CN108328588A - A kind of helium online recycling equipment for purifying - Google Patents

A kind of helium online recycling equipment for purifying Download PDF

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Publication number
CN108328588A
CN108328588A CN201810355398.9A CN201810355398A CN108328588A CN 108328588 A CN108328588 A CN 108328588A CN 201810355398 A CN201810355398 A CN 201810355398A CN 108328588 A CN108328588 A CN 108328588A
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CN
China
Prior art keywords
helium
equipment
recycling
membrane separator
level
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Pending
Application number
CN201810355398.9A
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Chinese (zh)
Inventor
张玉学
林蕾蕾
李德强
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
PENGJIE TECHNOLOGY CO.,LTD. HEFEI, Inc.
Original Assignee
Hefei Shuo Lang Automation Technology Co Ltd
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Hefei Shuo Lang Automation Technology Co Ltd filed Critical Hefei Shuo Lang Automation Technology Co Ltd
Priority to CN201810355398.9A priority Critical patent/CN108328588A/en
Publication of CN108328588A publication Critical patent/CN108328588A/en
Pending legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B23/00Noble gases; Compounds thereof
    • C01B23/001Purification or separation processes of noble gases
    • C01B23/0036Physical processing only
    • C01B23/0042Physical processing only by making use of membranes
    • CCHEMISTRY; METALLURGY
    • C01INORGANIC CHEMISTRY
    • C01BNON-METALLIC ELEMENTS; COMPOUNDS THEREOF; METALLOIDS OR COMPOUNDS THEREOF NOT COVERED BY SUBCLASS C01C
    • C01B23/00Noble gases; Compounds thereof
    • C01B23/001Purification or separation processes of noble gases
    • C01B23/0036Physical processing only
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02PCLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
    • Y02P20/00Technologies relating to chemical industry
    • Y02P20/10Process efficiency

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  • Chemical & Material Sciences (AREA)
  • Organic Chemistry (AREA)
  • Analytical Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Separation Using Semi-Permeable Membranes (AREA)

Abstract

The invention discloses a kind of helium online recycling equipment for purifying, are related to technical field of energy saving and environmental protection.Including retracting device and purifying plant;Retracting device includes recycling gas tank and vacuum pump;Purifying plant includes heat exchanger, filter, level-one membrane separator, two level membrane separator and concentrations of helium detector;The present invention is by recycling and being pressurized by helium under the action of vacuum pump or containing helium gas mixture, after heat exchanger, filter dedusting water removal, it cleans using membrane separator and purification, and detect concentrations of helium by concentrations of helium detector, mass flowmenter MFC is supplied by the paths A and reused with helium equipment after reaching established standards, the helium of established standards is not achieved through being purified again in B path return recycling gas tank, to ensure that equipment purification after helium concentration and impurity content it is up to standard, avoid with helium equipment use underproof helium.

