CN108335799A - It is a kind of to utilize electrified wire made of phosphor material powder - Google Patents
It is a kind of to utilize electrified wire made of phosphor material powder Download PDFInfo
- Publication number
- CN108335799A CN108335799A CN201810343962.5A CN201810343962A CN108335799A CN 108335799 A CN108335799 A CN 108335799A CN 201810343962 A CN201810343962 A CN 201810343962A CN 108335799 A CN108335799 A CN 108335799A
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- Prior art keywords
- doped
- powder
- indium
- blue
- phosphor
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Classifications
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/36—Insulated conductors or cables characterised by their form with distinguishing or length marks
- H01B7/361—Insulated conductors or cables characterised by their form with distinguishing or length marks being the colour of the insulation or conductor
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/88—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing selenium, tellurium or unspecified chalcogen elements
- C09K11/881—Chalcogenides
- C09K11/883—Chalcogenides with zinc or cadmium
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09K—MATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
- C09K11/00—Luminescent, e.g. electroluminescent, chemiluminescent materials
- C09K11/08—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials
- C09K11/88—Luminescent, e.g. electroluminescent, chemiluminescent materials containing inorganic luminescent materials containing selenium, tellurium or unspecified chalcogen elements
- C09K11/881—Chalcogenides
- C09K11/886—Chalcogenides with rare earth metals
Abstract
Electrified wire made of phosphor material powder is utilized the invention discloses a kind of, the electrified wire includes at least a blue-fluorescence powder, a red fluorescence powder and a Green phosphor, while the electrified wire further includes the silicon dioxide gel mutually stirred and evenly mixed with blue-fluorescence powder, red fluorescence powder and Green phosphor and leads core for conductive；Using the fluorescent powder of multigroup different colours, the dicoration and associativity of conducting wire can be enhanced；While ensureing that conducting wire is powered, it is noted that the resolution of conducting wire can be used in dark surrounds；The use scope of conducting wire is wide.
Description
Technical field
It is specially a kind of to be led using being powered made of phosphor material powder the present invention relates to fluorescent crystal correlative technology field
Line.
Background technology
Fluorescent material is by metal（Zinc, chromium）Sulfide or rare earth oxide coordinate with trace active agent through calcining.
Colourless or shallow white is under ultraviolet light (200~400nm) irradiation, not according to metal in pigment and activator species, content
Together, the visible light (400~800nm) of a variety of colors is showed.
With the progress of science and technology, people are more and more to the research of fluorescence, and the application range of fluorescent material is increasingly
Extensively.Fluorescent material in addition to as dyestuff, also organic pigment, Optical Bleaching Agent, photooxidant, coating, chemistry and biochemical analysis,
The fields such as solar energy trap, anti-fake mark, pharmaceutical indications and laser have obtained wider application, and fluorescent material is using
In the process, it is typically fabricated as fluorescent powder cooperation other materials to be used in mixed way, utilizes the photism of fluorescent powder itself, Ke Yizuo
For a kind of new type light source.
Therefore, using the reflective characteristic of fluorescent material, there can be many application fields, in traditional conducting wire field, conducting wire
It has no him other than being used to be powered to use, phosphor material powder and wire bonding are produced new conducting wire by the present invention, can be used for
The conductive numerous areas being satisfied by of decoration, present invention proposition is a kind of thus utilizes electrified wire made of phosphor material powder.
Invention content
The purpose of the present invention is to provide a kind of using electrified wire made of phosphor material powder, to solve in background technology
The problem of proposition.
It is a kind of using electrified wire made of phosphor material powder to realize that purpose, the present invention provide the following technical solutions, it should
Electrified wire includes at least a blue-fluorescence powder, a red fluorescence powder and a Green phosphor, while this is logical
Electric lead further includes that the silica that is mutually stirred and evenly mixed with blue-fluorescence powder, red fluorescence powder and Green phosphor is molten
Glue and lead core for conductive.
