CN108355897A - Enhanced diffustion type photocatalyst atomizer - Google Patents
Enhanced diffustion type photocatalyst atomizer Download PDFInfo
- Publication number
- CN108355897A CN108355897A CN201810353433.3A CN201810353433A CN108355897A CN 108355897 A CN108355897 A CN 108355897A CN 201810353433 A CN201810353433 A CN 201810353433A CN 108355897 A CN108355897 A CN 108355897A
- Authority
- CN
- China
- Prior art keywords
- photocatalyst
- box
- electromagnetic pump
- chemical tank
- electric appliance
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 239000011941 photocatalyst Substances 0.000 title claims abstract description 92
- 239000000126 substance Substances 0.000 claims abstract description 34
- 239000003814 drug Substances 0.000 claims abstract description 33
- 238000010438 heat treatment Methods 0.000 claims abstract description 21
- 229910001220 stainless steel Inorganic materials 0.000 claims abstract description 20
- 239000010935 stainless steel Substances 0.000 claims abstract description 20
- 239000000443 aerosol Substances 0.000 claims abstract description 12
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical group OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 62
- 239000003795 chemical substances by application Substances 0.000 claims description 18
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 18
- 239000000243 solution Substances 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 9
- 239000007864 aqueous solution Substances 0.000 claims description 8
- 239000000779 smoke Substances 0.000 claims description 8
- 230000005611 electricity Effects 0.000 claims description 5
- 238000009423 ventilation Methods 0.000 claims description 4
- 230000002146 bilateral effect Effects 0.000 claims description 3
- 238000007667 floating Methods 0.000 claims description 3
- 238000005086 pumping Methods 0.000 claims description 3
- 238000007789 sealing Methods 0.000 claims description 3
- 238000002663 nebulization Methods 0.000 claims 1
- 230000000694 effects Effects 0.000 abstract description 2
- 238000000889 atomisation Methods 0.000 description 11
- 238000009792 diffusion process Methods 0.000 description 9
- 239000003054 catalyst Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 235000013312 flour Nutrition 0.000 description 2
- 238000002604 ultrasonography Methods 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- 235000009508 confectionery Nutrition 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 230000032258 transport Effects 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B17/00—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups
- B05B17/04—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods
- B05B17/06—Apparatus for spraying or atomising liquids or other fluent materials, not covered by the preceding groups operating with special methods using ultrasonic or other kinds of vibrations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B05—SPRAYING OR ATOMISING IN GENERAL; APPLYING FLUENT MATERIALS TO SURFACES, IN GENERAL
- B05B—SPRAYING APPARATUS; ATOMISING APPARATUS; NOZZLES
- B05B15/00—Details of spraying plant or spraying apparatus not otherwise provided for; Accessories
Abstract
The present invention relates to a kind of enhanced diffustion type photocatalyst atomizers, it includes photocatalyst chemical tank and electric appliance control box, the photocatalyst chemical tank is seal case, babinet one side wall is provided with air inlet, aerosol outlet port is arranged in top of the box, the bottom of box is provided with stainless steel tube, and stainless steel tube both ends are stretched into across wall box in electric appliance control box, and the sloping baffle bottom of box is provided in babinet and is additionally provided with supersonic generator;Showy medicament pot, wind turbine, the first electromagnetic pump, the second electromagnetic pump, primary heater and secondary heater are provided in electric appliance control box, fan outlet is connected to air inlet, the medicament pot that floats is connected to primary heater by the first electromagnetic pump, primary heater is connected at fan outlet, the medicament pot that floats is connected to secondary heater by the second electromagnetic pump, secondary heater is connected to stainless steel tube one end, and the showy medicament pot of stainless steel tube other end connection forms circulating-heating circuit.Photocatalyst atomizing effect is good, and spreads uniformly, and diffusivity is strong, range is wide.
Description
Technical field
The present invention relates to photocatalyst fields, and in particular to a kind of enhanced diffustion type photocatalyst atomizer.
