CN108350391A - Composition for handling base material and method - Google Patents
Composition for handling base material and method Download PDFInfo
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- CN108350391A CN108350391A CN201680061265.XA CN201680061265A CN108350391A CN 108350391 A CN108350391 A CN 108350391A CN 201680061265 A CN201680061265 A CN 201680061265A CN 108350391 A CN108350391 A CN 108350391A
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- spot
- composition
- surfactant
- base material
- composition according
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- 239000000203 mixture Substances 0.000 title claims abstract description 85
- 239000000463 material Substances 0.000 title claims abstract description 24
- 238000000034 method Methods 0.000 title claims abstract description 17
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 claims abstract description 36
- 239000004094 surface-active agent Substances 0.000 claims abstract description 36
- 239000003945 anionic surfactant Substances 0.000 claims abstract description 19
- 239000004744 fabric Substances 0.000 claims abstract description 15
- 239000007844 bleaching agent Substances 0.000 claims abstract description 9
- 102000004190 Enzymes Human genes 0.000 claims abstract description 7
- 108090000790 Enzymes Proteins 0.000 claims abstract description 7
- USIUVYZYUHIAEV-UHFFFAOYSA-N diphenyl ether Chemical compound C=1C=CC=CC=1OC1=CC=CC=C1 USIUVYZYUHIAEV-UHFFFAOYSA-N 0.000 claims abstract description 7
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical group [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 6
- 125000000217 alkyl group Chemical group 0.000 claims abstract description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 17
- 239000003599 detergent Substances 0.000 claims description 7
- UQDUPQYQJKYHQI-UHFFFAOYSA-N methyl laurate Chemical group CCCCCCCCCCCC(=O)OC UQDUPQYQJKYHQI-UHFFFAOYSA-N 0.000 claims description 7
- 229910052739 hydrogen Inorganic materials 0.000 claims description 5
- 239000001257 hydrogen Substances 0.000 claims description 5
- 239000003795 chemical substances by application Substances 0.000 claims description 2
- 239000003921 oil Substances 0.000 description 17
- 239000002253 acid Substances 0.000 description 5
- 238000004140 cleaning Methods 0.000 description 5
- 238000005406 washing Methods 0.000 description 5
- 150000001450 anions Chemical group 0.000 description 4
- 125000004432 carbon atom Chemical group C* 0.000 description 4
- 230000000052 comparative effect Effects 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 239000002736 nonionic surfactant Substances 0.000 description 4
- 229940057950 sodium laureth sulfate Drugs 0.000 description 4
- 239000007788 liquid Substances 0.000 description 3
- SXHLENDCVBIJFO-UHFFFAOYSA-M sodium;2-[2-(2-dodecoxyethoxy)ethoxy]ethyl sulfate Chemical group [Na+].CCCCCCCCCCCCOCCOCCOCCOS([O-])(=O)=O SXHLENDCVBIJFO-UHFFFAOYSA-M 0.000 description 3
- 239000000126 substance Substances 0.000 description 3
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 238000004061 bleaching Methods 0.000 description 2
- 239000004973 liquid crystal related substance Substances 0.000 description 2
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 description 2
- JGHZJRVDZXSNKQ-UHFFFAOYSA-N methyl octanoate Chemical compound CCCCCCCC(=O)OC JGHZJRVDZXSNKQ-UHFFFAOYSA-N 0.000 description 2
- 238000012544 monitoring process Methods 0.000 description 2
- 239000007800 oxidant agent Substances 0.000 description 2
- 239000004033 plastic Substances 0.000 description 2
- 238000002360 preparation method Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 239000007921 spray Substances 0.000 description 2
- 238000010186 staining Methods 0.000 description 2
- 238000003860 storage Methods 0.000 description 2
- 239000004753 textile Substances 0.000 description 2
- QCDWFXQBSFUVSP-UHFFFAOYSA-N 2-phenoxyethanol Chemical class OCCOC1=CC=CC=C1 QCDWFXQBSFUVSP-UHFFFAOYSA-N 0.000 description 1
- 229920000742 Cotton Polymers 0.000 description 1
- 239000004593 Epoxy Substances 0.000 description 1
- OTMSDBZUPAUEDD-UHFFFAOYSA-N Ethane Chemical group CC OTMSDBZUPAUEDD-UHFFFAOYSA-N 0.000 description 1
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 description 1
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 description 1
- 239000004902 Softening Agent Substances 0.000 description 1
- QRSFFHRCBYCWBS-UHFFFAOYSA-N [O].[O] Chemical compound [O].[O] QRSFFHRCBYCWBS-UHFFFAOYSA-N 0.000 description 1
- 230000003213 activating effect Effects 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 125000003545 alkoxy group Chemical group 0.000 description 1
- 230000000845 anti-microbial effect Effects 0.000 description 1
- 239000003124 biologic agent Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 239000012459 cleaning agent Substances 0.000 description 1
