CN108314331A - A kind of preparation method of high strength glass material - Google Patents
A kind of preparation method of high strength glass material Download PDFInfo
- Publication number
- CN108314331A CN108314331A CN201810169532.6A CN201810169532A CN108314331A CN 108314331 A CN108314331 A CN 108314331A CN 201810169532 A CN201810169532 A CN 201810169532A CN 108314331 A CN108314331 A CN 108314331A
- Authority
- CN
- China
- Prior art keywords
- mixing
- preparation
- high strength
- glass material
- antioxidant
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Withdrawn
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C14/00—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix
- C03C14/002—Glass compositions containing a non-glass component, e.g. compositions containing fibres, filaments, whiskers, platelets, or the like, dispersed in a glass matrix the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Ceramic Engineering (AREA)
- Dispersion Chemistry (AREA)
- Life Sciences & Earth Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention provides a kind of preparation method of high strength glass material, includes the following steps：A, by silica, alkali compounds, zinc oxide and potassium oxide mixing and ball milling, re-dry obtains material one；B, glass fibre, compatilizer, toughener and heat stabilizer are added into material one, imports in reaction kettle and heats, is stirred to react, ventilation clarification obtains material two；C, processing aid, lubricant and antioxidant are added into material two, carries out melting mixing, then clarification of ventilating, obtains material three；D, material three is made annealing treatment, finally imports in mold, is cooled to room temperature.Glass material prepared by the present invention has good Resisting fractre ability and higher Vickers hardness, can significantly improve the application range of glass material.
Description
Technical field
The invention belongs to technical field of glass materials, and in particular to a kind of preparation method of high strength glass material.
Background technology
Extensive use with glassware in fields such as industry, medicine and buildings, the existing demand to glass is
It is not limited only to for barrier and light transmission.It is more then be the demand to the good mechanical strength of glass, such as good break resistance
With high hardness.But since the mechanics that the internal structure of glass itself causes it is bad, to glass preparation component
Improvement has become theme of people's attention.
For the prior art when improving the hardness of glass, lead oxide is usually added, and to obtain, hardness is high, wearability is good and resistance to fracture
The good glass of energy, but since the addition of lead oxide can have a negative impact to human body and environment, excellent is resisted
The environmentally friendly glass of fracture and high rigidity also has become needs.
Invention content
The object of the present invention is to provide a kind of preparation method of high strength glass material, glass material prepared by the present invention has
There are good Resisting fractre ability and higher Vickers hardness, can significantly improve the application range of glass material.
The present invention provides the following technical solutions：
A kind of preparation method of high strength glass material, including following preparation process：
A, silica, alkali compounds, zinc oxide and potassium oxide are mixed, imports ball milling 1-2h in ball mill, then be placed in 80-
Dry 30-40min, obtains material one at 90 DEG C；
B, glass fibre, compatilizer, toughener and heat stabilizer are added into material one, imports in reaction kettle after mixing,
It is heated to 1450-1550 DEG C, is stirred using quartz pushrod in heating process, after reacting 1-2h, it is clear to be passed through inert gas progress
Clearly, material two is obtained；
C, processing aid, lubricant and antioxidant are added into material two, temperature is risen into 1250-1340 DEG C of progress melting mixing
2-3h is passed through inert gas and is clarified, obtains material three again after mixing；
D, material three is made annealing treatment, when first stage annealing is to 880-960 DEG C, keeps the temperature 45-55min, second stage is moved back
When fire is to 560-620 DEG C, 40-50min is kept the temperature, finally imports in mold, is cooled to room temperature, you can obtain finished product.
Preferably, the alkali compounds of the step a is calcium carbonate, magnesium hydroxide, aluminium hydroxide, zinc hydroxide, carbonic acid
The mixing of hydrogen sodium, sodium carbonate and potassium carbonate any one or more of.
Preferably, the compatilizer of the step b be maleic anhydride inoculated polypropylene or glycidyl methacrylate with
Polyacrylic copolymer.
Preferably, the toughener of the step b is ethylene propylene diene rubber, polystyrene block copolymer and polyolefin elastic
The mixing of body any one or more of.
Preferably, the heat stabilizer of the step b is that phenolic thermostabilizers, amine heat stabilizer, phosphorous acid esters heat are steady
Determine any in agent, half Hinered phenols heat stabilizer, calixarene kind heat stabilizer and dilauryl thiodipropionate heat stabilizer
Kind or a variety of mixing.
