CN106139893A - A kind of preparation method of the effervesce air purifying preparation removing pernicious gas - Google Patents
A kind of preparation method of the effervesce air purifying preparation removing pernicious gas Download PDFInfo
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- CN106139893A CN106139893A CN201610548583.0A CN201610548583A CN106139893A CN 106139893 A CN106139893 A CN 106139893A CN 201610548583 A CN201610548583 A CN 201610548583A CN 106139893 A CN106139893 A CN 106139893A
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- aeo
- polyoxyethylene
- pernicious gas
- sorbitan
- effervesce
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/34—Chemical or biological purification of waste gases
- B01D53/74—General processes for purification of waste gases; Apparatus or devices specially adapted therefor
- B01D53/86—Catalytic processes
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D53/00—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols
- B01D53/02—Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols by adsorption, e.g. preparative gas chromatography
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2257/00—Components to be removed
- B01D2257/70—Organic compounds not provided for in groups B01D2257/00 - B01D2257/602
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- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01D—SEPARATION
- B01D2258/00—Sources of waste gases
- B01D2258/06—Polluted air
Abstract
The present invention relates to the preparation method of a kind of effervesce air purifying preparation removing pernicious gas, convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant are mixed according to certain mass ratio, it after extrusion equipment extruding granulating, is packaged to be the effervesce air purifying preparation removing pernicious gas.The present invention both can use under conditions of having light, it is also possible to uses under the conditions of light source is unallowed, and the effect removing pernicious gas under conditions of having light is more excellent.
Description
Technical field
The present invention relates to the preparation method of a kind of effervesce air purifying preparation removing pernicious gas.
Background technology
Current air purifying preparation be divided into two kinds a kind of be the cleanser of the purpose utilizing the fragrance of self to reach covering smell,
Another kind of for utilizing absorption or chemical reaction to reach absorption or the cleanser of degraded pernicious gas.The first simply covers different
Taste, itself is not to harmful gas removing；And the second existing market divides two kinds of a kind of traditional absorption utilizing activated carbon former
Reason is adsorbed, and pernicious gas is simply adsorbed by this type of method, does not thoroughly remove, adsorb saturated after need to change adsorbent；
Another kind is novel photocatalyst formulation, and under light illumination, valence-band electrons is excited to conduction band to nano photo-catalytic, defines electronics
And hole, and O2 and the H2O effect being adsorbed in its surface, generate superoxide anion radical, O2-and hydroxyl radical free radical-
OH, its free radical has very strong oxidative decomposition capacity, can destroy the C-C key in organic matter, c h bond, C-N key, C-O key, O-H
Key, N-H key, decomposing organic matter is carbon dioxide and water；Destroy the protein of the cell membrane solidification virus of bacterium simultaneously, change thin
Bacterium, virus living environment thus kill bacterium, virus, though this type of method can by harmful gas removing, but use when must have
The existence of light, use is subject to certain restrictions.
Content of the invention
The technical problem to be solved is to provide the preparation of a kind of effervesce air purifying preparation removing pernicious gas
Method, the present invention solves pernicious gas and peculiar smell in air.
