CN108299942A - A kind of UV solidification plate glass ink and preparation method thereof - Google Patents
A kind of UV solidification plate glass ink and preparation method thereof Download PDFInfo
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- CN108299942A CN108299942A CN201711494604.6A CN201711494604A CN108299942A CN 108299942 A CN108299942 A CN 108299942A CN 201711494604 A CN201711494604 A CN 201711494604A CN 108299942 A CN108299942 A CN 108299942A
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- plate glass
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/03—Printing inks characterised by features other than the chemical nature of the binder
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/101—Inks specially adapted for printing processes involving curing by wave energy or particle radiation, e.g. with UV-curing following the printing
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D11/00—Inks
- C09D11/02—Printing inks
- C09D11/10—Printing inks based on artificial resins
- C09D11/106—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C09D11/107—Printing inks based on artificial resins containing macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds from unsaturated acids or derivatives thereof
Abstract
The invention discloses a kind of UV to cure plate glass ink and preparation method thereof.It is mainly made of the component of following parts by weight：30~85 parts of silicone modified polyacrylate, 20~30 parts of acrylic resin, 5~25 parts of poly(ethylene glycol) methacrylate, aluminate coupling agent modified Nano SiO210~25 parts, 5~10 parts of nano-graphene, 5~30 parts of lauryl acrylate, 2~15 parts of photoinitiator, 0~30 part of pigment, 0.5~5 part of surfactant, 0~2 part of levelling agent.UV provided by the present invention cures plate glass ink, passes through each component, especially silicone modified polyacrylate, acrylic resin, poly(ethylene glycol) methacrylate, aluminate coupling agent modified Nano SiO2, nano-graphene, the mutual synergistic effect between the components such as lauryl acrylate, can make ink that there is high adhesion force, high scratch resistance and wearability, meet the requirements of artistic carving.
Description
Technical field
The invention belongs to ink areas, and in particular to a kind of UV solidification plate glass ink and preparation method thereof.
Background technology
Plate glass ink is exactly the ink that can carry out printing simultaneously energy firm attachment on glass.It can by processing temperature
It is divided into high temp glass ink, glass decoration firing ink, low temperature glass ink and simple glass ink etc..It can be divided into oil by membrane solvent is adjusted
Property glass ink, waterborne glass ink.It can be divided into flint glass ink and crown glass ink etc. by environmental protection standard.It is removed on glass
Have outside smooth flat, can also
It is carved with word or pattern, decorative pattern etc., as ornament, this glass generally scribes glass using etchant to corrode
Glass.As etchant, hydrofluoric acid is used for a long time.As engraving method, then be by glass to be etched, clean dry it is flat
It sets, coating thereon uses the paraffin liquid that gasoline dissolves as protective layer, and required text is carved out on the paraffin layer after solidification
Word or pattern.When engraving, it is necessary to carve paraffin layer, glass is made to expose.Then, hydrofluoric acid is dripped in the word or figure that expose glass
In case.According to the depth of required decorative pattern, the control corrosion rate time washes away paraffin and hydrofluoric acid after a predetermined time, with warm water,
It can be prepared by the glass with beautiful decorative pattern.
Due to having various words or pattern etc., UV solidification plate glass ink just to need to make oil on engraved glass
Ink reaches requirement in terms of adhesive force, scratch resistance and wearability simultaneously, and existing plate glass ink is difficult to while up to standard.
Invention content
The purpose of the present invention is on the basis of existing technology, provide a kind of UV solidification plate glass ink and its preparation side
Method.
The purpose of the present invention can be achieved by the following measures：
A kind of UV solidifications plate glass ink, it is mainly made of the component of following parts by weight：Organosilicon-modified acrylate
30~85 parts of polymer, 20~30 parts of acrylic resin, 5~25 parts of poly(ethylene glycol) methacrylate, aluminate coupling agent
Modified Nano SiO210~25 parts, 5~10 parts of nano-graphene, 5~30 parts of lauryl acrylate, 2~15 parts of photoinitiator,
0~30 part of pigment, 0.5~5 part of surfactant, 0~2 part of levelling agent.
