CN108328705B - Electrochemical water treatment equipment, electrochemical tube, cathode structure and anode structure - Google Patents

Electrochemical water treatment equipment, electrochemical tube, cathode structure and anode structure Download PDF

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Publication number
CN108328705B
CN108328705B CN201810362090.7A CN201810362090A CN108328705B CN 108328705 B CN108328705 B CN 108328705B CN 201810362090 A CN201810362090 A CN 201810362090A CN 108328705 B CN108328705 B CN 108328705B
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Prior art keywords
insulating
rod
electrochemical
rod body
tube
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CN201810362090.7A
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CN108328705A (en
Inventor
高永建
翟性泉
严晓培
万绍明
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Beijing Junhe Technology Co ltd
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Beijing Junhe Technology Co ltd
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    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46152Electrodes characterised by the shape or form
    • C02F2001/46171Cylindrical or tubular shaped
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F2201/00Apparatus for treatment of water, waste water or sewage
    • C02F2201/46Apparatus for electrochemical processes
    • C02F2201/461Electrolysis apparatus
    • C02F2201/46105Details relating to the electrolytic devices

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Electrochemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Water Treatment By Electricity Or Magnetism (AREA)

Abstract

The invention relates to electrochemical water treatment equipment, an electrochemical tube, a cathode structure and an anode structure. The electrochemical water treatment equipment comprises an electrochemical pipe and a power module connected with the electrochemical pipe, wherein the electrochemical pipe comprises a tubular main body, an anode rod arranged in the tubular main body and an insulating structure for forming an electric field which is arranged along the axial direction at intervals between the tubular main body and the anode rod, and the tubular main body is a continuous pipe body with an integral structure; the anode rod is provided with rod body insulating sections and rod body conducting sections which are alternately arranged along the axial direction, and the rod body conducting sections are mutually conducted; and/or the continuous pipe body is made of conductive material, and pipe body insulating sections which are arranged at intervals along the axial direction of the tubular body are arranged on the inner wall of the tubular body; the insulation structure is correspondingly formed by the rod body insulation section and/or the pipe body insulation section. The tubular main body is a continuous pipe body with an integrated structure, and the continuous pipe body forms a pipeline for water supply flow, so that water flow is prevented from flowing out of the tubular main body, and the tightness of the tubular main body is enhanced.

