CN108330494A - Stainless steel high pressure cleaning showers agent and preparation method thereof - Google Patents
Stainless steel high pressure cleaning showers agent and preparation method thereof Download PDFInfo
- Publication number
- CN108330494A CN108330494A CN201711420418.8A CN201711420418A CN108330494A CN 108330494 A CN108330494 A CN 108330494A CN 201711420418 A CN201711420418 A CN 201711420418A CN 108330494 A CN108330494 A CN 108330494A
- Authority
- CN
- China
- Prior art keywords
- stainless steel
- high pressure
- agent
- pressure cleaning
- steel high
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C23—COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
- C23G—CLEANING OR DE-GREASING OF METALLIC MATERIAL BY CHEMICAL METHODS OTHER THAN ELECTROLYSIS
- C23G1/00—Cleaning or pickling metallic material with solutions or molten salts
- C23G1/24—Cleaning or pickling metallic material with solutions or molten salts with neutral solutions
Abstract
A kind of stainless steel high pressure cleaning showers agent and preparation method thereof, wherein stainless steel high pressure cleaning showers agent includes each component of following mass parts：60 parts~80 parts of 3 parts~10 parts of N lauryl imino dipropionic acids sodium salt, 0.05 part~0.2 part of calcium nitrate, 3 parts~10 parts of the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, 10 parts~30 parts of saponification agent, 1 part~5 parts of chelating agent and water.Above-mentioned stainless steel high pressure cleaning showers agent, using each component of mass parts as above, cleaning performance is preferable, without additionally adding cosolvent, without additionally adding antifoaming agent, high/low temperature can be used, i.e., can be used at a temperature of 10 DEG C~80 DEG C, and above-mentioned stainless steel high pressure cleaning showers agent is not easy to be layered during storage and use.
Description
Technical field
The present invention relates to greasy dirt cleaning technique fields, more particularly to a kind of stainless steel high pressure cleaning showers agent and its preparation
Method.
Background technology
Stainless steel increasingly has been favored by people because of its excellent performance.In stainless steel production, process,
Surface often speckles with the greasy dirts such as cutting oil, drawing oil and needs to clean.For surface and oil contaminant is thicker or through a long time placement surface shape
At the workpiece of intractable oil stain, the aqueous cleaning agent of strong basicity is generally used to carry out high pressure spray to stainless steel surface on the market at present
Leaching cleaning.Strong alkaline water based cleaning agent cleaning performance is good, cleaning speed is fast, and stainless steel itself is corrosion-resistant, therefore strong alkaline water
Based cleaning agent will not usually cause any harmful effect to stainless steel surface.But strong alkaline water based cleaning agent is in process for preparation,
It is easy there is a problem of that surfactant and highly basic are incompatible, such as be susceptible to surfactant to analyse under strongly alkaline conditions
Go out to become cotton-shaped problem, so that strong alkaline water based cleaning agent is easy to be layered, to influence to stainless steel surface
Cleaning performance.
Existing strong alkaline water based cleaning agent, it is incompatible and cleaning agent is easy in order to solve surfactant and highly basic
The problem of being layered, it usually needs add a large amount of cosolvent.However after the such cosolvent of addition, not only cleaning is helped not
Greatly, and the cost of cleaning agent can be dramatically increased.
In addition, in high pressure cleaning showers, foam is relatively low when also cleaning agent being required to use.At present on the market frequently with addition
Additional antifoaming agent, such as organosilicon, polyethers antifoaming agent etc. are defoamed.Though organic silicon defoamer defoaming effect is good,
At regular intervals again need to add again, and organic silicon defoamer be easy it is counter stick in workpiece surface, be subsequently not easy to rinse.Polyethers
Antifoaming agent is slightly worse relative to organic silicon defoamer defoaming effect, and generally needs under the high temperature conditions, and ability is precipitated by polyethers
Embody good defoaming effect.
Chinese patent CN1548582A discloses a kind of cold rolled steel special cleaning agent, and key component is non-ionic surface
Activating agent, alkaline compound, chelating agent, solubilizer and solvent；Such cleaning agent need to largely use the increasings such as short-chain alkyl benzene sulfonate
Solvent is just avoided that layering, and cleaning performance is poor under the conditions of high-pressure spraying, and in middle low temperature, (10 degrees Celsius~60 is Celsius
Degree) there are a large amount of foams.Chinese patent CN103937628A discloses a kind of still cleaning showers agent of high alkalinity, main component
It is highly basic, polyethers, surfactant, solubilizer and solvent；Although such cleaning agent is at high temperature (60 degrees Celsius~80 degrees Celsius)
Satisfied cleaning performance is achieved in cleaning process, but still remains the excessive problem of foam in middle low temperature, thus is limited
Its use.
Invention content
Based on this, it is necessary to provide a kind of cleaning performance and preferably, without additional addition cosolvent, without additional addition defoam
The stainless steel high pressure cleaning showers agent and preparation method thereof that agent, high/low temperature can be used and are less prone to layering.
A kind of stainless steel high pressure cleaning showers agent, includes each component of following mass parts：
The agent of stainless steel high pressure cleaning showers includes each component of following mass parts in one of the embodiments,：
The agent of stainless steel high pressure cleaning showers includes each component of following mass parts in one of the embodiments,：
The N- lauryl imino dipropionic acids sodium salt, structural formula are as follows in one of the embodiments,：
The saponification agent is sodium hydroxide, potassium hydroxide, sodium bicarbonate, sodium carbonate, Dan Yi in one of the embodiments,
Hydramine, diethanol amine, triethanolamine, ethylenediamine, propane diamine, diethylamine, di-n-propylamine, (2-hydroxyethyl)methylamine), N- ethyl list second
At least one of hydramine, N- butyl monoethanolamine and N, N- dimethyl monoethanolamine.
The chelating agent is ethylenediamine tetra-acetic acid, edetate, nitrilotriacetic acid in one of the embodiments,
Sodium, diethylene-triamine pentaacetic acid, triethylenetetraaminehexaacetic acid, 1,3- diamino -2- hydroxy propanes-N, N, N ', N '-tetrems
At least one of acid and (1,2- cyclohexanediamine)-tetraacethyl.
In one of the embodiments, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, isomery alcohol carbon
Number is 12~14.
In one of the embodiments, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, polyoxyethylene
Number is 3~10.
In one of the embodiments, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, polyoxypropylene
Number is 3~10.