In order to solve above-mentioned technical problem, present invention employs techniques below scheme:
The preparation method of a kind of effervesce air purifying preparation removing pernicious gas, it is characterised in that follow the steps below:
It is 5～80:5～80:5 by convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant according to mass ratio
～80:5～80:0～80 mix, and after extrusion equipment extruding granulating, the effervesce air being packaged to be removing pernicious gas is net
Agent；
Described convergence adsorbent is the one in silica gel, activated alumina, activated carbon, zinc sulfate, Mayan indigo plant, alum and molecular sieve
Or arbitrary proportion is two or more；
Described photocatalyst agent is the one in nano titanium oxide, nano zine oxide, nano-sized iron oxide and nano-zinc sulfide or appoints
Meaning ratio two or more；
Described organic acid is the two or more of a kind of or arbitrary proportion in oxalic acid, citric acid, malic acid and glacial acetic acid；
Described foaming agent is two of a kind of or arbitrary proportion in sodium acid carbonate, saleratus, sodium carbonate, potassium carbonate and calcium carbonate
More than Zhong；
Described surfactant is neopelex, lauryl sodium sulfate, APES, Sorbitan
Alcohol fatty acid ester-20, sorbitan fatty acid ester-30, sorbitan fatty acid ester-80, polyoxyethylene sorbitan
Monolaurate-20, polyoxyethylene 20 sorbitan monolaurate-40, polyoxyethylene 20 sorbitan monolaurate-
60th, polyoxyethylene 20 sorbitan monolaurate-80, AEO-3, AEO-4, fat
Alcohol APEO-5, AEO-7, AEO-9, AEO-15, fat
A kind of or arbitrary proportion in alcohol APEO-20, AEO-23 and dimethicone two or more；
Described surfactant be neopelex, sorbitan fatty acid ester-20, sorbitan fatty acid ester-30,
Sorbitan fatty acid ester-80, polyoxyethylene 20 sorbitan monolaurate-20, polyoxyethylene sorbitan Dan Yue
Cinnamic acid ester-40, polyoxyethylene 20 sorbitan monolaurate-60, polyoxyethylene 20 sorbitan monolaurate-80, fat
Fat alcohol APEO-3, AEO-4, AEO-5, AEO-7, fat
Fat alcohol APEO-9, AEO-15, AEO-20, AEO-23,
A kind of or arbitrary proportion in benzalkonium chloride and dimethicone two or more.
Described convergence adsorbent is alum and the zinc sulfate composition according to mass ratio 2:1；Described photocatalyst agent is nanometer
Titanium dioxide and nano zine oxide are according to the composition of mass ratio 2:1；Described organic acid is citric acid；Described foaming agent is carbonic acid
Calcium and sodium acid carbonate are according to the composition of mass ratio 2:1；Described surfactant is neopelex and dodecyl
Sodium sulphate is according to the composition of mass ratio 2:3；The matter of convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant
Amount ratio is 30:30:10:15:15.
The present invention has a following Advantageous Effects:
1), the present invention not only can be adsorbed but also can degrade, and the pernicious gas of absorption and peculiar smell are degraded under the effect of photocatalyst agent,
Increase the utilization rate of absorption astringent, use absorption astringent consumptive material few than simple.
2), the present invention uses absorption to add the pattern of degraded, under conditions of having light unglazed all have removing pernicious gas and
The effect of peculiar smell, uses compared with photocatalyst agent with simple, and range is wider.
3), the present invention adds surfactant, increases the contact area of itself and air, and absorption efficiency is higher.
4), the present invention is solid particle, is dissolved and in water, fater disintegration under the effect of effervesce, dissolve during use
Time is short, convenient use.
Detailed description of the invention
Further illustrate the present invention below in conjunction with instantiation.
Embodiment one
By convergence adsorbent, photocatalyst agent, organic acid and foaming agent according to mass ratio be 35:35:15:15 mix, by extruding
It after equipment extruding granulating, is packaged to be the effervesce air purifying preparation removing pernicious gas.
Embodiment two
It is 30:30:10:15:15 by convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant according to mass ratio
Mix, after extrusion equipment extruding granulating, be packaged to be the effervesce air purifying preparation removing pernicious gas.
Embodiment three
It is 30:35:10:15:10 by convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant according to mass ratio
Mix, after extrusion equipment extruding granulating, be packaged to be the effervesce air purifying preparation removing pernicious gas.
Embodiment four
It is 35:25:10:15:15 by convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant according to mass ratio
Mix, after extrusion equipment extruding granulating, be packaged to be the effervesce air purifying preparation removing pernicious gas.