Description

A kind of helium online recycling equipment for purifying
Technical field
The invention belongs to technical field of energy saving and environmental protection, more particularly to a kind of helium online recycling equipment for purifying.
Background technology
Helium is a kind of inert gas of colorless and odorless, is widely used in fiber manufacturing, semiconductor production, made of metal It many industrial circles such as makes, weld and hunts leak.Although helium purposes is wide, usage amount is big, source is limited, is a kind of scarcity Strategic resource.Helium content is about 5ppm in air, does not have extraction value substantially, is mainly derived from natural gas extraction at present Associated gas recycles.Therefore for this scarce resource that should not be obtained of helium, the great meaning of recycling is carried out.The present invention can Recycling is carried out for the different classes of tail gas containing helium with used in helium equipment.
Invention content
The purpose of the present invention is to provide a kind of helium online recycling equipment for purifying, by under the action of vacuum pump by helium Or recycled and be pressurized containing helium gas mixture, after heat exchanger, filter dedusting water removal, removed using membrane separator and purification It is miscellaneous, and concentrations of helium is detected by concentrations of helium detector, reach after established standards by the paths A supply mass flowmenter MFC It is reused with helium equipment, the helium of established standards is not achieved through being purified again in B path return recycling gas tank, thus It ensure that the concentration of helium and impurity content are up to standard after equipment purifies, and avoid the problem that using unqualified helium with helium equipment.
In order to solve the above technical problems, the present invention is achieved by the following technical solutions:
The present invention is a kind of helium online recycling equipment for purifying, including retracting device and purifying plant;The retracting device Including recycling gas tank and vacuum pump;The entrance of the recycling gas tank is fixedly connected with the outlet of helium equipment;It is described to use helium equipment Entrance by gas piping with mend helium device be fixedly connected;It is described to be fixed with the gas piping week side of the inlet of helium equipment Mass flowmenter MFC is installed;The outlet of the recycling gas tank is fixedly connected with vacuum pump;The vacuum pump and purifying plant The entrance of heat exchanger is fixedly connected;
The purifying plant includes heat exchanger, filter, level-one membrane separator, two level membrane separator and concentrations of helium detection Instrument;The outlet of the heat exchanger is fixedly connected with the entrance of filter;The outlet of the filter enters with level-one membrane separator Mouth is fixedly connected;The level-one membrane separator outlet respectively with the entrance of two level membrane separator, recycle gas tank entrance and use The entrance of helium equipment is fixedly connected;The heat exchanger can be by low-temperature receivers such as cold air, refrigerant, cool circulation waters, by vacuum pump When gas cooling after supercharged is to specific temperature, and remove liquid water;
The infiltration air pipe week side of the level-one membrane separator is installed with a concentrations of helium detector;Described two Grade membrane separator is fixedly connected by permeating gas piping with the entrance for recycling gas tank;Gas in the two level membrane separator returns Flowing into the effect recycled in gas tank is, it is possible to reduce needle-valve can be used in the loss of helium, impermeable gas emptying, impermeable gas pipeline Or back pressure pressure regulating valve.
Further, dust removal filter and cooling gas check valve are installed with inside the recycling gas tank;The gas list Effect to valve is to prevent gas backstreaming;Due to being had differences with helium equipment, the recycling gas tank is to concentrations of helium in 10-90% It is recycled in range;I.e. recycling equipment for purifying of the invention can mix the helium that contains of the concentrations of helium within the scope of 10-90% Gas carries out recycling purification processes.
Further, the filtering accuracy of the filter is 0.01 micron;The filtering accuracy of the filter requires to reach 0.01 micron of effect is can to remove ultrafine dust and a small amount of moisture by failing to completely remove in heat exchanger.
Further, the level-one membrane separator and two level membrane separator use asymmetric hollow fiber membrane;Using non-right It is that the asymmetric hollow fiber membrane is to containing the segregation ratio in helium mixture, especially air to claim the effect of hollow-fibre membrane Bigger gas, the refining effect for carrying out helium are better.
Further, the vacuum pump uses oilless vacuum pump;The oilless vacuum pump, which has, prevents oil pollution entire The advantages of system;The vacuum pump, which to recycle in gas tank, generates negative pressure, will be used with helium equipment by negative pressure nature water conservancy diversion Helium recovery.
Further, described to be sealing with helium equipment or open use helium equipment, i.e., recycling of the invention purification Equipment to sealing or open can carry out real-time helium recovery purification processes with helium equipment.
Further, the concentrations of helium detector for detecting concentrations of helium in real time;In the concentrations of helium detector Purification concentrations of helium threshold value up to standard can be set, such as when given threshold is 99.0%, when concentrations of helium detector monitors Concentrations of helium>When 99.0%, before helium returns to mass flowmenter MFC according to the paths A, supply is recycled with helium equipment; Otherwise concentrations of helium<99.0%, it returns in recycling gas tank according to B path and is purified again.
Further, the heat exchanger can also with freezing type drier come instead of using.
Further, it is installed with microprocessor on the vacuum pump;The mass flowmenter MFC and A/D converter Connection;The A/D converter is connect with microprocessor;The mass flowmenter MFC exports electric signal to A/D converter;It is described A/D converter is to microprocessor output data information;The microprocessor is according to the data information of reception and the firing level of setting Value carries out size judgement, and opens or closes order to the output of the switch module of vacuum pump;When the data information of the reception is big In the activation threshold value of setting, the microprocessor exports to switch module and opens order;It is on the contrary then export shutdown command;With reality The advantages of existing intelligent operation.
