CN108330567A - Fiber for wig and preparation method thereof - Google Patents
Fiber for wig and preparation method thereof Download PDFInfo
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- CN108330567A CN108330567A CN201810200635.4A CN201810200635A CN108330567A CN 108330567 A CN108330567 A CN 108330567A CN 201810200635 A CN201810200635 A CN 201810200635A CN 108330567 A CN108330567 A CN 108330567A
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- 239000000835 fiber Substances 0.000 title claims abstract description 86
- 238000002360 preparation method Methods 0.000 title claims abstract description 14
- 239000002131 composite material Substances 0.000 claims abstract description 89
- 210000004209 hair Anatomy 0.000 claims abstract description 51
- 239000000463 material Substances 0.000 claims abstract description 4
- -1 N- butyl-pyridinium chloride salt ions Chemical class 0.000 claims description 44
- 229920000642 polymer Polymers 0.000 claims description 40
- 229910021645 metal ion Inorganic materials 0.000 claims description 39
- IXPNQXFRVYWDDI-UHFFFAOYSA-N 1-methyl-2,4-dioxo-1,3-diazinane-5-carboximidamide Chemical compound CN1CC(C(N)=N)C(=O)NC1=O IXPNQXFRVYWDDI-UHFFFAOYSA-N 0.000 claims description 35
- 239000000661 sodium alginate Substances 0.000 claims description 35
- 235000010413 sodium alginate Nutrition 0.000 claims description 35
- 229940005550 sodium alginate Drugs 0.000 claims description 35
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 claims description 30
- 238000003756 stirring Methods 0.000 claims description 28
- KDYFGRWQOYBRFD-UHFFFAOYSA-N succinic acid Chemical compound OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims description 28
- 238000000338 in vitro Methods 0.000 claims description 27
- 239000000839 emulsion Substances 0.000 claims description 23
- VSCWAEJMTAWNJL-UHFFFAOYSA-K aluminium trichloride Chemical compound Cl[Al](Cl)Cl VSCWAEJMTAWNJL-UHFFFAOYSA-K 0.000 claims description 22
- 239000002518 antifoaming agent Substances 0.000 claims description 22
- 230000001112 coagulating effect Effects 0.000 claims description 19
- 229920000139 polyethylene terephthalate Polymers 0.000 claims description 19
- 239000005020 polyethylene terephthalate Substances 0.000 claims description 19
- 239000000203 mixture Substances 0.000 claims description 18
- XUIMIQQOPSSXEZ-UHFFFAOYSA-N Silicon Chemical compound [Si] XUIMIQQOPSSXEZ-UHFFFAOYSA-N 0.000 claims description 17
- 229910052710 silicon Inorganic materials 0.000 claims description 17
- 239000010703 silicon Substances 0.000 claims description 17
- 239000003351 stiffener Substances 0.000 claims description 17
- 229920002978 Vinylon Polymers 0.000 claims description 16
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N phenol group Chemical group C1(=CC=CC=C1)O ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 claims description 16
- 239000007788 liquid Substances 0.000 claims description 15
- 239000001384 succinic acid Substances 0.000 claims description 14
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 13
- 238000001035 drying Methods 0.000 claims description 13
- 208000019901 Anxiety disease Diseases 0.000 claims description 11
- UXVMQQNJUSDDNG-UHFFFAOYSA-L Calcium chloride Chemical compound [Cl-].[Cl-].[Ca+2] UXVMQQNJUSDDNG-UHFFFAOYSA-L 0.000 claims description 11
- 230000036506 anxiety Effects 0.000 claims description 11
- 239000001110 calcium chloride Substances 0.000 claims description 11
- 229910001628 calcium chloride Inorganic materials 0.000 claims description 11
- 238000002156 mixing Methods 0.000 claims description 11
- 238000009987 spinning Methods 0.000 claims description 11
- 239000012744 reinforcing agent Substances 0.000 claims description 10
- 239000003921 oil Substances 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- 239000000377 silicon dioxide Substances 0.000 claims description 7
- QTBSBXVTEAMEQO-UHFFFAOYSA-N Acetic acid Chemical compound CC(O)=O QTBSBXVTEAMEQO-UHFFFAOYSA-N 0.000 claims description 6