- 230000000295 complement effect Effects 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 239000006184 cosolvent Substances 0.000 description 1
- 239000008367 deionised water Substances 0.000 description 1
- 229910021641 deionized water Inorganic materials 0.000 description 1
- 239000000645 desinfectant Substances 0.000 description 1
- 239000006185 dispersion Substances 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 125000003700 epoxy group Chemical group 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000796 flavoring agent Substances 0.000 description 1
- 235000013355 food flavoring agent Nutrition 0.000 description 1
- 150000002430 hydrocarbons Chemical group 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000010348 incorporation Methods 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 238000009940 knitting Methods 0.000 description 1
- 238000005259 measurement Methods 0.000 description 1
- 230000002906 microbiologic effect Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- 230000001590 oxidative effect Effects 0.000 description 1
- 238000012856 packing Methods 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 229910052698 phosphorus Inorganic materials 0.000 description 1
- 239000011574 phosphorus Substances 0.000 description 1
- 230000000704 physical effect Effects 0.000 description 1
- 229920000647 polyepoxide Polymers 0.000 description 1
- 239000003755 preservative agent Substances 0.000 description 1
- 230000002335 preservative effect Effects 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 238000011012 sanitization Methods 0.000 description 1
- 239000002453 shampoo Substances 0.000 description 1
- 229920002545 silicone oil Polymers 0.000 description 1
- MWNQXXOSWHCCOZ-UHFFFAOYSA-L sodium;oxido carbonate Chemical compound [Na+].[O-]OC([O-])=O MWNQXXOSWHCCOZ-UHFFFAOYSA-L 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000007711 solidification Methods 0.000 description 1
- 230000008023 solidification Effects 0.000 description 1
- 230000003381 solubilizing effect Effects 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 238000005507 spraying Methods 0.000 description 1
- 230000006641 stabilisation Effects 0.000 description 1
- 238000011105 stabilization Methods 0.000 description 1
- BDHFUVZGWQCTTF-UHFFFAOYSA-M sulfonate Chemical compound [O-]S(=O)=O BDHFUVZGWQCTTF-UHFFFAOYSA-M 0.000 description 1
- 229910052717 sulfur Inorganic materials 0.000 description 1
- 230000002195 synergetic effect Effects 0.000 description 1
- 238000011282 treatment Methods 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/37—Mixtures of compounds all of which are anionic
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/16—Organic compounds
- C11D3/20—Organic compounds containing oxygen
- C11D3/2093—Esters; Carbonates
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D3/00—Other compounding ingredients of detergent compositions covered in group C11D1/00
- C11D3/39—Organic or inorganic per-compounds
- C11D3/3947—Liquid compositions
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/22—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds
- C11D1/24—Sulfonic acids or sulfuric acid esters; Salts thereof derived from aromatic compounds containing ester or ether groups directly attached to the nucleus
-
- C—CHEMISTRY; METALLURGY
- C11—ANIMAL OR VEGETABLE OILS, FATS, FATTY SUBSTANCES OR WAXES; FATTY ACIDS THEREFROM; DETERGENTS; CANDLES
- C11D—DETERGENT COMPOSITIONS; USE OF SINGLE SUBSTANCES AS DETERGENTS; SOAP OR SOAP-MAKING; RESIN SOAPS; RECOVERY OF GLYCEROL
- C11D1/00—Detergent compositions based essentially on surface-active compounds; Use of these compounds as a detergent
- C11D1/02—Anionic compounds
- C11D1/12—Sulfonic acids or sulfuric acid esters; Salts thereof
- C11D1/29—Sulfates of polyoxyalkylene ethers
-
- C11D2111/12—
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Oil, Petroleum & Natural Gas (AREA)
- Wood Science & Technology (AREA)
- Organic Chemistry (AREA)
- Health & Medical Sciences (AREA)
- Emergency Medicine (AREA)
- Inorganic Chemistry (AREA)
- Detergent Compositions (AREA)
Abstract
The present invention relates to the compositions and method for handling base material such as fabric；Composition and method especially for removing spot in all types of spots.The single product to work in all different types of spots is still desired.It is an object of the present invention to provide for remove aqueous spot/can bleach spot, oil-dirt, graininess spot and enzyme spot composition.Astoundingly, it has been found that from fabric remove aqueous spot/can bleach spot, oil-dirt, graininess spot and enzyme spot can increase the composition of soluble oil and hydrogen peroxide by the surfactant system comprising anion surfactant and dianionic surfactant, fat and realize, the wherein described anion surfactant is selected from alkyl alkoxylated suifate, and the dianionic surfactant is selected from the diphenyl oxide disulfonates of the carbon chain lengths with C6 to C18.
