CN108342003A - A kind of tasteless reclaimed rubber and its automatic foot-mat of preparation - Google Patents
A kind of tasteless reclaimed rubber and its automatic foot-mat of preparation Download PDFInfo
- Publication number
- CN108342003A CN108342003A CN201810137522.4A CN201810137522A CN108342003A CN 108342003 A CN108342003 A CN 108342003A CN 201810137522 A CN201810137522 A CN 201810137522A CN 108342003 A CN108342003 A CN 108342003A
- Authority
- CN
- China
- Prior art keywords
- rubber
- parts
- tasteless
- reclaimed rubber
- reclaimed
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L17/00—Compositions of reclaimed rubber
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Abstract
The invention discloses a kind of tasteless reclaimed rubber and its automatic foot-mats of preparation, count in parts by weight, include following components, 1 10 parts of natural gum in raw material；0.5 5 parts of butadiene-styrene rubber；20 80 parts of reclaimed rubber；15 30 parts of calcium powder；5 15 parts of rubber powder；0.03 1 parts of rubber accelerator；0.1 2 parts of zinc oxide；0.1 2 parts of stearic acid；0.1 2 parts of sulphur；15 parts of aromatic naphtha.The present invention has the following advantages and effects：Tasteless reclaimed rubber raw material includes reclaimed rubber, natural gum, butadiene-styrene rubber, and reclaimed rubber is reused, and waste old is avoided to pollute environment, and resource utilizes again；Further include sulfated castor oil, tallow base benzyl chloride in raw material, improve the ageing-resistant performance of tasteless reclaimed rubber, has achieved the effect that ageing-resistant, usage time is long, tasteless environmental protection.
Description
Technical field
The present invention relates to rubber product field, more particularly to the automatic foot-mat of a kind of tasteless reclaimed rubber and its preparation.
Background technology
Rubber product refers to the various articles produced as raw material using natural rubber and synthetic rubber, and daily life is provided for people
The indispensable light industrys rubber product such as daily, medical in work, and it is widely used in digging, traffic, building, machinery, electronics
Etc. cushion in industries, such as automotive trim, foot pad and other items, mostly use rubber material etc. and be made.
Reclaimed rubber be leftover bits cured in being produced using rubber product as Raw material processing at, have it is certain plastic
Degree, the rubber that can be reused, reclaimed rubber is always the important raw and processed materials of world rubber industry, on the one hand it can substitute day
T PNR alleviates the serious scarcity of natural rubber, so that waste old is realized recycling, solves waste and old rubber
The problem of glue stain environment.But reclaimed rubber prepare rubber product, the disadvantage of generally existing weatherability difference, as Wang Si it is virtuous
《Chinese tire comprehensive utilization of resources CTRA》" research and development of the high ageing-resistant high-quality reclaimed rubber of hydrocarbon content " middle finger of 12nd phase in 2011
Go out, for reclaimed rubber since hydrocarbon content is low, loss of properties on aging, reclaimed rubber can only be used as packing material application mostly.Due to resistance to
Ageing properties are poor, limit application of the reclaimed rubber in rubber industry.
Invention content
The object of the present invention is to provide a kind of tasteless reclaimed rubber, have the effect of that ageing-resistant performance is good.
The present invention above-mentioned technical purpose technical scheme is that：A kind of tasteless reclaimed rubber, is pressed
Parts by weight meter, interior raw material includes following components, 1-10 parts of natural gum；0.5-5 parts of butadiene-styrene rubber；20-80 parts of reclaimed rubber；Calcium powder
15-30 parts；5-15 parts of rubber powder；0.03-1 parts of rubber accelerator；0.1-2 parts of zinc oxide；0.1-2 parts of stearic acid；Sulphur 0.1-2
Part；1-5 parts of aromatic naphtha.
By using above-mentioned technical proposal, reclaimed rubber, that is, reclaimed rubber is with cured in rubber product production process
Leftover bits be Raw material processing at, with certain plasticity, the rubber that can be reused, reclaimed rubber is 20-80 part, is tasteless
One of key component of reclaimed rubber.Calcium powder is as filler, and for sulphur as vulcanizing agent, stearic acid is vulcanizing activator, aromatic naphtha
It with good rubber compatibility, is distributed in tasteless reclaimed rubber raw material, improves the antioxygenic property of tasteless reclaimed rubber, resists
Weatherability improves the ageing-resistant performance of tasteless reclaimed rubber.