- CDQSJQSWAWPGKG-UHFFFAOYSA-N butane-1,1-diol Chemical compound CCCC(O)O CDQSJQSWAWPGKG-UHFFFAOYSA-N 0.000 claims description 6
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 150000003376 silicon Chemical class 0.000 claims description 6
- 239000004721 Polyphenylene oxide Substances 0.000 claims description 5
- DPXJVFZANSGRMM-UHFFFAOYSA-N acetic acid;2,3,4,5,6-pentahydroxyhexanal;sodium Chemical compound [Na].CC(O)=O.OCC(O)C(O)C(O)C(O)C=O DPXJVFZANSGRMM-UHFFFAOYSA-N 0.000 claims description 5
- AMTWCFIAVKBGOD-UHFFFAOYSA-N dioxosilane;methoxy-dimethyl-trimethylsilyloxysilane Chemical compound O=[Si]=O.CO[Si](C)(C)O[Si](C)(C)C AMTWCFIAVKBGOD-UHFFFAOYSA-N 0.000 claims description 5
- 239000003995 emulsifying agent Substances 0.000 claims description 5
- 229920000570 polyether Polymers 0.000 claims description 5
- 229940083037 simethicone Drugs 0.000 claims description 5
- 235000019812 sodium carboxymethyl cellulose Nutrition 0.000 claims description 5
- 229920001027 sodium carboxymethylcellulose Polymers 0.000 claims description 5
- 125000000217 alkyl group Chemical group 0.000 claims description 4
- 150000001412 amines Chemical group 0.000 claims description 4
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 239000004372 Polyvinyl alcohol Substances 0.000 claims description 2
- 229910052731 fluorine Inorganic materials 0.000 claims description 2
- 239000011737 fluorine Substances 0.000 claims description 2
- 229920002451 polyvinyl alcohol Polymers 0.000 claims description 2
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims 1
- ZNZYKNKBJPZETN-WELNAUFTSA-N Dialdehyde 11678 Chemical compound N1C2=CC=CC=C2C2=C1[C@H](C[C@H](/C(=C/O)C(=O)OC)[C@@H](C=C)C=O)NCC2 ZNZYKNKBJPZETN-WELNAUFTSA-N 0.000 claims 1
- YCKRFDGAMUMZLT-UHFFFAOYSA-N Fluorine atom Chemical compound [F] YCKRFDGAMUMZLT-UHFFFAOYSA-N 0.000 claims 1
- DGAQECJNVWCQMB-PUAWFVPOSA-M Ilexoside XXIX Chemical compound C[C@@H]1CC[C@@]2(CC[C@@]3(C(=CC[C@H]4[C@]3(CC[C@@H]5[C@@]4(CC[C@@H](C5(C)C)OS(=O)(=O)[O-])C)C)[C@@H]2[C@]1(C)O)C)C(=O)O[C@H]6[C@@H]([C@H]([C@@H]([C@H](O6)CO)O)O)O.[Na+] DGAQECJNVWCQMB-PUAWFVPOSA-M 0.000 claims 1
- 239000002253 acid Substances 0.000 claims 1
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims 1
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims 1
- 239000012467 final product Substances 0.000 claims 1
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims 1
- 229920006389 polyphenyl polymer Polymers 0.000 claims 1
- 229920002545 silicone oil Polymers 0.000 claims 1
- 239000011734 sodium Substances 0.000 claims 1
- 229910052708 sodium Inorganic materials 0.000 claims 1
- 230000008901 benefit Effects 0.000 abstract description 9
- 238000000034 method Methods 0.000 abstract description 3
- 230000000295 complement effect Effects 0.000 abstract description 2
- 230000003993 interaction Effects 0.000 abstract description 2
- 238000010521 absorption reaction Methods 0.000 abstract 1
- 229940018564 m-phenylenediamine Drugs 0.000 description 20
- WZCQRUWWHSTZEM-UHFFFAOYSA-N 1,3-phenylenediamine Chemical compound NC1=CC=CC(N)=C1 WZCQRUWWHSTZEM-UHFFFAOYSA-N 0.000 description 15
- AIJULSRZWUXGPQ-UHFFFAOYSA-N Methylglyoxal Chemical compound CC(=O)C=O AIJULSRZWUXGPQ-UHFFFAOYSA-N 0.000 description 8
- 239000002994 raw material Substances 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 4
- KKEYFWRCBNTPAC-UHFFFAOYSA-N Terephthalic acid Chemical compound OC(=O)C1=CC=C(C(O)=O)C=C1 KKEYFWRCBNTPAC-UHFFFAOYSA-N 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 229920000728 polyester Polymers 0.000 description 2
- 239000011347 resin Substances 0.000 description 2
- 229920005989 resin Polymers 0.000 description 2
- 238000004088 simulation Methods 0.000 description 2
- PXGOKWXKJXAPGV-UHFFFAOYSA-N Fluorine Chemical compound FF PXGOKWXKJXAPGV-UHFFFAOYSA-N 0.000 description 1
- 229920002292 Nylon 6 Polymers 0.000 description 1
