CN108328889A - A kind of cold rolling wastewater dregs of fat innocuity disposal system and method - Google Patents

A kind of cold rolling wastewater dregs of fat innocuity disposal system and method Download PDF

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Publication number
CN108328889A
CN108328889A CN201810168742.3A CN201810168742A CN108328889A CN 108328889 A CN108328889 A CN 108328889A CN 201810168742 A CN201810168742 A CN 201810168742A CN 108328889 A CN108328889 A CN 108328889A
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Prior art keywords
sludge
dregs
fat
cold rolling
anaerobic
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CN201810168742.3A
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CN108328889B (en
Inventor
陆正华
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Baowu Water Technology Co Ltd
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Baosteel Engineering and Technology Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • C02F11/02Biological treatment
    • C02F11/04Anaerobic treatment; Production of methane by such processes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F11/00Treatment of sludge; Devices therefor
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F3/00Biological treatment of water, waste water, or sewage
    • C02F3/02Aerobic processes
    • C02F3/12Activated sludge processes
    • C02F3/1236Particular type of activated sludge installations
    • C02F3/1263Sequencing batch reactors [SBR]
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2103/00Nature of the water, waste water, sewage or sludge to be treated
    • C02F2103/16Nature of the water, waste water, sewage or sludge to be treated from metallurgical processes, i.e. from the production, refining or treatment of metals, e.g. galvanic wastes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2303/00Specific treatment goals
    • C02F2303/06Sludge reduction, e.g. by lysis
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02WCLIMATE CHANGE MITIGATION TECHNOLOGIES RELATED TO WASTEWATER TREATMENT OR WASTE MANAGEMENT
    • Y02W10/00Technologies for wastewater treatment
    • Y02W10/10Biological treatment of water, waste water, or sewage

Abstract

The invention discloses a kind of dregs of fat innocuity disposal system and its methods.System includes anaerobic reaction slot, muddy water mixing channel, SBR biochemistry pools and effluent trough;Thermophilic oily bacterium is inoculated in anaerobic reaction slot, anaerobic reaction slot is connected to muddy water mixing channel by pipeline, and muddy water mixing channel is connected to by overflow manner with SBR biochemistry pools, and the water outlet of SBR biochemistry pools is located at top, which is connected to by pipeline with effluent trough;Effluent trough is provided with discharge outlet and the cycle mouth of a river, and the cycle mouth of a river is connected to by circulation pipe with the muddy water mixing channel.Processing method of the present invention is to carry out anaerobic digestion to dregs of fat sludge by obligate thermophilic oily bacterium using special anaerobic pond, sludge through Anaerobic Treatment is using the further resolution process of biochemical aerobic process, finally oil content in sludge is made to decompose completely, and remaining in the sludge after stabilizing inorganic point can be used as the Demulsification and coagulant process section recycling that demulsifier is back to again before air-float technology.

