CN108328827A - Leachate pyrolytic gasification treatment technology - Google Patents

Leachate pyrolytic gasification treatment technology Download PDF

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Publication number
CN108328827A
CN108328827A CN201810041274.3A CN201810041274A CN108328827A CN 108328827 A CN108328827 A CN 108328827A CN 201810041274 A CN201810041274 A CN 201810041274A CN 108328827 A CN108328827 A CN 108328827A
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China
Prior art keywords
leachate
percolate
processing
water
gasification
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CN201810041274.3A
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Chinese (zh)
Inventor
张波
杨红波
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Individual
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Priority to CN201810041274.3A priority Critical patent/CN108328827A/en
Publication of CN108328827A publication Critical patent/CN108328827A/en
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F9/00Multistage treatment of water, waste water or sewage
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B3/00Hydrogen; Gaseous mixtures containing hydrogen; Separation of hydrogen from mixtures containing it; Purification of hydrogen
    • C01B3/02Production of hydrogen or of gaseous mixtures containing a substantial proportion of hydrogen
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J3/00Production of combustible gases containing carbon monoxide from solid carbonaceous fuels
    • C10J3/46Gasification of granular or pulverulent flues in suspension
    • FMECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
    • F23COMBUSTION APPARATUS; COMBUSTION PROCESSES
    • F23GCREMATION FURNACES; CONSUMING WASTE PRODUCTS BY COMBUSTION
    • F23G5/00Incineration of waste; Incinerator constructions; Details, accessories or control therefor
    • F23G5/02Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment
    • F23G5/027Incineration of waste; Incinerator constructions; Details, accessories or control therefor with pretreatment pyrolising or gasifying stage
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/02Treatment of water, waste water, or sewage by heating
    • C02F1/025Thermal hydrolysis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/24Treatment of water, waste water, or sewage by flotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/52Treatment of water, waste water, or sewage by flocculation or precipitation of suspended impurities
    • CCHEMISTRY; METALLURGY
    • C10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
    • C10JPRODUCTION OF PRODUCER GAS, WATER-GAS, SYNTHESIS GAS FROM SOLID CARBONACEOUS MATERIAL, OR MIXTURES CONTAINING THESE GASES; CARBURETTING AIR OR OTHER GASES
    • C10J2300/00Details of gasification processes
    • C10J2300/09Details of the feed, e.g. feeding of spent catalyst, inert gas or halogens
    • C10J2300/0913Carbonaceous raw material
    • C10J2300/0946Waste, e.g. MSW, tires, glass, tar sand, peat, paper, lignite, oil shale

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Organic Chemistry (AREA)
  • Combustion & Propulsion (AREA)
  • General Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Inorganic Chemistry (AREA)
  • Processing Of Solid Wastes (AREA)

Abstract

The invention discloses a kind of leachate pyrolytic gasification treatment technologies comprising following steps:1) landfill leachate is filtered by grid, percolate and rubbish is separated;2) percolate is separated by solid-liquid separation by dissolved air flotation;3) solid and water are thoroughly separated, by filtering, clear liquid is sent into sewage disposal system, and final process is irrigation water or municipal water use;The sediment of suspended matter and lower layer for upper layer is sprayed by atomization and carries out gasification and pyrolysis processing in two sections of townhouse formula garbage pyrolysis gasification incinerators, and the gentle body of inorganic lime-ash is eventually converted into, and realizes thoroughly processing;Technical finesse provided by the invention is ingenious, and decrement more simplified than landfill leachate difficult to deal with by the way of pyrolytic gasification, effectively reduce the processing cost and difficulty of landfill leachate, it is efficient to organic matter removal, and stable effluent quality, impact resistance, load are strong, it can effectively realize the processing of landfill leachate, be conducive to wide popularization and application.

