CN108314465A - A kind of energy-conserving thermal insulation board of high fire-retardance and preparation method thereof - Google Patents
A kind of energy-conserving thermal insulation board of high fire-retardance and preparation method thereof Download PDFInfo
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- CN108314465A CN108314465A CN201810269079.6A CN201810269079A CN108314465A CN 108314465 A CN108314465 A CN 108314465A CN 201810269079 A CN201810269079 A CN 201810269079A CN 108314465 A CN108314465 A CN 108314465A
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- 238000009413 insulation Methods 0.000 title claims abstract description 28
- 238000002360 preparation method Methods 0.000 title claims abstract description 13
- OFBQJSOFQDEBGM-UHFFFAOYSA-N Pentane Chemical compound CCCCC OFBQJSOFQDEBGM-UHFFFAOYSA-N 0.000 claims abstract description 30
- KXGFMDJXCMQABM-UHFFFAOYSA-N 2-methoxy-6-methylphenol Chemical compound [CH]OC1=CC=CC([CH])=C1O KXGFMDJXCMQABM-UHFFFAOYSA-N 0.000 claims abstract description 17
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims abstract description 17
- 239000010459 dolomite Substances 0.000 claims abstract description 17
- 229910000514 dolomite Inorganic materials 0.000 claims abstract description 17
- 239000000428 dust Substances 0.000 claims abstract description 17
- 239000004088 foaming agent Substances 0.000 claims abstract description 17
- 239000010439 graphite Substances 0.000 claims abstract description 17
- 229910002804 graphite Inorganic materials 0.000 claims abstract description 17
- 229920001568 phenolic resin Polymers 0.000 claims abstract description 17
- 239000005011 phenolic resin Substances 0.000 claims abstract description 17
- 229910000410 antimony oxide Inorganic materials 0.000 claims abstract description 16
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 16
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims abstract description 16
- VTRUBDSFZJNXHI-UHFFFAOYSA-N oxoantimony Chemical compound [Sb]=O VTRUBDSFZJNXHI-UHFFFAOYSA-N 0.000 claims abstract description 16
- 239000002994 raw material Substances 0.000 claims abstract description 11
- 239000004615 ingredient Substances 0.000 claims description 36
- 239000006260 foam Substances 0.000 claims description 12
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 12
- 239000003063 flame retardant Substances 0.000 claims description 8
- 230000004520 agglutination Effects 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 6
- 239000008367 deionised water Substances 0.000 claims description 6
- 229910021641 deionized water Inorganic materials 0.000 claims description 6
- 238000005187 foaming Methods 0.000 claims description 6
- 239000003292 glue Substances 0.000 claims description 6
- 238000007731 hot pressing Methods 0.000 claims description 6
- 239000000155 melt Substances 0.000 claims description 6
- 238000002156 mixing Methods 0.000 claims description 6
- 239000003795 chemical substances by application Substances 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 8
- 229920006328 Styrofoam Polymers 0.000 abstract description 3
- 239000004814 polyurethane Substances 0.000 abstract description 3
- 239000008261 styrofoam Substances 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 2
- 238000004519 manufacturing process Methods 0.000 abstract description 2
- 231100000614 poison Toxicity 0.000 abstract description 2
- 230000007096 poisonous effect Effects 0.000 abstract description 2
- 229920002635 polyurethane Polymers 0.000 abstract description 2
- 230000035939 shock Effects 0.000 abstract description 2
- 239000000243 solution Substances 0.000 description 4
- 238000002347 injection Methods 0.000 description 3
- 239000007924 injection Substances 0.000 description 3
- 238000000034 method Methods 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000012774 insulation material Substances 0.000 description 2
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 229910052787 antimony Inorganic materials 0.000 description 1
- WATWJIUSRGPENY-UHFFFAOYSA-N antimony atom Chemical compound [Sb] WATWJIUSRGPENY-UHFFFAOYSA-N 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 238000010276 construction Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 239000004795 extruded polystyrene foam Substances 0.000 description 1
- 235000013312 flour Nutrition 0.000 description 1
- 238000000465 moulding Methods 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B38/00—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof
- C04B38/10—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam
- C04B38/106—Porous mortars, concrete, artificial stone or ceramic ware; Preparation thereof by using foaming agents or by using mechanical means, e.g. adding preformed foam by adding preformed foams
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/10—Macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/12—Condensation polymers of aldehydes or ketones
- C04B26/122—Phenol-formaldehyde condensation polymers
-
- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B2111/00—Mortars, concrete or artificial stone or mixtures to prepare them, characterised by specific function, property or use