Description

Electrochemical water treatment equipment, electrochemical tube, cathode structure and anode structure
Technical Field
The invention relates to electrochemical water treatment equipment, an electrochemical tube, a cathode structure and an anode structure.
Background
Along with the reduction of water resources, the purification treatment of sewage, seawater and ecological water is an important path for sustainable development of water resources. The existing water treatment mainly adopts a chemical flocculation method, and a water source is treated by adding a chemical flocculant into water, but the cost is higher when the chemical flocculation method is used for treatment, and meanwhile, a large amount of chemical substances remain in discharged wastewater, so that secondary pollution can be generated.
The chinese patent publication No. CN202107563U, publication No. 2012.01.11 discloses an electrode structure (i.e., electrochemical tube) for a composite pole electrochemical water treatment device, the electrochemical tube comprising a tubular body, an anode pole disposed in the tubular body, and an insulating structure for forming an electric field disposed at intervals along an axial direction between the tubular body and the anode pole, the tubular body comprising a plurality of annular cathodes disposed at intervals and an insulating tube (i.e., insulating structure) connecting adjacent annular cathodes, the tubular body and the anode pole forming an electric field disposed at intervals along an extending direction of a pipeline therebetween.
When the electrode structure for the electrochemical water treatment device with the composite electrode rod is used, the tubular main body is of a split structure formed by connecting the annular cathode with the insulating tube, the sealing performance between the annular cathode and the insulating tube is poor, and meanwhile, the tubular main body is formed by connecting a plurality of annular cathodes with the insulating tube, so that the manufacturing is difficult.
Disclosure of Invention
The invention aims to provide electrochemical water treatment equipment, which solves the problems of poor tightness and difficult manufacture caused by the split type structure of a tubular main body of an electrochemical tube of an electrochemical water treatment device in the prior art; the invention also provides an electrochemical tube of the electrochemical water treatment equipment; the invention also provides a cathode structure of the electrochemical tube; the invention also provides an anode structure of the electrochemical tube.
In order to solve the technical problems, the technical scheme of the electrochemical water treatment equipment is as follows:
The electrochemical water treatment equipment comprises an electrochemical pipe and a power module connected with the electrochemical pipe, wherein the electrochemical pipe comprises a tubular main body, an anode rod arranged in the tubular main body and an insulating structure for forming an electric field which is arranged along the axial direction at intervals between the tubular main body and the anode rod, and the tubular main body is a continuous pipe body with an integral structure; the anode rod is provided with rod body insulating sections and rod body conducting sections which are alternately arranged along the axial direction, and the rod body conducting sections are mutually conducted; the continuous pipe body is made of conductive materials, pipe body insulating sections which are arranged at intervals along the axial direction of the tubular body are arranged on the inner wall of the tubular body, and the rod body insulating sections correspond to the pipe body insulating sections; the insulation structure is formed by the rod body insulation section and the pipe body insulation section.
The beneficial effect of this technical scheme lies in: the tubular main body is a continuous pipe body with an integrated structure, the continuous pipe body forms a pipeline for water supply flow, the pipe body is of a sealing structure, water flow is prevented from flowing out of the tubular main body, the sealing performance of the tubular main body is enhanced, and meanwhile, the manufacturing is simple.
The anode rod is a continuous rod body with an integrated structure, and the rod body insulation section is formed by an insulation ring or an insulation coating on the continuous rod body. The continuous rod body has simple structure, low cost of the insulating ring and the insulating coating and convenient processing.
The insulating ring is a ceramic ring, a silica gel ring or a polytetrafluoroethylene ring. The ceramic ring, the silica gel ring and the polytetrafluoroethylene ring have low cost.
The anode rod comprises a plurality of rod body units which are arranged at intervals along the axial direction of the tubular main body, an insulating tube is connected between every two adjacent rod body units, the rod body conductive section is formed by the rod body units, and the rod body insulating section is formed by the insulating tube. The anode rod is a plurality of rod body units, so that the material is saved.
The two ends of the insulating tube are respectively sleeved on the outer sides of the adjacent rod body units. The two ends of the insulating tube are respectively sleeved on the adjacent rod body units, so that a sealing structure can be formed, and the tightness between the anode rod and the insulating tube is enhanced.
The continuous pipe body is a metal pipe. The metal tube has high structural strength.
