celebrating oxygen hair alcohol technique at present.Anaerobic fermentation technology It is widely used in terms of the bioenergy of sound feces of farm exploitation biogas, is realizing feces of farm recycling Meanwhile effectively reducing the primary pollution of feces of farm.However, while handling waste progress anaerobic fermentation utilization, Also a large amount of, concentrate, secondary pollutant-biogas residue and biogas slurry are produced.
Pass through aerobic hair ester along slag, organic fertilizer is made and returns soil, is utilized;But it is different from biogas residue.Biogas slurry Processing becomes problem.First, biogas slurry is liquid, and mobility and easily blocking the common reed are standby, and difficulty is enclosed in transport;Two, biogas slurry intensive quantity is big, becomes One evil, past, farm's ruleization degree are low, belong to peasant household's individual more and grow, oneself anaerobism hair, which is waken up, utilizes biogas, and biogas slurry is discharged into certainly It in the soil of family, is applied directly in soil alternatively, resting waste, has not only been effectively utilized the buckwheat point of liquid, but also ring will not be polluted Border.In recent years aquaculture large-scale degree be continuously improved and expand, it is adjoint and come largely control liquid, far from as before directly It connects as fertilizer on-site elimination.Third can be caused containing some harmful heavy metals, antibiotic, hormone in biogas slurry without processing Secondary pollution.4th, biogas slurry contains certain plant nutrient ingredient, and still, content is small.5th, to plant pest and beneficial at Divide and deposit, brings biogas slurry treatment technique and technical complexity.Therefore, biogas slurry is innoxious, recycling treatment and comprehensive profit With aquaculture industry of China is had become, the protrusion for controlling gas clean energy resource, agricultural environment pollution comprehensive treatment and agricultural sustainable development is asked Topic.
Through retrieval, 103274571 B of patent CN disclose the utilization of resources and the processing method of a kind of livestock breeding wastewater, Include the following steps:(1)Anaerobic digestion methane production;(2)Slagging-off;(3)Biological aerated filter is biochemical;(4)Disinfection;(5)Organic fertilizer Manufacture.The present invention is based on anaerobic digestion methane production technology, BAF technologies, disinfection technologies to be combined, and is money with livestock breeding wastewater Source handles it by anaerobic fermentation, produces biogas, produces the waste water after biogas again through being separated by solid-liquid separation, solid slag is used for conduct The raw material of organic fertilizer is produced, organic fertilizer is produced, waste water is recycled using BAF technologies and after sterilizing and qualified discharge, High treating effect, low energy consumption, and comprehensive utilization resource has economic benefit simultaneously.But supporting for meagre profit operation is in for China For growing industry, build that the required investment of such treatment for cow manure facility is too big, operating cost is excessively high.
Therefore, seek that facility investment is few, operating cost is low and the efficient large-scale pig farm biogas slurry of processing, it has also become solve to support Grow the key point of industry pollution.
Invention content
That the technical problem to be solved in the present invention is to provide a kind of facility investments is few, operating cost is low and being capable of efficient process rule The harmless processing of large-scale pig farm biogas slurry of modelling pig farm biogas slurry and utilization of resources technique.
In order to solve the above technical problems, the technical scheme is that:A kind of harmless processing of large-scale pig farm biogas slurry and money Source utilizes technique, innovative point to be:Include the following steps:
(1)Swine manure is collected using dry cleaning up excrement and is separated by solid-liquid separation, biogas residue and biogas slurry are obtained;
(2)By step(1)Biogas slurry the special taper reaction kettle in pretreatment system is entered by sewage draining passage, with 100 parts by weight Biogas slurry meter, the hydrated calcium chloroaluminate that 0.5~1.5wt% is then added into special taper reaction kettle carries out adsorption treatment, and stirs Mix 20~30min, natural subsidence after stirring is separated by solid-liquid separation, and obtains solid slag and treated biogas slurry;
(3)By step(2)Biogas slurry that treated is sent into aerobic system, with 100 parts by weight treated biogas slurry, then to aerobic system The active microorganism microbial inoculum that 0.4~0.6wt% is added in system carries out 40~60min of biochemical treatment, then natural subsidence, solid-liquid point From acquisition solid and liquid;
(4)To step(3)The liquid of acquisition is detected, if meeting livestock breeding wastewater discharge standard GB18596-2001, COD ≤ 150mg/l, BOD≤400mg/l, ammonia nitrogen≤80mg/l then recycle and carry out Fertilizer Transformed utilization.
Further, the step(3)In active microorganism microbial inoculum select growth promoting bacteria agent, bush mycorrhiza agent or biological prosthetic One or more of microbial inoculum.
The advantage of the invention is that:The harmless processing of large-scale pig farm biogas slurry of the present invention and utilization of resources technique, processing equipment Using taper reaction kettle and aerobic system, both equipment are commonly used equipment, can greatly reduce facility investment;Meanwhile with water Change calcium chloroaluminate and the pollution factor in the biogas slurry of pig farm is removed by absorption as adsorbent;Natural pond after the adsorption treatment Liquid, then biochemical treatment is carried out by aerobic system, treated, and liquid meets livestock breeding wastewater discharge standard, recyclable progress Fertilizer Transformed utilizes, and solves the disposal difficulties of prior art pig farm biogas slurry, realizes the recycling treatment of large-scale pig farm biogas slurry and comprehensive It closes and utilizes.
