CN108310900A - A kind of nano molecular charcoal - Google Patents

A kind of nano molecular charcoal Download PDF

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Publication number
CN108310900A
CN108310900A CN201810084796.1A CN201810084796A CN108310900A CN 108310900 A CN108310900 A CN 108310900A CN 201810084796 A CN201810084796 A CN 201810084796A CN 108310900 A CN108310900 A CN 108310900A
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Prior art keywords
carbon
charcoal
capacity
nano
nano molecular
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Chinese (zh)
Inventor
王禄林
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Compound New Materials Technology (shanghai) Co Ltd
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Compound New Materials Technology (shanghai) Co Ltd
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Priority to CN201810084796.1A priority Critical patent/CN108310900A/en
Publication of CN108310900A publication Critical patent/CN108310900A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/02Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/46Removing components of defined structure
    • B01D53/72Organic compounds not provided for in groups B01D53/48 - B01D53/70, e.g. hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D53/00Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
    • B01D53/34Chemical or biological purification of waste gases
    • B01D53/74General processes for purification of waste gases; Apparatus or devices specially adapted therefor
    • B01D53/81Solid phase processes
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/06Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising oxides or hydroxides of metals not provided for in group B01J20/04
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/10Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising silica or silicate
    • B01J20/16Alumino-silicates
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
    • B01J20/00Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
    • B01J20/02Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material
    • B01J20/20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof comprising inorganic material comprising free carbon; comprising carbon obtained by carbonising processes
    • B01J20/205Carbon nanostructures, e.g. nanotubes, nanohorns, nanocones, nanoballs
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2253/00Adsorbents used in seperation treatment of gases and vapours
    • B01D2253/10Inorganic adsorbents
    • B01D2253/102Carbon
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/702Hydrocarbons
    • B01D2257/7027Aromatic hydrocarbons
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/704Solvents not covered by groups B01D2257/702 - B01D2257/7027
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D2257/00Components to be removed
    • B01D2257/70Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
    • B01D2257/708Volatile organic compounds V.O.C.'s

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  • Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Environmental & Geological Engineering (AREA)
  • Organic Chemistry (AREA)
  • Inorganic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Health & Medical Sciences (AREA)
  • Biomedical Technology (AREA)
  • Crystallography & Structural Chemistry (AREA)
  • Materials Engineering (AREA)
  • Nanotechnology (AREA)
  • Solid-Sorbent Or Filter-Aiding Compositions (AREA)

Abstract

The invention discloses a kind of nano molecular charcoals, including following component;Active powdered carbon, silicate, effervescent tablet, titanium dioxide, this kind of nano molecular charcoal, not only adsorption capacity and capacity of decomposition are strong, and purification efficiency is high, long shelf-life, the harmful substances such as formaldehyde, Benzene and Homologues in purification air that can be lasting for a long time, and traditional sorbing material is changed without capacity of decomposition, or some have the material of capacity of decomposition but the poor problem of adsorption energy, it is non-volatility, non-corrosive, nontoxic, it is outstanding toxic gas scavenging material, and preparation method is simple, and production cost is low.

