CN108332214B - A kind of medical waste substance treating method - Google Patents

A kind of medical waste substance treating method Download PDF

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Publication number
CN108332214B
CN108332214B CN201810152803.7A CN201810152803A CN108332214B CN 108332214 B CN108332214 B CN 108332214B CN 201810152803 A CN201810152803 A CN 201810152803A CN 108332214 B CN108332214 B CN 108332214B
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filter plate
arc
chamber
reaction chamber
incinerator
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CN108332214A (en
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李建国
杨艳艳
冯妍
其他发明人请求不公开姓名
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Li Jianguo
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    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G7/00Incinerators or other apparatus for consuming industrial waste, e.g. chemicals
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/54Nitrogen compounds
    • B01D53/56Nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/60Simultaneously removing sulfur oxides and nitrogen oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/76Gas phase processes, e.g. by using aerosols
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/44Details; Accessories
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23JREMOVAL OR TREATMENT OF COMBUSTION PRODUCTS OR COMBUSTION RESIDUES; FLUES 
    • F23J15/00Arrangements of devices for treating smoke or fumes
    • F23J15/003Arrangements of devices for treating smoke or fumes for supplying chemicals to fumes, e.g. using injection devices
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/40Alkaline earth metal or magnesium compounds
    • B01D2251/404Alkaline earth metal or magnesium compounds of calcium
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2251/00Reactants
    • B01D2251/60Inorganic bases or salts
    • B01D2251/602Oxides
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2258/00Sources of waste gases
    • B01D2258/02Other waste gases
    • B01D2258/0283Flue gases

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  • Engineering & Computer Science (AREA)
  • Chemical & Material Sciences (AREA)
  • Environmental & Geological Engineering (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Analytical Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Dispersion Chemistry (AREA)
  • Treating Waste Gases (AREA)

Abstract

The present invention relates to a kind of medical waste substance treating method, the processing method uses medical waste treatment device, and the medical waste treatment device includes incinerator, mixing tube, primary adsorption room, secondary absorption room, critical reaction chamber and disengagement chamber.By the specific medical waste substance treating method of setting collocation of specific device, so that the processing method of existing known critical water process medical treatment flying ash can be realized flue gas and water and all re-start processing and reach complete harmless treatment.To not cause secondary pollution to atmosphere and water during handling Biohazard Waste.

Description

A kind of medical waste substance treating method
Technical field
The invention belongs to medical fields and field of waste recycle, and in particular to a kind of medical waste substance treating method.
Background technique
Since the comparison of ingredients of Biohazard Waste is complicated, in order to avoid the secondary propagation of the harmful organisms such as bacterial virus, mesh It is preceding mainly the mode of burning to be taken to be handled, but since Biohazard Waste is other than harmful microorganism, it is also possible to contain A large amount of heavy metal element and other harmful elements, flue gas and burning ash after burning can make environment if direct emission At secondary pollution.Supercritical water treatment flying ash becomes handles a kind of relatively effective method of medical flying ash at present, but It is the liquid for having dissolved a large amount of harmful substances to be taken into conventional plus alkali separation method, low separation efficiency at present, and separate effect Fruit is not very good.And incineration flue gas is mainly discharged by the way of direct emission at present.To in processing solid waste Gas and liquid debris are produced when object again, so that the processing mode environmental friendliness is bad.
Summary of the invention
Of the invention proposes a kind of medical waste substance treating method.
It is realized by following technological means:
A kind of medical waste substance treating method, the processing method use medical waste treatment device, and the medical treatment is useless Gurry processing unit includes incinerator, mixing tube, primary adsorption room, secondary absorption room, critical reaction chamber and disengagement chamber.
The incinerator includes burning stove outer covering, incinerator outlet flue and incinerator ash hole, the burning stove outer covering to be in Upper hollow cylindrical body lower hopper shape structure setting, is provided with porous plate, the porous plate is used between the upper The burning ash that top incinerated matter generates is drained into lower part, the incinerator cover top portion is provided with incinerator outlet flue, at it Lower hopper shape structure bottom end forms incinerator ash hole.
The mixing tube includes shell, carbonated drink spray head, ozone spray head and contraction mouth, and the shell is that vertical tubular structure is set It sets, shell top is provided with the contraction mouth of upside down funnel shape, the shell lower part is connected with the incinerator outlet flue, institute It states shell and tube sides portion and is respectively arranged with carbonated drink spray head and ozone spray head, it is mixed to be respectively used to the inside of mixing tube to spray carbonated drink obliquely Close object and ozone.
The primary adsorption room includes level-one chamber enclosure, level-one chamber inlet, the outlet of level-one room and calcium oxide particle and work Property charcoal particle;The calcium oxide particle and active carbon particle, which uniformly gather, to be distributed in the level-one chamber enclosure, outside level-one room Shell bottom side is provided with level-one chamber inlet, and shell-side top is provided with the outlet of level-one room outside level-one room;The level-one room enters Mouth is connected with the contraction mouth top.
The secondary absorption room includes second level chamber enclosure, secondary absorption chamber inlet, processing exhanst gas outlet and oxidation calcisphere;Institute It states secondary absorption chamber inlet to be arranged in secondary chamber outer casing bottom, and is connected with level-one room outlet, the processing flue gas Outlet is arranged in secondary chamber cover top portion side, and the oxidation calcisphere is uniformly distributed in the second level chamber enclosure.