Background technology
Photocatalyst series nanometer grade material, Photocatalyst water solution are that nanometer mountain flour is dissolved in water by special formula.
Less than 20 DEG C, with ultrasonic unit, it cannot be made fully to be atomized.Photocatalyst water solution ultrasonic wave
Device, atomization optimum temperature are 40 DEG C -50 DEG C, and due to the specific properties of photocatalyst, in order to make atomization temperature reach 40 DEG C -50
DEG C, the unavailable electromagnetic heating of mode of heating (cannot be by electromagnetic interference), unavailable electrothermal tube heating.
Due to photocatalyst system nanometer mountain flour aqueous solution, during ultrasonic atomization, the diffusion energy force difference of photocatalyst, diffusion
Range is small and uneven, cause far from equipment place diffusion less than.
Invention content
To solve the above problems, the present invention proposes a kind of enhanced diffustion type photocatalyst atomizer, photocatalyst atomizing effect is good,
And diffusion is uniform, diffusivity is strong, range is wide.
Technical scheme of the present invention:
A kind of enhanced diffustion type photocatalyst atomizer, it includes photocatalyst chemical tank and electric appliance control box, the photocatalyst
Chemical tank is seal case, and air inlet is provided in babinet one side wall, and aerosol outlet port is arranged in top of the box, and the bottom of box is provided with
Stainless steel tube, stainless steel tube both ends are stretched into across wall box in electric appliance control box, and sloping baffle, baffle top are provided in babinet
End is fixedly connected with top of the box, and bottom is tilted to air inlet side, baffle plate face face air inlet, between baffle and box bilateral wall
There are gap, the bottom of box is additionally provided with supersonic generator.
The electric appliance control box side wall is provided with ventilation hole, and showy medicament pot, wind turbine, are provided in electric appliance control box
One electromagnetic pump, the second electromagnetic pump, primary heater and secondary heater, fan outlet are connected to air inlet, and the medicament pot that floats is logical
The first electromagnetic pump connection primary heater is crossed, primary heater is connected at fan outlet, and the medicament pot that floats passes through the second electromagnetic pump
It is connected to secondary heater, secondary heater is connected to stainless steel tube one end, the showy medicament pot of stainless steel tube other end connection, and formation follows
Ring heating circuit is provided with control panel on the electric appliance control box, and control panel is electrically connected wind turbine, the first electromagnetic pump,
Two electromagnetic pumps, primary heater, secondary heater, supersonic generator and power interface, power interface are arranged in electric cabinet
Body side, power interface connect external power supply.
The interior addition Photocatalyst water solution of the photocatalyst chemical tank.
Agent of floating is added in the showy medicament pot.
Power on, control panel control starts the second electromagnetic pump, secondary heater, and leafing agent is pumped into via the second electromagnetism
Secondary heater heats, and the leafing agent smog of generation is by stainless steel tube, by the light in stainless steel tube and photocatalyst chemical tank
Photocatalyst water solution is heated in catalyst aqueous solution heat exchange, and leafing agent after cooling is sending showy medicament pot back to, circulating-heating,
When temperature sensor detects that temperature reaches setting value, control panel control stops the second electromagnetic pump, secondary heater, opens simultaneously
Dynamic wind turbine, the first electromagnetic pump, the second electromagnetic pump and supersonic generator, leafing agent are pumped into the first heating via the first electromagnetism
Device heats, and the leafing agent smog of generation is sent at fan outlet, and the air extracted with wind turbine mixes and by being sent into light together with wind turbine
Catalyst chemical tank, after mixing smog hits sloping baffle, leafing agent is uniformly dispersed, while sloping baffle forces mixing smog from gear
Two side runner of plate, into generation swirling eddy, while supersonic generator shakes Photocatalyst water solution so that Photocatalyst water solution
The photocatalyst of atomization, atomization drives external diffusion in swirling eddy, has achieved the purpose that heating and the enhanced diffustion of photocatalyst.