Further, level-one oil-free vacuum can be installed between the level-one membrane separator and two level membrane separator Pump, for make up vacuum pump supercharging it is limited and the problem of lead to insufficient pressure, so that it is guaranteed that two level membrane separator can maintain one A higher separative efficiency.
Further, it can be equipped on the gas piping between each component in recycling equipment for purifying of the invention multiple The components such as check valve, pressure sensor, flowmeter, temperature sensor, for monitoring and recording each section parameter values in real time, The control switch of the check valve is connect with microprocessor;The pressure sensor, flowmeter, temperature sensor are turned by A/D Parallel operation is to microprocessor output data information;The data information that the microprocessor receives is real by GPS module and system terminal Existing remote data transmission has real time monitoring, facilitates management, and when there is abnormal data, can find, locate in time in time The advantages of reason.
The invention has the advantages that:
1, the helium when the detection of concentrations of helium detector may be implemented by the effect of retracting device and purifying plant in the present invention Gas concentration supplies mass flowmenter MFC by the paths A after reaching established standards and is reused with helium equipment, setting is not achieved The helium of standard through B path return recycling gas tank in purified again, to ensure that equipment purification after helium concentration and Impurity content is up to standard, has the advantages that avoid using unqualified helium with helium equipment.
2, the present invention enters to recycle the effect in gas tank by the gas backflow in two level membrane separator, it is possible to reduce helium Needle-valve or back pressure pressure regulating valve can be used in loss, impermeable gas emptying, impermeable gas pipeline.
3, the present invention uses asymmetric hollow fiber membrane by level-one membrane separator and two level membrane separator;With to containing helium The bigger gas of segregation ratio in mixed gas, especially air, carries out the better advantage of the refining effect of helium.
It 4, can be under the action of the present invention is by that can set purification concentrations of helium threshold value up to standard in concentrations of helium detector Standard according to demand purifies to the helium of prescribed concentration, has the advantages that production chains and Multiple strategies.
Certainly, it implements any of the products of the present invention and does not necessarily require achieving all the advantages described above at the same time.
Description of the drawings
In order to illustrate the technical solution of the embodiments of the present invention more clearly, will be described below to embodiment required Attached drawing is briefly described, it should be apparent that, drawings in the following description are only some embodiments of the invention, for ability For the those of ordinary skill of domain, without creative efforts, it can also be obtained according to these attached drawings other attached Figure.
Fig. 1 is a kind of structural schematic diagram of helium online recycling equipment for purifying of the present invention;
In attached drawing, parts list represented by the reference numerals are as follows:
1- retracting devices, 2- purifying plants, 3- helium equipment, 4- mass flowmenters MFC, 5- mend helium device, 101- recycling Gas tank, 102- vacuum pumps, 201- heat exchangers, 202- filters, 203- level-one membrane separators, 204- two level membrane separators, 205- Concentrations of helium detector.
Specific implementation mode
Following will be combined with the drawings in the embodiments of the present invention, and technical solution in the embodiment of the present invention carries out clear, complete Site preparation describes, it is clear that described embodiments are only a part of the embodiments of the present invention, instead of all the embodiments.It is based on Embodiment in the present invention, those of ordinary skill in the art are obtained all other without creative efforts Embodiment shall fall within the protection scope of the present invention.
In the description of the present invention, it is to be understood that, term " trepanning ", "upper", "lower", " thickness ", "top", " in ", Indicating positions or the position relationship such as " length ", "inner", " surrounding ", are merely for convenience of description of the present invention and simplification of the description, without It is that the component of instruction or hint meaning or element must have a particular orientation, with specific azimuth configuration and operation, therefore not It can be interpreted as limitation of the present invention.
Refering to Figure 1, the present invention is a kind of helium online recycling equipment for purifying, including retracting device 1 and purification fill Set 2;Retracting device 1 includes recycling gas tank 101 and vacuum pump 102;The entrance for recycling gas tank 101 is consolidated with the outlet of helium equipment 3 Fixed connection;It is fixedly connected by gas piping with helium device 5 is mended with the entrance of helium equipment 3;With the gas of the inlet of helium equipment 3 Pipeline week, side was installed with mass flowmenter 4;The outlet of recycling gas tank 101 is fixedly connected with vacuum pump 102;Vacuum pump 102 are fixedly connected with the entrance of the heat exchanger 201 of purifying plant 2;
Purifying plant 2 includes heat exchanger 201, filter 202, level-one membrane separator 203, two level membrane separator 204 and helium Gas concentration detector 205;The outlet of heat exchanger 201 is fixedly connected with the entrance of filter 202;The outlet of filter 202 and one The entrance of grade membrane separator 203 is fixedly connected;Level-one membrane separator 203 outlet respectively with the entrance of two level membrane separator 204, The entrance of recycling gas tank 101 is fixedly connected with the entrance of helium equipment 3;Heat exchanger 3 can by cold air, refrigerant, cold follow The low-temperature receivers such as ring water when by 2 gas cooling after supercharged of vacuum pump to specific temperature, and remove liquid water;
The infiltration air pipe week side of level-one membrane separator 203 is installed with a concentrations of helium detector 205;Two level Membrane separator 204 is fixedly connected by permeating gas piping with the entrance for recycling gas tank 101;Gas in two level membrane separator 6 The effect backflowed in recycling gas tank 101 is, it is possible to reduce the loss of helium, impermeable gas emptying, impermeable gas pipeline can be adopted With needle-valve or back pressure pressure regulating valve.