Description
Technical field
The present invention relates to the compositions and method for handling base material such as fabric；Especially in all types of spots
The composition and method of middle removal spot.
Background technology
Textile stains include the entire scope from food spatters to daily substance, and can have different type；It is main
If aqueous, oiliness, granular and can bleach.Spot is the thing for being attempted to avoid, but they are can not to keep away
Exempt from.However, people still prefer to wear, spot is less or the not no clothes of spot completely.In fact, people are not only ready to keep away
Exempt from the spot on clothes, but also is usually ready to avoid the spot in kitchen, bathroom and on various daily surfaces.
Therefore, improved greasiness removal is one of immutable object of detergent industry.It is always of interest for improving clean effect,
Especially to the clean effect of textile stains.Using removal spot as the product of target generally directed to no more than two or three class
The spot of type.In fact, the single product to work in all different types of spots is still desired.
WO98/00498A1 (Procter and Gamble Company), which is disclosed, to be based on helping surface with one or more
The liquid cleansing composition of the dianionic surfactant of activating agent combination and shampoo.Dianionic surfactant can be
It is alkoxylated, there are at least five carbon atoms, institute is connected to by two anion substituents that at least three carbon atoms separate
State at least five carbon atoms.Moreover, in two anion substituents, a group is sulfate or the sulfuric acid of alkoxy connection
Salt, another anion substituent can be sulfate or sulfonate.
WO98/00503A1 (Procter and Gamble Company), which is also disclosed, to be based on and bleaching agent (0.1 to 50
Weight %) (such as perborate and/or percarbonate) combination WO98/00498 disclosed in dianionic surfactant
The similar cleaning compositions of (0.1 to 50 weight %).
US2006/100122A1 (Diversey Inc) discloses cleaning and sanitizing composition for hard surface.Combination
Object includes the oxidation resistant acid or its salt other than hydrogen peroxide and dephosphorization base acid.Phosphorus base acid is replaced to lead to improved peroxidating with acid
Stabilized hydrogen, while keeping or improving the cleaning effectiveness and antimicrobial acivity of composition.
WO2013/075913A1 (Unilever) is disclosed for doing washing and/or the ternary layered phase of the liquid crystal of daily cleaning
Detergent composition.It was found that detergent composition, it includes it is selected from nonionic surfactant and anion surfactant,
Nonionic surfactant:The ratio of anion surfactant is 5:1 to 1:1 surfactant；With fatty solubilising
Oily (fat solubilizing oil) and water provide removal solid or the solidification dirt of fat material and/or having for spot
Imitate solution；Stablize under normal storage and wash conditions, and drumped liquid delivery can be used as.
WO2014/016134A1 (Unilever) discloses the ternary layered phase detergent composition of liquid crystal, it includes selected from
Nonionic surfactant and anion surfactant, nonionic surfactant:The ratio of anion surfactant
It is 3:1 to 1:4 surfactant has the HLB value not less than 15；Fat increases soluble oil and water.Composition is in normal storage
Stablize under wash conditions, and drumped liquid delivery can be used as.
However, it is possible to which the sole cleaning agent composition for the spot of wide scope is still desired.