Description

Leachate pyrolytic gasification treatment technology
Technical field
The present invention relates to technical field of landfill leachate treatment, more particularly to a kind of leachate pyrolytic gasification handles skill Art.
Background technology
With China's rapid economic development, city size constantly expands, and Municipal Domestic Garbage Output also sharply increases.People Daily output quantity of refuse is increased more than 1.1kg with 8%~10% speed, and only the big cities such as Beijing, Shanghai generate daily House refuse is just up to 20,000 tons or so.China has become rubbish in the world and surrounds city one of the countries with the most serious ....
City biochemistry rubbish is oozed in stacking, landfill and the temporary rubbish for generating a large amount of intractable foul smelling smells in the process Filtrate.Percolate is influenced by several factors, cation, heavy metal containing ammonia nitrogen and various solubilised states, phenols, solubility Aliphatic acid and other organic pollutions, have water quality complicated, water quality and water variation greatly, organic matter, that is, BOD5 and COD concentration height, The distinguishing features such as ammonia-nitrogen content is high, and tenor is higher.The property of percolate changes in a sizable range.If being not added with It handles and is directly discharged into environment, serious environmental pollution can be caused.Landfill leachate harm is bigger, 1 ton of landfill leachate production Raw pollution is equivalent to the pollution of 100 tons of sanitary sewages generation.It is directly discharged in environment to surface water environment, groundwater environment Serious pollution will be will produce, while threatening the drinking water safety of resident.
Related decree and standard have been issued and implemented in 2008 in China, it is desirable that the necessary treatment in situ of landfill leachate is up to standard Discharge.The technology for capableing of qualified discharge at present mainly uses reverse osmosis technology, but the Treatment Landfill Leachate is still There are many problems, such as intractability is big, of high cost, are unfavorable for being widely popularized utilization.
Invention content
In view of the above-mentioned deficiencies, present invention aims at provide a kind of simple process and low cost, using pyrolytic gasification And decrement more simplified than landfill leachate difficult to deal with is effectively reduced the processing cost and difficulty of landfill leachate by mode Leachate pyrolytic gasification treatment technology.
To achieve the above object, the technical solution provided is the present invention:
A kind of leachate pyrolytic gasification treatment technology comprising following steps:
(1) landfill leachate is filtered by grid, percolate and rubbish is separated, percolate enters processing system System;
(2) percolate is separated by solid-liquid separation by dissolved air flotation, obtains solid portion and liquid part;
(3) solid and water is carried out to solid portion thoroughly to separate;Suspended matter and lower layer to the upper layer of liquid part it is heavy Starch is sprayed by atomization and carries out gasification and pyrolysis processing in two sections of townhouse formula garbage pyrolysis gasification incinerators, is eventually converted into inorganic Lime-ash and gas realize thoroughly processing.
As an improvement of the present invention, it before the step (2), after the primary separation of processing system, is oozing Addition accounts for the flocculant that its weight percent is 0.5-5% and is mixed in filtrate.The additive amount of flocculant can be according to leakage The property difference of liquid is adjusted in right amount in 0.5-5%.
As an improvement of the present invention, the step (2) specifically includes following steps:Molten gas gas is carried out to percolate Floating, to all or part of pending or treated, water pressurize and aerating, increases the Underwater sound field of water, in normal pressure situation Lower release, air are precipitated to form minute bubbles, are adhered on impurity wadding grain, wadding grain global density is caused to rise less than water, to Make separation of solid and liquid, obtains solid portion and liquid part.
As an improvement of the present invention, the step (3) specifically includes following steps:It will be by air-dissolving air-float processing Percolate introduces subsider, and water and the solid-state in solid portion are separated, and by filtering, clear liquid is sent into sewage disposal system, most Processing is irrigation water or municipal water use eventually;By the suspended matter for being located at topside position in liquid part and it is deposited in lower layer position Sediment carries out two sections of townhouse formula garbage pyrolysis gasification incinerators progress pyrolysis sections of atomization penetrating and is pyrolyzed and is gasified, final to turn Turn to the gentle body of inorganic lime-ash, realize percolate processing simplify and thoroughly.
As an improvement of the present invention, two sections of townhouses formula garbage pyrolysis gasification incinerator include two for pyrolysis and The incinerator for thermal decomposition that gasification process process is connected.It is combustion chamber heat supply that townhouse, which refers to pyrolysis oven both sides, the two of combustion chamber Side is pyrolysis chamber, the pyrolysis chamber of both sides when combustion chambers burn.Combustion chamber and pyrolysis chamber number depend on treating capacity Size.