The critical reaction chamber include reaction chamber enclosure, pure water, heating rod, gas siphunculus, air pump, pure water siphunculus, Water pump, reaction chamber entrance and reaction chamber outlet;Reaction chamber entrance setting reaction chamber cover top portion and with the incinerator Ash hole is connected, and is recessed downwards in the reaction chamber outer casing bottom and forms the reaction chamber outlet, in the reaction chamber enclosure Interior bottom is vertically arranged with multiple heating rods, and reaction chamber top side wall is provided with gas siphunculus, sets on the gas siphunculus It is equipped with air pump, the gas siphunculus and air pump are used to adjust critical reaction chamber internal pressure by the injection and extraction of gas, Reaction chamber side wall middle and upper part is provided with pure water siphunculus and water pump, the pure water siphunculus and water pump are used for reaction chamber enclosure Inside injection pure water, the pure water is set to reaction chamber interior of shell, and the height of pure water is that reaction chamber enclosure is high The 50% ~ 68% of degree.
The disengagement chamber includes filter plate, outer filter plate inner membrance, the outer filter plate of arc, support in separation chamber enclosure, arc Axis, disengagement chamber entrance and processing water out;The separation chamber enclosure is hollow rectangular parallelepiped structure, is provided with point in its center of top From chamber entrance, the disengagement chamber entrance is connected with reaction chamber outlet, sets gradually immediately below the disengagement chamber entrance There is the outer filter plate of filter plate in the arc of the hollow hemisphere bodily form, outer filter plate inner membrance and arc, the outer filter plate inner membrance is close to In inside filter plate, filter plate bottom is vertically arranged with support outside filter plate in the arc and arc outside the arc Axis, filter plate and the outer filter plate of arc are densely covered porous plate in the arc, the support shaft bottom by bearing with it is described The rotation of disengagement chamber outer casing bottom is affixed, and filter plate and the outer filter plate of arc can be rotated by axis of support shaft in the arc, institute Support shaft is stated as hollow structure setting, the hollow structure is being provided with out between filter plate outside filter plate in arc and arc Mouthful, for by alkaline matter by being placed to inside support shaft in arc outside filter plate and arc between filter plate;At described point Chamber enclosure side bottom is provided with processing water out.
The medical waste substance treating method includes the following steps.
(1) Biohazard Waste is placed in incinerator and is burned, the flue gas for burning generation passes through incinerator outlet flue It enters in mixing tube, the burning ash for burning generation is entered in critical reaction chamber by incinerator ash hole.
(2) flue gas for burning generation, which enters in mixing tube, moves upwards, and starts carbonated drink spray head and ozone spray head, to Steam water interface and ozone are sprayed in flue gas, so that flue gas brings moisture into uphill process, while ozone is to therein low Valence nitrogen oxides are the nitrogen oxides of high price, and the water adsorption dissolution being injected into.
(3) flue gas improves gas pressure by contraction mouth and accelerates into primary adsorption room, aqueous sulphur in flue gas Oxide and the aqueous nitrogen oxides being oxidized are reacted with calcium oxide particle, while the heavy metal element in flue gas is oxidized calcium Particle and active carbon particle absorption.
(4) flue gas enters in secondary absorption room from primary adsorption room, and the calcium oxide particle in secondary absorption room is by flue gas The water adsorption of middle remnants, then by processing exhanst gas outlet will treated flue gas emission into air.
(5) burning ash is entered in critical reaction chamber by incinerator ash hole, and critical reaction is intracavitary to be provided with pure water, Start and the intracavitary pressure of critical reaction is adjusted by gas pipeline and air pump while heating rod heats pure water, so that critical Pressure and temperature in reaction chamber reaches the critical pressure and critical-temperature of supercritical water so that pure water by burning ash a huge sum of money Belong to element dissolution.
(6) reaction chamber outlet is opened, solidliquid mixture is discharged into disengagement chamber, while opening motor and making mistake in arc Filter plate and the outer filter plate of arc are around support shaft high speed rotation, so that solid ash content is maintained at liquid separation in filter plate in arc In to arc outside filter plate and arc between filter plate, the opening being then turned in support shaft releases alkaline matter, continues high After a certain period of time, outer filter plate inner membrance is extracted away for speed rotation, continues high speed rotation, thus the heavy metal that will be obtained after reaction Alkaloid substance is maintained in the outer filter plate of arc, and the processing water after handling is split into the disengagement chamber outside the outer filter plate of arc In shell, then pass through processing water out discharge.
Preferably, the intracavitary pressure of the critical reaction is 22.1MPa, the temperature of pure water is 374 DEG C and (forms super faces The pressure and temperature of boundary's water).
Preferably, continuation high speed rotation certain time described in step (6) is specially 3 ~ 5min.
Preferably, opening support shaft top after filter plate rotation outside filter plate in arc and arc in step (6) Portion's opening solid ash content is discharged downwards by support shaft, then by opening support shaft side mouth for filter plate outside arc Interior heavy metal alkaloid substance passes through discharge downwards inside support shaft.
Preferably, alkaline matter described in step (6) is calcium hydroxide.
Preferably, the support shaft is detachable.
