CN108339556A - A kind of preparation method of alkali formula stannous chloride amorphous catalysis material - Google Patents
A kind of preparation method of alkali formula stannous chloride amorphous catalysis material Download PDFInfo
- Publication number
- CN108339556A CN108339556A CN201810103051.5A CN201810103051A CN108339556A CN 108339556 A CN108339556 A CN 108339556A CN 201810103051 A CN201810103051 A CN 201810103051A CN 108339556 A CN108339556 A CN 108339556A
- Authority
- CN
- China
- Prior art keywords
- catalysis material
- alkali formula
- stannous chloride
- preparation
- amorphous
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
- 239000000463 material Substances 0.000 title claims abstract description 32
- 235000011150 stannous chloride Nutrition 0.000 title claims abstract description 31
- 238000006555 catalytic reaction Methods 0.000 title claims abstract description 21
- 239000003513 alkali Substances 0.000 title claims abstract description 20
- TXUICONDJPYNPY-UHFFFAOYSA-N (1,10,13-trimethyl-3-oxo-4,5,6,7,8,9,11,12,14,15,16,17-dodecahydrocyclopenta[a]phenanthren-17-yl) heptanoate Chemical compound C1CC2CC(=O)C=C(C)C2(C)C2C1C1CCC(OC(=O)CCCCCC)C1(C)CC2 TXUICONDJPYNPY-UHFFFAOYSA-N 0.000 title claims abstract description 19
- 229910021626 Tin(II) chloride Inorganic materials 0.000 title claims abstract description 19
- 239000001119 stannous chloride Substances 0.000 title claims abstract description 19
- 238000002360 preparation method Methods 0.000 title claims abstract description 10
- 238000003756 stirring Methods 0.000 claims abstract description 15
- 239000003643 water by type Substances 0.000 claims abstract description 11
- 238000001291 vacuum drying Methods 0.000 claims abstract description 8
- 238000001556 precipitation Methods 0.000 claims abstract description 6
- 230000015572 biosynthetic process Effects 0.000 abstract description 4
- 238000003786 synthesis reaction Methods 0.000 abstract description 4
- 238000006243 chemical reaction Methods 0.000 abstract description 2
- 230000000694 effects Effects 0.000 abstract description 2
- 239000002957 persistent organic pollutant Substances 0.000 abstract description 2
- 230000015556 catabolic process Effects 0.000 description 11
- 238000006731 degradation reaction Methods 0.000 description 11
- 230000001699 photocatalysis Effects 0.000 description 7
- 238000007146 photocatalysis Methods 0.000 description 7
- 238000005516 engineering process Methods 0.000 description 5
- PYWVYCXTNDRMGF-UHFFFAOYSA-N rhodamine B Chemical compound [Cl-].C=12C=CC(=[N+](CC)CC)C=C2OC2=CC(N(CC)CC)=CC=C2C=1C1=CC=CC=C1C(O)=O PYWVYCXTNDRMGF-UHFFFAOYSA-N 0.000 description 4
- 229940043267 rhodamine b Drugs 0.000 description 4
- 238000003760 magnetic stirring Methods 0.000 description 3
- 238000005119 centrifugation Methods 0.000 description 2
- 238000003912 environmental pollution Methods 0.000 description 2
- QSHDDOUJBYECFT-UHFFFAOYSA-N mercury Chemical compound [Hg] QSHDDOUJBYECFT-UHFFFAOYSA-N 0.000 description 2
- 229910052753 mercury Inorganic materials 0.000 description 2
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 description 1
- 239000004215 Carbon black (E152) Substances 0.000 description 1
- 241000790917 Dioxys <bee> Species 0.000 description 1
- 238000010521 absorption reaction Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 238000005660 chlorination reaction Methods 0.000 description 1
- 239000002178 crystalline material Substances 0.000 description 1
- 238000010586 diagram Methods 0.000 description 1
- 239000000975 dye Substances 0.000 description 1
- 239000003344 environmental pollutant Substances 0.000 description 1
- 229930195733 hydrocarbon Natural products 0.000 description 1
- 150000002430 hydrocarbons Chemical class 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 230000003287 optical effect Effects 0.000 description 1
- 230000029553 photosynthesis Effects 0.000 description 1
- 238000010672 photosynthesis Methods 0.000 description 1
- 231100000719 pollutant Toxicity 0.000 description 1
- 239000000843 powder Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J27/00—Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
- B01J27/06—Halogens; Compounds thereof
- B01J27/135—Halogens; Compounds thereof with titanium, zirconium, hafnium, germanium, tin or lead
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2101/00—Nature of the contaminant
- C02F2101/30—Organic compounds
- C02F2101/308—Dyes; Colorants; Fluorescent agents
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Organic Chemistry (AREA)
- Materials Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Health & Medical Sciences (AREA)
- Toxicology (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Organic Low-Molecular-Weight Compounds And Preparation Thereof (AREA)
Abstract
The invention discloses a kind of preparation method of alkali formula stannous chloride amorphous catalysis material, the specific steps are：2.2554 4.5108g, bis- hydrated stannous chlorides are dissolved in 5 10mL deionized waters, stirring 15min is completely dissolved to two hydrated stannous chlorides, then mixed liquor is added in 100mL deionized waters, stirring 15min, which is centrifuged, to be precipitated, and is rinsed to solution taking-up precipitation vacuum drying after being in neutrality repeatedly and is obtained alkali formula stannous chloride amorphous catalysis material.Preparation process of the present invention is simple and practicable, and synthesis cycle is relatively short, and alkali formula stannous chloride amorphous catalysis material obtained shows higher activity in degradable organic pollutant reaction, is had potential application in field of photovoltaic materials.