The UV solidification plate glass ink of the present invention can only be made of said components, also can be on the basis of said components
Increasing other not influences the other components of this face oil main performance.
In a kind of preferred embodiment, UV solidification plate glass ink is mainly made of the component of following parts by weight：It is organic
35~80 parts of fluorine-silicon modified acrylic ester polymer, 20~30 parts of acrylic resin, poly(ethylene glycol) methacrylate 5~20
Part, aluminate coupling agent modified Nano SiO210~20 parts, 5~10 parts of nano-graphene, 5~20 parts of lauryl acrylate, light
2~15 parts of initiator, 0~30 part of pigment, 0.5~5 part of surfactant, 0.5~2 part of levelling agent.
In another preferred embodiment, UV solidification plate glass ink is mainly made of the component of following parts by weight：Have
40~70 parts of machine fluorine-silicon modified acrylic ester polymer, 20~25 parts of acrylic resin, poly(ethylene glycol) methacrylate 5~15
Part, aluminate coupling agent modified Nano SiO210~20 parts, 5~10 parts of nano-graphene, 5~15 parts of lauryl acrylate, light
2~10 parts of initiator, 5~20 parts of pigment, 0.5~5 part of surfactant, 0.5~2 part of levelling agent.
The silicone modified polyacrylate of the present invention is selected from the new four seas chemical industry SH-024 in Hubei, the honest coating in Tongxiang
5598, towards space chemical industry SKA001, SKA004, Suzhou Jiaxiang resin, which is contained, praises H-100, Shenzhen Ji roc fluosilicic material JP-R03 in Shanghai,
Shenzhen gold wins one or more of bright science and technology JBS-S166.
The present invention acrylic resin be selected from Shanghai weathercock chemistry FB9840, FB9805, Mitsubishi chemical industry BR-113,
BR-116, Dutch DSM B-735, one or more of Foshan Tai Chang resins TCA-6026A-12, TCN-116-80-1.
The degree of polymerization >=600 of the poly(ethylene glycol) methacrylate of the present invention, one kind in preferably 600/800/2000
Or it is several.
The present invention photoinitiator be selected from Changxing chemistry PI-184, PI-BDK, RAHN companies of Switzerland GENOCURE BDMM,
Chemical MV5006 is helped on GENOCURE CQ, middle mountain thousand（TPO）、MV5007（819)、MV5009（784）One or more of.
The pigment of the present invention is selected from Tianjin guide's pigment V7412C（C.I. P.Y.74）, Taiwan KCR pigment Red 5481,
Belgian Ka Peile pigment（Cappelle) PTM 0154N phthalocyanine blues, the graceful chemical industry TR52 titanium dioxides of Hensel, one new material of Hangzhou monarch
One or more of JY-227, JY-251 carbon black.
The surfactant of the present invention is preferably selected from Shanghai Chinese catalpa meaning chemical industry ZY-261, the high Tego Glide 432 of enlightening, Glide
435,2300 Rad, one or more of Bi Ke chemistry BYK-377, BYK-UV 3500.
The levelling agent of the present invention is selected from fowler that（Fuller) auxiliary agent GLK-364L, GLK-366, Ai Jian cover Omnivad
1116, Bi Ke chemistry BYK-307, BYK-345, one or more of Dongguan sky brightness chemical industry KP-826..
The present invention a kind of UV solidification plate glass ink preparation method be：First organosilicon-modified acrylate is polymerize
After object, acrylic resin and the mixing of poly(ethylene glycol) methacrylate, high-speed stirred is evenly dispersed, and it is even that Aluminate is then added
Join agent modified Nano SiO2, nano-graphene, lauryl acrylate, photoinitiator, pigment, surfactant and levelling agent, after
It is continuous to carry out stirring at low speed dispersion, it reuses three-roller and is repeatedly ground, obtain fineness in 7.5 μm of face oil below.
