CN108314453A - A method of improving silicon carbide powder dispersion stabilization in water system - Google Patents

A method of improving silicon carbide powder dispersion stabilization in water system Download PDF

Info

Publication number
CN108314453A
CN108314453A CN201810263048.XA CN201810263048A CN108314453A CN 108314453 A CN108314453 A CN 108314453A CN 201810263048 A CN201810263048 A CN 201810263048A CN 108314453 A CN108314453 A CN 108314453A
Authority
CN
China
Prior art keywords
silicon carbide
carbide powder
water system
sucrose ester
dispersion stabilization
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Granted
Application number
CN201810263048.XA
Other languages
Chinese (zh)
Other versions
CN108314453B (en
Inventor
张永刚
文章苹
王雪飞
钱鑫
李德宏
宋书林
王欣宇
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Ningbo Institute of Material Technology and Engineering of CAS
Original Assignee
Ningbo Institute of Material Technology and Engineering of CAS
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Ningbo Institute of Material Technology and Engineering of CAS filed Critical Ningbo Institute of Material Technology and Engineering of CAS
Priority to CN201810263048.XA priority Critical patent/CN108314453B/en
Publication of CN108314453A publication Critical patent/CN108314453A/en
Application granted granted Critical
Publication of CN108314453B publication Critical patent/CN108314453B/en
Active legal-status Critical Current
Anticipated expiration legal-status Critical

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/515Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics
    • C04B35/56Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides
    • C04B35/565Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products based on non-oxide ceramics based on carbides or oxycarbides based on silicon carbide
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62625Wet mixtures
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/62605Treating the starting powders individually or as mixtures
    • C04B35/62625Wet mixtures
    • C04B35/6263Wet mixtures characterised by their solids loadings, i.e. the percentage of solids
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B35/00Shaped ceramic products characterised by their composition; Ceramics compositions; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/622Forming processes; Processing powders of inorganic compounds preparatory to the manufacturing of ceramic products
    • C04B35/626Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B
    • C04B35/63Preparing or treating the powders individually or as batches ; preparing or treating macroscopic reinforcing agents for ceramic products, e.g. fibres; mechanical aspects section B using additives specially adapted for forming the products, e.g.. binder binders
    • C04B35/632Organic additives
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5427Particle size related information expressed by the size of the particles or aggregates thereof millimeter or submillimeter sized, i.e. larger than 0,1 mm
    • CCHEMISTRY; METALLURGY
    • C04CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
    • C04BLIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
    • C04B2235/00Aspects relating to ceramic starting mixtures or sintered ceramic products
    • C04B2235/02Composition of constituents of the starting material or of secondary phases of the final product
    • C04B2235/50Constituents or additives of the starting mixture chosen for their shape or used because of their shape or their physical appearance
    • C04B2235/54Particle size related information
    • C04B2235/5418Particle size related information expressed by the size of the particles or aggregates thereof
    • C04B2235/5436Particle size related information expressed by the size of the particles or aggregates thereof micrometer sized, i.e. from 1 to 100 micron

Landscapes

  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Ceramic Engineering (AREA)
  • Manufacturing & Machinery (AREA)
  • Materials Engineering (AREA)
  • Structural Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • Ceramic Products (AREA)
  • Carbon And Carbon Compounds (AREA)

Abstract

The present invention relates to a kind of methods improving silicon carbide powder dispersion stabilization in water system.Silicon carbide powder is scattered in water system by this method is made into slurry, and sucrose ester surfactants solution is added, and so that sucrose ester quality is accounted for 5% the 30% of silicon carbide quality, is mixed evenly, obtains mixed liquor, and adjust the pH value of the mixed liquor between 8~12;In the sucrose ester surfactants solution, sucrose ester is solute, and ethyl alcohol is solvent.This method is easy to operate, uses dispersant is nontoxic, energy conservation and environmental protection, at low cost, the good dispersion of silicon carbide, stability are high in the silicon carbide water system prepared, it can be used as silicon carbide slurry and prepare silicon carbide ceramics by techniques such as injection formings, to improve the dispersion stabilization of silicon carbide ceramics.