A kind of preparation method of stainless steel high pressure cleaning showers agent, the stainless steel high pressure cleaning showers agent are as above any
Stainless steel high pressure cleaning showers agent described in embodiment, the preparation method include the following steps：
Saponification agent, chelating agent, calcium nitrate and water are mixed, the first mixed liquor is obtained；
N- lauryl imino dipropionic acids sodium salt and the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene are mixed, obtained
To the second mixed liquor；
First mixed liquor and second mixed liquor are mixed, the stainless steel high pressure cleaning showers agent is obtained.
Above-mentioned stainless steel high pressure cleaning showers agent, by the way that the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene is added,
There is branch so that isomery alcohol is poly- in carbochain in the isomery alcohol groups of the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene
The phenyl end capped polyethers of ethylene oxide polyoxypropylene has good emulsifying capacity to grease, to clean energy with preferable greasy dirt
Power, it is preferable to the cleaning performance of stainless steel surface greasy dirt, and pass through in polyoxypropylene end phenyl end capped so that above-mentioned stainless
The bubble amt generated during steel high pressure cleaning showers agent cleaning use is few, and antifoaming agent is added without additional, so that
Above-mentioned stainless steel high pressure cleaning showers agent is particularly suitable for the high pressure cleaning showers of stainless steel.By the way that N- lauryl imino groups are added
Dipropionic acid sodium salt, the amido in molecular structure has hydrophily, but also there are two hydrophilic carboxylate groups, make it not only
It itself can be dissolved in high alkalinity solution, and can have certain dissolution assistant effect to other nonionic surfactants.Cause
And after N- lauryl imino dipropionic acid sodium salts are added so that without additionally adding it in stainless steel high pressure cleaning showers agent
Its cosolvent, can be so that each component fully dissolves.In addition, N- lauryl imino dipropionic acid sodium salts itself belong to low bubble class
Surfactant, under the conditions of adding a small amount of calcium nitrate, i.e., in 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and nitric acid
When 0.05 part~0.2 part of calcium is used together, the calcium in carboxylate radical and calcium nitrate in N- lauryl imino dipropionic acid sodium salts from
Son generates corresponding calcium soap in the solution, can further decrease the frothing capacity of stainless steel high pressure cleaning showers agent.Moreover, N-
Amido in lauryl imino dipropionic acid sodium salt is not by calcium ion effect, it is thus possible to avoid its corresponding calcium soap from aqueous solution
Middle precipitation so that stainless steel high pressure cleaning showers agent is less prone to layering.In addition, N- lauryl imino dipropionic acid sodium salts belong to
Amphoteric surfactant, 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and 3 parts~10 parts of non-ionic surface active
When the phenyl end capped polyethers of agent isomery alcohol polyoxyethylene polyoxypropylene is used together, N- lauryl imino dipropionic acids sodium salt can be significantly
The cloud point for improving the phenyl end capped polyethers of nonionic surfactant isomery alcohol polyoxyethylene polyoxypropylene, so that stainless steel is high
Press cleaning showers agent that can keep clarification within the scope of very wide temperature, thus under 10 DEG C~80 DEG C of high and low temperature environment
It uses.Also, above-mentioned stainless steel high pressure cleaning showers agent, without additional addition cosolvent, without additional addition antifoaming agent, therefore
Cleaning agent cost can be reduced.
Above-mentioned stainless steel high pressure cleaning showers agent, using each component of mass parts as above, cleaning performance is preferable, without additional
Cosolvent is added, without additional addition antifoaming agent, high/low temperature can be used, i.e., can be used at a temperature of 10 DEG C~80 DEG C,
And above-mentioned stainless steel high pressure cleaning showers agent is not easy to be layered during storage and use.
Description of the drawings
Fig. 1 is the step flow chart of the preparation method of the stainless steel high pressure cleaning showers agent of an embodiment of the present invention.
Specific implementation mode
To facilitate the understanding of the present invention, below with reference to relevant drawings to invention is more fully described.In attached drawing
Give the better embodiment of the present invention.But the present invention can realize in many different forms, however it is not limited to herein
Described embodiment.On the contrary, the purpose of providing these embodiments is that making to understand more the disclosure
Add thorough and comprehensive.Certainly, they are merely examples, and is not intended to limit the present invention.In addition, the present invention can be in difference
Repeat reference numerals and/or letter in example.This repetition is for purposes of simplicity and clarity, itself not indicate to be discussed
Relationship between various embodiments and/or setting.In addition, term " first ", " second " are used for description purposes only, and cannot understand
To indicate or implying relative importance or implicitly indicate the quantity of indicated technical characteristic.Define as a result, " first ",
The feature of " second " can explicitly or implicitly include at least one of the features.Unless otherwise defined, institute used herein
Some technical and scientific terms have the same meaning as commonly understood by one of ordinary skill in the art to which this invention belongs.Institute herein
The term used is intended merely to the purpose of description specific embodiment, it is not intended that in the limitation present invention.It is used herein
Term " and/or " include one or more relevant Listed Items any and all combinations.
For example, a kind of stainless steel high pressure cleaning showers agent, includes each component of following mass parts：
Above-mentioned stainless steel high pressure cleaning showers agent, by the way that the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene is added,
There is branch so that isomery alcohol is poly- in carbochain in the isomery alcohol groups of the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene
The phenyl end capped polyethers of ethylene oxide polyoxypropylene has good emulsifying capacity to grease, to clean energy with preferable greasy dirt
Power, it is preferable to the cleaning performance of stainless steel surface greasy dirt, and pass through in polyoxypropylene end phenyl end capped so that above-mentioned stainless
The bubble amt generated during steel high pressure cleaning showers agent cleaning use is few, adds antifoaming agent without additional so that above-mentioned
Stainless steel high pressure cleaning showers agent is particularly suitable for the high pressure cleaning showers of stainless steel.By the way that N- lauryl imino group dipropyls are added
Acid sodium-salt, the amido in molecular structure have hydrophily, but also there are two hydrophilic carboxylate group, make its not only itself
It can be dissolved in high alkalinity solution, and can have certain dissolution assistant effect to other nonionic surfactants.Thus,
After N- lauryl imino dipropionic acid sodium salts are added so that helped without additional addition others in stainless steel high pressure cleaning showers agent
Solvent, can be so that each component fully dissolves.It lives in addition, N- lauryl imino dipropionic acid sodium salts itself belong to low bubble class surface
Property agent, under the conditions of adding a small amount of calcium nitrate, i.e., in 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and calcium nitrate 0.05
Part~0.2 part when being used together, the calcium ion in carboxylate radical and calcium nitrate in N- lauryl imino dipropionic acid sodium salts is molten
Corresponding calcium soap is generated in liquid, can further decrease the frothing capacity of stainless steel high pressure cleaning showers agent.Moreover, N- lauryls
Amido in dipropionic acid sodium salt is not by calcium ion effect, it is thus possible to its corresponding calcium soap be avoided to be analysed from aqueous solution
Go out so that stainless steel high pressure cleaning showers agent is less prone to layering.In addition, N- lauryl imino dipropionic acid sodium salts belong to both sexes
Surfactant, 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and 3 parts~10 parts of nonionic surfactant are different
When the phenyl end capped polyethers of structure alcohol polyoxyethylene polyoxypropylene is used together, N- lauryl imino dipropionic acids sodium salt can significantly improve
The cloud point of the phenyl end capped polyethers of nonionic surfactant isomery alcohol polyoxyethylene polyoxypropylene, so that stainless steel high pressure spray
Clarification can be kept within the scope of very wide temperature by drenching cleaning agent, thus (10 DEG C~80 DEG C) can make under high and low temperature environment
With.Above-mentioned stainless steel high pressure cleaning showers agent without additional addition antifoaming agent, therefore can be dropped without additional addition cosolvent
Low cleaning agent cost.
