CN1083463A - Gas generating agent used for safety gas bag - Google Patents
Gas generating agent used for safety gas bag Download PDFInfo
- Publication number
- CN1083463A CN1083463A CN93109451A CN93109451A CN1083463A CN 1083463 A CN1083463 A CN 1083463A CN 93109451 A CN93109451 A CN 93109451A CN 93109451 A CN93109451 A CN 93109451A CN 1083463 A CN1083463 A CN 1083463A
- Authority
- CN
- China
- Prior art keywords
- gas
- halate
- agent
- evolution agent
- compound
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 70
- 239000007789 gas Substances 0.000 claims abstract description 47
- IJGRMHOSHXDMSA-UHFFFAOYSA-N Atomic nitrogen Chemical compound N#N IJGRMHOSHXDMSA-UHFFFAOYSA-N 0.000 claims abstract description 18
- 229910052757 nitrogen Inorganic materials 0.000 claims abstract description 9
- 150000002894 organic compounds Chemical class 0.000 claims abstract description 9
- -1 amino organic compound Chemical class 0.000 claims description 35
- 150000001875 compounds Chemical class 0.000 claims description 16
- USVVENVKYJZFMW-ONEGZZNKSA-N (e)-carboxyiminocarbamic acid Chemical compound OC(=O)\N=N\C(O)=O USVVENVKYJZFMW-ONEGZZNKSA-N 0.000 claims description 13
- 239000003054 catalyst Substances 0.000 claims description 12
- 230000001105 regulatory effect Effects 0.000 claims description 7
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims description 6
- 239000001301 oxygen Substances 0.000 claims description 6
- 229910052760 oxygen Inorganic materials 0.000 claims description 6
- 238000005474 detonation Methods 0.000 claims description 5
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 claims description 3
- BSPUVYFGURDFHE-UHFFFAOYSA-N Nitramine Natural products CC1C(O)CCC2CCCNC12 BSPUVYFGURDFHE-UHFFFAOYSA-N 0.000 claims description 3
- 229910052728 basic metal Inorganic materials 0.000 claims description 3
- 150000003818 basic metals Chemical class 0.000 claims description 3
- POCJOGNVFHPZNS-UHFFFAOYSA-N isonitramine Natural products OC1CCCCC11CNCCC1 POCJOGNVFHPZNS-UHFFFAOYSA-N 0.000 claims description 3
- 230000000737 periodic effect Effects 0.000 claims description 3
- 229920013662 Zylonite Polymers 0.000 claims 1
- SMEGJBVQLJJKKX-HOTMZDKISA-N [(2R,3S,4S,5R,6R)-5-acetyloxy-3,4,6-trihydroxyoxan-2-yl]methyl acetate Chemical compound CC(=O)OC[C@@H]1[C@H]([C@@H]([C@H]([C@@H](O1)O)OC(=O)C)O)O SMEGJBVQLJJKKX-HOTMZDKISA-N 0.000 claims 1
- 238000002485 combustion reaction Methods 0.000 abstract description 23
- 239000000470 constituent Substances 0.000 description 41
- PXIPVTKHYLBLMZ-UHFFFAOYSA-N Sodium azide Chemical compound [Na+].[N-]=[N+]=[N-] PXIPVTKHYLBLMZ-UHFFFAOYSA-N 0.000 description 34
- 238000012360 testing method Methods 0.000 description 32
- 239000000203 mixture Substances 0.000 description 20
- 239000002585 base Substances 0.000 description 15
- 238000006243 chemical reaction Methods 0.000 description 15
- QPLDLSVMHZLSFG-UHFFFAOYSA-N Copper oxide Chemical compound [Cu]=O QPLDLSVMHZLSFG-UHFFFAOYSA-N 0.000 description 10
- 239000012467 final product Substances 0.000 description 7
- 239000011734 sodium Substances 0.000 description 7
- 229910001220 stainless steel Inorganic materials 0.000 description 7
- 239000010935 stainless steel Substances 0.000 description 7
- PXHVJJICTQNCMI-UHFFFAOYSA-N Nickel Chemical compound [Ni] PXHVJJICTQNCMI-UHFFFAOYSA-N 0.000 description 6
- 229940042795 hydrazides for tuberculosis treatment Drugs 0.000 description 6
- 238000004519 manufacturing process Methods 0.000 description 6
- 238000000034 method Methods 0.000 description 6
- 238000002360 preparation method Methods 0.000 description 6
- 231100000331 toxic Toxicity 0.000 description 6
- 230000002588 toxic effect Effects 0.000 description 6
- BZSXEZOLBIJVQK-UHFFFAOYSA-N 2-methylsulfonylbenzoic acid Chemical compound CS(=O)(=O)C1=CC=CC=C1C(O)=O BZSXEZOLBIJVQK-UHFFFAOYSA-N 0.000 description 5
- 239000004698 Polyethylene Substances 0.000 description 5
- 239000003638 chemical reducing agent Substances 0.000 description 5
- 239000000463 material Substances 0.000 description 5
- 229920000573 polyethylene Polymers 0.000 description 5
- 231100000419 toxicity Toxicity 0.000 description 5
- 230000001988 toxicity Effects 0.000 description 5
- XTFIVUDBNACUBN-UHFFFAOYSA-N 1,3,5-trinitro-1,3,5-triazinane Chemical compound [O-][N+](=O)N1CN([N+]([O-])=O)CN([N+]([O-])=O)C1 XTFIVUDBNACUBN-UHFFFAOYSA-N 0.000 description 4
- 229910052782 aluminium Inorganic materials 0.000 description 4
- 150000001412 amines Chemical class 0.000 description 4
- 230000003750 conditioning effect Effects 0.000 description 4
- 239000004615 ingredient Substances 0.000 description 4
- KINULKKPVJYRON-PVNXHVEDSA-N n-[(e)-[10-[(e)-(4,5-dihydro-1h-imidazol-2-ylhydrazinylidene)methyl]anthracen-9-yl]methylideneamino]-4,5-dihydro-1h-imidazol-2-amine;hydron;dichloride Chemical compound Cl.Cl.N1CCN=C1N\N=C\C(C1=CC=CC=C11)=C(C=CC=C2)C2=C1\C=N\NC1=NCCN1 KINULKKPVJYRON-PVNXHVEDSA-N 0.000 description 4
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 239000000654 additive Substances 0.000 description 3
- 239000004411 aluminium Substances 0.000 description 3
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 3
- AXZAYXJCENRGIM-UHFFFAOYSA-J dipotassium;tetrabromoplatinum(2-) Chemical compound [K+].[K+].[Br-].[Br-].[Br-].[Br-].[Pt+2] AXZAYXJCENRGIM-UHFFFAOYSA-J 0.000 description 3
- HTUMBQDCCIXGCV-UHFFFAOYSA-N lead oxide Chemical compound [O-2].[Pb+2] HTUMBQDCCIXGCV-UHFFFAOYSA-N 0.000 description 3
- YEXPOXQUZXUXJW-UHFFFAOYSA-N lead(II) oxide Inorganic materials [Pb]=O YEXPOXQUZXUXJW-UHFFFAOYSA-N 0.000 description 3
- 229910052749 magnesium Inorganic materials 0.000 description 3