Preferably, the processing aid of the step c is low molecule esters processing aid, metal soap processing aid, tristearin
The mixing of acid compound esters processing aid and amides processing aid any one or more of.
Preferably, the lubricant of the step c is appointing in paraffin, polypropylene wax, polyethylene wax, amide waxe and stearic acid
One or more mixing.
Preferably, the antioxidant of the step c is Hinered phenols antioxidant, suffocated amine antioxidant, phosphite ester antioxygen
The mixing of agent and thioether kind antioxidant any one or more of.
The beneficial effects of the invention are as follows：
Glass material prepared by the present invention has good Resisting fractre ability and higher Vickers hardness, can significantly improve glass
The application range of material.
The toughener being added in the present invention may make the glass material of preparation to have good shock resistance, intensity
It is also maintained at higher level with rigidity, comprehensive performance is superior.
The compatilizer that the present invention selects is mixed with alkali compounds, and basic treatment can be carried out to compatilizer, is neutralized well
Remaining acidic materials in compatilizer, effectively prevent compatilizer and are chemically reacted with other adding ingredients, make preparation
Glass material also makes the weather resistance of glass material be improved significantly while with excellent mechanical performance, to have
There are vast market prospect and market efficiency.
Specific implementation mode
Embodiment 1
A kind of preparation method of high strength glass material, including following preparation process：
A, silica, alkali compounds, zinc oxide and potassium oxide are mixed, imports ball milling 2h in ball mill, then be placed in 90 DEG C
Lower dry 30min, obtains material one；
B, glass fibre, compatilizer, toughener and heat stabilizer are added into material one, imports in reaction kettle after mixing,
1450 DEG C are heated to, is stirred using quartz pushrod in heating process, after reacting 2h, inert gas is passed through and is clarified, obtained
Material two；
C, processing aid, lubricant and antioxidant are added into material two, temperature is risen into 1340 DEG C of progress melting mixing 3h, is mixed
Inert gas is passed through after refining again to be clarified, material three is obtained；
D, material three is made annealing treatment, when first stage annealing is to 960 DEG C, keeps the temperature 45min, secondary stage annealing to 560
DEG C when, keep the temperature 50min, finally import mold in, be cooled to room temperature, you can obtain finished product.
The alkali compounds of step a is calcium carbonate, magnesium hydroxide, aluminium hydroxide, zinc hydroxide, sodium bicarbonate, sodium carbonate
With the mixing of potassium carbonate.
The compatilizer of step b is glycidyl methacrylate and polyacrylic copolymer.
The toughener of step b is the mixing of ethylene propylene diene rubber, polystyrene block copolymer and polyolefin elastomer.
The heat stabilizer of step b is phenolic thermostabilizers, amine heat stabilizer, phosphite ester type thermal stabilizing agent, is partly obstructed
The mixing of phenolic thermostabilizers, calixarene kind heat stabilizer and dilauryl thiodipropionate heat stabilizer.
The processing aid of step c is low molecule esters processing aid, metal soap processing aid, the compound esters of stearic acid add
The mixing of work auxiliary agent and amides processing aid.
The lubricant of step c is paraffin, polypropylene wax, polyethylene wax, amide waxe and stearic mixing.
The antioxidant of step c is that Hinered phenols antioxidant, suffocated amine antioxidant, phosphite antioxidant and thioether class are anti-
The mixing of oxygen agent.
Embodiment 2
A kind of preparation method of high strength glass material, including following preparation process：
A, silica, alkali compounds, zinc oxide and potassium oxide are mixed, imports ball milling 1h in ball mill, then be placed in 80 DEG C
Lower dry 30min, obtains material one；
B, glass fibre, compatilizer, toughener and heat stabilizer are added into material one, imports in reaction kettle after mixing,
1450 DEG C are heated to, is stirred using quartz pushrod in heating process, after reacting 1h, inert gas is passed through and is clarified, obtained
Material two；
C, processing aid, lubricant and antioxidant are added into material two, temperature is risen into 1250 DEG C of progress melting mixing 2h, is mixed
Inert gas is passed through after refining again to be clarified, material three is obtained；
D, material three is made annealing treatment, when first stage annealing is to 880 DEG C, keeps the temperature 45min, secondary stage annealing to 560
DEG C when, keep the temperature 40min, finally import mold in, be cooled to room temperature, you can obtain finished product.