Wherein, it recycles inside gas tank 101 and is installed with dust removal filter and cooling gas check valve;The effect of cooling gas check valve It is to prevent gas backstreaming;Due to being had differences with helium equipment 3, recycling gas tank 101 carries out concentrations of helium within the scope of 10-90% Recycling;Recycling equipment for purifying i.e. of the invention can to concentrations of helium being recycled containing helium gas mixture within the scope of 10-90% Purification processes.
Wherein, the filtering accuracy of filter 202 is 0.01 micron;It is micro- that the filtering accuracy requirement of filter 202 reaches 0.01 The effect of rice is can to remove ultrafine dust and a small amount of moisture by failing to completely remove in heat exchanger 201.
Wherein, level-one membrane separator 203 and two level membrane separator 204 use asymmetric hollow fiber membrane;Using asymmetric The effect of hollow-fibre membrane is that asymmetric hollow fiber membrane is bigger to containing the segregation ratio in helium mixture, especially air Gas, the refining effect for carrying out helium are better.
Wherein, vacuum pump 102 uses oilless vacuum pump;Oilless vacuum pump have prevent the excellent of oil pollution whole system Point;Vacuum pump 2 generates negative pressure so that recycling in gas tank 1,8 used helium of helium equipment will be used to return by negative pressure nature water conservancy diversion It receives.
Wherein, with helium equipment 3 can be sealing or it is open use helium equipment, i.e. recycling equipment for purifying of the invention can be with To sealing or open carry out real-time helium recovery purification processes with helium equipment.
Wherein, concentrations of helium detector 205 for detecting concentrations of helium in real time;It can be set in concentrations of helium detector 205 Surely concentrations of helium threshold value up to standard is purified, such as when given threshold is 99.0%, when concentrations of helium detector 205 monitors helium Concentration>When 99.0%, before helium returns to mass flowmenter MFC4 according to the paths A, supply is recycled with helium equipment 3;It is no Then concentrations of helium<99.0%, it returns in recycling gas tank 101 according to B path and is purified again.
Wherein, heat exchanger 3 can also with freezing type drier come instead of using.
Wherein, it is installed with microprocessor on vacuum pump 102;Mass flowmenter MFC4 is connect with A/D converter;A/D Converter is connect with microprocessor;Mass flowmenter MFC4 exports electric signal to A/D converter;A/D converter is to microprocessor Output data information;Microprocessor carries out size judgement according to the data information of reception and the activation threshold value of setting, and to vacuum The switch module output of pump 102 opens or closes order;When the data information of reception is more than the activation threshold value of setting, microprocessor It is exported to switch module and opens order;It is on the contrary then export shutdown command;Have the advantages that realize intelligent operation.
Wherein, it can be installed with level-one oilless vacuum pump between level-one membrane separator 5 and two level membrane separator 6, be used for Make up vacuum pump 2 be pressurized it is limited and the problem of lead to insufficient pressure, so that it is guaranteed that two level membrane separator 6 can maintain it is one higher Separative efficiency.
Wherein, it can be equipped on the gas piping between each component in recycling equipment for purifying of the invention multiple unidirectional The components such as valve, pressure sensor, flowmeter, temperature sensor, for monitoring in real time and recording each section parameter values, unidirectionally The control switch of valve is connect with microprocessor;Pressure sensor, flowmeter, temperature sensor are by A/D converter to microprocessor Device output data information;The data information that microprocessor receives realizes remote data transmission, tool by GPS module and system terminal Have real time monitoring, facilitate management, and when there is abnormal data, can find in time, timely processing the advantages of.
The operation principle of the present embodiment is:Mass flowmenter MFC is to the microprocessor feedback data information of vacuum pump, micro- place Manage the start and stop that device controls vacuum pump by given threshold;Vacuum pump generates negative pressure in recycling gas tank, passes through negative-pressure guide effect It will use in the used helium indentation recycling gas tank of helium equipment institute, and be pressurized by vacuum pump;Recycling helium after supercharged passes through Heat exchanger, filter etc. remove the impurity such as dust, moisture, then detach and obtain in level-one membrane separator and two level membrane separator The helium of required concentration, and monitor and show in real time by concentrations of helium detector;By the way that the paths A and B path is arranged, realize With concentrations of helium detector data locking, reused with helium equipment by the supply of the paths A when concentrations of helium is met the requirements, it is no Then by B path return as recycling gas tank purify again, so that it is guaranteed that purification after helium quality.
In the description of this specification, the description of reference term " one embodiment ", " example ", " specific example " etc. means Particular features, structures, materials, or characteristics described in conjunction with this embodiment or example are contained at least one implementation of the present invention In example or example.In the present specification, schematic expression of the above terms may not refer to the same embodiment or example. Moreover, particular features, structures, materials, or characteristics described can be in any one or more of the embodiments or examples to close Suitable mode combines.
Present invention disclosed above preferred embodiment is only intended to help to illustrate the present invention.There is no detailed for preferred embodiment All details are described, are not limited the invention to the specific embodiments described.Obviously, according to the content of this specification, It can make many modifications and variations.These embodiments are chosen and specifically described to this specification, is in order to preferably explain the present invention Principle and practical application, to enable skilled artisan to be best understood by and utilize the present invention.The present invention is only It is limited by claims and its full scope and equivalent.