Description

A kind of nano molecular charcoal
Technical field
The present invention relates to material for air purification technical fields, more particularly, to a kind of nano molecular charcoal.
Background technology
Air purification refers to removing haze for indoor various environmental problems offer sterilizings, depositing dust, dispelling harmful finishing Residual and the total solution such as peculiar smell, raising makes the life better, office conditions, promotes physically and mentally healthy, indoor environmental pollution object Include mainly radgas, mould, particulate matter, finishing residual, secondhand smoke etc. with pollution source, people need to suck sky when breathing Gas, oxygen is ingested in alveolar, is then discharged out containing high concentration carbon dioxide and some other toxic, pernicious gas.Research It was found that people's lung, which can be discharged more than 20, plants noxious material, wherein more than 10 kinds contain volatile poison, therefore, people crowded, air not It in the room of circulation, often comes over dizzy, have difficulty in breathing, uncomfortable in chest, cold perspiration, nausea etc., symptom occurs in severe patient.In addition, suffering from Pathogen can be broadcast to other people by the patient of respiratory infectious disease by expiratory air, sneeze, cough, phlegm and nasal mucus etc..
Tobacco will produce nicotine, tar, hydrocyanic acid etc. in burning.Nicotine can excitor nerve, vasoconstriction, rise Hypertension and reduction tissue blood supply can improve zmount of oxygen consumption by increasing heart rate, and continuous sucking nicotine can excessively make one It dies.Tar contains a variety of organic compounds, wherein containing substances such as micro BaP, benzene anthracenes, BaP has stronger carcinogenic Effect.The data that the World Health Organization announces shows the lung cancer death of 65 years old or less male 90/100,75/100 chronic branch gas The death of Guan Yan and pulmonary emphysema is due to caused by smoking, with being done step-by-step for fairly comfortable life, quality of the people to home environment It also has higher requirement, finishing has become fashion at home, however people often ignore the living environment by finishing to strong The influence of health and safety.
In recent years, the room air pollution situation caused by finishing problem was more and more common, and in these finishing pollutions, Formaldehyde pollution, benzene homologues pollution etc. is very big to the health hazard of human body, causes the attention of all circles' understanding.Currently on the market Air purifying preparation is mainly based on activated carbon and photocatalyst spray, and activated carbon is administered pernicious gas and is not thorough, because of adsorption saturation Later, it is particularly easy to the case where pernicious gas overflows, sky is caused to go secondary pollution again occur, photocatalyst spray is of high cost, and And photocatalyst is that spray is aerial, can only solve the pernicious gases such as the formaldehyde for being discharged into air for the moment, can not solve Interior Space Gas pollutant acquisition time is up to the fundamental issue of 3-15, therefore, it is also desirable to novel material for air purification be developed, to avoid It is insufficient existing for current material.
Invention content
The technical problem to be solved by the present invention is to overcome the existing defects, provides a kind of nano molecular charcoal, on solving State problem.
To achieve the above object, the present invention provides the following technical solutions:A kind of nano molecular charcoal, including following component;
Active powdered carbon, silicate, effervescent tablet, titanium dioxide.
As a preferred technical solution of the present invention, the activity powdered carbon weight is 60%.
As a preferred technical solution of the present invention, the silicate weight is 20%.
As a preferred technical solution of the present invention, the effervesce sheet weight is 5%.
As a preferred technical solution of the present invention, the titania weight is 15%.
Compared with prior art, the beneficial effects of the invention are as follows:This kind of nano molecular charcoal, not only adsorption capacity and resolution Power is strong, and purification efficiency is high, long shelf-life, and formaldehyde, the Benzene and Homologues etc. in purification air that can be lasting for a long time have Evil substance, and traditional sorbing material is changed without capacity of decomposition or some have the material of capacity of decomposition but adsorption energy is poor Problem, it is non-volatility, non-corrosive, nontoxic, it is outstanding toxic gas scavenging material, and preparation method is simple, it is raw It produces at low cost.
Specific implementation mode
Technical scheme in the embodiment of the invention is clearly and completely described, it is clear that described embodiment is only It is a part of the embodiment of the present invention, instead of all the embodiments, based on the embodiments of the present invention, ordinary skill people The every other embodiment that member is obtained without making creative work, shall fall within the protection scope of the present invention.
The present invention provides a kind of technical solution:A kind of nano molecular charcoal, including following component;
Active powdered carbon, silicate, effervescent tablet, titanium dioxide.
Active powdered carbon weight is 60%, and silicate weight is 20%, and effervesce sheet weight is 5%, and titania weight is 15%.
Embodiment 1
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 10- is evacuated to by the container equipped with substance to be evaporated After 6Pa high vacuum, it is filled with inert gas, then heats 20min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation On condenser, the particle of the nanoscale of aggregation is collected in the range between 100-120 to get to nano-powder, wherein profit Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound Oxide, the diameter of general active carbon particle at 11 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere, Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized From effervesce sheet weight is 5%, and titania weight 15%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters 0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air It is basic that evil substance is purified.
Embodiment 2