The alkali compounds of step a is calcium carbonate, magnesium hydroxide, aluminium hydroxide, zinc hydroxide, sodium bicarbonate, sodium carbonate
With the mixing of potassium carbonate.
The compatilizer of step b is glycidyl methacrylate and polyacrylic copolymer.
The toughener of step b is the mixing of ethylene propylene diene rubber, polystyrene block copolymer and polyolefin elastomer.
The heat stabilizer of step b is phenolic thermostabilizers, amine heat stabilizer, phosphite ester type thermal stabilizing agent, is partly obstructed
The mixing of phenolic thermostabilizers, calixarene kind heat stabilizer and dilauryl thiodipropionate heat stabilizer.
The processing aid of step c is low molecule esters processing aid, metal soap processing aid, the compound esters of stearic acid add
The mixing of work auxiliary agent and amides processing aid.
The lubricant of step c is paraffin, polypropylene wax, polyethylene wax, amide waxe and stearic mixing.
The antioxidant of step c is that Hinered phenols antioxidant, suffocated amine antioxidant, phosphite antioxidant and thioether class are anti-
The mixing of oxygen agent.
Embodiment 3
A kind of preparation method of high strength glass material, including following preparation process：
A, silica, alkali compounds, zinc oxide and potassium oxide are mixed, imports ball milling 2h in ball mill, then be placed in 90 DEG C
Lower dry 40min, obtains material one；
B, glass fibre, compatilizer, toughener and heat stabilizer are added into material one, imports in reaction kettle after mixing,
1550 DEG C are heated to, is stirred using quartz pushrod in heating process, after reacting 2h, inert gas is passed through and is clarified, obtained
Material two；
C, processing aid, lubricant and antioxidant are added into material two, temperature is risen into 1340 DEG C of progress melting mixing 2h, is mixed
Inert gas is passed through after refining again to be clarified, material three is obtained；
D, material three is made annealing treatment, when first stage annealing is to 960 DEG C, keeps the temperature 55min, secondary stage annealing to 620
DEG C when, keep the temperature 50min, finally import mold in, be cooled to room temperature, you can obtain finished product.
The alkali compounds of step a is calcium carbonate, magnesium hydroxide, aluminium hydroxide, zinc hydroxide, sodium bicarbonate, sodium carbonate
With the mixing of potassium carbonate.
The compatilizer of step b is maleic anhydride inoculated polypropylene.
The toughener of step b is the mixing of ethylene propylene diene rubber, polystyrene block copolymer and polyolefin elastomer.
The heat stabilizer of step b is phenolic thermostabilizers, amine heat stabilizer, phosphite ester type thermal stabilizing agent, is partly obstructed
The mixing of phenolic thermostabilizers, calixarene kind heat stabilizer and dilauryl thiodipropionate heat stabilizer.
The processing aid of step c is low molecule esters processing aid, metal soap processing aid, the compound esters of stearic acid add
The mixing of work auxiliary agent and amides processing aid.
The lubricant of step c is paraffin, polypropylene wax, polyethylene wax, amide waxe and stearic mixing.
The antioxidant of step c is that Hinered phenols antioxidant, suffocated amine antioxidant, phosphite antioxidant and thioether class are anti-
The mixing of oxygen agent.
Material prepared by above example is detected, following detection data is obtained：
Table one：
| Project | Tensile strength（MPa） | Bending strength（MPa） | Bending modulus（MPa） | Notch impact strength（KJ/m2） |
| Examination criteria | IS0527 | IS0180 | IS0178 | IS0178 |
| Embodiment 1 | 125 | 146 | 6200 | 17.8 |
| Embodiment 2 | 128 | 152 | 6000 | 18.5 |
| Embodiment 3 | 125 | 153 | 6300 | 18.2 |
The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, although with reference to the foregoing embodiments
Invention is explained in detail, for those skilled in the art, still can be to foregoing embodiments institute
The technical solution of record is modified or equivalent replacement of some of the technical features.It is all the present invention spirit and
Within principle, any modification, equivalent replacement, improvement and so on should all be included in the protection scope of the present invention.