Above-mentioned stainless steel high pressure cleaning showers agent, using each component of mass parts as above, cleaning performance is preferable, without additional
Cosolvent is added, without additional addition antifoaming agent, high/low temperature can be used, i.e., can be used at a temperature of 10 DEG C~80 DEG C,
And above-mentioned stainless steel high pressure cleaning showers agent is not easy to be layered during storage and use.
In one embodiment, the saponification agent is sodium hydroxide, potassium hydroxide, sodium bicarbonate, sodium carbonate, monoethanolamine, two
Ethanol amine, triethanolamine, ethylenediamine, propane diamine, diethylamine, di-n-propylamine, (2-hydroxyethyl)methylamine), N- ethyls monoethanolamine, N-
Butyl monoethanolamine and N, at least one of N- dimethyl monoethanolamine.Preferably, the saponification agent is sodium hydroxide and hydrogen
At least one of potassium oxide can further increase stainless steel high pressure cleaning showers agent in this way, having preferable saponification effect
Cleaning performance, and so that the bubble amt that generates is less during use is cleaned in above-mentioned stainless steel high pressure cleaning showers agent.
For another example, the saponification agent is sodium hydroxide and potassium hydroxide, and the mass ratio of the sodium hydroxide and the potassium hydroxide is 1：
(0.82~0.87) can further increase the cleaning of stainless steel high pressure cleaning showers agent in this way, having better saponification effect
Effect, and make the bubble amt generated during above-mentioned stainless steel high pressure cleaning showers agent cleaning use less.For another example, institute
The mass ratio for stating sodium hydroxide and the potassium hydroxide is 1：(0.83~0.85), for another example, the sodium hydroxide and the hydrogen-oxygen
The mass ratio for changing potassium is 1：0.84, in this way, having better saponification effect, stainless steel high pressure cleaning showers can be further increased
The cleaning performance of agent, and make the bubble amt generated during above-mentioned stainless steel high pressure cleaning showers agent cleaning use more
It is few.
In one embodiment, the chelating agent is ethylenediamine tetra-acetic acid, edetate, sodium nitrilo triacetate, two Asias
Ethyl pentaacetic acid, triethylenetetraaminehexaacetic acid, 1,3- diamino -2- hydroxy propanes-N, N, N ', N '-tetraacethyls and (1,
At least one of 2- cyclohexanediamine)-tetraacethyl, the metal ion during chelating agent is used to degrease remains.Preferably, described
Chelating agent is at least one of ethylenediamine tetra-acetic acid, edetate and sodium nitrilo triacetate.In this way, with better
Chelate effect, and the metal ion residual in capable of further degreasing, it is clear can to further increase stainless steel high-pressure spraying
The cleaning performance of lotion, and make the bubble amt generated during above-mentioned stainless steel high pressure cleaning showers agent cleaning use more
It is few.
In one embodiment, the edetate is ethylenediamine tetrem disodium, and the chelating agent is ethylenediamine tetrem
The mass ratio of acid disodium and sodium nitrilo triacetate, the disodium ethylene diamine tetraacetate and the sodium nitrilo triacetate is 1：(0.28
~0.36) the metal ion residual, in this way, having better chelate effect, and in capable of further degreasing, can be into one
Step improves the cleaning performance of stainless steel high pressure cleaning showers agent, and to clean in above-mentioned stainless steel high pressure cleaning showers agent and use
The bubble amt generated in the process is less.For another example, the mass ratio of the disodium ethylene diamine tetraacetate and the sodium nitrilo triacetate
It is 1：(0.29~0.32), for another example, the mass ratio of the disodium ethylene diamine tetraacetate and the sodium nitrilo triacetate is 1：0.31,
In this way, there is better chelate effect, and the metal ion residual in capable of further degreasing, it can further increase not
The cleaning performance of rust steel high pressure cleaning showers agent, and to produce during use is cleaned in above-mentioned stainless steel high pressure cleaning showers agent
Raw bubble amt is less.
In one embodiment, the structural formula of the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene is RO
(CH2CH2O)m(CH2CHCH3O)nC6H5.For another example, R herein is isomery carbochain.For another example, the isomery alcohol polyoxyethylene polyoxy third
In alkene phenyl end capped polyether, isomery alcohol carbon number is 12~14.For another example, the isomery alcohol polyoxyethylene polyoxypropylene is phenyl end capped poly-
In ether, polyoxyethylene (EO) number m is 3~10.For another example, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene,
The number n of polyoxypropylene (PO) is 3~10.It so, it is possible to further increase the cleaning performance of stainless steel high pressure cleaning showers agent,
And make the bubble amt generated during above-mentioned stainless steel high pressure cleaning showers agent cleaning use less.For another example, described different
The phenyl end capped polyethers of structure alcohol polyoxyethylene polyoxypropylene uses to be prepared following preparation method：By isomery under the protection of nitrogen
Alcohol polyoxyethylene poly-oxygen propylene aether is warming up to 100 DEG C~130 DEG C, vacuumizes 1 hour, adds alkaline reagent sodium methoxide, reaction
It 1.5 hours, is further continued for vacuum outgas 1.5 hours, is cooled to 85 DEG C, be slowly added chlorobenzene into reaction kettle, then aging 2 hours~
It 4.5 hours, cools and obtains the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene.Wherein, isomery alcohol polyoxy used
Ethylene polyethenoxy ether, sodium methoxide, chlorobenzene molar ratio be 1:0.05:1.It should be noted that isomery alcohol polyoxyethylene polyoxy
Commercial product may be used in propylene ether.For another example, described to vacuumize until vacuum degree is the pa of 1 pa~100.For another example, described to vacuumize
Either vacuum outgas is to keep vacuum or closing on vacuum in reaction, that is, it is the pa of 1 pa~100 to keep vacuum degree.For another example, vacuum is de-
Gas is to keep vacuum on the basis of 1 pa~100 pa, the gas in abstraction reaction kettle.In this way, using method system produced above
It is standby preferably to prepare the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, keep higher purity and polymerization
Degree, additionally it is possible to further increase the cleaning performance of stainless steel high pressure cleaning showers agent, and make in above-mentioned stainless steel high-pressure spraying
It is less that cleaning agent cleans the bubble amt generated during use.