- 229920002302 Nylon 6,6 Polymers 0.000 description 1
- BZHJMEDXRYGGRV-UHFFFAOYSA-N Vinyl chloride Chemical compound ClC=C BZHJMEDXRYGGRV-UHFFFAOYSA-N 0.000 description 1
- 150000001335 aliphatic alkanes Chemical class 0.000 description 1
- 230000008859 change Effects 0.000 description 1
- 239000003795 chemical substances by application Substances 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 150000005690 diesters Chemical class 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 238000004945 emulsification Methods 0.000 description 1
- PCHJSUWPFVWCPO-UHFFFAOYSA-N gold Chemical compound [Au] PCHJSUWPFVWCPO-UHFFFAOYSA-N 0.000 description 1
- 239000010931 gold Substances 0.000 description 1
- 229910052737 gold Inorganic materials 0.000 description 1
- 230000006872 improvement Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920001707 polybutylene terephthalate Polymers 0.000 description 1
- 229920002215 polytrimethylene terephthalate Polymers 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 238000004513 sizing Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 238000006467 substitution reaction Methods 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- A—HUMAN NECESSITIES
- A41—WEARING APPAREL
- A41G—ARTIFICIAL FLOWERS; WIGS; MASKS; FEATHERS
- A41G3/00—Wigs
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F1/00—General methods for the manufacture of artificial filaments or the like
- D01F1/02—Addition of substances to the spinning solution or to the melt
- D01F1/10—Other agents for modifying properties
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/02—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from cellulose, cellulose derivatives, or proteins
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/10—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/12—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyamide as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/14—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one polyester as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/04—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers
- D01F8/16—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from synthetic polymers with at least one other macromolecular compound obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds as constituent
-
- D—TEXTILES; PAPER
- D01—NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
- D01F—CHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
- D01F8/00—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof
- D01F8/18—Conjugated, i.e. bi- or multicomponent, artificial filaments or the like; Manufacture thereof from other substances
Abstract
The invention provides a fiber for wigs and a preparation method thereof. The fiber for wigs prepared by the method reduces the use amount of human hair, uses a composite material, can keep the original advantages of various materials, combines the interaction between different molecules, has complementary advantages, so that the fiber for wigs with excellent performance is obtained, the mechanical strength such as breaking strength, initial modulus and the like is obviously improved, and the fiber has the advantages of high strength, high elasticity and difficult moisture absorption.
Description
Technical field
The invention belongs to hair products technical fields, and in particular to a kind of wig fiber and preparation method thereof.
Background technology
With the raising of economic level development and living standards of the people, wig has become fashion decorations important in the modern life
Product, the whole world is per annual consumption at 150,000 tons or so.With going from strength to strength for hair product industry, human hair material rate is increasingly
It is few, not only supply more and more difficult, and trim labor intensive and time, if moistening if sizing be easy to upset, hair
It is easy wrapped around one another.