- 238000000465 moulding Methods 0.000 description 3
- 229910001487 potassium perchlorate Inorganic materials 0.000 description 3
- 239000000843 powder Substances 0.000 description 3
- 230000037452 priming Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 239000003380 propellant Substances 0.000 description 3
- 230000035945 sensitivity Effects 0.000 description 3
- 229910052708 sodium Inorganic materials 0.000 description 3
- SUKJFIGYRHOWBL-UHFFFAOYSA-N sodium hypochlorite Chemical compound [Na+].Cl[O-] SUKJFIGYRHOWBL-UHFFFAOYSA-N 0.000 description 3
- BAZAXWOYCMUHIX-UHFFFAOYSA-M sodium perchlorate Chemical compound [Na+].[O-]Cl(=O)(=O)=O BAZAXWOYCMUHIX-UHFFFAOYSA-M 0.000 description 3
- 229910001488 sodium perchlorate Inorganic materials 0.000 description 3
- ZRALSGWEFCBTJO-UHFFFAOYSA-N Guanidine Chemical compound NC(N)=N ZRALSGWEFCBTJO-UHFFFAOYSA-N 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 229910010413 TiO 2 Inorganic materials 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 230000000996 additive effect Effects 0.000 description 2
- 229910052783 alkali metal Inorganic materials 0.000 description 2
- ZJRXSAYFZMGQFP-UHFFFAOYSA-N barium peroxide Chemical compound [Ba+2].[O-][O-] ZJRXSAYFZMGQFP-UHFFFAOYSA-N 0.000 description 2
- LSWZMKLTBNIIHY-UHFFFAOYSA-N barium(2+);oxido-(oxido(dioxo)chromio)oxy-dioxochromium Chemical compound [Ba+2].[O-][Cr](=O)(=O)O[Cr]([O-])(=O)=O LSWZMKLTBNIIHY-UHFFFAOYSA-N 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 2
- 239000001913 cellulose Substances 0.000 description 2
- 229920002678 cellulose Polymers 0.000 description 2
- SNRUBQQJIBEYMU-UHFFFAOYSA-N dodecane Chemical compound CCCCCCCCCCCC SNRUBQQJIBEYMU-UHFFFAOYSA-N 0.000 description 2
- 150000002148 esters Chemical class 0.000 description 2
- 238000004880 explosion Methods 0.000 description 2
- 230000003116 impacting effect Effects 0.000 description 2
- QQVIHTHCMHWDBS-UHFFFAOYSA-N isophthalic acid Chemical compound OC(=O)C1=CC=CC(C(O)=O)=C1 QQVIHTHCMHWDBS-UHFFFAOYSA-N 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- 239000012188 paraffin wax Substances 0.000 description 2
- LLYCMZGLHLKPPU-UHFFFAOYSA-M perbromate Chemical compound [O-]Br(=O)(=O)=O LLYCMZGLHLKPPU-UHFFFAOYSA-M 0.000 description 2
- 230000008447 perception Effects 0.000 description 2
- VLTRZXGMWDSKGL-UHFFFAOYSA-N perchloric acid Chemical compound OCl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-N 0.000 description 2
- 229910052700 potassium Inorganic materials 0.000 description 2
- VKJKEPKFPUWCAS-UHFFFAOYSA-M potassium chlorate Chemical compound [K+].[O-]Cl(=O)=O VKJKEPKFPUWCAS-UHFFFAOYSA-M 0.000 description 2
- 239000012286 potassium permanganate Substances 0.000 description 2
- 239000000047 product Substances 0.000 description 2
- 238000006479 redox reaction Methods 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 125000001424 substituent group Chemical group 0.000 description 2
- 125000000383 tetramethylene group Chemical group [H]C([H])([*:1])C([H])([H])C([H])([H])C([H])([H])[*:2] 0.000 description 2
- 229910052725 zinc Inorganic materials 0.000 description 2
- 229910052726 zirconium Inorganic materials 0.000 description 2
- POCJOGNVFHPZNS-ZJUUUORDSA-N (6S,7R)-2-azaspiro[5.5]undecan-7-ol Chemical compound O[C@@H]1CCCC[C@]11CNCCC1 POCJOGNVFHPZNS-ZJUUUORDSA-N 0.000 description 1
- OTXHZHQQWQTQMW-UHFFFAOYSA-N (diaminomethylideneamino)azanium;hydrogen carbonate Chemical compound OC([O-])=O.N[NH2+]C(N)=N OTXHZHQQWQTQMW-UHFFFAOYSA-N 0.000 description 1
- GNWLDEDHYUOIDF-UHFFFAOYSA-N 1-amino-3-(methylamino)urea Chemical compound CNNC(=O)NN GNWLDEDHYUOIDF-UHFFFAOYSA-N 0.000 description 1
- IDCPFAYURAQKDZ-UHFFFAOYSA-N 1-nitroguanidine Chemical compound NC(=N)N[N+]([O-])=O IDCPFAYURAQKDZ-UHFFFAOYSA-N 0.000 description 1
- XRNSUHLEVOUTDT-UHFFFAOYSA-N 10-hydrazinyl-10-oxodecanoic acid Chemical class NNC(=O)CCCCCCCCC(O)=O XRNSUHLEVOUTDT-UHFFFAOYSA-N 0.000 description 1
- UOYIYWCAYFTQLH-UHFFFAOYSA-N 3,7-dinitro-1,3,5,7-tetrazabicyclo[3.3.1]nonane Chemical compound C1N2CN([N+](=O)[O-])CN1CN([N+]([O-])=O)C2 UOYIYWCAYFTQLH-UHFFFAOYSA-N 0.000 description 1
- LEVONNIFUFSRKZ-UHFFFAOYSA-N 3-(carboxymethyl)-2,2-dimethylcyclobutane-1-carboxylic acid Chemical compound CC1(C)C(CC(O)=O)CC1C(O)=O LEVONNIFUFSRKZ-UHFFFAOYSA-N 0.000 description 1
- XWNSFEAWWGGSKJ-UHFFFAOYSA-N 4-acetyl-4-methylheptanedinitrile Chemical compound N#CCCC(C)(C(=O)C)CCC#N XWNSFEAWWGGSKJ-UHFFFAOYSA-N 0.000 description 1
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 1
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 229920002134 Carboxymethyl cellulose Polymers 0.000 description 1
- 241000195493 Cryptophyta Species 0.000 description 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 description 1
- CHJJGSNFBQVOTG-UHFFFAOYSA-N N-methyl-guanidine Natural products CNC(N)=N CHJJGSNFBQVOTG-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 239000000020 Nitrocellulose Substances 0.000 description 1
- 239000004677 Nylon Substances 0.000 description 1
- 235000003140 Panax quinquefolius Nutrition 0.000 description 1
- 240000005373 Panax quinquefolius Species 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000004153 Potassium bromate Substances 0.000 description 1
- 229920002472 Starch Polymers 0.000 description 1
- XSQUKJJJFZCRTK-UHFFFAOYSA-N Urea Chemical compound NC(N)=O XSQUKJJJFZCRTK-UHFFFAOYSA-N 0.000 description 1
