CN108342024A - A kind of haloflex general purpose rubber blending fire retardant material with general purpose rubber good bonding - Google Patents
A kind of haloflex general purpose rubber blending fire retardant material with general purpose rubber good bonding Download PDFInfo
- Publication number
- CN108342024A CN108342024A CN201710055900.XA CN201710055900A CN108342024A CN 108342024 A CN108342024 A CN 108342024A CN 201710055900 A CN201710055900 A CN 201710055900A CN 108342024 A CN108342024 A CN 108342024A
- Authority
- CN
- China
- Prior art keywords
- parts
- refers
- mixture
- haloflex
- polydiene
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/26—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment
- C08L23/28—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers modified by chemical after-treatment by reaction with halogens or compounds containing halogen
- C08L23/286—Chlorinated polyethylene
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
Elastic flame material is blended with polydiene for a kind of haloflex, mixer will be put into after haloflex, polydiene, stabilizer, acid absorbent, vulcanizing agent, auxiliary curing agent, reinforcing agent, plasticizer, filler, fire retardant cooperation, turn refining uniform bottom sheet on a mill after dumping, vulcanizes 20 minutes in 151 degrees Celsius on vulcanizing press later.It is characteristic of the invention that, relative to using natural butadiene styrene rubber as the composite material of main material, equal adhesive force, tensile strength, elongation at break, abrasion resistance and good flame retardant property are maintained, weatherability, oil resistivity is improved, reduces production cost.It can be used for flame-retardant conveyer belt coating rubber and tire sidewall.
Description
Technical field
The present invention relates to a kind of chlorinated polyethylene rubbers, and energy is made by main material of haloflex more particularly to one kind
With the rubber compound of dienes general purpose rubber bonding, flame-retardant conveyer belt coating rubber and tire sidewall can be applied to.
Background technology
Haloflex is a kind of good rubber material, it is cheap, ageing-resistant, and flame retardant property is good.It is main at present
Applied to glue inside and outside cable cover(ing), sebific duct.The main reason for not can apply to rubber conveyer belt and tire sidewall is that it cannot
Realize the excellent bonds with framework material (including cloth, line and steel wire) or polydiene.The present invention realizes chlorinated polyethylene
The excellent bonds of alkene blend rubber material and polydiene, and the material high intensity, high elongation at tear and good
Flame retardant property.The present invention is invented with another：It is a kind of that material being blended with the haloflex general purpose rubber of general purpose rubber good bonding
Expect (application number：201611271470.7) based on.
Invention content
The purpose of the present invention is to provide it is a kind of can be with polydiene excellent bonds using haloflex as main material
Blending elastic material and preparation method thereof.Intermingling material provided by the invention, relative to based on natural butadiene styrene rubber
The composite material of material maintains identical adhesive force, tensile strength, elongation at break, abrasion resistance and good resistance
Performance is fired, weatherability, oil resistivity is improved, reduces production cost.
The purpose of the present invention is what is be achieved through the following technical solutions：
Elastic material is blended with polydiene for a kind of haloflex, and the blending elastic material is by following compositions by quality
Part ratio composition：Haloflex, 30 to 80 parts；Polydiene, 20 to 70 parts；Stabilizer, 2 to 10 parts；Acid absorbent, 2 to
14 parts；Stearic acid, 0.5 to 2 part；Zinc oxide, 2 to 10 parts；Filler, 0 to 100 part；Reinforcing agent, 10 to 50 parts；Plasticizer, 10
To 40 parts；Vulcanizing agent A, 2 to 20 parts；Vulcanizing agent B, 2 to 20 parts；Auxiliary curing agent, 1 to 5 part；Coumarone, 0 to 20 part；Nanometer is high
