CN108314147A - A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater - Google Patents

A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater Download PDF

Info

Publication number
CN108314147A
CN108314147A CN201810213387.7A CN201810213387A CN108314147A CN 108314147 A CN108314147 A CN 108314147A CN 201810213387 A CN201810213387 A CN 201810213387A CN 108314147 A CN108314147 A CN 108314147A
Authority
CN
China
Prior art keywords
electrode
steel wire
bath wastewater
original position
wire lump
Prior art date
Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
Withdrawn
Application number
CN201810213387.7A
Other languages
Chinese (zh)
Inventor
张捍民
厉琨
Current Assignee (The listed assignees may be inaccurate. Google has not performed a legal analysis and makes no representation or warranty as to the accuracy of the list.)
Dalian University of Technology
Original Assignee
Dalian University of Technology
Priority date (The priority date is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the date listed.)
Filing date
Publication date
Application filed by Dalian University of Technology filed Critical Dalian University of Technology
Priority to CN201810213387.7A priority Critical patent/CN108314147A/en
Publication of CN108314147A publication Critical patent/CN108314147A/en
Withdrawn legal-status Critical Current

Links

Classifications

    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/463Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electrocoagulation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/465Treatment of water, waste water, or sewage by electrochemical methods by electrolysis by electroflotation
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F2001/007Processes including a sedimentation step
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/46Treatment of water, waste water, or sewage by electrochemical methods
    • C02F1/461Treatment of water, waste water, or sewage by electrochemical methods by electrolysis
    • C02F1/46104Devices therefor; Their operating or servicing
    • C02F1/46109Electrodes
    • C02F2001/46133Electrodes characterised by the material

Abstract

The invention discloses a kind of using fluffy steel wire lump as the method for electrode original position treatment for reuse bath wastewater, belongs to technology of middle water recycle field.Using the fluffy steel wire lump of household as electrode material, single group parallel pole is horizontally placed at bottom of device, appropriate NaCl is added and adjusts conductivity, adjust electrode spacing and voltage and current, carries out electric flocculation air-flotation process, stable effluent quality meets《Urban sewage reutilization urban reclaimed water water quality》It flushes the toilet in (GB/T 18920-2002) water standard, realizes the in-situ treatment reuse of bath wastewater, with good economic efficiency and environmental benefit.

