CN108300210A - A kind of novel anti-anti-aging preparation method for coating of corruption - Google Patents

A kind of novel anti-anti-aging preparation method for coating of corruption Download PDF

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Publication number
CN108300210A
CN108300210A CN201710918223.XA CN201710918223A CN108300210A CN 108300210 A CN108300210 A CN 108300210A CN 201710918223 A CN201710918223 A CN 201710918223A CN 108300210 A CN108300210 A CN 108300210A
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China
Prior art keywords
parts
temperature
coating
corruption
preservative
Prior art date
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Withdrawn
Application number
CN201710918223.XA
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Chinese (zh)
Inventor
吴江
陈秀兰
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Zhenjiang Ze Lin Lin Building Materials Co Ltd
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Zhenjiang Ze Lin Lin Building Materials Co Ltd
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Priority to CN201710918223.XA priority Critical patent/CN108300210A/en
Publication of CN108300210A publication Critical patent/CN108300210A/en
Withdrawn legal-status Critical Current

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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D167/00Coating compositions based on polyesters obtained by reactions forming a carboxylic ester link in the main chain; Coating compositions based on derivatives of such polymers
    • C09D167/08Polyesters modified with higher fatty oils or their acids, or with natural resins or resin acids
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Wood Science & Technology (AREA)
  • Organic Chemistry (AREA)
  • Oil, Petroleum & Natural Gas (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Paints Or Removers (AREA)
  • Compositions Of Macromolecular Compounds (AREA)

Abstract

The novel anti-anti-aging preparation method for coating of corruption of one kind provided by the invention includes following components, 50 70 parts of vinyltoluene alkyd resin by weight, 5 15 parts of titanium dioxide, 20 30 parts of epoxy resin, 8 12 parts of oyster shell whiting, 39 parts of bentonite, 35 parts of levelling agent, 13 parts of curing agent, 24 parts of preservative, 58 parts of organic solvent, composition is simple, configuration is convenient, and cost is relatively low, non-hazardous, strong adsorption is not easy the embrittlement that turns to be yellow, and effectively extends its service life, can more meet the needs of producer.