Description

A kind of cold rolling wastewater dregs of fat innocuity disposal system and method
Technical field
The invention belongs to cold rolling wastewater dregs of fat dangerous waste processing technology fields, and in particular to a kind of cold rolling wastewater dregs of fat are innoxious Processing system and method.
Background technology
Cold rolling oil-containing waste water treatment process often uses air supporting or ceramic membrane ultrafitration as pretreating process in steel industry Then most of oil emulsion removal in waste water is subjected to biochemical treatment again, wherein no matter using air-float technology or ceramic membrane ultrafitration Technique can all generate dregs of fat sludge, and the mud cake generated after these dregs of fat sludge dewaterings at present is needed according to environmental requirement as dangerous Waste is disposed, and cost of disposal is higher, and is had greater environmental impacts.
Invention content
For deficiencies of the prior art, stable, cost that the purpose of the present invention is to provide a kind for the treatment of effects Low and environmental-friendly cold rolling wastewater dregs of fat innocuity disposal system and method.
To achieve the goals above, the technical solution adopted by the present invention is as follows:
A kind of cold rolling wastewater dregs of fat innocuity disposal system, including anaerobic reaction slot, muddy water mixing channel, SBR biochemistry pools and Effluent trough;Thermophilic oily bacterium is inoculated in the anaerobic reaction slot, the anaerobic reaction slot is connected to muddy water mixing channel by pipeline, The muddy water mixing channel is connected to by overflow manner with the SBR biochemistry pools, and the water outlet of the SBR biochemistry pools is located at top, The water outlet is connected to by pipeline with the effluent trough;The effluent trough is provided with discharge outlet and the cycle mouth of a river, the recirculated water Mouth is connected to by circulation pipe with the muddy water mixing channel.
Further, further include regeneration sludge slot, the mud inlet of the regeneration sludge slot is biochemical by sludge pipe and the SBR The bottom in pond is connected to, and the lower part of the regeneration sludge slot is also communicated with sludge pipe, for regeneration sludge to be discharged, so that cycle makes With.
Further, it is equipped with heating device and the first temperature monitor in the anaerobic reaction slot, described detests for controlling Oxygen reaction tank interior reaction temperature is between 28-30 DEG C.
Further, pPH detectors are provided in the anaerobic reation pool, for controlling PHpH in the anaerobic reation pool Between 7.0-7.5.
Further, it is provided with mixed stirring device in the muddy water mixing channel.
Further, the SBR biochemistry pools bottom is provided with the first aerator, the oxygen for providing aerobic biochemical reaction Gas.
Further, the SBR biochemistry pools bottom is provided with dissolved oxygen detector, and aeration quantity is adjusted for detecting.
Further, the SBR biochemistry pools are equipped with heating device and second temperature detector, are reacted for controlling in pond Temperature is between 28-30 DEG C.
Further, the regeneration sludge trench bottom is provided with the second aerator, for providing the regeneration sludge Required oxygen.
A kind of cold rolling wastewater dregs of fat method for innocent treatment is based on above-mentioned cold rolling wastewater dregs of fat innocuity disposal system, packet Include following steps:
1) after the cold rolling wastewater dregs of fat enter anaerobic reaction slot, the oil in the dregs of fat is reacted in the anaerobic digestion of thermophilic oily microorganism To decomposition;The anaerobic reaction slot interior reaction temperature control is between 30-35 DEG C, and PH is controlled between 7.0-7.5, entire anaerobism The digestion reaction time was at 10-15 days.
2) sludge after anaerobic digestion is mixed by being pumped into be mixed to get with the recirculation water of effluent trough in muddy water mixing channel Mud waste water.
3) the mixing sludge waste water gravity described in, which flows into, carries out biology aerobic decomposition, the biochemistry pool in SBR biochemistry pools Interior reaction temperature control is adjusted aeration quantity between 28-30 DEG C, while by dissolved oxygen meter;The aerobic reaction time exists Between 10-12 hours.
4) supernatant enters in effluent trough after the mixture mud waste water described in is stablized, and passes through the adjusting of pumped back waste water station Pond, and oil content has been decomposed the sludge finished by being pumped into sludge regeneration tank after stablizing.
5) regeneration sludge slot is equipped with blast aerator, and the regeneration tank reaction time is 3-5 days, and the sludge after regeneration is as broken Emulsion recycles, and Demulsification and coagulant reaction, warp are carried out to cold rolling oil-containing waste water by the pretreatment unit of conveying pumped back waste water station The dregs of fat are formed again after air supporting reaction returns to present treatment system.
Compared with prior art, the present invention has the advantages that:
1, solve the dregs of fat that are generated in existing steel industry cold rolling wastewater processing procedure as hazardous waste need it is high at The problem of being handled outside this committee realizes internal resourceization cycle, substantially reduces processing cost.
2, any medicament is not added, it is environmentally friendly, do not generate secondary pollution.
3, the sludge residue after stabilizing can be used as demulsifier and reuse, and reduce cost for wastewater treatment.
4, system run all right, easy to operate.
Description of the drawings
