CN108301922A - Mixing energy supplying system based on gas turbine and molten carbonate fuel cell - Google Patents
Mixing energy supplying system based on gas turbine and molten carbonate fuel cell Download PDFInfo
- Publication number
- CN108301922A CN108301922A CN201710019836.XA CN201710019836A CN108301922A CN 108301922 A CN108301922 A CN 108301922A CN 201710019836 A CN201710019836 A CN 201710019836A CN 108301922 A CN108301922 A CN 108301922A
- Authority
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- China
- Prior art keywords
- gas turbine
- carbonate fuel
- fuel cell
- molten carbonate
- chamber
- Prior art date
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- Pending
Links
- 239000000446 fuel Substances 0.000 title claims abstract description 64
- BVKZGUZCCUSVTD-UHFFFAOYSA-L Carbonate Chemical compound [O-]C([O-])=O BVKZGUZCCUSVTD-UHFFFAOYSA-L 0.000 title claims abstract description 49
- 239000007789 gas Substances 0.000 claims abstract description 38
- 238000002485 combustion reaction Methods 0.000 claims abstract description 14
- UGFAIRIUMAVXCW-UHFFFAOYSA-N Carbon monoxide Chemical compound [O+]#[C-] UGFAIRIUMAVXCW-UHFFFAOYSA-N 0.000 claims abstract description 8
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000001301 oxygen Substances 0.000 claims abstract description 8
- 229910052760 oxygen Inorganic materials 0.000 claims abstract description 8
- 239000003546 flue gas Substances 0.000 claims abstract description 7
- 230000005611 electricity Effects 0.000 claims abstract description 6
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000010763 heavy fuel oil Substances 0.000 claims description 3
- 239000000567 combustion gas Substances 0.000 claims description 2
- 238000000926 separation method Methods 0.000 claims description 2
- 238000004781 supercooling Methods 0.000 claims 1
- 238000001816 cooling Methods 0.000 abstract 1
- 238000004134 energy conservation Methods 0.000 abstract 1
- 230000007613 environmental effect Effects 0.000 abstract 1
- 238000006243 chemical reaction Methods 0.000 description 7
- 239000012530 fluid Substances 0.000 description 6
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 4
- 239000000376 reactant Substances 0.000 description 4
- 238000007254 oxidation reaction Methods 0.000 description 3
- 230000008901 benefit Effects 0.000 description 2
- 239000003054 catalyst Substances 0.000 description 2
- 230000008859 change Effects 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000003792 electrolyte Substances 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- 238000002844 melting Methods 0.000 description 2
- 230000008018 melting Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 239000003345 natural gas Substances 0.000 description 2
- 238000005192 partition Methods 0.000 description 2
- 238000010248 power generation Methods 0.000 description 2
- 238000006722 reduction reaction Methods 0.000 description 2
- 230000004913 activation Effects 0.000 description 1
- 150000004649 carbonic acid derivatives Chemical class 0.000 description 1
- 238000005034 decoration Methods 0.000 description 1
- 238000003487 electrochemical reaction Methods 0.000 description 1
- 238000003411 electrode reaction Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 239000010416 ion conductor Substances 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 238000000034 method Methods 0.000 description 1
- 229910000510 noble metal Inorganic materials 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 230000008569 process Effects 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 230000036647 reaction Effects 0.000 description 1
- 238000011084 recovery Methods 0.000 description 1
- 238000004064 recycling Methods 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 230000008439 repair process Effects 0.000 description 1
- 239000000779 smoke Substances 0.000 description 1
- 125000006850 spacer group Chemical group 0.000 description 1
- 239000002699 waste material Substances 0.000 description 1
Classifications
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C3/00—Gas-turbine plants characterised by the use of combustion products as the working fluid
- F02C3/34—Gas-turbine plants characterised by the use of combustion products as the working fluid with recycling of part of the working fluid, i.e. semi-closed cycles with combustion products in the closed part of the cycle
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F02—COMBUSTION ENGINES; HOT-GAS OR COMBUSTION-PRODUCT ENGINE PLANTS