In embodiment 1 to 4, described convergence adsorbent is alum and the zinc sulfate composition according to mass ratio 2:1；Described light
Catalyzer contact agent is nano titanium oxide and the nano zine oxide composition according to mass ratio 2:1；Described organic acid is citric acid；Described
Foaming agent is calcium carbonate and the sodium acid carbonate composition according to mass ratio 2:1；Described surfactant is DBSA
Sodium and lauryl sodium sulfate are according to the composition of mass ratio 2:3.
Further illustrate beneficial effects of the present invention below in conjunction with experimental data:
1st, material to be tested is tested
1 materials and methods:
1.1 test spaces: by four 4m*4m*4m confined spaces that detection content of formaldehyde is consistent.
1.2 materials to be tested: the embodiment of the present invention the 1st, embodiment the 2nd, embodiment 3 and embodiment 4 do effectiveness comparison.
1.3 experimental design: test sets 4 process, takes embodiment the 1st, embodiment the 2nd, embodiment 3 and the embodiment of same quality
4 are dissolved separately in the plastic cup filling same water, put in confined space, keep turning on light state in space, detect respectively 0h,
Content of formaldehyde (mg/m in 6h, 12h, 18h, 24h, 30h, 36h, 42h and 48 hours confined spaces3).
This experiment other conditions in addition to the embodiment using is different are all consistent.
2 results and analysis
Embodiment the 1st, embodiment the 2nd, embodiment 3 processes with embodiment 4 and compares, result such as table 1.
Table 1 respectively processes the impact of PARA FORMALDEHYDE PRILLS(91,95)
| Embodiment 1 | Embodiment 2 | Embodiment 3 | Embodiment 4 | |
| 0h | 0.35 | 0.35 | 0.35 | 0.35 |
| 6h | 0.28 | 0.22 | 0.25 | 0.24 |
| 12h | 0.22 | 0.16 | 0.22 | 0.22 |
| 18h | 0.18 | 0.14 | 0.17 | 0.16 |
| 24h | 0.16 | 0.13 | 0.16 | 0.15 |
| 30h | 0.15 | 0.12 | 0.15 | 0.14 |
| 36h | 0.14 | 0.11 | 0.14 | 0.13 |
| 42h | 0.13 | 0.10 | 0.13 | 0.12 |
| 48h | 0.12 | 0.09 | 0.12 | 0.11 |
To remove effect of formaldehyde the highest for embodiment 2 as can be seen from Table 1.
Discuss: newly-decorated family moves in ventilation, plant absorption and charcoal absorption etc. can be used simply to arrange as no hurry
Execute, remove pernicious gas, move in preferably with the preferable product removing pernicious gas as worried, prevent pernicious gas to human body
Murder by poisoning.
Claims (2)
1. the preparation method of the effervesce air purifying preparation removing pernicious gas, it is characterised in that follow the steps below:
It is 5～80:5～80:5 by convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant according to mass ratio
～80:5～80:0～80 mix, and after extrusion equipment extruding granulating, the effervesce air being packaged to be removing pernicious gas is net
Agent；
Described convergence adsorbent is the one in silica gel, activated alumina, activated carbon, zinc sulfate, Mayan indigo plant, alum and molecular sieve
Or arbitrary proportion is two or more；
Described photocatalyst agent is the one in nano titanium oxide, nano zine oxide, nano-sized iron oxide and nano-zinc sulfide or appoints
Meaning ratio two or more；
Described organic acid is the two or more of a kind of or arbitrary proportion in oxalic acid, citric acid, malic acid and glacial acetic acid；
Described foaming agent is two of a kind of or arbitrary proportion in sodium acid carbonate, saleratus, sodium carbonate, potassium carbonate and calcium carbonate
More than Zhong；
Described surfactant is neopelex, lauryl sodium sulfate, APES, Sorbitan
Alcohol fatty acid ester-20, sorbitan fatty acid ester-30, sorbitan fatty acid ester-80, polyoxyethylene sorbitan
Monolaurate-20, polyoxyethylene 20 sorbitan monolaurate-40, polyoxyethylene 20 sorbitan monolaurate-
60th, polyoxyethylene 20 sorbitan monolaurate-80, AEO-3, AEO-4, fat
Alcohol APEO-5, AEO-7, AEO-9, AEO-15, fat
A kind of or arbitrary proportion in alcohol APEO-20, AEO-23 and dimethicone two or more；
Described surfactant be neopelex, sorbitan fatty acid ester-20, sorbitan fatty acid ester-30,
Sorbitan fatty acid ester-80, polyoxyethylene 20 sorbitan monolaurate-20, polyoxyethylene sorbitan Dan Yue
Cinnamic acid ester-40, polyoxyethylene 20 sorbitan monolaurate-60, polyoxyethylene 20 sorbitan monolaurate-80, fat
Fat alcohol APEO-3, AEO-4, AEO-5, AEO-7, fat
Fat alcohol APEO-9, AEO-15, AEO-20, AEO-23,
A kind of or arbitrary proportion in benzalkonium chloride and dimethicone two or more.