Description

A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater
Technical field
The invention belongs to technology of middle water recycle fields, and in particular to one kind is handled back using fluffy steel wire lump as electrode original position With the method for bath wastewater.
Background technology
Water resource is the basis of human lives.In recent years, the problem of many countries all suffer from shortage of water resources.Middle water returns With being the effective measures of city water problems of improving the ecological environment, solve.Buck accounts for the 50%~80% of sanitary sewage, is at sewage The precious resources of reason and reuse.Graywater treating method has Physical, chemical method, bioanalysis etc..In addition, many researchers also grind The combination of two or more methods is studied carefully.The parameter and purposes of water outlet are the key factors of Screening Treatment method.
In buck, bath wastewater pollution level is lighter, and intractability is low, and discharge capacity is big, is easy to shunt and collect, It is suitble to original position reuse.Practice have shown that bioanalysis need professional carry out operational management, processing unit can not household, and hold Peculiar smell is easily caused, harmful effect is generated to residential environments.Membrane processing method is there are fouling membrane, chemical sludge pollution and cannot effectively go The shortcomings of ash disposal disease caused by infectious water pathogenic microorganism.The physical chemistry methods such as activated carbon adsorption and chemical coagulation need to combine other technologies means It can be only achieved the water standard of Treated sewage reusing.These technologies are unsuitable for the recycling processing technique in situ as bath wastewater.
Electric flocculation Bubble-floating Method is dissolved out using aluminium or iron anode, polymorphic poly-aluminium or the Polyferric Sulfate flocculation of in-situ preparation high activity Contaminant particle in water body is assembled agglomerating and dissolved air flotation by agent.Electric flocculation Bubble-floating Method is efficient, secondary convenient for being separated by solid-liquid separation Pollution is few, and manipulation and plant maintenance are simple, are easy to automatically control, and total molten solid (TDS) is small in final outflow water, is to meet bath wastewater The technology technology that in-situ treatment reuse requires.But the problem of that there is also energy consumptions is excessively high for traditional electric flocculation technique, and electrode is easily passivated.
Invention content
The purpose of the present invention is in order to solve the above technical problems, the invention discloses a kind of electric flocculation air supporting in-situ treatment reuses The technology of bath wastewater, using the fluffy steel wire lump of household (fluffy clump steel wire abbreviation FCSW) as electrode material, Single group parallel pole is horizontally placed at bottom of device, appropriate NaCl is added and adjusts conductivity, adjust electrode spacing and voltage and current, Electric flocculation air-flotation process is carried out, stable effluent quality meets《Urban sewage reutilization urban reclaimed water water quality》(GB/T 18920-2002) flush the toilet in water standard, realize the in-situ treatment reuse of bath wastewater, it is with good economic efficiency and Environmental benefit.
Technical scheme of the present invention:
A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater, steps are as follows:
(1) bath wastewater is passed through to the reaction tank of electric flocculation air-floating apparatus, addition NaCl adjusts conductivity, startup power supply, Carry out electric flocculation air-flotation process;
The electric flocculation air-floating apparatus uses single group parallel pole, electrode material to use FCSW, and two electrodes are drawn into thin Pie, makes it be paved with reaction tank bottom, and two electrode qualities difference is no more than 5%;2~5cm of electrode spacing, electrode are placed horizontally at Reaction tank bottom;
(2) scrape off the dross generated during electric flocculation air supporting, collect water outlet and arrive secondary settling tank, it is to be precipitated completely after, be used for It flushes the toilet.
The NaCl additive amounts are 0.5~2g/L, and conductivity is 2mS/cm after adjusting.
It is 0.5~3A that the power supply, which uses D.C. regulated power supply, setting electric current, and voltage is 5~30V, electric flocculation at this time The air-floating apparatus opening time is 5~40min.
The sedimentation in secondary sedimentation tank time is 30~45min.
The main component of the electrode material FCSW is Fe, also contain the metallic elements such as a small amount of Cr, Mn, Ni and C, The nonmetalloids such as Si, Cl, the main component of the wherein FCSW of Fe are Fe, mass percent 82.33%, followed by Cr and C, Mass percent is respectively 12.00% and 4.07%, in addition also a small amount of Na, Mn, Si, C1, Ni and other full includes Al, S, Ca, K With P etc.), mass percent is respectively 0.56%, 0.33%, 0.30%, 0.11%, 0.10% and 0.20%.
Beneficial effects of the present invention:For the present invention using FCSW as electrode, specific surface area larger FCSW is conducive to anode Dissolving and Fe2+Diffusion, fluff structure be also convenient for electrolysis generate microbubble rising, can also as electrode use Realize waste utilization.After optimizing reaction condition, stable effluent quality meets《Urban sewage reutilization urban reclaimed water water quality》 It flushes the toilet in (GB/T 18920-2002) water standard, realizes in-situ treatment reuse bath wastewater, there is good economic imitate Benefit and environmental benefit.
Specific implementation mode
With reference to technical solution, the technical solution of invention is described in detail.
Embodiment 1
(1) bath wastewater is discharged into reaction tank, each reaction tank addition 1.07gNaCl adjusts conductivity.
(2) it is 2cm to adjust electrode spacing, starts electric flocculation air-floating apparatus, and electric current 1A runs 30min.
(3) scrape off the dross generated during electric flocculation air supporting, collect water outlet and arrive secondary settling tank, it is to be precipitated completely after, be used for It flushes the toilet.
Effluent quality and cost after this method is handled for flushing the toilet is as shown in table 1.
Embodiment 2
(1) bath wastewater is discharged into reaction tank, each reaction tank addition 1.07gNaCl adjusts conductivity.
(2) it is 1cm to adjust electrode spacing, starts electric flocculation air-floating apparatus, and electric current 1A runs 30min.
(3) scrape off the dross generated during electric flocculation air supporting, collect water outlet and arrive secondary settling tank, it is to be precipitated completely after, be used for It flushes the toilet.
Effluent quality and cost after this method is handled for flushing the toilet is as shown in table 1.
Embodiment 3
(1) bath wastewater is discharged into reaction tank, each reaction tank addition 1.07gNaCl adjusts conductivity.
(2) it is 1cm to adjust electrode spacing, starts electric flocculation air-floating apparatus, and electric current 0.8A runs 30min.
(3) scrape off the dross generated during electric flocculation air supporting, collect water outlet and arrive secondary settling tank, it is to be precipitated completely after, be used for It flushes the toilet.
Effluent quality and cost after this method is handled for flushing the toilet is as shown in table 1.
Embodiment 4
(1) bath wastewater is discharged into reaction tank, each reaction tank addition 2.12gNaCl adjusts conductivity.
(2) it is 1cm to adjust electrode spacing, starts electric flocculation air-floating apparatus, and electric current 0.8A runs 30min.
(3) scrape off the dross generated during electric flocculation air supporting, collect water outlet and arrive secondary settling tank, it is to be precipitated completely after, be used for It flushes the toilet.
Effluent quality and cost after this method is handled for flushing the toilet is as shown in table 1.
COD removal rates Ammonia nitrogen removal frank LAS removal rates Cost
Embodiment 1 67.69% 73.03% 48.15% 4.3 yuan/m3
Embodiment 2 80.81% 78.45% 70.37% 2.7 yuan/m3
Embodiment 3 79.75% 77.35% 79.69% 2.6 yuan/m3
Embodiment 4 82.8% 80.42% 71.24% 1.4 yuan/m3
Example the above is only the implementation of the present invention is not intended to limit the scope of the invention, and is created using the present invention It makes design and carries out several modifications and improvements, also belong to protection scope of the present invention.

