CN108299875A - Inorganic insulating paste and preparation method thereof - Google Patents
Inorganic insulating paste and preparation method thereof Download PDFInfo
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- CN108299875A CN108299875A CN201710749837.XA CN201710749837A CN108299875A CN 108299875 A CN108299875 A CN 108299875A CN 201710749837 A CN201710749837 A CN 201710749837A CN 108299875 A CN108299875 A CN 108299875A
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- weight
- resin
- inorganic insulating
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- insulating paste
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- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D125/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Coating compositions based on derivatives of such polymers
- C09D125/02—Homopolymers or copolymers of hydrocarbons
- C09D125/04—Homopolymers or copolymers of styrene
- C09D125/08—Copolymers of styrene
- C09D125/14—Copolymers of styrene with unsaturated esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D133/00—Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
- C09D133/04—Homopolymers or copolymers of esters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D163/00—Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
- C08K3/36—Silica
Abstract
The invention discloses a kind of inorganic insulating pastes and preparation method thereof, and the inorganic thermal insulation is by including following component:10 parts by weight of binder, 30 to 100 parts by weight of water, 9 to 40 parts by weight of aerogel material and surfactant, the aerogel material:The weight ratio of surfactant is 1:0.01‑0.1.Inorganic insulating paste according to the present invention, preparation process is relatively easy, of low cost, and largely remain the heat preservation insulation effect of inorganic porous material, after lotion is dry in nature, the hydrophobic property of aeroge is remained, surface hydrophobicity angle is between 90 ° to 125 °.Slurry has good compatibility, water paint to be only in around inorganic porous material powder substantially with coating, plays cementation.The coating can be used for indoor and outdoor coating for wall surface, and metal, above, the market space is wide for timber etc..
Description
Technical field
The invention belongs to technical field of composite materials more particularly to inorganic insulating paste and preparation method thereof.
Background technology
Porous material is a kind of by being mutually communicated or closed hole constitutes the material of network structure, have volume density it is small,
Large specific surface area, than high mechanical properties, damping capacity is good the features such as, it has also become a kind of outstanding new function structural material.Closely
Nian Lai, nanotechnology are constantly progressive, and the application field of obtained material is also constantly being opened up newly.The hole of nano-porous materials is nanometer
Scale, therefore excellent thermal insulation properties are shown, it is the research hotspot in high-performance insulation material field.By nano-porous materials
Be introduced into heat-barrier material field prepare a kind of ultra heat insulating material be after nano-porous materials be catalyzed, adsorb and detach, from
Son exchanges, gradually finds and grows up on the basis of new material assembling and the application of the fields such as electrochemistry, at this stage by
Scientific circles pay close attention to.
This concept of ultra heat insulating material is by American scholar Hunt A J etc. in 1992 in international material engineering conference
On be put forward for the first time.It refers under predetermined use condition, and thermal coefficient is less than the heat-insulated of the thermal coefficient of " no convected air "
Material.There are two types of the ultra heat insulating materials studied at present:One is nano-pore heat-barrier materials;Another kind is vacuum heat insulation material.
Both heat-barrier materials are all by reaching heat insulation and preservation effect to the control of basal body structure, and with the fastest developing speed is to receive
Metre hole heat-barrier material.Compared with general heat-barrier material, volume smaller, the quality of nano-pore heat-barrier material are lighter.
Inorganic porous material belongs to the nano-pore heat-barrier material in ultra heat insulating material.Such as aerosil, it
It is to be replaced the liquid in wet gel by gas by drying means, while the network structure of gel retains constant gained substantially
Material.The technology of preparing of porous material reaches its maturity, and the utilization of inorganic porous material is always to be engaged in porous material to grind
The focus on research direction of the worker studied carefully.
