CN108320816A - A kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load - Google Patents

A kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load Download PDF

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Publication number
CN108320816A
CN108320816A CN201810072472.6A CN201810072472A CN108320816A CN 108320816 A CN108320816 A CN 108320816A CN 201810072472 A CN201810072472 A CN 201810072472A CN 108320816 A CN108320816 A CN 108320816A
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CN
China
Prior art keywords
boron carbide
carbide coating
tungsten substrate
tungsten
heat resistance
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Pending
Application number
CN201810072472.6A
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Chinese (zh)
Inventor
许铁军
韩乐
姚达毛
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Hefei Institutes of Physical Science of CAS
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Hefei Institutes of Physical Science of CAS
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Priority to CN201810072472.6A priority Critical patent/CN108320816A/en
Publication of CN108320816A publication Critical patent/CN108320816A/en
Pending legal-status Critical Current

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    • GPHYSICS
    • G21NUCLEAR PHYSICS; NUCLEAR ENGINEERING
    • G21BFUSION REACTORS
    • G21B1/00Thermonuclear fusion reactors
    • G21B1/11Details
    • G21B1/13First wall; Blanket; Divertor
    • YGENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
    • Y02TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
    • Y02EREDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
    • Y02E30/00Energy generation of nuclear origin
    • Y02E30/10Nuclear fusion reactors

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  • Physics & Mathematics (AREA)
  • Engineering & Computer Science (AREA)
  • Plasma & Fusion (AREA)
  • General Engineering & Computer Science (AREA)
  • High Energy & Nuclear Physics (AREA)
  • Coating By Spraying Or Casting (AREA)

Abstract

The invention discloses a kind of tungsten substrate nickel packet boron carbide coating cooling structures of high heat resistance load, including apply the tungsten substrate in tokamak device, and are sprayed on the nickel packet boron carbide coating of tungsten substrate surface.The present invention proposes a kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load.The structure carries out heat fatigue test according to actual basic cooling unit situation design structure.The present invention by the cooling-part of substrate of tungsten mainly to carrying out the work, and structure can bear stable state thermic load not less than 5 MW/m after spray coating boron carbide coating2

