CN108311810A - A kind of safe welding rod of low spatter type - Google Patents
A kind of safe welding rod of low spatter type Download PDFInfo
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- CN108311810A CN108311810A CN201810062495.9A CN201810062495A CN108311810A CN 108311810 A CN108311810 A CN 108311810A CN 201810062495 A CN201810062495 A CN 201810062495A CN 108311810 A CN108311810 A CN 108311810A
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Classifications
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B23—MACHINE TOOLS; METAL-WORKING NOT OTHERWISE PROVIDED FOR
- B23K—SOLDERING OR UNSOLDERING; WELDING; CLADDING OR PLATING BY SOLDERING OR WELDING; CUTTING BY APPLYING HEAT LOCALLY, e.g. FLAME CUTTING; WORKING BY LASER BEAM
- B23K35/00—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting
- B23K35/22—Rods, electrodes, materials, or media, for use in soldering, welding, or cutting characterised by the composition or nature of the material
- B23K35/36—Selection of non-metallic compositions, e.g. coatings, fluxes; Selection of soldering or welding materials, conjoint with selection of non-metallic compositions, both selections being of interest
- B23K35/362—Selection of compositions of fluxes
Abstract
The invention belongs to welding material of metal technical fields, and in particular to a kind of safe welding rod of low spatter type.The welding rod is made of metal core wire and the first welding agent layer being coated on outside core wire, and the second welding agent layer is also coated with outside the first welding agent layer.Wherein, the first welding agent layer main ingredient is:High carbon ferro-chrome, mid-carbon fe-mn, tungsten carbide, nickel powder, rutile, ferrosilicon, vanadium iron, magnesia, fluorite, fluoride and bonding agent;The granularity of each raw material is 80 mesh or more, and the composition of the second welding agent layer is based on rosin and vaseline.In welding process, second welding agent melts and volatilization process can reduce the temperature for the welding slag that the first welding agent generates, and increases the degree of adhesion between welding slag, to pass through the use of two kinds of welding agent, the welding rod degree and range that in welding, welding slag splashes significantly reduce, and the safety of welding rod is improved.
Description
Technical field
The invention belongs to welding material of metal technical fields, and in particular to a kind of safe welding rod of low spatter type.
Background technology
Welding is the system of a kind of jointing metal in a manner of heating, high temperature or high pressure or other thermoplastic materials such as plastics
Make technique and technology.Electric welding is one kind of welding technique, and electric welding can be not only used for carrying out metalwork connection, can also be to metal
Part surface is modified, and to obtain the cladding layer of the required properties such as wear-resisting, heat-resisting or corrosion-resistant, welding technique is extensive
Applied to industrial circles such as mine, metallurgy, agricultural machinery, building, railway, oil and chemical industry, there is high economic and social benefit.
Fusing is filled in the metal strip of weldment junction when welding rod is electric welding, mainly by core wire and external welding agent layer structure
At according to the difference of function and usage and application places and welding procedure, welding rod is segmented into multiple and different types.The weldering of welding rod
Medicine complicated component, type is various can be applied in different weldments, play the stability for improving arc burning, and protection welding is molten
Pond ensures weld seam deoxidation, desulfuration phosphorus impurities, and alloys producing is supplemented for weld seam.But molten alloy temperature when due to welding
Degree is higher, the problem of welding slag splashes is being easy to happen, using different welding agent since temperature difference is larger with weldment contact
Its splashing of welding rod degree it is different, but welding slag splashing is not avoided that.Welding slag splashes may be to the body of welding operating personnel
Body health damages, it is also possible to cause the harm such as fire in welding place.
Invention content
In view of the above problems, the purpose of the present invention is to provide a kind of safe welding rod of low spatter type, which was using
Welding slag splashing degree is very small in journey, and welding quality is good, and very safe using process.
A kind of safe welding rod of low spatter type, the welding rod are wrapped in the first welding agent layer and on core wire by core wire and successively
Two welding agent layers are constituted.