Therefore, it is an object of the present invention to provide for removing aqueous spot/can bleach spot, oil-dirt, particle
The composition of shape spot and enzyme spot.
It is a further object to provide the single products to work in different types of spot.
A further object of the present invention is to provide the laundry pretreatment compositions for removing spot.
Astoundingly, it has been found that remove aqueous spot/can bleach spot, oil-dirt, graininess spot from fabric
It can pass through the surfactant system comprising anion surfactant and dianionic surfactant, fat with enzyme spot
The composition for increasing soluble oil and hydrogen peroxide is realized.
Invention content
Therefore, in a first aspect, the present invention provides the composition for handling base material, the composition includes：10 to
The surfactant system for including anion surfactant and dianionic surfactant of 25 weight %, wherein described the moon
Ionic surface active agent is selected from alkyl alkoxylated suifate, and the dianionic surfactant is selected from C6 extremely
The diphenyl oxide disulfonates of the carbon chain lengths of C18；The fat of 1 to 15 weight % increases soluble oil, has 14 to 22 MPa0.5(
At 25 DEG C) Hansen solubility parameters (δ HSP), wherein Hansen polar components (polar component) (δ P) be 0.5
To 10 MPa0.5(at 25 DEG C), dispersive (dispersion component) (δ H) are 3 to 10 MPa0.5(at 25 DEG C
Under), hydrogen bond component (hydrogen bond component) (δ D) is 13 to 18 MPa0.5(at 25 DEG C)；2 to 12 weight %
Hydrogen peroxide；And water.
In second aspect, the present invention provides the methods for handling base material comprising the step of following sequence：By basis
The composition of the present invention is administered on the base material；The base material is washed with detergent；With so that the base material is dried.
In the third aspect, the present invention provides the purposes that composition according to the present invention is used for excellent greasiness removal.
By reading described in detail below and appended claims, these and other aspects, feature and advantage are for ability
Domain those of ordinary skill will be apparent.In order to avoid query, any feature of one aspect of the present invention may be used to this
Any other aspect of invention.Word "comprising" is intended to indicate that " comprising ", but is not necessarily " consist of " or " by ... structure
At ".In other words, listed step or option need not be exhaustive.It should be noted that the embodiment provided in being described below
It is intended to illustrate the present invention, and is not intended to that the present invention is made to be limited to these embodiments itself.Similarly, unless otherwise stated, institute
It is w/w percentage to have percentage.Only in working Examples and comparing embodiment, or in addition clear
In the case of pointing out, all numbers of quantity of material or reaction condition, material physical properties and/or purposes are otherwise indicated in this specification
Word shall be construed as being modified by word " about ".The numberical range indicated in the form of " x to y " is understood to include x and y.When
When describing multiple preferred scopes in the form of " x to y " for special characteristic, it should be understood that it is also contemplated that combining all models of different endpoints
It encloses.
Specific implementation mode
The present invention provides the compositions for handling base material, and it includes include anion surfactant and dianion
Surfactant system, the fat of surfactant increase soluble oil and hydrogen peroxide.The surplus of composition is complemented to 100 with water
Weight %.
Surfactant system
The composition of the present invention includes the table for basically comprising anion surfactant and dianionic surfactant
Surfactant system, wherein the anion surfactant is selected from alkyl alkoxylated suifate, and the dianion
Surfactant is selected from the diphenyl oxide disulfonates of the carbon chain lengths with C6 to C18.
Particularly preferred anion surfactant is sodium laureth sulfate (SLES), preferably has 2 to 30 epoxies
Ethane group and about 8 to 18 carbon atoms in alkyl.
Dianionic surfactant is selected from the diphenyl oxide disulfonates of the carbon chain lengths with C6 to C18.
The non-limiting examples of dianionic surfactant include being selected to have C6 to C18, preferably C8 to C16, more excellent
Select the surfactant of the diphenyl oxide disulfonates of the carbon chain lengths of C10 to C14.Commercially available example is8390
(coming from Dow).
In the present compositions, surfactant system based on the weight of composition with 10 to 25%, preferably at least
12%, more preferably at least 15%, still more preferably at least 17%, but typically not greater than 24%, preferably more than 22%, more preferably not
Concentration more than 20% exists.