Claims (5)

1. a kind of using fluffy steel wire lump as the method for electrode original position treatment for reuse bath wastewater, which is characterized in that steps are as follows:
(1) bath wastewater is passed through to the reaction tank of electric flocculation air-floating apparatus, addition NaCl adjusts conductivity, and startup power supply carries out Electric flocculation air-flotation process;
The electric flocculation air-floating apparatus uses single group parallel pole, electrode material that FCSW, two electrodes is used to be drawn into pancake shape, It is set to be paved with reaction tank bottom, two electrode qualities difference is no more than 5%;2~5cm of electrode spacing, electrode are placed horizontally at reaction Bottom of pond portion;
(2) scrape off the dross generated during electric flocculation air supporting, collect water outlet and arrive secondary settling tank, it is to be precipitated completely after, for flushing the toilet.
2. it is according to claim 1 using fluffy steel wire lump as the method for electrode original position treatment for reuse bath wastewater, it is special Sign is that the NaCl additive amounts are 0.5~2g/L, and conductivity is 2mS/cm after adjusting.
3. it is according to claim 1 or 2 using fluffy steel wire lump as the method for electrode original position treatment for reuse bath wastewater, It is characterized in that, it is 0.5~3A that the power supply, which uses D.C. regulated power supply, setting electric current, and voltage is 5~30V, electric flocculation at this time The air-floating apparatus opening time is 5~40min.
4. it is according to claim 1 or 2 using fluffy steel wire lump as the method for electrode original position treatment for reuse bath wastewater, It is characterized in that, the sedimentation in secondary sedimentation tank time is 30~45min.
5. it is according to claim 3 using fluffy steel wire lump as the method for electrode original position treatment for reuse bath wastewater, it is special Sign is that the sedimentation in secondary sedimentation tank time is 30~45min.
CN201810213387.7A 2018-03-15 2018-03-15 A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater Withdrawn CN108314147A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810213387.7A CN108314147A (en) 2018-03-15 2018-03-15 A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater

Applications Claiming Priority (1)

Application Number Priority Date Filing Date Title
CN201810213387.7A CN108314147A (en) 2018-03-15 2018-03-15 A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater

