CN108323565A - A kind of navel orange preserving agent and preparation method thereof - Google Patents

A kind of navel orange preserving agent and preparation method thereof Download PDF

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Publication number
CN108323565A
CN108323565A CN201711412304.9A CN201711412304A CN108323565A CN 108323565 A CN108323565 A CN 108323565A CN 201711412304 A CN201711412304 A CN 201711412304A CN 108323565 A CN108323565 A CN 108323565A
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Prior art keywords
navel orange
parts
chitosan
mass fraction
added
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CN201711412304.9A
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Chinese (zh)
Inventor
刘晓艳
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Qingdao Madil Biological Engineering Co Ltd
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Qingdao Madil Biological Engineering Co Ltd
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Priority to CN201711412304.9A priority Critical patent/CN108323565A/en
Publication of CN108323565A publication Critical patent/CN108323565A/en
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    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/154Organic compounds; Microorganisms; Enzymes
    • AHUMAN NECESSITIES
    • A23FOODS OR FOODSTUFFS; TREATMENT THEREOF, NOT COVERED BY OTHER CLASSES
    • A23BPRESERVING, e.g. BY CANNING, MEAT, FISH, EGGS, FRUIT, VEGETABLES, EDIBLE SEEDS; CHEMICAL RIPENING OF FRUIT OR VEGETABLES; THE PRESERVED, RIPENED, OR CANNED PRODUCTS
    • A23B7/00Preservation or chemical ripening of fruit or vegetables
    • A23B7/14Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10
    • A23B7/153Preserving or ripening with chemicals not covered by groups A23B7/08 or A23B7/10 in the form of liquids or solids
    • A23B7/157Inorganic compounds

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • General Chemical & Material Sciences (AREA)
  • Wood Science & Technology (AREA)
  • Zoology (AREA)
  • Food Science & Technology (AREA)
  • Polymers & Plastics (AREA)
  • Inorganic Chemistry (AREA)
  • Microbiology (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)

Abstract

The present invention provides a kind of navel orange preserving agent and preparation method thereof, are prepared by following main component, and by weight, 5 10 parts of chitosan, 15 25 parts of chitosan oligosaccharide, 10 30 parts of glacial acetic acid, 15 parts of glycerine, 0.1 0.5 parts of NaCl, surplus is that hydration is calculated as 100 parts.Antistaling agent provided by the invention can significantly extend the holding time of navel orange, and decayed fruit rate is greatly lowered, and have many advantages, such as that formula is simple, easy to operate.

