CN108343465A - Extinguishing method - Google Patents

Extinguishing method Download PDF

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Publication number
CN108343465A
CN108343465A CN201810146933.XA CN201810146933A CN108343465A CN 108343465 A CN108343465 A CN 108343465A CN 201810146933 A CN201810146933 A CN 201810146933A CN 108343465 A CN108343465 A CN 108343465A
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CN
China
Prior art keywords
mixture
blender
quality
coagulant
accounts
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Pending
Application number
CN201810146933.XA
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Chinese (zh)
Inventor
王利军
曾海利
赵洪伟
朱建伟
赵振波
贺帅
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Inner Mongolia Yitai Coal Co Ltd
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Inner Mongolia Yitai Coal Co Ltd
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Application filed by Inner Mongolia Yitai Coal Co Ltd filed Critical Inner Mongolia Yitai Coal Co Ltd
Priority to CN201810146933.XA priority Critical patent/CN108343465A/en
Publication of CN108343465A publication Critical patent/CN108343465A/en
Pending legal-status Critical Current

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    • EFIXED CONSTRUCTIONS
    • E21EARTH OR ROCK DRILLING; MINING
    • E21FSAFETY DEVICES, TRANSPORT, FILLING-UP, RESCUE, VENTILATION, OR DRAINING IN OR OF MINES OR TUNNELS
    • E21F5/00Means or methods for preventing, binding, depositing, or removing dust; Preventing explosions or fires
    • E21F5/08Rock dusting of mines; Depositing other protective substances
    • AHUMAN NECESSITIES
    • A62LIFE-SAVING; FIRE-FIGHTING
    • A62CFIRE-FIGHTING
    • A62C3/00Fire prevention, containment or extinguishing specially adapted for particular objects or places

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  • Engineering & Computer Science (AREA)
  • Mining & Mineral Resources (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • General Life Sciences & Earth Sciences (AREA)
  • Geochemistry & Mineralogy (AREA)
  • Geology (AREA)
  • Health & Medical Sciences (AREA)
  • Public Health (AREA)
  • Business, Economics & Management (AREA)
  • Emergency Management (AREA)
  • Fire-Extinguishing Compositions (AREA)

Abstract

The present invention relates to fire extinguishing fields, in particular to a kind of extinguishing method.Extinguishing method includes the following steps:Note is applied after being mixed again with the first mixture of waterglass class compound, flocculant and the remaining blender after coagulant and 5 15% blender of blender quality are mixed.It is this method mobility strong, flexibly practical, can to dotted, small space and it is uncomfortable share the Conflagration Caused by Coal Self-ignition that water is put out and handle, achieve the effect that safety, quickly, effectively put out a fire.