- FJWGYAHXMCUOOM-QHOUIDNNSA-N [(2s,3r,4s,5r,6r)-2-[(2r,3r,4s,5r,6s)-4,5-dinitrooxy-2-(nitrooxymethyl)-6-[(2r,3r,4s,5r,6s)-4,5,6-trinitrooxy-2-(nitrooxymethyl)oxan-3-yl]oxyoxan-3-yl]oxy-3,5-dinitrooxy-6-(nitrooxymethyl)oxan-4-yl] nitrate Chemical compound O([C@@H]1O[C@@H]([C@H]([C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O)O[C@H]1[C@@H]([C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@@H](CO[N+]([O-])=O)O1)O[N+]([O-])=O)CO[N+](=O)[O-])[C@@H]1[C@@H](CO[N+]([O-])=O)O[C@@H](O[N+]([O-])=O)[C@H](O[N+]([O-])=O)[C@H]1O[N+]([O-])=O FJWGYAHXMCUOOM-QHOUIDNNSA-N 0.000 description 1
- XCSDWRTXMNEANB-UHFFFAOYSA-N [K].Br(=O)(=O)(=O)O Chemical compound [K].Br(=O)(=O)(=O)O XCSDWRTXMNEANB-UHFFFAOYSA-N 0.000 description 1
- QPLYLJGKQHTSKJ-UHFFFAOYSA-N [Na].Br(=O)(=O)(=O)O Chemical compound [Na].Br(=O)(=O)(=O)O QPLYLJGKQHTSKJ-UHFFFAOYSA-N 0.000 description 1
- OFLXLNCGODUUOT-UHFFFAOYSA-N acetohydrazide Chemical compound C\C(O)=N\N OFLXLNCGODUUOT-UHFFFAOYSA-N 0.000 description 1
- 150000001340 alkali metals Chemical class 0.000 description 1
- PNEYBMLMFCGWSK-UHFFFAOYSA-N aluminium oxide Inorganic materials [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 description 1
- 239000000440 bentonite Substances 0.000 description 1
- 229910000278 bentonite Inorganic materials 0.000 description 1
- SVPXDRXYRYOSEX-UHFFFAOYSA-N bentoquatam Chemical compound O.O=[Si]=O.O=[Al]O[Al]=O SVPXDRXYRYOSEX-UHFFFAOYSA-N 0.000 description 1
- CUBCNYWQJHBXIY-UHFFFAOYSA-N benzoic acid;2-hydroxybenzoic acid Chemical compound OC(=O)C1=CC=CC=C1.OC(=O)C1=CC=CC=C1O CUBCNYWQJHBXIY-UHFFFAOYSA-N 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- OHJMTUPIZMNBFR-UHFFFAOYSA-N biuret Chemical compound NC(=O)NC(N)=O OHJMTUPIZMNBFR-UHFFFAOYSA-N 0.000 description 1
- 229910052796 boron Inorganic materials 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-M bromate Inorganic materials [O-]Br(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-M 0.000 description 1
- SXDBWCPKPHAZSM-UHFFFAOYSA-N bromic acid Chemical compound OBr(=O)=O SXDBWCPKPHAZSM-UHFFFAOYSA-N 0.000 description 1
- 238000004364 calculation method Methods 0.000 description 1
- 239000004202 carbamide Substances 0.000 description 1
- 235000013877 carbamide Nutrition 0.000 description 1
- XEVRDFDBXJMZFG-UHFFFAOYSA-N carbonyl dihydrazine Chemical compound NNC(=O)NN XEVRDFDBXJMZFG-UHFFFAOYSA-N 0.000 description 1
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- 235000010948 carboxy methyl cellulose Nutrition 0.000 description 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 description 1
- 229940105329 carboxymethylcellulose Drugs 0.000 description 1
- 239000003153 chemical reaction reagent Substances 0.000 description 1
- 235000019504 cigarettes Nutrition 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 239000000567 combustion gas Substances 0.000 description 1
- 239000002131 composite material Substances 0.000 description 1
- 239000013256 coordination polymer Substances 0.000 description 1
- 229910052802 copper Inorganic materials 0.000 description 1
- 230000007797 corrosion Effects 0.000 description 1
- 238000005260 corrosion Methods 0.000 description 1
- 229960004643 cupric oxide Drugs 0.000 description 1
- 238000000354 decomposition reaction Methods 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- QGBSISYHAICWAH-UHFFFAOYSA-N dicyandiamide Chemical compound NC(N)=NC#N QGBSISYHAICWAH-UHFFFAOYSA-N 0.000 description 1
- SWSQBOPZIKWTGO-UHFFFAOYSA-N dimethylaminoamidine Natural products CN(C)C(N)=N SWSQBOPZIKWTGO-UHFFFAOYSA-N 0.000 description 1
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 1
- 229940079593 drug Drugs 0.000 description 1
- 239000003814 drug Substances 0.000 description 1
- 125000001495 ethyl group Chemical group [H]C([H])([H])C([H])([H])* 0.000 description 1
- 239000000835 fiber Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 125000002485 formyl group Chemical group [H]C(*)=O 0.000 description 1
- 230000006870 function Effects 0.000 description 1
- ZZUFCTLCJUWOSV-UHFFFAOYSA-N furosemide Chemical compound C1=C(Cl)C(S(=O)(=O)N)=CC(C(O)=O)=C1NCC1=CC=CO1 ZZUFCTLCJUWOSV-UHFFFAOYSA-N 0.000 description 1
- 239000010439 graphite Substances 0.000 description 1
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- 239000003721 gunpowder Substances 0.000 description 1
- 231100001261 hazardous Toxicity 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 125000004029 hydroxymethyl group Chemical group [H]OC([H])([H])* 0.000 description 1
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 description 1
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- 229910052748 manganese Inorganic materials 0.000 description 1
- 238000002844 melting Methods 0.000 description 1
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- ZXDZVVSOWQEMOD-UHFFFAOYSA-N nitric hydrazide Chemical class NN[N+]([O-])=O ZXDZVVSOWQEMOD-UHFFFAOYSA-N 0.000 description 1
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- QJGQUHMNIGDVPM-UHFFFAOYSA-N nitrogen group Chemical group [N] QJGQUHMNIGDVPM-UHFFFAOYSA-N 0.000 description 1
- 125000000018 nitroso group Chemical group N(=O)* 0.000 description 1
- XKLJHFLUAHKGGU-UHFFFAOYSA-N nitrous amide Chemical compound ON=N XKLJHFLUAHKGGU-UHFFFAOYSA-N 0.000 description 1
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- 239000007800 oxidant agent Substances 0.000 description 1
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- VLTRZXGMWDSKGL-UHFFFAOYSA-M perchlorate Inorganic materials [O-]Cl(=O)(=O)=O VLTRZXGMWDSKGL-UHFFFAOYSA-M 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 235000019396 potassium bromate Nutrition 0.000 description 1
- 229940094037 potassium bromate Drugs 0.000 description 1
- 239000003507 refrigerant Substances 0.000 description 1
- 238000011160 research Methods 0.000 description 1
- 229920005989 resin Polymers 0.000 description 1