Publications (1)

Publication Number Publication Date
CN108314147A true CN108314147A (en) 2018-07-24

Family

ID=62902562

Family Applications (1)

Application Number Title Priority Date Filing Date
CN201810213387.7A Withdrawn CN108314147A (en) 2018-03-15 2018-03-15 A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater

Country Status (1)

Country Link
CN (1) CN108314147A (en)

Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875522A (en) * 2010-06-09 2010-11-03 南京大学 Grading recycle device for electric flocculation and electric floatation purification bathing and washing wastewater
CN102633325A (en) * 2012-04-19 2012-08-15 波鹰(厦门)科技有限公司 Novel nanometer catalytic electrolysis device
CN102745781A (en) * 2012-07-25 2012-10-24 合肥工业大学 Method for carrying out in-situ remediation on underground water nitrate pollution by adopting iron fuel cell
KR101616276B1 (en) * 2015-07-31 2016-04-28 주식회사 우리종합기술 Sewage sludge treament complex solubilizing system

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101875522A (en) * 2010-06-09 2010-11-03 南京大学 Grading recycle device for electric flocculation and electric floatation purification bathing and washing wastewater
CN102633325A (en) * 2012-04-19 2012-08-15 波鹰(厦门)科技有限公司 Novel nanometer catalytic electrolysis device
CN102745781A (en) * 2012-07-25 2012-10-24 合肥工业大学 Method for carrying out in-situ remediation on underground water nitrate pollution by adopting iron fuel cell
KR101616276B1 (en) * 2015-07-31 2016-04-28 주식회사 우리종합기술 Sewage sludge treament complex solubilizing system

Similar Documents

Publication Publication Date Title
CN203866160U (en) Municipal wastewater treatment system
CN103449678A (en) Agricultural equipment coating wastewater treatment technology
CN105692814B (en) A kind of high concentration suspended matter electric flocculation and flco precipitation and separation integrated treatment unit
CN105084633A (en) Eutrophication water body in-situ electromagnetic coupling flocculation precipitation device
CN104370350A (en) Electrochemistry apparatus for water treatment and method
CN203419777U (en) Electrochemical device for water treatment
CN103922521B (en) Method used for chrome tanning waste water treatment and chrome recovery
CN209890411U (en) Integrated refuse transfer station percolate premixing electrolysis air-flotation pretreatment device
CN112979090A (en) Method suitable for treating percolate of small and medium-sized refuse transfer stations
CN106746054A (en) A kind of method that three-dimensional electrolysis process galvanograph waste water
CN207659276U (en) A kind of integrated sewage disposal system
CN111925044B (en) Sequencing batch biofilm-electrolysis treatment and recycling device and method for domestic sewage
CN211226826U (en) Device based on sulphur is from oxygen denitrogenation dephosphorization
CN109650613A (en) A kind of method of Split type electric Fenton equipment and its efficient process coal chemical industrial waste water
CN110357319B (en) Electrochemical sewage treatment device and treatment process
CN203461851U (en) Electrolytic oxidation device for garbage percolate
CN205472811U (en) Magnetism fe3O4 granule coupling electro -fenton reactor
CN108314147A (en) A method of using fluffy steel wire lump as electrode original position treatment for reuse bath wastewater
CN213475699U (en) Combined building reclaimed water recycling device
CN107216006B (en) Leather wastewater treatment system and method
CN205442907U (en) Flocculation of high concentration suspended solid electricity deposits integration treatment device with flco separation
CN109607691B (en) Method for treating wastewater by coupling galvanic cell and electric flocculation
CN211111206U (en) Electric flocculation purifies little surface water device that pollutes
CN108911366A (en) A kind of rural area integrated effluent disposal system
CN111439897B (en) Economical electrochemical dephosphorization process

Legal Events

Date Code Title Description
PB01 Publication
PB01 Publication
SE01 Entry into force of request for substantive examination
SE01 Entry into force of request for substantive examination
WW01 Invention patent application withdrawn after publication
WW01 Invention patent application withdrawn after publication

Application publication date: 20180724