In one embodiment, the N- lauryl imino dipropionic acids sodium salt, structural formula is as follows：
It so, it is possible to further increase the cleaning performance of stainless steel high pressure cleaning showers agent, and make in above-mentioned stainless steel
It is less that the bubble amt generated during use is cleaned in high pressure cleaning showers agent.It should be noted that N- lauryl imino-diacetics
Commercial product can be used in propionic acid sodium salt.For another example, No. CAS of N- lauryl imino dipropionic acids sodium salt is 14960-06-6.
In one embodiment, stainless steel high pressure cleaning showers agent includes each component of following mass parts：
It so, it is possible to further increase the cleaning performance of stainless steel high pressure cleaning showers agent, and make in above-mentioned stainless steel
It is less that the bubble amt generated during use is cleaned in high pressure cleaning showers agent.
Preferably, the agent of stainless steel high pressure cleaning showers includes each component of following mass parts：
It so, it is possible to further increase the cleaning performance of stainless steel high pressure cleaning showers agent, and make in above-mentioned stainless steel
It is less that the bubble amt generated during use is cleaned in high pressure cleaning showers agent.
In one embodiment, the integral multiple that the mass parts numerical value of N- lauryl imino dipropionic acid sodium salts is in 3~10 0.1,
I.e.：3.1、3.2、3.3、……、9.8、9.9、10.For another example, the integer that the mass parts numerical value of calcium nitrate is in 0.05~0.2 0.01
Times, i.e.,：0.05、0.06、0.07、……、0.19、0.2.For another example, isomery alcohol polyoxyethylene polyoxypropylene phenyl end capped polyethers
The integral multiple that mass parts numerical value is in 3~10 0.1, i.e.,：3.1、3.2、3.3、……、9.8、9.9、10.For another example, the matter of saponification agent
The integral multiple that number value is in 10~30 0.1 is measured, i.e.,：10、10.1、10.2、……、29.8、29.9、30.For another example, chelating agent
The integral multiple that mass parts numerical value is in 1~5 0.1, i.e.,：1、1.1、1.2、……、4.9、5.For another example, the mass parts numerical value of water is 60
0.01 integral multiple in~80, i.e.,：60、60.01、60.02、……、79.98、79.99、80.Certainly, it should be noted that
Each integral multiple of above-mentioned numerical value is only illustrated, and is not that integral multiple also may be used.
Above-mentioned stainless steel high pressure cleaning showers agent, by the way that the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene is added,
There is branch so that isomery alcohol is poly- in carbochain in the isomery alcohol groups of the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene
The phenyl end capped polyethers of ethylene oxide polyoxypropylene has good emulsifying capacity to grease, to clean energy with preferable greasy dirt
Power, it is preferable to the cleaning performance of stainless steel surface greasy dirt, and pass through in polyoxypropylene end phenyl end capped so that above-mentioned stainless
The bubble amt generated during steel high pressure cleaning showers agent cleaning use is few, and antifoaming agent is added without additional, so that
Above-mentioned stainless steel high pressure cleaning showers agent is particularly suitable for the high pressure cleaning showers of stainless steel.By the way that N- lauryl imino groups are added
Dipropionic acid sodium salt, the amido in molecular structure has hydrophily, but also there are two hydrophilic carboxylate groups, make it not only
It itself can be dissolved in high alkalinity solution, and can have certain dissolution assistant effect to other nonionic surfactants.Cause
And after N- lauryl imino dipropionic acid sodium salts are added so that without additionally adding it in stainless steel high pressure cleaning showers agent
Its cosolvent, can be so that each component fully dissolves.In addition, N- lauryl imino dipropionic acid sodium salts itself belong to low bubble class
Surfactant, under the conditions of adding a small amount of calcium nitrate, i.e., in 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and nitric acid
When 0.05 part~0.2 part of calcium is used together, the calcium in carboxylate radical and calcium nitrate in N- lauryl imino dipropionic acid sodium salts from
Son generates corresponding calcium soap in the solution, can further decrease the frothing capacity of stainless steel high pressure cleaning showers agent.Moreover, N-
Amido in lauryl imino dipropionic acid sodium salt is not by calcium ion effect, it is thus possible to avoid its corresponding calcium soap from aqueous solution
Middle precipitation so that stainless steel high pressure cleaning showers agent is less prone to layering.In addition, N- lauryl imino dipropionic acid sodium salts belong to
Amphoteric surfactant, 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and 3 parts~10 parts of non-ionic surface active
When the phenyl end capped polyethers of agent isomery alcohol polyoxyethylene polyoxypropylene is used together, N- lauryl imino dipropionic acids sodium salt can be significantly
The cloud point for improving the phenyl end capped polyethers of nonionic surfactant isomery alcohol polyoxyethylene polyoxypropylene, so that stainless steel is high
Press cleaning showers agent that can keep clarification, thus under high and low temperature environment (10 DEG C~80 DEG C) within the scope of very wide temperature
It uses.Above-mentioned stainless steel high pressure cleaning showers agent, without additional addition cosolvent, without additional addition antifoaming agent, therefore can
Reduce cleaning agent cost.
The present invention also provides a kind of preparation methods of stainless steel high pressure cleaning showers agent, wherein the stainless steel high pressure spray
It is the stainless steel high pressure cleaning showers agent described in any implementation as above to drench cleaning agent.For another example, the preparation method includes as follows
Step：
S110：Saponification agent, chelating agent, calcium nitrate and water are mixed, the first mixed liquor is obtained；
It should be noted that saponification agent, chelating agent, calcium nitrate and water mass parts be stainless steel in any embodiment as above
The corresponding mass parts of correspondence component of high pressure cleaning showers agent.It is for another example, described to mix saponification agent, chelating agent, calcium nitrate and water,
The first mixed liquor is obtained, specially：
Saponification agent, chelating agent, calcium nitrate and water are added in the first reaction kettle and mixed, the first mixed liquor is obtained.In this way,
Saponification agent, chelating agent, calcium nitrate and water are mixed by the first reaction kettle, each component can be enable to mix more abundant.