Description

A method of improving silicon carbide powder dispersion stabilization in water system
Technical field
The present invention relates to silicon carbide ceramics technical field, more particularly to a kind of raising silicon carbide powder disperses surely in water system Qualitative method.
Background technology
Silicon carbide (SiC) is not only a kind of strongly covalent bond type carbide, but also is a kind of engineering ceramics haveing excellent performance Material.Silicon carbide has high decomposition temperature, and up to 2600 DEG C, not only the performances such as intensity, hardness, wear-resistant are excellent under room temperature It is good, and the performances such as inoxidizability, creep resistance are optimal in known ceramic material under high temperature.Currently, silicon carbide is wide It is general to be applied to the fields such as aerospace, chemical industry, machinery, traffic, the energy and metallurgy, it is considered to be rocket engine, gas turbine One of optimal candidate materials such as machine, advanced heat engine, heat exchanger, high-temperature wearable part.
Silicon carbide ceramics preparation method is more at present, and slip casting dip forming is one of most common method, wherein preparing height Solid concentration, stably dispersing, uniform silicon carbide ceramics slurry are the committed steps in this method.But silicon carbide powder is difficult Stable slurry is formed in water system, easily occur to reunite and is settled, therefore dispersion stabilization of the silicon carbide powder in water system It is the critical issue of slip casting dip forming.That is, to greatest extent using silicon carbide slurry come injection forming, must just control The dispersibility and stability of good silicon carbide slurry.
Currently, more to the research of the dispersibility and rheological characteristic of silicon carbide ceramics slurry both at home and abroad, dispersing technology is also various Various kinds.For example, the primary existing different dispersants of Tang Xue are different to the silicon carbide slurry dispersibility mechanism of action.Intelligence etc. is opened to pass through Addition Ludox prepares the silicon carbide slurry that solid volume fraction is 69%.Li Wei etc. uses tetramethylammonium hydroxide conduct point Powder studies its influence to silicon carbide slurry rheological characteristic, and analyzes its reason.Sun etc. is made using polyethyleneimine (PEI) For dispersant, influence of the research dispersant dosage to silicon carbide slurry mobility.Zhang Qingyong etc. uses graft copolymerization coating modification Technology forms a strata dielectric film in silicon carbide, and the dispersibility of modified silicon carbide powder is made to greatly improve.
Invention content
Present situation in view of the above technology, the present invention is directed to improve dispersion stabilization of the silicon carbide powder in water system, to for The silicon carbide ceramics that high quality is made lays the foundation.
In order to solve the above-mentioned technical problem, the technical scheme is that:A kind of raising silicon carbide powder is in water system point The method of stability is dissipated, it is characterized in that:Silicon carbide powder is scattered in water system, it is 10%-50% to be made into solid volume fraction Slurry, sucrose ester surfactants solution is added, sucrose ester quality is made to account for the 5%-30% of silicon carbide quality, is mixed equal It is even, mixed liquor is obtained, and adjust the pH value of the mixed liquor between 8~12;In the sucrose ester surfactants solution, Sucrose ester is solute, and ethyl alcohol is solvent.
Preferably, the mean particle size range of the silicon carbide powder is 7.5 μm~102.5 μm.
Preferably, sucrose ester quality accounts for the 15%-25% of silicon carbide quality, further preferably 25%.
As a kind of realization method, the sucrose ester surfactants solution is the temperature by sucrose ester at 60~80 DEG C Then lower dissolving is added ethyl alcohol and prepares to obtain;Preferably, further including third in the sucrose ester surfactants solution Ketone.
As a kind of realization method, the pH value of the mixed liquor is adjusted using alkali.Preferably, the alkali is hydroxide One kind in sodium solution and ammonium hydroxide;As further preferred, a concentration of the 5%~10% of sodium hydroxide solution, ammonia spirit A concentration of 5%~10%.
Preferably, silicon carbide powder is scattered in before water system, silicon carbide powder is started the cleaning processing first.As one Kind realization method, the cleaning treatment process of silicon carbide powder are:Silicon carbide powder is scattered in the hydrochloric acid solution of 2%-10%, It is stood after being mixed evenly, supernatant liquid is removed after slurry layering, centrifugation then is carried out to gained slurry and distilled water is clear It washes, until pH value in neutral range, is finally dried, obtains silicon carbide powder.
A kind of sic powder of polymolecularity can also be made using the method for the present invention, be the method using the present invention It improves silicon carbide powder to be stood, dried after dispersion stabilization in water system, obtains the sic powder of polymolecularity.
Compared with prior art, beneficial effects of the present invention are as follows:
(1) dispersant sucrose ester is added after silicon carbide powder is scattered in water system.Sucrose ester is uncharged nonionic Surfactant is rich in hydrophilic hydroxyl, mainly passes through space stability ultimate load to the dispersion of the silicon carbide powder in water system Mechanism is completed, its one end is adsorbed on silicon-carbide particle surface, and the state of stretching, extension is presented in the strand of the other end, forms space Barrier provides steric hindrance, and the reunion and sedimentation of silicon carbide powder particle in the slurry, therefore energy can be hindered under its effect Enough improve dispersion stabilization of the silicon carbide powder in aqueous based systems suspension.
