CN108329004A - A kind of red mud base slip casting plugging material - Google Patents
A kind of red mud base slip casting plugging material Download PDFInfo
- Publication number
- CN108329004A CN108329004A CN201810124232.6A CN201810124232A CN108329004A CN 108329004 A CN108329004 A CN 108329004A CN 201810124232 A CN201810124232 A CN 201810124232A CN 108329004 A CN108329004 A CN 108329004A
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- China
- Prior art keywords
- red mud
- slip casting
- plugging material
- base slip
- mud base
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B28/00—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements
- C04B28/14—Compositions of mortars, concrete or artificial stone, containing inorganic binders or the reaction product of an inorganic and an organic binder, e.g. polycarboxylate cements containing calcium sulfate cements
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/70—Grouts, e.g. injection mixtures for cables for prestressed concrete
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2201/00—Mortars, concrete or artificial stone characterised by specific physical values
- C04B2201/50—Mortars, concrete or artificial stone characterised by specific physical values for the mechanical strength
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- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Inorganic Chemistry (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Soil Conditioners And Soil-Stabilizing Materials (AREA)
Abstract
The invention discloses a kind of red mud base slip casting plugging material, percentage, including following components:Red mud 20% 40%, flyash 20% 40% and cement 20% 45%, it is 100% that the sum of said components, which add up,;The rheology component that the red mud base slip casting plugging material further includes the expansion component that additional volume is 0.6% 9% and additional volume is 1.3% 6%;Wherein, the expansion component includes swelling agent and antifoaming agent, and the rheological component includes water-reducing agent and silicon powder.The red mud base slip casting plugging material of the present invention be mainly in the sealing of hole plugging material of coal mine gas, have the advantages that plugging effect is good, block after intensity is high, air-tightness well and later stage self-constriction is less.
Description
Technical field
The invention belongs to plugging material technical field more particularly to a kind of red mud base slip casting plugging materials.
Background technology
Red mud is the waste material of aluminum oxide industry production, and ingredient is extremely complex, generally often produces one ton of aluminium oxide and about produces 1-
1.3 tons of red muds.A large amount of red mud causes people's production and living direct or indirect influence, with the day of red mud quantum of output
The beneficial enhancing increased and people's environmental protection is realized, limits the harm of red mud to greatest extent, and utilization and improvement by all kinds of means is red
Mud is extremely urgent.
It is main problem that current China's coal-bed gas faces that it is too fast that coal bed gas extraction concentration is low, concentration value is decayed.Its
Reason except major part is poor by extraction gas permeability of coal seam, in addition to the agensis of crack, it is most important that sealing of hole is not tight, and sealing quality is paid no attention to
Think, the selection of sealing material is particularly critical, more demanding to air-tightness.
Patent of invention CN201510830990.6 discloses a kind of modified coal mine polyurethane plugging material, and air-tightness is very
Well but since plugging material belongs to high molecular material, expensive, it cannot be quoted extensively, and the present invention uses the materials such as red mud
Expect cheap.Patent of invention CN201710373800.1 discloses a kind of mining ickings base hole-sealing grouting material, although cost
It is more cheap, but sealing material intensity is relatively low, and only 2-3MPa is unable to get good application.Therefore, it is necessary to be directed to coal mine
The plugging material for the requirement exploitation function admirable that gas blocks.
Invention content
The present invention provides that a kind of air-tightness is good, and early strength meets micro-expansibility and price to solve above-mentioned technical problem
Cheap red mud base slip casting plugging material.
The purpose of the present invention is what is realized by following technical scheme:
A kind of red mud base slip casting plugging material, percentage, including following components:Red mud 20%-40%, fine coal
Grey 20%-40% and cement 20%-45%, it is 100% that the sum of said components, which add up,;The red mud base slip casting plugging material
Further include the expansion component that additional volume is 0.6%-9% and the rheology component that additional volume is 1.3%-6%;Wherein, institute
It includes swelling agent and antifoaming agent to state expansion component, and the rheological component includes water-reducing agent and silicon powder.
In said program, the cement includes portland cement 17%-35% and sulphate aluminium cement 3%-10%.
In said program, the volume of the water-reducing agent is 0.3%-1%, and the volume of the silicon powder is 1%-5%.
In said program, the volume of the swelling agent is 0.5%-1%, and the volume of the antifoaming agent is 0.1%-0.5%.
In said program, the expansion component further includes gypsum, and the volume of the gypsum is 2.5%-7.5%.