- C04B2111/20—Resistance against chemical, physical or biological attack
- C04B2111/28—Fire resistance, i.e. materials resistant to accidental fires or high temperatures
- C04B2111/285—Intumescent materials
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Materials Engineering (AREA)
- Structural Engineering (AREA)
- Organic Chemistry (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a kind of energy-conserving thermal insulation boards of high fire-retardance, are made of the raw material below according to parts by weight：13 parts of 25 30 parts of dolomite dust, 35 parts of talcum powder, 6 12 parts of expansible graphite, 35 52 parts of phenolic resin, 12 parts of EVA6,25 parts of foaming agent, 12 parts of silester, 1.2 2.5 parts of antimony oxide, 15 23 parts of pentane and DCP crosslinking agents.The preparation method of the thermal insulation board is also disclosed in the present invention.The energy-conserving thermal insulation board of high fire-retardance prepared by the present invention, simple production process, easy to operation, low energy consumption, using poisonous material, cost of material is low, does not pollute the environment, heat insulating ability and good flame resistance, intensity is high, anti-corrosive properties, shock resistance and water-tolerant are the ideal products instead of various polyurethane thermal insulation boards and styrofoam, have prodigious market prospects.
Description
The application is application number 2016102416326, on 04 19th, 2016 applying date, a kind of denomination of invention " high fire-retardance
Energy-conserving thermal insulation board and preparation method thereof " divisional application.
Technical field
The present invention relates to a kind of energy-saving material, the energy-conserving thermal insulation board of specifically a kind of high fire-retardance.
Background technology
With the needs that the quickening of Re-search on Urbanization process and various regions are developed, various buildings are all being built in each place.It builds
Build be building and structures general name, be people to meet social life needs, utilize grasped material technology means,
And the artificial environment created with certain scientific law, geomantic omen theory and aesthetic principle.In recent years, country has put into effect building section
Energy specification, while the requirement to structural fire protection is also increasingly stringenter, and is used in building popular in China market at present inside and outside
Thermal insulation material includes molding styrofoam（EPS）, extruded polystyrene board（XPS）, polyurethane（PU）Material etc., these materials are because fire-retardant
Performance and heat-insulating property are not well positioned to meet the requirement of national construction standards, since China is carrying out the emerging of various buildings
It builds, the thermal insulation material of high flame retardant and high heat insulating ability has prodigious market prospects.
Invention content
It is mentioned above in the background art to solve the purpose of the present invention is to provide a kind of energy-conserving thermal insulation board of high fire-retardance
Problem.
To achieve the above object, the present invention provides the following technical solutions：
A kind of energy-conserving thermal insulation board of high fire-retardance, is made of the raw material below according to parts by weight：25-30 parts of dolomite dust, talcum powder
3-5 parts, 6-12 parts of expansible graphite, 35-52 parts of phenolic resin, EVA6-12 parts, 2-5 parts of foaming agent, 1-2 parts of silester, three
Aoxidize 1-3 parts of 1.2-2.5 parts of two antimony, 15-23 parts of pentane and DCP crosslinking agents, the preparation of the energy-conserving thermal insulation board of the high fire-retardance
Method is as follows：
Silester and antimony oxide are mixed and are stirred 20-30 minutes, then expansible graphite is added thereto by step 1
It is stirred with phenolic resin to being uniformly dispersed, fire retardant is made；
Step 2 dolomite dust, talcum powder, EVA and pentane is mixed evenly under room temperature, and major ingredient is made；
Deionized water is added in foaming agent, then is sufficiently mixed major ingredient and foam at foam by foaming mechanism for step 3,
And agglutination is melted in 200-260 degrees Celsius of glue melts machine, 30-60 degrees Celsius is cooled to, obtains secondary major ingredient；
DCP crosslinking agents are added into secondary major ingredient and are mixed evenly, obtain major ingredient three times for step 4；
Step 5 will be placed on mixer mixing 10-15 minutes at a temperature of 80-105 degrees Celsius for major ingredient three times, be cooled to often
Temperature is then injected into steam hot pressing die and seals mould, is passed through high-pressure water vapor to 0.02-0.10MPa and after being kept for 30-50 seconds,
Unloading pressure can be prepared by final products after cooling and die sinking.