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 8- is evacuated to by the container equipped with substance to be evaporated After 4Pa high vacuum, it is filled with inert gas, then heats 12min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation On condenser, the particle of the nanoscale of aggregation is collected in the range between 108-110 to get to nano-powder, wherein profit Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound Oxide, the diameter of general active carbon particle at 13 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere, Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized From effervesce sheet weight is 3%, and titania weight 12%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters 0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air It is basic that evil substance is purified.
Embodiment 3
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 10- is evacuated to by the container equipped with substance to be evaporated After 8Pa high vacuum, it is filled with inert gas, then heats 23min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation On condenser, wherein adding hybrid reaction by obtained nano powder using hydrothermal deposition and hydrothermal oxidization reaction, obtains metal and receive The diameter of rice flour oxide or composite oxides, general active carbon particle passes through the oxygen that pressure-variable adsorption is realized at 10 μm or more The separation of gas and nitrogen, effervesce sheet weight are 6%, and titania weight 17%, charcoal molecule aperture size is adjusted Microporous Carbon allows relatively small O2 molecules (diameter 0.346nm) to rapidly diffuse into inside nano-space and block relatively large N2 Molecule (diameter 0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, it can shape At oxygen-enriched absorption phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently in air formaldehyde, benzene and its The harmful substances such as homologue are purified basic.
Embodiment 4
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 11- is evacuated to by the container equipped with substance to be evaporated After 3Pa high vacuum, it is filled with inert gas, then heats 16min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation On condenser, the particle of the nanoscale of aggregation is collected in the range between 90-100 to get to nano-powder, wherein utilizing Hydrothermal deposition and hydrothermal oxidization reaction add hybrid reaction by obtained nano powder, obtain metal nano powder oxide or composite oxygen Compound, the diameter of general active carbon particle is at 11 μm or more, in addition, can be divided into hollow carbon sphere, reality according to the structure and morphology of carbon ball Hard-hearted carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized From effervesce sheet weight is 4%, and titania weight 14%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters 0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air It is basic that evil substance is purified.
Embodiment 5
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 10- is evacuated to by the container equipped with substance to be evaporated After 6Pa high vacuum, it is filled with inert gas, then heats 22min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation On condenser, the particle of the nanoscale of aggregation is collected in the range between 105-130 to get to nano-powder, wherein profit Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound Oxide, the diameter of general active carbon particle at 11 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere, Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized From effervesce sheet weight is 5%, and titania weight 15%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters 0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air It is basic that evil substance is purified.
Embodiment 6
Active powdered carbon, silicate, effervescent tablet, titanium dioxide are weighed respectively, 11- is evacuated to by the container equipped with substance to be evaporated After 8Pa high vacuum, it is filled with inert gas, then heats 18min, so that substance is evaporated the atom that nebulizes, arrived with inert-gas condensation On condenser, the particle of the nanoscale of aggregation is collected in the range between 100-120 to get to nano-powder, wherein profit Hybrid reaction is added by obtained nano powder with hydrothermal deposition and hydrothermal oxidization reaction, obtains metal nano powder oxide or compound Oxide, the diameter of general active carbon particle at 11 μm or more, in addition, according to the structure and morphology of carbon ball can be divided into hollow carbon sphere, Solid hard carbon ball, porous carbon ball, nucleocapsid carbon ball and gluey carbon ball pass through point of oxygen and nitrogen that pressure-variable adsorption is realized From effervesce sheet weight is 6%, and titania weight 17%, the Microporous Carbon that charcoal molecule aperture size is adjusted allows phase Small O2 molecules (diameter 0.346nm) are rapidly diffused into inside nano-space and block relatively large N2 molecule (diameters 0.364nm), since the kinetic selectivity of O2 is better than N2, so when carbon molecular sieve and air contact, oxygen-enriched absorption can be formed Phase, here it is the bases that air separation is carried out with carbon molecular sieve, and persistently have to formaldehyde, the Benzene and Homologues etc. in air It is basic that evil substance is purified.
Concrete principle:In use, nano molecular charcoal distributes purification factor, persistently to formaldehyde, benzene and its homology in air The harmful substances such as object are purified.
This kind of nano molecular charcoal, not only adsorption capacity and capacity of decomposition are strong, but also purification efficiency is high, long shelf-life, can be with The harmful substances such as formaldehyde, Benzene and Homologues in lasting for a long time purification air, and change traditional sorbing material without point Solution ability or some have the material of capacity of decomposition but a poor problem of adsorption energy, it is non-volatility, non-corrosive, nontoxic, be Outstanding toxic gas scavenging material, and preparation method is simple, and production cost is low.
Finally it should be noted that:The foregoing is only a preferred embodiment of the present invention, is not intended to restrict the invention, Although the present invention is described in detail referring to the foregoing embodiments, for those skilled in the art, still may be used With technical scheme described in the above embodiments is modified or equivalent replacement of some of the technical features, All within the spirits and principles of the present invention, any modification, equivalent replacement, improvement and so on should be included in the present invention's Within protection domain.