Wherein, according to mass fraction, the ingredient of the first welding agent layer includes:30-40 parts of high carbon ferro-chrome, mid-carbon fe-mn 5-10
Part, 15-20 parts of tungsten carbide, 8-10 parts of nickel powder, 2-3 parts of rutile, 1-4 parts of ferrosilicon, 4-6 parts of vanadium iron, 1-3 parts of magnesia, fluorite
2-3 parts, 0.4-0.8 parts of fluoride, 20-25 parts of bonding agent.
The ingredient of second welding agent includes:60-70 parts of rosin, 8-15 parts of vaseline, 2-5 parts of hydroabietyl alcohol, succinic acid 4-7
Part, 1-2 parts of diethanol amine, 1-3 parts of surfactant.
Preferably, according to mass fraction, the ingredient of the first welding agent layer includes:34-36 parts of high carbon ferro-chrome, mid-carbon fe-mn 7-8
Part, 17-19 parts of tungsten carbide, 8-9 parts of nickel powder, 2-2.5 parts of rutile, 1-2 parts of ferrosilicon, 4-5 parts of vanadium iron, 2-3 parts of magnesia, fluorite
2-2.5 parts, 0.6-0.7 parts of fluoride.
The ingredient of second welding agent includes:65-68 parts of rosin, 11-13 parts of vaseline, 3-4 parts of hydroabietyl alcohol, succinic acid 5-
6 parts, 1.5-2 parts of diethanol amine, 2-3 parts of surfactant.
The technical thought of the present invention is the second welding agent layer to be arranged by the outer layer in welding agent, the second welding agent layer choosing selects use
The substances such as rosin and vaseline are made, when being welded, due to the effect of electric current, and the alloy in core wire and the first welding agent layer
By heating and melting be attached to weldment surface formed weld seam, wherein welding slag etc. due to being contacted with the substance of the second welding agent layer, wherein
Partial heat be pulled away, and lead to the heated volatilization of the second welding agent layer segment substance, after the temperature of welding slag reduces, splashing journey
Degree is reduced.In addition, since part the second welding agent layer substance fails to volatilize completely, forms melt substance and closed with welding slag and welding
Gold is fallen, and in welded joints, the density of the second welding agent layer substance is relatively low therefore can form top layer in face of weld for attachment
Protective layer can improve the quality of weld seam, and carry out cladding and adhesion to substances such as welding slags, further decrease welding slag splashing
Degree.
Second welding agent layer substance will not be blended in inside welding alloy in the welding process since fusing point and boiling point are relatively low,
The weld seam welding quality of weldment is impacted, the second welding agent layer substance will only adhere to the top layer of weld seam.
Preferably, in the welding rod, the thickness of the first welding agent layer is 7-10 times of the second welding agent layer thickness.Second welding agent layer
Content it is relatively low, while can playing a role, do not interfere with the normal use of welding rod, when the second welding agent layer is blocked up, due to
It, which is taken away too many heat and influences oxygen, enters inside welding rod, it is willing can cause welding rod cannot the normal starting the arc, two outer second welderings
The welding quality that weldment can be also influenced in alloy is penetrated into after medicine melting.
Preferably, the fluoride in the first welding agent layer is one kind in calcirm-fluoride, sodium fluoride and potassium fluotitanate.Fluoride
It uses, the crystal grain thinning of weld metal can be improved, change inclusion morphology, improve welding quality.
Preferably, the bonding agent used in the first welding agent layer is potassium water glass or sodium silicate.
Preferably, the surfactant in the second welding agent layer is silicone based surfactant or fluorocarbon surfactant.
Surfactant can reduce the surface tension of welding agent, improve the wetability and solderability of welding agent, play the protection of the second welding agent
Performance.
Preferably, the granularity of each ingredient is more than 80 mesh in the first welding agent layer.Each material composition in first welding agent layer
Granularity is smaller, and the degree that welding slag splashes is lower, and by lowering the grain size of welding agent raw material, welding slag splashes when can also reduce electric welding
Degree.