As a further solution of the present invention：It is made of the raw material below according to parts by weight：27-30 parts of dolomite dust is slided
4-5 parts of mountain flour, 8-12 parts of expansible graphite, 42-52 parts of phenolic resin, EVA8-12 parts, 3-5 parts of foaming agent, silester 1-2
Part, 1.6-2.5 parts of antimony oxide, 18-23 parts of pentane and 2-3 parts of DCP crosslinking agents.
As a further solution of the present invention：It is made of the raw material below according to parts by weight：29 parts of dolomite dust, talcum powder
5 parts, 10 parts of expansible graphite, 48 parts of phenolic resin, EVA10 parts, 4 parts of foaming agent, 2 parts of silester, antimony oxide 2.1
3 parts of part, 20 parts of pentane and DCP crosslinking agents.
Compared with prior art, the beneficial effects of the invention are as follows：The energy-conserving thermal insulation board of high fire-retardance prepared by the present invention, production
Simple for process, easy to operation, low energy consumption, and using poisonous material, cost of material is low, does not pollute the environment, heat insulating ability and anti-flammability
Good, intensity is high, anti-corrosive properties, shock resistance and water-tolerant, is the ideal product instead of various polyurethane thermal insulation boards and styrofoam, tool
There are prodigious market prospects.
Specific implementation mode
The technical solution of this patent is described in more detail With reference to embodiment.
Embodiment 1
A kind of energy-conserving thermal insulation board of high fire-retardance, is made of the raw material below according to parts by weight：25 parts of dolomite dust, 3 parts of talcum powder,
6 parts of expansible graphite, 35 parts of phenolic resin, EVA6 parts, 2 parts of foaming agent, 1 part of silester, 1.2 parts of antimony oxide, positive penta
1 part of 15 parts of alkane and DCP crosslinking agents.
The preparation method of the energy-conserving thermal insulation board of the high fire-retardance, is as follows：
Silester and antimony oxide are mixed and are stirred 20 minutes by step 1, then be added thereto expansible graphite and
Phenolic resin is stirred to being uniformly dispersed, and fire retardant is made；
Step 2 dolomite dust, talcum powder, EVA and pentane is mixed evenly under room temperature, and major ingredient is made；
Deionized water is added in foaming agent, then is sufficiently mixed major ingredient and foam at foam by foaming mechanism for step 3,
And agglutination is melted in 200 degrees Celsius of glue melts machine, 30 degrees Celsius is cooled to, obtains secondary major ingredient；
DCP crosslinking agents are added into secondary major ingredient and are mixed evenly, obtain major ingredient three times for step 4；
Step 5 will be placed on mixer mixing 10 minutes at a temperature of 80 degrees Celsius for major ingredient three times, and be cooled to room temperature, then
Seal mould in injection steam hot pressing die, be passed through high-pressure water vapor to 0.02MPa and after being kept for 30 seconds, unloading pressure, it is cooling and
It can be prepared by final products after die sinking.
Embodiment 2
A kind of energy-conserving thermal insulation board of high fire-retardance, is made of the raw material below according to parts by weight：27 parts of dolomite dust, 4 parts of talcum powder,
8 parts of expansible graphite, 42 parts of phenolic resin, EVA8 parts, 3 parts of foaming agent, 1 part of silester, 1.6 parts of antimony oxide, positive penta
2 parts of 18 parts of alkane and DCP crosslinking agents.
The preparation method of the energy-conserving thermal insulation board of the high fire-retardance, is as follows：
Silester and antimony oxide are mixed and are stirred 24 minutes by step 1, then be added thereto expansible graphite and
Phenolic resin is stirred to being uniformly dispersed, and fire retardant is made；
Step 2 dolomite dust, talcum powder, EVA and pentane is mixed evenly under room temperature, and major ingredient is made；
Deionized water is added in foaming agent, then is sufficiently mixed major ingredient and foam at foam by foaming mechanism for step 3,
And agglutination is melted in 220 degrees Celsius of glue melts machine, 40 degrees Celsius is cooled to, obtains secondary major ingredient；
DCP crosslinking agents are added into secondary major ingredient and are mixed evenly, obtain major ingredient three times for step 4；
Step 5 will be placed on mixer mixing 12 minutes at a temperature of 90 degrees Celsius for major ingredient three times, and be cooled to room temperature, then
Seal mould in injection steam hot pressing die, be passed through high-pressure water vapor to 0.05MPa and after being kept for 35 seconds, unloading pressure, it is cooling and
It can be prepared by final products after die sinking.