Claims (8)
1. a kind of preparation method of high strength glass material, which is characterized in that including following preparation process：
A, silica, alkali compounds, zinc oxide and potassium oxide are mixed, imports ball milling 1-2h in ball mill, then be placed in 80-
Dry 30-40min, obtains material one at 90 DEG C；
B, glass fibre, compatilizer, toughener and heat stabilizer are added into material one, imports in reaction kettle after mixing,
It is heated to 1450-1550 DEG C, is stirred using quartz pushrod in heating process, after reacting 1-2h, it is clear to be passed through inert gas progress
Clearly, material two is obtained；
C, processing aid, lubricant and antioxidant are added into material two, temperature is risen into 1250-1340 DEG C of progress melting mixing
2-3h is passed through inert gas and is clarified, obtains material three again after mixing；
D, material three is made annealing treatment, when first stage annealing is to 880-960 DEG C, keeps the temperature 45-55min, second stage is moved back
When fire is to 560-620 DEG C, 40-50min is kept the temperature, finally imports in mold, is cooled to room temperature, you can obtain finished product.
2. a kind of preparation method of high strength glass material according to claim 1, which is characterized in that the step a's
Alkali compounds is any in calcium carbonate, magnesium hydroxide, aluminium hydroxide, zinc hydroxide, sodium bicarbonate, sodium carbonate and potassium carbonate
Kind or a variety of mixing.
3. a kind of preparation method of high strength glass material according to claim 1, which is characterized in that the step b's
Compatilizer is maleic anhydride inoculated polypropylene or glycidyl methacrylate and polyacrylic copolymer.
4. a kind of preparation method of high strength glass material according to claim 1, which is characterized in that the step b's
Toughener is the mixing of ethylene propylene diene rubber, polystyrene block copolymer and polyolefin elastomer any one or more of.
5. a kind of preparation method of high strength glass material according to claim 1, which is characterized in that the step b's
Heat stabilizer is phenolic thermostabilizers, amine heat stabilizer, phosphite ester type thermal stabilizing agent, half Hinered phenols heat stabilizer, cup
The mixing of aromatic hydrocarbons type thermal stabilizing agent and dilauryl thiodipropionate heat stabilizer any one or more of.
6. a kind of preparation method of high strength glass material according to claim 1, which is characterized in that the step c's
Processing aid is low molecule esters processing aid, metal soap processing aid, the compound esters processing aid of stearic acid and amides
The mixing of processing aid any one or more of.
7. a kind of preparation method of high strength glass material according to claim 1, which is characterized in that the step c's
Lubricant is the mixing of paraffin, polypropylene wax, polyethylene wax, amide waxe and stearic acid any one or more of.
8. a kind of preparation method of high strength glass material according to claim 1, which is characterized in that the step c's
Antioxidant is any one of Hinered phenols antioxidant, suffocated amine antioxidant, phosphite antioxidant and thioether kind antioxidant
Or a variety of mixing.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810169532.6A CN108314331A (en) | 2018-03-01 | 2018-03-01 | A kind of preparation method of high strength glass material |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201810169532.6A CN108314331A (en) | 2018-03-01 | 2018-03-01 | A kind of preparation method of high strength glass material |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN108314331A true CN108314331A (en) | 2018-07-24 |
Family
ID=62901010
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201810169532.6A Withdrawn CN108314331A (en) | 2018-03-01 | 2018-03-01 | A kind of preparation method of high strength glass material |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN108314331A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108892373A (en) * | 2018-07-30 | 2018-11-27 | 合肥利裕泰玻璃制品有限公司 | A kind of glass material and preparation method thereof |
| CN109279784A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of high strength glass material |
| CN110627369A (en) * | 2019-09-27 | 2019-12-31 | 安徽省聚科石墨烯科技股份公司 | Preparation method of graphene glass |
