CN108329630A - A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof - Google Patents

A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof Download PDF

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Publication number
CN108329630A
CN108329630A CN201711408956.5A CN201711408956A CN108329630A CN 108329630 A CN108329630 A CN 108329630A CN 201711408956 A CN201711408956 A CN 201711408956A CN 108329630 A CN108329630 A CN 108329630A
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CN
China
Prior art keywords
parts
aquatic products
preservative film
preparation
antibacterial deodorization
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Pending
Application number
CN201711408956.5A
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Chinese (zh)
Inventor
董如兵
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Hefei Good Teng Plastics Technology Co Ltd
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Hefei Good Teng Plastics Technology Co Ltd
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Priority to CN201711408956.5A priority Critical patent/CN108329630A/en
Publication of CN108329630A publication Critical patent/CN108329630A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J5/00Manufacture of articles or shaped materials containing macromolecular substances
    • C08J5/18Manufacture of films or sheets
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08JWORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2329/00Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Derivatives of such polymer
    • C08J2329/02Homopolymers or copolymers of unsaturated alcohols
    • C08J2329/04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K2201/00Specific properties of additives
    • C08K2201/008Additives improving gas barrier properties
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/005Stabilisers against oxidation, heat, light, ozone
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K5/00Use of organic ingredients
    • C08K5/0008Organic ingredients according to more than one of the "one dot" groups of C08K5/01 - C08K5/59
    • C08K5/0058Biocides

Abstract

The invention discloses a kind of aquatic products antibacterial deodorization preservative films and preparation method thereof.The raw material of the aquatic products antibacterial deodorization preservative film includes by weight:90 110 parts of polyvinyl alcohol, 5 15 parts of purple perilla extracting solution, 25 parts of ginger extract, 25 parts of garlic extract, 13 parts of isoflavones, citric acid 15,35 parts of glycerine, 200 400 parts of deionized water.The preparation method of the aquatic products antibacterial deodorization preservative film includes the following steps:(1) raw material is mixed in proportion;(2) it is cast plastic film mulch;(3) dry;(4) it balances.Preservative film produced by the present invention not only has preferable moisture retention, sterilization antibacterial functions, can slow down the rotten corruption of aquatic products, extend fresh keeping time, but also aquatic products can be made to keep and had better quality and mouthfeel with deodorization.Materials safety is nontoxic, and the Product Green of preparation is degradable, simple production process, is suitble to large-scale industrial production.