Ridge soil, 0 to 50 part；Fire retardant, 10 to 100 parts；The polydiene refers to natural rubber, butadiene-styrene rubber and butadiene rubber
The mixture of one or more kinds of arbitrary proportions；The stabilizer refers to calcium stearate, zinc stearate, barium stearate, tristearin
Sour cadmium, lead stearate, lead sulfate tribasic, dibasic lead phosphite be a kind of and the mixture of more than one arbitrary proportions；It is described
Acid absorbent refers to, light magnesium oxide, activated magnesia, magnesium hydroxide be a kind of and the mixture of more than one arbitrary proportions；It is described
Reinforcing agent refers to, white carbon, carbon black N220, carbon black N330 and corresponding granularity level other model carbon blacks it is a kind of and more than one
The mixture of arbitrary proportion；The filler refers to, precipitated calcium carbonate, powdered whiting, kaolin, talcum powder or by surface
The modified above component is a kind of and the mixture of more than one arbitrary proportions；The plasticizer refers to, dioctyl phthalate,
Dibutyl phthalate, diisononyl phthalate, dioctyl sebacate, dioctyl adipate, epoxidized vegetable oil, aromatic hydrocarbons
A kind of and more than one arbitrary proportions mixture of oil；The vulcanizing agent A refers to trithiocyanuric acid, sulphur, ethylene thiourea, ammonia
Base zinc formate, zinc dibutyl dithiocaarbamate, DZ (N, N- dicyclohexyl -2,2- bisbenzothiazole sulfenamide) are a kind of
And the mixture of more than one arbitrary proportions；The vulcanizing agent B refers to DTDM (dimorpholinyl disulfide), alkylphenol curing
The mixture of object (VTB-710, Vulta 5) one or more arbitrary proportion；The auxiliary curing agent refers to M (2- mercaptos
Benzothiazole), the mixtures of the one or more kinds of arbitrary proportions of DM (2,2 '-dibenzothiazyl disulfide)；The fire retardant,
Refer to antimony oxide, antimony pentoxide, decabromodiphenyl oxide, octa-BDE, chlorinated paraffin, magnesium hydroxide, aluminium hydroxide with
And the mixture of zinc borate one or more arbitrary proportion.
The preparation method of elastic material is blended with polydiene for a kind of haloflex, and the method includes following steps
Suddenly：
Claim [0004] described material to standard, put into mixer, turns refining through squeezing, dumping when 90 to 110 degrees Celsius.
It will be placed in open mill obtained by [0006], bottom sheet after turning refining uniformly.
By [0007] rubber compound vulcanizing press in 151 degrees Celsius, vulcanize 20 minutes.
It is a feature of the present invention that relative to using natural butadiene styrene rubber as the composite material of main material, maintain equal
Adhesive force, tensile strength, elongation at break, abrasion resistance and good flame retardant property, improve weatherability, oil resistant
Property, reduce production cost.It can be used for conveyer belt coating rubber and tire sidewall.
Specific embodiment
With reference to embodiment, the present invention is expanded on further.
A kind of haloflex is blended elastic material with polydiene, the blending elastic material be by following compositions by
Mass parts ratio forms：Haloflex, 60 parts；Butadiene-styrene rubber, 40 parts；Calcium stearate, 2 parts；Light magnesium oxide, 10 parts；Firmly
Resin acid, 0.5 part；Zinc oxide, 2.5 parts；White carbon, 20 parts；Carbon black N220,30 parts；Dioctyl phthalate, 40 parts；Trimerization
Thiocyanic acid, 1 part；Zinc dibutyl dithiocaarbamate, 0.4 part；Ethylene thiourea, 0.6 part；Alkyl phenol disulfide, 3
Part；M (2- benzothiazolyl mercaptans), 1 part；Coumarone, 20 parts；Nano kaoline, 20 parts.Antimony oxide, 5 parts；Chlorination stone
20 parts of wax；Magnesium hydroxide, 50 parts.Claim above-mentioned material to standard, put into mixer, turns refining through squeezing, arranged when 90 to 110 degrees Celsius
Glue.It is placed in open mill, bottom sheet after turning refining uniformly.It uses vulcanizing press in 151 degrees Celsius later, vulcanizes 20 minutes, detection.