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- XUXNAKZDHHEHPC-UHFFFAOYSA-M sodium bromate Chemical compound [Na+].[O-]Br(=O)=O XUXNAKZDHHEHPC-UHFFFAOYSA-M 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 239000008107 starch Substances 0.000 description 1
- 235000019698 starch Nutrition 0.000 description 1
- 150000003585 thioureas Chemical class 0.000 description 1
- 239000002341 toxic gas Substances 0.000 description 1
- LOZOGGLFSJGOHI-UHFFFAOYSA-N triazin-4-ylhydrazine Chemical class NNC1=CC=NN=N1 LOZOGGLFSJGOHI-UHFFFAOYSA-N 0.000 description 1
- 230000000007 visual effect Effects 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
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Images
Landscapes
- Air Bags (AREA)
- Feeding, Discharge, Calcimining, Fusing, And Gas-Generation Devices (AREA)
Abstract
Gas generating agent used for safety gas bag of the present invention is made of organic compounds containing nitrogen and oxo halate, the invention provides superior impact ignition quality, combustionvelocity and gas generating capacity, and reach the gas generating agent used for safety gas bag of lower temperature of combustion.
Description
The present invention relates to the gas-evolution agent that a kind of air bag is used.
When vehicles such as automobile bump against at a high speed, locate at the handle portion of vehicle or windshield etc. and cause the casualties in order to prevent that the occupant from hitting, inside at handle or panel board is incorporated with Nylon Bag, it can perception collides and produces and expand, and improves growth sharp for the demand of this air bag system day by day because of the security requirement to automobile etc.
The moment of air bag after perception collides makes gas-evolution agent fire burns by electric or mechanical means igniting, and the gas that produces expands airbag.And the gas-evolution agent sheet of moulding or discoid normally, used gas-evolution agent must have suitable combustionvelocity.Combustionvelocity slowly then deficiency thereby can not be used as air bag so that the instantaneous expansion of airbag.In addition, if gas-evolution agent is a powder stock, then have and impact the character of catching fire, so-called impact ignition quality is for the ballistic sensitivity of catching fire, its oversensitiveness then can have bigger explosion hazard in manufacturing processedes such as married operation or moulding process, so from safety say be do not wish such, and desirable be that to impact ignition quality low as much as possible.
In addition, do not require that gas-evolution agent has too high temperature of combustion.This is because common airbag sponges impact when the occupant is clashed into, and then in order to help the occupant to deviate from, allows internal gas after expanding emit and shrink.The temperature that the temperature of combustion height is then emitted gas is just high, thereby gas is burnt the occupant, or boiled hole descends its function on airbag, even the danger of airbag burning causing vehicle fire is increased.
The gas-evolution agent that the air bag in past is used is well known that with sodiumazide as gas generation base, and comprises for example oxygenant [TiO
2, MnO
2, Fe
2O
3, metal oxides such as CuO, NaNO
3, KNO
3, Cu(NO
3)
2Deng nitrate, KClO
4, NaClO
4Deng perchlorate, KClO
3, NaClO
3Deng oxymuriate or the like], metallic reducing agent [Zr, Mg, AL, Ti etc.], refrigerant [Na
2CO
3, K
2CO
3, CaCO
3, FeSO
4Deng], pH value conditioning agent [ferric sulfate etc.], mechanical property rising agent [MoS
2, KBr, graphite etc.] etc. additive.
Because above-mentioned is that the gas-evolution agent of base mainly produces nitrogen with the sodiumazide, suitable combustionvelocity is arranged again, lower high-performances such as temperature of combustion, thereby be widely used as the gas-evolution agent of air bag, but sodiumazide exists following problem:
(1) have because of decomposing or burning causes the danger of fire, thereby (when mixing with oxygenant, make when granular preparation etc.) causes the danger of fire because when manufacturing is arranged, so security control that must the implementation strictness.
Generate Na when (2) decomposing, Na and water reaction produce hydrogen, and be on fire easily, also can produce toxic smog, therefore handles very difficulty.
(3) because and oxidant reaction, produce Na
2O, and inductor (NaOH etc.) toxic ingredient handle during manufacturing and must pay close attention to.
(4) sodiumazide burns or decomposes the gas that is produced because the very high concentration of toxic gases of nitrogen concentration is very low, thereby no problem in practicality, but people still wish to have lower toxic ingredient concentration in the hope of perfectly sound.
(5) the rough sodiumazide as gas-evolution agent has water absorbability, and moisture absorption afterfire performance reduces, and therefore must have to prevent to draw wet countermeasure.
(6), thereby need the promising facility investment that guarantee that safety is carried out owing to toxic, dangerous high material.
These problems in view of sodiumazide, people wish the gas-evolution agent that has a kind of air bag to use, it has with sodiumazide is the identical or lower impact ignition quality of gas-evolution agent of base, identical or higher combustionvelocity and gas generating capacity are arranged, it is the lower danger and the toxicity of gas-evolution agent of base that the sodiumazide lower than temperature of combustion arranged, and more cheap.