Description

A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof
Technical field
The present invention relates to plastic fresh-keeping membranes, and in particular to a kind of aquatic products antibacterial deodorization preservative film and preparation method thereof.
Background technology
Aquatic products delicious meat, protein is high, and minerals are abundant, and fat height is unsaturated, and nutritive value is high, by people Favor.But the water activity that aquatic products often contain is very high, it is easily corrupt, in storage, transport, processing and sales process often It is set to be easy rapid deterioration because of a large amount of proliferation of microorganism, to reduce or lose edible value.Since food borne pathogens are micro- The safety problem of fresh aquatic product caused by eruption point of biology is more and more, seeks new method to inhibit microorganism in the fresh flesh of fish Growth make the preservation of fishery time increase.
The preservation method of traditional aquatic products is Cord blood, cold storing and fresh-keeping or be placed at room temperature for often be unable to reach transport and Storage period needed for sales process, and freeze preservation is in the storage quality for maintaining fish to a certain degree, but cannot after freezing Keep its original fresh state, shape, color and luster and smell etc..Also occurs the side impregnated or coated using antistaling agent at present Method, however on the one hand this method increases technique, it is complicated for operation, it is not appropriate for public use;On the other hand, some chemistry examinations Agent is not totally nontoxic, does not meet the food-safe requirement of people.
Preservative film is to maintain a kind of fresh important measures of food materials, however current preservative film is mostly prepared by polyethylene, Without antibiotic and sterilizing function, while easily fogging is conducive to bacterial reproduction, and cannot degrade and pollute at water droplet.Therefore, it prepares Preservation of fishery can be had a very important significance with antibacterial degradable preservative film.
Invention content
(1) the technical issues of solving
In view of the deficiencies of the prior art, the present invention provides a kind of novel degradable sterilization fresh-keeping film and preparation method thereof, Solve the problems, such as that current preservation of fishery is difficult, preservative film is unable to antibiotic and sterilizing and easily causes environmental pollution, while can be with Deodorization keeps and improves the quality and mouthfeel of aquatic products.
(2) technical solution
To achieve the above object, the present invention provides the following technical solutions:A kind of aquatic products antibacterial deodorization preservative film and its system Preparation Method.
The raw material of the aquatic products antibacterial deodorization preservative film includes by weight:
It is 90-110 parts of polyvinyl alcohol, 5-15 parts of purple perilla extracting solution, 2-5 parts of ginger extract, 2-5 parts of garlic extract, big 1-3 parts of beans isoflavones, 1-5 parts of citric acid, 3-5 parts of glycerine, 200-400 parts of deionized water.
Mainly include the following steps:
(1) raw material is mixed in proportion.
5-15 parts of purple perilla extracting solution, 2-5 parts of ginger extract, 2-5 parts of garlic extract are uniformly mixed, it is different that soybean is added 1-3 parts of flavones, 1-5 parts of citric acid, are uniformly mixed, and form solution A.
200-400 parts of 3-5 parts of glycerine and deionized water are uniformly mixed, are heated to 80-95 DEG C, polyvinyl alcohol 90- is added 110 parts, stirring forms B solution to being completely dissolved.
Solution A is added in B solution, is uniformly mixed to form C solution, ultrasound 2 hours discharge bubble, formed in advance at Film liquid.
(2) the membranae praeformativa liquid vacuum outgas at 80 DEG C that will be prepared in step (1) is cast plastic film mulch.
(3) film for preparing step (2) is dry under the conditions of 80 DEG C;
(4) by the dried film of step (3) in 25 DEG C, humidity be 50% under conditions of balance 24 hours.
Preferably, terpene content is 0.05-0.08% in the purple perilla extracting solution.
Preferably, zingiberol, gingerol total content are 0.05-0.1% in the ginger extract.
Preferably, the content of allicin is 0.05-0.1% in the garlic extract
(3) advantageous effect
The present invention provides a kind of aquatic products antibacterial deodorization preservative films and preparation method thereof, have following advantageous effect:
(1) polyvinyl alcohol in present invention process formula has a large amount of hydroxyl polar group, can be acted on hydrone, Make preservative film produced by the present invention that there is preferable moisture retention, aquatic products is made to keep moisture, it is in good taste.It has good simultaneously Gas barrier acts on, and obstructs aquatic products ingress of air, extends fresh keeping time.
(2) purple perilla extracting solution, ginger extract, garlic extract natural disinfection antibacterial are used in present invention process formula, Anti- spoilage organisms and mould can effectively be inhibited, be a kind of green safe bacteriostatic agent, make preservative film produced by the present invention that there is height The sterilization antibacterial functions of effect.
(3) also had using purple perilla extracting solution, ginger extract, garlic extract, these substances in present invention process formula There is deodorization and carry fresh, so that aquatic products is kept and there is better quality and mouthfeel.
(4) isoflavones is flavonoid antioxidant in present invention process formula, and aquatic products can be inhibited endogenous The growth of the activity of protease and corrupt bacteria microorganism, the long-time for being conducive to aquatic products are fresh-keeping.
(5) raw material is safe and non-toxic in present invention process formula, and the Product Green of preparation is degradable, simple production process, fits Close large-scale industrial production.
(6) specific implementation mode
Below in conjunction with the embodiment of the present invention, technical solution in the embodiment of the present invention is clearly and completely retouched It states, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.Based on the present invention In embodiment, every other implementation obtained by those of ordinary skill in the art without making creative efforts Example, shall fall within the protection scope of the present invention.
Embodiment 1