Preferably, the blue-fluorescence powder is mixed by blue colour fluorescent powder and above-mentioned silicon dioxide gel according to certain component ratio
The blue-fluorescence powder surface for closing and being formed, and formed is coated with decorative material, and the face finish material includes doped with indium (In)
Tin oxide (SnO2:In), wherein tin oxide (SnO2 doped with indium (In):In it) is hydrated by an indium acetate and First Five-Year Plan
Butter of tin is formed；The blue-fluorescence powder includes the zinc sulphide (ZnS doped with silver:Ag), doped with the aluminium nitride of europium
(AlN:Eu) or doped with tungsten artificial schellite (CaWO4:W), the weight percent which accounts for the Tin tetrachloride pentahydrate is
0.5~4.5%.
Preferably, the red fluorescence powder is mixed by red fluorescence powder and above-mentioned silicon dioxide gel according to certain component ratio
The red fluorescence powder surface for closing and being formed, and formed is coated with decorative material, and the face finish material includes doped with indium (In)
Tin oxide (SnO2:In), wherein tin oxide (SnO2 doped with indium (In):In it) is hydrated by an indium acetate and First Five-Year Plan
Butter of tin is formed；The red fluorescence powder includes the yttrium oxide (Y2O3 doped with europium:Eu), doped with the zinc sulphide of silver
Cadmium ((Zn, Cd) S:Ag), doped with the trbasic zinc phosphate of manganese (Zn3 (PO4) 2:Mn) or doped with manganese magnesium silicate (MgSiO3:
Mn), the weight percent which accounts for the Tin tetrachloride pentahydrate is 2~8%.
Preferably, the Green phosphor is mixed by green emitting phosphor and above-mentioned silicon dioxide gel according to certain component ratio
The Green phosphor surface closed and formed, and formed is coated with decorative material, and the face finish material includes doped with indium (In)
Tin oxide (SnO2:In), wherein tin oxide (SnO2 doped with indium (In):In tetrachloro) is hydrated by an indium acetate and First Five-Year Plan
Change tin to be formed；The Green phosphor includes the zinc sulphide (ZnS doped with copper and aluminium:Cu, Al), doped with the sulphur of copper and aluminium
Change zinc cadmium ((Zn, Cd) S:Cu, Al), doped with the zinc silicate (Zn2SiO4 of manganese and arsenic:Mn, As), doped with the zinc oxide of manganese
(ZnO:Mn), doped with the yttrium oxysulfide (Y2O2S of terbium:Tb) or doped with terbium sulphur cadmium oxide (Cd2O2S:Tb), the indium acetate
The weight percent for accounting for the Tin tetrachloride pentahydrate is 1.5~7.5%.
A kind of preparation method using electrified wire made of phosphor material powder, this approach includes the following steps：
S1：Blue-fluorescence powder, red fluorescence powder and Green phosphor are sufficiently mixed with corresponding silicon dioxide gel
Stirring forms insulated conductor set by drying, mold, calcining process；
S2：The fluorescent powder wire sleeve of the different colours formed in above-mentioned steps S1 is melted to form solid conductor by colloid casting
Set, and be combined with each other between different colours, then the face finish material of corresponding fluorescent powder is pressed together on by film covering device
The surface of fluorescent powder；
S3：It is worn into the fluorescent powder pipeline after synthesis using conducting wire threading device by core is led, forms decorative conducting wire.
Compared with prior art, the beneficial effects of the invention are as follows：
1. using the fluorescent powder of multigroup different colours, the dicoration and associativity of conducting wire can be enhanced；
2. while ensureing that conducting wire is powered, it is noted that the resolution of conducting wire can be used in dark surrounds；
3. the use scope of conducting wire is wide.
Specific implementation mode
The following is a clear and complete description of the technical scheme in the embodiments of the invention, it is clear that described embodiment
Only a part of the embodiment of the present invention, instead of all the embodiments.Based on the embodiments of the present invention, the common skill in this field
The every other embodiment that art personnel are obtained without making creative work belongs to the model that the present invention protects
It encloses.
The present invention provides a kind of technical solution：The technical solution of this patent is made With reference to embodiment further
It explains in detail.