In preparation method, it is preferred that the speed of high-speed stirred is 800~1000 revs/min, and the speed of stirring at low speed is
400~750 revs/min.
UV provided by the present invention cures plate glass ink, passes through each component, especially organosilicon-modified acrylate
Polymer, acrylic resin, poly(ethylene glycol) methacrylate, aluminate coupling agent modified Nano SiO2, nano-graphene,
Mutual synergistic effect between the components such as lauryl acrylate can make ink have high adhesion force, high scratch resistance and wear-resisting
Property, meet the requirements of artistic carving.
Specific implementation mode
The solution of the present invention is described further with reference to embodiments, but the scope of the invention is not limited to following
Each embodiment.
The weight and performance of the raw material of Examples 1 to 3 and comparative example are as shown in table 1.
Table 1
The weight and performance of the raw material of comparative example 1~3 are as shown in table 2.
Table 2
The preparation method of each embodiment：First by silicone modified polyacrylate, acrylic resin and poly(ethylene glycol) first
After base crylic acid ester mixture, dispersion is stirred evenly with 800~1000 revs/min of rotating speeds, aluminate coupling agent modification is then added and receives
Rice SiO2, nano-graphene, lauryl ester initiators, pigment, surfactant and levelling agent, continue 400~
600 revs/min of stirring at low speed dispersions, reuse three-roller and are repeatedly ground, obtain fineness in 7.5 μm of ink below.
The preparation method of each comparative example is similar with embodiment.
The test method of the present invention is as follows：
Adhesive force：3M adhesive tapes, the test of hundred lattice, GB/T 9286-1998.
Scratch resistance：Ink is printed on glass slide and fully cures drying, using QHQ shaking pencil hardometers,
Hardness is the pencil of H, load 175g power, the scratch resistance of test ink coating surface.
Wearability：Ink is printed on glass slide and fully cures drying, is tested using multifunctional alcohol rubber friction
Machine（Model：LX-5600, Dongguan Li Xin instrument and equipments factory）Test, load 500g.
The representation method of adhesive force, scratch resistance, wearability：1 is worst, and 5 be optimal.
Claims (10)
1. a kind of UV cures plate glass ink, it is characterised in that it is mainly made of the component of following parts by weight：
30~85 parts of silicone modified polyacrylate, 20~30 parts of acrylic resin, poly(ethylene glycol) methacrylic acid
5~25 parts of ester, aluminate coupling agent modified Nano SiO210~25 parts, 5~10 parts of nano-graphene, lauryl acrylate 5~
30 parts, 2~15 parts of photoinitiator, 0~30 part of pigment, 0.5~5 part of surfactant, 0~2 part of levelling agent.
2. UV according to claim 1 cures plate glass ink, it is characterised in that it is mainly by following parts by weight
Component is made：35~80 parts of silicone modified polyacrylate, 20~30 parts of acrylic resin, poly(ethylene glycol) methyl-prop
5~20 parts of olefin(e) acid ester, aluminate coupling agent modified Nano SiO210~20 parts, 5~10 parts of nano-graphene, lauryl
5~20 parts of ester, 2~15 parts of photoinitiator, 0~30 part of pigment, 0.5~5 part of surfactant, 0.5~2 part of levelling agent.
3. UV according to claim 2 cures plate glass ink, it is characterised in that it is mainly by following parts by weight
Component is made：40~70 parts of silicone modified polyacrylate, 20~25 parts of acrylic resin, poly(ethylene glycol) methyl-prop
5~15 parts of olefin(e) acid ester, aluminate coupling agent modified Nano SiO210~20 parts, 5~10 parts of nano-graphene, lauryl
5~15 parts of ester, 2~10 parts of photoinitiator, 5~20 parts of pigment, 0.5~5 part of surfactant, 0.5~2 part of levelling agent.