The technical scheme of the electrochemical tube is as follows:
the electrochemical tube comprises a tubular main body, an anode rod arranged in the tubular main body and an insulating structure for forming an electric field which is arranged along the axial direction at intervals between the tubular main body and the anode rod, wherein the tubular main body is a continuous tube body with an integral structure; the anode rod is provided with rod body insulating sections and rod body conducting sections which are alternately arranged along the axial direction, and the rod body conducting sections are mutually conducted; the continuous pipe body is made of conductive materials, pipe body insulating sections which are arranged at intervals along the axial direction of the tubular body are arranged on the inner wall of the tubular body, and the rod body insulating sections correspond to the pipe body insulating sections; the insulation structure is formed by the rod body insulation section and the pipe body insulation section.
The beneficial effect of this technical scheme lies in: the tubular main body is a continuous pipe body with an integrated structure, the continuous pipe body forms a pipeline for water supply flow, the pipe body is of a sealing structure, water flow is prevented from flowing out of the tubular main body, the sealing performance of the tubular main body is enhanced, and meanwhile, the manufacturing is simple.
The anode rod is a continuous rod body with an integrated structure, and the rod body insulation section is formed by an insulation ring or an insulation coating on the continuous rod body. The continuous rod body has simple structure, low cost of the insulating ring and the insulating coating and convenient processing.
The insulating ring is a ceramic ring, a silica gel ring or a polytetrafluoroethylene ring. The ceramic ring, the silica gel ring and the polytetrafluoroethylene ring have low cost.
The anode rod comprises a plurality of rod body units which are arranged at intervals along the axial direction of the tubular main body, an insulating tube is connected between every two adjacent rod body units, the rod body conductive section is formed by the rod body units, and the rod body insulating section is formed by the insulating tube. The anode rod is a plurality of rod body units, so that the material is saved.
The two ends of the insulating tube are respectively sleeved on the outer sides of the adjacent rod body units. The two ends of the insulating tube are respectively sleeved on the adjacent rod body units, so that a sealing structure can be formed, and the tightness between the anode rod and the insulating tube is enhanced.
The continuous pipe body is a metal pipe. The metal tube has high structural strength.
Drawings
FIG. 1 is a schematic view of the structure of example 1 of the electrochemical water treatment apparatus of the present invention;
FIG. 2 is a schematic structural view of embodiment 2 of the electrochemical water treatment apparatus of the present invention;
FIG. 3 is a schematic view of the structure of example 3 of the electrochemical water treatment apparatus of the present invention;
FIG. 4 is a schematic view of the structure of example 4 of the electrochemical water treatment apparatus of the present invention;
fig. 5 is a schematic structural view of example 5 of the electrochemical water treatment apparatus of the present invention.
Each mark in the figure: 1. an anode rod; 2. an insulating structure; 3. a continuous pipe body; 4. an electrode terminal; 5. and a rod unit.
Detailed Description
An embodiment 1 of an electrochemical water treatment apparatus of the present invention is shown in fig. 1, which includes an electrochemical tube and a power module connected to the electrochemical tube, the electrochemical tube including a tubular body, an anode rod 1 disposed within the tubular body, and an insulating structure 2 for forming an electric field between the tubular body and the anode rod 1, which is arranged at intervals in an axial direction. The continuous pipe body 3 with the integral structure of the tubular main body is made of conductive materials, the continuous pipe body 3 forms a pipeline for water supply flow, the continuous pipe body 3 is of a sealing structure, the tubular main body is an integral body, water flow is prevented from flowing out of the tubular main body, the sealing performance of the tubular main body is enhanced, and meanwhile, the manufacturing is simple; the continuous pipe body 3 is connected with an electrode binding post 4, and the electrode binding post 4 is used for being connected with a power supply module. In this embodiment, the continuous tube body 3 is a metal tube, and the continuous tube body 3 serves as a cathode of an electrochemical tube, and the metal tube has high structural strength. In other embodiments, the continuous tube body 3 may be an insulating tube such as a plastic tube or a ceramic tube, the inner wall of the continuous tube body 3 is provided with conductive coatings and insulating coatings which are alternately arranged, the conductive coatings form a tube body insulating section, the insulating coatings form a tube body insulating section, and the anode rod 1 is provided with an insulating ring at a position corresponding to the tube body insulating section.