Effect of the invention is that:
1, both the flue gas for burning generation was handled, while having carried out the nocuousness such as heavy metal to the flying dust generated is burned Substance processing, and the water to contain hazardous substance after processing has also carried out separating-adding alkali reaction-separation mode to processing water It is handled, to realize the full processing of solid, liquid, gas, is truly realized harmless treatment.
2, it burns in the flue gas of generation containing lower nitrogen oxides and oxysulfide, by spraying ozone, while also spraying Steam water interface, so that lower nitrogen oxides are relatively high higher nitrogen oxides, then higher nitrogen oxides by ozone Be dissolved in water (trivalent and pentavalent nitrogen oxides is only absorbed by the water to form acid), at the same oxysulfide be also dissolved in water it is (anti-with water Acid should be formed), flue gas enters in primary adsorption room with these acid solutions, and steam dissolves calcium oxide particle surface to form hydrogen Calcium oxide solution, and calcium hydroxide solution reacts i.e. forming salt with acid, thus by harmful nitrogen oxides and sulphur oxygen in flue gas Compound is adsorbed.There can be the harmful substances such as some heavy metal elements in flue gas simultaneously, by being arranged in primary adsorption room Active carbon particle, these harmful elements are adsorbed.It is entered in secondary absorption room in flue gas, remaining steam in flue gas (also including solution) is further oxidized calcisphere adsorption, to play dry purpose to flue gas.
3, the harmful elements such as heavy metal in medical flying ash are dissolved into pure water by supercritical water reaction, and are uniformly released It is put into arc in filter plate, by high speed rotation, is separated solution and solid burning ash using centrifugal force.Work as liquid When arrival in outer filter plate inner membrance, due to the inner membrance be it is non-penetrating, fluid preservation in the position, passes through rotation at this time Turn for the alkaline matters such as calcium hydroxide to be discharged into solution, calcium hydroxide reacts generation with harmful elements such as heavy metals in solution Precipitating pumps inner membrance at this time and continues high speed rotation, to precipitating be separated with processing water, the water after realizing supercritical water treatment It is not contaminated.
Pass through the interior filter plate of setting specific structure (coaxial, hollow hemisphere body, interior accessibke porosity, and film is set in outer arc) Cooperate with outer filter plate and inner membrance, two steps filtered and the reaction between the filtering of two steps is completed during same, To greatly improve the treatment effeciency of processing water.
Detailed description of the invention
Fig. 1 is the structural schematic diagram of medical waste treatment device of the present invention.
Wherein: 1- incinerator, 11- incinerator outlet flue, 12- incinerator ash hole, 2- mixing tube, 21- carbonated drink spray head, 22- ozone spray head, 23- contraction mouth, 3- primary adsorption room, 31- calcium oxide particle, 32- active carbon particle, 4- secondary absorption room, 41- aoxidizes calcisphere, 42- secondary absorption chamber inlet, and 43- handles exhanst gas outlet, 5- critical reaction chamber, 51- pure water, 52- heating Stick, 53- gas siphunculus, 531- air pump, 54- pure water siphunculus, 541- water pump, the outlet of 55- reaction chamber, 6- disengagement chamber, 61- arc Interior filter plate, the outer filter plate inner membrance of 62-, the outer filter plate of 63- arc, 64- support shaft, 65- handle water out.
Specific embodiment
Embodiment 1
A kind of medical waste substance treating method, the processing method use medical waste treatment device, and the medical treatment is useless Gurry processing unit includes incinerator, mixing tube, primary adsorption room, secondary absorption room, critical reaction chamber and disengagement chamber.
The incinerator includes burning stove outer covering, incinerator outlet flue and incinerator ash hole, the burning stove outer covering to be in Upper hollow cylindrical body lower hopper shape structure setting, is provided with porous plate, the porous plate is used between the upper The burning ash that top incinerated matter generates is drained into lower part, the incinerator cover top portion is provided with incinerator outlet flue, at it Lower hopper shape structure bottom end forms incinerator ash hole.
The mixing tube includes shell, carbonated drink spray head, ozone spray head and contraction mouth, and the shell is that vertical tubular structure is set It sets, shell top is provided with the contraction mouth of upside down funnel shape, the shell lower part is connected with the incinerator outlet flue, institute It states shell and tube sides portion and is respectively arranged with carbonated drink spray head and ozone spray head, it is mixed to be respectively used to the inside of mixing tube to spray carbonated drink obliquely Close object and ozone.
The primary adsorption room includes level-one chamber enclosure, level-one chamber inlet, the outlet of level-one room and calcium oxide particle and work Property charcoal particle;The calcium oxide particle and active carbon particle, which uniformly gather, to be distributed in the level-one chamber enclosure, outside level-one room Shell bottom side is provided with level-one chamber inlet, and shell-side top is provided with the outlet of level-one room outside level-one room;The level-one room enters Mouth is connected with the contraction mouth top.
The secondary absorption room includes second level chamber enclosure, secondary absorption chamber inlet, processing exhanst gas outlet and oxidation calcisphere;Institute It states secondary absorption chamber inlet to be arranged in secondary chamber outer casing bottom, and is connected with level-one room outlet, the processing flue gas Outlet is arranged in secondary chamber cover top portion side, and the oxidation calcisphere is uniformly distributed in the second level chamber enclosure.