Beneficial effects of the present invention are:Technical finesse provided by the invention is ingenious, and handle compares by the way of pyrolytic gasification Intractable landfill leachate is simplified and decrement, effectively reduces the processing cost and difficulty of landfill leachate, the technical side Method processing cost is low, efficient to organic matter removal, and stable effluent quality, and impact resistance, load is strong, can effectively realize that rubbish oozes The processing of filtrate is conducive to wide popularization and application.In general, leachate pyrolytic gasification treatment technology of the present invention is with following excellent Point:
1, through experimental tests, leachate pyrolytic gasification treatment technology handling result index of the present invention disclosure satisfy that country 《Household refuse landfill sites contamination control standard》(GB16889-2008) requires discharge standard;
2, leachate pyrolytic gasification treatment technology of the present invention is adaptable, can be adapted for creating, conventional garbage is transformed Percolation liquid treating system, to ensure the stably reaching standard discharge of landfill leachate;
3, leachate pyrolytic gasification treatment technology of the present invention can realize resource reclaim, by the landfill leachate of high concentration It is handled by the way of pyrolytic gasification, useful pyrolysis gas can be generated, be allowed to recycling;
4, leachate pyrolytic gasification treatment technology treatment process of the present invention is simple, and treatment effect is good;
5, leachate pyrolytic gasification treatment technology applicability of the present invention is extensive, for " old-age group ", " youth " garbage filter Liquid is suitable for, applied widely.
With reference to embodiment, the present invention is further described.
Specific implementation mode
Embodiment:The embodiment of the present invention provides a kind of leachate pyrolytic gasification treatment technology comprising following steps:
A kind of leachate pyrolytic gasification treatment technology comprising following steps:
(1) landfill leachate is filtered by grid, percolate and rubbish is separated, percolate enters processing system System;Preferably, after the primary separation by processing system, it is 0.5-5%'s to be added in percolate and account for its weight percent Flocculant is mixed.The additive amount of flocculant can in right amount be adjusted according to the property difference of effusion in 0.5-5%.
(2) percolate is separated by solid-liquid separation by dissolved air flotation, obtains solid portion and liquid part;The step (2) following steps are specifically included:Air-dissolving air-float is carried out to percolate, water adds to all or part of pending or treated Simultaneously aerating is pressed, increases the Underwater sound field of water, is discharged in normal pressure, air is precipitated to form minute bubbles, is adhered to impurity wadding On grain, wadding grain global density is caused to rise less than water, to make separation of solid and liquid, obtains solid portion and liquid part.
(3) solid and water is carried out to solid portion thoroughly to separate;Suspended matter and lower layer to the upper layer of liquid part it is heavy Starch is sprayed by atomization and carries out gasification and pyrolysis processing in two sections of townhouse formula garbage pyrolysis gasification incinerators, is eventually converted into inorganic Lime-ash and gas realize thoroughly processing.Two sections of townhouses formula garbage pyrolysis gasification incinerator includes two gentle to be pyrolyzed Change the incinerator for thermal decomposition that technical process is connected.Townhouse refers to that pyrolysis oven both sides are combustion chamber heat supply, the both sides of combustion chamber It is pyrolysis chamber, the pyrolysis chamber of both sides when combustion chambers burn.Combustion chamber and pyrolysis chamber number depend on the big for the treatment of capacity It is small.The step (3) specifically includes following steps:Subsider will be introduced by the percolate of air-dissolving air-float processing, by solid-state portion Water and solid-state in point separate, and by filtering, clear liquid is sent into sewage disposal system, and final process is that irrigation water or municipal administration are used Water;The suspended matter for being located at topside position in liquid part and the sediment for being deposited in lower layer position are subjected to atomization and spray into two sections of connection Row's formula garbage pyrolysis gasification incinerator carries out pyrolysis section and is pyrolyzed and gasifies, and is eventually converted into the gentle body of inorganic lime-ash, realizes The processing of percolate simplifies and thoroughly.
Technical finesse provided by the invention is ingenious, than landfill leachate difficult to deal with letter by the way of pyrolytic gasification Change and decrement, effectively reduces the processing cost and difficulty of landfill leachate, the technical method processing cost is low, to organic matter Removal efficiency is high, and stable effluent quality, and impact resistance, load is strong, can effectively realize the processing of landfill leachate, conducive to pushing away extensively Wide application.
According to the disclosure and teachings of the above specification, those skilled in the art in the invention can also be to above-mentioned embodiment party Formula is changed and is changed.Therefore, the invention is not limited in specific implementation modes disclosed and described above, to the present invention's Some modifications and changes should also be as falling into the scope of the claims of the present invention.In addition, although being used in this specification Some specific terms, these terms are merely for convenience of description, does not limit the present invention in any way.Such as the present invention Described in above-described embodiment, using same or similar treatment technology and method, all fall in the scope of protection of the present invention.