(2) simultaneously, research finds that pH value influences the molecular conformation and degree of ionization of dispersant, and carbonization can be adjusted by adjusting pH value The charged characteristic on silicon particle surface, makes Particle surface charge increase, and electronic double layer repulsion can increase, to increase silicon carbide water system body The stability of system;The isoelectric point (IEP) of silicon carbide powder particle is generally pH=3~6 in pulp suspension, in isoelectric point Place, silicon-carbide particle surface can form stable uncharged silanol, and particle positive and negative charge numerical value is equal in suspension at this time, Zeta potential is zero, and electrostatic repulsion zero, particle is easy to happen reunion and sedimentation;When pH value is higher, silicon-carbide particle band is negative Charge, pH value is bigger, and particle surface institute is negatively charged more, and Zeta potential gradually increases, and is conducive to silicon carbide powder particle and exists Dispersion stabilization in water system.By many experiments exploration discovery, pH value is adjusted when between 8~12, can realize silicon carbide There is good dispersion stabilization in water system, especially dispersibility is good when pH value is 10.
(3) preparation process of the present invention is easy to operate, uses dispersant is nontoxic, energy conservation and environmental protection, at low cost, prepares Silicon carbide water system in the good dispersion of silicon carbide, stability it is high, can be used as silicon carbide slurry and pass through the techniques systems such as injection forming Standby silicon carbide ceramics, can be improved the dispersion stabilization of silicon carbide ceramics.
Description of the drawings
Fig. 1 is the scanning electron microscopic picture of silicon carbide powder obtained in comparative example 1;
Fig. 2 is the scanning electron microscopic picture of the silicon carbide powder obtained in embodiment 1 when pH value is 10 in step (1);
Fig. 3 is the viscosity of suspension section and the relationship of pH value in the silicon carbide slurry that step (1) obtains in embodiment 1;
Fig. 4 is that the volume of distribution of silicon carbide solid phase in the silicon carbide slurry that step (1) obtains in embodiment 1 is (referred to as heavy Product volume) with the relationship of pH value;
Fig. 5 is the viscosity and dispersant of suspension section in the silicon carbide slurry that step (1) obtains in embodiment 2 Relationship;
Fig. 6 is that the volume of distribution of silicon carbide solid phase in the silicon carbide slurry that step (1) obtains in embodiment 2 is (referred to as heavy Product volume) with the relationship of dispersant.
Specific implementation mode
With reference to embodiment, present invention is further described in detail, it should be pointed out that embodiment described below purport Convenient for the understanding of the present invention, and any restriction effect is not played to it.
Embodiment 1:
In the present embodiment, the preparation method of silicon carbide ceramics powder is as follows:
(1) silicon carbide powder is scattered in distilled water, silicon carbide powder quality is 1 with distilled water mass ratio:1, then Sucrose ester surfactants solution is added, sucrose ester quality is made to account for the 25% of silicon carbide quality, is mixed under conditions of 750r/min Stirring 5h is closed, silicon carbide slurry is obtained;
For sucrose ester as dispersant, ethyl alcohol, as solvent, is by sucrose ester with acetone in the surfactant solution It is dissolved at a temperature of 60~80 DEG C, ethyl alcohol and acetone then is added and prepares to obtain;
Then, the pH value that silicon carbide slurry is adjusted with ammonium hydroxide and hydrochloric acid, obtains six groups that pH is respectively 2,4,6,8,10,12 Slurry continues to stir 1h under conditions of 300r/min, the pH value of silicon carbide slurry is adjusted after stirring again, to ensure pH It is worth constant;The silicon carbide slurry is stood later, the distribution space of wherein silicon carbide solid phase is observed after stablizing, and samples top Suspension, by the solid concentration information for measuring the available wherein silicon carbide of its viscosity;
(2) it takes out silicon carbide slurry to stand for 24 hours, is finally putting into drying in 50 DEG C of constant temperature drying boxes and for 24 hours, obtains silicon carbide pottery Ceramic powder.
Comparative example 1:
The present embodiment is the comparative example of above-described embodiment 1.
In the present embodiment, the preparation method of silicon carbide ceramics powder is as follows:
(1) silicon carbide powder is scattered in distilled water, silicon carbide powder quality is 1 with distilled water mass ratio:1, 5h is mixed under conditions of 750r/min, obtains silicon carbide slurry;
(2) identical as step (2) in embodiment 1.
Fig. 1 is the scanning electron microscopic picture of silicon carbide powder obtained in comparative example 1.Fig. 2 is to work as step in embodiment 1 Suddenly the scanning electron microscopic picture of the silicon carbide powder obtained when pH value is 10 in (1).The two compares, in display and comparative example 1 It is compared without the silicon carbide powder of sucrose ester surfactants solution modification, sucrose ester surfactants is passed through in embodiment 1 The reunion of silicon carbide powder reduces after solution modification, favorable dispersibility.
Fig. 3 is the viscosity of suspension section and the pass of pH value in the silicon carbide slurry that step (1) obtains in above-described embodiment 1 System, display is with the increase of pH value, and suspension viscosity, which is presented, first increases the trend subtracted afterwards, the major part depositing SiC as pH=2 In bottom, suspension viscosity is minimum;As pH value increases, silicon carbide dispersibility is gradually increased, and the deposition volume of bottom gradually subtracts Small, carborundum content gradually rises in the suspension of top, and suspension viscosity gradually increases;As pH=8, suspension viscosity is most Greatly;When pH value continues growing, suspension viscosity declines, this is because ammonium hydroxide continuously adds, although pH value continues growing, carbon SiClx dispersibility still improves, but increases suspension vol simultaneously, and the solid concentration of silicon carbide declines in suspension The reason of, but even if viscosity declines, as pH=12, viscosity is still higher.