In said program, the gypsum is the mixed of one or more of anhydrite, the plaster of paris or dihydrate gypsum composition
Close object.
In said program, the unit weight of the red mud base slip casting plugging material is 900kg/m3-1200kg/m3。
In said program, the swelling agent is azodicarbonamide class swelling agent.
In said program, the antifoaming agent is polysiloxane defoaming agent, silicone emulsion antifoaming agent or high-carbon alcohol fatty acid ester
Compound antifoaming agent.
In said program, the water-reducing agent include polycarboxylic-acid or how based water reducer.
Red mud is aluminum oxide industry Bayer process red mud in red mud base slip casting plugging material provided by the invention.
The swelling agent that the present invention uses is a kind of flaxen azo type organic, and main component is azodicarbonamide,
What the present invention selected is such swelling agent of Pu Xin building materials Co., Ltd of Weifang City exploitation, such as HEA-GY models.This swelling agent energy
In cement hydration process, itself constantly decomposes and generate nitrogen to reach expansion effect and nitrogen is produced compared to swelling agents such as aluminium powders
Raw hydrogen is more advantageous to be used safely in gas environment.Existence of the bubble in slurry is similar to air-entraining concrete,
The endurance quality such as resist drying shrinkage of material, anti-carbonation properties etc. can be improved.Because in slurry the presence of bubble with
The fineness of material and the tension of slurry have relationship, so the fineness of red mud can limit the Air Bubble Size and spacing of swelling agent generation
Coefficient, water-reducing agent change the surface tension of slurry, also can preferably regulate and control bubble regime in slurry.Antifoaming agent can also be with expansion
Agent interacts, and removes larger bubbles extra in slurry, leaves behind miniature harmless bubble.
The present invention is based on the principle of alkali-activated carbonatite, the calcium hydroxide that highly basic and hydrated cementitious in red mud provide is made full use of to swash
SiO in hair powder coal ash2And Al2O3, hydrated calcium silicate and drated calcium aluminate are produced, early powerful feature is generated.Red mud has preferable
Water holding bleed performance, the moisture content in slip casting plugging material can be retained, greatly reduce later stage cement self-constriction drying receive
Contracting phenomenon.Red mud itself will not be shunk after drying dehydration.
The interaction of silicon powder and water-reducing agent makes the lubricating action of silicon powder embody out, can enhance slip casting envelope
The fluidity of stifled material, improves sealed borehole length.Silicon powder has also filled up plugging material hole, is formed with hydrolysis product of cement solidifying
Glue enhances plugging material intensity.
The present invention also provides a kind of application methods of red mud base slip casting plugging material:According to said ratio, by silicate
Cement, sulphate aluminium cement, red mud, flyash, expansion component and rheology component uniformly mix, according still further to ratio of water to material 0.6-
0.75:1 ratio calculates water consumption, and water is added uniformly to mix.
Compared with prior art, technical solution provided by the invention has following advantageous effect;
1) present invention uses aluminum oxide industry waste material, and raw material is easy to get, of low cost.
2) the slip casting plugging material intensity that the present invention obtains is high:3d can reach 6MPa, can reach 10MPa within 28 days.
3) the obtained slip casting plugging material good fluidity of the present invention, initial flux degree is up to 340mm, fluidity after 30min
>=260mm, the slip casting plugging material leakproofness that the present invention obtains is good, air permeability coefficient≤2 × 10-8m2。
4) present invention has early strong, high-strength feature.
5) slip casting plugging material of the present invention has microdilatancy, later stage shrinkage-free feature.
Specific implementation mode
With reference to embodiment, the present invention is further explained.
Embodiment 1
The present embodiment provides a kind of red mud base slip casting plugging material, raw materials:Red mud 2kg, flyash 4kg, PO42.5 are general
Silicon cement 3.5kg, sulphate aluminium cement 0.5kg, swelling agent 0.5%, gypsum 2.5%, antifoaming agent 0.1%, water-reducing agent 0.4%,
Silicon powder 3%, institute's water requirement are 7kg.
A, all solid raw materials are proportionally added blender and are uniformly mixed.
B, water-reducing agent is added to the water uniform mixing.
C, blender is added water to stir 3 minutes.
Initial flow degree 350mm, fluidity 320mm after 30 minutes;3d intensity 5.3MPa, 28d intensity 7MPa;Air penetration
Coefficient 1 × 10-8m2, the vertical expansion rates of 3d 0.5%.