4. UV according to claim 1 cures plate glass ink, it is characterised in that the organosilicon-modified acrylate
Polymer is selected from the new four seas chemical industry SH-024 in Hubei, the honest coating 5598 in Tongxiang, and Shanghai is revived towards space chemical industry SKA001, SKA004
State Jiaxiang resin, which is contained, praises H-100, Shenzhen Ji roc fluosilicic material JP-R03, and Shenzhen gold wins one kind or several in bright science and technology JBS-S166
Kind.
5. UV according to claim 1 cures plate glass ink, it is characterised in that the acrylic resin is selected from Shanghai
Weathercock chemistry FB9840, FB9805, Mitsubishi chemical industry BR-113, BR-116, Dutch DSM B-735, Foshan Tai Chang resins
One or more of TCA-6026A-12, TCN-116-80-1.
6. UV according to claim 1 cures plate glass ink, it is characterised in that the poly(ethylene glycol) metering system
The degree of polymerization >=600 of acid esters, preferably one or more of 600/800/2000.
7. UV according to claim 1 cures plate glass ink, it is characterised in that the photoinitiator is selected from long Xinghua
PI-184, PI-BDK are learned, RAHN companies of Switzerland GENOCURE BDMM, GENOCURE CQ, chemical MV5006 is helped on middle mountain thousand
（TPO）、MV5007（819)、MV5009（784）One or more of；The pigment is selected from Tianjin guide pigment V7412C, platform
Gulf KCR pigment Red 5481, Belgian Ka Peile pigment PTM 0154N phthalocyanine blues, the graceful chemical industry TR52 titanium dioxides of Hensel, Hangzhou monarch
One or more of one new material JY-227, JY-251 carbon black.
8. UV according to claim 1 cures plate glass ink, it is characterised in that the surfactant is selected from Shanghai
Anticipate chemical industry ZY-261, the high Tego Glide 432 of enlightening, Glide 435, Rad 2300 for Chinese catalpa, Bi Ke chemistry BYK-377, BYK-UV
One or more of 3500；The levelling agent is selected from fowler that（Fuller) auxiliary agent GLK-364L, GLK-366, Ai Jianmeng
Omnivad 1116, Bi Ke chemistry BYK-307, BYK-345, one or more of Dongguan sky brightness chemical industry KP-826.
9. the preparation method of UV solidifications plate glass ink described in claim 1, it is characterised in that first by organic-silicon-modified third
After olefine acid ester polymer, acrylic resin and the mixing of poly(ethylene glycol) methacrylate, high-speed stirred is evenly dispersed, then adds
Enter aluminate coupling agent modified Nano SiO2, nano-graphene, lauryl acrylate, photoinitiator, pigment, surfactant and
Levelling agent continues stirring at low speed dispersion, reuses three-roller and repeatedly ground, obtain fineness in 7.5 μm of faces below
Oil.
10. the preparation method of UV solidifications plate glass ink according to claim 9, it is characterised in that the high-speed stirred
Speed be 800~1000 revs/min, the speed of the stirring at low speed is 400~750 revs/min.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711494604.6A CN108299942A (en) | 2017-12-31 | 2017-12-31 | A kind of UV solidification plate glass ink and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201711494604.6A CN108299942A (en) | 2017-12-31 | 2017-12-31 | A kind of UV solidification plate glass ink and preparation method thereof |
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| CN108299942A true CN108299942A (en) | 2018-07-20 |
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| CN201711494604.6A Withdrawn CN108299942A (en) | 2017-12-31 | 2017-12-31 | A kind of UV solidification plate glass ink and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110698911A (en) * | 2019-11-24 | 2020-01-17 | 邵美忠 | Double-curing glass printing ink and preparation method thereof |
-
2017
- 2017-12-31 CN CN201711494604.6A patent/CN108299942A/en not_active Withdrawn
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110698911A (en) * | 2019-11-24 | 2020-01-17 | 邵美忠 | Double-curing glass printing ink and preparation method thereof |
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| WW01 | Invention patent application withdrawn after publication |
Application publication date: 20180720 |
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| WW01 | Invention patent application withdrawn after publication |