The further setting of the present invention is：It counts in parts by weight, the natural gum is 4-8 parts；The butadiene-styrene rubber is 1-3
Part；The reclaimed rubber is 40-50 parts；The calcium powder is 25-30 parts；The rubber powder is 10-13 parts；The aromatic hydrocarbons is 2-3 parts promising.
The further setting of the present invention is：The reclaimed rubber is butyl renewable rubber, butyronitrile reclaimed rubber, the regeneration rubber of second third
It is one or more in glue, tire reclaimed rubber, footwear reclaim, mechanical goods reclaim, light color reclaim.
By using above-mentioned technical proposal, butyl renewable rubber is using waste butyl rubber as primary raw material, and butyronitrile regenerates rubber
Glue is using useless nitrile rubber as primary raw material, and the third reclaimed rubber of second is using useless EP rubbers as primary raw material；Footwear reclaim
For waste and old instep shoes, cloth cover shoes rubber part, mechanical goods reclaim is that the rubber product mixing based on general purpose rubber etc. is useless
Rubber；Light color reclaim is one kind in universal reclaimed rubber, is non-black raw material.
The further setting of the present invention is：The rubber accelerator is rubber accelerator DM, rubber accelerator M, rubber promote
Into one or more in agent TMTD.
By using above-mentioned technical proposal, rubber accelerator, that is, thiofide, the vulcanization of rubber mainly uses sulphur
Carry out, but sulphur and reacting for rubber be very slow, rubber accelerator can promote vulcanizing agent to activate, to accelerate vulcanizing agent with
The cross-linking reaction of rubber molecule achievees the effect that shorten vulcanization time and reduces curing temperature.Rubber accelerator DM chemical names
For 2,2'- dithio-bis-benzothiazoles.
The further setting of the present invention is：It counts in parts by weight, tasteless reclaimed rubber raw material includes sulfated castor oil 1-
15 parts.
By using above-mentioned technical proposal, aging is a kind of irreversible chemical reaction, is the category of high molecular material itself
Property, table picture shows degenerating, deteriorating for performance.The aging of rubber is raw rubber and vulcanized rubber storage, transport or processing,
During use, due to the comprehensive function and influence by internal and external factor, cause component, the structural damage of rubber, make its by
Step loses original excellent performance, or even loses use value.
The ageing process of rubber includes strand crosslinking and degradation, with the extension of ageing time, degradation process mainly with
Based on random cracking, such as main chain break, side chain break.Sulfated castor oil is made with effect of sulfuric acid by castor oil
, it is dispersed in tasteless reclaimed rubber raw material, the main chain break of rubber molecule, Jin Erqi in tasteless reclaimed rubber can be significantly inhibited
Degradation reaction to during inhibition ageing of rubber, improves the ageing-resistant performance of tasteless reclaimed rubber.Sulfated castor oil can dilute
With covering part rubber smell, the rubber smell of tasteless reclaimed rubber is reduced.
The further setting of the present invention is：It counts in parts by weight, tasteless reclaimed rubber raw material includes tallow base benzyl diformazan
1-10 parts of ammonium chloride.
By using above-mentioned technical proposal, tallow base benzyl chloride is dispersed in tasteless reclaimed rubber raw material,
It can play the role of that rubber cross degree is inhibited to rise, improve the ageing-resistant performance of tasteless reclaimed rubber.
The further setting of the present invention is：It counts in parts by weight, tasteless reclaimed rubber raw material includes that 5-8 parts of succinyls are poly-
Sugar.
By using above-mentioned technical proposal, succinoglycan is dispersed in tasteless reclaimed rubber raw material, can be in ageing process
The middle random cracking for inhibiting rubber, and succinoglycan can enhance sulfated castor oil to the inhibiting effect randomly cracked, the two
Synergistic effect can be played.
The further setting of the present invention is：Score meter by weight, tasteless reclaimed rubber raw material include 1-5 parts of gluconic acids
Zinc.
By using above-mentioned technical proposal, zinc gluconate is dispersed in tasteless reclaimed rubber raw material, inhibits rubber cross
The raising of degree, and chain break on the inside of rubber molecule can be inhibited, improve the ageing-resistant performance of tasteless reclaimed rubber.
It is another object of the present invention to provide a kind of automatic foot-mats, are prepared with tasteless reclaimed rubber.
By using above-mentioned technical proposal, the automatic foot-mat of preparation, ageing-resistant, usage time is long.