Fig. 4 is the volume of distribution and pH value of silicon carbide solid phase in the silicon carbide slurry that step (1) obtains in above-described embodiment 1 Relationship, show as pH=2, volume of distribution is relatively low, this is because most of depositing SiC is in bottom;With the increasing of pH value Add, dispersibility of the silicon carbide in suspension improves, and distribution space volume gradually increases;As pH=10, silicon carbide solid phase Distribution space volume it is maximum, reach 100ml, illustrating silicon carbide powder particle, dispersibility and stability is most in aqueous based systems It is good;When continuing growing gradual pH value, the distribution space volume of silicon carbide solid phase declines, but as pH=12, the distribution Spatial volume is still higher.
Embodiment 2:
In the present embodiment, the preparation method of silicon carbide ceramics powder is as follows:
(1) silicon carbide powder is scattered in distilled water, silicon carbide powder quality is 1 with distilled water mass ratio:1, then Sucrose ester surfactants solution is added, sucrose ester quality is made to account for the 5% of silicon carbide quality, 10% respectively, 15%, 20%, 25%, 30%, 5h is mixed under conditions of 750r/min, obtains six groups of silicon carbide slurries;
For sucrose ester as dispersant, ethyl alcohol, as solvent, is by sucrose ester with acetone in the surfactant solution It is dissolved at a temperature of 60~80 DEG C, ethyl alcohol and acetone then is added and prepares to obtain;
Then, the pH value that silicon carbide slurry is adjusted with ammonium hydroxide and hydrochloric acid, it is 10 to obtain pH, under conditions of 300r/min after Continuous stirring 1h, adjusts the pH value of silicon carbide slurry, to ensure that pH value is constant again after stirring;Silicon carbide slurry is stood later Material, observes the distribution space of wherein silicon carbide solid phase, and sample the suspension on top after stablizing, can by measuring its viscosity Obtain the solid concentration information of wherein silicon carbide;
(2) it takes out silicon carbide slurry to stand for 24 hours, is finally putting into drying in 50 DEG C of constant temperature drying boxes and for 24 hours, obtains silicon carbide pottery Ceramic powder.
Fig. 5 is that the viscosity of suspension section in the silicon carbide slurry that step (1) obtains in above-described embodiment 2 contains with dispersant The relationship of amount.Fig. 6 be in the silicon carbide slurry that step (1) obtains in above-described embodiment 2 volume of distribution of silicon carbide solid phase with point The relationship of powder content.From show that sucrose ester adds content to the viscosity of suspension section and silicon carbide solid phase in Fig. 3 and Fig. 4 Volume of distribution has large effect.When dispersant is 5%, the viscosity of suspension section and the distribution body of silicon carbide solid phase Product is all minimum;When dispersant increases, the viscosity of dispersant suspension section and the volume of distribution of silicon carbide solid phase totally become Gesture is constantly increased with the increase of dispersant;When dispersant reaches 25%, the distribution body of silicon carbide solid phase Product reaches maximum;When dispersant continues growing, the viscosity of suspension section continues growing, and the distribution body of silicon carbide solid phase Product no longer changes, this is because there are a critical values for the absorption on sucrose ester and silicon-carbide particle surface, when sucrose ester content reaches When to 25%, silicon-carbide particle can be thoroughly dispersed in water system system suspension at this time, and steric hindrance function and effect are best.When When the content of sucrose ester continues growing, an oversaturated state can be reached, inherently had when sucrose ester is soluble in water certain Viscosity, content increase can cause slurry viscosity to continue to increase, and particle occurs to reunite and flocculation, mobility are deteriorated.Therefore, when point When powder content is 25%, slurry dispersibility and stability reach best.
Embodiment 3:
(1) essentially identical with the step (1) in embodiment 1, except that sucrose ester quality accounts for silicon carbide quality 5%, the pH value that silicon carbide slurry is adjusted with ammonium hydroxide and hydrochloric acid is 10;
(2) identical as step (2) in embodiment 1.
Embodiment 4:
(1) essentially identical with the step (1) in embodiment 1, except that sucrose ester quality accounts for silicon carbide quality 10%, the pH value that silicon carbide slurry is adjusted with ammonium hydroxide and hydrochloric acid is 10;
(2) identical as step (2) in embodiment 1.
Embodiment 5:
(1) essentially identical with the step (1) in embodiment 1, except that sucrose ester quality accounts for silicon carbide quality 20%, the pH value that silicon carbide slurry is adjusted with ammonium hydroxide and hydrochloric acid is 10;
(2) identical as step (2) in embodiment 1.
Embodiment 6:
The present embodiment is substantially the same manner as Example 3, the difference is that before step (1), is carried out such as to silicon carbide powder Lower processing:
Silicon carbide powder is scattered in 5% hydrochloric acid solution, is made into the suspension that solid volume fraction is 20% respectively, It is stood after 1h is mixed under conditions of 750r/min, removes supernatant liquid after suspension layering, then to gained suspension Centrifugation and distilled water cleaning are carried out, until suspension pH value in neutral range, is finally putting into drying in 100 DEG C of constant temperature drying boxes 12h obtains silicon carbide powder.
Technical scheme of the present invention is described in detail in embodiment described above, it should be understood that the above is only For specific embodiments of the present invention, it is not intended to restrict the invention, all any modifications made in the spirit of the present invention, Supplement or similar fashion replacement etc., should all be included in the protection scope of the present invention.