A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof, aquatic products antibacterial deodorization preservative film by it is following by weight It is prepared by the raw material of part meter:
Aquatic products antibacterial deodorization preservative film preparation process includes:
(1) raw material is mixed in proportion.
By purple perilla extracting solution 5 parts (terpene content is 0.08%), (zingiberol, gingerol total content are 2 parts of ginger extract 0.1%), 2 parts of garlic extract (content of allicin is 0.1%) is uniformly mixed, and 3 parts of isoflavones, citric acid 5 is added Part, it is uniformly mixed, forms solution A.
200 parts of 3 parts of glycerine and deionized water are uniformly mixed, are heated to 80 DEG C, 90 parts of polyvinyl alcohol is added, is stirred to complete Fully dissolved forms B solution.
Solution A is added in B solution, is uniformly mixed to form C solution, ultrasound 2 hours discharge bubble, formed in advance at Film liquid.
(2) the membranae praeformativa liquid vacuum outgas at 80 DEG C that will be prepared in step (1) is cast plastic film mulch.
(3) film for preparing step (2) is dry under the conditions of 80 DEG C;
(4) by the dried film of step (3) in 25 DEG C, humidity be 50% under conditions of balance 24 hours.
The common PE preservative film that aquatic products antibacterial deodorization preservative film made from the implementation case and market are sold compares, and uses It now kills grass carp to test as aquatic products, prepared with the implementation case respectively and common PE preservative film wraps up grass carp, is placed on 4 DEG C of items Under part, it is found that aquatic products antibacterial deodorization preservative film made from the implementation case can effectively inhibit the growth of microorganism or kill micro- Biology can slow down the rotten corruption of aquatic products, extend fresh keeping time, can extend aquatic products relative to common PE preservative film fresh more 8 days periods, and can be with deodorization, mouthfeel is more preferable.And it is safe and non-toxic, it is degradable pollution-free.
Embodiment 2
A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof, aquatic products antibacterial deodorization preservative film by it is following by weight It is prepared by the raw material of part meter:
Aquatic products antibacterial deodorization preservative film preparation process includes:
(1) raw material is mixed in proportion.
By purple perilla extracting solution 10 parts (terpene content is 0.06%), (zingiberol, gingerol total content are 3 parts of ginger extract 0.08%), 3 parts of garlic extract (content of allicin is 0.08%) is uniformly mixed, and 2 parts of isoflavones, citric acid 3 is added Part, it is uniformly mixed, forms solution A.
300 parts of 4 parts of glycerine and deionized water are uniformly mixed, are heated to 80 DEG C, 100 parts of polyvinyl alcohol is added, stirring is extremely It is completely dissolved, forms B solution.
Solution A is added in B solution, is uniformly mixed to form C solution, ultrasound 2 hours discharge bubble, formed in advance at Film liquid.
(2) the membranae praeformativa liquid vacuum outgas at 80 DEG C that will be prepared in step (1) is cast plastic film mulch.
(3) film for preparing step (2) is dry under the conditions of 80 DEG C;
(4) by the dried film of step (3) in 25 DEG C, humidity be 50% under conditions of balance 24 hours.
The common PE preservative film that aquatic products antibacterial deodorization preservative film made from the implementation case and market are sold compares, and uses It now kills grass carp to test as aquatic products, prepared with the implementation case respectively and common PE preservative film wraps up grass carp, is placed on 4 DEG C of items Under part, it is found that aquatic products antibacterial deodorization preservative film made from the implementation case can effectively inhibit the growth of microorganism or kill micro- Biology can slow down the rotten corruption of aquatic products, extend fresh keeping time, can extend aquatic products relative to common PE preservative film fresh more 9 days periods, and can be with deodorization, mouthfeel is more preferable.And it is safe and non-toxic, it is degradable pollution-free.
Embodiment 3
A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof, aquatic products antibacterial deodorization preservative film by it is following by weight It is prepared by the raw material of part meter:
Aquatic products antibacterial deodorization preservative film preparation process includes:
(1) raw material is mixed in proportion.
By purple perilla extracting solution 15 parts (terpene content is 0.05%), (zingiberol, gingerol total content are 2 parts of ginger extract 0.05%), 2 parts of garlic extract (content of allicin is 0.05%) is uniformly mixed, and 1 part of isoflavones, citric acid 1 is added Part, it is uniformly mixed, forms solution A.
400 parts of 5 parts of glycerine and deionized water are uniformly mixed, are heated to 80 DEG C, 110 parts of polyvinyl alcohol is added, stirring is extremely It is completely dissolved, forms B solution.
Solution A is added in B solution, is uniformly mixed to form C solution, ultrasound 2 hours discharge bubble, formed in advance at Film liquid.
(2) the membranae praeformativa liquid vacuum outgas at 80 DEG C that will be prepared in step (1) is cast plastic film mulch.
(3) film for preparing step (2) is dry under the conditions of 80 DEG C;
(4) by the dried film of step (3) in 25 DEG C, humidity be 50% under conditions of balance 24 hours.
The common PE preservative film that aquatic products antibacterial deodorization preservative film made from the implementation case and market are sold compares, and uses It now kills grass carp to test as aquatic products, prepared with the implementation case respectively and common PE preservative film wraps up grass carp, is placed on 4 DEG C of items Under part, it is found that aquatic products antibacterial deodorization preservative film made from the implementation case can effectively inhibit the growth of microorganism or kill micro- Biology can slow down the rotten corruption of aquatic products, extend fresh keeping time, can extend aquatic products relative to common PE preservative film fresh more 8 days periods, and can be with deodorization, mouthfeel is more preferable.And it is safe and non-toxic, it is degradable pollution-free.
It although an embodiment of the present invention has been shown and described, for the ordinary skill in the art, can be with Understanding without departing from the principles and spirit of the present invention can carry out these embodiments a variety of variations, modification, replace And modification, the scope of the present invention is defined by the appended.