Description

A kind of novel anti-anti-aging preparation method for coating of corruption
Technical field
The present invention relates to technical field of coatings, more particularly to a kind of novel anti-anti-aging preparation method for coating of corruption.
Background technology
Coating, in the entitled paint of Chinese tradition.So-called coating be coated in the body surface being protected or decorated, and The continuous film of firm attachment can be formed with coated article, typically based on resin or oil or lotion, add or do not add face Material, filler add corresponding additive, the thick liquid being formulated with organic solvent or water.However existing coating is used for a long time After can turn to be yellow embrittlement, the phenomenon that generation falls off, it is readily volatilized go out toxic gas, there is security risk, can not meet user's It needs.
Invention content
The object of the present invention is to provide a kind of novel anti-anti-aging preparation method for coating of corruption, and solve existing coating makes for a long time Can turn to be yellow embrittlement after, generation the phenomenon that falling off, it is readily volatilized go out toxic gas, there is security risk, can not meet user The problem of needs.
The purpose of the present invention can be achieved through the following technical solutions;
A kind of novel anti-anti-aging preparation method for coating of corruption, preparation method are as follows:
(1)Following components, 50-70 parts of vinyltoluene alkyd resin, 5-15 parts of titanium dioxide, asphalt mixtures modified by epoxy resin are weighed by weight 20-30 parts of fat, 8-12 parts of oyster shell whiting, 3-9 parts of bentonite, 3-5 parts of levelling agent, 1-3 parts of curing agent, 2-4 parts of preservative, You Jirong 5-8 parts of agent;
(2)Polyacrylic acid, carboxymethyl cellulose are put into reaction kettle, temperature is 25 DEG C -35 DEG C, and uniform stirring 7-15min is obtained To levelling agent;
(3)Benzoic acid and sodium benzoate are put into reaction kettle, temperature is 35 DEG C -55 DEG C, and uniform stirring 10-20min is obtained into Preservative;
(4)Toluene and dimethylbenzene are put into reaction kettle, temperature is 20 DEG C -40 DEG C, uniform stirring 15-30min, is obtained organic molten Agent;
(5)Vinyltoluene alkyd resin and titanium dioxide are entered in reaction kettle, 10-20min is stirred, temperature is 35 DEG C -40 DEG C;When After temperature is promoted to 45 DEG C -55 DEG C, it is separately added into epoxy resin and oyster shell whiting, continues to stir 5-15min, when temperature is promoted to 60 After DEG C -70 DEG C, bentonite, levelling agent and preservative is added, continues to stir 10-30min, when temperature is promoted to 80 DEG C -100 DEG C Afterwards, organic solvent and curing agent is added, stirs 20-30min.
The above-mentioned novel anti-anti-aging preparation method for coating of corruption of one kind, wherein the levelling agent is polyacrylic acid, carboxylic first Base cellulose mixes together, weight fraction ratio 3:2.
The above-mentioned novel anti-anti-aging preparation method for coating of corruption of one kind, wherein the curing agent is amine curing agent.
The above-mentioned novel anti-anti-aging preparation method for coating of corruption of one kind, wherein the preservative is benzoic acid and benzene first Sour sodium mixes together, weight fraction ratio 2:1.
The above-mentioned novel anti-anti-aging preparation method for coating of corruption of one kind, wherein the organic solvent is toluene and diformazan Benzene mixes together, weight fraction ratio 1:5.
The advantageous effect of this programme:
The novel anti-anti-aging preparation method for coating of corruption of one kind provided by the invention, composition is simple, and configuration is convenient, and cost is relatively low, nothing Harm, strong adsorption are not easy the embrittlement that turns to be yellow, effectively extend its service life, can more meet the needs of producer.
Specific implementation mode
Embodiment 1:A kind of novel anti-anti-aging preparation method for coating of corruption, preparation method are as follows:
(1)Following components, 70 parts of vinyltoluene alkyd resin, 15 parts of titanium dioxide, epoxy resin 30 are weighed by weight Part, 12 parts of oyster shell whiting, 9 parts of bentonite, 5 parts of levelling agent, 3 parts of curing agent, 4 parts of preservative, 8 parts of organic solvent;
(2)Polyacrylic acid, carboxymethyl cellulose are put into reaction kettle, temperature is 25 DEG C, and uniform stirring 7min obtains levelling Agent;
(3)Benzoic acid and sodium benzoate are put into reaction kettle, temperature is 35 DEG C, and uniform stirring 10min obtains into preservative;
(4)Toluene and dimethylbenzene are put into reaction kettle, temperature is 40 DEG C, and uniform stirring 15min obtains organic solvent;
(5)Vinyltoluene alkyd resin and titanium dioxide are entered in reaction kettle, 10min is stirred, temperature is 35 DEG C;When temperature is promoted To after 45 DEG C, it is separately added into epoxy resin and oyster shell whiting, continues to stir 5min, after temperature is promoted to 60 DEG C, addition bentonite, Levelling agent and preservative continue to stir 10min, and after temperature is promoted to 80 DEG C, organic solvent and curing agent, stirring is added 20min.
Embodiment 2:A kind of novel anti-anti-aging preparation method for coating of corruption, preparation method are as follows:
(1)Following components, 60 parts of vinyltoluene alkyd resin, 10 parts of titanium dioxide, epoxy resin 25 are weighed by weight Part, 10 parts of oyster shell whiting, 6 parts of bentonite, 4 parts of levelling agent, 2 parts of curing agent, 3 parts of preservative, 6 parts of organic solvent;
(2)Polyacrylic acid, carboxymethyl cellulose are put into reaction kettle, temperature is 30 DEG C, and uniform stirring 10min obtains levelling Agent;
(3)Benzoic acid and sodium benzoate are put into reaction kettle, temperature is 40 DEG C, and uniform stirring 15min obtains into preservative;
(4)Toluene and dimethylbenzene are put into reaction kettle, temperature is 30 DEG C, and uniform stirring 25min obtains organic solvent;
(5)Vinyltoluene alkyd resin and titanium dioxide are entered in reaction kettle, 15min is stirred, temperature is 37 DEG C;When temperature is promoted To after 40 DEG C, it is separately added into epoxy resin and oyster shell whiting, continues to stir 10min, after temperature is promoted to 65 DEG C, swelling is added Soil, levelling agent and preservative continue to stir 20min, and after temperature is promoted to 90 DEG C, organic solvent and curing agent, stirring is added 25min.
Embodiment 3:A kind of novel anti-anti-aging preparation method for coating of corruption, preparation method are as follows:
(1)Following components, 70 parts of vinyltoluene alkyd resin, 15 parts of titanium dioxide, epoxy resin 30 are weighed by weight Part, 12 parts of oyster shell whiting, 9 parts of bentonite, 5 parts of levelling agent, 3 parts of curing agent, 4 parts of preservative, 8 parts of organic solvent;
(2)Polyacrylic acid, carboxymethyl cellulose are put into reaction kettle, temperature is 35 DEG C, and uniform stirring 15min obtains levelling Agent;
(3)Benzoic acid and sodium benzoate are put into reaction kettle, temperature is 55 DEG C, and uniform stirring 20min obtains into preservative;
(4)Toluene and dimethylbenzene are put into reaction kettle, temperature is 40 DEG C, and uniform stirring 30min obtains organic solvent;
(5)Vinyltoluene alkyd resin and titanium dioxide are entered in reaction kettle, 20min is stirred, temperature is 40 DEG C;When temperature is promoted To after 55 DEG C, it is separately added into epoxy resin and oyster shell whiting, continues to stir 15min, after temperature is promoted to 70 DEG C, swelling is added Soil, levelling agent and preservative continue to stir 30min, and after temperature is promoted to 100 DEG C, organic solvent and curing agent, stirring is added 30min.
The novel anti-anti-aging preparation method for coating of corruption of one kind provided by the invention, composition is simple, and configuration is convenient, cost compared with Low, non-hazardous, strong adsorption is not easy the embrittlement that turns to be yellow, and effectively extends its service life, can more meet the needs of producer.
The foregoing is only a preferred embodiment of the present invention, but scope of protection of the present invention is not limited thereto, Any one skilled in the art in the technical scope disclosed by the present invention, the change or replacement that can be readily occurred in, Should all it cover within the scope of the present invention.Therefore, protection scope of the present invention should be with the protection domain of claims Subject to.