Claims (1)
1. elastic flame material is blended with polydiene for a kind of haloflex, which is characterized in that the blending elastic material
It is made of in mass parts ratio following compositions：Haloflex, 30 to 80 parts；Polydiene, 20 to 70 parts；Stabilizer, 2
To 10 parts；Acid absorbent, 2 to 14 parts；Stearic acid, 0.5 to 2 part；Zinc oxide, 2 to 10 parts；Filler, 0 to 100 part；Reinforcing agent,
10 to 50 parts；Plasticizer, 10 to 40 parts；Vulcanizing agent A, 2 to 20 parts；Vulcanizing agent B, 2 to 20 parts；Auxiliary curing agent, 1 to 5 part；Ancient horse
It is grand, 0 to 20 part；Nano kaoline, 0 to 50 part；Fire retardant, 10 to 100 parts；The polydiene refers to natural rubber, fourth
The mixture of benzene rubber and butadiene rubber one or more arbitrary proportion；The stabilizer refers to calcium stearate, stearic acid
Zinc, barium stearate, cadmium stearate, lead stearate, lead sulfate tribasic, dibasic lead phosphite are a kind of and more than one arbitrarily compare
The mixture of example；The acid absorbent refers to that light magnesium oxide, activated magnesia, magnesium hydroxide are a kind of and more than one arbitrarily compare
The mixture of example；The reinforcing agent refers to, white carbon, carbon black N220, carbon black N330 and corresponding granularity level other model charcoals
Black a kind of and more than one arbitrary proportions mixtures；The filler refers to, precipitated calcium carbonate, powdered whiting, kaolin,
Talcum powder or by surface be modified the above component is a kind of and the mixture of more than one arbitrary proportions；The plasticizer refers to,
Dioctyl phthalate, dibutyl phthalate, diisononyl phthalate, dioctyl sebacate, adipic acid two are pungent
Ester, epoxidized vegetable oil, aromatic naphtha be a kind of and the mixture of more than one arbitrary proportions；The vulcanizing agent A refers to three polysulfide cyanogen
Acid, sulphur, ethylene thiourea, carbaminate, zinc dibutyl dithiocaarbamate, DZ (N, N- dicyclohexyl -2,2- hexichol
And thiazolesulfenamide) a kind of and more than one arbitrary proportions mixtures；The vulcanizing agent B refers to DTDM (curing two
Quinoline), the mixtures of the one or more kinds of arbitrary proportions of alkyl phenol disulfide (VTB-710, Vulta 5)；It is described to help sulphur
Agent refers to the one or more kinds of arbitrary proportions of M (2- benzothiazolyl mercaptans), DM (2,2 '-dibenzothiazyl disulfide)
Mixture；The fire retardant, refer to antimony oxide, antimony pentoxide, decabromodiphenyl oxide, octa-BDE, chlorinated paraffin,
The mixture of magnesium hydroxide, aluminium hydroxide and zinc borate one or more arbitrary proportion.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710055900.XA CN108342024A (en) | 2017-01-21 | 2017-01-21 | A kind of haloflex general purpose rubber blending fire retardant material with general purpose rubber good bonding |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201710055900.XA CN108342024A (en) | 2017-01-21 | 2017-01-21 | A kind of haloflex general purpose rubber blending fire retardant material with general purpose rubber good bonding |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108342024A true CN108342024A (en) | 2018-07-31 |
Family
ID=62963083
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201710055900.XA Pending CN108342024A (en) | 2017-01-21 | 2017-01-21 | A kind of haloflex general purpose rubber blending fire retardant material with general purpose rubber good bonding |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108342024A (en) |
Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111333969A (en) * | 2020-04-30 | 2020-06-26 | 际华三五三九制鞋有限公司 | Flame-retardant, insulating, oil-resistant, acid-and alkali-resistant rubber compound |
| CN113354878A (en) * | 2021-05-25 | 2021-09-07 | 无锡百年通工业输送有限公司 | Flame-retardant ozone-resistant tubular conveyor belt covering rubber and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110315486A1 (en) * | 2009-03-16 | 2011-12-29 | Nok Corporation | Rubber composition |
| CN103772869A (en) * | 2014-01-13 | 2014-05-07 | 四川隆盛科发实业有限公司 | Long-shelf-period acrylate rubber and preparation method thereof |
| CN104072895A (en) * | 2014-06-13 | 2014-10-01 | 安徽先锋门业科技有限公司 | Preparation method of chlorinated polyethylene-butadiene styrene rubber blended waterproof coiled material |