Fig. 1 is technological process and the structural schematic diagram of the present invention.
In attached drawing:1-anaerobic reaction slot;11-pH detectors;12-the first temperature monitor;2-muddy water mixing channels; 21-mixed stirring devices;3-SBR biochemistry pools;31-dissolved oxygen detectors;32-second temperature detectors;33-the first aeration Device;4-effluent troughs;5-regeneration sludge slots;51-the second aerator;61-delivery pumps;62-sludge recovery pumps;63— Water circulating pump.
Specific implementation mode
With reference to specific embodiment, invention is further described in detail.
A kind of cold rolling wastewater dregs of fat innocuity disposal system, including anaerobic reaction slot 1, muddy water mixing channel 2, SBR biochemistry pools With effluent trough 3;Thermophilic oily bacterium is inoculated in the anaerobic reaction slot 1, the anaerobic reaction slot 1 and muddy water mixing channel 2 pass through pipe Road is connected to, and the muddy water mixing channel 2 is connected to by overflow manner with the SBR biochemistry pools 3, the water outlet of the SBR biochemistry pools 3 Positioned at top, which is connected to by pipeline with the effluent trough 4;The effluent trough 4 is provided with discharge outlet and the cycle mouth of a river, The cycle mouth of a river is connected to by circulation pipe with the muddy water mixing channel 2.
Further include regeneration sludge slot 5, the mud inlet of the regeneration sludge slot 5 passes through sludge pipe and the SBR biochemistry pools 3 Bottom is connected to, and the lower part of the regeneration sludge slot 5 is also communicated with sludge pipe, for regeneration sludge to be discharged, for recycling.
In order to make this more optimized stable operation of set system, it is equipped with simultaneously equipped with heating device in the anaerobic reaction slot 2 First temperature monitor 12, for controlling the anaerobic reation pool interior reaction temperature between 28-30 DEG C.The anaerobic reaction PH detectors 11 are provided in pond, for controlling in the anaerobic reation pool PH between 7.0-7.5.The muddy water mixing channel Mixed stirring device 21 is provided in 2.3, the SBR biochemistry pools bottom is provided with the first aerator 33, aerobic for providing The oxygen of biochemical reaction.3 bottom of SBR biochemistry pools is provided with dissolved oxygen detector 31, and aeration quantity is adjusted for detecting.It is described SBR biochemistry pools 5 be equipped with heating device simultaneously be equipped with second temperature detector 32, for controlling pond interior reaction temperature in 28-30 Between DEG C.5 bottom of regeneration sludge slot is provided with the second aerator 51, for providing the regeneration sludge requisite oxygen Gas.
Have enough pressure heads in transmission process in order to ensure waterpower, the anaerobic reaction slot 1 and muddy water mixing channel 2 it Between pipeline on be provided with delivery pump 61, sludge recovery pump 62 is provided on the sludge pipe, is arranged on the circulation pipe There is water circulating pump 63.
Based on the processing method of above-mentioned cold rolling wastewater dregs of fat innocuity disposal system, including following processing step:
1) after the cold rolling wastewater dregs of fat enter anaerobic reaction slot 1, the oil in the dregs of fat is reacted in the anaerobic digestion of thermophilic oily microorganism It is decomposed;1 interior reaction temperature of the anaerobic reaction slot control is between 30-35 DEG C, and PH is controlled between 7.0-7.5, entirely The anaerobic digestion reaction time was at 10-15 days;
2) sludge after anaerobic digestion is mixed by being pumped into be mixed to get with the recirculation water of effluent trough in muddy water mixing channel 2 Mud waste water;
3) the mixing sludge waste water gravity described in, which flows into, carries out biology aerobic decomposition, the biochemistry pool in SBR biochemistry pools 3 Interior reaction temperature control is adjusted aeration quantity between 28-30 DEG C, while by dissolved oxygen meter;The aerobic reaction time exists Between 10-12 hours;
4) supernatant enters in effluent trough 4 after the mixture mud waste water described in is stablized, and passes through the tune of pumped back waste water station Pond is saved, and oil content has been decomposed the sludge finished by being pumped into sludge regeneration tank 5 after stablizing;
5) regeneration sludge slot 5 is equipped with blast aerator, and 5 reaction time of regeneration tank is 3-5 days, the sludge conduct after regeneration Demulsifier reuse carries out Demulsification and coagulant reaction, through gas by the pretreatment unit of conveying pumped back waste water station to cold rolling oil-containing waste water The dregs of fat are formed again after floating reaction returns to present treatment system.
Treatment effect of the present invention is stablized, not only can be by the oily substance harmlessness disposing in the dregs of fat, moreover it is possible to will finally generate Inorganic point of sludge recycling and front end waster water process, the process method equipment automation mechanized operation degree is high, operation operation It is easy.
In whole processing technology, the control process of each process section is automatically performed by PLC, without adding any other medicine Agent.
The above embodiment of the present invention is only example to illustrate the invention, and is not the implementation to the present invention The restriction of mode.For those of ordinary skill in the art, other can also be made not on the basis of the above description With the variation and variation of form.Here all embodiments can not be exhaustive.It is every to belong to technical scheme of the present invention Row of the changes and variations that derived from still in protection scope of the present invention.