In conclusion the invention has the advantages that：Tasteless reclaimed rubber raw material includes reclaimed rubber, natural gum, fourth
Benzene glue, reclaimed rubber is reused, and waste old is avoided to pollute environment, and resource utilizes again；It further include sulphation castor in raw material
Sesame oil, tallow base benzyl chloride, improve the ageing-resistant performance of tasteless reclaimed rubber, when having reached ageing-resistant, having used
Between long, environmentally friendly effect.
Specific implementation mode
Embodiment 1：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is butyl renewable rubber.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
Stearic acid, sulphur are kneaded after five minutes, and aromatic naphtha is added and is kneaded 8 minutes, and last rubber accelerator is kneaded 1 minute.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded, and shaped article is automatic foot-mat.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes.
Embodiment 2：A kind of tasteless reclaimed rubber, difference from example 1 is that, each component and content be such as in raw material
Shown in table 1, rubber accelerator includes 0.2kg rubber accelerator DM, 0.2kg rubber accelerator M, 0.03kg rubber accelerators
TMTD, reclaimed rubber are butyronitrile reclaimed rubber.
Embodiment 3：A kind of tasteless reclaimed rubber, difference from example 1 is that, each component and content be such as in raw material
Shown in table 1, rubber accelerator is rubber accelerator M, and reclaimed rubber is the third reclaimed rubber of second.
Embodiment 4：A kind of tasteless reclaimed rubber, difference from example 1 is that, each component and content be such as in raw material
Shown in table 1, rubber accelerator is rubber accelerator TMTD, and reclaimed rubber is the third reclaimed rubber of second.
Embodiment 5：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is butyl renewable rubber.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
Stearic acid, sulphur are kneaded after five minutes, aromatic naphtha are added, sulfated castor oil is kneaded 8 minutes, last rubber accelerator, mixing 1
Minute.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded, and shaped article is automatic foot-mat.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes.
Embodiment 6：A kind of tasteless reclaimed rubber, difference lies in each component and content such as tables 1 in raw material with embodiment 5
Shown, wherein reclaimed rubber is tire reclaimed rubber.
Embodiment 7：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is butyl renewable rubber.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
Stearic acid, sulphur are kneaded after five minutes, aromatic naphtha are added, tallow base benzyl chloride is kneaded 8 minutes, last rubber rush
Into agent, it is kneaded 1 minute.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded, and shaped article is automatic foot-mat.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes
Embodiment 8：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is footwear reclaim.
The preparation process of tasteless reclaimed rubber：One, dispensing is kneaded bowl temperature and is controlled always using open kneading machine
At 50-60 DEG C, kneading machine roll spacing is adjusted to 8mm, natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide, tristearin is added
Acid, sulphur be kneaded after five minutes, be added aromatic naphtha, sulfated castor oil, tallow base benzyl chloride be kneaded 8 minutes, most
Rubber accelerator afterwards is kneaded 1 minute.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded, and shaped article is automatic foot-mat.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 20 minutes.
Embodiment 9：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is butyl renewable rubber.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
Stearic acid, sulphur are kneaded after five minutes, aromatic naphtha are added, succinoglycan is kneaded 8 minutes, last rubber accelerator, 1 point of mixing
Clock.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes.
Embodiment 10：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is mechanical goods reclaim.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
Stearic acid, sulphur are kneaded after five minutes, and aromatic naphtha, sulfated castor oil, tallow base benzyl chloride, succinyl is added
Glycan is kneaded 8 minutes, last rubber accelerator, is kneaded 1 minute.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes.
Embodiment 11：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is butyl renewable rubber.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
Stearic acid, sulphur are kneaded after five minutes, aromatic naphtha are added, zinc gluconate is kneaded 8 minutes, last rubber accelerator, 1 point of mixing
Clock.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded, and shaped article is automatic foot-mat.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes.
Embodiment 12：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is light color reclaim.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
Stearic acid, sulphur are kneaded after five minutes, and aromatic naphtha, sulfated castor oil, tallow base benzyl chloride, succinyl is added
Glycan, zinc gluconate are kneaded 8 minutes, and last rubber accelerator is kneaded 1 minute.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded, and shaped article is automatic foot-mat.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes.
Comparative example 1：A kind of tasteless reclaimed rubber, each component and content are as shown in table 1 in raw material, the list of each component in table 1
Position is kg.Wherein rubber accelerator is rubber accelerator DM, and reclaimed rubber is butyl renewable rubber.
The preparation process of tasteless reclaimed rubber：Step 1, dispensing are kneaded bowl temperature always using open kneading machine
Control adjusts kneading machine roll spacing to 8mm at 50-60 DEG C, be added natural gum, butadiene-styrene rubber, reclaimed rubber, calcium powder, rubber powder, zinc oxide,
After stearic acid, sulphur are kneaded 13 minutes, last rubber accelerator is kneaded 1 minute.