Description

A kind of navel orange preserving agent and preparation method thereof
Technical field
The present invention relates to antistaling agent technical field, especially a kind of navel orange preserving agent.
Technical background
Navel orange has many advantages, such as that pulp delicacy, the dense sweet tea natural fragrance of flavor are deep to be liked by consumers in general.Navel orange is storing and transporting Rotting rate is up to 30% in the process, brings huge loss for numerous orchard workers, is also unfavorable for the popularization of south jiangxi navel orange industry.Cause The problem of principal element that navel orange goes mouldy is microbial action and adverse weather and picking link.
Chitosan is easy to dissolve in weakly acidic solvent, and amino is contained in dissolved solution, these amino can pass through knot Negative electron is closed to inhibit the growth of bacterium.Chitosan can inhibit the activity of bacterial growth, make it in necks such as medicine, weaving and food Domain has a wide range of applications.In addition chitosan and its derivative has preferable antibacterial activity, can inhibit some fungies, bacterium and The growth and breeding of virus.Chitosan antimicrobial mechanism is mainly the polycation due to chitosan, is easy to fungal cell surface band The group of negative electrical charge acts on, to change the mobility and permeability of pathogen cell membrane;Second is that interfering the duplication of DNA and turning Record;Third, blocking pathogen metabolism.
The purpose of preserving fruit and vegetable utilizing is mainly to maintain fruits and vegetables after picking until shelf life, can maintain normal quality, taste, Nutritional ingredient and appearance improve its commodity value.Coating-film fresh-keeping is carried out with chitosan, film layer has permeability, water preventing ability, can To increase penetration resistance to various gas molecules, a kind of microenvironment is formd, is that the carbon dioxide content in fruits and vegetables tissue increases, Oxygen content reduces, it is suppressed that the respiratory metabolism of fruits and vegetables and moisture loss slow down fruits and vegetables tissue and structure aging, to effectively Extend fruits and vegetables adopts the rear service life.
Chitosan oligosaccharide is made of chitosan depolymerization, is the upgrading products of chitin, chitosan product, can dissolve aspect tool There is the superiority that chitosan is incomparable.Chitosan oligosaccharide prevents or treats by staphylococcus aureus, Escherichia coli, unwrapping wire bar Animal diseases caused by the bacteriums such as bacterium, streptococcus mutans.The disease resistance that can induce plant produces a variety of fungies, bacterium and virus Raw immune and killing effect.
Invention content
It can make navel orange preserving time lengthening while guarantor again non-toxic to humans the purpose of the present invention is to provide a kind of Fresh dose.
The purpose of the present invention is achieved through the following technical solutions:A kind of navel orange preserving agent, including following weight group Point
5-10 parts of chitosan,
15-25 parts of chitosan oligosaccharide,
10-30 parts of glacial acetic acid,
Further, the present invention also includes the component of following weight:1-5 parts of glycerine;
Further, the present invention can also include NaCl0.1-0.5 parts.
Compared with the prior art, the present invention has the following advantages:
1. the main component of antistaling agent of the present invention contains antipathogenic composition, the life for leading to the microorganism of navel orange corruption can be inhibited It is long, therefore can significantly extend the fresh keeping time of navel orange;
2. antistaling agent is different from, drug is fresh-keeping, and ingredient is all natural component, is had no toxic and side effect to human body, safer;
3. antistaling agent can form one layer of diaphragm, air can be obstructed, to reduce the exposure of oxygen, reduces breathing Effect, film with, since oxygen is constantly consumed, CO2 contents are continuously increased in the microenvironment on navel orange surface, form a kind of hypoxemia height CO2 environment reduces oxidation, therefore can keep the gloss of navel orange for a long time using this antistaling agent.
Specific implementation mode
The present invention is described in detail in present invention combination specific embodiment
Embodiment 1
The antistaling agent that the present embodiment is related to is configured by the component of following mass parts:
A kind of navel orange preserving agent, including following components by weight percent:5-10 parts of chitosan, 15-25 parts of chitosan oligosaccharide, glacial acetic acid 10- 30 parts, 1-5 parts of glycerine, NaCl0.1-0.5 parts, surplus is water, amounts to 100 parts.
Embodiment 2
The present embodiment is on the basis of embodiment 1, as a preferred embodiment, navel orange preserving agent is by following quality The component configuration of part:5 parts of glycan, 15 parts of chitosan oligosaccharide, 10 parts of glacial acetic acid, 1 part, NaCl0.1 parts of glycerine;Surplus is water, amounts to 100 Part.
Embodiment 3:
As a preferred embodiment, navel orange preserving agent is configured by the component of following mass parts:10 parts of chitosan, shell 25 parts of oligosaccharides, 30 parts of glacial acetic acid, 5 parts, NaCl0.5 parts of glycerine;Surplus is water, amounts to 100 parts.
Embodiment 4:
As a preferred embodiment, navel orange preserving agent is configured by the component of following mass parts:7.5 parts of chitosan, 20 parts of chitosan oligosaccharide, 15 parts of glacial acetic acid, 2.5 parts of glycerine, NaCl0.25 parts, surplus is water, amounts to 100 parts.
A kind of preparation method of navel orange preserving agent of the present invention, is realized by following steps:
Step 1:Configuration quality score is the acetum of 10%-30%;
Step 2:Be added chitosan in acetum described in step 1,60-70 DEG C of heating water bath to being completely dissolved, The mass fraction for controlling chitosan is 5%-10%;
Step 3:Be added chitosan oligosaccharide in solution described in above-mentioned steps two, 30-40 DEG C of heating water bath to being completely dissolved, The mass fraction for controlling chitosan oligosaccharide is 15%-25%;
Step 4:NaCl is added in solution described in above-mentioned steps three, 30-40 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of NaCl processed is 0.1%-0.5%;
Step 5:Glycerine is added in solution described in above-mentioned steps four, 20-30 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of glycerine processed is 1%-5%;
Step 6:Navel orange will just be picked and immersed in clear water and impregnate 10-20s, after drying, navel orange is immersed into five institute of above-mentioned steps 20-30s in the solution stated pulls navel orange out to navel orange surface without dripping at stock liquid, under the conditions of 25-30 DEG C, dries 10-20min.