Above-mentioned technical proposal is improved further and is refined, is additionally provided in the babinet of the photocatalyst chemical tank
Liquid level gauge, liquid level gauge are electrically connected control panel, control panel control while the second electromagnetic pump of startup, secondary heater, ultrasound
At least 30s when wave producer time delay, because diethylene glycol (DEG) has certain toxicity, and the excessive sucking photocatalyst of human body also can be to human body
It causes to damage, the present invention relates at least delay times of 30s, safely evacuate before atomizer generates smog for personnel, while profit
Atomizer is controlled when Photocatalyst water solution reaches certain low liquid level with liquid level gauge control to be stopped.
Above-mentioned technical proposal is improved further and is refined, the showy agent is diethylene glycol (DEG) aqueous solution, sweet by two
Alcohol is with pure water according to weight ratio 1:3 are mixed, and the weight ratio of diethylene glycol (DEG) aqueous solution and Photocatalyst water solution is 0.4-
0.5kg :3kg.
Above-mentioned technical proposal is improved further and is refined, the heating of the primary heater, secondary heater
Temperature setting is 100-143 DEG C, atomization after diethylene glycol (DEG) heating reaches 100 DEG C or more, and the flash temperature of diethylene glycol (DEG) is 143 DEG C, is dodged
The safety index that point is flammable liquid storage, transports and use.
Above-mentioned technical proposal is improved further and is refined, is additionally provided in the babinet of photocatalyst chemical tank U-shaped
Baffle, U-shaped baffle cover is in aerosol outlet port, and U-shaped baffle both sides and top of the box composition runner, on mixed swirling eddy
Touching baffle is risen, baffle forces air-flow to carry out vertical direction convolution, to the contact for increasing air-flow with being atomized photocatalyst, Jin Erjin
One step increases the diffusion of photocatalyst.
Above-mentioned technical proposal is improved further and is refined, the runner direction and inclining in photocatalyst chemical tank
Slanting baffle is vertical, if runner direction is parallel with the sloping baffle of the babinet of photocatalyst chemical tank, air-flow passes through sloping baffle two
Behind side, most of gas does not generate swirling eddy, and directly through runner by being discharged from aerosol outlet port, air-flow utilization rate is little,
After being vertically arranged, swirling eddy greatly enhances, and air-flow utilization rate is high.
Above-mentioned technical proposal is improved further and is refined, the bottom of box of the photocatalyst chemical tank is also set up
There is dewatering outlet, after atomization, recycles extra medicament;Smoke pipe is also vertically installed on the aerosol outlet port, smoke pipe is sleeved on
On aerosol outlet port, increases smoke height, smog is facilitated to spread.
Above-mentioned technical proposal is improved further and is refined, electric appliance control box side wall is provided with opening, in opening
It is provided with L-type supporting plate, supporting plate lateral part passes through opening to stretch into electric appliance control box, and is fixedly mounted in supporting plate lateral part
There are showy medicament pot, supporting plate vertical portion covering opening to be connect with electric appliance control box side wall, be conveniently replaceable showy medicament pot medicine
Agent.
Above-mentioned technical proposal is improved further and is refined, temperature is additionally provided in the bottom of box of photocatalyst chemical tank
Sensor is spent, temperature sensor is electrically connected control panel, realizes Photocatalyst water solution heating and temperature control in photocatalyst chemical tank, institute
The set temperature for the temperature sensor stated is 40-50 DEG C, and it is 40 DEG C -50 DEG C that photocatalyst, which is atomized optimum temperature,.
Above-mentioned technical proposal is improved further and is refined, is set among the top of the box of the photocatalyst chemical tank
It is equipped with opening, case lid is provided in opening, is tightly connected by sealing ring between case lid and babinet, is facilitated to photocatalyst chemical tank
Interior addition Photocatalyst water solution.
The benefit that the present invention generates:Using stainless steel tube, generates leafing agent smog using heating and recycled in stainless steel tube
Flowing, with photocatalyst solution heat exchange, circulating-heating, to reach 40 DEG C -50 DEG C of photocatalyst atomization temperature.