Application No. is the Chinese patent applications of CN104629581A to report a kind of high tenacity aerosil heat preservation
The preparation method of coating, the patent are the raw materials that addition prepares coating during preparing aerosil, make acquisition
Aeroge can self-crosslinking be coating, such method not only significantly reduces the heat insulating effect of aerosil,
And the performances such as film forming of coating are also greatly reduced.
Invention content
The purpose of the present invention is to propose to a kind of novel inorganic insulating pastes and preparation method thereof, and high property is prepared with easy method
The paste adiabatic coating based on inorganic porous material of energy.
The inorganic insulating paste of embodiment according to an aspect of the present invention, including following component:10 parts by weight of binder, water 30 arrive
100 parts by weight, 9 to 40 parts by weight of aerogel material and surfactant, the aerogel material:The weight of surfactant
Amount is than being 1:0.01-0.1.
Insulating paste according to the above embodiment of the present invention largely remains the aeroge as inorganic porous material
The heat preservation insulation effect of material.
According to some embodiments of the present invention, the binder includes organosilicon, polyurethane resin, polyester resin, epoxy
Resin, acrylic resin, alkyd resin, silicone modified polyester resin, modifying epoxy resin by organosilicon, organic-silicon-modified propylene
One or more in acid resin, silicone alkyd, styrene-acrylic resin, pure third resin, organosilicon acrylic resin.Preferably, being can
With one or more in the styrene-acrylic resin, pure third resin, organosilicon acrylic resin with water formation lotion.
According to some embodiments of the present invention, the surfactant includes lauryl sodium sulfate, detergent alkylate sulphur
1 in sour sodium, dodecyl trimethyl ammonium chloride, dodecyl trimethyl ammonium bromide, sodium stearate, nonylphenol polyoxyethylene ether
Kind is a variety of.By the addition surfactant, can aerogel material be better dispersed in binder, from
And the volume fraction of aerogel material ingredient is helped to improve, and then improve the heat insulation of inorganic insulating paste.
According to some embodiments of the present invention, the aerogel material includes aerosil, carbon aerogels, three oxygen
Change two aluminium aeroges and its mixture.Wherein, the aerogel material can be commercially available, and can also be according to conventional methods
It prepares;Above-mentioned aerogel material a kind of can both be used alone, and a variety of can also be used in mixed way.
According to some embodiments of the present invention, the density of the aerogel material is 30-1000kg/m3, heat conduction under room temperature
Coefficient is 0.010-0.034W/ (mK), porosity 60%-99%, and aperture is 500nm hereinafter, specific surface area is 300-
1000m2/g.Thus, it is possible to greatly play the porous structure feature of aerogel material, better heat insulation is obtained.
According to some embodiments of the present invention, inorganic insulating paste can also include:The inorganic filler of 1 to 10 parts by weight, institute
It includes one or more in white carbon, titanium dioxide, dicalcium powder, diatomite, sepiolite powder to state inorganic filler;And 1 to 10 weight
The auxiliary agent of part, the auxiliary agent includes one or more in antifoaming agent, dispersant, pigment, levelling agent, fire retardant.
The preparation method of the inorganic insulating paste of embodiment according to a second aspect of the present invention, includes the following steps:
(1) surfactant is completely soluble in water, acquired solution and aerogel material are then sequentially added into ball grinder
In, aerogel material slurry is made in ball milling 3-108 hours;
(2) aqueous binders lotion is provided, contains organic binder and water in the aqueous binders lotion;
(3) the aqueous binders lotion is added in the aerogel material slurry obtained by step (1), and carries out ball again
Mill 1-48 hours, obtains the inorganic insulating paste,
Wherein, in the inorganic insulating paste, contain:10 parts by weight of the organic binder, 30 to 100 parts by weight of water,
9 to 40 parts by weight of the aerogel material, and the aerogel material:The weight ratio of surfactant is 1:0.01~0.1.