The critical reaction chamber include reaction chamber enclosure, pure water, heating rod, gas siphunculus, air pump, pure water siphunculus, Water pump, reaction chamber entrance and reaction chamber outlet;Reaction chamber entrance setting reaction chamber cover top portion and with the incinerator Ash hole is connected, and is recessed downwards in the reaction chamber outer casing bottom and forms the reaction chamber outlet, in the reaction chamber enclosure Interior bottom is vertically arranged with multiple heating rods, and reaction chamber top side wall is provided with gas siphunculus, sets on the gas siphunculus It is equipped with air pump, the gas siphunculus and air pump are used to adjust critical reaction chamber internal pressure by the injection and extraction of gas, Reaction chamber side wall middle and upper part is provided with pure water siphunculus and water pump, the pure water siphunculus and water pump are used for reaction chamber enclosure Inside injection pure water, the pure water is set to reaction chamber interior of shell, and the height of pure water is that reaction chamber enclosure is high The 52% of degree.
The disengagement chamber includes filter plate, outer filter plate inner membrance, the outer filter plate of arc, support in separation chamber enclosure, arc Axis, disengagement chamber entrance and processing water out;The separation chamber enclosure is hollow rectangular parallelepiped structure, is provided with point in its center of top From chamber entrance, the disengagement chamber entrance is connected with reaction chamber outlet, sets gradually immediately below the disengagement chamber entrance There is the outer filter plate of filter plate in the arc of the hollow hemisphere bodily form, outer filter plate inner membrance and arc, the outer filter plate inner membrance is close to In inside filter plate, filter plate bottom is vertically arranged with support outside filter plate in the arc and arc outside the arc Axis, filter plate and the outer filter plate of arc are densely covered porous plate in the arc, the support shaft bottom by bearing with it is described The rotation of disengagement chamber outer casing bottom is affixed, and filter plate and the outer filter plate of arc can be rotated by axis of support shaft in the arc, institute Support shaft is stated as hollow structure setting, the hollow structure is being provided with out between filter plate outside filter plate in arc and arc Mouthful, for by alkaline matter by being placed to inside support shaft in arc outside filter plate and arc between filter plate;At described point Chamber enclosure side bottom is provided with processing water out.
The support shaft is detachable.
The medical waste substance treating method includes the following steps.
(1) Biohazard Waste is placed in incinerator and is burned, the flue gas for burning generation passes through incinerator outlet flue It enters in mixing tube, the burning ash for burning generation is entered in critical reaction chamber by incinerator ash hole.
(2) flue gas for burning generation, which enters in mixing tube, moves upwards, and starts carbonated drink spray head and ozone spray head, to Steam water interface and ozone are sprayed in flue gas, so that flue gas brings moisture into uphill process, while ozone is to therein low Valence nitrogen oxides are the nitrogen oxides of high price, and the water adsorption dissolution being injected into.
(3) flue gas improves gas pressure by contraction mouth and accelerates into primary adsorption room, aqueous sulphur in flue gas Oxide and the aqueous nitrogen oxides being oxidized are reacted with calcium oxide particle, while the heavy metal element in flue gas is oxidized calcium Particle and active carbon particle absorption.
(4) flue gas enters in secondary absorption room from primary adsorption room, and the calcium oxide particle in secondary absorption room is by flue gas The water adsorption of middle remnants, then by processing exhanst gas outlet will treated flue gas emission into air.
(5) burning ash is entered in critical reaction chamber by incinerator ash hole, and critical reaction is intracavitary to be provided with pure water, Start and the intracavitary pressure of critical reaction is adjusted by gas pipeline and air pump while heating rod heats pure water, so that critical Pressure and temperature in reaction chamber reaches the critical pressure and critical-temperature of supercritical water so that pure water by burning ash a huge sum of money Belong to element dissolution.
The intracavitary pressure of the critical reaction is 22.2MPa, and the temperature of pure water is 375 DEG C.
(6) reaction chamber outlet is opened, solidliquid mixture is discharged into disengagement chamber, while opening motor and making mistake in arc Filter plate and the outer filter plate of arc are around support shaft high speed rotation, so that solid ash content is maintained at liquid separation in filter plate in arc In to arc outside filter plate and arc between filter plate, the opening being then turned in support shaft releases calcium hydroxide, continues high After a certain period of time, outer filter plate inner membrance is extracted away for speed rotation, continues high speed rotation, thus the heavy metal that will be obtained after reaction Alkaloid substance is maintained in the outer filter plate of arc, and the processing water after handling is split into the disengagement chamber outside the outer filter plate of arc In shell, then pass through processing water out discharge.
The continuation high speed rotation certain time is specially 3.2min.
After filter plate rotation outside filter plate in arc and arc, support shaft top opening is opened, by solid ash content It is discharged downwards by support shaft, is then led to the heavy metal alkaloid substance outside arc in filter plate by opening support shaft side mouth Cross discharge downwards inside support shaft.
Embodiment 2
A kind of medical waste substance treating method, the processing method use medical waste treatment device, and the medical treatment is useless Gurry processing unit includes incinerator, mixing tube, primary adsorption room, secondary absorption room, critical reaction chamber and disengagement chamber.