Atomization photocatalyst rotational flow is driven using swirling eddy, for atomization photocatalyst with Diffusion of gas stream, diffusion is uniform, expands
The ability of dissipating is strong, range is wide, enhances the diffusivity of photocatalyst.
Description of the drawings
Fig. 1 is enhanced diffustion type photocatalyst atomizer structure schematic diagram.
Fig. 2 is enhanced diffustion type photocatalyst atomizer front view.
Fig. 3 is enhanced diffustion type photocatalyst atomizer half section structure diagram.
Fig. 4 is electric control box internal structure annexation figure.
01 electric appliance control box of photocatalyst chemical tank, 02 air inlet, 03 aerosol outlet port, 04 sloping baffle, 05 ultrasound in figure
06 ventilation hole 07 of wave producer floats 13 wind turbine of medicament pot, 08 first 14 second electromagnetic pump of electromagnetic pump, 15 primary heater
16 secondary heater, 17 circulating-heating circuit, 18 09 U-shaped baffle of control panel, 10 dewatering outlet, 11 L-type supporting plate 12.
Specific implementation mode
Embodiment 1
Picture 1-4, a kind of enhanced diffustion type photocatalyst atomizer, it includes photocatalyst chemical tank 01 and electric appliance control box 02,
The photocatalyst chemical tank 01 is seal case, and air inlet 03 is provided in babinet one side wall, and top of the box setting smog goes out
Mouth 04, the bottom of box is provided with stainless steel tube, and stainless steel tube both ends are stretched into across wall box in electric appliance control box 02, in babinet
It is provided with sloping baffle 05,05 top of baffle is fixedly connected with top of the box, and bottom is tilted to air inlet side, 05 plate face face of baffle
Air inlet 03, there are gap between baffle 05 and box bilateral wall, the bottom of box is additionally provided with supersonic generator 06;Described
02 side wall of electric appliance control box is provided with ventilation hole 07, and showy medicament pot 13, the 08, first electricity of wind turbine are provided in electric appliance control box 02
Magnetic pumping 14, the second electromagnetic pump 15, primary heater 16 and secondary heater 17,08 outlet air inlet 03 of wind turbine float
Medicament pot 13 is connected to primary heater 16 by the first electromagnetic pump 14, and primary heater 16 is connected to 08 exit of wind turbine, and float medicine
Agent pot 13 is connected to secondary heater 17 by the second electromagnetic pump 15, and secondary heater 17 is connected to stainless steel tube one end, stainless steel tube
The showy medicament pot 13 of other end connection, forms circulating-heating circuit 18, control panel 09 is provided on the electric appliance control box 02,
Control panel 09 be electrically connected wind turbine 08, the first electromagnetic pump 14, the second electromagnetic pump 15, primary heater 16, secondary heater 17,
Supersonic generator 06 and power interface, power interface are arranged in 02 side of electronic-control box, and power interface 02 connects external electricity
Source;The interior addition Photocatalyst water solution of the photocatalyst chemical tank 01;It is added by diethylene glycol (DEG) in the showy medicament pot 13
With pure water according to weight ratio 1:The 3 diethylene glycol (DEG) aqueous solutions being mixed;And the weight of diethylene glycol (DEG) aqueous solution and Photocatalyst water solution
Amount ratio is 0.4-0.5kg:3kg;The heating temperature of the primary heater 16, secondary heater 17 is set as 100-143
℃;U-shaped baffle 10 is additionally provided in the babinet of photocatalyst chemical tank 01, the cover of U-shaped baffle 10 is in aerosol outlet port 04, and U
10 both sides of type baffle and top of the box constitute runner, and mixed swirling eddy rises touching baffle 10, baffle 10 force air-flow into
Row vertical direction circles round, and to increase air-flow and be atomized the contact of photocatalyst, and then further increases the diffusion of photocatalyst;It is described
Runner direction it is vertical with the sloping baffle 05 in photocatalyst chemical tank, if the babinet of runner direction and photocatalyst chemical tank
Sloping baffle 05 is parallel, and for air-flow behind sloping baffle both sides, most of gas does not generate swirling eddy, and directly logical through runner
It crosses and is discharged from aerosol outlet port 04, air-flow utilization rate is little, and after being vertically arranged, swirling eddy greatly enhances, and air-flow utilization rate is high;Institute