Specific implementation mode
The following examples can make professional and technical personnel that the present invention be more fully understood, but therefore not send out this It is bright to be limited among the embodiment described range.
Embodiment 1
The present embodiment is harmless processing and the utilization of resources technique of 500 ton per day large-scale pig farm biogas slurries, is included the following steps:
(1)Swine manure is collected using dry cleaning up excrement and is separated by solid-liquid separation, biogas residue and biogas slurry are obtained;The biogas slurry water quality index After measured as shown in table 1.
The water quality index of 1 biogas slurry of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 5.2 1080 960
(2)By step(1)Biogas slurry the special taper reaction kettle in pretreatment system is entered by sewage draining passage, with 100 parts by weight Biogas slurry meter, the hydrated calcium chloroaluminate that 0.5wt% is then added into special taper reaction kettle carries out adsorption treatment, and stirs 20min, natural subsidence after stirring are separated by solid-liquid separation, and obtain solid slag and treated biogas slurry;
The water quality index of biogas slurry after 2 adsorption treatment of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 7 96 44
(3)By step(2)Biogas slurry that treated is sent into aerobic system, with 100 parts by weight treated biogas slurry, then to aerobic system The biological prosthetic microbial inoculum that 0.4wt% is added in system carries out biochemical treatment 40min, then natural subsidence, is separated by solid-liquid separation, and obtains solid And liquid;
The water quality index of biogas slurry after 3 biochemical treatment of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 7 92 40
(4)As shown in Table 3, step(3)In liquid meet livestock breeding wastewater discharge standard GB18596-2001, COD≤ 150mg/l, BOD≤400mg/l, ammonia nitrogen≤80mg/l then recycle and carry out Fertilizer Transformed utilization.
Embodiment 2
The present embodiment is harmless processing and the utilization of resources technique of 1200 ton per day large-scale pig farm biogas slurries, including following step Suddenly:
(1)Swine manure is collected using dry cleaning up excrement and is separated by solid-liquid separation, biogas residue and biogas slurry are obtained;The biogas slurry water quality index After measured as shown in table 4.
The water quality index of 4 biogas slurry of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 4.8 1130 920
(2)By step(1)Biogas slurry the special taper reaction kettle in pretreatment system is entered by sewage draining passage, with 100 parts by weight Biogas slurry meter, the hydrated calcium chloroaluminate that 1.5wt% is then added into special taper reaction kettle carries out adsorption treatment, and stirs 30min, natural subsidence after stirring are separated by solid-liquid separation, and obtain solid slag and treated biogas slurry;
The water quality index of biogas slurry after 5 adsorption treatment of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 7 96 40
(3)By step(2)Biogas slurry that treated is sent into aerobic system, with 100 parts by weight treated biogas slurry, then to aerobic system The biological prosthetic microbial inoculum that 0.6wt% is added in system carries out biochemical treatment 60min, then natural subsidence, is separated by solid-liquid separation, and obtains solid And liquid;
The water quality index of biogas slurry after 6 biochemical treatment of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 7 94 38
(4)As shown in Table 6, step(3)In liquid meet livestock breeding wastewater discharge standard GB18596-2001, COD≤ 150mg/l, BOD≤400mg/l, ammonia nitrogen≤80mg/l then recycle and carry out Fertilizer Transformed utilization.
Embodiment 3
The present embodiment is harmless processing and the utilization of resources technique of 2000 ton per day large-scale pig farm biogas slurries, including following step Suddenly:
(1)Swine manure is collected using dry cleaning up excrement and is separated by solid-liquid separation, biogas residue and biogas slurry are obtained;The biogas slurry water quality index After measured as shown in table 7.
The water quality index of 7 biogas slurry of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 5.6 980 850
(2)By step(1)Biogas slurry the special taper reaction kettle in pretreatment system is entered by sewage draining passage, with 100 parts by weight Biogas slurry meter, the hydrated calcium chloroaluminate that 1.0wt% is then added into special taper reaction kettle carries out adsorption treatment, and stirs 25min, natural subsidence after stirring are separated by solid-liquid separation, and obtain solid slag and treated biogas slurry;
The water quality index of biogas slurry after 8 adsorption treatment of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 7 94 40
(3)By step(2)Biogas slurry that treated is sent into aerobic system, with 100 parts by weight treated biogas slurry, then to aerobic system The biological prosthetic microbial inoculum that 0.5wt% is added in system carries out biochemical treatment 50min, then natural subsidence, is separated by solid-liquid separation, and obtains solid And liquid;
The water quality index of biogas slurry after 9 biochemical treatment of table
Item controlled pH COD(mg/l) Ammonia nitrogen (mg/l)
Measured value 7 92 38
(4)As shown in Table 9, step(3)In liquid meet livestock breeding wastewater discharge standard GB18596-2001, COD≤ 150mg/l, BOD≤400mg/l, ammonia nitrogen≤80mg/l then recycle and carry out Fertilizer Transformed utilization.
The basic principles and main features and advantages of the present invention of the present invention have been shown and described above.The skill of the industry Art personnel it should be appreciated that the present invention is not limited to the above embodiments, the above embodiments and description only describe The principle of the present invention, without departing from the spirit and scope of the present invention, various changes and improvements may be made to the invention, these Changes and improvements all fall within the protetion scope of the claimed invention.The claimed scope of the invention by appended claims and Its equivalent thereof.