Description

A kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load
Technical field
The present invention relates to a kind of tungsten substrate nickel packet boron carbide coating coolings of high heat resistance load in tokamak device field Structure.
Background technology
EAST(Experimental Advanced Superconducting Tokamak)Tokamak device divertor Target plate material is gradually from graphite to tungsten transition.Tungsten is considered as the preferred material of first wall components such as the following fusion reactor divertor target plate Material, however tungsten belongs to high Z(Atomic number)Material can cause heavy seeds poly- when plasma is run since tungsten inclusion sputters Core declines so as to cause plasma restraint performance, or even plasma is caused to vanish.
It can solve the problems, such as that tungsten sputters using the method in high Z materials such as tungsten surface spraying boron carbide coatings.Boron carbide applies Layer absorbs the features such as ability and boron carbide Flouride-resistani acid phesphatase of neutron using wherein boron, and the control rod of reactor is used in nuclear technology field The security mask material etc. of material and reactor core.
Boron carbide coating is mainly concentrated in both at home and abroad at present and prepares evenly fine and close boron carbide coating, improve painting Binding force, reduction coating stress between layer and matrix.Nearest foreign countries have scholar to suggest that spraying pure boron carbide on divertor applies Layer, the stable state hot-fluid that heat fatigue is tested in the case of no cooling can reach 1MW/m2
The invention content present invention be for overcome the deficiencies in the prior art place, a kind of tungsten base of high heat resistance load is provided Bottom nickel packet boron carbide coating cooling structure solves the problems, such as that structure tungsten material surface when plasma is run sputters.
In order to achieve the above object, the technical solution adopted in the present invention is:
A kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load, it is characterised in that:Including applying in support Karma Tungsten substrate in gram device, and it is sprayed on the nickel packet boron carbide coating of tungsten substrate surface, in the nickel packet boron carbide coating, nickel Content accounts for the 55%-65% of total weight, and the content of boron carbide accounts for the 35%-45% of total weight.
A kind of tungsten substrate nickel packet boron carbide coating cooling structure of the high heat resistance load, it is characterised in that:Nickel packet carbon Change in boron coating, when the content that the content of nickel accounts for the 60% of total weight, boron carbide accounts for the 40% of total weight, nickel packet boron carbide coating exists Tungsten substrate surface reaches best interface binding power.
A kind of tungsten substrate nickel packet boron carbide coating cooling structure of the high heat resistance load, it is characterised in that:Nickel packet carbon Change boron coating using plasma and is sprayed on tungsten substrate surface.
A kind of tungsten substrate nickel packet boron carbide coating cooling structure of the high heat resistance load, it is characterised in that:Plasma Flame temperature control is at 10000-12000 degrees Celsius when body sprays, preferably 11000 degrees Celsius.
Compared with the prior art, beneficial effects of the present invention are embodied in:
The present invention, in tungsten surface spraying boron carbide coating, reaches best interface binding power by adjusting the content of nickel is mixed.
The present invention carries out heat fatigue test according to actual basic cooling unit situation design structure, and structure can be born surely State thermic load is not less than 5 MW/m2, boron carbide coating does not fall off or occurs other abnormal conditions in test process, solves structure and exists Tungsten material surface sputters problem when plasma is run.
The present invention extends to the tungsten part coating cooling structure of the high heat resistance load of all anti-neutron radiations.
Description of the drawings
Fig. 1 is tungsten substrate nickel packet boron carbide coating cooling structure basic unit.
Fig. 2 is the front and back comparison of tungsten string spray coating boron carbide coating, wherein:
Fig. 2 a are tungsten string before spraying, and Fig. 2 b are tungsten string after spraying.
Fig. 3 is heat fatigue test block.
Fig. 4 is test surfaces thermal cycling temperature(1000 times), wherein:Fig. 4 a are test surfaces 1, and Fig. 4 b are test surfaces 2。
Fig. 5 is the photo for testing latter two surface.
Specific implementation mode
Embodiments of the present invention are described in further detail with reference to embodiment and attached drawing, implementation of the invention Mode is without being limited thereto.
Embodiment 1
The structured testing is mainly that EAST lower hybrid wave slicer designs provide foundation, and the first wall components of limiter front end will use tungsten Cooling structure, tungsten substrate nickel packet boron carbide coating cooling structure basic unit are as shown in Figure 1.This spraying tungsten substrate 101 be Tungsten string, tungsten substrate 101 overall length 270mm, Fig. 2 are that tungsten string sprays forward and backward photo.201 coating thickness of nickel packet boron carbide coating, 100 μ M, wherein nickel content 60%, be carbonized boron content 40%.Using plasma sprays, about 11000 degrees Celsius of flame temperature.
Test block is as shown in Figure 3.It has chosen as shown in Figure 21,2 positions and carries out heat fatigue test.
It obtains lower hybrid wave to protect limiter tungsten hot face temperature under 4m/s flow conditions being 248 by numerical computations DEG C, and heat fatigue test maximum temperature need it is 100 DEG C higher than numerical computations, therefore heat fatigue test maximum temperature determine exist 400℃.1 temperature of test surfaces changes in room temperature ~ 434 DEG C, 5.25 MW/m of heat flow density2, single thermal cycle times are 31s;It surveys 2 temperature of face of taking temperature changes at 100 ~ 416 DEG C, 6.94 MW/m of heat flow density2, single thermal cycle times are 53s.Two test tables Face is different in temperature, surface thermal power and thermal cycle times etc., and reason is the tungsten string that manufacturer provides Welding quality is different everywhere, affects heat transfer property everywhere.Fig. 4 is the thermal cycling temperature of test surfaces 1 and 2, is recycled altogether 1000 times.After 1000 cycles, two test surfaces do not observe that boron carbide coating falls off or other abnormal conditions, sees Heat fatigue shown in Fig. 5 tests the photo on latter two surface, and it is not small to show that the tungsten string structure of the design can bear stable state thermic load In 5 MW/m2