Wherein, the welding agent preparation method of the second welding agent layer is:According to mass fraction, rosin and vaseline are added to
In reaction kettle, 140 DEG C are heated to be completely melt up to rosin, then by hydroabietyl alcohol, succinic acid, diethanol amine and surface
Activating agent is added in reaction kettle, is stirred continuously each component to being completely dissolved and being uniformly mixed, and obtains required second welding agent.
A kind of safe welding rod of low spatter type provided by the invention has the following advantages compared with prior art:
First welding agent layer choosing of the welding rod welding agent of low spatter type, all welding agent components have selected granularity smaller
Material can reduce the possibility for welding slag splashing occur;The second welding agent layer choosing ingredients such as rosin vaseline, these materials are welding
When connecing, the ability that can reduce welding slag by absorbing heat prevents welding slag from splashing on a large scale.In addition, since the second welding agent of part is inhaled
It is attached to welding slag surface, leads to the degree of adhesion bigger between welding slag, to further improve the spattering problem of welding process.
Second welding agent layer is in addition to improving spattering problem, additionally it is possible to after the cooling period, form protective layer outside weld metal, ensure
Weld seam deoxidation prevents weld seam alloy from oxidation or corrosion occurs, improves the quality and stability of welding.
Specific implementation mode
The specific implementation mode of the present invention is described in detail below.It should be understood that described herein specific
Embodiment is merely to illustrate and explain the present invention, and is not intended to restrict the invention.
Embodiment 1
A kind of safe welding rod of low spatter type, the welding rod are wrapped in the first welding agent layer and on core wire by core wire and successively
Two welding agent layers are constituted.
According to mass fraction, the ingredient of the first welding agent layer includes:30 parts of high carbon ferro-chrome, 5 parts of mid-carbon fe-mn, tungsten carbide 15
Part, 8 parts of nickel powder, 2 parts of rutile, 1 part of ferrosilicon, 4 parts of vanadium iron, 1 part of magnesia, 2 parts of fluorite, 0.4 part of fluoride, bonding agent 20
Part.
The ingredient of second welding agent includes:60 parts of rosin, 8 parts of vaseline, 2 parts of hydroabietyl alcohol, 4 parts of succinic acid, diethanol
1 part of amine, 1 part of surfactant.
The thickness of the first welding agent layer is 7 times of the second welding agent layer thickness in welding rod;Fluoride in first welding agent layer is fluorine
Change calcium;The bonding agent used in first welding agent layer is potassium water glass;Surfactant in second welding agent layer is siloxanes base table
Face activating agent;The granularity of each ingredient is 100 mesh in first welding agent layer.
Wherein, the welding agent preparation method of the second welding agent layer is:According to mass fraction, rosin and vaseline are added to
In reaction kettle, it is heated to 145 DEG C and is completely melt to rosin, then by hydroabietyl alcohol, succinic acid, diethanol amine and surface-active
Agent is added in reaction kettle, is stirred continuously each component to being completely dissolved and being uniformly mixed, and obtains required second welding agent.
Embodiment 2
A kind of safe welding rod of low spatter type, the welding rod are wrapped in the first welding agent layer and on core wire by core wire and successively
Two welding agent layers are constituted.
According to mass fraction, the ingredient of the first welding agent layer includes:40 parts of high carbon ferro-chrome, 10 parts of mid-carbon fe-mn, tungsten carbide 20
Part, 10 parts of nickel powder, 3 parts of rutile, 4 parts of ferrosilicon, 6 parts of vanadium iron, 3 parts of magnesia, 3 parts of fluorite, 0.8 part of fluoride, bonding agent 25
Part.
The ingredient of second welding agent includes:70 parts of rosin, 15 parts of vaseline, 5 parts of hydroabietyl alcohol, 7 parts of succinic acid, diethanol
2 parts of amine, 3 parts of surfactant.