Claims (10)

1. a kind of method improving silicon carbide powder dispersion stabilization in water system, it is characterized in that:Silicon carbide powder is scattered in In water system, it is made into the slurry that solid volume fraction is 10%-50%, sucrose ester surfactants solution is added, makes sucrose ester matter Amount accounts for the 5%-30% of silicon carbide quality, is mixed evenly, obtains mixed liquor, and adjust the pH value of the mixed liquor 8~ Between 12;
In the sucrose ester surfactants solution, sucrose ester is solute, and ethyl alcohol is solvent.
2. the method for improving silicon carbide powder dispersion stabilization in water system as described in claim 1, it is characterized in that:Described The mean particle size range of silicon carbide powder is 7.5 μm~102.5 μm.
3. the method for improving silicon carbide powder dispersion stabilization in water system as described in claim 1, it is characterized in that:Sucrose ester Quality accounts for the 15%-25% of silicon carbide quality, preferably 25%.
4. the method for improving silicon carbide powder dispersion stabilization in water system as described in claim 1, it is characterized in that:Adjusting should The pH value of mixed liquor is 9~10.
5. the method for improving silicon carbide powder dispersion stabilization in water system as described in claim 1, it is characterized in that:Described Sucrose ester surfactants solution is to dissolve sucrose ester at a temperature of 60~80 DEG C, and ethyl alcohol then is added and prepares to obtain.
6. the method for improving silicon carbide powder dispersion stabilization in water system as claimed in claim 4, it is characterized in that:Described Further include acetone in sucrose ester surfactants solution.
7. the method for improving silicon carbide powder dispersion stabilization in water system as described in claim 1, it is characterized in that:Utilize alkali Adjust the pH value of the mixed solution;The alkali is one kind in sodium hydroxide solution and ammonium hydroxide;As further preferred, hydrogen A concentration of the 5%~10% of sodium hydroxide solution, a concentration of the 5%~10% of ammonia spirit.
8. the method for improving silicon carbide powder dispersion stabilization in water system as described in claim 1, it is characterized in that:Silicon carbide Powder is scattered in before water system, first starts the cleaning processing silicon carbide powder.
9. the method for improving silicon carbide powder dispersion stabilization in water system as claimed in claim 8, it is characterized in that:Silicon carbide The cleaning treatment process of powder is:Silicon carbide powder is scattered in the hydrochloric acid solution of 2%-10%, is mixed evenly rear quiet It sets, supernatant liquid is removed after slurry layering, centrifugation then is carried out to gained slurry and distilled water cleans, until pH value is in neutrality It in range, is finally dried, obtains silicon carbide powder.
10. a kind of preparation method of the sic powder of polymolecularity utilizes any claim institute in such as claim 1 to 9 The method stated improves silicon carbide powder dispersion stabilization in water system, is then stood, is dried, obtains the carbonization of polymolecularity Silica flour material.
CN201810263048.XA 2018-03-28 2018-03-28 Method for improving dispersion stability of silicon carbide powder in water system Active CN108314453B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810263048.XA CN108314453B (en) 2018-03-28 2018-03-28 Method for improving dispersion stability of silicon carbide powder in water system