Embodiment 2
The present embodiment provides a kind of red mud base slip casting plugging material, raw materials:Red mud 4kg, flyash 2kg, PO42.5 are general
Logical portland cement 3.5kg, sulphate aluminium cement 0.5kg, swelling agent 0.5%, gypsum 5%, antifoaming agent 0.2%, water-reducing agent
0.5%, silicon powder 3%, institute's water requirement is 6.6kg.
A, all solid raw materials are proportionally added blender and are uniformly mixed.
B, it weighs water-reducing agent to be added to the water, uniformly mix.
C, mixed water is proportionally added into uniformly mixed siccative, is then stirred.
Initial flow degree 342mm, fluidity 300mm after 30 minutes;3d intensity 5.7MPa, 28d intensity 8MPa;Air penetration
Coefficient 3.2 × 10-8m2, vertical expansion rate 0.8%.
Embodiment 3
The present embodiment provides a kind of red mud base slip casting plugging material, raw materials:Red mud 3kg, flyash 3kg, PO42.5 are general
Silicon cement 3.2kg, sulphate aluminium cement 0.8kg, swelling agent 0.7%, gypsum 7%, antifoaming agent 0.3%, water-reducing agent 0.5%, silicon
Micro mist 5%, water 6.5kg.
A, all solid raw materials are proportionally added blender and are uniformly mixed.
B, it weighs water-reducing agent to be added to the water, be uniformly mixed.
C, mixed water is added in powder, is then stirred.
Initial flow degree 300mm, fluidity 260mm after 30 minutes;3d intensity 5.6MPa, 28d intensity 7.5MPa;Air oozes
Saturating coefficient 3 × 10-8m2, vertical expansion rate 0.8%.
The embodiment of the present invention is described above, but the invention is not limited in above-mentioned specific embodiment parties
Formula, the above mentioned embodiment is only schematical, rather than restrictive, and those skilled in the art are in this hair
Under bright enlightenment, without breaking away from the scope protected by the purposes and claims of the present invention, many forms can be also made, this
It is a little to belong within the protection of the present invention.
Claims (10)
1. a kind of red mud base slip casting plugging material, which is characterized in that percentage, including following components:Red mud 20%-
40%, flyash 20%-40% and cement 20%-45%, it is 100% that the sum of said components, which add up,;The red mud base slip casting
The rheology component that plugging material further includes the expansion component that additional volume is 0.6%-9% and additional volume is 1.3%-6%;
Wherein, the expansion component includes swelling agent and antifoaming agent, and the rheological component includes water-reducing agent and silicon powder.
2. red mud base slip casting plugging material according to claim 1, which is characterized in that the cement includes portland cement
17%-35% and sulphate aluminium cement 3%-10%.
3. red mud base slip casting plugging material according to claim 1, which is characterized in that the volume of the water-reducing agent is
The volume of 0.3%-1%, the silicon powder are 1%-5%.
4. red mud base slip casting plugging material according to claim 1, which is characterized in that the volume of the swelling agent is
The volume of 0.5%-1%, the antifoaming agent are 0.1%-0.5%.
5. red mud base slip casting plugging material according to claim 4, which is characterized in that the expansion component further includes stone
The volume of cream, the gypsum is 2.5%-7.5%.
6. red mud base slip casting plugging material according to claim 5, which is characterized in that the gypsum is anhydrite, ripe stone
The mixture of one or more of cream or dihydrate gypsum composition.
7. red mud base slip casting plugging material according to claim 1, which is characterized in that the red mud base slip casting plugging material
Unit weight be 900kg/m3-1200kg/m3。
8. red mud base slip casting plugging material according to claim 1, which is characterized in that the swelling agent is two formyl of azo
Amine swelling agent.
9. red mud base slip casting plugging material according to claim 1, which is characterized in that the antifoaming agent disappears for polysiloxanes
Infusion, silicone emulsion antifoaming agent or the fatty acid ester compounded object antifoaming agent of higher alcohols.
10. red mud base slip casting plugging material according to claim 1, which is characterized in that the water-reducing agent includes polycarboxylic acids
System or how based water reducer.