- F02C—GAS-TURBINE PLANTS; AIR INTAKES FOR JET-PROPULSION PLANTS; CONTROLLING FUEL SUPPLY IN AIR-BREATHING JET-PROPULSION PLANTS
- F02C6/00—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use
- F02C6/18—Plural gas-turbine plants; Combinations of gas-turbine plants with other apparatus; Adaptations of gas- turbine plants for special use using the waste heat of gas-turbine plants outside the plants themselves, e.g. gas-turbine power heat plants
-
- F—MECHANICAL ENGINEERING; LIGHTING; HEATING; WEAPONS; BLASTING
- F25—REFRIGERATION OR COOLING; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS; MANUFACTURE OR STORAGE OF ICE; LIQUEFACTION SOLIDIFICATION OF GASES
- F25B—REFRIGERATION MACHINES, PLANTS OR SYSTEMS; COMBINED HEATING AND REFRIGERATION SYSTEMS; HEAT PUMP SYSTEMS
- F25B29/00—Combined heating and refrigeration systems, e.g. operating alternately or simultaneously
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
- H01M8/00—Fuel cells; Manufacture thereof
- H01M8/14—Fuel cells with fused electrolytes
- H01M8/141—Fuel cells with fused electrolytes the anode and the cathode being gas-permeable electrodes or electrode layers
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02E—REDUCTION OF GREENHOUSE GAS [GHG] EMISSIONS, RELATED TO ENERGY GENERATION, TRANSMISSION OR DISTRIBUTION
- Y02E60/00—Enabling technologies; Technologies with a potential or indirect contribution to GHG emissions mitigation
- Y02E60/30—Hydrogen technology
- Y02E60/50—Fuel cells
Abstract
The present invention relates to the mixing energy supplying systems based on gas turbine and molten carbonate fuel cell, belong to distributing-supplying-energy system field.The system includes the components such as air separator, combustion chamber, gas turbine, VM circulating heat pumps.H2And O2It reacts and produces electricl energy in the anode of molten carbonate fuel cell, cathode respectively, meanwhile, the high-temperature gas that oxygen-enriched combusting generates in combustion chamber enters gas turbine expansion work, and makes electrical power generators;Gas turbine flue gas driving VM circulating heat pumps are recycled in winter to user's heat supply, and to provide domestic hot-water's load of user's whole year in summer to user's cooling.This mixing energy supplying system can not only ensure system electricity, the hot and cold demand with energy, but also have the characteristics that high generating efficiency, fuel selection diversity, energy conservation and environmental protection.
Description
Technical field
The invention belongs to distributing-supplying-energy system fields, more particularly to are based on gas turbine and molten carbonate fuel cell
Mixing energy supplying system.
Background technology
Molten carbonate fuel cell is a kind of using fused carbonate as the high-temperature fuel cell of oxygen ion conductor, usually quilt
Referred to as second generation fuel cell, operating temperature is in 973-923K or so.Compared with low-temperature fuel cell, in fused carbonate fuel
Under the operating temperature of battery, fuel (such as natural gas) can be converted directly in inside battery, not only reduce cost, but also improve
Efficiency;Secondly, the high-temperature residual heat of cell reaction can be used for industrial processes or boiler cycle;Finally, the CO that fuel conversion generates
Not but not electrode catalyst of fuel cell is made to be poisoned, the fuel of molten carbonate fuel cell can be become instead.
But there are one significant drawbacks for molten carbonate fuel cell, that is, need constantly to supply CO to cathode2.It is conventional
Way be the CO that anode is precipitated2It is re-delivered to cathode, but also increases the complexity of system structure.
Currently, be most common thermoelectric conversion device by natural gas driving gas turbine, but gas turbine is followed by Kano
Ring limits and combustible loss influences, and system generating efficiency is still to be improved.
Accordingly, it is considered to common thermoelectric conversion device is combined with molten carbonate fuel cell, it both can be fully sharp
With the raw material and product of molten carbonate fuel cell power generation process, the indoor oxygen-enriched combusting that burns is realized, and can utilize
CO in combustor product2Ensure the CO of fused carbonate fuel battery cathode2Content, and then improve the power generation effect of whole system
Rate and fuel availability.