Claims (10)

1. a kind of cold rolling wastewater dregs of fat innocuity disposal system, which is characterized in that including anaerobic reaction slot, muddy water mixing channel, SBR Biochemistry pool and effluent trough;Thermophilic oily bacterium is inoculated in the anaerobic reaction slot, the anaerobic reaction slot and muddy water mixing channel pass through Pipeline is connected to, and the muddy water mixing channel is connected to by overflow manner with the SBR biochemistry pools, the water outlet of the SBR biochemistry pools Positioned at top, which is connected to by pipeline with the effluent trough;The effluent trough is provided with discharge outlet and the cycle mouth of a river, institute The cycle mouth of a river is stated to be connected to the muddy water mixing channel by circulation pipe.
2. cold rolling wastewater dregs of fat innocuity disposal system as described in claim 1, which is characterized in that further include regeneration sludge The mud inlet of slot, the regeneration sludge slot is connected to by sludge pipe with the bottom of the SBR biochemistry pools, the regeneration sludge slot Lower part is also communicated with sludge pipe, for regeneration sludge to be discharged, for recycling.
3. cold rolling wastewater dregs of fat innocuity disposal system as described in claim 1, which is characterized in that the anaerobic reaction slot It is interior to be equipped with heating device and the first temperature monitor, for controlling the anaerobic reation pool interior reaction temperature between 28-30 DEG C.
4. cold rolling wastewater dregs of fat innocuity disposal system as described in claim 1, which is characterized in that the anaerobic reation pool PH detectors are inside provided with, for controlling in the anaerobic reation pool pH between 7.0-7.5.
5. cold rolling wastewater dregs of fat innocuity disposal system as described in claim 1, which is characterized in that the muddy water mixing channel Inside it is provided with mixed stirring device.
6. cold rolling wastewater dregs of fat innocuity disposal system as described in claim 1, which is characterized in that the SBR biochemistry pools Bottom is provided with the first aerator, the oxygen for providing aerobic biochemical reaction.
7. cold rolling wastewater dregs of fat innocuity disposal system as described in claim 1, which is characterized in that the SBR biochemistry pools Bottom is provided with dissolved oxygen detector, and aeration quantity is adjusted for detecting.
8. cold rolling wastewater dregs of fat innocuity disposal system as claimed in claim 6, which is characterized in that the SBR biochemistry pools Equipped with heating device and second temperature detector, for controlling pond interior reaction temperature between 28-30 DEG C.
9. cold rolling wastewater dregs of fat innocuity disposal system as claimed in claim 2, which is characterized in that the regeneration sludge slot Bottom is provided with the second aerator, for providing oxygen needed for the regeneration sludge.
10. a kind of cold rolling wastewater dregs of fat method for innocent treatment, which is characterized in that based on the cold rolling wastewater described in claim 2 Dregs of fat innocuity disposal system, includes the following steps:
1) after the cold rolling wastewater dregs of fat enter anaerobic reaction slot, oil in the dregs of fat is obtained by the reaction point in the anaerobic digestion of thermophilic oily microorganism Solution;The anaerobic reaction slot interior reaction temperature control is between 30-35 DEG C, and PH is controlled between 7.0-7.5, entire anaerobic digestion Reaction time was at 10-15 days;
2) sludge after anaerobic digestion is mixed to get mixing sludge by being pumped into the recirculation water in muddy water mixing channel with effluent trough Waste water;
3) the mixing sludge waste water gravity described in flows into and carries out biology aerobic decomposition in SBR biochemistry pools, anti-in the biochemistry pool Answer temperature control that aeration quantity is adjusted between 28-30 DEG C, while by dissolved oxygen meter;The aerobic reaction time is in 10-12 Between hour;
4) supernatant enters in effluent trough after mixture mud waste water described in is stablized, by the regulating reservoir of pumped back waste water station, And oil content has been decomposed the sludge finished by being pumped into sludge regeneration tank after stablizing;
5) regeneration sludge slot is equipped with blast aerator, and the regeneration tank reaction time is 3-5 days, and the sludge after regeneration is as demulsifier It recycles.
CN201810168742.3A 2018-02-28 2018-02-28 Cold rolling wastewater oil residue harmless treatment system and method Active CN108328889B (en)