The incinerator includes burning stove outer covering, incinerator outlet flue and incinerator ash hole, the burning stove outer covering to be in Upper hollow cylindrical body lower hopper shape structure setting, is provided with porous plate, the porous plate is used between the upper The burning ash that top incinerated matter generates is drained into lower part, the incinerator cover top portion is provided with incinerator outlet flue, at it Lower hopper shape structure bottom end forms incinerator ash hole.
The mixing tube includes shell, carbonated drink spray head, ozone spray head and contraction mouth, and the shell is that vertical tubular structure is set It sets, shell top is provided with the contraction mouth of upside down funnel shape, the shell lower part is connected with the incinerator outlet flue, institute It states shell and tube sides portion and is respectively arranged with carbonated drink spray head and ozone spray head, it is mixed to be respectively used to the inside of mixing tube to spray carbonated drink obliquely Close object and ozone.
The primary adsorption room includes level-one chamber enclosure, level-one chamber inlet, the outlet of level-one room and calcium oxide particle and work Property charcoal particle;The calcium oxide particle and active carbon particle, which uniformly gather, to be distributed in the level-one chamber enclosure, outside level-one room Shell bottom side is provided with level-one chamber inlet, and shell-side top is provided with the outlet of level-one room outside level-one room;The level-one room enters Mouth is connected with the contraction mouth top.
The secondary absorption room includes second level chamber enclosure, secondary absorption chamber inlet, processing exhanst gas outlet and oxidation calcisphere;Institute It states secondary absorption chamber inlet to be arranged in secondary chamber outer casing bottom, and is connected with level-one room outlet, the processing flue gas Outlet is arranged in secondary chamber cover top portion side, and the oxidation calcisphere is uniformly distributed in the second level chamber enclosure.
The critical reaction chamber include reaction chamber enclosure, pure water, heating rod, gas siphunculus, air pump, pure water siphunculus, Water pump, reaction chamber entrance and reaction chamber outlet;Reaction chamber entrance setting reaction chamber cover top portion and with the incinerator Ash hole is connected, and is recessed downwards in the reaction chamber outer casing bottom and forms the reaction chamber outlet, in the reaction chamber enclosure Interior bottom is vertically arranged with multiple heating rods, and reaction chamber top side wall is provided with gas siphunculus, sets on the gas siphunculus It is equipped with air pump, the gas siphunculus and air pump are used to adjust critical reaction chamber internal pressure by the injection and extraction of gas, Reaction chamber side wall middle and upper part is provided with pure water siphunculus and water pump, the pure water siphunculus and water pump are used for reaction chamber enclosure Inside injection pure water, the pure water is set to reaction chamber interior of shell, and the height of pure water is that reaction chamber enclosure is high The 58% of degree.
The disengagement chamber includes filter plate, outer filter plate inner membrance, the outer filter plate of arc, support in separation chamber enclosure, arc Axis, disengagement chamber entrance and processing water out;The separation chamber enclosure is hollow rectangular parallelepiped structure, is provided with point in its center of top From chamber entrance, the disengagement chamber entrance is connected with reaction chamber outlet, sets gradually immediately below the disengagement chamber entrance There is the outer filter plate of filter plate in the arc of the hollow hemisphere bodily form, outer filter plate inner membrance and arc, the outer filter plate inner membrance is close to In inside filter plate, filter plate bottom is vertically arranged with support outside filter plate in the arc and arc outside the arc Axis, filter plate and the outer filter plate of arc are densely covered porous plate in the arc, the support shaft bottom by bearing with it is described The rotation of disengagement chamber outer casing bottom is affixed, and filter plate and the outer filter plate of arc can be rotated by axis of support shaft in the arc, institute Support shaft is stated as hollow structure setting, the hollow structure is being provided with out between filter plate outside filter plate in arc and arc Mouthful, for by alkaline matter by being placed to inside support shaft in arc outside filter plate and arc between filter plate;At described point Chamber enclosure side bottom is provided with processing water out.
The support shaft is detachable.
The medical waste substance treating method includes the following steps.
(1) Biohazard Waste is placed in incinerator and is burned, the flue gas for burning generation passes through incinerator outlet flue It enters in mixing tube, the burning ash for burning generation is entered in critical reaction chamber by incinerator ash hole.
(2) flue gas for burning generation, which enters in mixing tube, moves upwards, and starts carbonated drink spray head and ozone spray head, to Steam water interface and ozone are sprayed in flue gas, so that flue gas brings moisture into uphill process, while ozone is to therein low Valence nitrogen oxides are the nitrogen oxides of high price, and the water adsorption dissolution being injected into.
(3) flue gas improves gas pressure by contraction mouth and accelerates into primary adsorption room, aqueous sulphur in flue gas Oxide and the aqueous nitrogen oxides being oxidized are reacted with calcium oxide particle, while the heavy metal element in flue gas is oxidized calcium Particle and active carbon particle absorption.
(4) flue gas enters in secondary absorption room from primary adsorption room, and the calcium oxide particle in secondary absorption room is by flue gas The water adsorption of middle remnants, then by processing exhanst gas outlet will treated flue gas emission into air.
(5) burning ash is entered in critical reaction chamber by incinerator ash hole, and critical reaction is intracavitary to be provided with pure water, Start and the intracavitary pressure of critical reaction is adjusted by gas pipeline and air pump while heating rod heats pure water, so that critical Pressure and temperature in reaction chamber reaches the critical pressure and critical-temperature of supercritical water so that pure water by burning ash a huge sum of money Belong to element dissolution.