At the same time, the exhaust gas temperature of gas turbine is up to 600 DEG C, and energy waste can be caused by directly draining, in order to this
Partial heat carries out cascade utilization, selects VM circulating heat pumps as cold and hot production equipment.
Invention content
In view of the above problems and phenomenon, the present invention is provided based on gas turbine and molten carbonate fuel cell
Mix energy supplying system, it is intended to meet the use energy demand of user by mixed distribution formula system, and recycling is carried out to after-heat,
Realize better cascaded utilization of energy pattern.
To achieve the goals above, the technical solution that the present invention takes is:
Mixing energy supplying system based on gas turbine and molten carbonate fuel cell, including:
Compressor:It is configured to compress air;
Air separator:It is configured to detach air;
Converter:It is configured to convert the fuel into the reactant needed for molten carbonate fuel cell;
Fused carbonate fuel battery anode:It is configured to that reduction reaction occurs;
Fused carbonate fuel battery cathode:It is configured to mode oxidation reaction;
Combustion chamber:Its residual fuel being configured in being vented fused carbonate fuel battery anode fires again, and carries out richness
Oxygen burns, and further increases combustor exhaust temperature;
Gas turbine:It is configured to the thermal energy of high-temperature gas being converted to mechanical energy;
Generator:It is configured to mechanical energy being changed into electric energy, produces required electric power;
VM circulating heat pumps:It is configured to the low-temperature heat source of steam being transferred to high temperature heat source, is freezed and is heated, and meets
User's energy demand;
Heat exchanger I:It is configured to the hot fluid heat transfer by the hot chamber of VM circulating heat pumps to cold fluid;
Heat exchanger II:It is configured to the hot fluid heat transfer by VM circulating heat pump room temperature chambers to cold fluid;
Heat exchanger III:It is configured to the cold fluid cold of the cold chamber of VM circulating heat pumps passing to hot fluid.
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the air
The product of separator is O2And N2Product.
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the conversion
The product of device is CO and H2.
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the melting
Reactant in carbonate fuel battery anode is H2And CO3 2-, product is H2O and CO2。
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the melting
Reactant in carbonate fuel battery cathode is O2And CO2, product is CO3 2-。
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the combustion gas
The flue gas part that turbine generates enters combustion chamber, and another part enters converter.
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the VM is followed
Ring heat pump supplies domestic hot-water's load by hot chamber, supplies user institute chilling requirement by cold chamber, heat is supplied by room temperature chamber.
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the heat exchange
Device I is connect with the hot chamber of VM circulating heat pumps, whole year operation.
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the heat exchange
Device II is connect with VM circulating heat pump room temperature chambers, winter operation, and summer stops transport.
The above-mentioned mixing energy supplying system based on gas turbine and molten carbonate fuel cell, wherein the heat exchange
Device III is connect with the cold chamber of VM circulating heat pumps, summer operation, and winter stops transport.
Above-mentioned technical proposal has the following advantages that or advantageous effect:
1, molten carbonate fuel cell operating temperature is high, electrode reaction activation energy is small, no matter hydrogen oxidation or oxygen
Reduction, does not all need noble metal and makees catalyst, reduce system cost of electricity-generating.
2, the CO that combustion chamber oxygen-enriched combusting obtains2Product is passed directly into fused carbonate fuel battery cathode as reactant
Reaction is participated in, had not only reduced oxycarbide discharge, but also ensure molten carbonate fuel cell continuous work.
3, after gas turbine smoke evacuation is passed through converter, combustion chamber carries out heat recovery, the work of VM circulating heat pumps is finally driven,
This flue gas utilization approach not only can guarantee energy demands at different levels, but also can be energy saving.
Description of the drawings
By reading with reference to attached drawing below to being described in detail made by non-limiting embodiment, of the invention and its feature,
Shape and advantage will become more apparent.Identical label indicates identical part in whole attached drawings.Not deliberately according to
Ratio draws attached drawing, it is preferred that emphasis is shows the purport of the present invention.