Claims (5)

1. a kind of helium online recycling equipment for purifying, it is characterised in that:Including retracting device (1) and purifying plant (2);
The retracting device (1) includes recycling gas tank (101) and vacuum pump (102);The entrance and use of the recycling gas tank (101) The outlet of helium equipment (3) is fixedly connected;The entrance with helium equipment (3) fixes company by gas piping with helium device (5) is mended It connects;It is described to be installed with mass flowmenter MFC (4) with the gas piping week side of the inlet of helium equipment (3);The recycling The outlet of gas tank (101) is fixedly connected with vacuum pump (102);The heat exchanger of the vacuum pump (102) and purifying plant (2) (201) entrance is fixedly connected;
The purifying plant (2) includes heat exchanger (201), filter (202), level-one membrane separator (203), two level membrane separator (204) and concentrations of helium detector (205);The outlet of the heat exchanger (201) is fixedly connected with the entrance of filter (202); The outlet of the filter (202) is fixedly connected with the entrance of level-one membrane separator (203);The level-one membrane separator (203) Outlet consolidate respectively with the entrance of two level membrane separator (204), the entrance of recycling gas tank (101) and with the entrance of helium equipment (3) Fixed connection;
The infiltration air pipe week side of the level-one membrane separator (203) is installed with a concentrations of helium detector (205); The two level membrane separator (204) is fixedly connected by permeating gas piping with the entrance for recycling gas tank (101).
2. a kind of helium online recycling equipment for purifying according to claim 1, which is characterized in that the recycling gas tank (101) internal to be installed with dust removal filter and cooling gas check valve.
3. a kind of helium online recycling equipment for purifying according to claim 1, which is characterized in that the filter (202) Filtering accuracy be 0.01 micron.
4. a kind of helium online recycling equipment for purifying according to claim 1, which is characterized in that the level-one membrane separator (203) and two level membrane separator (204) uses asymmetric hollow fiber membrane.
5. a kind of helium online recycling equipment for purifying according to claim 1, which is characterized in that the vacuum pump (102) Using oilless vacuum pump.
CN201810355398.9A 2018-04-19 2018-04-19 A kind of helium online recycling equipment for purifying Pending CN108328588A (en)