For another example, described saponification agent, chelating agent, calcium nitrate and water are added in the first reaction kettle mixes, and obtains the first mixed liquor, specifically
For：Saponification agent, chelating agent, calcium nitrate and water are added sequentially to mix in the first reaction kettle, obtain the first mixed liquor.Again
Such as, described to be added sequentially to mix in the first reaction kettle by saponification agent, chelating agent, calcium nitrate and water, obtain the first mixing
Liquid, specially：Saponification agent, chelating agent, calcium nitrate and water are added sequentially to be mixed in the first reaction kettle and carry out first
Secondary stirring operation obtains the first mixed liquor.For another example, the mixing speed of first time stirring operation is 60 turns/min~75 turn/min,
For another example, the mixing time of first time stirring operation is 20 minutes~30 minutes, so, it is possible to make saponification agent, chelating agent, calcium nitrate
Mix more abundant with water.
S120：N- lauryl imino dipropionic acids sodium salt and the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene are mixed
It closes, obtains the second mixed liquor；
For example, the step S120 is specially：N- lauryl imino dipropionic acids sodium salt and isomery alcohol polyoxyethylene are gathered
The phenyl end capped polyethers of oxypropylene, which is added in the second reaction kettle, to be mixed, and the second mixed liquor is obtained；For another example, described that N- lauryls is sub-
Lauriminodipropionate salt and the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene are added in the second reaction kettle and mix, and obtain
Second mixed liquor, specially：N- lauryl imino dipropionic acids sodium salt and isomery alcohol polyoxyethylene polyoxypropylene is phenyl end capped
Polyethers, which is added in the second reaction kettle, mixes and carries out second of stirring operation, obtains the second mixed liquor.For another example, described second
The mixing speed of stirring operation is 60 turns/min~75 turn/min, and for another example, the mixing time of second of stirring operation is 20
Minute~30 minutes, it so, it is possible to make N- lauryl imino dipropionic acids sodium salt and isomery alcohol polyoxyethylene polyoxypropylene phenyl
End capped polyether mixes more abundant.
S130：First mixed liquor and second mixed liquor are mixed, the stainless steel high pressure cleaning showers are obtained
Agent.
For example, the step S130 is specially：The first reaction is added in first mixed liquor and second mixed liquor
It is mixed in kettle, obtains the stainless steel high pressure cleaning showers agent.It is that the second mixed liquor is directly appended to the in concrete operations
It is mixed in first reaction kettle of one mixed liquor.For another example, described that first mixed liquor and second mixed liquor are added
It is mixed in first reaction kettle, obtains the stainless steel high pressure cleaning showers agent, specially：By first mixed liquor and described
Two mixed liquors are added in the first reaction kettle and mix and carry out third time stirring operation, obtain the stainless steel high pressure cleaning showers
Agent.For another example, the mixing speed of the third time stirring operation is 60 turns/min~75 turn/min, for another example, the third time stirring
The mixing time of operation is 20 minutes~30 minutes, so, it is possible preferably to be stirred operation so that the first mixed liquor and the
Two mixed liquors mix more abundant.
The stainless steel high pressure cleaning showers agent that the preparation method of above-mentioned stainless steel high pressure cleaning showers agent is prepared, passes through
Be added the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene it is different
There is branch so that the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene has grease good in carbochain in structure alcohol groups
Good emulsifying capacity, it is preferable to the cleaning performance of stainless steel surface greasy dirt to have preferable greasy dirt cleaning ability, and poly-
Oxypropylene end passes through phenyl end capped so that cleans the foam generated during use in above-mentioned stainless steel high pressure cleaning showers agent
Quantity is few, without additional addition antifoaming agent, so that above-mentioned stainless steel high pressure cleaning showers agent is particularly suitable for stainless steel
High pressure cleaning showers.By the way that N- lauryl imino dipropionic acid sodium salts are added, the amido in molecular structure has hydrophily,
But also there are two hydrophilic carboxylate group, it is set itself can be not only dissolved in high alkalinity solution, but also can be to other
Nonionic surfactant has certain dissolution assistant effect.Thus, after N- lauryl imino dipropionic acid sodium salts are added so that
It, can be so that each component fully dissolves without the other cosolvents of additional addition in stainless steel high pressure cleaning showers agent.In addition, N-
Lauryl imino dipropionic acid sodium salt itself belongs to low bubble class surfactant, under the conditions of adding a small amount of calcium nitrate, i.e., in N-
When 0.05 part~0.2 part of 3 parts~10 parts of lauryl imino dipropionic acid sodium salt and calcium nitrate is used together, N- lauryl imino groups
Carboxylate radical in dipropionic acid sodium salt generates corresponding calcium soap in the solution with the calcium ion in calcium nitrate, can further decrease not
The frothing capacity of rust steel high pressure cleaning showers agent.Moreover, the amido in N- lauryl imino dipropionic acid sodium salts is not by calcium ion
It influences, it is thus possible to avoid its corresponding calcium soap from being precipitated from aqueous solution so that stainless steel high pressure cleaning showers agent is less prone to
Layering.In addition, N- lauryl imino dipropionic acid sodium salts belong to amphoteric surfactant, 3 parts~10 parts of N- lauryl imido
Base dipropionic acid sodium salt and the phenyl end capped polyethers of 3 parts~10 parts of nonionic surfactant isomery alcohol polyoxyethylene polyoxypropylene one
It rises in use, N- lauryl imino dipropionic acids sodium salt can significantly improve nonionic surfactant isomery alcohol polyoxyethylene polyoxy
The cloud point of the phenyl end capped polyethers of propylene, so that the agent of stainless steel high pressure cleaning showers can be kept within the scope of very wide temperature
Clarification, thus (10 DEG C~80 DEG C) can be used under high and low temperature environment.Above-mentioned stainless steel high pressure cleaning showers agent, without additional
Cosolvent is added, without additional addition antifoaming agent, therefore cleaning agent cost can be reduced.
Continue to be explained the present invention with reference to specific embodiment.
Embodiment 1
The agent of stainless steel high pressure cleaning showers is grouped as by each group of following weight in the present embodiment：
Wherein, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, isomery alcohol carbon number is 12-14, polyoxyethylene
(EO) number is 8, and polyoxypropylene (PO) number is 4.