And as the raw material of artificial hair, there are acrylic acid series (modified acroleic acid or vinyl chloride etc.), polyamide-based (nylon
6 or nylon66 fiber etc.), Polyester (polyethylene terephthalate or polybutylene terephthalate, polytrimethylene terephthalate
Deng) monofilament.The artificial hair of above-mentioned raw material has both various the strengths and weaknesses, but with polyester, especially poly terephthalic acid
Second diester resin（PET）Have many advantages, such as follows for the artificial hair of raw material, and starts to be widely used in recent years：It is heat-resisting
Property is higher, curly hair is can easily form by curler etc., even if in addition, under conditions of the high temperature and humidity such as balneation, hair washing also
Keep curly hair.These artificial hairs are in addition to the general superior function with chemical fibre, as intensity is high, light, quick-drying washable, bullet
Property is good, is not afraid of the features such as mould moth, brings great convenience to human lives, application in production is also extremely wide, early stage wig
Production all uses PET resin to reel off raw silk from cocoons production, PET wig silks have many advantages, such as it is cheap, process simple, well-pressed, but simulation quality
It is poor, especially burning when formed molten drop adherency cause to burn on the skin, certain occasions using when be restricted.Cause
This, artificial hair product industry need find a kind of new human hair substitution of resources product.
Invention content
The purpose of the invention is to overcome the shortcomings of above-mentioned background technology, a kind of new wig fiber is provided.
To achieve the object of the present invention, wig of the invention fiber includes in-vitro human hair, sodium alginate, composite flame-proof height
Polymers, N- butyl-pyridinium chloride salt ions liquid, composite fortifier, antifoaming agent and organic silicon emulsion stiffening agent.
Preferably, the present invention in, the in-vitro human hair, sodium alginate, composite flame-proof high polymer mass ratio be 1 ~ 3：8~
10：10~12.
In the present invention, the composite flame-proof high polymer is phenolic fibre, polyethylene terephthalate, Flame Vinylon, gathers
The mixture of mpd-i fiber.
Preferably, the phenolic fibre, polyethylene terephthalate, Flame Vinylon, poly
The mass ratio of fiber is 1 ~ 2：2~3：2~3：1~2.
In the present invention, the group of the composite fortifier becomes：Methyl-glyoxal 50 ~ 65%, hydrochloric acid and succinic acid mixture
40 ~ 50%, wherein the volume ratio of hydrochloric acid and succinic acid is 1 in the hydrochloric acid and succinic acid mixture:5.
In the present invention, the antifoaming agent includes the raw material of following parts by weight：28 parts of dimethyl siloxane, polyether-modified silicon
3 parts of oil, 3 parts of silica, 6 parts of emulsifier, 0.5 part of sodium carboxymethylcellulose, 4 parts of butanediol, 76 parts of deionized water.
In the present invention, the preparation method of the antifoaming agent includes the following steps：Number is by dimethyl silica according to the required weight
Alkane, polyether modified silicon oil and silica are added in reaction vessel, are stirred and are heated to 78 DEG C, until solution state is thin
It is greasy, after the little particle that do not suspend, stop stirring, emulsifier, sodium carboxymethylcellulose and deionized water is added, stirs and heats liter
Temperature continues to stir, no layering and floating oil phenomenon uniform to solution state to 85 DEG C, is cooled to room temperature, and addition butanediol continues to stir
It mixes to solution uniformly up to antifoaming agent.
In the present invention, the preparation method of the organic silicon emulsion stiffening agent is：The parts by weight of alkyl quaternary amine are denoted as 3
Part, at 90 DEG C ~ 95 DEG C, the alkyl quaternary amine of 3 parts by weight and suitable water are stirred and evenly mixed in mulser, is obtained transparent equal
Even liquid is cooled to 45 DEG C, and the simethicone emulsion of grain size 5nm ~ 15nm, the fluorine of 25 parts by weight that 25 parts by weight are added change
The polyvinyl alcohol of the simethicone emulsion and 7 parts by weight of property simethicone emulsion and 25 parts by weight grain size 200nm ~ 365nm,
Constant temperature stirs half an hour, is adjusted after pH value to neutrality up to organic silicon emulsion stiffening agent using acetic acid.
The present invention also provides a kind of preparation method of wig fiber, the preparation method is as described below：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3With 15 ~ 25%
AlCl3。
In the present invention, the graded composite metal ion coagulating bath of the twice 8 ~ 14%, refers to that composite metal ion is dense
Spend the twice composite metal ion coagulating bath with appropriate gradient being made of the sequence of low concentration to high concentration, the low concentration
Refer to composite metal ion a concentration of 8 ~ 11%, the high concentration refers to composite metal ion a concentration of 12 ~ 14%.