The anode rod 1 is a continuous rod body with an integral structure extending along the axial direction of the tubular main body, and the anode rod 1 can be made of metal materials such as aluminum, iron, titanium alloy and the like, or conductive nonmetallic materials such as carbon rods, carbon fibers and the like. The outer wall of the anode rod 1 is sleeved with an insulating ring, the part of the anode rod 1 wrapped by the insulating ring forms a rod body insulating section of the anode rod 1, the part between adjacent insulating rings forms a rod body conducting section of the anode rod 1, and the insulating ring forms an insulating structure 2, and in the embodiment, the insulating ring can be a ceramic ring, a silica gel ring, a polytetrafluoroethylene ring and the like; instead of the insulating ring, an insulating coating may be used, and the volume of the anode rod 1 may be reduced.
The part of the anode rod 1 wrapped by the insulating ring forms a rod body insulating section of the anode rod 1, and the part between adjacent insulating structures 2 forms a rod body conducting section of the anode rod 1, so that an electric field which is arranged at intervals along the axial direction of the tubular main body is formed between the anode rod 1 and the continuous tube body 3. The continuous tube body 3 and the anode rod 1 are not conductive at the position with the insulating structure 2, a pulse electric field and a magnetic field are formed, charged particles are acted by the pulse electric field, a pulse high current is generated at the position without the insulating structure 2 due to the conductivity of water flow, and the water flow is electrochemically treated to change the property.
Example 2 of the electrochemical water treatment apparatus of the present invention is different from example 1 in that as shown in fig. 2: in the embodiment 1, the insulating structure is a rod body insulating section of the anode rod, and in this embodiment, an insulating ring or an insulating coating may be disposed on the inner wall of the continuous pipe body, and the insulating ring and the part covered by the insulating coating form a pipe body insulating section of the continuous pipe body, and the pipe body insulating section forms an insulating structure.
Example 3 of the electrochemical water treatment apparatus of the present invention is different from example 1 in that as shown in fig. 3: in the embodiment 1, the insulating ring is disposed on the outer wall of the anode rod, the rod body insulating section of the anode rod forms an insulating structure, in this embodiment, the insulating ring is disposed at the corresponding position of the inner wall of the continuous pipe body and the outer wall of the anode rod, and the pipe body insulating section on the continuous pipe body and the rod body insulating section of the anode rod form an insulating structure.
Example 4 of the electrochemical water treatment apparatus of the present invention is different from example 1 in that as shown in fig. 4: in the continuous rod body with the integral structure of the anode rod in the embodiment 1, in the embodiment, the anode rod comprises seven rod body units 5 which are arranged at intervals, two adjacent rod body units 5 are electrically connected, an insulating tube is connected between the two adjacent rod body units 5, the insulating tube forms a rod body insulating section of the anode rod, the rod body units 5 form a rod body conducting section of the anode rod, and two ends of the insulating tube are respectively sleeved outside the two adjacent rod body units; in other embodiments, the number of rod units may be increased or decreased as desired.
Example 5 of the electrochemical water treatment apparatus of the present invention is shown in fig. 5, and differs from example 4 in that: in embodiment 4, the two ends of the insulating tube are sleeved outside the two adjacent rod units, and in this embodiment, the insulating tube may be adhered and fixed to the rod units by an adhesive layer or the like.
The invention also provides an electrochemical tube for the electrochemical water treatment device, the specific structure of which is the same as that of the electrochemical tube of the electrochemical water treatment device, and the details are not repeated here.
The invention also provides a cathode structure of the electrochemical tube, which comprises a tubular main body and a continuous tube body, wherein the tubular main body is of an integral structure; the coiled tubing is made of an electrically conductive material, and the tubular body has tubing insulation segments arranged at intervals along the axial direction of the tubular body, the tubing insulation segments being formed by an insulating ring or insulating coating on the coiled tubing. The specific structures of the continuous pipe body and the pipe body insulation section are the same as those of the continuous pipe body and the pipe body insulation section in the embodiment 2 and the embodiment 3 of the electrochemical water treatment device, and are not repeated here.
The invention also provides an anode structure of the electrochemical tube, which comprises an anode rod, wherein the anode rod is provided with rod body insulating sections and rod body conducting sections which are alternately arranged along the axial direction, and the rod body conducting sections are mutually conducted. The specific structures of the anode rod and the rod body insulation section are the same as those of the anode rod and the rod body insulation section in the embodiment 1, the embodiment 4 and the embodiment 5 of the electrochemical water treatment device, and are not repeated here.