Description

Extinguishing method
Technical field
The present invention relates to fire extinguishing fields, in particular to a kind of extinguishing method.
Background technology
As coal mine gob range constantly increases, mine pressure shows gradually apparent, goaf coal column, closed compression easily formation Crack, goaf air leaking increase, and are very easy to cause spontaneous combustion of float in goaf.Fire once occurs for underground, is usually taken straight The method to fire-fight by water is connect, but water will produce water-gas by 600 DEG C or more red-hot coals, and it is quick-fried easily to induce water-gas It is fried, cause second accident;And existing thick loess grouting system inactivation system can not meet small range, sudden fire, and flexibly Mobility is poor;Nitrogen fire extinguishing is noted since nitrogen is easy leakage, generally requires first to close ignition region and need longer The note time is applied, extinguishing effect is poor, and flame range is easy to happen resume combustion phenomenon.Therefore it needs using a kind of mobility strong, is flexibly practical Extinguishing method come to dotted, small space and it is uncomfortable share the Conflagration Caused by Coal Self-ignition that water is put out and handle, reach safety, quickly, The effect effectively put out a fire.
Invention content
It is this method mobility strong, flexibly practical the present invention provides a kind of extinguishing method, can to dotted, small space and Discomfort shares the Conflagration Caused by Coal Self-ignition that water is put out and is handled, achieve the effect that safety, quickly, effectively put out a fire.
The invention is realized in this way:
A kind of extinguishing method, includes the following steps:The blender of coagulant and the 5-15% of blender quality are mixed Note is applied after being mixed again with the first mixture of waterglass class compound, flocculant and the remaining blender after conjunction.
The beneficial effects of the invention are as follows:Extinguishing method of the present invention, by when needing fire extinguishing just by coagulant and waterglass The silicic acid of netted condensation is obtained by the reaction in class compound, can cover coal mine surface or to gap blocked then effectively every Exhausted air, while gelatinous silicic acid can cure water so that water can quick extinguishing, prevent the generation of water-gas.Meanwhile passing through Silicic acid acts synergistically with flocculant, promotes the generation of gel and prevents gel from falling off or being cracked, then ensures its extinguishing effect. And coagulant and waterglass class compound are separately transported, stored, need fire extinguishing according to proportioning provided in an embodiment of the present invention, into Note is applied in row configuration, and the flexible ratio of the embodiment of the present invention, easy to operate, and not will produce poisonous and harmful gas in fire extinguishing procedure Body.And the gel of the extinguishing method is now with the current, solves the problems, such as that market ready gels storage time is short.
Specific implementation mode
It in order to make the object, technical scheme and advantages of the embodiment of the invention clearer, below will be in the embodiment of the present invention Technical solution be clearly and completely described.The person that is not specified actual conditions in embodiment, builds according to normal condition or manufacturer The condition of view carries out.Reagents or instruments used without specified manufacturer is the conventional production that can be obtained by commercially available purchase Product.
The extinguishing method of the embodiment of the present invention is specifically described below.
An embodiment of the present invention provides a kind of extinguishing methods, include the following steps:
The blender of coagulant and the 5-15% of blender quality is mixed to get the second mixture, ensures coagulant It for liquid, is uniformly mixed with waterglass class compound convenient for coagulant, then ensures that the two can fully react, promote netted contracting Close the generation of silicic acid.
Meanwhile waterglass class compound, flocculant and the remaining blender are mixed to get the first mixture, waterglass Class compound is uniformly mixed with flocculant and blender, ensures that gel can quickly be formed by generating obtained netted condensation silicic acid, And ensure to be formed the stabilization and consistency of gel.
Then by the second mixture with 1.5-3m3The flow of/s is mixed to get total mixture with first mixture.The Two mixtures with the first mixture mix so that coagulant and waterglass class compound chemically react, and are then contracted The silicic acid of conjunction, netted silicic acid can be adhered to coal mine either other with fire extinguishing matrix surfaces or gap at, then can Air is effectively blocked, reduces the intensity of a fire, prevents to glow.Meanwhile silicic acid and blender act on, and can cure water, then so that solidification Water for putting out a fire, prevent from generating water-gas at high operating temperatures, effective preventing secondary accident.Silicic acid is made with flocculant simultaneously With shortening gelation time promotes silicic acid plastic effect, promotes gel stability, occur after preventing silicic acid to be adhered to matrix surface It falls off or is cracked, extinguishing effect has been effectively ensured.
Further, the flow of the first mixture is 2-3m3/s。