On the other hand, people to the nitrogen compound for the gas-evolution agent base has carried out all tests, for example, propose use Zr, oxygenants such as metallic reducing agent such as Mg and potassium perchlorate, Potcrate carry out redox reaction, Sheng Re and gas generation base is burnt.Enumerated with smokeless powder, cellulose nitrate, azo-dicarboxylic acid amides as gas generation base, the arsyl guanidine, thio ureas etc. (are seen special public clear 49-9734, special public clear 49-21171 communique), but the combustionvelocity of aforesaid method is still impracticable as air bag, the mixture of metallic reducing agent and oxygenant has very high impact ignition quality in addition, thereby has and handle to go up dangerous greatly problem, and can envision it very high temperature of combustion is arranged.
Though and the spy opens to disclose in the clear 50-118979 communique and uses the azo-dicarboxylic acid amides, oxygenants such as organic compounds containing nitrogen such as three hydrazino triazines and potassium permanganate, Manganse Dioxide, barium dichromate, barium peroxide are formed the airbag gas-evolution agent, but use potassium permanganate, it impacts ignition quality during oxygenants such as Manganse Dioxide, combustionvelocity can not meet the demands, use barium dichromate, during oxygenants such as barium peroxide, then can generate toxic ingredient in the gas.
One of purpose of the present invention provides a kind of gas generating agent used for safety gas bag, and it has with sodiumazide is the identical or lower impact ignition quality of gas-evolution agent of base.
Another object of the present invention provides that a kind of to have with sodiumazide be the identical or higher combustionvelocity of the gas-evolution agent of base and the airbag gas-evolution agent of gas generating capacity.
Another purpose of the present invention provides a kind of airbag gas-evolution agent that does not have above-mentioned (1)～(a 6) shortcoming of triazo-compound.
A further object of the present invention provides a kind of danger and lower gas generating agent used for safety gas bag of toxicity of the sodiumazide lower than temperature of combustion.
In order to reach above-mentioned purpose of the present invention, according to causing the extremely low nitrogenous compound of the danger of fire and the toxicity result of research with keen determination repeatedly to decomposing with burning, the heat that has obtained can not taking place owing to redox reaction is given birth to makes nitrogenous compound incendiary secondary reaction, utilize the reductibility of this nitrogenous compound make itself and specific oxygenant promptly with oxo halate direct reaction, reach with sodiumazide is the identical or lower impact ignition quality of gas-evolution agent of base, identical or than its higher combustionvelocity and gas generating capacity, and the practical low combustion temperature that requires that attains full and complete satisfaction.
Promptly the invention relates to the gas generating agent used for safety gas bag of forming by organic compounds containing nitrogen and oxo halate.
The present invention has used nitrogenous compound as gas generation base; nitrogenous compound is so long as there is the organic compound of nitrogen-atoms to get final product in molecule; do not limited especially; can enumerate for example amino organic compound; contain the nitramine organic compound; contain nitrosamine organic compound etc.; as the example that contains amino organic compound; also do not limit especially; can enumerate for example azo-dicarboxylic acid amides; urea; aminoguanidine bicarbonate; biuret; the dicyano diamide; hydrazides class (acethydrazide for example; 1; 2-di-acetyl hydrazine; the laurostearic acid hydrazides; the Whitfield's ointment hydrazides; the nitric acid hydrazides; carbohydrazide; the pinic acid hydrazides; the sebacic acid hydrazides; the dodecane hydrazides; the iso-phthalic acid hydrazides, methyl carbohydrazide, half carbodiazide; formyl row; 1; 2-diformyl hydrazine) etc., also do not limited especially, can be enumerated for example dinitropentamethylenetetramine as the compound that contains nitramine; trimethylene-trinitramine (RDX); tetramethylene tetranitro amine (HMX) etc. have a fatty compounds and an ester ring type compound to a plurality of nitramines as substituent, and the organic compound that contains nitrosamine is not limited especially, and for example can enumerate to wait as substituent with dinitroso pentamethylene tsiklomitsin (DPT) has extremely a plurality of nitroso fatty compoundss and an ester ring type compound; in these nitrogenous compounds; azo carbon amide, the past for example all is widely used as resin expanded dose, so since not fire hazardous with toxicity is low thereby handle in the less particularly suitable of danger; nitrogenous compound can be used alone or with two or more whiles and usefulness, nitrogenous compound can directly use the commercial goods.The shape of nitrogenous compound, granularity etc. are all unrestricted, suitably select for use to get final product.
The used oxygenant of the present invention is oxo halate, oxo halate is public use already, halate wherein, it is then better to cross halate etc., and their an alkali metal salt is better, the basic metal halate can be enumerated for example Potcrate, sodium chlorate, potassium bromate, the oxymuriate of sodium bromate etc. and bromate etc., and the alkali-metal halate of crossing can be enumerated for example potassium perchlorate, the sodium perchlorate, perbromic acid potassium, perchlorates such as perbromic acid sodium and perbromate etc., oxo halate both can use separately also can be two or more and use, the use level of oxo halate is benchmark usually with the oxygen level, nitrogenous compound complete oxidation incendiary chemistry amount is got final product, and the appropriate change nitrogenous compound just can be adjusted combustionvelocity arbitrarily with the ratio that cooperates of oxo halate, temperature of combustion, the composition of combustion gases etc., thereby can in broad range, suitably select, be that 100 weight ratios can be with the oxo halate of 20～200 weight ratios for nitrogenous compound for example, cooperating with 30～200 part by weight then can be better.The shape of oxo halate, size etc. do not have special restriction, and suitable selecting for use gets final product.
Constituent of the present invention can select for use above-mentioned two kinds must contain a kind of burning adjusting catalyst, detonation suppressor and oxygen generating agent outside the composition not damage its performance degree of being at least.
It is that to keep the low safety performances such as ignition quality, explosion-proof of impacting constant or to keep the fundamental property of gas-evolution agents such as gas generating capacity constant that catalyst is regulated in burning, corresponding to application target to the suit catalyst of change of the combustionvelocity of one of fundamental property, catalyst is regulated in burning for example can enumerate the oxide compound of the 4th cycle and the 6th period element, muriate, carbonate, vitriol, cellulose compound, organic high molecular compound etc. in the periodic table of elements.Object lesson as oxide compound, muriate, carbonate and the vitriol of the 4th cycle in the periodic table of elements and the 6th period element for example can be enumerated ZnO, ZnCO
3, MnO
2, FeCl
3, CuO, Pb
3O
4, PbO
2, PbO, Pb
2O
3, S, TiO
2, V
2O
5, CeO
2, Ho
2O
3, CaO
2, Yb
2O
3, Al
2(SO
4)
3, ZnSO
4, MnSO
4, FeSO
4Deng.As the example of cellulose compound, can enumerate for example carboxy methylcellulose and ethyl group, hydroxymethyl fiber etc., and, can enumerate for example Zulkovsky starch, polyvinyl alcohol and partly-hydrolysed thing thereof etc. as the example of organic high molecular compound.Burning adjusting catalyst can be used alone or two or more and usefulness, it is unrestricted that the use level of catalyst is regulated in burning, can suit to select in broad range, usually for 100 the weight composition of adding up to of nitride and oxo halate, can use 0.1～50, the most handy 0.2～10.The granularity of catalyst is regulated in burning does not have special restriction, suitably selects to use to get final product.