Secondly, adjustment kneading machine roll spacing is thin 5 times logical to 1.5mm；
Finally, adjustment kneading machine roll spacing is to 8m, bottom sheet after fiddling with uniformly, cooling 5h.
Step 2, molding, the shape needed for product are molded.
Step 3, sulfuration process carry out vulcanizing treatment using vulcanizing press to sheet stock.Wherein, temperature control is in 150-
180 DEG C, pressure is controlled in 18-25MPa, and time control was at 25 minutes.
Table 1
Degradation：It is tested with reference to GB/T18173.1-2000, aging condition is 80 DEG C × 168h, and 16h is placed after taking-up,
Carry out Mechanics Performance Testing, change rate=[performance before (performance before aged properties-aging)/aging] × 100%.Experiment is tied
Fruit is listed in table 2.
Table 2
By the result of degradation in table 2 it is found that sulfated castor oil, tallow base benzyl chloride, succinyl
Glycan, zinc gluconate can be obviously improved the ageing-resistant performance of tasteless reclaimed rubber.
Specific embodiment is only explanation of the invention, is not limitation of the present invention, those skilled in the art
The modification that not creative contribution can be made to the present embodiment as needed after reading this specification, but as long as in this hair
It is all protected by Patent Law in bright right.
Claims (9)
- Include following components in raw material 1. a kind of tasteless reclaimed rubber, is counted in parts by weight,
- 2. a kind of tasteless reclaimed rubber according to claim 1, it is characterised in that：It counts in parts by weight, the natural gum It is 4-8 parts；The butadiene-styrene rubber is 1-3 parts；The reclaimed rubber is 40-50 parts；The calcium powder is 25-30 parts；The rubber powder is 10- 13 parts；The aromatic hydrocarbons is 2-3 parts promising.
- 3. a kind of tasteless reclaimed rubber according to claim 1, it is characterised in that：The reclaimed rubber is that butyl regenerates rubber Glue, butyronitrile reclaimed rubber, the third reclaimed rubber of second, tire reclaimed rubber, footwear reclaim, mechanical goods reclaim, light color regeneration It is one or more in rubber.
- 4. a kind of tasteless reclaimed rubber according to claim 1, it is characterised in that：The rubber accelerator promotes for rubber It is one or more in agent DM, rubber accelerator M, rubber accelerator TMTD.
- 5. a kind of tasteless reclaimed rubber according to claim 1, it is characterised in that：It counts in parts by weight, tasteless regeneration rubber Collagen material includes 1-15 parts of sulfated castor oil.
- 6. a kind of tasteless reclaimed rubber according to claim 1, it is characterised in that：It counts in parts by weight, tasteless regeneration rubber Collagen material includes 1-10 parts of tallow base benzyl chloride.
- 7. a kind of tasteless reclaimed rubber according to claim 1, it is characterised in that：It counts in parts by weight, tasteless regeneration rubber Collagen material includes 5-8 parts of succinoglycans.
- 8. a kind of tasteless reclaimed rubber according to claim 1, it is characterised in that：Score meter by weight, tasteless regeneration rubber Collagen material includes 1-5 parts of zinc gluconates.