Description
Technical field
The invention belongs to the synthesis technical fields of photoelectric material, and in particular to a kind of alkali formula stannous chloride amorphous photocatalysis material
The preparation method of material.
Background technology
The energy shortage faced within the scope of Present Global and problem of environmental pollution are increasingly serious.Solar energy be green, can be again
The Typical Representative of raw new energy, above-mentioned two large problems can be alleviated or solve from the root cause by efficiently utilizing.In Solar use
In form, photocatalysis technology belongs to typical manual simulation's photosynthesis, it can not only decompose water and generate hydrogen, restores dioxy
Change carbon and produce hydrocarbon dyestuff, can also degrade each pollutant, therefore can solve energy shortage and problem of environmental pollution simultaneously.
So developing one of the hot spot that new and effective catalysis material is photocatalysis technology area research.
Invention content
The alkali formula chlorination simple and relatively short the period the technical problem to be solved by the present invention is to provide a kind of synthesis technology
The preparation method of stannous amorphous catalysis material.
The present invention adopts the following technical scheme that solve above-mentioned technical problem, a kind of alkali formula stannous chloride amorphous photocatalysis material
The preparation method of material, it is characterised in that the specific steps are：Bis- hydrated stannous chlorides of 2.2554-4.5108g are dissolved in 5-10mL
In ionized water, stirring 15min to two hydrated stannous chlorides is completely dissolved, and then mixed liquor is added in 100mL deionized waters, stirs
It mixes 15min and centrifuges and precipitated, rinse repeatedly to solution after being in neutrality and take out precipitation vacuum drying to obtain alkali formula stannous chloride non-
Brilliant catalysis material.
Further preferably, the vacuum drying condition is 60 DEG C of dry 180min or more.
Preparation process of the present invention is simple and practicable, and synthesis cycle is relatively short, alkali formula stannous chloride amorphous photocatalysis obtained
Material shows higher activity in degradable organic pollutant reaction, is had potential application in field of photovoltaic materials.
Description of the drawings
Fig. 1 is the XRD diagram of alkali formula stannous chloride amorphous catalysis material made from embodiment 1；
Fig. 2 is the abosrption spectrogram of alkali formula stannous chloride amorphous catalysis material made from embodiment 1；
Fig. 3 is the photocatalytic degradation Luo Dan under 300W mercury lamps of alkali formula stannous chloride amorphous catalysis material made from embodiment 1
Bright B concentration changes with time curve；
Fig. 4 is the photocatalytic degradation Luo Dan under 300W mercury lamps of alkali formula stannous chloride amorphous catalysis material made from embodiment 1
The degradation curve of bright B.
Specific implementation mode
The above of the present invention is described in further details by the following examples, but this should not be interpreted as to this
The range for inventing above-mentioned theme is only limitted to embodiment below, and all technologies realized based on the above of the present invention belong to this hair
Bright range.
Embodiment 1
Bis- hydrated stannous chlorides of 2.2554g are dissolved in 5mL deionized waters, in fast with the stirring of 400n/min on magnetic stirring apparatus
Rate stirs 15min and is completely dissolved to two hydrated stannous chlorides, and then mixed liquor is added in 100mL deionized waters, stirs 15min
Centrifugation is precipitated, and is rinsed to solution taking-up precipitation vacuum drying after being in neutrality repeatedly and is obtained alkali formula stannous chloride amorphous photocatalysis
Material.