Anion surfactant and dianionic surfactant are with 4:1 to 20:1 ratio, preferably 4:1 to 19:1
Ratio, more preferable 5:1 to 15:1 ratio, even more preferably from 7:1 to 10:1 ratio is present in surfactant system.
Fat increases soluble oil
The composition of the present invention includes that fat increases soluble oil, has 14 to 22 MPa0.5The Hansen of (at 25 DEG C) is molten
Solution degree parameter (δ HSP), wherein Hansen polar components (δ P) are 0.5 to 10 MPa0.5(at 25 DEG C), dispersive (δ H) are
3 to 10 MPa0.5(at 25 DEG C), hydrogen bond component (δ D) are 13 to 18 MPa0.5(at 25 DEG C).
It is preferable to use referred to as 3.1 editions (http of HSPiP for Hansen solubility parameters://
Hspip.software.informer.com/3.1/ software) calculates.The input for being given to software is the structure for the oil proposed
The form of SMILES (Simplified Molecular Input Line Entry Specification).
Preferred fat solubilizer is the ester of the aliphatic acid with general formula R COOR', and wherein R is that length is C6To C14Alkane
Base hydrocarbon chain, R'=CH3(methyl) or C2H5(ethyl) group.Particularly preferred fat solubilisation oils are methyl laurates.It is another excellent
The oil of choosing is methyl caprylate or methyl laurate.
Fat increases soluble oil based on the weight of composition with 1 to 15%, preferably more than 12%, even more preferably from no more than
10%, even more preferably no more than 8%, but usually be no less than 1.5%, preferably not less than 3%, more preferably no less than 6% it is dense
Degree is present in the composition of the present invention.
Hydrogen peroxide
The composition of the present invention includes hydrogen peroxide.Hydrogen peroxide, which is simplest peroxide, (has oxygen-oxygen singly-bound
Compound), it can be used as strong oxidizer, bleaching agent and disinfectant.
Hydrogen peroxide based on the weight of composition with 2 to 12%, preferably more than 10%, more preferably no more than 8%, also more
Preferably more than 7%, but it is usually no less than 3%, preferably not less than 4%, more preferably no less than 5% concentration is present in the present invention
Composition in.
Without wishing to be bound by theory, it is believed that hydrogen peroxide serves as oxidant and is mainly responsible for bleaching in the composition
Effect, but the excellent hydrogen peroxide that is removed by of other spots increases the synergistic effect realization that soluble oil combines with fat.
Water
The composition of the present invention is the water-based composition for including water.By adding water that composition is made to complement to 100%.Composition
Preferably comprise the water of 45 to 90 weight %.
Optional member
Composition can further include the softening agent as being usually used in fabric softening compositions, and bleach stable enzyme resists micro-
Biological agent, silicone oil and cosolvent such as 2- Phenoxyethanols (can be used asEP trade marks are commercially available from Dow Chemicals)
To improve stability and dispersibility, hydrotrote, preservative and flavouring agent.
Method for handling fabric
In second aspect, the present invention relates to the methods for handling base material comprising the step of following sequence：It will be according to this
The composition of invention is administered on base material；The base material is washed with detergent；With so that the base material is dried.
Composition can be applied by any known method, such as by using cleaning piece, sprayer, including spray gun, mist
Change device or other are directly applied.
It is preferred that rinsing surface after washing base material and before dry.
The purposes of composition
In the third aspect, the present invention relates to the purposes that composition according to the present invention is used for excellent greasiness removal
Product form
Product is usually with 250ml to 5L, and the capacity packing of more preferable 250ml to 1.5L is in bottle, preferably in plastic bottle.
The bottle of common supermarket's size is 250ml, 500ml, 750ml, 1L and 1.5L.Bottle can optionally have the amount of connection
Measurement scales indicator in cup or lid enables a consumer to apply suitable amount.
It for the purpose directly applied, such as is applied directly on fabric, what is be also contemplated in the context of the present invention is
The product being packaged in the bottle with the trigger-type spray dispenser comprising composition according to the present invention.Trigger-type spraying point
The orchestration bottle usually volume with 250ml to 1.5L.Common capacity includes 400ml, 500ml, 750ml and 1L.