Mixing energy supplying system structural schematic diagrams of Fig. 1 based on gas turbine and molten carbonate fuel cell
Fig. 2 molten carbonate fuel cell fundamental diagrams
Each label meaning is as follows in figure:1- compressors;2- air separators;3- converters;4- fused carbonates fuel electricity
Pond anode;5- fused carbonate fuel battery cathodes;The combustion chambers 6-;7- gas turbines;8- generators;9-VM circulating heat pumps;10-
Heat exchanger I;11- heat exchangers II;12- heat exchangers III;
Specific implementation mode
The present invention is further illustrated in the following with reference to the drawings and specific embodiments, but not as the limit of the present invention
It is fixed.
The operation principle of VM circulating heat pumps refers to Chinese patent CN101865566A.
As shown in Figure 1, this system includes:Compressor 1, air separator 2, converter 3, molten carbonate fuel cell sun
Pole 4, fused carbonate fuel battery cathode 5, combustion chamber 6, gas turbine 7, generator 8, VM circulating heat pumps 9, heat exchanger I 10,
Heat exchanger II 11, heat exchanger III 12.Enter air separator 2 by 1 compressed air of compressor and carry out gas separation,
Obtain O2And N2Product, a part of O2Into fused carbonate fuel battery cathode 5, another part O2Into combustion chamber 6;Fuel
The H obtained after the conversion of converter 32Into fused carbonate fuel battery anode 4, with O2Electrochemical reaction occurs to be sent out
Electricity;Meanwhile fuel, CO, O2, the residual fuel in flue gas and anode exhaust mixed in combustion chamber 6, oxygen-enriched combusting is generated
High-temperature flue gas is sent into 7 expansion work of gas turbine, and generator 8 is made to generate electricity;Recycle the flue gas driving VM cycles of gas turbine 7
Heat pump 9, winter are heated by heat exchanger II 11 to user, and summer absorbs heat system by heat exchanger III 12 from the external world
Cold, heat exchanger I 10 then supplies annual domestic hot-water.
Molten carbonate fuel cell operation principle is introduced with reference to Fig. 2.
In Fig. 2, the structure of molten carbonate fuel cell includes mainly upper spacer, lower clapboard, fused carbonate fuel electricity
Pond anode 4, fused carbonate fuel battery cathode 5 and electrolyte panel.O2And CO2Oxidation reaction generation is carried out in cathode and electronics
CO3 2-, the CO in electrolyte panel3 2-Directly from movable cathode to anode;H in fuel2With CO3 2-It reacts generation in anode
CO2、H2O and electronics, electronics reach partition board after being collected by collector plate;Finally, it is connected with load equipment composition by upper and lower partition board
Complete circuit including electron-transport and ion movement.
It should be appreciated by those skilled in the art that those skilled in the art combine the prior art and above-described embodiment can be real
The existing change case, it will not be described here.Such change case does not affect the essence of the present invention, and it will not be described here.
Presently preferred embodiments of the present invention is described above.It is to be appreciated that the invention is not limited in above-mentioned
Particular implementation, wherein the equipment and structure be not described in detail to the greatest extent are construed as giving reality with the common mode in this field
It applies;Any technical person familiar with the field makes many possible changes and modifications not departing from technical solution of the present invention, or
It is revised as the equivalent embodiment of equivalent variations, this is not affected the essence of the present invention.Therefore, every without departing from skill of the present invention
The content of art scheme, according to the technical essence of the invention any simple modification made to the above embodiment, equivalent variations and repair
Decorations, still fall within technical solution of the present invention protection in the range of.