As shown in Figure 1, obtained catalysis material is non-crystalline material；As shown in Fig. 2, being obtained according to powder abosrption spectrogram
Go out dusty material ABSORPTION EDGE probably in 342nm, corresponding optical band gap is about 3.63eV；As shown in figure 3, gained catalysis material
The rhodamine B degradation under 300W Hg lamp irradiations, 45min degradation rates are about 88%, are almost weighed in the degradation curve of 60min and 75min
It closes, and its degradation rate is about 97%；As shown in figure 4, gained catalysis material rhodamine B degradation under 300W Hg lamp irradiations,
45min degradation rates are 88%, have just been degraded completely in 60min.
Embodiment 2
Bis- hydrated stannous chlorides of 2.2554g are dissolved in 10mL deionized waters, on magnetic stirring apparatus with the stirring of 400n/min
Rate stirs 15min and is completely dissolved to two hydrated stannous chlorides, and then mixed liquor is added in 100mL deionized waters, stirring
15min, which is centrifuged, to be precipitated, and is rinsed to solution taking-up precipitation vacuum drying after being in neutrality repeatedly and is obtained alkali formula stannous chloride amorphous
Catalysis material.Gained catalysis material rhodamine B degradation under 300W Hg lamp irradiations is 85% in 45min degradation rates.
Embodiment 3
Bis- hydrated stannous chlorides of 4.5108g are dissolved in 5mL deionized waters, in fast with the stirring of 400n/min on magnetic stirring apparatus
Rate stirs 15min and is completely dissolved to two hydrated stannous chlorides, and then mixed liquor is added in 100mL deionized waters, stirs 15min
Centrifugation is precipitated, and is rinsed to solution taking-up precipitation vacuum drying after being in neutrality repeatedly and is obtained alkali formula stannous chloride amorphous photocatalysis
Material.Gained catalysis material rhodamine B degradation under 300W Hg lamp irradiations is 80% in 45min degradation rates.
Embodiment above describes the basic principles and main features and advantage of the present invention, and the technical staff of the industry should
Understand, the present invention is not limited to the above embodiments, and the above embodiments and description only describe the originals of the present invention
Reason, under the range for not departing from the principle of the invention, various changes and improvements may be made to the invention, these changes and improvements are each fallen within
In the scope of protection of the invention.
Claims (2)
1. a kind of preparation method of alkali formula stannous chloride amorphous catalysis material, it is characterised in that the specific steps are：By 2.2554-
Bis- hydrated stannous chlorides of 4.5108g are dissolved in 5-10mL deionized waters, and stirring 15min to two hydrated stannous chlorides is completely dissolved,
Then mixed liquor is added in 100mL deionized waters, stirring 15min, which is centrifuged, to be precipitated, and is rinsed repeatedly to solution after being in neutrality
It takes out precipitation vacuum drying and obtains alkali formula stannous chloride amorphous catalysis material.
2. the preparation method of alkali formula stannous chloride amorphous catalysis material according to claim 1, it is characterised in that：It is described
Vacuum drying condition is 60 DEG C of dry 180min or more.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810103051.5A CN108339556A (en) | 2018-02-01 | 2018-02-01 | A kind of preparation method of alkali formula stannous chloride amorphous catalysis material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810103051.5A CN108339556A (en) | 2018-02-01 | 2018-02-01 | A kind of preparation method of alkali formula stannous chloride amorphous catalysis material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108339556A true CN108339556A (en) | 2018-07-31 |
Family
ID=62958439
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810103051.5A Withdrawn CN108339556A (en) | 2018-02-01 | 2018-02-01 | A kind of preparation method of alkali formula stannous chloride amorphous catalysis material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108339556A (en) |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005014885A1 (en) * | 2003-07-28 | 2005-02-17 | De Nora Elettrodi S.P.A. | Electrode for electrochemical processes and method for producing the same |
| CN101428847A (en) * | 2008-12-15 | 2009-05-13 | 吉林大学 | Process for producing nanostructured tin dioxide lithium ion battery negative pole material |