The intracavitary pressure of the critical reaction is 22.1MPa, and the temperature of pure water is 374 DEG C.
(6) reaction chamber outlet is opened, solidliquid mixture is discharged into disengagement chamber, while opening motor and making mistake in arc Filter plate and the outer filter plate of arc are around support shaft high speed rotation, so that solid ash content is maintained at liquid separation in filter plate in arc In to arc outside filter plate and arc between filter plate, the opening being then turned in support shaft releases sodium hydroxide, continues high After a certain period of time, outer filter plate inner membrance is extracted away for speed rotation, continues high speed rotation, thus the heavy metal that will be obtained after reaction Alkaloid substance is maintained in the outer filter plate of arc, and the processing water after handling is split into the disengagement chamber outside the outer filter plate of arc In shell, then pass through processing water out discharge.
The continuation high speed rotation certain time is specially 3.5min.
After filter plate rotation outside filter plate in arc and arc, support shaft top opening is opened, by solid ash content It is discharged downwards by support shaft, is then led to the heavy metal alkaloid substance outside arc in filter plate by opening support shaft side mouth Cross discharge downwards inside support shaft.
Embodiment 3
A kind of medical waste substance treating method, the processing method use medical waste treatment device, and the medical treatment is useless Gurry processing unit includes incinerator, mixing tube, primary adsorption room, secondary absorption room, critical reaction chamber and disengagement chamber.
The incinerator includes burning stove outer covering, incinerator outlet flue and incinerator ash hole, the burning stove outer covering to be in Upper hollow cylindrical body lower hopper shape structure setting, is provided with porous plate, the porous plate is used between the upper The burning ash that top incinerated matter generates is drained into lower part, the incinerator cover top portion is provided with incinerator outlet flue, at it Lower hopper shape structure bottom end forms incinerator ash hole.
The mixing tube includes shell, carbonated drink spray head, ozone spray head and contraction mouth, and the shell is that vertical tubular structure is set It sets, shell top is provided with the contraction mouth of upside down funnel shape, the shell lower part is connected with the incinerator outlet flue, institute It states shell and tube sides portion and is respectively arranged with carbonated drink spray head and ozone spray head, it is mixed to be respectively used to the inside of mixing tube to spray carbonated drink obliquely Close object and ozone.
The primary adsorption room includes level-one chamber enclosure, level-one chamber inlet, the outlet of level-one room and calcium oxide particle and work Property charcoal particle;The calcium oxide particle and active carbon particle, which uniformly gather, to be distributed in the level-one chamber enclosure, outside level-one room Shell bottom side is provided with level-one chamber inlet, and shell-side top is provided with the outlet of level-one room outside level-one room;The level-one room enters Mouth is connected with the contraction mouth top.
The secondary absorption room includes second level chamber enclosure, secondary absorption chamber inlet, processing exhanst gas outlet and oxidation calcisphere;Institute It states secondary absorption chamber inlet to be arranged in secondary chamber outer casing bottom, and is connected with level-one room outlet, the processing flue gas Outlet is arranged in secondary chamber cover top portion side, and the oxidation calcisphere is uniformly distributed in the second level chamber enclosure.
The critical reaction chamber include reaction chamber enclosure, pure water, heating rod, gas siphunculus, air pump, pure water siphunculus, Water pump, reaction chamber entrance and reaction chamber outlet;Reaction chamber entrance setting reaction chamber cover top portion and with the incinerator Ash hole is connected, and is recessed downwards in the reaction chamber outer casing bottom and forms the reaction chamber outlet, in the reaction chamber enclosure Interior bottom is vertically arranged with multiple heating rods, and reaction chamber top side wall is provided with gas siphunculus, sets on the gas siphunculus It is equipped with air pump, the gas siphunculus and air pump are used to adjust critical reaction chamber internal pressure by the injection and extraction of gas, Reaction chamber side wall middle and upper part is provided with pure water siphunculus and water pump, the pure water siphunculus and water pump are used for reaction chamber enclosure Inside injection pure water, the pure water is set to reaction chamber interior of shell, and the height of pure water is that reaction chamber enclosure is high The 62% of degree.
The disengagement chamber includes filter plate, outer filter plate inner membrance, the outer filter plate of arc, support in separation chamber enclosure, arc Axis, disengagement chamber entrance and processing water out;The separation chamber enclosure is hollow rectangular parallelepiped structure, is provided with point in its center of top From chamber entrance, the disengagement chamber entrance is connected with reaction chamber outlet, sets gradually immediately below the disengagement chamber entrance There is the outer filter plate of filter plate in the arc of the hollow hemisphere bodily form, outer filter plate inner membrance and arc, the outer filter plate inner membrance is close to In inside filter plate, filter plate bottom is vertically arranged with support outside filter plate in the arc and arc outside the arc Axis, filter plate and the outer filter plate of arc are densely covered porous plate in the arc, the support shaft bottom by bearing with it is described The rotation of disengagement chamber outer casing bottom is affixed, and filter plate and the outer filter plate of arc can be rotated by axis of support shaft in the arc, institute Support shaft is stated as hollow structure setting, the hollow structure is being provided with out between filter plate outside filter plate in arc and arc Mouthful, for by alkaline matter by being placed to inside support shaft in arc outside filter plate and arc between filter plate;At described point Chamber enclosure side bottom is provided with processing water out.