2. the preparation method of the effervesce air purifying preparation removing pernicious gas as claimed in claim 1, it is characterised in that: described
Convergence adsorbent is alum and the zinc sulfate composition according to mass ratio 2:1；Described photocatalyst agent is nano titanium oxide and receives
Rice zinc oxide is according to the composition of mass ratio 2:1；Described organic acid is citric acid；Described foaming agent is calcium carbonate and sodium acid carbonate
Composition according to mass ratio 2:1；Described surfactant is that neopelex and lauryl sodium sulfate are according to matter
The composition than 2:3 for the amount；The mass ratio of convergence adsorbent, photocatalyst agent, organic acid, foaming agent and surfactant is 30:30:
10:15:15。
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| Application Number | Priority Date | Filing Date | Title |
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| CN201610548583.0A CN106139893A (en) | 2016-07-13 | 2016-07-13 | A kind of preparation method of the effervesce air purifying preparation removing pernicious gas |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106732817A (en) * | 2016-12-21 | 2017-05-31 | 重庆中鼎三正科技有限公司 | The titanium dioxide optical catalyst and preparation method of a kind of adsorbable organic matter |
| CN108310900A (en) * | 2018-01-29 | 2018-07-24 | 复纳新材料科技（上海）有限公司 | A kind of nano molecular charcoal |
| CN108452673A (en) * | 2018-03-22 | 2018-08-28 | 淮北智淮科技有限公司 | A kind of preparation method of antibacterial type air purifying preparation |
| CN109529608A (en) * | 2018-12-19 | 2019-03-29 | 舒沐科技(武汉)有限公司 | A kind of environment-friendly highly efficient photocatalyst formaldehyde scavenger with fragrance |
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| CN104707452A (en) * | 2015-03-09 | 2015-06-17 | 北京中天国宏环保科技有限公司 | Benzaldehyde scavenger |
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Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1820838A (en) * | 2005-02-16 | 2006-08-23 | 周成一 | Air purifying material and its preparing method |
| CN101491257A (en) * | 2009-03-05 | 2009-07-29 | 河北科技大学 | Effervescence type disinfection deodorizer and preparation method thereof |
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Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106732817A (en) * | 2016-12-21 | 2017-05-31 | 重庆中鼎三正科技有限公司 | The titanium dioxide optical catalyst and preparation method of a kind of adsorbable organic matter |
| CN108310900A (en) * | 2018-01-29 | 2018-07-24 | 复纳新材料科技（上海）有限公司 | A kind of nano molecular charcoal |
| CN108452673A (en) * | 2018-03-22 | 2018-08-28 | 淮北智淮科技有限公司 | A kind of preparation method of antibacterial type air purifying preparation |
| CN109529608A (en) * | 2018-12-19 | 2019-03-29 | 舒沐科技(武汉)有限公司 | A kind of environment-friendly highly efficient photocatalyst formaldehyde scavenger with fragrance |
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Application publication date: 20161123 |
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