It is a kind of using electrified wire made of phosphor material powder, the electrified wire include at least a blue-fluorescence powder,
A red fluorescence powder and a Green phosphor, while the electrified wire further includes glimmering with blue-fluorescence powder, red
The silicon dioxide gel and lead core for conductive that light powder and Green phosphor mutually stir and evenly mix；
Blue-fluorescence powder is mixed to form by blue colour fluorescent powder and above-mentioned silicon dioxide gel according to certain component ratio, and formed
Blue-fluorescence powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):
In), wherein tin oxide (SnO2 doped with indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；
The blue-fluorescence powder includes the zinc sulphide (ZnS doped with silver:Ag), doped with the aluminium nitride (AlN of europium:Eu) or doped with tungsten
Artificial schellite (CaWO4:W), the weight percent which accounts for the Tin tetrachloride pentahydrate is 0.5~4.5%；
Red fluorescence powder is mixed to form by red fluorescence powder and above-mentioned silicon dioxide gel according to certain component ratio, and formed
Red fluorescence powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):
In), wherein tin oxide (SnO2 doped with indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；
The red fluorescence powder includes the yttrium oxide (Y2O3 doped with europium:Eu), doped with zinc-cadmium sulfide ((Zn, Cd) S of silver:Ag)、
Doped with the trbasic zinc phosphate (Zn3 (PO4) 2 of manganese:Mn) or doped with manganese magnesium silicate (MgSiO3:Mn), the indium acetate account for this five
The weight percent for being hydrated butter of tin is 2~8%；
Green phosphor is mixed to form by green emitting phosphor and above-mentioned silicon dioxide gel according to certain component ratio, and formed
Green phosphor surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):
In), wherein tin oxide (SnO2 doped with indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；This is green
Color fluorescent powder includes the zinc sulphide (ZnS doped with copper and aluminium:Cu, Al), doped with the zinc-cadmium sulfide ((Zn, Cd) of copper and aluminium
S:Cu, Al), doped with the zinc silicate (Zn2SiO4 of manganese and arsenic:Mn, As), doped with the zinc oxide (ZnO of manganese:Mn), doped with
Yttrium oxysulfide (the Y2O2S of terbium:Tb) or doped with terbium sulphur cadmium oxide (Cd2O2S:Tb), which accounts for the five hydrations tetrachloro
The weight percent for changing tin is 1.5~7.5%.
A kind of preparation method using electrified wire made of phosphor material powder, which is characterized in that this method includes following
Step：
S1：Blue-fluorescence powder, red fluorescence powder and Green phosphor are sufficiently mixed with corresponding silicon dioxide gel
Stirring forms insulated conductor set by drying, mold, calcining process；
S2：The fluorescent powder wire sleeve of the different colours formed in above-mentioned steps S1 is melted to form solid conductor by colloid casting
Set, and be combined with each other between different colours, then the face finish material of corresponding fluorescent powder is pressed together on by film covering device
The surface of fluorescent powder；
S3：It is worn into the fluorescent powder pipeline after synthesis using conducting wire threading device by core is led, forms decorative conducting wire.
Embodiment one
In above-mentioned colors fluorescent powder, when practical combinations make, when choosing the fluorescent powder of different colours, according to being shown
Fluorescent characteristic it is different, select the fluorescent powder of reasonable content to merge making conduit with silicon dioxide gel；It is glimmering to choose blue
The combination of light powder and red fluorescence powder：
Blue-fluorescence powder is by blue colour fluorescent powder and above-mentioned silicon dioxide gel according to 1:10 mass ratioes are mixed to form, and formed
Blue-fluorescence powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):
In), wherein tin oxide (SnO2 doped with indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；
The blue-fluorescence powder includes the zinc sulphide (ZnS doped with silver:Ag), doped with the aluminium nitride (AlN of europium:Eu) or doped with tungsten
Artificial schellite (CaWO4:W), the weight percent which accounts for the Tin tetrachloride pentahydrate is 0.5%；
Red fluorescence powder is by red fluorescence powder and above-mentioned silicon dioxide gel according to 1:20 mass ratioes are mixed to form, and formed
Red fluorescence powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):
In), wherein tin oxide (SnO2 doped with indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；
The red fluorescence powder includes the yttrium oxide (Y2O3 doped with europium:Eu), doped with zinc-cadmium sulfide ((Zn, Cd) S of silver:Ag)、
Doped with the trbasic zinc phosphate (Zn3 (PO4) 2 of manganese:Mn) or doped with manganese magnesium silicate (MgSiO3:Mn), the indium acetate account for this five
The weight percent for being hydrated butter of tin is 2%.