Detonation suppressor is the additive for preventing the gas-evolution agent presence of fire, set off an explosion by thump to add in processes such as manufacturing, processing, conveying, if cause that possibility that gas-evolution agent explodes becomes nothing and has owing to added explosion-proofly to make, then can improve the security of processes such as gas-evolution agent manufacturing, processing, conveying more.Detonation suppressor can use material known, for example can enumerate, the oxide compound of bentonite, alumina, algae soil etc., Na, K, Ca, Mg, Zn, Cu, metal carbonates such as Al, supercarbonate etc.The use level of detonation suppressor does not have special restriction, can be in broad range suitably selects, and be to be taken as 5～30 at 100 o'clock to get final product for the gross weight of nitrogenous compound and oxo hydracid usually.
Oxygen generating agent has more effectively increased the O in the gas that constituent of the present invention burning generated
2Concentration.Oxygen generating agent does not have particular restriction, can use known material, can enumerate for example CuO
2, K
2O
4Deng.Use level to oxygen generating agent does not have particular restriction yet, can in broad range, choose, and be to be taken as 10～100 at 100 o'clock to get final product usually for the gross weight of nitrogenous compound and oxo halate.
In the constituent of the present invention, in the scope of not damaging its performance and then also, can contain temperature of combustion conditioning agent and combustion velocity regulator, the temperature of combustion conditioning agent, can enumerate for example metal carbonates such as Na, K, Ca, Mg, supercarbonate etc., combustion velocity regulator for example can be enumerated, the vitriol of Al, Zn, Mn etc. etc., the use level of temperature of combustion conditioning agent and/or combustion velocity regulator, specifically, usually be to be taken as 10 at 100 o'clock for the gross weight of nitrogenous compound and oxo halate, preferably be no more than 5 scope.
Can also be in the scope of not damaging its performance in the constituent of the present invention, contain used various additives in the gas-evolution agent of air bag in the past.
Constituent of the present invention gets by above-mentioned each composition is mixed, and the mixture that makes promptly can be used as gas-evolution agent, preferably makes preparation and uses, and preparation is made with ordinary method.For example with the present composition and an amount of hybrid shaping of tackiness agent and obtain.Tackiness agent can use the material commonly used that is suitable for this purpose.The preparation shape does not have particular restriction, for example can enumerate sheet, disk shape, spherical, bar-shaped, hollow cylindrical, " Application ん ペ ん " sugared shape, four jiaos of jar shapes etc., and atresia porose (for example honeycomb coaly) all can.Perhaps each composition of constituent of the present invention is made preparation respectively separately, they are mixed use again.
Constituent of the present invention has following advantage:
(a) since during constituent decomposition combustion of the present invention danger and the toxicity of presence of fire very low, danger is very little when making processing, it is easy to make preparation.
(b) constituent of the present invention has the identical or lower impact ignition quality of gas-evolution agent of making base with sodiumazide, and security is very high.
(c) to have with sodiumazide be the identical or higher combustionvelocity and the gas generating capacity of gas-evolution agent of base to constituent of the present invention.
(d) be the identical or lower temperature of combustion of gas-evolution agent of base owing to constituent of the present invention has with sodiumazide, thereby do not make the danger that the occupant burns, airbag punches, airbag catches fire, and toxic ingredient content is few in the gas that is produced.
(e) nitrogenous compound as the gas base of constituent of the present invention does not have water absorbability, so need not anti-moisture absorption measure.
(f) constituent of the present invention has low-down production cost.
(g) compare with the gas-evolution agent in past, constituent waste treatment of the present invention is easy.
Fig. 1 is the longitudinal sectional view of the employed collection and confinement of gases pump of pump testing;
Fig. 2 and Fig. 3 are the enlarged views that is assembled in the reaction vessel in the collection and confinement of gases pump;
Fig. 4 to Fig. 7 is the synoptic diagram that the fire test order is impacted in expression;
1. ... reactor 11. ... the aluminium fracture plate
2. ... collection and confinement of gases pump 12. ... priming mixture
3. ... pump cover 13. ... nickel wire
4. ... igniter fuse 14. ... pressure transmitter
5. ... electrode 15. ... stainless steel vessel
6. ... thermopair 16. ... pulverized specimen
7. ... pressure transmitter 17. ... the polyethylene card
8. ... exhaust 18. ... the polyethylene card
9. ... gas-evolution agent 19. ... detonator
10. ... nozzle 20. ... paraffin wax
List embodiment below, so that understand the present invention more.In the following embodiments, use the formal title of contract contracted notation or chemical formulation compound:
ADCA: azo-dicarboxylic acid amides
DPT: dinitroso pentamethylene tsiklomitsin
RDX: trimethylene-trinitramine
HMX: tetramethylene tetranitro amine
NQ: nitroguanidine
In the cooperation ratio (weight %) in the following Table 1, nitrogenous compound with oxo halate, add that as required combustionregulator mixes again, is obtained constituent of the present invention (NO.1～17)
Table 1
ACDA(30%ZnO): contain the ADCA of 30% weight ratio ZnO and the mixture of ZnO.
60Kg/cm is used in constituent NO.1～17 of the invention described above on hydraulic type tablet forming mill
2Pressure be pressed into the usefulness of tablet (footpath 5mm, high 5.0m.m) for 7.5 liters of pump testings, the result is as shown in table 2.