First mixture and the second mixture are mixed using above-mentioned flow, can be further ensured that between raw material and be mixed Uniformly, ensure that the gelling properties to be formed are uniform.
Further, the first mixture is stated to be mixed in a manner of liquidating with second mixture.Using what is liquidated Mode is mixed, and the progress of reaction is can speed up, and ensures that each material mixing is uniform in the first mixture and the second mixture.
Further, the quality of waterglass class compound accounts for the coagulant, the blender, the waterglass class chemical combination The 13-20% of the total mixture quality of object and the flocculant, the coagulant account for the 3-15% of the total mixture quality, institute State the 2-3% that flocculant accounts for the total mixture.Under the conditions of aforementioned proportion, gelation time can be controlled in 30-60 seconds, and gel Material put out a fire after delivery tube flows out, colloid can be formed, and colloid is not susceptible to be cracked, be not easy to fall off, completely cuts off effect It is good.
Further, waterglass class compound accounts for the 17-18% of gel smother quality of materials, and coagulant accounts for gel smother material Expect that the 10-15% of quality, flocculant account for the 2-3% of gel smother quality of materials, surplus is blender.Under the ratio, coagulate Glue fire extinguishing material can form plugging colloid, and gelation time was can be controlled within 60 seconds, and plastic is fast, sticky larger, the glue of colloid Body accumulation molding, is suitable for the filling such as closed, coal column, coal working face corner or larger crack blocks.
Further, waterglass class compound is waterglass or its derivative, is selected as waterglass, cheap, former Material is easy to get.
Further, coagulant is bicarbonate, preferably alkali metal hydrogencarbonate, more preferably sodium bicarbonate.Now For the coagulant used for ammonium hydrogen carbonate, and in actual use, ammonium hydrogen carbonate easy tos produce the gases such as ammonia by high temperature, Then the body of worker in well is impacted.Or the substances such as saleratus used, activity is higher, not easy to store, cannot The gel smother material is prepared in time and quickly, or reduces the performance for the gel smother material being prepared, reduces it Practicability.The embodiment of the present invention uses sodium bicarbonate for coagulant, can not only effectively prevent the destructive stimulus gas such as ammonia The generation of body, and sodium bicarbonate property is stablized, room temperature will not react during storing, and ensure the gel smother material being prepared Material has good colloidal property.
Further, blender is solvent, preferably water.Water provides solid water for gel smother material so that the water can For fire extinguishing, the generation of water-gas is prevented.
Further, flocculant is composite flocculation agent, preferably bodied ferric sulfate or aluminium polychloride.Flocculant can The active force for promoting the combinations of substances such as netted condensation silicic acid and the coal mine of waterglass class compound and coagulant production, promotes solidifying The generation of glue prevents gel from falling off or being cracked.And inorganic polymer ingredient adsorbing contaminant and suspended particulates in composite flocculation agent, Make to form particle and gradually increase, and organic polymer ingredient is by the bridge linking effect of itself, using being adsorbed on organic polymer On active group generate the net effect of catching, net catches other impurity particles and sinks together.Meanwhile the presence of inorganic salts makes pollutant table Surface charge neutralizes, and promotes organic macromolecule flocculation, greatly improves flocculating effect, then shortens gel gelation time, and Ensure the stability of gel.
Further, bodied ferric sulfate and aluminium polychloride are a kind of inorganic polymer flocculant agent of superior performance, A variety of coagulations can be generated to colloidal solid so that condensation silicic acid can generate gel, and gel is prevented to be cracked.
Finally, total mixture is carried out applying note, it is to spray the total mixture to coal mine surface, each gap to apply note And ignition point.Total mixture, which is sprayed to coal mine surface, enables to the gel to be formed to be bonded in the matrix surfaces such as coal mine, prevents Only fire spreading, and air can be completely cut off.Spray is set to can not only completely cut off air at gap, while also being had and being blocked, support The effect of.And spray and set to ignition point, be conducive to and completely cut off air, and the utilization rate of solid water can be promoted.
The feature and performance of the present invention are described in further detail with reference to embodiments.
Embodiment 1
The present embodiment provides a kind of extinguishing methods, include the following steps:
The water of sodium bicarbonate and 5% is uniformly mixed and obtains the second mixture.
Waterglass is uniformly mixed to obtain the first mixture with bodied ferric sulfate and remaining water.
By the first mixing with 2m3The flow of/s and the second mixture are with 1.5m3The volume for volume of/s is mixed to get total mixing Total mixture is then applied note to coal mine surface, at each gap and ignition point by object.
Wherein, waterglass accounts for the 13% of total mixture quality, and sodium bicarbonate accounts for the 3% of total mixture quality, polyaluminum sulfate Iron accounts for the 2% of total mixture quality, and surplus is water.