Claims (2)

1. a kind of harmless processing of large-scale pig farm biogas slurry and utilization of resources technique, it is characterised in that:Include the following steps:
(1)Swine manure is collected using dry cleaning up excrement and is separated by solid-liquid separation, biogas residue and biogas slurry are obtained;
(2)By step(1)Biogas slurry the special taper reaction kettle in pretreatment system is entered by sewage draining passage, with 100 parts by weight Biogas slurry meter, the hydrated calcium chloroaluminate that 0.5~1.5wt% is then added into special taper reaction kettle carries out adsorption treatment, and stirs Mix 20~30min, natural subsidence after stirring is separated by solid-liquid separation, and obtains solid slag and treated biogas slurry;
(3)By step(2)Biogas slurry that treated is sent into aerobic system, with 100 parts by weight treated biogas slurry, then to aerobic system The active microorganism microbial inoculum that 0.4~0.6wt% is added in system carries out 40~60min of biochemical treatment, then natural subsidence, solid-liquid point From acquisition solid and liquid;
(4)To step(3)The liquid of acquisition is detected, if meeting livestock breeding wastewater discharge standard GB18596-2001, COD ≤ 150mg/l, BOD≤400mg/l, ammonia nitrogen≤80mg/l then recycle and carry out Fertilizer Transformed utilization.
2. the harmless processing of large-scale pig farm biogas slurry according to claim 1 and utilization of resources technique, it is characterised in that:It is described Step(3)In active microorganism microbial inoculum select one or more of growth promoting bacteria agent, bush mycorrhiza agent or biological prosthetic microbial inoculum.
CN201810193880.7A 2018-03-09 2018-03-09 A kind of harmless processing of large-scale pig farm biogas slurry and utilization of resources technique Pending CN108358389A (en)

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110272843A (en) * 2019-07-01 2019-09-24 温州科技职业学院 It is a kind of for handling the composite bacteria agent and method of piggery waste water
CN113860668A (en) * 2021-11-09 2021-12-31 中科国发(深圳)技术有限公司 Culture manure purification method

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101250068A (en) * 2008-04-02 2008-08-27 上海市农业科学院 Method for producing photosynthetic bacterium biological fertilizer by using livestock house sewage water
CN105110567A (en) * 2015-09-16 2015-12-02 广东石油化工学院 Process for advanced treatment of southern large-scale swine wastewater
CN106745911A (en) * 2017-03-06 2017-05-31 江苏隆昌化工有限公司 A kind of recycling processing method of livestock breeding wastewater

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101250068A (en) * 2008-04-02 2008-08-27 上海市农业科学院 Method for producing photosynthetic bacterium biological fertilizer by using livestock house sewage water
CN105110567A (en) * 2015-09-16 2015-12-02 广东石油化工学院 Process for advanced treatment of southern large-scale swine wastewater
CN106745911A (en) * 2017-03-06 2017-05-31 江苏隆昌化工有限公司 A kind of recycling processing method of livestock breeding wastewater

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110272843A (en) * 2019-07-01 2019-09-24 温州科技职业学院 It is a kind of for handling the composite bacteria agent and method of piggery waste water
CN113860668A (en) * 2021-11-09 2021-12-31 中科国发(深圳)技术有限公司 Culture manure purification method

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Application publication date: 20180803