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Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3986953A (en) * 1974-04-01 1976-10-19 Interlake, Inc. Treatment of waste rolling oil
US4004918A (en) * 1974-09-04 1977-01-25 Nissin Steel Co. Ltd. Method of treating waste produced during stainless steel making
CN101481195A (en) * 2009-02-09 2009-07-15 武汉钢铁(集团)公司 Anaerobic-aerobic combined biological treatment method for oily wastewater of cold rolling mill
CN202519129U (en) * 2012-02-17 2012-11-07 武汉都市环保工程技术股份有限公司 System for coprocessing cold-rolled oil-contained wastewater by physical-chemical and bio-chemical methods
CN106315908A (en) * 2015-06-29 2017-01-11 宝山钢铁股份有限公司 Deep processing method and device of cold rolling oil-containing wastewater
CN106316023A (en) * 2016-09-21 2017-01-11 重庆赛迪热工环保工程技术有限公司 Supercritical water gasification and recycling method and apparatus for steel mill high-oil-content iron-containing sludge

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US3986953A (en) * 1974-04-01 1976-10-19 Interlake, Inc. Treatment of waste rolling oil
US4004918A (en) * 1974-09-04 1977-01-25 Nissin Steel Co. Ltd. Method of treating waste produced during stainless steel making
CN101481195A (en) * 2009-02-09 2009-07-15 武汉钢铁(集团)公司 Anaerobic-aerobic combined biological treatment method for oily wastewater of cold rolling mill
CN202519129U (en) * 2012-02-17 2012-11-07 武汉都市环保工程技术股份有限公司 System for coprocessing cold-rolled oil-contained wastewater by physical-chemical and bio-chemical methods
CN106315908A (en) * 2015-06-29 2017-01-11 宝山钢铁股份有限公司 Deep processing method and device of cold rolling oil-containing wastewater
CN106316023A (en) * 2016-09-21 2017-01-11 重庆赛迪热工环保工程技术有限公司 Supercritical water gasification and recycling method and apparatus for steel mill high-oil-content iron-containing sludge

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