The support shaft is detachable.
The medical waste substance treating method includes the following steps.
(1) Biohazard Waste is placed in incinerator and is burned, the flue gas for burning generation passes through incinerator outlet flue It enters in mixing tube, the burning ash for burning generation is entered in critical reaction chamber by incinerator ash hole.
(2) flue gas for burning generation, which enters in mixing tube, moves upwards, and starts carbonated drink spray head and ozone spray head, to Steam water interface and ozone are sprayed in flue gas, so that flue gas brings moisture into uphill process, while ozone is to therein low Valence nitrogen oxides are the nitrogen oxides of high price, and the water adsorption dissolution being injected into.
(3) flue gas improves gas pressure by contraction mouth and accelerates into primary adsorption room, aqueous sulphur in flue gas Oxide and the aqueous nitrogen oxides being oxidized are reacted with calcium oxide particle, while the heavy metal element in flue gas is oxidized calcium Particle and active carbon particle absorption.
(4) flue gas enters in secondary absorption room from primary adsorption room, and the calcium oxide particle in secondary absorption room is by flue gas The water adsorption of middle remnants, then by processing exhanst gas outlet will treated flue gas emission into air.
(5) burning ash is entered in critical reaction chamber by incinerator ash hole, and critical reaction is intracavitary to be provided with pure water, Start and the intracavitary pressure of critical reaction is adjusted by gas pipeline and air pump while heating rod heats pure water, so that critical Pressure and temperature in reaction chamber reaches the critical pressure and critical-temperature of supercritical water so that pure water by burning ash a huge sum of money Belong to element dissolution.
The intracavitary pressure and temperature for forming supercritical water of the critical reaction, specially pressure 22.3MPa, the temperature of pure water Degree is 374 DEG C.
(6) reaction chamber outlet is opened, solidliquid mixture is discharged into disengagement chamber, while opening motor and making mistake in arc Filter plate and the outer filter plate of arc are around support shaft high speed rotation, so that solid ash content is maintained at liquid separation in filter plate in arc In to arc outside filter plate and arc between filter plate, the opening being then turned in support shaft releases potassium hydroxide, continues high After a certain period of time, outer filter plate inner membrance is extracted away for speed rotation, continues high speed rotation, thus the heavy metal that will be obtained after reaction Alkaloid substance is maintained in the outer filter plate of arc, and the processing water after handling is split into the disengagement chamber outside the outer filter plate of arc In shell, then pass through processing water out discharge.
The continuation high speed rotation certain time is specially 3.8min.
After filter plate rotation outside filter plate in arc and arc, support shaft top opening is opened, by solid ash content It is discharged downwards by support shaft, is then led to the heavy metal alkaloid substance outside arc in filter plate by opening support shaft side mouth Cross discharge downwards inside support shaft.

Claims (6)

1. a kind of medical waste substance treating method, which is characterized in that the processing method uses medical waste treatment device, institute Stating medical waste treatment device includes incinerator, mixing tube, primary adsorption room, secondary absorption room, critical reaction chamber and separation Chamber;
The incinerator includes burning stove outer covering, incinerator outlet flue and incinerator ash hole, the burning stove outer covering to present portion Hollow cylinder lower hopper shape structure setting, is provided with porous plate between the upper, the porous plate be used for by The burning ash that portion's incinerated matter generates drains to lower part, the incinerator cover top portion is provided with incinerator outlet flue, in its underpart Funnel-shaped structure bottom end forms incinerator ash hole;
The mixing tube includes shell, carbonated drink spray head, ozone spray head and contraction mouth, and the shell is vertical tubulose structure setting, Shell top is provided with the contraction mouth of upside down funnel shape, the shell lower part is connected with the incinerator outlet flue, described Shell and tube sides portion is respectively arranged with carbonated drink spray head and ozone spray head, is respectively used to spray steam-water mixing obliquely to the inside of mixing tube Object and ozone;
The primary adsorption room includes level-one chamber enclosure, level-one chamber inlet, the outlet of level-one room and calcium oxide particle and active carbon Particle;The calcium oxide particle and active carbon particle, which uniformly gather, to be distributed in the level-one chamber enclosure, at level-one chamber enclosure bottom Portion side is provided with level-one chamber inlet, and shell-side top is provided with the outlet of level-one room outside level-one room;The level-one chamber inlet with The contraction mouth top is connected;
The secondary absorption room includes second level chamber enclosure, secondary absorption chamber inlet, processing exhanst gas outlet and oxidation calcisphere;Described two Grade absorption chamber inlet is arranged in secondary chamber outer casing bottom, and is connected with level-one room outlet, the processing exhanst gas outlet It is arranged in secondary chamber cover top portion side, the oxidation calcisphere is uniformly distributed in the second level chamber enclosure;