The more bulk container that commercial scale uses is intended to be included within the scope of the present invention.
The present invention is now illustrated by following non-limiting embodiment.
Embodiment
Material
Anion surfactant：SLES pastes (70%)-sodium laureth sulfate (come from 70 2EO of Galaxy LES)
Dianionic surfactant：35% solution of diphenyl oxide disulfonates (comes from Dow Chemicals)8390
Hydrogen peroxide：- 30% solution of hydrogen peroxide (comes from Merck India)
Fat increases soluble oil：Methyl laurate (comes from KLK Oleo, Malaysia)
Deionized water：
The preparation of composition：
By each ingredient to be added in right amount in plastic containers and use SilversionTMMixer mixes.The technique used
Condition is as follows：
Mixer types：SilversionTMMixer
RPM：1500 to 2500
Mixer blade diameter：4cm
Mixer blade type：Two plane blades on 90 degree of SS bars being connected on motor
Incorporation time：It it is 30 minutes for 1kg batch sizes
Temperature：25 DEG C (laboratory temperatures)
Spot group
Object is monitored using the more spots of the standard purchased from SUV-TUV South East Asia Pvt limited.Research
It is middle to monitor object, i.e. ICSS1 and ICSS2 using two kinds of more spots.Both spots monitor object by knitting cotton fabric system
At with a variety of spots (40 kinds of spots in total, 4 pollution categories：Oiliness/fat, can bleaching, enzyme and graininess
's；For ICSS1 and ICSS2).It stains and is carried out under conditions of controlled and repeatable.
Fabric treating scheme：
0.3 to 1.5ml composition is applied in each spot by scale buret.Applying 2 to 10 points of composition
Zhong Hou washs processed fabric.
Washing scheme：
Processed standard is stained monitoring object to wash in standard 5kg household vertical axis top loading rinsing machings.Always wash
It is 2.5kg to wash load, including stains monitoring both object and shirt ballast.With 60 gramsExcel Matic Top
Load (coming from Hindustan Unilever Ltd, India) is washed at 24 °F of H.Typical wash cycle by impregnating,
Washing and twice rinsing composition.After the completion of washing, sample is removed, then air dried overnight.
Fabric is assessed：
The effect of each composition is assessed using SRI (greasiness removal index).It usesF1(Innotech
Scanner the SRI of each spot) is measured.As follows SRI values are calculated from blank with L*, a*, b* value for staining fabric：
Fabric (is not stained) for blank：LB, aB, bB
For staining fabric：LS, aS, bS
SRI=100-Delta E
Delta SRI=SRI (Expt)-SRI (control)
Delta SRI values are higher (positive number), and preparation is more effective to greasiness removal.
It is tested as a contrast with commercially available household cleanser.Recognition combination object, will compared with commercially available household cleanser
There is provided in all spots more be positive number Delta SRI values, be within the scope of the invention.
Embodiment 1：Influence of each component of composition to greasiness removal
In this embodiment, by the ratio of composition according to the present invention (Ex 1) and at least one component for lacking composition
It is compared compared with property (that is, in addition to the present invention) composition (Comp A to Comp F).
Each composition in the following table 1 is handled in various spots, and calculates their Delta (Δ) SRI values.
Composition is prepared by method as described above.
Table 1
Note：Surplus in each composition is water.
As a result (greasiness removal indicated with Delta (Δ) SRI) is listed in Table 2 below.
Table 2
Note：MSR refers to commercially available household cleanser
Upper table is shown, only in the case of composition according to the present invention (Ex 1) of all components comprising composition,
Observe the excellent greasiness removal (higher Delta SRI values) in all different type spots relative to control.
Embodiment 2：Influence of the concentration of hydrogen peroxide to greasiness removal
The embodiment proved that influence of the concentration of hydrogen peroxide to greasiness removal.By example composition Ex 2 to Ex 4 and packet
Containing concentration, the comparative example Comp F to Comp G of the hydrogen peroxide beyond the scope of the invention are compared.
Each composition is tested to various spots in the following table 3, and calculates their Delta SRI values.Composition passes through such as
It is prepared by the upper method.
Table 3
Surplus is water.
((Delta (Δ) SRI) is listed in the table below in 4 observed value.