Claims (5)

1. a kind of nano molecular charcoal, which is characterized in that including following component;
Active powdered carbon, silicate, effervescent tablet, titanium dioxide.
2. a kind of nano molecular charcoal according to claim 1, which is characterized in that the activity powdered carbon weight is 60%.
3. a kind of nano molecular charcoal according to claim 1, which is characterized in that the silicate weight is 20%.
4. a kind of nano molecular charcoal according to claim 1, which is characterized in that the effervesce sheet weight is 5%.
5. a kind of nano molecular charcoal according to claim 1, which is characterized in that the titania weight is 15%.
CN201810084796.1A 2018-01-29 2018-01-29 A kind of nano molecular charcoal Pending CN108310900A (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
CN201810084796.1A CN108310900A (en) 2018-01-29 2018-01-29 A kind of nano molecular charcoal

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Application Number Priority Date Filing Date Title
CN201810084796.1A CN108310900A (en) 2018-01-29 2018-01-29 A kind of nano molecular charcoal

Publications (1)

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102284287A (en) * 2010-06-18 2011-12-21 上海牛翼新能源科技有限公司 Titanium dioxide molecular sieve supported platinum cold catalyst for removing formaldehyde in indoor air
CN104186539A (en) * 2014-08-01 2014-12-10 东莞市邦尼洁生物科技有限公司 Controlled-release agent for purifying spatial environment
CN106139893A (en) * 2016-07-13 2016-11-23 吴美燕 A kind of preparation method of the effervesce air purifying preparation removing pernicious gas
CN106799000A (en) * 2017-01-24 2017-06-06 南京双全科技有限公司 Except formaldehyde effervescent tablet and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102284287A (en) * 2010-06-18 2011-12-21 上海牛翼新能源科技有限公司 Titanium dioxide molecular sieve supported platinum cold catalyst for removing formaldehyde in indoor air
CN104186539A (en) * 2014-08-01 2014-12-10 东莞市邦尼洁生物科技有限公司 Controlled-release agent for purifying spatial environment
CN106139893A (en) * 2016-07-13 2016-11-23 吴美燕 A kind of preparation method of the effervesce air purifying preparation removing pernicious gas
CN106799000A (en) * 2017-01-24 2017-06-06 南京双全科技有限公司 Except formaldehyde effervescent tablet and preparation method thereof

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