| CN104122304A (en) * | 2014-07-22 | 2014-10-29 | 苏州能斯达电子科技有限公司 | Preparation method of sensor based on stannic oxide functionalized graphene |
| CN104815654A (en) * | 2015-04-09 | 2015-08-05 | 湖北文理学院 | Visible light nano composite photocatalysis material and preparation method thereof |
-
2018
- 2018-02-01 CN CN201810103051.5A patent/CN108339556A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2005014885A1 (en) * | 2003-07-28 | 2005-02-17 | De Nora Elettrodi S.P.A. | Electrode for electrochemical processes and method for producing the same |
| CN101428847A (en) * | 2008-12-15 | 2009-05-13 | 吉林大学 | Process for producing nanostructured tin dioxide lithium ion battery negative pole material |
| CN104122304A (en) * | 2014-07-22 | 2014-10-29 | 苏州能斯达电子科技有限公司 | Preparation method of sensor based on stannic oxide functionalized graphene |
| CN104815654A (en) * | 2015-04-09 | 2015-08-05 | 湖北文理学院 | Visible light nano composite photocatalysis material and preparation method thereof |
Non-Patent Citations (4)
| Title |
|---|
| 浙江大学普通化学教研组编: "《普通化学》", 30 September 1999, 高等教育出版社 * |
| 潘祖亭等: "《分析化学》", 31 August 2011, 华中科技大学出版社 * |
| 肖佳阳: ""简便合成几种铋、锡化合物及在光电化学和染料去除中的应用"", 《中国优秀硕士学位论文全文数据库 工程科技Ⅰ辑》 * |
| 薛玉泉等: "《化纤原料与化工手册》", 31 July 1983, 纺织工业出版社 * |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| Tian et al. | 0D/3D coupling of g-C3N4 QDs/hierarchical macro-mesoporous CuO-SiO2 for high-efficiency norfloxacin removal in photo-Fenton-like processes | |
| CN103551201B (en) | A kind of preparation method of copper hydroxyphosphate catalyst | |
| CN108147462A (en) | A kind of tungsten trioxide nano-rod and its preparation with photocatalysis performance | |
| CN101722013A (en) | Method for preparing photocatalyst for sensitization of TiO2 nanotubes by semiconductor quantum dots | |
| CN102068979A (en) | Method for degrading methyl orange dye wastewater with ZnIn2S4 visible light catalyst | |
| CN106944074B (en) | A kind of visible-light response type composite photo-catalyst and its preparation method and application | |
| CN102716758B (en) | Composite visible-light-driven photocatalyst Ag3PO4 and Zn3(PO4)2 and preparation method thereof | |
| CN108686649A (en) | A kind of Mn based on absorbent cotton biomorph3O4/ ZnO/ACFs micro motors photochemical catalyst and its application | |
| CN104001496A (en) | BiVO4 nanosheet composite photocatalyst, and preparation method and application thereof | |
| CN108786895B (en) | BiOCOOH/g-C3N4Composite photocatalyst and preparation method and application thereof | |
| CN106268869A (en) | A kind of preparation method and application of carbon quantum dot/flower-shaped indium sulfide calcium composite photo-catalyst | |
| CN106944043A (en) | A kind of micro-nano hetero-junctions visible light composite photocatalyst and its preparation method and application | |
| CN109675547A (en) | A kind of preparation method and applications of hollow cube type zinc stannate photochemical catalyst | |
| CN105080553A (en) | Method for preparing stanniferous double-perovskite type phenol photocatalytic degradation catalyst | |
| CN105688937B (en) | A kind of preparation method of titanium dioxide-graphene-sulfur cadmium composite material | |
| CN114130410A (en) | Bismuth iron titanium oxyhalide photocatalytic material and preparation method and application thereof | |
| CN110540243B (en) | Preparation method of amorphous iron oxyhydroxide and recovery method after organic matter adsorption | |
| CN103721713A (en) | Three-phase composite visible-light-driven photocatalyst capable of efficiently degrading dyes | |
| CN103506104B (en) | Carbon-doped TiO2 visible light-responding catalytic film on glass carrier and preparation method thereof | |
| CN103212405B (en) | Cadmium-doped bismuth molybdate visible-light-induced photocatalyst and preparation method and application of cadmium-doped bismuth molybdate visible-light-induced photocatalyst | |
| CN108339556A (en) | A kind of preparation method of alkali formula stannous chloride amorphous catalysis material | |
| CN104971746A (en) | Doped quantum dot-loading reduced graphene oxide photocatalyst and application thereof | |
| CN103920510A (en) | Preparation method and application of photocatalyst Mn-BiOCl | |
| CN107774291B (en) | Preparation method of spherical nitrogen-doped zinc sulfide photocatalyst for efficiently degrading metronidazole wastewater | |
| CN110143640A (en) | A kind of method of butyl xanthate in photocatalytic oxidation degradation beneficiation wastewater of sulphide ore |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180731 |