Embodiment 3
A kind of energy-conserving thermal insulation board of high fire-retardance, is made of the raw material below according to parts by weight：29 parts of dolomite dust, 5 parts of talcum powder,
10 parts of expansible graphite, 48 parts of phenolic resin, EVA10 parts, 4 parts of foaming agent, 2 parts of silester, 2.1 parts of antimony oxide, just
3 parts of 20 parts of pentane and DCP crosslinking agents.
The preparation method of the energy-conserving thermal insulation board of the high fire-retardance, is as follows：
Silester and antimony oxide are mixed and are stirred 27 minutes by step 1, then be added thereto expansible graphite and
Phenolic resin is stirred to being uniformly dispersed, and fire retardant is made；
Step 2 dolomite dust, talcum powder, EVA and pentane is mixed evenly under room temperature, and major ingredient is made；
Deionized water is added in foaming agent, then is sufficiently mixed major ingredient and foam at foam by foaming mechanism for step 3,
And agglutination is melted in 240 degrees Celsius of glue melts machine, 50 degrees Celsius is cooled to, obtains secondary major ingredient；
DCP crosslinking agents are added into secondary major ingredient and are mixed evenly, obtain major ingredient three times for step 4；
Step 5 will be placed on mixer mixing 15 minutes at a temperature of 95 degrees Celsius for major ingredient three times, and be cooled to room temperature, then
Seal mould in injection steam hot pressing die, be passed through high-pressure water vapor to 0.08MPa and after being kept for 45 seconds, unloading pressure, it is cooling and
It can be prepared by final products after die sinking.
Embodiment 4
A kind of energy-conserving thermal insulation board of high fire-retardance, is made of the raw material below according to parts by weight：30 parts of dolomite dust, 5 parts of talcum powder,
12 parts of expansible graphite, 52 parts of phenolic resin, EVA12 parts, 5 parts of foaming agent, 2 parts of silester, 2.5 parts of antimony oxide, just
3 parts of 23 parts of pentane and DCP crosslinking agents.
The preparation method of the energy-conserving thermal insulation board of the high fire-retardance, is as follows：
Silester and antimony oxide are mixed and are stirred 30 minutes by step 1, then be added thereto expansible graphite and
Phenolic resin is stirred to being uniformly dispersed, and fire retardant is made；
Step 2 dolomite dust, talcum powder, EVA and pentane is mixed evenly under room temperature, and major ingredient is made；
Deionized water is added in foaming agent, then is sufficiently mixed major ingredient and foam at foam by foaming mechanism for step 3,
And agglutination is melted in 260 degrees Celsius of glue melts machine, 60 degrees Celsius is cooled to, obtains secondary major ingredient；
DCP crosslinking agents are added into secondary major ingredient and are mixed evenly, obtain major ingredient three times for step 4；
Step 5 will be placed on mixer mixing 15 minutes at a temperature of 105 degrees Celsius for major ingredient three times, and be cooled to room temperature, so
It injects in steam hot pressing die afterwards and seals mould, be passed through high-pressure water vapor to 0.10MPa and after being kept for 50 seconds, unloading pressure is cooling
With can be prepared by final products after die sinking.
The better embodiment of this patent is explained in detail above, but this patent is not limited to above-mentioned embodiment party
Formula, one skilled in the relevant art within the scope of knowledge, can also be under the premise of not departing from this patent objective
It makes a variety of changes.