Embodiment two
In above-mentioned colors fluorescent powder, when practical combinations make, when choosing the fluorescent powder of different colours, according to being shown
Fluorescent characteristic it is different, select the fluorescent powder of reasonable content to merge making conduit with silicon dioxide gel；It chooses red glimmering
The combination of light powder and Green phosphor：
Red fluorescence powder is by red fluorescence powder and above-mentioned silicon dioxide gel according to 1:10 mass ratioes are mixed to form, and formed
Red fluorescence powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):
In), wherein tin oxide (SnO2 doped with indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；
The red fluorescence powder includes the yttrium oxide (Y2O3 doped with europium:Eu), doped with zinc-cadmium sulfide ((Zn, Cd) S of silver:Ag)、
Doped with the trbasic zinc phosphate (Zn3 (PO4) 2 of manganese:Mn) or doped with manganese magnesium silicate (MgSiO3:Mn), the indium acetate account for this five
The weight percent for being hydrated butter of tin is 3%；
Green phosphor is by green emitting phosphor and above-mentioned silicon dioxide gel according to 1:15 mass ratioes are mixed to form, and formed
Green phosphor surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):
In), wherein tin oxide (SnO2 doped with indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；This is green
Color fluorescent powder includes the zinc sulphide (ZnS doped with copper and aluminium:Cu, Al), doped with the zinc-cadmium sulfide ((Zn, Cd) of copper and aluminium
S:Cu, Al), doped with the zinc silicate (Zn2SiO4 of manganese and arsenic:Mn, As), doped with the zinc oxide (ZnO of manganese:Mn), doped with
Yttrium oxysulfide (the Y2O2S of terbium:Tb) or doped with terbium sulphur cadmium oxide (Cd2O2S:Tb), which accounts for the five hydrations tetrachloro
The weight percent for changing tin is 4%.
Combining form further includes blue-fluorescence powder and Green phosphor；Blue-fluorescence powder, red fluorescence powder and
The combination of Green phosphor and the fluorescent powder combination that other colors are added.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with
Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace
And modification, the scope of the present invention is defined by the appended.
Claims (5)
1. a kind of utilizing electrified wire made of phosphor material powder, which is characterized in that the electrified wire includes at least a blue
Fluorescent powder, a red fluorescence powder and a Green phosphor, while the electrified wire further includes and blue colour fluorescent powder
The silicon dioxide gel and lead core for conductive that body, red fluorescence powder and Green phosphor mutually stir and evenly mix.
2. electrified wire made of a kind of utilization phosphor material powder according to claim 1, it is characterised in that：The blue
Fluorescent powder is mixed to form by blue colour fluorescent powder and above-mentioned silicon dioxide gel according to certain component ratio, and the blue-fluorescence formed
Powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):In), wherein
Doped with the tin oxide (SnO2 of indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；The blue is glimmering
Light powder includes the zinc sulphide (ZnS doped with silver:Ag), doped with the aluminium nitride (AlN of europium:Eu) or doped with tungsten artificial schellite
(CaWO4:W), the weight percent which accounts for the Tin tetrachloride pentahydrate is 0.5~4.5%.
3. electrified wire made of a kind of utilization phosphor material powder according to claim 1, it is characterised in that：The red
Fluorescent powder is mixed to form by red fluorescence powder and above-mentioned silicon dioxide gel according to certain component ratio, and the red fluorescence formed
Powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):In), wherein
Doped with the tin oxide (SnO2 of indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；The red is glimmering
Light powder includes the yttrium oxide (Y2O3 doped with europium:Eu), doped with zinc-cadmium sulfide ((Zn, Cd) S of silver:Ag), doped with manganese
Trbasic zinc phosphate (Zn3 (PO4) 2:Mn) or doped with manganese magnesium silicate (MgSiO3:Mn), which accounts for the five hydrations tetrachloro
The weight percent for changing tin is 2~8%.