The bottom of box for the photocatalyst chemical tank stated is additionally provided with dewatering outlet, after atomization, recycles extra medicament;The smog goes out
Smoke pipe is also vertically installed on mouth, smoke pipe is sleeved on aerosol outlet port, increases smoke height, smog is facilitated to spread;In electric appliance control
02 side wall of case processed is provided with opening, and L-type supporting plate 12 is provided in opening, and 12 lateral part of supporting plate passes through opening to stretch into electrical equipment control
In case 02, and showy medicament pot, 12 vertical portion of supporting plate covering opening, with electric appliance are fixedly mounted in 12 lateral part of supporting plate
02 side wall of control cabinet connects, and is conveniently replaceable showy medicament pot medicament;It is additionally provided with temperature in the bottom of box of photocatalyst chemical tank 02
Sensor is spent, temperature sensor is electrically connected control panel 09, realizes Photocatalyst water solution heating and temperature control in photocatalyst chemical tank,
The set temperature of temperature sensor is 40-50 DEG C, and it is 40 DEG C -50 DEG C that photocatalyst, which is atomized optimum temperature,;The photocatalyst medicament
It is provided with opening among the top of the box of case 01, case lid is provided in opening, is sealed and is connected by sealing ring between case lid and babinet
It connects.
Due to the finiteness of literal expression, and objectively there is unlimited concrete structure, for the common of the art
For technical staff, without departing from the principle of the present invention, several improvement, retouching or variation can also be made, it can also
Above-mentioned technical characteristic is combined in the right way;These improve retouching, variation or combination, or not improved by invention
Design and technical solution directly apply to other occasions, are regarded as protection scope of the present invention.
Claims (10)
1. a kind of enhanced diffustion type photocatalyst atomizer, it includes photocatalyst chemical tank and electric appliance control box, it is characterised in that:
The photocatalyst chemical tank is seal case, and air inlet is provided in babinet one side wall, and top of the box setting smog goes out
Mouthful, the bottom of box is evenly arranged with stainless steel tube, and stainless steel tube both ends are stretched into across wall box in electric appliance control box, in babinet
It is provided with sloping baffle, baffle top is fixedly connected with top of the box, and bottom is tilted to air inlet side, baffle plate face face air inlet
Mouthful, there are gaps, the bottom of box to be additionally provided with supersonic generator between baffle and box bilateral wall;
The electric appliance control box side wall is provided with ventilation hole, and showy medicament pot, wind turbine, the first electricity are provided in electric appliance control box
Magnetic pumping, the second electromagnetic pump, primary heater and secondary heater, fan outlet are connected to the air inlet of photocatalyst chemical tank, float
Floating medicament pot is connected to primary heater by the first electromagnetic pump, and primary heater is connected at fan outlet, and the medicament pot that floats passes through
Second electromagnetic pump is connected to secondary heater, and secondary heater is connected to stainless steel tube one end, the showy medicine of stainless steel tube other end connection
Agent pot forms circulating-heating circuit, is provided with control panel on the electric appliance control box, and control panel is electrically connected wind turbine, the
One electromagnetic pump, the second electromagnetic pump, primary heater, secondary heater, supersonic generator, liquid level gauge and power interface, electricity
Source interface setting connects external power supply in electronic-control box side, power interface;
The interior addition Photocatalyst water solution of the photocatalyst chemical tank;
Agent of floating is added in the showy medicament pot.
2. a kind of enhanced diffustion type photocatalyst atomizer according to claim 1, it is characterised in that:The photocatalyst medicine
Liquid level gauge is additionally provided in the babinet of agent case, liquid level gauge is electrically connected control panel, control panel control while the second electricity of startup
At least 30s when magnetic pumping, secondary heater, supersonic generator time delay.