Surfactant is dissolved in water first, is then made by ball grinding method by preparation method according to the ... of the embodiment of the present invention
Aerogel material is sufficiently mixed with the aqueous solution dissolved with surfactant, can be prepared with high solid loading, dispersion
Hereafter good aeroge slurry passes through the inorganic insulating paste being sufficiently mixed with aqueous binders lotion, Neng Gouchong
The heat insulation that the porous structure of aeroge is brought is waved in distribution.
According to the present invention, at least have the advantages that:
Insulating paste using the present invention largely remains the heat preservation insulation effect of inorganic porous material, and process
Relatively easy, slurry has good compatibility, water paint to be only in around inorganic porous material, play viscous substantially with coating
Knot acts on.The coating can be used for indoor and outdoor coating for wall surface, and metal, above, the market space is wide for timber etc..
Description of the drawings
Fig. 1 is the flow diagram of the preparation method of inorganic insulating paste according to the ... of the embodiment of the present invention;
Fig. 2 is the photo of inorganic insulating paste coating according to the ... of the embodiment of the present invention on a glass, wherein:
1 is droplet, and 2 be inorganic insulating paste, and 3 be glass plate
Specific implementation mode
The embodiment of the present invention is described below in detail, examples of the embodiments are shown in the accompanying drawings, wherein from beginning to end
Same or similar label indicates same or similar element or element with the same or similar functions.Below with reference to attached
The embodiment of figure description is exemplary, and is only used for explaining the present invention, and is not considered as limiting the invention.
Unless otherwise specified, the meaning that the meaning of the scientific and technical terminology in this specification is commonly understood by with those skilled in the art
It is identical, but if any conflict, then the definition in this specification shall prevail.
What is used in the specification and in the claims is related to the institute of group component, process conditions such as reaction temperature and time etc.
There is numerical value in all scenario it should be understood that being modified by " about ".All ranges for being related to same composition or property include endpoint,
The endpoint can be combined independently.Since these ranges are continuous, they include between a minimum and a maximum value every
One numerical value.It will also be appreciated that any numberical range of the application reference is expected to include all subranges within the scope of this.
First, the preparation method of inorganic insulating paste according to the ... of the embodiment of the present invention is described in detail in conjunction with Fig. 1.
As shown in Figure 1, the preparation method of inorganic insulating paste according to the ... of the embodiment of the present invention includes the following steps:
(1) surfactant is completely soluble in water, acquired solution and aerogel material are then sequentially added into ball grinder
In, aerogel material slurry is made in ball milling 3-108 hours
To obtain the inorganic insulating paste with good heat-proof quality, it is desirable that the solid concentration of aerogel material needs enough
Height, and in order to improve the solid concentration of aerogel material, the dispersibility of aerogel material is crucial.Up to now in technology,
The dispersibility of aerogel material is rarely reported.The present inventor is by repeatedly the study found that by dissolving surfactant
Hereafter Yu Shui, then aerogel material and aqueous surfactant solution is sufficiently mixed, can obtain good dispersion property, solid phase
The high aerogel material slurry of content.
Wherein, the surfactant can use lauryl sodium sulfate, neopelex, dodecyl three
One or more in ammonio methacrylate, dodecyl trimethyl ammonium bromide, sodium stearate, nonylphenol polyoxyethylene ether.
In addition, aerogel material includes aerosil, carbon aerogels, alundum (Al2O3) aeroge and its mixing
Object.
(2) aqueous binders lotion is provided, contains organic binder and water in the aqueous binders lotion
Herein, aqueous binders lotion can be the product of market sale, can also be by the organic adhesive of market sale
What agent obtained after being sufficiently mixed with water.
Wherein, as organic binder, organosilicon, polyurethane resin, polyester resin, epoxy resin, propylene can be used
Acid resin, silicone modified polyester resin, modifying epoxy resin by organosilicon, organosilicon modified crylic acid resin, has alkyd resin
One or more in machine Si modification alkyd resin, styrene-acrylic resin, pure third resin, organosilicon acrylic resin.Preferably, using can be with water
Form one or more in the styrene-acrylic resin, pure third resin, organosilicon acrylic resin of lotion.