The preparation method of above-mentioned stainless steel high pressure cleaning showers agent is as follows：By sodium hydroxide, EDTA, calcium nitrate and water according to
Above-mentioned weight carries out first time stirring operation after being added sequentially in the first reaction kettle, the time of stirring is 25 minutes for the first time,
The speed of stirring is 70 revs/min for the first time, obtains the first mixed liquor.By N- lauryl imino dipropionic acids sodium salt and isomery alcohol
The phenyl end capped polyethers of polyoxyethylene polyoxypropylene carries out second after being sequentially added in the second reaction kettle according to above-mentioned weight and stirs
Operation, second of mixing time are 25 minutes, and second of mixing speed is 70 revs/min, obtains the second mixed liquor；By gained
Two mixed liquors pour into progress third time stirring operation in the first reaction kettle equipped with the first mixed liquor, and third time stirs 25 minutes,
Third time mixing speed is 70 revs/min to get to stainless steel high pressure cleaning showers agent A.
Embodiment 2
Stainless steel high pressure cleaning showers agent in the present embodiment, includes each component of following mass parts：
Wherein, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, isomery alcohol carbon number is 12-14, polyoxyethylene
(EO) number is 8, and polyoxypropylene (PO) number is 4.
The preparation method of above-mentioned stainless steel high pressure cleaning showers agent is as follows：By sodium hydroxide, EDTA, calcium nitrate and water according to
Above-mentioned weight carries out first time stirring operation after being added sequentially in the first reaction kettle, the time of stirring is 25 minutes for the first time,
The speed of stirring is 70 revs/min for the first time, obtains the first mixed liquor.By N- lauryl imino dipropionic acids sodium salt and isomery alcohol
The phenyl end capped polyethers of polyoxyethylene polyoxypropylene carries out second after being sequentially added in the second reaction kettle according to above-mentioned weight and stirs
Operation, second of mixing time are 25 minutes, and second of mixing speed is 70 revs/min, obtains the second mixed liquor；By gained
Two mixed liquors pour into progress third time stirring operation in the first reaction kettle equipped with the first mixed liquor, and third time stirs 25 minutes,
Third time mixing speed is 70 revs/min to get to stainless steel high pressure cleaning showers agent B.
Embodiment 3
Stainless steel high pressure cleaning showers agent in the present embodiment, includes each component of following mass parts：
Wherein, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, isomery alcohol carbon number is 12-14, polyoxyethylene
(EO) number is 8, and polyoxypropylene (PO) number is 4.
The preparation method of above-mentioned stainless steel high pressure cleaning showers agent is as follows：By sodium hydroxide, EDTA, calcium nitrate and water according to
Above-mentioned weight carries out first time stirring operation after being added sequentially in the first reaction kettle, the time of stirring is 25 minutes for the first time,
The speed of stirring is 70 revs/min for the first time, obtains the first mixed liquor.By N- lauryl imino dipropionic acids sodium salt and isomery alcohol
The phenyl end capped polyethers of polyoxyethylene polyoxypropylene carries out second after being sequentially added in the second reaction kettle according to above-mentioned weight and stirs
Operation, second of mixing time are 25 minutes, and second of mixing speed is 70 revs/min, obtains the second mixed liquor；By gained
Two mixed liquors pour into progress third time stirring operation in the first reaction kettle equipped with the first mixed liquor, and third time stirs 25 minutes,
Third time mixing speed is 70 revs/min to get to stainless steel high pressure cleaning showers agent C.
Comparative example 1
Cleaning agent is grouped as by the group of following weight in this comparative example：
Wherein, in the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene, isomery alcohol carbon number is 12-14, polyoxyethylene
(EO) number is 8, and polyoxypropylene (PO) number is 4.
The preparation method of above-mentioned cleaning agent is as follows：Sodium hydroxide, EDTA and water are added sequentially to according to above-mentioned weight
First time stirring operation is carried out after in one reaction kettle, the time of stirring is 25 minutes for the first time, and the speed of stirring is 70 for the first time
Rev/min, obtain the first mixed liquor.By N- lauryl imino dipropionic acids sodium salt and isomery alcohol polyoxyethylene polyoxypropylene phenyl
End capped polyether carries out second of stirring operation after being sequentially added in the second reaction kettle according to above-mentioned weight, and second of mixing time is
25 minutes, second of mixing speed was 70 revs/min, obtains the second mixed liquor；The second mixed liquor of gained is poured into equipped with first
In first reaction kettle of mixed liquor carry out third time stirring operation, third time stirring 25 minutes, third time mixing speed be 70 turns/
Minute to get to cleaning agent D.
Comparative example 2
This comparative example provides a kind of cleaning agent in the prior art, is grouped as by the group of following weight：
The preparation method of above-mentioned comparative example cleaning agent is as follows：By sodium hydroxide, 1-hydroxy ethylidene-1,1-diphosphonic acid sodium, isopropyl sulfonic acid
Sodium and water are added sequentially to according to above-mentioned weight in the first reaction kettle, are stirred 25 minutes, and speed of agitator is 60 revs/min, then
Ethylene glycol ethyl ether and nonionic surfactant are added, is stirred for 25 minutes, you can obtains this comparative example cleaning agent E.
Comparative example 3
This comparative example provides a kind of cleaning agent in the prior art, is grouped as by the group of following weight：
Sodium hydroxide is first used to the water dissolution of 3000g.Again by BASF XP-80, octyl phosphate sylvite, solubilizer H66,
Hydrophilic polyether, sodium gluconate, triethanolamine, Sodium Polyacrylate are dissolved in the water of 2700g.Above-mentioned gained liquid is poured into hydrogen again
In sodium hydroxide solution, diethylene glycol ether is added after mixing and can be obtained this comparative example cleaning agent F.