| CN104212084A (en) * | 2014-09-16 | 2014-12-17 | 无锡宝通带业股份有限公司 | Rubber for covering layer of fabric core flame-retarded conveyor belt with CPE as main body and preparation method and application of rubber |
| CN104829880A (en) * | 2015-05-13 | 2015-08-12 | 无锡宝通带业股份有限公司 | Rubber for fabric core laminated flame-retardant conveyor belt covering layer and preparation method thereof |
-
2017
- 2017-01-21 CN CN201710055900.XA patent/CN108342024A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US20110315486A1 (en) * | 2009-03-16 | 2011-12-29 | Nok Corporation | Rubber composition |
| CN103772869A (en) * | 2014-01-13 | 2014-05-07 | 四川隆盛科发实业有限公司 | Long-shelf-period acrylate rubber and preparation method thereof |
| CN104072895A (en) * | 2014-06-13 | 2014-10-01 | 安徽先锋门业科技有限公司 | Preparation method of chlorinated polyethylene-butadiene styrene rubber blended waterproof coiled material |
| CN104212084A (en) * | 2014-09-16 | 2014-12-17 | 无锡宝通带业股份有限公司 | Rubber for covering layer of fabric core flame-retarded conveyor belt with CPE as main body and preparation method and application of rubber |
| CN104829880A (en) * | 2015-05-13 | 2015-08-12 | 无锡宝通带业股份有限公司 | Rubber for fabric core laminated flame-retardant conveyor belt covering layer and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111333969A (en) * | 2020-04-30 | 2020-06-26 | 际华三五三九制鞋有限公司 | Flame-retardant, insulating, oil-resistant, acid-and alkali-resistant rubber compound |
| CN111333969B (en) * | 2020-04-30 | 2022-10-28 | 际华三五三九制鞋有限公司 | Flame-retardant, insulating, oil-resistant, acid-and alkali-resistant rubber compound |
| CN113354878A (en) * | 2021-05-25 | 2021-09-07 | 无锡百年通工业输送有限公司 | Flame-retardant ozone-resistant tubular conveyor belt covering rubber and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| JP5892055B2 (en) | Rubber composition and conveyor belt | |
| CN106543505B (en) | A kind of high-performance acrylonitrile butadiene packing material and preparation method thereof | |
| US2638460A (en) | Butadiene polymers as elastomer additives | |
| CN102459449A (en) | Rubber composition for conveyor belt, and conveyor belt | |
| JP2000001584A (en) | Fire retardant epdm roofing membrane composition for use on high-sloped roof | |
| CN104086839A (en) | High-strength wear-resistant tear-resistant rubber material | |
| CN107151356A (en) | The composition for thermoplastic elastomer being made up of elastomer, non-elastomeric polyolefin and polyolefin block copolymer analog thermoplastic elastomer | |
| CN104086829A (en) | Environment-friendly high-elasticity rubber material | |
| ITMI20000701A1 (en) | RUBBER COMPOSITION PROCEDURE TO PRODUCE THE SAME AND SLEEVE USING THE RUBBER COMPOSITION | |
| KR101502802B1 (en) | Aramid particles containing peroxide radical initiator | |
| CN108342024A (en) | A kind of haloflex general purpose rubber blending fire retardant material with general purpose rubber good bonding | |
| CN104072830A (en) | Wear-resistant anti-aging rubber material | |
| CN104212084A (en) | Rubber for covering layer of fabric core flame-retarded conveyor belt with CPE as main body and preparation method and application of rubber | |
| CN103756223B (en) | High temperature resisting halogen-free flame retardant conveyer belt covering adhesive and preparation method thereof | |
| EP2945985A1 (en) | Cross-linking of carboxylated nitrile rubbers by means of cross-linking systems containing resol | |
| AU2016294056B2 (en) | Rubber composition for flame-retardant hose, and flame-retardant hose | |
| JP7410081B2 (en) | Rubber composition for conveyor belts | |
| CN109554031A (en) | A kind of preparation method of rubber waterproof film | |
| Amin et al. | Comparative study of Bentonite filled acrylonitrile butadiene rubber and carbon black filled NBR composites properties | |
| CN107446160B (en) | Functionalization montmorillonite Reinforced PVC/NBR elastic body sealing strip and preparation method thereof | |
| CN100473687C (en) | Rubber composition for adhesive bonding | |
| CA2144224A1 (en) | Green strength promoters for epdm/epm compositions | |
| CN108239348A (en) | A kind of haloflex general purpose rubber intermingling material with general purpose rubber good bonding | |
| JP6077921B2 (en) | Coated rubber composition for conveyor belt, laminate and conveyor belt | |
| JP2017031381A (en) | Rubber composition for coating fiber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180731 |