(3) the aqueous binders lotion is added in the aerogel material slurry obtained by step (1), and carries out ball again
Mill 1-48 hours, obtains the inorganic insulating paste,
Hereafter, aqueous binders lotion is sufficiently mixed with aerogel material slurry by ball milling, you can obtain nothing
Machine insulating paste.Wherein, in the inorganic insulating paste, contain:10 parts by weight of the organic binder, 30 to 100 parts by weight of water,
9 to 40 parts by weight of the aerogel material, and the aerogel material:The weight ratio of surfactant is 1:0.01~0.1.
Hereinafter, carrying out further detailed description to the present invention by specific embodiment.
Embodiment 1
(1) by water:Silicon dioxide aerogel powder (commercially available, source Shanghai Yi Yuan):Lauryl sodium sulfate is (substantially former
Material, commercially available, 99% or more purity) by weight 20:6:0.7 ratio, it is first that lauryl sodium sulfate is completely soluble in water, so
Acquired solution and silicon dioxide aerogel powder are sequentially added in ball grinder afterwards, ball milling 3 hours, inorganic silicon dioxide gas is made
Gel slurry.
Hereafter, according to following weight proportion:Styrene-acrylic emulsion (commercially available, source Beijing east joins BS-104) 10 parts by weight, water 10
Parts by weight, 9 parts by weight of inorganic silicon dioxide aeroge slurry, proceed as follows:
(2) styrene-acrylic emulsion and water are uniformly mixed by said ratio, obtain waterborne styrene-acrylic emulsion;
(3) the inorganic silicon dioxide aeroge slurry prepared in waterborne styrene-acrylic emulsion and (1) is pressed into said ratio again
It is put into ball grinder, ball milling 1 hour is to get to inorganic insulating paste.
Embodiment 2
(1) by water:Silica aerogel particles (commercially available, source Shanghai Yi Yuan):Sodium stearate (base stock, it is commercially available,
99% or more purity) by weight 20:14:0.5 ratio, it is first that sodium stearate is completely soluble in water, then by acquired solution and
Silica aerogel particles sequentially add in ball grinder, ball milling 48 hours, and inorganic silicon dioxide aeroge slurry is made.
Hereafter, according to following weight proportion:10 parts by weight of aqueous epoxy resins, 100 parts by weight of water, inorganic silicon dioxide gas
40 parts by weight of gel slurry, proceed as follows:
(2) aqueous epoxy resins (commercially available, the deep treasure in source Guangzhou) and water are uniformly mixed according to the ratio, obtain water-base epoxy tree
Fat liquor;
(3) the inorganic silicon dioxide aeroge slurry prepared in aqueous epoxy resin emulsion and (1) is pressed into said ratio again
It is secondary
It is put into ball grinder, ball milling 4 hours is to get to inorganic insulating paste.
Embodiment 3
(1) by water:Silica aerogel particles (commercially available, source Shanghai Yi Yuan):Neopelex is (substantially former
Material, commercially available, 99% or more purity):Dodecyl trimethyl ammonium chloride (base stock, commercially available, 99% or more purity) is by weight
Than 20:20:0.1:0.4 ratio, it is first that neopelex and dodecyl trimethyl ammonium chloride is completely soluble in water, so
Acquired solution and aerosil are sequentially added in ball grinder afterwards, ball milling 108 hours, inorganic silicon dioxide airsetting is made
Rubber cement material.
Hereafter, according to following weight proportion:10 parts by weight of pure-acrylic emulsion, 2 parts by weight of silicone acrylic emulsion, 80 parts by weight of water, nothing
32 parts by weight of machine aerosil slurry, proceed as follows:
(2) pure-acrylic emulsion (commercially available, source Beijing east joins BS-104) and water are uniformly mixed according to the ratio, are obtained diluted pure
Acrylic emulsion;
(3) the inorganic silicon dioxide aeroge slurry prepared in diluted pure-acrylic emulsion and (1) is pressed into said ratio again
It puts
Enter in ball grinder, ball milling 48 hours is to get to inorganic insulating paste.