The thickness of the first welding agent layer is 10 times of the second welding agent layer thickness in welding rod;Fluoride in first welding agent layer is fluorine
Change sodium;The bonding agent used in first welding agent layer is sodium silicate;Surfactant in second welding agent layer is lived for fluorocarbon surface
Property agent;The granularity of each ingredient is 120 mesh in first welding agent layer.
Wherein, the welding agent preparation method of the second welding agent layer is:According to mass fraction, rosin and vaseline are added to
In reaction kettle, it is heated to 150 DEG C and is completely melt to rosin, then by hydroabietyl alcohol, succinic acid, diethanol amine and surface-active
Agent is added in reaction kettle, is stirred continuously each component to being completely dissolved and being uniformly mixed, and obtains required second welding agent.
Embodiment 3
A kind of safe welding rod of low spatter type, the welding rod are wrapped in the first welding agent layer and on core wire by core wire and successively
Two welding agent layers are constituted.
According to mass fraction, the ingredient of the first welding agent layer includes:35 parts of high carbon ferro-chrome, 8 parts of mid-carbon fe-mn, tungsten carbide 17
Part, 9 parts of nickel powder, 2.5 parts of rutile, 2 parts of ferrosilicon, 5 parts of vanadium iron, 2 parts of magnesia, 2.5 parts of fluorite, 0.6 part of fluoride, bonding agent
23 parts.
The ingredient of second welding agent includes:65 parts of rosin, 12 parts of vaseline, 3 parts of hydroabietyl alcohol, 5 parts of succinic acid, diethanol
1.5 parts of amine, 2 parts of surfactant.
The thickness of the first welding agent layer is 8 times of the second welding agent layer thickness in welding rod;Fluoride in first welding agent layer is fluorine
Potassium titanate;The bonding agent used in first welding agent layer is potassium water glass;Surfactant in second welding agent layer is siloxy group
Surfactant;The granularity of each ingredient is 100 mesh in first welding agent layer.
Wherein, the welding agent preparation method of the second welding agent layer is:According to mass fraction, rosin and vaseline are added to
In reaction kettle, it is heated to 145 DEG C and is completely melt to rosin, then by hydroabietyl alcohol, succinic acid, diethanol amine and surface-active
Agent is added in reaction kettle, is stirred continuously each component to being completely dissolved and being uniformly mixed, and obtains required second welding agent.
Embodiment 4
A kind of safe welding rod of low spatter type, the welding rod are wrapped in the first welding agent layer and on core wire by core wire and successively
Two welding agent layers are constituted.
According to mass fraction, the ingredient of the first welding agent layer includes:32 parts of high carbon ferro-chrome, 9 parts of mid-carbon fe-mn, tungsten carbide 16
Part, 10 parts of nickel powder, 2 parts of rutile, 2 parts of ferrosilicon, 4 parts of vanadium iron, 3 parts of magnesia, 2 parts of fluorite, 0.8 part of fluoride, bonding agent 20
Part.
The ingredient of second welding agent includes:70 parts of rosin, 15 parts of vaseline, 3 parts of hydroabietyl alcohol, 6 parts of succinic acid, diethanol
2 parts of amine, 1 part of surfactant.
The thickness of the first welding agent layer is 9 times of the second welding agent layer thickness in welding rod;Fluoride in first welding agent layer is fluorine
Change calcium;The bonding agent used in first welding agent layer is sodium silicate;Surfactant in second welding agent layer is lived for fluorocarbon surface
Property agent;The granularity of each ingredient is 150 mesh in first welding agent layer.
Wherein, the welding agent preparation method of the second welding agent layer is:According to mass fraction, rosin and vaseline are added to
In reaction kettle, it is heated to 155 DEG C and is completely melt to rosin, then by hydroabietyl alcohol, succinic acid, diethanol amine and surface-active
Agent is added in reaction kettle, is stirred continuously each component to being completely dissolved and being uniformly mixed, and obtains required second welding agent.
Embodiment 5
A kind of safe welding rod of low spatter type, the welding rod are wrapped in the first welding agent layer and on core wire by core wire and successively
Two welding agent layers are constituted.