[pump testing]
Supervisor below with reference to Fig. 1～3 explanation pump testings;
1. take by weighing predetermined amount reagent (gas-evolution agent), constituent NO.1 of the present invention～15 tablets are put into reaction vessel (1).Reaction vessel divides two kinds of sizes, big internal diameter 50mm * high 50mm(Fig. 2), little internal diameter 30mm * high 50mm(Fig. 3);
2. nozzle of predetermined diameter (10) and aluminium fracture plate (11) (0.2mm is thick) are assemblied on the reaction vessel;
3. priming mixture (12) is installed in the reaction vessel, priming mixture is the boron and the KNO of 0.3 or 1 gram
3Mixture (2: 8) be rolled into entrainment with saran, pass spiral shell web-like nickel wire (13) (diameter 0.3mm * long 100mm) therein and constitute;
4. lid is installed on the reaction vessel, again reaction vessel is installed on the collection and confinement of gases pump (2);
5. igniter fuse (4) is contained on the electrode (5) of pump cover;
6. pump cover (3) is contained on the pump (2);
7. connect to go up and measure circuit system;
8. light a fire temperature in time pressure curve in the record reaction vessel and the pump after the reading the clock.
CP in the table 2
MaxBe peak pressure (Kg/cm in the chamber
2), W1/2 is 1/2 o'clock the time (millisecond) that cavity pressure arrives peak pressure, BP
MaxBe the peak pressure (Kg/cm in the pump
2), T
90Be that the pump internal pressure arrives 90% o'clock desired time (millisecond), BT
MaxBe the top temperature (Kg/cm that reaches in the pump
2).In these parameters, T is the numerical value of simulating Safety airbag developing time.CP
MaxBe that the index of constituent of the present invention as the superperformance of airbag propellant kept in expression.W1/2 is the parameter of simulation intracavity gas propellant combustionvelocity.BP
MaxIt is the parameter of gas generating capacity of the gas-evolution agent of representation unit quality.BT
MaxThe parameter of gas temperature in this airbag when being the expansion of simulating Safety airbag.
With cooperation ratio shown in the following table 3 (weight %),, adding as required that again burning regulates catalyst and mix and obtain constituent of the present invention with nitrogenous compound and oxo halate.
Constituent of the present invention is carried out following impact ignition quality test.For relatively, provide existing gas-evolution agent (NaN
3-KclO
4-Fe
3O
4With NaN
3-CuO) impact ignition quality test.
[impacting the ignition quality test]
This test is to measure the method for gas generation constituent because of the complexity on fire that is hit (impact catch fire sensitivity), below with reference to Fig. 4～Fig. 7 illustrative experiment program.
1.[Fig. 4]
Measure powdery test portion (16) 5 grams and put into test stainless steel vessel (15).Stainless steel vessel (15) be stainless steel (SuS304) make round-ended cylinder, internal diameter 31mm, external diameter 36mm, thick 2.5mm, high 55mm arranged.
2.[Fig. 5]
Load onto the polyethylene card (17) of desired thickness on test portion, the thickness summation of polyethylene card (17) is the length in gap.
3.[Fig. 6]
Detonator (19) is wherein inserted in the hole of opening diameter 6.5mm on the polyethylene card (18) of two thick 1mm, refills in the stainless steel vessel (15).The O electric detonator that detonator uses Japanese chemical drug (strain) to make.
4.[Fig. 7]
For the situation of the gas-evolution agent that contains water absorbability gas-evolution agent (for example sodiumazide),, cover the top of stainless sodium container (15) with paraffin (20) for protection against the tide.
5. this stainless steel vessel is fixed on the vice of blast in the vault, energising is ignited to detonator.
6. this moment, observe test portion and whether catch fire.
7. under the also non-ignitable situation of the long 1mm in gap, adopt 20 gram powdery test portions (16), D detonator (19) is inserted in the test portion, on stainless steel vessel (15), load onto threaded cap and test, in this way, impact the extremely low material of ignition quality also can fire burns or blast.
Inflammability limit gap length (to this gap length time catch fire) and missing of ignition clearance limit length (it is then missing of ignition to be longer than this gap length) have been shown in the table 3.
In this test, clearance limit length length mean impact catch fire highly sensitive.That is, the sensitivity of catching fire of the long more impact of inflammability limit gap length is high more, and danger is big more.
The impact ignition quality of constituent of the present invention is identical with existing product or than blunt as can be seen from table 3, and comparing with existing product has identical or higher security.
With the cooperation ratio (weight %) shown in the following table 4, azo-dicarboxylic acid amides (in the following table claim " ADCA ") with oxo halate, mix with burning adjusting catalyst as required again and obtain constituent of the present invention.
Use the invention described above constituent hydraulic type tablet forming mill with 60Kg/cm
2Pressure be pressed into tablet (diameter 7.6mm, high 3mm), for above-mentioned 7.5 liters of pump testing usefulness, its result also charges in the table 4.
In order to compare, to existing gas-evolution agent (NaN
3-CuO) carrying out 7.5 liters of pump testings, the result also charges in the table 4.
And then when carrying out 7.5 liters of pump testings, adopt two of the thick aluminium sheets of 0.1mm for being installed in the fracture plate that reaction vessel covers.
With the weight ratio of components is that 45 azo-dicarboxylic acid amides and weight ratio are that 55 sodium chlorate and weight ratio are 2.75 MnO
2Constituent tablet of the present invention (diameter 12.3mm * thick 3mm) 20 gram of formation, the automobile safety air bag of packing into is with in the gas generation cavity, and it is installed in the pump of capacity 28.61 of band pressure transmitter, uses B-KNO
31 gram makes the burning of this constituent with the tablet igniting.The interior peak pressure of container this moment is 4.3Kgf/cm
2Gauge pressure, the time that container inner pressure is risen owing to the burning of this constituent is 50 milliseconds.
In order to compare, with disclosed constituent among the public clear 49-21171 of spy, be that weight consists of the sodium chlorate of 200 azo-dicarboxylic acid amides and heavy 90 and gas generation constituent tablet (diameter 12.3mm * thick 3mm) 20 grams that heavy 110A constitutes, provide and be used for chamber test same as described above, its result, only observe the burning rapidly of the agent of catching fire, but do not observe the burning rapidly of gas composition thing.And the top pressure in the container is no more than 0.3Kgf/cm
2Gauge pressure.
Embodiment 5 and embodiment 6
Consist of 200 azo-dicarboxylic acid amides (claiming " ADCA " in the following table) and heavy 90 sodium chlorate (NaClO with weight
3) mix and to obtain constituent of the present invention.
For relatively, also made disclosed gas-evolution agent among the clear 49-21171 of special public affairs.That is, with weight consist of 200 azo-dicarboxylic acid amides and heavy 90 sodium chlorate and heavy 10 the Zr powder mixes and the comparison constituent.
Respectively they are configured as the tablet (diameter 5mm, high 5.0mm) identical, are with nozzle steel pipe combustion test and impact the ignition quality test, observe simultaneously and have or not generation flame, the results are shown in table 5 and the table 6 with embodiment 1.