Embodiment 5
In a kind of preferred preparation method,
Step 1:The acetum that configuration quality score is 10%;
Step 2:Chitosan is added in acetum described in step 1,60 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of chitosan is 5%;
Step 3:Chitosan oligosaccharide is added in solution described in above-mentioned steps two, 30 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of chitosan oligosaccharide is 15%;
Step 4:NaCl is added in solution described in above-mentioned steps three, 30 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of NaCl is 0.1%;
Step 5:Glycerine is added in solution described in above-mentioned steps four, 20-30 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of glycerine processed is 1%;
Step 6:Navel orange will just be picked and immersed in clear water and impregnate 10s, after drying, navel orange will be immersed described in above-mentioned steps five Solution in 20s, pull navel orange out to navel orange surface without dripping at stock liquid, under the conditions of 25 DEG C, dry 10min.
Embodiment 6
A kind of preferred preparation method:
Step 1:The acetum that configuration quality score is 30%;
Step 2:Chitosan is added in acetum described in step 1,60 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of chitosan is 10%;
Step 3:Chitosan oligosaccharide is added in solution described in above-mentioned steps two, 30 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of chitosan oligosaccharide is 25%;
Step 4:NaCl is added in solution described in above-mentioned steps three, 30 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of NaCl is 0.5%;
Step 5:Glycerine is added in solution described in above-mentioned steps four, 20-30 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of glycerine processed is 5%;
Step 6:Navel orange will just be picked and immersed in clear water and impregnate 10s, after drying, navel orange will be immersed described in above-mentioned steps five Solution in 20s, pull navel orange out to navel orange surface without dripping at stock liquid, under the conditions of 25 DEG C, dry 10min.
Embodiment 7
A kind of preferred preparation method
Step 1:The acetum that configuration quality score is 15%;
Step 2:Chitosan is added in acetum described in step 1,60 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of chitosan is 15%;
Step 3:Chitosan oligosaccharide is added in solution described in above-mentioned steps two, 30 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of chitosan oligosaccharide is 20%;
Step 4:NaCl is added in solution described in above-mentioned steps three, 30 DEG C of heating water baths are controlled to being completely dissolved The mass fraction of NaCl is 0.25%;
Step 5:Glycerine is added in solution described in above-mentioned steps four, 20-30 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of glycerine processed is 2.5%;
Step 6:Navel orange will just be picked and immersed in clear water and impregnate 10s, after drying, navel orange will be immersed described in above-mentioned steps five Solution in 20s, pull navel orange out to navel orange surface without dripping at stock liquid, under the conditions of 25 DEG C, dry 10min.
In the preparation component of the present invention, all components be all it is natural, it is harmless, can play and cooperate with antibacterial work With.There is bacteriostasis, glycerine a kind of plasticiser can be used as to add, improve rate of film build, increased by chitosan, chitosan oligosaccharide, NaCl The toughness of blooming.
Embodiment 8
1. experimental method:
Take 150 sizes uniform, 3 each groups are arranged in the consistent navel orange of color and luster:
(1) blank control group, after taking 50 navel orange clear water to impregnate 10s, 20 DEG C of drying.
(2) another to take 50 navel oranges as positive controls, after clear water impregnates 10s, 20 DEG C of drying, navel orange is dipped into commercialization 20s in chemical agent, 20 DEG C of drying.
(3) experimental group, after taking 50 navel oranges, clear water to impregnate 10s, 20 DEG C of drying, navel orange is dipped into fresh-keeping obtained by the present invention 20s in agent, 20 DEG C of drying.Above-mentioned three groups stand in 25 DEG C of constant incubator, primary every observation in 7 days.
2. experimental result
Influence of 1. Different treatments of table to long term storage navel orange rotting rate
Navel orange in preserving process, will appear over time it is rotten, so the rotting rate of navel orange be judgement it is fresh-keeping The index of effect.Navel orange rotting rate is substantially reduced after having used the navel orange preserving agent of the present invention, is significantly better than control group, and Also slightly it is better than the antistaling agent of commercialization, antistaling agent of the present invention is ingredient than the remarkable advantage of the chemicals antistaling agent of commercialization It is nontoxic, all it is natural component, through antistaling agent of the present invention, treated that its surface of navel orange forms thin film, and the film is in navel Orange surface forms a microenvironment for hindering air to be contacted with navel orange surface so that and oxygen is not easy to contact with navel orange surface, To reduce respiration, rot because of postmaturity to greatly avoid fruit.In addition in microenvironment rich in antibacterial, Antibacterial component can effectively inhibit the growth for the microorganism that navel orange surface causes navel orange rotten.The film is dropped due to having completely cut off air Low Surface Oxygen rate, and greatly enhanced at film toughness due to being added to glycerine so that navel orange surface is more smooth, and color and luster becomes Rate is significantly less than control group.
Influence of 2. Different treatments of table to long term storage navel orange weight-loss ratio
Caused by weight-loss ratio is respiration and transpiration after navel orange picking, weight-loss ratio can also be made For the mark for judging fresh-keeping.Experimental group weight-loss ratio is significantly less than control group, the reason is that the film can obstruct transpiration, reduction is exhaled Suction acts on, to reduce the loss of moisture, simultaneously because the film component can be effectively reduced because of microbial action with antibacterial Caused by loss of water.
Influence of 3. Different treatments of table to long term storage navel orange Vc contents
Vitamin C is important one of the nutritional ingredient of fruit, therefore its content can react the fresh-keeping effect of navel orange.With The extension of time, orange fruit is constantly ripe, and Vc contents are lower and lower, but apply the experimental group of antistaling agent of the present invention due to The respiration of orange is reduced, thus the Vc contents of orange decline degree significantly less than control group.