According to mass fraction, the ingredient of the first welding agent layer includes:39 parts of high carbon ferro-chrome, 5 parts of mid-carbon fe-mn, tungsten carbide 18
Part, 8 parts of nickel powder, 2 parts of rutile, 4 parts of ferrosilicon, 6 parts of vanadium iron, 1 part of magnesia, 2 parts of fluorite, 0.8 part of fluoride, bonding agent 20
Part.
The ingredient of second welding agent includes:60 parts of rosin, 15 parts of vaseline, 5 parts of hydroabietyl alcohol, 7 parts of succinic acid, diethanol
1 part of amine, 3 parts of surfactant.
The thickness of the first welding agent layer is 7 times of the second welding agent layer thickness in welding rod;Fluoride in first welding agent layer is fluorine
Change sodium;The bonding agent used in first welding agent layer is potassium water glass;Surfactant in second welding agent layer is lived for fluorocarbon surface
Property agent;The granularity of each ingredient is 120 mesh in first welding agent layer.
Wherein, the welding agent preparation method of the second welding agent layer is:According to mass fraction, rosin and vaseline are added to
In reaction kettle, it is heated to 150 DEG C and is completely melt to rosin, then by hydroabietyl alcohol, succinic acid, diethanol amine and surface-active
Agent is added in reaction kettle, is stirred continuously each component to being completely dissolved and being uniformly mixed, and obtains required second welding agent.
Performance test
The mechanical property of welding rod in the present embodiment is tested, while testing welding rod and splashing in the welding slag of welding process
Degree, and compared with common welding rod in the market, obtain following test result:
Table 1:The mechanical experimental results of the present embodiment
Table 2:The splashing Tachistoscope result of the present embodiment and control group welding rod welding process
Project | Control group | Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | Embodiment 5 |
Splashing degree | Acutely | Slightly | Slightly | Slightly | Slightly | Slightly |
Splashing range | It is larger | It is smaller | It is smaller | It is smaller | It is smaller | It is smaller |
The above experimental data shows welding rod provided by the invention, and every mechanical performance index performance is preferable, and is welding
In termination process, the degree that welding slag splashes has obtained very good control, and the range of splashing is also smaller with respect to crying, and welding rod is using more
Add safety.
Specific embodiments of the present invention are described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, those skilled in the art can make various deformations or amendments within the scope of the claims, this not shadow
Ring the substantive content of the present invention.
Claims (8)
1. a kind of safe welding rod of low spatter type, it is characterised in that:The welding rod is wrapped in first on core wire by core wire and successively
Welding agent layer and the second welding agent layer are constituted;
Wherein, according to mass fraction, the ingredient of the first welding agent layer includes:30-40 parts of high carbon ferro-chrome, 5-10 parts of mid-carbon fe-mn, carbon
15-20 parts of tungsten of change, 8-10 parts of nickel powder, 2-3 parts of rutile, 1-4 parts of ferrosilicon, 4-6 parts of vanadium iron, 1-3 parts of magnesia, 2-3 parts of fluorite,
0.4-0.8 parts of fluoride, 20-25 parts of bonding agent;
The ingredient of second welding agent includes:60-70 parts of rosin, 8-15 parts of vaseline, 2-5 parts of hydroabietyl alcohol, 4-7 parts of succinic acid,
1-2 parts of diethanol amine, 1-3 parts of surfactant.
2. a kind of safe welding rod of low spatter type according to claim 1, it is characterised in that:According to mass fraction, described first
The ingredient of welding agent layer includes:34-36 parts of high carbon ferro-chrome, 7-8 parts of mid-carbon fe-mn, 17-19 parts of tungsten carbide, 8-9 parts of nickel powder, rutile
2-2.5 parts, 1-2 parts of ferrosilicon, 4-5 parts of vanadium iron, 2-3 parts of magnesia, 2-2.5 parts of fluorite, 0.6-0.7 parts of fluoride;
The ingredient of second welding agent includes:65-68 parts of rosin, 11-13 parts of vaseline, 3-4 parts of hydroabietyl alcohol, succinic acid 5-
6 parts, 1.5-2 parts of diethanol amine, 2-3 parts of surfactant.