[band nozzle steel pipe combustion test]
1. gas-evolution agent 5 gram is packed in the flame resistivity Steel Vessel (internal diameter 50mm, the cylinder of high 50mm), install nickel wire and add a cover, cover the hole that has diameter 7mm.
2. by the slip voltate regulator nickel wire is added 10V voltage, make the gas-evolution agent igniting.
3. the white cigarette of from the hole, emerging earlier, on fire then, measure record with visual or videocorder and be listed as the flame duration (combustion time) that stops burning from getting angry.
As can be seen from Table 5, owing to add the metallic reducing agent of Zr class the danger of gas-evolution agent is increased, and, the reaction of constituent of the present invention (burning) is a no flame, cryogenic, the comparison constituent that contains Zr then is flaming combustion and resultant of reaction (gas) temperature height, and therefore, constituent of the present invention does not preferably add Zr, AL, metallic reducing agents such as Mg.
The comparison constituent that contains Zr as can be seen from Table 6 is flaming combustion, and resultant of reaction (gas) temperature height.
This constituent is carried out strand combustion test (for example put down into 4 annual annual meetings, read to drill and want the 98th～99 page of point set " sodiumazide is the combustioncharacteristics of a gas-evolution agent " literary composition with reference to Corporation industry gunpowder association), study its combustionproperty.
1. at first weight is consisted of 55 the azo-dicarboxylic acid amides and the sodium perchlorate of weight 55 and heavy 5 lead monoxide and mix constituent of the present invention.
2. with this constituent press molding prism-shaped ((the pressure 1.25t/cm of 8mm * 5mm * 50mm)
2), prismatical side coating silicone resin is made test portion as stop-off gent.
3. in this test, use chimney strand corrosion chamber, during mensuration, on test portion with spaced apart two holes of about 40mm (diameter 0.6mm), fuse (diameter 0.5mm) therefrom by and be fixed in the device.
4. with this state, after the test temperature to be arrived (20 ℃), from top by the nickel wire igniting, make the test portion burning, the difference of the melting time by two fuses and the interval calculation in hole go out combustionvelocity (mm/ second).
5. this is determined at 10,20 and 40Kgf/cm
2Pressure under carry out.
Combustionvelocity is at 10Kgf/cm
2The time be 28.3mm/ second, 20Kgf/cm
2The time be 37.9mm, 40Kgf/cm
2The time be 46.0mm/ second.
Embodiment 8
Consist of 30 with weight, the azo-dicarboxylic acid amides mixes with the sodium perchlorate of weight 70 and obtains constituent of the present invention, carries out the test same with the foregoing description 7, and to calculate combustionvelocity be 10Kgf/cm
2The time missing of ignition, 40Kgf/cm
2The time be 48.3mm/ second.
40 grams are consisted of 45 azo-dicarboxylic acid amides with weight, automobile safety air bag pack into in the gas generation cavity with the tablet (diameter 112.3mm * thick 3mm) of the composite constituent of the present invention of cupric oxide of heavy 55 potassium perchlorate and heavy 10, the internal volume of being with pressure transmitter of again it being packed into is in 28.6 liters the pump, with 1 gram B-KNO
3Tablet is lighted, made constituent burning of the present invention.The result obtains and restrains airbag propellant (NaN in the past with 80
3: KClO
4: Fe
3O
4=60: 10: 30) time pressure curve in the resulting 28.6 liters identical pump.
Claims (9)
1, a kind of gas generating agent used for safety gas bag is characterized in that it is made up of organic compounds containing nitrogen and oxo halate.
2, a kind of gas-evolution agent as claimed in claim 1, wherein, oxo halate is halate and/or crosses halate.
3, a kind of gas-evolution agent as claimed in claim 1, wherein halate is the basic metal halate.
4, a kind of gas-evolution agent as claimed in claim 1, wherein crossing halate is that basic metal is crossed halate.
5, a kind of gas-evolution agent as claimed in claim 1, wherein organic compounds containing nitrogen is from containing amino organic compound, contain the nitramine organic compound and containing at least a compound of selecting the nitrosamine organic compound.
6, a kind of gas-evolution agent as claimed in claim 1, wherein, organic compounds containing nitrogen is the azo-dicarboxylic acid amides.
7, a kind of gas-evolution agent as claimed in claim 1 is wherein also regulated in catalyst, detonation suppressor and the oxygen generating agent in burning when containing organic compounds containing nitrogen and oxo halate and is contained therefrom select a kind of at least.
8, a kind of gas-evolution agent as claimed in claim 7, wherein, the oxide compound that catalyst is the 4th cycle and the 6th period element in the periodic table of elements is regulated in burning, and that chooses in muriate and the carbonate is at least a.
9, a kind of gas-evolution agent as claimed in claim 7, wherein, it is select in zylonite based compound and the organic high molecular compound at least a that catalyst is regulated in burning.
Applications Claiming Priority (6)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| JP4185251A JPH0632689A (en) | 1992-07-13 | 1992-07-13 | Gas-generating agent for air bag |
| JP185253/92 | 1992-07-13 | ||
| JP185251/92 | 1992-07-13 | ||
| JP4185253A JPH0632690A (en) | 1992-07-13 | 1992-07-13 | Gas-generating agent for air bag |
| JP18782/93 | 1993-02-05 | ||
| JP1878293A JPH06227884A (en) | 1993-02-05 | 1993-02-05 | Gas generator for air bag |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN1083463A true CN1083463A (en) | 1994-03-09 |
Family
ID=51579207
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93109451A Pending CN1083463A (en) | 1992-07-13 | 1993-06-22 | Gas generating agent used for safety gas bag |
Country Status (2)
| Country | Link |
|---|---|
| CN (1) | CN1083463A (en) |
| TW (1) | TW246684B (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301941C (en) * | 2002-06-14 | 2007-02-28 | 奥托里夫Asp股份有限公司 | Micro-gas generation |
| CN109721446A (en) * | 2019-03-17 | 2019-05-07 | 程爱宝 | A kind of micro- pyrotechnic composition complex composition and its application |
-
1993
- 1993-05-25 TW TW082104138A patent/TW246684B/zh active
- 1993-06-22 CN CN93109451A patent/CN1083463A/en active Pending
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1301941C (en) * | 2002-06-14 | 2007-02-28 | 奥托里夫Asp股份有限公司 | Micro-gas generation |
| CN109721446A (en) * | 2019-03-17 | 2019-05-07 | 程爱宝 | A kind of micro- pyrotechnic composition complex composition and its application |
| CN109721446B (en) * | 2019-03-17 | 2021-07-13 | 程爱宝 | Micro-pyrotechnic composition and application thereof |
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| TW246684B (en) | 1995-05-01 |
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