Claims (3)
1. the mixing energy supplying system based on gas turbine and molten carbonate fuel cell, it is characterised in that:It include compressor,
Air separator, converter, fused carbonate fuel battery anode, fused carbonate fuel battery cathode, combustion chamber, combustion gas wheel
Machine, generator, VM circulating heat pumps, heat exchanger I, heat exchanger II, heat exchanger III;The VM circulating heat pumps include hot chamber, room temperature
Chamber, cold chamber;
Enter air separator by the compressed air of compressor and carry out gas separation, obtains O2And N2Product, a part of O2Into
Enter cathode, another part O2Into combustion chamber;Fuel obtains H by converter2, H2Into anode and O2It reacts
Electricity;Meanwhile fuel, O2, the residual fuel in flue gas and anode exhaust be mixed and burned in combustion chamber, the high-temperature gas of generation into
Enter gas turbine expansion work, and makes electrical power generators;Meanwhile driving VM circulating heat pumps, summer logical using gas turbine flue gas
Supercooling chamber absorbs heat from the external world and freezes, and winter is heated by room temperature chamber to user, the hot annual domestic hot-water of chamber supply.
2. the mixing energy supplying system based on gas turbine and molten carbonate fuel cell as described in claim 1, feature
It is, the driving heat source temperature of the VM circulating heat pumps is in the range of 800-900K.
3. the mixing energy supplying system based on gas turbine and molten carbonate fuel cell as described in claim 1, feature
It is, the O of oxygen-enriched combusting in the combustion chamber2Concentration controls between 27-39%.
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710019836.XA CN108301922A (en) | 2017-01-12 | 2017-01-12 | Mixing energy supplying system based on gas turbine and molten carbonate fuel cell |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
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CN201710019836.XA CN108301922A (en) | 2017-01-12 | 2017-01-12 | Mixing energy supplying system based on gas turbine and molten carbonate fuel cell |
Publications (1)
Publication Number | Publication Date |
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CN108301922A true CN108301922A (en) | 2018-07-20 |
Family
ID=62871975
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CN201710019836.XA Pending CN108301922A (en) | 2017-01-12 | 2017-01-12 | Mixing energy supplying system based on gas turbine and molten carbonate fuel cell |
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Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109252959A (en) * | 2018-09-27 | 2019-01-22 | 武汉理工大学 | Solid oxide fuel cell peculiar to vessel and steam-injected gas turbine combined generating system and method |
CN109779694A (en) * | 2019-01-15 | 2019-05-21 | 东北大学 | Utilize the iron and steel enterprise's distributed energy resource system and working method of blast furnace gas |
CN110410289A (en) * | 2019-07-24 | 2019-11-05 | 中国科学院电工研究所 | Utilize the SOFC-GT combined generating system of solar-heating and high temperature heat chemistry heat accumulation |
CN111029626A (en) * | 2019-12-18 | 2020-04-17 | 中国华能集团清洁能源技术研究院有限公司 | Molten carbonate fuel cell test model using hydrogen as raw material and design method |
WO2021120812A1 (en) * | 2019-12-18 | 2021-06-24 | 中国华能集团清洁能源技术研究院有限公司 | Molten carbonate fuel cell test model using natural gas as raw material, and design method therefor |
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Cited By (6)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109252959A (en) * | 2018-09-27 | 2019-01-22 | 武汉理工大学 | Solid oxide fuel cell peculiar to vessel and steam-injected gas turbine combined generating system and method |
CN109779694A (en) * | 2019-01-15 | 2019-05-21 | 东北大学 | Utilize the iron and steel enterprise's distributed energy resource system and working method of blast furnace gas |
CN109779694B (en) * | 2019-01-15 | 2021-05-28 | 东北大学 | Iron and steel enterprise distributed energy system using blast furnace gas and working method |
CN110410289A (en) * | 2019-07-24 | 2019-11-05 | 中国科学院电工研究所 | Utilize the SOFC-GT combined generating system of solar-heating and high temperature heat chemistry heat accumulation |
CN111029626A (en) * | 2019-12-18 | 2020-04-17 | 中国华能集团清洁能源技术研究院有限公司 | Molten carbonate fuel cell test model using hydrogen as raw material and design method |
WO2021120812A1 (en) * | 2019-12-18 | 2021-06-24 | 中国华能集团清洁能源技术研究院有限公司 | Molten carbonate fuel cell test model using natural gas as raw material, and design method therefor |
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