Claims (3)
1. a kind of preparation method of the energy-conserving thermal insulation board of high fire-retardance, which is characterized in that the energy-conserving thermal insulation board of the high fire-retardance, by with
Under according to parts by weight raw material form：25-30 parts of dolomite dust, 3-5 parts of talcum powder, 6-12 parts of expansible graphite, phenolic resin
35-52 parts, EVA6-12 parts, 2-5 parts of foaming agent, 1-2 parts of silester, 1.2-2.5 parts of antimony oxide, 15-23 parts of pentane
With 1-3 parts of DCP crosslinking agents, the preparation method of the energy-conserving thermal insulation board of the high fire-retardance is as follows：
Silester and antimony oxide are mixed and are stirred 20-30 minutes, then expansible graphite is added thereto by step 1
It is stirred with phenolic resin to being uniformly dispersed, fire retardant is made；
Step 2 dolomite dust, talcum powder, EVA and pentane is mixed evenly under room temperature, and major ingredient is made；
Deionized water is added in foaming agent, then is sufficiently mixed major ingredient and foam at foam by foaming mechanism for step 3,
And agglutination is melted in 200-260 degrees Celsius of glue melts machine, 30-60 degrees Celsius is cooled to, obtains secondary major ingredient；
DCP crosslinking agents are added into secondary major ingredient and are mixed evenly, obtain major ingredient three times for step 4；
Step 5 will be placed on mixer mixing 10-15 minutes at a temperature of 80-105 degrees Celsius for major ingredient three times, be cooled to often
Temperature is then injected into steam hot pressing die and seals mould, is passed through high-pressure water vapor to 0.02-0.10MPa and after being kept for 30-50 seconds,
Unloading pressure can be prepared by final products after cooling and die sinking.
2. the preparation method of the energy-conserving thermal insulation board of high fire-retardance according to claim 1, which is characterized in that the high fire-retardance
Energy-conserving thermal insulation board is made of the raw material below according to parts by weight：27-30 parts of dolomite dust, 4-5 parts of talcum powder, expansible graphite
8-12 parts, 42-52 parts of phenolic resin, EVA8-12 parts, 3-5 parts of foaming agent, 1-2 parts of silester, antimony oxide 1.6-2.5
2-3 parts of part, 18-23 parts of pentane and DCP crosslinking agents.
3. the preparation method of the energy-conserving thermal insulation board of high fire-retardance according to claim 1, which is characterized in that the high fire-retardance
Energy-conserving thermal insulation board is made of the raw material below according to parts by weight：29 parts of dolomite dust, 5 parts of talcum powder, 10 parts of expansible graphite,
48 parts of phenolic resin, EVA10 parts, 4 parts of foaming agent, 2 parts of silester, 2.1 parts of antimony oxide, 20 parts of pentane and DCP are handed over
Join 3 parts of agent.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201810269079.6A CN108314465B (en) | 2016-04-19 | 2016-04-19 | High-flame-retardance energy-saving insulation board and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810269079.6A CN108314465B (en) | 2016-04-19 | 2016-04-19 | High-flame-retardance energy-saving insulation board and preparation method thereof |
| CN201610241632.6A CN105884393B (en) | 2016-04-19 | 2016-04-19 | A kind of energy-conserving thermal insulation board of high fire-retardance and preparation method thereof |
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| CN201610241632.6A Division CN105884393B (en) | 2016-04-19 | 2016-04-19 | A kind of energy-conserving thermal insulation board of high fire-retardance and preparation method thereof |
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| CN201610241632.6A Expired - Fee Related CN105884393B (en) | 2016-04-19 | 2016-04-19 | A kind of energy-conserving thermal insulation board of high fire-retardance and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN113004652A (en) * | 2021-03-01 | 2021-06-22 | 滦县盛泽保温科技有限公司 | High-temperature-resistant phenolic foam composite thermal insulation material and preparation method thereof |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107674372A (en) * | 2017-11-21 | 2018-02-09 | 南宁可煜能源科技有限公司 | A kind of phenolic aldehyde foam thermal insulation material and preparation method thereof |
| CN109437788B (en) * | 2018-12-29 | 2021-11-30 | 成都固迪建材有限公司 | Non-combustible composite expanded polystyrene insulation board and pressing method thereof |
| CN112898043B (en) * | 2021-03-19 | 2022-06-24 | 北京中科原创节能环保科技有限公司 | High-temperature-resistant energy-saving insulation board for industrial furnace and preparation method |
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| Publication number | Publication date |
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| CN105884393A (en) | 2016-08-24 |
| CN105884393B (en) | 2018-05-25 |
| CN108314465B (en) | 2020-07-10 |
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