Respectively by stainless steel high pressure cleaning showers agent A, stainless steel high pressure cleaning showers agent B, stainless steel high pressure cleaning showers
Agent C, cleaning agent D, cleaning agent E, cleaning agent F carry out cleaning performance test.Test method is as follows：
The stainless steel work-piece that surface is speckled with to greasy dirt, with the agent of stainless steel high pressure cleaning showers or cleaning after 1 to 20 dilution
Agent, respectively at high, normal, basic temperature (80,60,10 DEG C), high pressure (28PSI) cleaning showers 2 minutes, then three times with pure water rinsing,
It places into 120 DEG C of baking ovens and dries 3 minutes, then natural cooling 30 minutes.With No. 40 dynes of pens workpiece surface cross, lines without
Contraction then judges qualification, and it is then unqualified that lines, which are shunk, and counts qualification rate.High pressure pump circulation liquid level after 2 hours is recorded simultaneously
Foam height, test result are as shown in table 1：
1 test result of table
It can be seen from Table 1 that embodiment 1-3 cleaning performances under high/low temperature condition are better than comparative example 2-3.Pass through reality
Example 1 is applied with comparative example 1 as can be seen that the addition of calcium nitrate can significantly reduce the foam height of cleaning agent.Therefore, it can be deduced that：
The present invention the agent of stainless steel high pressure cleaning showers not only cleaning ability is strong, but also its foam is extremely low under high/low temperature condition, have
Very high actual application value.
Above-mentioned stainless steel high pressure cleaning showers agent, by the way that the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene is added,
There is branch so that isomery alcohol is poly- in carbochain in the isomery alcohol groups of the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene
The phenyl end capped polyethers of ethylene oxide polyoxypropylene has good emulsifying capacity to grease, to clean energy with preferable greasy dirt
Power, it is preferable to the cleaning performance of stainless steel surface greasy dirt, and pass through in polyoxypropylene end phenyl end capped so that above-mentioned stainless
The bubble amt generated during steel high pressure cleaning showers agent cleaning use is few, and antifoaming agent is added without additional, so that
Above-mentioned stainless steel high pressure cleaning showers agent is particularly suitable for the high pressure cleaning showers of stainless steel.By the way that N- lauryl imino groups are added
Dipropionic acid sodium salt, the amido in molecular structure has hydrophily, but also there are two hydrophilic carboxylate groups, make it not only
It itself can be dissolved in high alkalinity solution, and can have certain dissolution assistant effect to other nonionic surfactants.Cause
And after N- lauryl imino dipropionic acid sodium salts are added so that without additionally adding it in stainless steel high pressure cleaning showers agent
Its cosolvent, can be so that each component fully dissolves.In addition, N- lauryl imino dipropionic acid sodium salts itself belong to low bubble class
Surfactant, under the conditions of adding a small amount of calcium nitrate, i.e., in 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and nitric acid
When 0.05 part~0.2 part of calcium is used together, the calcium in carboxylate radical and calcium nitrate in N- lauryl imino dipropionic acid sodium salts from
Son generates corresponding calcium soap in the solution, can further decrease the frothing capacity of stainless steel high pressure cleaning showers agent.Moreover, N-
Amido in lauryl imino dipropionic acid sodium salt is not by calcium ion effect, it is thus possible to avoid its corresponding calcium soap from aqueous solution
Middle precipitation so that stainless steel high pressure cleaning showers agent is less prone to layering.In addition, N- lauryl imino dipropionic acid sodium salts belong to
Amphoteric surfactant, 3 parts~10 parts of N- lauryl imino dipropionic acids sodium salt and 3 parts~10 parts of non-ionic surface active
When the phenyl end capped polyethers of agent isomery alcohol polyoxyethylene polyoxypropylene is used together, N- lauryl imino dipropionic acids sodium salt can be significantly
The cloud point for improving the phenyl end capped polyethers of nonionic surfactant isomery alcohol polyoxyethylene polyoxypropylene, so that stainless steel is high
Press cleaning showers agent that can keep clarification, thus under high and low temperature environment (10 DEG C~80 DEG C) within the scope of very wide temperature
It uses.Above-mentioned stainless steel high pressure cleaning showers agent, without additional addition cosolvent, without additional addition antifoaming agent, therefore can
Reduce cleaning agent cost.
Each technical characteristic of embodiment described above can be combined arbitrarily, to keep description succinct, not to above-mentioned reality
It applies all possible combination of each technical characteristic in example to be all described, as long as however, the combination of these technical characteristics is not deposited
In contradiction, it is all considered to be the range of this specification record.It should be noted that " in an embodiment ", " example of the application
Such as ", " for another example ", it is intended to the application is illustrated, rather than for limiting the application.Embodiment described above only table
The several embodiments of the present invention, the description thereof is more specific and detailed have been reached, but can not be therefore interpreted as to patent of invention
The limitation of range.It should be pointed out that for those of ordinary skill in the art, in the premise for not departing from present inventive concept
Under, various modifications and improvements can be made, these are all within the scope of protection of the present invention.Therefore, the protection of patent of the present invention
Range should be determined by the appended claims.
Claims (10)
1. a kind of stainless steel high pressure cleaning showers agent, which is characterized in that include each component of following mass parts：
2. stainless steel high pressure cleaning showers agent according to claim 1, which is characterized in that include each group of following mass parts
Point：
3. stainless steel high pressure cleaning showers agent according to claim 1, which is characterized in that include each group of following mass parts
Point：
4. stainless steel high pressure cleaning showers agent according to claim 1, which is characterized in that the N- lauryls imino-diacetic
The structural formula of propionic acid sodium salt is as follows：
5. stainless steel high pressure cleaning showers agent according to claim 1, which is characterized in that the saponification agent is hydroxide
Sodium, potassium hydroxide, sodium bicarbonate, sodium carbonate, monoethanolamine, diethanol amine, triethanolamine, ethylenediamine, propane diamine, diethylamine,
In di-n-propylamine, (2-hydroxyethyl)methylamine), N- ethyls monoethanolamine, N- butyl monoethanolamine and N, N- dimethyl monoethanolamine extremely
Few one kind.
6. stainless steel high pressure cleaning showers agent according to claim 1, which is characterized in that the chelating agent is ethylenediamine tetraacetic
Acetic acid, edetate, sodium nitrilo triacetate, diethylene-triamine pentaacetic acid, triethylenetetraaminehexaacetic acid, 1,3- bis-
Amino -2- hydroxy propanes-N, N, N ', at least one of N '-tetraacethyls and (1,2- cyclohexanediamine)-tetraacethyl.
7. stainless steel high pressure cleaning showers agent according to claim 1, which is characterized in that the isomery alcohol polyoxyethylene is poly-
In the phenyl end capped polyethers of oxypropylene, isomery alcohol carbon number is 12~14.
8. stainless steel high pressure cleaning showers agent according to claim 7, which is characterized in that the isomery alcohol polyoxyethylene is poly-
In the phenyl end capped polyethers of oxypropylene, polyoxyethylene number is 3~10.
9. stainless steel high pressure cleaning showers agent according to claim 7, which is characterized in that the isomery alcohol polyoxyethylene is poly-
In the phenyl end capped polyethers of oxypropylene, polyoxypropylene number is 3~10.