Claims (12)

1. Electrochemical water treatment facilities, including electrochemical tube and with the power module of electrochemical tube connection, the electrochemical tube includes tubular main part, sets up the positive pole stick in tubular main part and is used for forming the insulating structure along the electric field of axial interval arrangement between tubular main part and the positive pole stick, its characterized in that: the tubular main body is a continuous pipe body with an integrated structure; the anode rod is provided with rod body insulating sections and rod body conducting sections which are alternately arranged along the axial direction, and the rod body conducting sections are mutually conducted; the continuous pipe body is made of conductive materials, pipe body insulating sections which are arranged at intervals along the axial direction of the tubular body are arranged on the inner wall of the tubular body, and the rod body insulating sections correspond to the pipe body insulating sections; the insulation structure is formed by the rod body insulation section and the pipe body insulation section.
2. An electrochemical water treatment apparatus according to claim 1, characterized in that: the anode rod is a continuous rod body with an integrated structure, and the rod body insulation section is formed by an insulation ring or an insulation coating on the continuous rod body.
3. An electrochemical water treatment apparatus according to claim 2, characterized in that: the insulating ring is a ceramic ring, a silica gel ring or a polytetrafluoroethylene ring.
4. An electrochemical water treatment apparatus according to claim 1, characterized in that: the anode rod comprises a plurality of rod body units which are arranged at intervals along the axial direction of the tubular main body, an insulating tube is connected between every two adjacent rod body units, the rod body conductive section is formed by the rod body units, and the rod body insulating section is formed by the insulating tube.
5. An electrochemical water treatment apparatus according to claim 4, characterized in that: the two ends of the insulating tube are respectively sleeved on the outer sides of the adjacent rod body units.
6. An electrochemical water treatment apparatus according to any one of claims 1 to 5, characterized in that: the continuous pipe body is a metal pipe.
7. Electrochemical tube, including the tubular body, set up the positive pole stick in the tubular body and be used for forming along the insulating structure of axial interval arrangement's electric field between tubular body and positive pole stick, its characterized in that: the tubular main body is a continuous pipe body with an integrated structure; the anode rod is provided with rod body insulating sections and rod body conducting sections which are alternately arranged along the axial direction, and the rod body conducting sections are mutually conducted; the continuous pipe body is made of conductive materials, pipe body insulating sections which are arranged at intervals along the axial direction of the tubular body are arranged on the inner wall of the tubular body, and the rod body insulating sections correspond to the pipe body insulating sections; the insulation structure is formed by the rod body insulation section and the pipe body insulation section.
8. The electrochemical tube of claim 7, wherein: the anode rod is a continuous rod body with an integrated structure, and the rod body insulation section is formed by an insulation ring or an insulation coating on the continuous rod body.
9. The electrochemical tube of claim 8, wherein: the insulating ring is a ceramic ring, a silica gel ring or a polytetrafluoroethylene ring.
10. The electrochemical tube of claim 7, wherein: the anode rod comprises a plurality of rod body units which are arranged at intervals along the axial direction of the tubular main body, an insulating tube is connected between every two adjacent rod body units, the rod body conductive section is formed by the rod body units, and the rod body insulating section is formed by the insulating tube.
11. The electrochemical tube of claim 10, wherein: the two ends of the insulating tube are respectively sleeved on the outer sides of the adjacent rod body units.
12. The electrochemical tube of any one of claims 7-11, wherein: the continuous pipe body is a metal pipe.
CN201810362090.7A 2018-04-20 2018-04-20 Electrochemical water treatment equipment, electrochemical tube, cathode structure and anode structure Active CN108328705B (en)

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CN201810362090.7A CN108328705B (en) 2018-04-20 2018-04-20 Electrochemical water treatment equipment, electrochemical tube, cathode structure and anode structure

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Application Number Priority Date Filing Date Title
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CN108328705B true CN108328705B (en) 2024-06-14

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202107563U (en) * 2011-04-08 2012-01-11 中国科学院苏州纳米技术与纳米仿生研究所 Electric pole structure used for electrochemical water treatment device with composite poles
CN104192953A (en) * 2014-08-13 2014-12-10 东莞市东元新能源科技有限公司 Electric flocculation wastewater treatment electrode
CN208500446U (en) * 2018-04-20 2019-02-15 北京君禾科技有限公司 A kind of electrification water treatment facilities and its electrochemical pipe

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SU1623971A1 (en) * 1987-10-06 1991-01-30 Научно-Производственное Объединение По Защите Атмосферы, Водоемов, Использованию Вторичных Энергоресурсов И Охлаждению Металлургических Агрегатов На Предприятиях Черной Металлургии "Энергосталь" Apparatus for electrochemical purification of water
CN101293686B (en) * 2007-04-23 2011-01-12 河南大学 Electrization device for treatment of water
EP2609645A4 (en) * 2010-08-24 2016-07-06 Sion Power Corp Electrically non-conductive materials for electrochemical cells
RU2518606C1 (en) * 2013-02-05 2014-06-10 Государственное научное учреждение Поволжский научно-исследовательский институт эколого-мелиоративных технологий Российской академии сельскохозяйственных наук Installation for electrochemical water activation
KR101804979B1 (en) * 2017-07-31 2018-01-11 주식회사 이앤에프 Device for spraying hydroxyl radical water

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN202107563U (en) * 2011-04-08 2012-01-11 中国科学院苏州纳米技术与纳米仿生研究所 Electric pole structure used for electrochemical water treatment device with composite poles
CN104192953A (en) * 2014-08-13 2014-12-10 东莞市东元新能源科技有限公司 Electric flocculation wastewater treatment electrode
CN208500446U (en) * 2018-04-20 2019-02-15 北京君禾科技有限公司 A kind of electrification water treatment facilities and its electrochemical pipe

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