Claims (4)

1. a kind of navel orange preserving agent, it is characterised in that:It is configured by weight by following components,
5-10 parts of chitosan,
15-25 parts of chitosan oligosaccharide,
10-30 parts of glacial acetic acid,
35-70 parts of water.
2. a kind of navel orange preserving agent according to claim 1, it is characterised in that:
Also include 1-5 parts of glycerine in component.
3. a kind of navel orange preserving agent according to claim 1 or 2, it is characterised in that:
Also include NaCl0.1-0.5 parts in component.
4. a kind of preparation method of navel orange preserving agent, it is characterised in that:It is realized by following steps:
Step 1:Configuration quality score is the acetum of 10%-30%;
Step 2:Chitosan is added in acetum described in step 1,60-70 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of chitosan is 5%-10%;
Step 3:Chitosan oligosaccharide is added in solution described in above-mentioned steps two, 30-40 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of chitosan oligosaccharide is 15%-25%;
Step 4:NaCl is added in solution described in above-mentioned steps three, 30-40 DEG C of heating water bath is controlled to being completely dissolved The mass fraction of NaCl is 0.1%-0.5%;
Step 5:Glycerine is added in solution described in above-mentioned steps four, for 20-30 DEG C of heating water bath to being completely dissolved, control is sweet The mass fraction of oil is 1%-5%;
Step 6:Navel orange will just be picked and immersed in clear water and impregnate 10-20s, after drying, navel orange will be immersed described in above-mentioned steps five 20-30s in solution pulls navel orange out to navel orange surface without dripping at stock liquid, under the conditions of 25-30 DEG C, dries 10-20min.
CN201711412304.9A 2017-12-23 2017-12-23 A kind of navel orange preserving agent and preparation method thereof Withdrawn CN108323565A (en)

Priority Applications (1)

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CN201711412304.9A CN108323565A (en) 2017-12-23 2017-12-23 A kind of navel orange preserving agent and preparation method thereof

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Application Number Priority Date Filing Date Title
CN201711412304.9A CN108323565A (en) 2017-12-23 2017-12-23 A kind of navel orange preserving agent and preparation method thereof

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101513211A (en) * 2009-04-03 2009-08-26 西南大学 Complex biological preservative formula of citrus fruit chitosan oligosaccharide
CN106305992A (en) * 2016-08-18 2017-01-11 陕西科技大学 Strawberry bio-preservative combining with lysozyme, propolis and chitosan and preparation method thereof
US20170013850A1 (en) * 2014-03-18 2017-01-19 Vural Gokmen A solution for extending shelf life of ready-to-eat fresh fruits and/or vegetables and an application method thereof
CN107232299A (en) * 2017-06-29 2017-10-10 中国水产科学研究院黄海水产研究所 A kind of citrus antimicrobial antistaling agent

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101513211A (en) * 2009-04-03 2009-08-26 西南大学 Complex biological preservative formula of citrus fruit chitosan oligosaccharide
US20170013850A1 (en) * 2014-03-18 2017-01-19 Vural Gokmen A solution for extending shelf life of ready-to-eat fresh fruits and/or vegetables and an application method thereof
CN106305992A (en) * 2016-08-18 2017-01-11 陕西科技大学 Strawberry bio-preservative combining with lysozyme, propolis and chitosan and preparation method thereof
CN107232299A (en) * 2017-06-29 2017-10-10 中国水产科学研究院黄海水产研究所 A kind of citrus antimicrobial antistaling agent

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Application publication date: 20180727

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