Claims (5)

1. a kind of leachate pyrolytic gasification treatment technology, which is characterized in that it includes the following steps:
(1) landfill leachate is filtered by grid, percolate and rubbish is separated, percolate enters processing system;
(2) percolate is separated by solid-liquid separation by dissolved air flotation, obtains solid portion and liquid part;
(3) solid and water is carried out to solid portion thoroughly to separate;The sediment of suspended matter and lower layer to the upper layer of liquid part It is sprayed by atomization and carries out gasification and pyrolysis processing in two sections of townhouse formula garbage pyrolysis gasification incinerators, be eventually converted into inorganic lime-ash And gas, realize thoroughly processing.
2. leachate pyrolytic gasification treatment technology according to claim 1, which is characterized in that the step (2) it Before, after the primary separation of processing system, the flocculant progress for accounting for that its weight percent is 0.5-5% is added in percolate Mixing.
3. leachate pyrolytic gasification treatment technology according to claim 1 or 2, which is characterized in that step (2) tool Body includes the following steps:
Air-dissolving air-float is carried out to percolate, water pressurize and aerating to all or part of pending or treated, increases water Underwater sound field, discharged in normal pressure, air is precipitated to form minute bubbles, be adhered to impurity wadding grain on, cause wadding grain it is whole Volume density rises less than water, to make separation of solid and liquid, obtains solid portion and liquid part.
4. leachate pyrolytic gasification treatment technology according to claim 1, which is characterized in that the step (3) is specific Include the following steps:Subsider will be introduced by the percolate of air-dissolving air-float processing, water and the solid-state in solid portion is separated, By filtering, clear liquid is sent into sewage disposal system, and final process is irrigation water or municipal water use;It is upper by being located in liquid part The suspended matter of layer position and the sediment for being deposited in lower layer position carry out atomization and spray into two sections of townhouse formula refuse pyrolysis gasification burnings Stove carry out pyrolysis section be pyrolyzed and gasified, be eventually converted into the gentle body of inorganic lime-ash, realize percolate processing simplify and it is thorough Bottom.
5. leachate pyrolytic gasification treatment technology according to claim 1, which is characterized in that two sections of townhouses formula rubbish It is to be pyrolyzed the incinerator for thermal decomposition being connected with gasification process process that rubbish incinerator for thermal decomposition, which includes two,.
CN201810041274.3A 2018-01-16 2018-01-16 Leachate pyrolytic gasification treatment technology Pending CN108328827A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108424790A (en) * 2018-03-06 2018-08-21 西安交通大学 A kind of refuse gasification cogeneration system
CN109231319A (en) * 2018-09-06 2019-01-18 上海焓净电力技术有限公司 Evaporation burning zero discharge treatment device is melted down in a kind of Leachate site/waste water/waste oil atomization
CN109974003A (en) * 2019-03-07 2019-07-05 张波 A kind of townhouse formula refuse pyrolysis gasification furnace
CN110104907A (en) * 2019-06-11 2019-08-09 武汉深能环保新沟垃圾发电有限公司 A kind of landfill leachate oil removing system and method

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101850351A (en) * 2010-05-10 2010-10-06 中国科学院广州能源研究所 Novel method for generating electricity by pyrolysis and incineration of waste
JP2015020136A (en) * 2013-07-22 2015-02-02 株式会社クラレ Method for treating landfill leachate
CN105776741A (en) * 2016-03-23 2016-07-20 北京神雾环境能源科技集团股份有限公司 Refuse pyrolysis comprehensive sewage treatment system and method
CN205635249U (en) * 2016-03-23 2016-10-12 北京神雾环境能源科技集团股份有限公司 Garbage pyrolytic synthesizes processing system of sewage

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101850351A (en) * 2010-05-10 2010-10-06 中国科学院广州能源研究所 Novel method for generating electricity by pyrolysis and incineration of waste
JP2015020136A (en) * 2013-07-22 2015-02-02 株式会社クラレ Method for treating landfill leachate
CN105776741A (en) * 2016-03-23 2016-07-20 北京神雾环境能源科技集团股份有限公司 Refuse pyrolysis comprehensive sewage treatment system and method
CN205635249U (en) * 2016-03-23 2016-10-12 北京神雾环境能源科技集团股份有限公司 Garbage pyrolytic synthesizes processing system of sewage

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN108424790A (en) * 2018-03-06 2018-08-21 西安交通大学 A kind of refuse gasification cogeneration system
CN108424790B (en) * 2018-03-06 2020-08-28 西安交通大学 Garbage gasification combined heat and power system
CN109231319A (en) * 2018-09-06 2019-01-18 上海焓净电力技术有限公司 Evaporation burning zero discharge treatment device is melted down in a kind of Leachate site/waste water/waste oil atomization
CN109974003A (en) * 2019-03-07 2019-07-05 张波 A kind of townhouse formula refuse pyrolysis gasification furnace
CN110104907A (en) * 2019-06-11 2019-08-09 武汉深能环保新沟垃圾发电有限公司 A kind of landfill leachate oil removing system and method

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Application publication date: 20180727