Table 4
The data presented in table 4 show, when the amount of hydrogen peroxide within the scope of the invention when obtain optimum.
Embodiment 3：Fat increases influence of the concentration of soluble oil to greasiness removal
In this embodiment, the composition according to the present invention (Ex 5 to Ex of soluble oil will be increased comprising different amounts of fat
7) increase the comparative composition of soluble oil with the fat with the amount outside the scope of the invention for being labeled as (Comp I to Comp K)
It is compared.
Each composition in the following table 5 is contacted with various spots, and calculates gained Delta SRI values.Composition passes through
It is prepared by method as described above.
Table 5
Surplus in each composition is water.
((Delta (Δ) SRI) is listed in Table 6 below observed value.
Table 6
Best greasiness removal of the data instruction when fat increases the amount of soluble oil within the scope of the present invention in upper table 6.
Embodiment 4：Influence of the concentration of surfactant system to greasiness removal
The embodiment proved that influence of the concentration of surfactant system to greasiness removal.By 8 Hes of example composition Ex
Ex 9 with comprising the scope of the invention outside the Comparative Example Comp L to Comp N of surfactant of amount be compared.
Each composition in table 7 is contacted with various spots, calculates and record their DeltaSRI values.Composition passes through
It is prepared by method as described above.
Table 7
Surplus in each composition is water.
((Delta (Δ) SRI) is listed in Table 8 below observed value.
Table 8
The inferred from input data that can be presented from upper table can be had when surfactant system is according to the present invention
There is the stabilization composition of excellent greasiness removal.
Embodiment 5：Influence of the ratio of anion surfactant and dianionic surfactant to greasiness removal
In this embodiment, the not year-on-year of the amount of anion surfactant and dianionic surfactant is compared
Rate.Ex 10 to Ex 14 is composition according to an embodiment of the invention, and by they with ratio outside the scope of the present invention
Comp O and Comp P (Comparative Example) be compared.
Table 9
Surplus is water.
The various stain treatments of each composition in following table, and calculate Delta SRI values.Composition passes through as described above
Method prepare.
((Delta (Δ) SRI) is listed in the table below in 10 observed value.
Table 10
Table 10 shows at anion according to the present invention and dianion ratio, obtains best greasiness removal result.
Claims (8)
1. a kind of composition for handling base material, it includes：
A) surfactant system for including anion surfactant and dianionic surfactant of 10 to 25 weight %,
The wherein described anion surfactant is selected from alkyl alkoxylated suifate, and the dianionic surfactant is selected from
The diphenyl oxide disulfonates of carbon chain lengths with C6 to C18；
B) fat of 1 to 15 weight % increases soluble oil, has 14 to 22MPa0.5The Hansen solubility parameters of (at 25 DEG C)
(δ HSP), wherein Hansen polar components (δ P) are 0.5 to 10MPa0.5(at 25 DEG C), dispersive (δ H) be 3 to
10MPa0.5(at 25 DEG C) and hydrogen bond component (δ D) are 13 to 18MPa0.5(at 25 DEG C)；
C) hydrogen peroxide of 2 to 12 weight %；With
D) water.
2. composition according to claim 1, wherein the δ HSP are calculated using 3.1 editions softwares of HSPiP.
3. composition according to claim 1 or 2, wherein the anion surfactant and dianion surface active
The ratio of agent is 4:1 to 20:1.
4. composition according to any one of claim 1 to 3, wherein it is methyl laurate that the fat, which increases soluble oil,.
5. composition according to any one of the preceding claims, it includes the water of 45 to 90 weight %.
6. a kind of method for handling base material comprising the step of following sequence：
A) composition according to any one of claim 1 to 5 is administered on the base material；
B) base material is washed with detergent；With,
C) dry the base material.
7. composition according to any one of claim 1 to 5 is used to remove the purposes of spot.
8. the purposes of composition according to claim 7, it is used to remove aqueous spot/can bleach spot, oil from fabric
Property spot, graininess spot and enzyme spot.