Compared with prior art, wig of the invention reduces human hair usage amount with fiber, using composite material, and it is various
The advantage that material can keep itself original is combined by the interaction between different molecular, is had complementary advantages, thus acquired
Can superior wig fiber, the mechanical strengths such as fracture strength, initial modulus significantly improve, have intensity it is high, it is high-elastic, be not easy to inhale
The advantage of tide, and the fiber manufacturing process is simple, green non-pollution, the wig being thus prepared has bright, smooth, anti-
It is dirty, light, quick-drying washable, elasticity is good, it is high not to be afraid of performances, the simulation qualities such as mould moth.
Specific implementation mode
In order to make the purpose , technical scheme and advantage of the present invention be clearer, with reference to embodiments, to the present invention
It is further elaborated.It should be appreciated that the specific embodiments described herein are merely illustrative of the present invention, it is not used to
Limit the present invention.As long as in addition, technical characteristic involved in the various embodiments of the present invention described below each other it
Between do not constitute conflict and can be combined with each other.
Embodiment 1：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 1：10：10；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Wherein, composite flame-proof high polymer is phenolic fibre, polyethylene terephthalate, Flame Vinylon, poly- isophthalic diformazan
The mixture of acyl m-phenylene diamine (MPD) fiber, the phenolic fibre, polyethylene terephthalate, Flame Vinylon, it is poly- between phenyl-diformyl
The mass ratio of m-phenylene diamine (MPD) fiber is 1：3：3：1.
Embodiment 2：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 3：8~10：10~12；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Wherein, composite flame-proof high polymer is phenolic fibre, polyethylene terephthalate, Flame Vinylon, poly- isophthalic diformazan
The mixture of acyl m-phenylene diamine (MPD) fiber, the phenolic fibre, polyethylene terephthalate, Flame Vinylon, it is poly- between phenyl-diformyl
The mass ratio of m-phenylene diamine (MPD) fiber is 1：3：3：1.
Embodiment 3：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 2：9：11；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Wherein, composite flame-proof high polymer is phenolic fibre, polyethylene terephthalate, Flame Vinylon, poly- isophthalic diformazan
The mixture of acyl m-phenylene diamine (MPD) fiber, the phenolic fibre, polyethylene terephthalate, Flame Vinylon, it is poly- between phenyl-diformyl
The mass ratio of m-phenylene diamine (MPD) fiber is 1.5：2.5：2.5：2.5.
Embodiment 4：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 2：9：11；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in 33 ~ 9% graded composite metal ion coagulating bath
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
The graded composite metal ion coagulating bath of described 33 ~ 9% refers to composite metal ion concentration by low concentration
The three composite metal ion coagulating baths with appropriate gradient constituted to the sequence of high concentration, the concentration is followed successively by 5%,
7%, 9%.
Embodiment 5：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 2：9：11；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Wherein, composite flame-proof high polymer is phenolic fibre, polyethylene terephthalate, Flame Vinylon, poly- isophthalic diformazan
The mixture of acyl m-phenylene diamine (MPD) fiber, the phenolic fibre, polyethylene terephthalate, Flame Vinylon, it is poly- between phenyl-diformyl
The mass ratio of m-phenylene diamine (MPD) fiber is 1.5：2.5：2.5：2.5.
The group of the composite fortifier becomes：Methyl-glyoxal 50 ~ 65%, hydrochloric acid and succinic acid mixture 40 ~ 50%,
Described in hydrochloric acid and succinic acid mixture the volume ratio of hydrochloric acid and succinic acid be 1:3.
Embodiment 6：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 2：9：11；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Wherein, composite flame-proof high polymer is the mixture of phenolic fibre, polyethylene terephthalate, Flame Vinylon, institute
State phenolic fibre, polyethylene terephthalate, Flame Vinylon mass ratio be 1.5：2.5：2.5.
The group of the composite fortifier becomes：Methyl-glyoxal 50 ~ 65%, hydrochloric acid and succinic acid mixture 40 ~ 50%,
Described in hydrochloric acid and succinic acid mixture the volume ratio of hydrochloric acid and succinic acid be 1:5.