10. a kind of preparation method of stainless steel high pressure cleaning showers agent, which is characterized in that the stainless steel high pressure cleaning showers agent
For stainless steel high pressure cleaning showers agent as claimed in any one of claims 1-9 wherein, the preparation method includes the following steps：
Saponification agent, chelating agent, calcium nitrate and water are mixed, the first mixed liquor is obtained；
N- lauryl imino dipropionic acids sodium salt and the phenyl end capped polyethers of isomery alcohol polyoxyethylene polyoxypropylene are mixed, obtain the
Two mixed liquors；
First mixed liquor and second mixed liquor are mixed, the stainless steel high pressure cleaning showers agent is obtained.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711420418.8A CN108330494B (en) | 2017-12-25 | 2017-12-25 | Stainless steel high-pressure spray cleaning agent and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711420418.8A CN108330494B (en) | 2017-12-25 | 2017-12-25 | Stainless steel high-pressure spray cleaning agent and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN108330494A true CN108330494A (en) | 2018-07-27 |
| CN108330494B CN108330494B (en) | 2020-03-13 |
Family
ID=62924356
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711420418.8A Active CN108330494B (en) | 2017-12-25 | 2017-12-25 | Stainless steel high-pressure spray cleaning agent and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108330494B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111020611A (en) * | 2019-12-12 | 2020-04-17 | 广东红日星实业有限公司 | Stainless steel spray paraffin removal water and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1548582A (en) * | 2003-05-09 | 2004-11-24 | 上海白猫专用化学品有限公司 | Cleaner specially for cold rolled steel plate |
| JP5284609B2 (en) * | 2007-08-09 | 2013-09-11 | 花王株式会社 | Non-electrolytically cleaned cold-rolled steel sheet detergent composition |
| CN103509473A (en) * | 2012-06-20 | 2014-01-15 | 杭州益满科技有限公司 | Car cleaning and maintenance liquid |
| CN103937628A (en) * | 2014-05-12 | 2014-07-23 | 苏州禾川化学技术服务有限公司 | High-alkalinity non-foaming spraying cleaning agent |
-
2017
- 2017-12-25 CN CN201711420418.8A patent/CN108330494B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1548582A (en) * | 2003-05-09 | 2004-11-24 | 上海白猫专用化学品有限公司 | Cleaner specially for cold rolled steel plate |
| JP5284609B2 (en) * | 2007-08-09 | 2013-09-11 | 花王株式会社 | Non-electrolytically cleaned cold-rolled steel sheet detergent composition |
| CN103509473A (en) * | 2012-06-20 | 2014-01-15 | 杭州益满科技有限公司 | Car cleaning and maintenance liquid |
| CN103937628A (en) * | 2014-05-12 | 2014-07-23 | 苏州禾川化学技术服务有限公司 | High-alkalinity non-foaming spraying cleaning agent |
Non-Patent Citations (1)
| Title |
|---|
| 辛寅昌等: "醚化封端聚醚的研究进展及应用", 《精细与专用化学品》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111020611A (en) * | 2019-12-12 | 2020-04-17 | 广东红日星实业有限公司 | Stainless steel spray paraffin removal water and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN108330494B (en) | 2020-03-13 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| EP2649171B1 (en) | Composition for cleaning of hard surfaces | |
| AU2002257654B2 (en) | Low foaming/defoaming compositions containing alkoxylated quaternary ammonium compounds | |
| JPS6335697A (en) | Low fomable and/or foam control surfactant mixture and its use | |
| CN104245912B (en) | The manufacture method of steel plate alkalis composition | |
| CN102732388B (en) | Special surfactant composition for mixed oil stain cleaning, and preparation method thereof | |
| WO2009069826A1 (en) | Liquid detergent composition | |
| CA2136172A1 (en) | Pumpable alkaline cleaning concentrates | |
| JP2009185252A (en) | Liquid detergent composition | |
| CN105854216B (en) | Aqueous film-forming foam extinguishing agent based on short carbon fluorine chain | |
| JP2007016263A (en) | Detergent composition for copper or copper alloy | |
| CN108330494A (en) | Stainless steel high pressure cleaning showers agent and preparation method thereof | |
| JP2992277B1 (en) | Aqueous liquid cleaner | |
| CA1327932C (en) | Polyethylene glycol ether low temperature foam suppressing agents in low-foam cleaning agents | |
| JP2018505272A5 (en) | ||
| CN109456847A (en) | A kind of cleaning agent, preparation method and application | |
| JP5242656B2 (en) | Cleaning composition | |
| JP4301382B2 (en) | Acid detergent for beer brewing equipment | |
| JP2008150460A (en) | Detergent composition | |
| JPH06346259A (en) | Alkali detergent composition | |
| JP4850455B2 (en) | Detergent composition for metal | |
| TWI401313B (en) | Detergent composition | |
| CN112724050B (en) | Phosphorus-free alkali-resistant solubilizer and preparation and application thereof | |
| CN112126935B (en) | Low-temperature adaptive degreasing agent | |
| JPH05500073A (en) | Use of selected mixtures of polyethylene glycol ethers as foam control aids in low foam cleaning agents | |
| CN112458468B (en) | Spray cleaning agent and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| GR01 | Patent grant | ||
| CP01 | Change in the name or title of a patent holder | ||
| CP01 | Change in the name or title of a patent holder |
Address after: 516100 south of Guangshan highway, niutianling village group, Xinjie village committee, Luoyang Town, BOLUO County, Huizhou City, Guangdong Province Patentee after: Guangdong Dongming New Material Technology Co.,Ltd. Patentee after: BOLUO Dongming New Material Research Institute Address before: 516100 south of Guangshan highway, niutianling village group, Xinjie village committee, Luoyang Town, BOLUO County, Huizhou City, Guangdong Province Patentee before: BO LUO XIAN DOMIN CHEMICAL CO.,LTD. Patentee before: BOLUO Dongming New Material Research Institute |
|
| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20220711 Address after: 516100 south of Guangshan highway, niutianling village group, Xinjie village committee, Luoyang Town, BOLUO County, Huizhou City, Guangdong Province Patentee after: Guangdong Dongming New Material Technology Co.,Ltd. Address before: 516100 south of Guangshan highway, niutianling village group, Xinjie village committee, Luoyang Town, BOLUO County, Huizhou City, Guangdong Province Patentee before: Guangdong Dongming New Material Technology Co.,Ltd. Patentee before: BOLUO Dongming New Material Research Institute |