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| EP15190551.0 | 2015-10-20 | ||
| EP15190551 | 2015-10-20 | ||
| PCT/EP2016/073538 WO2017067772A1 (en) | 2015-10-20 | 2016-10-03 | A composition and method for treating substrates |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108350391A true CN108350391A (en) | 2018-07-31 |
| CN108350391B CN108350391B (en) | 2020-09-08 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201680061265.XA Expired - Fee Related CN108350391B (en) | 2015-10-20 | 2016-10-03 | Compositions and methods for treating substrates |
Country Status (9)
| Country | Link |
|---|---|
| EP (1) | EP3365416B1 (en) |
| CN (1) | CN108350391B (en) |
| AR (1) | AR106389A1 (en) |
| BR (1) | BR112018007652A2 (en) |
| CL (1) | CL2018000985A1 (en) |
| ES (1) | ES2740643T3 (en) |
| TR (1) | TR201906872T4 (en) |
| WO (1) | WO2017067772A1 (en) |
| ZA (1) | ZA201802090B (en) |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998000498A1 (en) * | 1996-06-28 | 1998-01-08 | The Procter & Gamble Company | Liquid cleaning compositions and shampoos containing dianionic or alkoxylated dianionic surfactants |
| WO1998000503A1 (en) * | 1996-06-28 | 1998-01-08 | The Procter & Gamble Company | Bleaching detergent compositions containing selected dianionic or alkoxylated dianionic surfactants |
| US20060100122A1 (en) * | 2004-11-05 | 2006-05-11 | Baars Evert P I | Cleaning and disinfectant compositions |
| CN102471725A (en) * | 2009-08-06 | 2012-05-23 | 阿科玛股份有限公司 | Liquid cleaning compositions |
| WO2014016134A1 (en) * | 2012-07-26 | 2014-01-30 | Unilever N.V. | Liquid detergent composition |
| CN103946357A (en) * | 2011-11-25 | 2014-07-23 | 荷兰联合利华有限公司 | Liquid detergent composition |
-
2016
- 2016-10-03 CN CN201680061265.XA patent/CN108350391B/en not_active Expired - Fee Related
- 2016-10-03 TR TR2019/06872T patent/TR201906872T4/en unknown
- 2016-10-03 BR BR112018007652A patent/BR112018007652A2/en not_active Application Discontinuation
- 2016-10-03 ES ES16778313T patent/ES2740643T3/en active Active
- 2016-10-03 EP EP16778313.3A patent/EP3365416B1/en active Active
- 2016-10-03 WO PCT/EP2016/073538 patent/WO2017067772A1/en active Application Filing
- 2016-10-18 AR ARP160103171A patent/AR106389A1/en active IP Right Grant
-
2018
- 2018-03-28 ZA ZA2018/02090A patent/ZA201802090B/en unknown
- 2018-04-17 CL CL2018000985A patent/CL2018000985A1/en unknown
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO1998000498A1 (en) * | 1996-06-28 | 1998-01-08 | The Procter & Gamble Company | Liquid cleaning compositions and shampoos containing dianionic or alkoxylated dianionic surfactants |
| WO1998000503A1 (en) * | 1996-06-28 | 1998-01-08 | The Procter & Gamble Company | Bleaching detergent compositions containing selected dianionic or alkoxylated dianionic surfactants |
| US20060100122A1 (en) * | 2004-11-05 | 2006-05-11 | Baars Evert P I | Cleaning and disinfectant compositions |
| CN102471725A (en) * | 2009-08-06 | 2012-05-23 | 阿科玛股份有限公司 | Liquid cleaning compositions |
| CN103946357A (en) * | 2011-11-25 | 2014-07-23 | 荷兰联合利华有限公司 | Liquid detergent composition |
| WO2014016134A1 (en) * | 2012-07-26 | 2014-01-30 | Unilever N.V. | Liquid detergent composition |
Also Published As
| Publication number | Publication date |
|---|---|
| AR106389A1 (en) | 2018-01-10 |
| WO2017067772A1 (en) | 2017-04-27 |
| EP3365416A1 (en) | 2018-08-29 |
| EP3365416B1 (en) | 2019-05-01 |
| BR112018007652A2 (en) | 2018-11-06 |
| CL2018000985A1 (en) | 2018-07-06 |
| TR201906872T4 (en) | 2019-05-21 |
| ES2740643T3 (en) | 2020-02-06 |
| ZA201802090B (en) | 2019-07-31 |
| CN108350391B (en) | 2020-09-08 |
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