Following performance evaluation is carried out to the inorganic insulating paste that embodiment 3 obtains:By inorganic thermal insulation made from above-described embodiment 3
On a glass, thickness 3mm, it is 125 ° to survey its contact angle for cream brushing, and thermal coefficient (25 DEG C of environment) is 0.034W/ (mK),
Tensile bond strength is 1MPa;After being impregnated 72 hours in water, it is 122 ° to survey its contact angle, and thermal coefficient (25 DEG C of environment) is
0.036W/ (mK), tensile bond intensity are 0.8MPa.From experimental data as can be seen that the insulating paste coating hydrophobic effect is prominent
Go out, heat insulation effect is excellent, and after immersion, hydrophobic effect and heat insulation effect variation are little, illustrate that its water resistance is also fine.
Tensile bond intensity either drying regime or Riddled Condition are all higher than JG298-2010《Architecture indoor putty》In internally
The requirement of wall putty.
Although by some embodiments describing the present invention, it is understood by one of ordinary skill in the art that can be to them
Various changes are carried out, the element of the present invention can be replaced with equivalent, the improvement that can also be needed is so that specific situation
Or material is suitable for the invention introduction, without departing from the essence and base region of the present invention.Therefore, the present invention will include falling
Enter all embodiments in scope.
In addition, it should be understood that although this specification is described in terms of embodiments, but not each embodiment is only wrapped
Containing an independent technical solution, this description of the specification is merely for the sake of clarity, and those skilled in the art should
It considers the specification as a whole, the technical solutions in the various embodiments may also be suitably combined, forms those skilled in the art
The other embodiment being appreciated that.
Claims (10)
1. a kind of inorganic insulating paste, which is characterized in that include following component:
10 parts by weight of binder, 30 to 100 parts by weight of water, 9 to 40 parts by weight of aerogel material and surfactant, it is described
Aerogel material:The weight ratio of surfactant is 1:0.01-0.1.
2. inorganic insulating paste as described in claim 1, which is characterized in that the binder include organosilicon, polyurethane resin,
Polyester resin, epoxy resin, acrylic resin, alkyd resin, silicone modified polyester resin, modifying epoxy resin by organosilicon,
1 kind or more in organosilicon modified crylic acid resin, silicone alkyd, styrene-acrylic resin, pure third resin, organosilicon acrylic resin
Kind.
3. inorganic insulating paste as described in claim 1, which is characterized in that the surfactant includes dodecyl sulphate
Sodium, neopelex, dodecyl trimethyl ammonium chloride, dodecyl trimethyl ammonium bromide, sodium stearate, nonyl phenol
One or more in polyoxyethylene ether.
4. inorganic insulating paste as described in claim 1, which is characterized in that the aerogel material includes silica airsetting
Glue, carbon aerogels, alundum (Al2O3) aeroge and its mixture.
5. inorganic insulating paste as claimed in claim 4, which is characterized in that the density of the aerogel material is 30-1000kg/
m3, thermal coefficient is 0.010-0.034W/ (mK) under room temperature, and porosity 60%-99%, aperture is 500nm hereinafter, specific surface
Product is 300-1000m2/g。
6. inorganic insulating paste as described in claim 1, which is characterized in that also include:
The inorganic filler of 1 to 10 parts by weight, the inorganic filler include white carbon, titanium dioxide, dicalcium powder, diatomite, sepiolite
One or more in powder;And
The auxiliary agent of 1 to 10 parts by weight, the auxiliary agent include a kind or more in antifoaming agent, dispersant, pigment, levelling agent, fire retardant
Kind.