Claims (5)

1. a kind of novel anti-anti-aging preparation method for coating of corruption, it is characterized in that, preparation method is as follows:
(1)Following components, 50-70 parts of vinyltoluene alkyd resin, 5-15 parts of titanium dioxide, asphalt mixtures modified by epoxy resin are weighed by weight 20-30 parts of fat, 8-12 parts of oyster shell whiting, 3-9 parts of bentonite, 3-5 parts of levelling agent, 1-3 parts of curing agent, 2-4 parts of preservative, You Jirong 5-8 parts of agent;
(2)Polyacrylic acid, carboxymethyl cellulose are put into reaction kettle, temperature is 25 DEG C -35 DEG C, and uniform stirring 7-15min is obtained To levelling agent;
(3)Benzoic acid and sodium benzoate are put into reaction kettle, temperature is 35 DEG C -55 DEG C, and uniform stirring 10-20min is obtained into Preservative;
(4)Toluene and dimethylbenzene are put into reaction kettle, temperature is 20 DEG C -40 DEG C, uniform stirring 15-30min, is obtained organic molten Agent;
(5)Vinyltoluene alkyd resin and titanium dioxide are entered in reaction kettle, 10-20min is stirred, temperature is 35 DEG C -40 DEG C;When After temperature is promoted to 45 DEG C -55 DEG C, it is separately added into epoxy resin and oyster shell whiting, continues to stir 5-15min, when temperature is promoted to 60 After DEG C -70 DEG C, bentonite, levelling agent and preservative is added, continues to stir 10-30min, when temperature is promoted to 80 DEG C -100 DEG C Afterwards, organic solvent and curing agent is added, stirs 20-30min.
2. a kind of novel anti-anti-aging preparation method for coating of corruption as described in claim 1, it is characterized in that, the levelling agent is Polyacrylic acid, carboxymethyl cellulose mix together, weight fraction ratio 3:2.
3. a kind of novel anti-anti-aging preparation method for coating of corruption as described in claim 1, it is characterized in that, the curing agent is Amine curing agent.
4. a kind of novel anti-anti-aging preparation method for coating of corruption as described in claim 1, it is characterized in that, the preservative is Benzoic acid is mixed together with sodium benzoate, weight fraction ratio 2:1.
5. a kind of novel anti-anti-aging preparation method for coating of corruption as described in claim 1, it is characterized in that, the organic solvent It is mixed together for toluene and dimethylbenzene, weight fraction ratio 1:5.
CN201710918223.XA 2017-09-30 2017-09-30 A kind of novel anti-anti-aging preparation method for coating of corruption Withdrawn CN108300210A (en)

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Application Number Priority Date Filing Date Title
CN201710918223.XA CN108300210A (en) 2017-09-30 2017-09-30 A kind of novel anti-anti-aging preparation method for coating of corruption

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Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449283A (en) * 2014-11-14 2015-03-25 无锡中洁能源技术有限公司 Anti-aging coating and preparation method thereof
CN106046999A (en) * 2016-07-20 2016-10-26 芜湖昊轩环保新材料有限公司 Nano modified anti-aging coating and preparation method thereof
CN106519839A (en) * 2016-10-31 2017-03-22 程志鹏 Mechanical anti-aging coating and preparation method thereof
CN106752791A (en) * 2016-11-30 2017-05-31 江苏经纬技术创新咨询有限公司 A kind of anti-aging coating and preparation method thereof

Patent Citations (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104449283A (en) * 2014-11-14 2015-03-25 无锡中洁能源技术有限公司 Anti-aging coating and preparation method thereof
CN106046999A (en) * 2016-07-20 2016-10-26 芜湖昊轩环保新材料有限公司 Nano modified anti-aging coating and preparation method thereof
CN106519839A (en) * 2016-10-31 2017-03-22 程志鹏 Mechanical anti-aging coating and preparation method thereof
CN106752791A (en) * 2016-11-30 2017-05-31 江苏经纬技术创新咨询有限公司 A kind of anti-aging coating and preparation method thereof

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Application publication date: 20180720