Claims (5)

1. a kind of aquatic products antibacterial deodorization preservative film and preparation method thereof, which is characterized in that the aquatic products antibacterial deodorization is fresh-keeping The raw material of film includes by weight:
90-110 parts of polyvinyl alcohol, 5-15 parts of purple perilla extracting solution, 2-5 parts of ginger extract, 2-5 parts of garlic extract, soybean are different 1-3 parts of flavones, 1-5 parts of citric acid, 3-5 parts of glycerine, 200-400 parts of deionized water.
2. a kind of aquatic products antibacterial deodorization preservative film according to claim 1 and preparation method thereof, which is characterized in that including Following steps:
(1) raw material is mixed in proportion.
5-15 parts of purple perilla extracting solution, 2-5 parts of ginger extract, 2-5 parts of garlic extract are uniformly mixed, isoflavones is added 1-3 parts, 1-5 parts of citric acid, are uniformly mixed, and form solution A.
200-400 parts of 3-5 parts of glycerine and deionized water are uniformly mixed, are heated to 80-95 DEG C, polyvinyl alcohol 90-110 is added Part, stirring forms B solution to being completely dissolved.
Solution A is added in B solution, is uniformly mixed to form C solution, 2 hours discharge bubbles of ultrasound form membranae praeformativa Liquid.
(2) the membranae praeformativa liquid vacuum outgas at 80 DEG C that will be prepared in step (1) is cast plastic film mulch.
(3) film for preparing step (2) is dry under the conditions of 80 DEG C;
(4) by the dried film of step (3) in 25 DEG C, humidity be 50% under conditions of balance 24 hours.
3. a kind of aquatic products antibacterial deodorization preservative film according to claim 1 or 2 and preparation method thereof, which is characterized in that Terpene content is 0.05-0.08% in the purple perilla extracting solution.
4. a kind of aquatic products antibacterial deodorization preservative film according to claim 1 or 2 and preparation method thereof, which is characterized in that Zingiberol, gingerol total content are 0.05-0.1% in the ginger extract.
5. a kind of aquatic products antibacterial deodorization preservative film according to claim 1 or 2 and preparation method thereof, which is characterized in that The content of allicin is 0.05-0.1% in the garlic extract.
CN201711408956.5A 2017-12-22 2017-12-22 A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof Pending CN108329630A (en)

Priority Applications (1)

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CN201711408956.5A CN108329630A (en) 2017-12-22 2017-12-22 A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201711408956.5A CN108329630A (en) 2017-12-22 2017-12-22 A kind of aquatic products antibacterial deodorization preservative film and preparation method thereof

Publications (1)

Publication Number Publication Date
CN108329630A true CN108329630A (en) 2018-07-27

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114409971A (en) * 2022-01-20 2022-04-29 浙江艾杰斯生物科技有限公司 Lysozyme composite antibacterial preservative film for food

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN114409971A (en) * 2022-01-20 2022-04-29 浙江艾杰斯生物科技有限公司 Lysozyme composite antibacterial preservative film for food
CN114409971B (en) * 2022-01-20 2022-11-22 浙江艾杰斯生物科技有限公司 Lysozyme composite antibacterial preservative film for food

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Application publication date: 20180727

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