4. electrified wire made of a kind of utilization phosphor material powder according to claim 1, it is characterised in that：The green
Fluorescent powder is mixed to form by green emitting phosphor and above-mentioned silicon dioxide gel according to certain component ratio, and the green fluorescence formed
Powder surface is coated with decorative material, and the face finish material includes the tin oxide (SnO2 doped with indium (In):In), wherein mixing
Miscellaneous tin oxide (the SnO2 for having indium (In):In it) is formed by an indium acetate and a Tin tetrachloride pentahydrate；The Green phosphor
Including doped with the zinc sulphide (ZnS of copper and aluminium:Cu, Al), doped with zinc-cadmium sulfide ((Zn, Cd) S of copper and aluminium:Cu, Al), mix
Miscellaneous zinc silicate (the Zn2SiO4 for having manganese and arsenic:Mn, As), doped with the zinc oxide (ZnO of manganese:Mn), doped with the yttrium oxysulfide of terbium
(Y2O2S:Tb) or doped with terbium sulphur cadmium oxide (Cd2O2S:Tb), which accounts for the weight hundred of the Tin tetrachloride pentahydrate
Divide than being 1.5~7.5%.
5. a kind of preparation method using electrified wire made of phosphor material powder according to claim 1-4, feature
It is, this approach includes the following steps：
S1：Blue-fluorescence powder, red fluorescence powder and Green phosphor are sufficiently mixed with corresponding silicon dioxide gel
Stirring forms insulated conductor set by drying, mold, calcining process；
S2：The fluorescent powder wire sleeve of the different colours formed in above-mentioned steps S1 is melted to form solid conductor by colloid casting
Set, and be combined with each other between different colours, then the face finish material of corresponding fluorescent powder is pressed together on by film covering device
The surface of fluorescent powder；
S3：It is worn into the fluorescent powder pipeline after synthesis using conducting wire threading device by core is led, forms decorative conducting wire.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810343962.5A CN108335799A (en) | 2018-04-17 | 2018-04-17 | It is a kind of to utilize electrified wire made of phosphor material powder |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810343962.5A CN108335799A (en) | 2018-04-17 | 2018-04-17 | It is a kind of to utilize electrified wire made of phosphor material powder |
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| CN108335799A true CN108335799A (en) | 2018-07-27 |
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ID=62933459
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| CN101180242A (en) * | 2005-04-19 | 2008-05-14 | 肖特股份公司 | Glass or glass-ceramic article with a decorative coating |
| CN103146374A (en) * | 2012-12-04 | 2013-06-12 | 友达光电股份有限公司 | Fluorescent material |
| CN105931721A (en) * | 2016-06-29 | 2016-09-07 | 孟根森 | Power cable for water conservancy and hydropower station |
| CN106189162A (en) * | 2016-07-29 | 2016-12-07 | 华蓥伟创立电子科技有限公司 | A kind of communication insulation acid and alkali-resistance flame retardant cable |
| CN107502078A (en) * | 2017-07-20 | 2017-12-22 | 江苏荣鑫铝业科技有限公司 | Application aluminium weather resistant luminescent coating and its application method |
-
2018
- 2018-04-17 CN CN201810343962.5A patent/CN108335799A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101180242A (en) * | 2005-04-19 | 2008-05-14 | 肖特股份公司 | Glass or glass-ceramic article with a decorative coating |
| CN103146374A (en) * | 2012-12-04 | 2013-06-12 | 友达光电股份有限公司 | Fluorescent material |
| CN105931721A (en) * | 2016-06-29 | 2016-09-07 | 孟根森 | Power cable for water conservancy and hydropower station |
| CN106189162A (en) * | 2016-07-29 | 2016-12-07 | 华蓥伟创立电子科技有限公司 | A kind of communication insulation acid and alkali-resistance flame retardant cable |
| CN107502078A (en) * | 2017-07-20 | 2017-12-22 | 江苏荣鑫铝业科技有限公司 | Application aluminium weather resistant luminescent coating and its application method |
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Application publication date: 20180727 |
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