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CN201810355398.9A CN108328588A (en) 2018-04-19 2018-04-19 A kind of helium online recycling equipment for purifying

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111573643A (en) * 2020-06-09 2020-08-25 安徽中科皖能科技有限公司 Helium recovery and purification device and method
CN114115083A (en) * 2022-01-26 2022-03-01 南通西屋智能科技有限公司 Automatic control method and system for improving helium gas recovery quality

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Publication number Priority date Publication date Assignee Title
EP0621070A2 (en) * 1993-04-21 1994-10-26 Praxair Technology, Inc. Pressurizing with and recovering helium
JP2003192315A (en) * 2001-12-19 2003-07-09 Sumitomo Seika Chem Co Ltd Equipment for refining helium
CN103553322A (en) * 2013-10-22 2014-02-05 安徽万瑞冷电科技有限公司 Helium-rich tail gas recovering and purifying online circulating system for optical fiber production
CN103771362A (en) * 2014-01-25 2014-05-07 安徽万瑞冷电科技有限公司 Online purifying system of waste helium generated in optical fiber manufacturing
CN104001409A (en) * 2014-05-22 2014-08-27 上海精腾新能源科技有限公司 Membrane-method helium purifying device system and process
CN208200387U (en) * 2018-04-19 2018-12-07 合肥硕朗自动化科技有限公司 A kind of helium online recycling equipment for purifying

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
EP0621070A2 (en) * 1993-04-21 1994-10-26 Praxair Technology, Inc. Pressurizing with and recovering helium
JP2003192315A (en) * 2001-12-19 2003-07-09 Sumitomo Seika Chem Co Ltd Equipment for refining helium
CN103553322A (en) * 2013-10-22 2014-02-05 安徽万瑞冷电科技有限公司 Helium-rich tail gas recovering and purifying online circulating system for optical fiber production
CN103771362A (en) * 2014-01-25 2014-05-07 安徽万瑞冷电科技有限公司 Online purifying system of waste helium generated in optical fiber manufacturing
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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111573643A (en) * 2020-06-09 2020-08-25 安徽中科皖能科技有限公司 Helium recovery and purification device and method
CN114115083A (en) * 2022-01-26 2022-03-01 南通西屋智能科技有限公司 Automatic control method and system for improving helium gas recovery quality

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