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CN201810124232.6A CN108329004B (en) | 2018-02-07 | 2018-02-07 | Red mud-based grouting plugging material |
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CN201810124232.6A CN108329004B (en) | 2018-02-07 | 2018-02-07 | Red mud-based grouting plugging material |
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CN108329004A true CN108329004A (en) | 2018-07-27 |
CN108329004B CN108329004B (en) | 2020-01-14 |
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Cited By (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109867492A (en) * | 2019-04-08 | 2019-06-11 | 嘉科吉地(北京)环保材料研究院有限公司 | One kind turns waste into wealth injecting paste material |
CN110028256A (en) * | 2019-04-24 | 2019-07-19 | 山东大学 | A kind of red mud base one-step method geopolymer injecting paste material and preparation method thereof |
CN111072335A (en) * | 2018-10-19 | 2020-04-28 | 南京化学工业园环保产业协同创新有限公司 | Inorganic grouting plugging material |
CN111153672A (en) * | 2020-01-16 | 2020-05-15 | 阳泉煤业(集团)有限责任公司 | Hole sealing material for coal mine gas drainage hole and application thereof |
CN112110687A (en) * | 2020-09-12 | 2020-12-22 | 六枝特区华兴管业制品有限公司 | Gas plugging agent made of inorganic material and preparation and use methods thereof |
CN112250384A (en) * | 2020-10-20 | 2021-01-22 | 陕西煤业化工技术研究院有限责任公司 | High-expansion quick-setting inorganic mining hole sealing material and preparation method thereof |
CN112500056A (en) * | 2020-12-10 | 2021-03-16 | 华北水利水电大学 | Superfine solid waste base grouting material and preparation method thereof |
CN113087474A (en) * | 2021-04-17 | 2021-07-09 | 中冶地集团西北岩土工程有限公司 | Inorganic grouting plugging material and preparation method thereof |
CN115180913A (en) * | 2022-08-01 | 2022-10-14 | 合肥工业大学 | Expansion type full-tailing filling material for top filling of mine goaf |
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CN106927766A (en) * | 2017-04-01 | 2017-07-07 | 东南大学 | The grouting material of prefabricated components energy dissipation node |
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CN102503310A (en) * | 2011-11-07 | 2012-06-20 | 西南交通大学 | Super-high early-strength grouting material for repairing ballastless track structure of high speed railway |
US20140374948A1 (en) * | 2011-12-01 | 2014-12-25 | W.R. Grace & Co.-Conn. | Composition and Method for Obtaining Exposed Aggregates in Surfaces of Moulded Concrete And Other Cementitious Materials |
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Cited By (12)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN111072335A (en) * | 2018-10-19 | 2020-04-28 | 南京化学工业园环保产业协同创新有限公司 | Inorganic grouting plugging material |
CN109867492A (en) * | 2019-04-08 | 2019-06-11 | 嘉科吉地(北京)环保材料研究院有限公司 | One kind turns waste into wealth injecting paste material |
CN109867492B (en) * | 2019-04-08 | 2021-08-24 | 洛阳同道泥砼新材料研究院有限公司 | Grouting material for coal mine grouting |
CN110028256A (en) * | 2019-04-24 | 2019-07-19 | 山东大学 | A kind of red mud base one-step method geopolymer injecting paste material and preparation method thereof |
CN111153672A (en) * | 2020-01-16 | 2020-05-15 | 阳泉煤业(集团)有限责任公司 | Hole sealing material for coal mine gas drainage hole and application thereof |
CN112110687A (en) * | 2020-09-12 | 2020-12-22 | 六枝特区华兴管业制品有限公司 | Gas plugging agent made of inorganic material and preparation and use methods thereof |
CN112250384A (en) * | 2020-10-20 | 2021-01-22 | 陕西煤业化工技术研究院有限责任公司 | High-expansion quick-setting inorganic mining hole sealing material and preparation method thereof |
CN112500056A (en) * | 2020-12-10 | 2021-03-16 | 华北水利水电大学 | Superfine solid waste base grouting material and preparation method thereof |
CN112500056B (en) * | 2020-12-10 | 2022-07-08 | 华北水利水电大学 | Superfine solid waste base grouting material and preparation method thereof |
CN113087474A (en) * | 2021-04-17 | 2021-07-09 | 中冶地集团西北岩土工程有限公司 | Inorganic grouting plugging material and preparation method thereof |
CN115180913A (en) * | 2022-08-01 | 2022-10-14 | 合肥工业大学 | Expansion type full-tailing filling material for top filling of mine goaf |
CN115180913B (en) * | 2022-08-01 | 2023-08-22 | 合肥工业大学 | Expansion type full tailing filling material for mine goaf roof filling |
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