Embodiment 2
The present embodiment provides a kind of extinguishing methods, include the following steps:
The water of sodium bicarbonate and 10% is uniformly mixed and obtains the second mixture.
Waterglass is uniformly mixed to obtain the first mixture with bodied ferric sulfate and remaining water.
By the first mixing with 2.5m3The flow of/s and the second mixture are with 2m3The volume for volume of/s is mixed to get total mixing Total mixture is then applied note to coal mine surface, at each gap and ignition point by object.
Wherein, waterglass accounts for the 20% of total mixture quality, and sodium bicarbonate accounts for the 15% of total mixture quality, polyaluminum sulfate Iron accounts for the 3% of total mixture quality, and surplus is water.
Embodiment 3
The present embodiment provides a kind of extinguishing methods, include the following steps:
The water of sodium bicarbonate and 15% is uniformly mixed and obtains the second mixture.
Waterglass is uniformly mixed to obtain the first mixture with aluminium polychloride and remaining water.
By the first mixing with 3m3The flow of/s and the second mixture are with 2.5m3The volume for volume of/s is mixed to get total mixing Total mixture is then applied note to coal mine surface, at each gap and ignition point by object.
Wherein, waterglass accounts for the 15% of total mixture quality, and sodium bicarbonate accounts for the 4% of total mixture quality, polyaluminium Aluminium accounts for the 2.5% of total mixture quality, and surplus is water.
Embodiment 4
The present embodiment provides a kind of extinguishing methods, include the following steps:
The water of sodium bicarbonate and 12% is uniformly mixed and obtains the second mixture.
Waterglass is uniformly mixed to obtain the first mixture with aluminium polychloride and remaining water.
By the first mixing with 2.6m3The flow of/s and the second mixture are with 2.8m3The volume for volume of/s is mixed to get total mixing Total mixture is then applied note to coal mine surface, at each gap and ignition point by object.
Wherein, waterglass accounts for the 16% of total mixture quality, and sodium bicarbonate accounts for the 5% of total mixture quality, polyaluminium It is water that aluminium, which accounts for the 2.3% of total mixture its surplus,.
Embodiment 5
The present embodiment provides a kind of extinguishing methods, include the following steps:
The water of sodium bicarbonate and 8% is uniformly mixed and obtains the second mixture.
Waterglass is uniformly mixed to obtain the first mixture with bodied ferric sulfate and remaining water.
By the first mixing with 2.7m3The flow of/s and the second mixture are with 2.2m3The volume for volume of/s is mixed to get total mixing Total mixture is then applied note to coal mine surface, at each gap and ignition point by object.
Wherein, waterglass accounts for the 17% of total mixture quality, and sodium bicarbonate accounts for the 10% of total mixture quality, polyaluminum sulfate Iron accounts for the 2.2% of total mixture quality, and surplus is water.
Embodiment 6
The present embodiment provides a kind of extinguishing methods, include the following steps:
The water of sodium bicarbonate and 13% is uniformly mixed and obtains the second mixture.
Waterglass is uniformly mixed to obtain the first mixture with aluminium polychloride and remaining water.
By the first mixing with 2.7m3The flow of/s and the second mixture are with 2.4m3The volume for volume of/s is mixed to get total mixing Total mixture is then applied note to coal mine surface, at each gap and ignition point by object.
Wherein, waterglass accounts for the 18% of total mixture quality, and sodium bicarbonate accounts for the 14% of total mixture quality, polyaluminium Aluminium accounts for the 2.8% of total mixture quality, and surplus is water.
Comparative example
Comparative example 1:It puts out a fire according to the method for embodiment 1, difference lies in without containing flocculant.
Comparative example 2:It puts out a fire according to the method for embodiment 1, is 1.5% difference lies in the ratio of coagulant.
Comparative example 3:It puts out a fire according to the method for embodiment 1, difference lies in waterglass class compounds to account for 25%, coagulant 20% is accounted for, flocculant accounts for 4%, and surplus is water.
Comparative example 4:It puts out a fire according to the method for embodiment 1, difference lies in coagulant and waterglass class compound to mix It is mixed afterwards with flocculant and blender.
Comparative example 5:It puts out a fire according to the method for embodiment 1, is ammonium hydrogen carbonate difference lies in coagulant.
Experimental example
Embodiment 1-6 and comparative example the 1-4 gelation time of fire-fighting mode used and the resistance rate of colloid are detected, Testing result is referring to table 1.
Colloid viscosity is detected by alternating temperature falling needle viscosimeter, and gel strength is detected by gel strength detector, resistance Rate (%)=(naked coal CO incidences-sample CO incidences)/naked coal CO incidences.
1 testing result of table
According to table 1 it is found that the present invention, which implements increase flocculant, can be obviously improved gel gelation time in fire extinguishing procedure, carry Its viscosity and intensity are risen, gel fire proofing material can be effectively prevent to be cracked, and can guarantee and do not have water precipitation.
To embodiment 1 and comparative example 5 in the confined space of same size using same amount of gel smother material according to Identical extinguishing method is put out a fire, and same time of putting out a fire detects the content of ammonia in confined space, testing result is referring to table 2.