7. a kind of preparation method of inorganic insulating paste, which is characterized in that include the following steps:
(1) surfactant is completely soluble in water, then acquired solution and aerogel material are sequentially added in ball grinder,
Aerogel material slurry is made in ball milling 3-108 hours;
(2) aqueous binders lotion is provided, contains organic binder and water in the aqueous binders lotion;
(3) the aqueous binders lotion is added in the aerogel material slurry obtained by step (1), and carries out ball milling 1- again
48 hours, the inorganic insulating paste is obtained,
Wherein, in the inorganic insulating paste, contain:10 parts by weight of the organic binder, 30 to 100 parts by weight of water are described
9 to 40 parts by weight of aerogel material, and the aerogel material:The weight ratio of surfactant is 1:0.01~0.1.
8. preparation method as claimed in claim 7, the organic binder include organosilicon, polyurethane resin, polyester resin,
It is epoxy resin, acrylic resin, alkyd resin, silicone modified polyester resin, modifying epoxy resin by organosilicon, organic-silicon-modified
One or more in acrylic resin, silicone alkyd, styrene-acrylic resin, pure third resin, organosilicon acrylic resin.
9. preparation method as claimed in claim 7, which is characterized in that the surfactant include lauryl sodium sulfate,
Neopelex, dodecyl trimethyl ammonium chloride, dodecyl trimethyl ammonium bromide, sodium stearate, nonyl phenol are poly-
One or more in ethylene oxide ether.
10. preparation method as claimed in claim 7, which is characterized in that the aerogel material include aerosil,
Carbon aerogels, alundum (Al2O3) aeroge and its mixture.
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Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109058662A (en) * | 2018-09-27 | 2018-12-21 | 中科高新材料(南通)有限责任公司 | A kind of preparation method of aerosil composite plate |
CN110054915A (en) * | 2019-03-20 | 2019-07-26 | 中山科邦化工材料技术有限公司 | A kind of super-hydrophobic glass antirain agent aerosol composition and preparation method thereof |
WO2021015676A1 (en) * | 2019-07-22 | 2021-01-28 | Krosslinker Pte Ltd | System and method for manufacturing water-based hydrophobic aerogels and aerogel composites |
WO2024007513A1 (en) * | 2022-07-04 | 2024-01-11 | 江苏集萃功能材料研究所有限公司 | High-density aerogel water-based paste material and preparation method therefor |
Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
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WO2011083174A1 (en) * | 2010-01-11 | 2011-07-14 | Parexlanko | Insulating silica xerogel plaster |
CN104496399A (en) * | 2014-12-15 | 2015-04-08 | 苏州同玄新材料有限公司 | Aerogel building heat preservation and thermal insulation composite material and preparation method thereof |
-
2017
- 2017-08-28 CN CN201710749837.XA patent/CN108299875A/en active Pending
Patent Citations (2)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
WO2011083174A1 (en) * | 2010-01-11 | 2011-07-14 | Parexlanko | Insulating silica xerogel plaster |
CN104496399A (en) * | 2014-12-15 | 2015-04-08 | 苏州同玄新材料有限公司 | Aerogel building heat preservation and thermal insulation composite material and preparation method thereof |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN109058662A (en) * | 2018-09-27 | 2018-12-21 | 中科高新材料(南通)有限责任公司 | A kind of preparation method of aerosil composite plate |
CN110054915A (en) * | 2019-03-20 | 2019-07-26 | 中山科邦化工材料技术有限公司 | A kind of super-hydrophobic glass antirain agent aerosol composition and preparation method thereof |
WO2021015676A1 (en) * | 2019-07-22 | 2021-01-28 | Krosslinker Pte Ltd | System and method for manufacturing water-based hydrophobic aerogels and aerogel composites |
WO2024007513A1 (en) * | 2022-07-04 | 2024-01-11 | 江苏集萃功能材料研究所有限公司 | High-density aerogel water-based paste material and preparation method therefor |
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