Embodiment 7：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate are cleaned, then baked dry to constant weight, wherein in-vitro human hair, sodium alginate
Mass ratio be 2：9；
（2）By in-vitro human hair, sodium alginate and N- butyl-pyridinium chloride salt ions liquid blendings, composite fortifier is added, 195 ~
Antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Embodiment 8：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 2：11：13；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Embodiment 9：
Wig fiber is prepared as follows：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight, wherein from
Body human hair, sodium alginate, composite flame-proof high polymer mass ratio be 2：9：11；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3, 15 ~ 25%
AlCl3。
Wherein, composite flame-proof high polymer is phenolic fibre, polyethylene terephthalate, Flame Vinylon, poly- isophthalic diformazan
The mixture of acyl m-phenylene diamine (MPD) fiber, the phenolic fibre, polyethylene terephthalate, Flame Vinylon, it is poly- between phenyl-diformyl
The mass ratio of m-phenylene diamine (MPD) fiber is 2：3：3：1.
The group of the composite fortifier becomes：Methyl-glyoxal 50 ~ 65%, hydrochloric acid and succinic acid mixture 40 ~ 50%,
Described in hydrochloric acid and succinic acid mixture the volume ratio of hydrochloric acid and succinic acid be 1:5.
The antifoaming agent includes the raw material of following parts by weight：28 parts of dimethyl siloxane, 3 parts of polyether modified silicon oil, two
3 parts of silica, 6 parts of emulsifier, 0.5 part of sodium carboxymethylcellulose, 4 parts of butanediol, 76 parts of deionized water；The preparation side of antifoaming agent
Method includes the following steps：Dimethyl siloxane, polyether modified silicon oil and silica are added to reaction by number according to the required weight
It in container, stirs and is heated to 78 DEG C, until solution state is fine and smooth, after the little particle that do not suspend, stops stirring, emulsification is added
Agent, sodium carboxymethylcellulose and deionized water stir and are heated to 85 DEG C, and it is uniform to solution state to continue stirring, without point
Layer and floating oil phenomenon are cooled to room temperature, and butanediol is added, and continue stirring to solution uniformly up to antifoaming agent.
The graded composite metal ion coagulating bath of the twice 8 ~ 14% refers to composite metal ion concentration by low concentration
The twice composite metal ion coagulating bath with appropriate gradient constituted to the sequence of high concentration, the low concentration refers to compound gold
It is 8 ~ 11% to belong to ion concentration, and the high concentration refers to composite metal ion a concentration of 12 ~ 14%.
Wig is as follows with fiber effects testing result obtained by above-described embodiment：
As it will be easily appreciated by one skilled in the art that example the above is only the implementation of the present invention, not limiting this hair
It is bright, all within the spirits and principles of the present invention made by all any modification, equivalent and improvement etc., should be included in the present invention
Protection domain within.
Claims (10)
1. a kind of wig fiber, which is characterized in that wig fiber includes in-vitro human hair, sodium alginate, composite flame-proof height
Polymers, N- butyl-pyridinium chloride salt ions liquid, composite fortifier, antifoaming agent and organic silicon emulsion stiffening agent.
2. wig fiber according to claim 1, which is characterized in that the in-vitro human hair, sodium alginate, composite flame-proof
The mass ratio of high polymer is 1 ~ 3：8~10：10~12.
3. wig fiber according to claim 1, which is characterized in that the composite flame-proof high polymer be phenolic fibre,
The mixture of polyethylene terephthalate, Flame Vinylon, Fanglun 1313.
4. wig fiber according to claim 3, which is characterized in that the phenolic fibre, polyphenyl dioctyl phthalate ethylene glycol
Ester, Flame Vinylon, Fanglun 1313 mass ratio be 1 ~ 2：2~3：2~3：1~2.
5. wig fiber according to claim 1, which is characterized in that the group of the composite fortifier becomes：Methyl second
Dialdehyde 50 ~ 65%, hydrochloric acid and succinic acid mixture 40 ~ 50%, wherein hydrochloric acid and fourth two in the hydrochloric acid and succinic acid mixture
The volume ratio of acid is 1:5.
6. wig fiber according to claim 1, which is characterized in that the antifoaming agent includes the original of following parts by weight
Material：28 parts of dimethyl siloxane, 3 parts of polyether modified silicon oil, 3 parts of silica, 6 parts of emulsifier, sodium carboxymethylcellulose 0.5
76 parts of part, 4 parts of butanediol and deionized water.