Claims (4)

1. a kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load, it is characterised in that:Block in support including applying Tungsten substrate in mark's device, and it is sprayed on the nickel packet boron carbide coating of tungsten substrate surface, in the nickel packet boron carbide coating, nickel Content account for the 55%-65% of total weight, the content of boron carbide accounts for the 35%-45% of total weight.
2. a kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load according to claim 1, feature It is:In nickel packet boron carbide coating, when the content that the content of nickel accounts for the 60% of total weight, boron carbide accounts for the 40% of total weight, nickel packet Boron carbide coating reaches best interface binding power in tungsten substrate surface.
3. a kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load according to claim 1, feature It is:Nickel packet boron carbide coating using plasma is sprayed on tungsten substrate surface.
4. a kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load according to claim 3, feature It is:Flame temperature control is at 10000-12000 degrees Celsius when plasma spray coating, preferably 11000 degrees Celsius.
CN201810072472.6A 2018-01-25 2018-01-25 A kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load Pending CN108320816A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810072472.6A CN108320816A (en) 2018-01-25 2018-01-25 A kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810072472.6A CN108320816A (en) 2018-01-25 2018-01-25 A kind of tungsten substrate nickel packet boron carbide coating cooling structure of high heat resistance load

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Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2804452C1 (en) * 2020-11-19 2023-09-29 Токемек Энерджи Лтд Blanket breeder
US11869677B2 (en) 2020-11-19 2024-01-09 Tokamak Energy Ltd Breeder blanket for nuclear fusion reactor

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1787115A (en) * 2005-10-27 2006-06-14 中国科学院等离子体物理研究所 First wall part coated with thick wolfram coat or copper alloy heat sink and mfg. method thereof
CN103422048A (en) * 2012-05-14 2013-12-04 中国科学院上海硅酸盐研究所 High abrasion resistant boron carbide coating layer and preparation method thereof
CN105886995A (en) * 2016-03-23 2016-08-24 上海工程技术大学 Preparation method of B4C (boron carbide)/aluminum composite coating

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1787115A (en) * 2005-10-27 2006-06-14 中国科学院等离子体物理研究所 First wall part coated with thick wolfram coat or copper alloy heat sink and mfg. method thereof
CN100367414C (en) * 2005-10-27 2008-02-06 中国科学院等离子体物理研究所 First wall part coated with thick wolfram coat or copper alloy heat sink and mfg. method thereof
CN103422048A (en) * 2012-05-14 2013-12-04 中国科学院上海硅酸盐研究所 High abrasion resistant boron carbide coating layer and preparation method thereof
CN105886995A (en) * 2016-03-23 2016-08-24 上海工程技术大学 Preparation method of B4C (boron carbide)/aluminum composite coating

Non-Patent Citations (5)

* Cited by examiner, † Cited by third party
Title
E.AZIZOV ET AL.: "Boron carbide(B4C)coating.Deposition and testing", 《JOURNAL OF NUCLEAR MATERIALS》 *
XIANG LIU ET AL.: "Erosion and erosion products of tungsten and carbon-based materials irradiated by a high energy electron beam", 《JOURNAL OF NUCLEAR MATERIALS》 *
吴明忠 等: "B4C颗粒增强镍基合金喷涂层耐磨性研究", 《佳木斯大学学报(自然科学版)》 *
赵冬梅: "激光熔覆镍包碳化硼界面耦合机制及其组织性能研究", 《万方数据》 *
顾立德: "《特种耐火材料》", 31 March 2006, 冶金工业出版社 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
RU2804452C1 (en) * 2020-11-19 2023-09-29 Токемек Энерджи Лтд Blanket breeder
US11869677B2 (en) 2020-11-19 2024-01-09 Tokamak Energy Ltd Breeder blanket for nuclear fusion reactor

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Application publication date: 20180724