- 9. a kind of automatic foot-mat, it is characterised in that：It is prepared with tasteless reclaimed rubber described in claim 1.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810137522.4A CN108342003A (en) | 2018-02-10 | 2018-02-10 | A kind of tasteless reclaimed rubber and its automatic foot-mat of preparation |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810137522.4A CN108342003A (en) | 2018-02-10 | 2018-02-10 | A kind of tasteless reclaimed rubber and its automatic foot-mat of preparation |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108342003A true CN108342003A (en) | 2018-07-31 |
Family
ID=62958713
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810137522.4A Pending CN108342003A (en) | 2018-02-10 | 2018-02-10 | A kind of tasteless reclaimed rubber and its automatic foot-mat of preparation |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108342003A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112250927A (en) * | 2020-10-10 | 2021-01-22 | 浙江鸿盛原汽车用品有限公司 | Odorless regenerated rubber and automobile foot pad prepared from same |
| WO2022269194A1 (en) * | 2021-06-23 | 2022-12-29 | Compagnie Generale Des Etablissements Michelin | Inner sealing layer for a tyre against the proliferation of mosquitoes |
| CN116120647A (en) * | 2022-12-26 | 2023-05-16 | 宣城博源橡塑有限公司 | Rubber compound directly produced from desulfurized waste tire rubber powder and production process thereof |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1246900A (en) * | 1997-02-05 | 2000-03-08 | 阿克佐诺贝尔公司 | Aqueous dispersions of hydrophobic material |
| CN102304066A (en) * | 2011-05-31 | 2012-01-04 | 华南理工大学 | Method for preparing sulphated castor oil |
| CN103881164A (en) * | 2014-04-14 | 2014-06-25 | 柳州市颖航汽配有限公司 | Automotive rubber material and production method thereof |
-
2018
- 2018-02-10 CN CN201810137522.4A patent/CN108342003A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1246900A (en) * | 1997-02-05 | 2000-03-08 | 阿克佐诺贝尔公司 | Aqueous dispersions of hydrophobic material |
| CN102304066A (en) * | 2011-05-31 | 2012-01-04 | 华南理工大学 | Method for preparing sulphated castor oil |
| CN103881164A (en) * | 2014-04-14 | 2014-06-25 | 柳州市颖航汽配有限公司 | Automotive rubber material and production method thereof |
Non-Patent Citations (1)
| Title |
|---|
| 李永河: "《橡胶硫化技术》", 31 May 2012, 黄河水利出版社 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN112250927A (en) * | 2020-10-10 | 2021-01-22 | 浙江鸿盛原汽车用品有限公司 | Odorless regenerated rubber and automobile foot pad prepared from same |
| WO2022269194A1 (en) * | 2021-06-23 | 2022-12-29 | Compagnie Generale Des Etablissements Michelin | Inner sealing layer for a tyre against the proliferation of mosquitoes |
| FR3124518A1 (en) * | 2021-06-23 | 2022-12-30 | Compagnie Generale Des Etablissements Michelin | Inner waterproof layer for tires against the proliferation of mosquitoes |
| CN116120647A (en) * | 2022-12-26 | 2023-05-16 | 宣城博源橡塑有限公司 | Rubber compound directly produced from desulfurized waste tire rubber powder and production process thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108342003A (en) | A kind of tasteless reclaimed rubber and its automatic foot-mat of preparation | |
| CN109181041A (en) | A kind of ultralight rubber plastic sole material and preparation method thereof | |
| CN101481473A (en) | Rubber composition and product thereof | |
| CN102977428B (en) | Method for preparing blend composite material by virtue of performing blending modification on kaolin/white carbon black | |
| CN108440807B (en) | Sole material and preparation method thereof | |
| CN107722390A (en) | A kind of formula and preparation method of inexpensive tire tread glue | |
| CN104231372B (en) | Extend the Motorcycle tire side sizing material in mold cleaning cycle and preparation method thereof | |
| RU2018112717A (en) | ELASTOMER COMPOSITIONS FOR TIRES COMPONENTS AND CONTAINING THEIR TIRES | |
| US4101463A (en) | Molded composition and article molded therefrom | |
| CN107337846A (en) | A kind of rubber-plastic foamed sole composition, rubber-plastic foamed sole and its manufacture method | |
| US10435541B2 (en) | Rubber mixture and vehicle tires | |
| CN100572431C (en) | A kind of method of improving rubber air tightness | |
| CN113773565A (en) | Sulfur-free vulcanized carboxylic nitrile latex and vulcanization method and application thereof | |
| CN107108967A (en) | Rubber composition, tread member, the manufacture method of pneumatic tire and rubber composition | |
| CN115960401B (en) | Preparation method of high-strength anti-slip butyronitrile foaming glove without surface treatment | |
| EP2289985A1 (en) | Preparation of silica-containing epdm rubber composition and use thereof for articles of manufacture including tires and engineered products | |
| CN110023355B (en) | Method for producing conjugated diene copolymer, conjugated diene copolymer produced thereby, and rubber composition containing same | |
| CN1266866A (en) | Curing of butyl rubber | |
| JPS6172505A (en) | Molding and vulcanizing process of rubber product | |
| CN102898689A (en) | Ultra-soft rubber for sole and preparation method thereof | |
| US7338998B2 (en) | Cement for modification of rubber articles and process for production thereof | |
| JPH10316766A (en) | Production of rubber material | |
| KR100375042B1 (en) | Manufacturing method of cure bladder | |
| CN115010828B (en) | Preparation method and application of stretching-induced crystallization self-reinforced gutta percha vulcanized rubber | |
| JP5853729B2 (en) | Rubber composition |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20180731 |
|
| RJ01 | Rejection of invention patent application after publication |