3. a kind of safe welding rod of low spatter type according to claim 1, it is characterised in that:In the welding rod, the first welding agent layer
Thickness be 7-10 times of the second welding agent layer thickness.
4. a kind of safe welding rod of low spatter type according to claim 1, it is characterised in that:Fluorination in the first welding agent layer
Object is one kind in calcirm-fluoride, sodium fluoride and potassium fluotitanate.
5. a kind of safe welding rod of low spatter type according to claim 1, it is characterised in that:It is used in the first welding agent layer
Bonding agent is potassium water glass or sodium silicate.
6. a kind of safe welding rod of low spatter type according to claim 1, it is characterised in that:Surface in the second welding agent layer
Activating agent is silicone based surfactant or fluorocarbon surfactant.
7. a kind of safe welding rod of low spatter type according to claim 1, it is characterised in that:Each ingredient in the first welding agent layer
Granularity be more than 80 mesh.
8. a kind of safe welding rod of low spatter type according to claim 1, it is characterised in that:The welding agent system of the second welding agent layer
Preparation Method is:According to mass fraction, rosin and vaseline are added in reaction kettle, are heated to 140 DEG C with complete up to rosin
Hydroabietyl alcohol, succinic acid, diethanol amine and surfactant, are then added in reaction kettle, are stirred continuously each group by fusing
Divide to being completely dissolved and being uniformly mixed, obtains required second welding agent.
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CN201810062495.9A CN108311810A (en) | 2018-01-23 | 2018-01-23 | A kind of safe welding rod of low spatter type |
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CN201810062495.9A CN108311810A (en) | 2018-01-23 | 2018-01-23 | A kind of safe welding rod of low spatter type |
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Citations (6)
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JPS5265144A (en) * | 1975-11-26 | 1977-05-30 | Kawasaki Steel Co | Antihygroscopic double covered arc electrode |
CN2282957Y (en) * | 1996-06-29 | 1998-06-03 | 周承业 | Multi-layer flat welding rod |
CN1293093A (en) * | 2000-12-07 | 2001-05-02 | 房爱存 | High-temp antiwear surfacing welding electrode |
RU2244615C1 (en) * | 2003-10-20 | 2005-01-20 | Тольяттинский государственный университет | Electric arc welding electrode |
CN102922180A (en) * | 2012-11-26 | 2013-02-13 | 沈阳哈维尔表面工程技术有限公司 | Build-up welding rod for intermetallic high abrasion and medium impact |
CN103394824A (en) * | 2013-08-02 | 2013-11-20 | 瑞玛泰(北京)科技有限公司 | Low-splash and halogen-free welding agent for tin wires and preparation method thereof |
-
2018
- 2018-01-23 CN CN201810062495.9A patent/CN108311810A/en not_active Withdrawn
Patent Citations (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5265144A (en) * | 1975-11-26 | 1977-05-30 | Kawasaki Steel Co | Antihygroscopic double covered arc electrode |
CN2282957Y (en) * | 1996-06-29 | 1998-06-03 | 周承业 | Multi-layer flat welding rod |
CN1293093A (en) * | 2000-12-07 | 2001-05-02 | 房爱存 | High-temp antiwear surfacing welding electrode |
RU2244615C1 (en) * | 2003-10-20 | 2005-01-20 | Тольяттинский государственный университет | Electric arc welding electrode |
CN102922180A (en) * | 2012-11-26 | 2013-02-13 | 沈阳哈维尔表面工程技术有限公司 | Build-up welding rod for intermetallic high abrasion and medium impact |
CN103394824A (en) * | 2013-08-02 | 2013-11-20 | 瑞玛泰(北京)科技有限公司 | Low-splash and halogen-free welding agent for tin wires and preparation method thereof |
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