| CN110803865A (en) * | 2019-12-03 | 2020-02-18 | 南通华丰工艺品有限公司 | High-strength explosion-proof novel composite material for glass artware and preparation method thereof |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898723A (en) * | 2011-07-28 | 2013-01-30 | 合肥杰事杰新材料股份有限公司 | Polypropylene composition and preparation method thereof |
| CN103771702A (en) * | 2014-01-21 | 2014-05-07 | 江苏奥蓝工程玻璃有限公司 | Bending-resistant impact-resistant glass material and preparation method thereof |
| CN103771704A (en) * | 2014-01-21 | 2014-05-07 | 江苏奥蓝工程玻璃有限公司 | Light-transmitting hard glass material and preparation method thereof |
| CN104530559A (en) * | 2014-12-15 | 2015-04-22 | 江苏金发科技新材料有限公司 | Weather-resistant glass fiber reinforced polypropylene composite material and preparation method thereof |
-
2018
- 2018-03-01 CN CN201810169532.6A patent/CN108314331A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102898723A (en) * | 2011-07-28 | 2013-01-30 | 合肥杰事杰新材料股份有限公司 | Polypropylene composition and preparation method thereof |
| CN103771702A (en) * | 2014-01-21 | 2014-05-07 | 江苏奥蓝工程玻璃有限公司 | Bending-resistant impact-resistant glass material and preparation method thereof |
| CN103771704A (en) * | 2014-01-21 | 2014-05-07 | 江苏奥蓝工程玻璃有限公司 | Light-transmitting hard glass material and preparation method thereof |
| CN104530559A (en) * | 2014-12-15 | 2015-04-22 | 江苏金发科技新材料有限公司 | Weather-resistant glass fiber reinforced polypropylene composite material and preparation method thereof |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108892373A (en) * | 2018-07-30 | 2018-11-27 | 合肥利裕泰玻璃制品有限公司 | A kind of glass material and preparation method thereof |
| CN109279784A (en) * | 2018-09-18 | 2019-01-29 | 江苏锐阳照明电器设备有限公司 | A kind of high strength glass material |
| CN110627369A (en) * | 2019-09-27 | 2019-12-31 | 安徽省聚科石墨烯科技股份公司 | Preparation method of graphene glass |
| CN110803865A (en) * | 2019-12-03 | 2020-02-18 | 南通华丰工艺品有限公司 | High-strength explosion-proof novel composite material for glass artware and preparation method thereof |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN108314331A (en) | A kind of preparation method of high strength glass material | |
| EP0544201B1 (en) | An acrylic ester copolymer plastisol composition | |
| GB0304276D0 (en) | Reactive hot melt adhesive | |
| JP5909009B2 (en) | Poly (propylene carbonate) chloride and method for preparing the same | |
| CN107488316A (en) | A kind of clear hard PVC formula | |
| KR20110008045A (en) | Thermoplastic acrylic resin composition | |
| KR102152066B1 (en) | Hybrid type PVC stabilizer comprising liquid and powder | |
| CN106905674B (en) | A kind of Flame-retardant PET and PC composite material and preparation method | |
| CN105602078B (en) | A kind of expansion type flame-retarding eva foam composite and its preparation method and application | |
| WO2000069961A1 (en) | Flame retardant resin composition | |
| JP2005255722A (en) | Resin composition and manufacturing method therefor | |
| CN106634358A (en) | High-elasticity external wall coating with enhanced anti-corrosive performance of composite epoxy resin emulsion | |
| CN103936286B (en) | A kind of method utilizing unleaded high barium to discard fluorescent tube to prepare crystallite foam glass | |
| JP2021533216A (en) | Ionomer of ethylenic acid copolymer with improved creep resistance | |
| CN106147280A (en) | A kind of fire-resistant PVC of high-strength high temperature-resistant | |
| KR101465227B1 (en) | Plastic Resin Composition Having High Hardness with Low Lightweight and Method of Producing the Same | |
| CN103849029A (en) | Polyethylene/elastomer/micron calcium carbonate ternary blend composite material | |
| CN104592663A (en) | High-toughness and high-elasticity expandable polystyrene and preparation method thereof | |
| JP6192331B2 (en) | Ethylene-vinyl acetate copolymer resin composition, crosslinked foam, and footwear | |
| CN113801429B (en) | Impact-resistant heat-resistant flame-retardant ABS resin and preparation method thereof | |
| CN106700389B (en) | A kind of ultra-toughness ABS masterbatch composite material | |
| CN109181148B (en) | Nano-modified PVC composite foam material and preparation method thereof | |
| CN107349918A (en) | A kind of preparation method of diatomite aids,filter | |
| CN108359159A (en) | A kind of environment-friendly anti-aging CABLE MATERIALS and preparation method thereof | |
| CN108359149A (en) | A kind of preparation method of expansion type flame-proof rubber |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WW01 | Invention patent application withdrawn after publication | ||
| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180724 |