7. wig fiber according to claim 1, which is characterized in that the preparation method of the antifoaming agent includes following step
Suddenly：Dimethyl siloxane, polyether modified silicon oil and silica are added in reaction vessel by number according to the required weight, and stirring is simultaneously
78 DEG C are heated to, until solution state is fine and smooth, after the little particle that do not suspend, stops stirring, emulsifier, carboxymethyl cellulose is added
Plain sodium and deionized water stir and are heated to 85 DEG C, and it is uniform to solution state to continue stirring, no layering and floating oil phenomenon,
It is cooled to room temperature, butanediol is added, continues stirring to solution uniformly up to antifoaming agent.
8. wig fiber according to claim 1, which is characterized in that the preparation method of the organic silicon emulsion stiffening agent
For：The parts by weight of alkyl quaternary amine are denoted as 3 parts, at 90 DEG C ~ 95 DEG C, the alkyl quaternary amine of 3 parts by weight and suitable
Water stirs and evenly mixs in mulser, obtains the liquid of clear homogeneous, is cooled to 45 DEG C, and grain size 5nm ~ 15nm of 25 parts by weight is added
Simethicone emulsion, 25 parts by weight fluorine richness simethicone emulsion and 25 parts by weight grain size 200nm ~ 365nm two
The polyvinyl alcohol of methyl-silicone oil emulsion and 7 parts by weight, constant temperature stir half an hour, have to obtain the final product after adjusting pH value to neutrality using acetic acid
Machine silicon emulsion stiffening agent.
9. according to the preparation method of any one of the claim 1-8 wig fibers, which is characterized in that the preparation method is as follows
It is described：
（1）In-vitro human hair, sodium alginate, composite flame-proof high polymer are cleaned, then baked dry to constant weight；
（2）By in-vitro human hair, sodium alginate, composite flame-proof high polymer and N- butyl-pyridinium chloride salt ions liquid blendings, it is added multiple
Reinforcing agent is closed, antifoaming agent, vacuum standing and defoaming is added in stirring and dissolving under the conditions of 195 ~ 255 DEG C；
（3）Deaeration is placed in spinning box and is squeezed out at 35 ~ 45 DEG C, in the graded composite metal ion coagulating bath of twice 8 ~ 14%
It is solidified into silk under the conditions of 35 ~ 45 DEG C, the drafting multiple that gradient is solidified into fiber after silk is 4 ~ 5 times, is soaked under the conditions of 28 ~ 35 DEG C
Enter in organic silicon emulsion stiffening agent after 20 ~ 30min, wash, drying is to get wig fiber under the conditions of anxiety, wherein by weight
Percentages are measured, the group of the composite metal ion becomes：50 ~ 70% CaCl2, 15 ~ 25% Al (NO3)3With 15 ~ 25%
AlCl3。
10. the preparation method of wig fiber according to claim 9, which is characterized in that the twice 8 ~ 14%
It is suitable by having of constituting of the sequence of low concentration to high concentration that graded composite metal ion coagulating bath refers to composite metal ion concentration
When the twice composite metal ion coagulating bath of gradient, the low concentration refers to composite metal ion a concentration of 8 ~ 11%, the height
Concentration refers to composite metal ion a concentration of 12 ~ 14%.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810200635.4A CN108330567A (en) | 2018-03-12 | 2018-03-12 | Fiber for wig and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810200635.4A CN108330567A (en) | 2018-03-12 | 2018-03-12 | Fiber for wig and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108330567A true CN108330567A (en) | 2018-07-27 |
Family
ID=62930664
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| Application Number | Title | Priority Date | Filing Date |
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| CN201810200635.4A Withdrawn CN108330567A (en) | 2018-03-12 | 2018-03-12 | Fiber for wig and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113100523A (en) * | 2021-03-31 | 2021-07-13 | 安徽富泰发饰文化股份有限公司 | High-quality condensed water yeast production process |
-
2018
- 2018-03-12 CN CN201810200635.4A patent/CN108330567A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113100523A (en) * | 2021-03-31 | 2021-07-13 | 安徽富泰发饰文化股份有限公司 | High-quality condensed water yeast production process |
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Application publication date: 20180727 |