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810263048.XA CN108314453B (en) 2018-03-28 2018-03-28 Method for improving dispersion stability of silicon carbide powder in water system

Publications (2)

Publication Number Publication Date
CN108314453A true CN108314453A (en) 2018-07-24
CN108314453B CN108314453B (en) 2021-03-09

Family

ID=62899378

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810263048.XA Active CN108314453B (en) 2018-03-28 2018-03-28 Method for improving dispersion stability of silicon carbide powder in water system

Country Status (1)

Country Link
CN (1) CN108314453B (en)

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111463113A (en) * 2020-05-25 2020-07-28 哈尔滨晶创科技有限公司 Processing method for protecting silicon carbide surface in semi-insulating SiC ion doping annealing process

Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61293540A (en) * 1985-06-22 1986-12-24 Lion Corp Dispersant for ceramic
JPH05319931A (en) * 1992-05-20 1993-12-03 Toshiba Ceramics Co Ltd Preparation of silicon carbide powder slurry for cast forming
CN1344675A (en) * 2001-08-07 2002-04-17 宁夏回族自治区新技术应用研究所 Production process of submicron level silicon carbide
CN105645968A (en) * 2016-03-03 2016-06-08 南京工业大学 Preparation method of ultramicro silicon carbide powder high-performance size
CN107445203A (en) * 2017-09-06 2017-12-08 潮州三环(集团)股份有限公司 A kind of zirconium oxide of scandia stabilized and preparation method thereof
CN107602129A (en) * 2017-10-12 2018-01-19 华中科技大学 A kind of water-based tape casting preparation method of SiC

Family Cites Families (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JP5319931B2 (en) * 2008-02-22 2013-10-16 株式会社日立ハイテクノロジーズ Electron microscope system and pattern dimension measuring method using the same