3. a kind of enhanced diffustion type photocatalyst atomizer according to claim 2, it is characterised in that:The showy agent is
Diethylene glycol (DEG) aqueous solution, by diethylene glycol (DEG) and pure water according to weight ratio 1:3 are mixed, and diethylene glycol (DEG) aqueous solution and photocatalyst are water-soluble
The weight ratio of liquid is 0.4-0.5kg:3kg.
4. a kind of enhanced diffustion type photocatalyst atomizer according to claim 3, it is characterised in that:First heating
Device, secondary heater heating temperature be set as 100-143 DEG C.
5. a kind of enhanced diffustion type photocatalyst atomizer according to claim 4, it is characterised in that:First electromagnetic pump goes out
Mouthful flow is set with primary heater heating temperature according to the nebulization efficiency of leafing agent, and leafing agent enters the by the first electromagnetic pump
One heater is atomized completely.
6. a kind of enhanced diffustion type photocatalyst atomizer according to claim 5, it is characterised in that:In photocatalyst chemical tank
Babinet in be additionally provided with U-shaped baffle, U-shaped baffle cover is in aerosol outlet port, and U-shaped baffle both sides constitute with top of the box and flow
Road, runner direction are vertical with the sloping baffle in photocatalyst chemical tank.
7. a kind of enhanced diffustion type photocatalyst atomizer according to claim 6, it is characterised in that:The photocatalyst medicine
The bottom of box of agent case is additionally provided with dewatering outlet;Smoke pipe is also vertically installed on the aerosol outlet port, smoke pipe is sleeved on smog
In outlet.
8. a kind of enhanced diffustion type photocatalyst atomizer according to claim 7, it is characterised in that:In electric appliance control box side
Wall is provided with opening, and L-type supporting plate is provided in opening, and supporting plate lateral part passes through opening to stretch into electronic-control box, and in supporting plate
Lateral part has been fixedly mounted on showy medicament pot, and supporting plate vertical portion covering opening is connect with electric appliance control box side wall.
9. a kind of enhanced diffustion type photocatalyst atomizer according to claim 8, it is characterised in that:In photocatalyst chemical tank
The bottom of box be additionally provided with temperature sensor, temperature sensor is electrically connected control panel, and the set temperature of temperature sensor is 40-
50℃。
10. a kind of enhanced diffustion type photocatalyst atomizer according to claim 9, it is characterised in that:The photocatalyst
It is provided with opening among the top of the box of chemical tank, case lid is provided in opening, is sealed by sealing ring between case lid and babinet
Connection.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201810353433.3A CN108355897B (en) | 2018-04-19 | 2018-04-19 | Enhanced diffusion type photocatalyst atomizer |
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Application Number | Priority Date | Filing Date | Title |
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CN201810353433.3A CN108355897B (en) | 2018-04-19 | 2018-04-19 | Enhanced diffusion type photocatalyst atomizer |
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Publication Number | Publication Date |
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CN108355897A true CN108355897A (en) | 2018-08-03 |
CN108355897B CN108355897B (en) | 2023-11-17 |
Family
ID=63008753
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113385354A (en) * | 2020-03-13 | 2021-09-14 | 株式会社空间除菌 | Spraying device |
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GB525736A (en) * | 1939-02-27 | 1940-09-03 | Geoffrey Warner Parr | Improvements in and relating to apparatus for the nebulisation of liquids |
JPH1085314A (en) * | 1996-09-11 | 1998-04-07 | Aisan Ind Co Ltd | Fragrance generator |
CN2905069Y (en) * | 2005-12-12 | 2007-05-30 | 顾永良 | Novel indoor air purifier |
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JP2009143868A (en) * | 2007-12-14 | 2009-07-02 | Earth Chem Corp Ltd | Method for exterminating crawling pest |
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Publication number | Priority date | Publication date | Assignee | Title |
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CN113385354A (en) * | 2020-03-13 | 2021-09-14 | 株式会社空间除菌 | Spraying device |
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CN108355897B (en) | 2023-11-17 |
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