The content of 2 ammonia of table
Ammonia level (ppm)
Embodiment 1 0.009
Comparative example 1 4000
According to table 2 it is found that the content of ammonia can significantly be promoted by replacing coagulant, the health of personnel in well is influenced.
To sum up, extinguishing method of the present invention, by just reacting coagulant and waterglass class compound when needing fire extinguishing To the silicic acid of netted condensation, coal mine surface can be covered or then effectively isolation air, while glue is blocked to gap The silicic acid of shape can cure water so that water can quick extinguishing, prevent the generation of water-gas.Meanwhile passing through silicic acid and flocculant Synergistic effect, promotes the generation of gel and prevents gel from falling off or being cracked, then ensure its extinguishing effect.And by coagulant and Waterglass class compound is separately transported, is stored, and is needed fire extinguishing according to proportioning provided in an embodiment of the present invention, is carried out configuration and apply note, And it is the flexible ratio of the embodiment of the present invention, easy to operate, and not will produce toxic and harmful gas in fire extinguishing procedure.And the fire extinguishing The gel of method is now with the current, solves the problems, such as that market ready gels storage time is short.
It these are only the preferred embodiment of the present invention, be not intended to restrict the invention, for the technology of this field For personnel, the invention may be variously modified and varied.All within the spirits and principles of the present invention, any made by repair Change, equivalent replacement, improvement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of extinguishing method, which is characterized in that include the following steps:Described in coagulant and the 5-15% of blender quality It is applied after being mixed again with the first mixture of waterglass class compound, flocculant and the remaining blender after blender mixing Note.
2. extinguishing method according to claim 1, which is characterized in that the quality of the waterglass class compound accounts for the rush Coagulate the 13-20% of the total mixture quality of agent, the blender, the waterglass class compound and the flocculant, the rush Solidifying agent accounts for the 3-15% of the total mixture quality, and the flocculant accounts for the 2-3% of the total mixture, and surplus is to reconcile Agent.
3. extinguishing method according to claim 2, which is characterized in that the waterglass class compound accounts for the total mixture The 15-16% of quality, the coagulant account for the 4-5% of the total mixture quality, and the flocculant accounts for the total mixture matter The 2-3% of amount, surplus are blender.
4. extinguishing method according to claim 2, which is characterized in that the waterglass class compound accounts for the total mixture The 17-18% of quality, the coagulant account for the 10-15% of the total mixture quality, and the flocculant accounts for the total mixture The 2-3% of quality, surplus are blender.
5. extinguishing method according to claim 2, which is characterized in that the blender of the coagulant and 5-15%, The mixing of first mixture is the second mixture of the blender by the coagulant, 5-15% with 1.5-3m3/s Flow mixed with first mixture.
6. extinguishing method according to claim 5, which is characterized in that first mixture and second mixture Mixing is that first mixture is mixed with second mixture in a manner of liquidating.
7. extinguishing method according to claim 6, which is characterized in that the flow of first mixture is 2-3m3/s。
8. according to claim 2-7 any one of them extinguishing methods, which is characterized in that it is to spray the total mixture to apply note At to coal mine surface, each gap and ignition point.
9. extinguishing method according to claim 8, which is characterized in that the flocculant is composite flocculation agent, preferably poly- Close ferric sulfate or aluminium polychloride.
10. extinguishing method according to claim 8, which is characterized in that the coagulant is bicarbonate, preferably alkali gold Belong to bicarbonate, more preferably sodium bicarbonate.
CN201810146933.XA 2018-02-12 2018-02-12 Extinguishing method Pending CN108343465A (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN110964585A (en) * 2019-12-24 2020-04-07 苏州科镭沃环保科技有限公司 Deoxidation inerting type coal spontaneous combustion inhibitor and preparation method thereof

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CN104803652A (en) * 2015-01-12 2015-07-29 贾博宇 Novel coal mine fireproof leaking-stoppage colloid material
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CN103242023A (en) * 2013-05-16 2013-08-14 北京科技大学 Material of yellow mud added with gel for preventing spontaneous combustion of residual coal
CN104803652A (en) * 2015-01-12 2015-07-29 贾博宇 Novel coal mine fireproof leaking-stoppage colloid material
CN104944893A (en) * 2015-06-12 2015-09-30 北京工业大学 Grouting material capable of improving water retention capacity of water glass composite colloid used in coal mine and preparation method of grouting material

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CN110964585A (en) * 2019-12-24 2020-04-07 苏州科镭沃环保科技有限公司 Deoxidation inerting type coal spontaneous combustion inhibitor and preparation method thereof

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Application publication date: 20180731