The critical reaction chamber include reaction chamber enclosure, pure water, heating rod, gas siphunculus, air pump, pure water siphunculus, water pump, Reaction chamber entrance and reaction chamber outlet;Reaction chamber entrance setting reaction chamber cover top portion and with the incinerator ash hole It is connected, is recessed downwards in the reaction chamber outer casing bottom and forms the reaction chamber outlet, the bottom in the reaction chamber enclosure Multiple heating rods are vertically arranged with, reaction chamber top side wall is provided with gas siphunculus, is provided with gas on the gas siphunculus Pump, the gas siphunculus and air pump are used to adjust critical reaction chamber internal pressure by the injection and extraction of gas, are reacting Chamber side wall middle and upper part is provided with pure water siphunculus and water pump, and the pure water siphunculus and water pump are used to infuse to reaction chamber interior of shell Enter pure water, the pure water is set to reaction chamber interior of shell, and the height of pure water is the 50% of reaction chamber outer cover height ~68%;
The disengagement chamber include separation chamber enclosure, the outer filter plate of filter plate, outer filter plate inner membrance, arc in arc, support shaft, point From chamber entrance and processing water out;The separation chamber enclosure is hollow rectangular parallelepiped structure, its center of top is provided with disengagement chamber Entrance, the outlet of the disengagement chamber entrance and the reaction chamber be connected, and is disposed with immediately below the disengagement chamber entrance The outer filter plate of filter plate, outer filter plate inner membrance and arc, the outer filter plate inner membrance are tightly attached to institute in the arc of the empty hemisphere bodily form It states inside the outer filter plate of arc, filter plate bottom is vertically arranged with support shaft outside filter plate in the arc and arc, institute Stating filter plate and the outer filter plate of arc in arc is densely covered porous plate, and the support shaft bottom passes through bearing and the disengagement chamber Outer casing bottom rotation is affixed, and filter plate and the outer filter plate of arc can be rotated by axis of support shaft in the arc, the support Axis is hollow structure setting, and the hollow structure is being provided with opening, is being used between filter plate outside filter plate in arc and arc By alkaline matter by being placed to inside support shaft in arc outside filter plate and arc between filter plate;In the separation chamber enclosure Side bottom is provided with processing water out;
The medical waste substance treating method includes the following steps:
(1) Biohazard Waste is placed in incinerator and is burned, the flue gas for burning generation is entered by incinerator outlet flue Into mixing tube, the burning ash for burning generation is entered in critical reaction chamber by incinerator ash hole;
(2) flue gas for burning generation, which enters in mixing tube, moves upwards, and starts carbonated drink spray head and ozone spray head, to flue gas Middle injection steam water interface and ozone, so that flue gas brings moisture into uphill process, while ozone is to Low-Charged Nitrogen therein Oxides are the nitrogen oxides of high price, and the water adsorption dissolution being injected into;
(3) flue gas improves gas pressure by contraction mouth and accelerates into primary adsorption room, aqueous sulphur oxidation in flue gas Object and the aqueous nitrogen oxides being oxidized are reacted with calcium oxide particle, while the heavy metal element in flue gas is oxidized calcium particle It is adsorbed with active carbon particle;
(4) flue gas enters in secondary absorption room from primary adsorption room, and the calcium oxide particle in secondary absorption room will be residual in flue gas Remaining water adsorption, then by processing exhanst gas outlet will treated flue gas emission into air;
(5) burning ash is entered in critical reaction chamber by incinerator ash hole, and critical reaction is intracavitary to be provided with pure water, starting The intracavitary pressure of critical reaction is adjusted by gas pipeline and air pump while heating rod heats pure water, so that critical reaction Intracavitary pressure and temperature reaches the critical pressure and critical-temperature of supercritical water, so that pure water is first by heavy metal in incineration ash Element dissolution;
(6) reaction chamber outlet is opened, solidliquid mixture is discharged into disengagement chamber, while opening motor and making filter plate in arc With filter plate outside arc around support shaft high speed rotation so that solid ash content is maintained in arc in filter plate and liquid is separated to arc In shape between filter plate and the outer filter plate of arc, the opening being then turned in support shaft releases alkaline matter, continues high speed and revolves Turn that after a certain period of time, outer filter plate inner membrance is extracted away, continues high speed rotation, thus the heavy metal alkali object that will be obtained after reaction Matter is maintained in the outer filter plate of arc, and the processing water after handling is split into the separation chamber enclosure outside the outer filter plate of arc It is interior, then pass through processing water out discharge.
2. medical waste substance treating method according to claim 1, which is characterized in that the intracavitary pressure of the critical reaction For 22.1MPa, the temperature of pure water is 374 DEG C.
3. -2 described in any item medical waste substance treating methods according to claim 1, which is characterized in that described in step (6) Continuing high speed rotation certain time is specially 3 ~ 5min.
4. medical waste substance treating method according to claim 3, which is characterized in that when being filtered in arc in step (6) After plate and the outer filter plate rotation of arc, support shaft top opening is opened, solid ash content is discharged downwards by support shaft, so The heavy metal alkaloid substance outside arc in filter plate is passed through into discharge downwards inside support shaft by opening support shaft side mouth afterwards.
5. medical waste substance treating method according to claim 1, which is characterized in that basic species described in step (6) Matter is calcium hydroxide.
6. medical waste substance treating method according to claim 1, which is characterized in that the support shaft is detachable.
CN201810152803.7A 2018-02-20 2018-02-20 A kind of medical waste substance treating method Expired - Fee Related CN108332214B (en)

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