Patent Citations (6)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
JPS61293540A (en) * 1985-06-22 1986-12-24 Lion Corp Dispersant for ceramic
JPH05319931A (en) * 1992-05-20 1993-12-03 Toshiba Ceramics Co Ltd Preparation of silicon carbide powder slurry for cast forming
CN1344675A (en) * 2001-08-07 2002-04-17 宁夏回族自治区新技术应用研究所 Production process of submicron level silicon carbide
CN105645968A (en) * 2016-03-03 2016-06-08 南京工业大学 Preparation method of ultramicro silicon carbide powder high-performance size
CN107445203A (en) * 2017-09-06 2017-12-08 潮州三环(集团)股份有限公司 A kind of zirconium oxide of scandia stabilized and preparation method thereof
CN107602129A (en) * 2017-10-12 2018-01-19 华中科技大学 A kind of water-based tape casting preparation method of SiC

Non-Patent Citations (3)

* Cited by examiner, † Cited by third party
Title
R. RAMACHANDRA RAO ET AL.: "Effect of pH on the dispersability of silicon carbide powders in aqueous media", 《CERAMICS INTERNATIONAL》 *
张云龙等: "《碳化硅及其复合材料的制造与应用》", 31 July 2015, 国防工业出版社 *
陆有军: "碳纳米颗粒改性碳化硅陶瓷基复合材料的制备及其性能研究", 《中国博士学位论文全文数据库 工程科技Ⅰ辑》 *

Cited By (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN111463113A (en) * 2020-05-25 2020-07-28 哈尔滨晶创科技有限公司 Processing method for protecting silicon carbide surface in semi-insulating SiC ion doping annealing process
CN111463113B (en) * 2020-05-25 2023-04-11 哈尔滨晶创科技有限公司 Processing method for protecting silicon carbide surface in semi-insulating SiC ion doping annealing process

Also Published As

Publication number Publication date
CN108314453B (en) 2021-03-09

Similar Documents

Publication Publication Date Title
CN101007252B (en) Apparent particle size controllable ultra-fine and ultra-dispersed micropowder of nanocrystalline diamond and its producing method
US10364193B2 (en) Method for synthesizing high-purity ultrafine ZrC—SiC composite powder
CN107151029B (en) A kind of sol-gel self-combustion synthesis preparation process of tetra phase barium titanate powder
CN109879303B (en) Preparation method of nano calcium carbonate capable of stably suspending and dispersing in aqueous solution
WO1987006495A1 (en) Liquefaction of highly loaded particulate suspensions
DE102006011965A1 (en) Process for producing fine alpha-alumina particles
CN108751247B (en) Preparation method of nano yttrium oxide with stable BET
Foratirad et al. Effects of dispersants on dispersibility of titanium carbide aqueous suspension
CN109721357A (en) A kind of Zirconium oxide powder and its preparation method and application that the nanometer yttrium that monodisperse granularity is controllable is stable
Coupé et al. Dispersion behaviour of laser-synthesized silicon carbide nanopowders in ethanol for electrophoretic infiltration
CN105645968A (en) Preparation method of ultramicro silicon carbide powder high-performance size
CN1313842A (en) Barium titanate dispersions
CN108314453A (en) A method of improving silicon carbide powder dispersion stabilization in water system
CN107337454B (en) A kind of preparation method of silicon nitride composite powder
Wang et al. Preparation of kaolinite/titania coated nanocomposite particles and their electrorheological properties
WO2010080453A2 (en) Methods for stabilizing hydrous kaolin
Yang et al. Thin films by consolidation and sintering of nanocrystalline powders
Yang et al. Gelation, Consolidation, and Rheological Properties of Boehmite‐Coated Silicon Carbide Suspensions
Liu et al. Effect of 2‐Phosphonobutane‐1, 2, 4‐tricarboxylic Acid Adsorption on the Stability and Rheological Properties of Aqueous Nanosized 3‐mol%‐Yttria‐Stabilized Tetragonal‐Zirconia Polycrystal Suspensions
CN112390643A (en) Ceramic composite powder for thermal spraying and preparation method thereof
Albano et al. Dispersion of aluminum hydroxide coated Si3N4 powders with ammonium polyacrylate dispersant
KR101328495B1 (en) Anionic polymer surface-treated ceramic particle and method thereof
Shin et al. Preparation of high-solid-loading and highly dispersible ZrB2 slurry in non-aqueous solvent via surface functionalization of cationic/anionic polymers
Bo et al. Monazite coatings on short alumina fibers using layer-by-layer assembly technique
CN115818740B (en) Synthetic method of ruthenium dioxide nano powder

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
GR01 Patent grant
GR01 Patent grant