CN108298591A - A kind of synthetic method of hexagon iron titanate nanometer sheet material and application - Google Patents
A kind of synthetic method of hexagon iron titanate nanometer sheet material and application Download PDFInfo
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- CN108298591A CN108298591A CN201810331771.7A CN201810331771A CN108298591A CN 108298591 A CN108298591 A CN 108298591A CN 201810331771 A CN201810331771 A CN 201810331771A CN 108298591 A CN108298591 A CN 108298591A
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- Prior art keywords
- sheet material
- nanometer sheet
- hexagon
- iron
- iron titanate
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- JCDAAXRCMMPNBO-UHFFFAOYSA-N iron(3+);oxygen(2-);titanium(4+) Chemical compound [O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[O-2].[Ti+4].[Ti+4].[Fe+3].[Fe+3] JCDAAXRCMMPNBO-UHFFFAOYSA-N 0.000 title claims abstract description 80
- 239000000463 material Substances 0.000 title claims abstract description 71
- 238000010189 synthetic method Methods 0.000 title claims abstract description 20
- 230000015556 catabolic process Effects 0.000 claims abstract description 43
- 238000006731 degradation reaction Methods 0.000 claims abstract description 43
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 26
- 150000003608 titanium Chemical class 0.000 claims abstract description 22
- 238000000034 method Methods 0.000 claims abstract description 20
- 239000000356 contaminant Substances 0.000 claims abstract description 18
- 239000003054 catalyst Substances 0.000 claims abstract description 17
- 238000006243 chemical reaction Methods 0.000 claims abstract description 16
- 239000008367 deionised water Substances 0.000 claims abstract description 15
- 229910021641 deionized water Inorganic materials 0.000 claims abstract description 15
- 150000002505 iron Chemical class 0.000 claims abstract description 15
- 239000012266 salt solution Substances 0.000 claims abstract description 14
- 239000003153 chemical reaction reagent Substances 0.000 claims abstract description 13
- 230000001376 precipitating effect Effects 0.000 claims abstract description 13
- 230000003197 catalytic effect Effects 0.000 claims abstract description 11
- 230000035484 reaction time Effects 0.000 claims abstract description 11
- 238000006385 ozonation reaction Methods 0.000 claims abstract description 10
- 238000010438 heat treatment Methods 0.000 claims abstract description 9
- 150000007530 organic bases Chemical class 0.000 claims abstract description 9
- HDBYDWGHRMUVNW-UHFFFAOYSA-H [Ti+4].[OH-].[Fe+2].[OH-].[OH-].[OH-].[OH-].[OH-] Chemical compound [Ti+4].[OH-].[Fe+2].[OH-].[OH-].[OH-].[OH-].[OH-] HDBYDWGHRMUVNW-UHFFFAOYSA-H 0.000 claims abstract description 4
- 239000002243 precursor Substances 0.000 claims abstract description 4
- 239000003513 alkali Substances 0.000 claims description 17
- 238000001027 hydrothermal synthesis Methods 0.000 claims description 17
- 239000003518 caustics Substances 0.000 claims description 11
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 claims description 10
- 238000005406 washing Methods 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 8
- RBTARNINKXHZNM-UHFFFAOYSA-K iron trichloride Chemical compound Cl[Fe](Cl)Cl RBTARNINKXHZNM-UHFFFAOYSA-K 0.000 claims description 7
- 239000010936 titanium Substances 0.000 claims description 7
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 claims description 6
- 238000001035 drying Methods 0.000 claims description 6
- 229940073455 tetraethylammonium hydroxide Drugs 0.000 claims description 6
- WGTYBPLFGIVFAS-UHFFFAOYSA-M tetramethylammonium hydroxide Chemical group [OH-].C[N+](C)(C)C WGTYBPLFGIVFAS-UHFFFAOYSA-M 0.000 claims description 6
- 229910052719 titanium Inorganic materials 0.000 claims description 6
- 239000011790 ferrous sulphate Substances 0.000 claims description 5
- 235000003891 ferrous sulphate Nutrition 0.000 claims description 5
- 229910052742 iron Inorganic materials 0.000 claims description 5
- BAUYGSIQEAFULO-UHFFFAOYSA-L iron(2+) sulfate (anhydrous) Chemical compound [Fe+2].[O-]S([O-])(=O)=O BAUYGSIQEAFULO-UHFFFAOYSA-L 0.000 claims description 5
- 229910000359 iron(II) sulfate Inorganic materials 0.000 claims description 5
- 229940062993 ferrous oxalate Drugs 0.000 claims description 4
- OWZIYWAUNZMLRT-UHFFFAOYSA-L iron(2+);oxalate Chemical compound [Fe+2].[O-]C(=O)C([O-])=O OWZIYWAUNZMLRT-UHFFFAOYSA-L 0.000 claims description 4
- VCJMYUPGQJHHFU-UHFFFAOYSA-N iron(3+);trinitrate Chemical group [Fe+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O VCJMYUPGQJHHFU-UHFFFAOYSA-N 0.000 claims description 4
- LRGJRHZIDJQFCL-UHFFFAOYSA-M tetraethylazanium;hydroxide Chemical compound [OH-].CC[N+](CC)(CC)CC LRGJRHZIDJQFCL-UHFFFAOYSA-M 0.000 claims description 4
- JMXKSZRRTHPKDL-UHFFFAOYSA-N titanium ethoxide Chemical compound [Ti+4].CC[O-].CC[O-].CC[O-].CC[O-] JMXKSZRRTHPKDL-UHFFFAOYSA-N 0.000 claims description 4
- ZLXPLDLEBORRPT-UHFFFAOYSA-M [NH4+].[Fe+].[O-]S([O-])(=O)=O Chemical compound [NH4+].[Fe+].[O-]S([O-])(=O)=O ZLXPLDLEBORRPT-UHFFFAOYSA-M 0.000 claims description 3
- LPSKDVINWQNWFE-UHFFFAOYSA-M tetrapropylazanium;hydroxide Chemical compound [OH-].CCC[N+](CCC)(CCC)CCC LPSKDVINWQNWFE-UHFFFAOYSA-M 0.000 claims description 3
- 229910000349 titanium oxysulfate Inorganic materials 0.000 claims description 3
- XJDNKRIXUMDJCW-UHFFFAOYSA-J titanium tetrachloride Chemical compound Cl[Ti](Cl)(Cl)Cl XJDNKRIXUMDJCW-UHFFFAOYSA-J 0.000 claims description 3
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 claims description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 2
- ZLMJMSJWJFRBEC-UHFFFAOYSA-N Potassium Chemical compound [K] ZLMJMSJWJFRBEC-UHFFFAOYSA-N 0.000 claims description 2
- FPCJKVGGYOAWIZ-UHFFFAOYSA-N butan-1-ol;titanium Chemical compound [Ti].CCCCO.CCCCO.CCCCO.CCCCO FPCJKVGGYOAWIZ-UHFFFAOYSA-N 0.000 claims description 2
- NMGYKLMMQCTUGI-UHFFFAOYSA-J diazanium;titanium(4+);hexafluoride Chemical compound [NH4+].[NH4+].[F-].[F-].[F-].[F-].[F-].[F-].[Ti+4] NMGYKLMMQCTUGI-UHFFFAOYSA-J 0.000 claims description 2
- 230000005484 gravity Effects 0.000 claims description 2
- FBAFATDZDUQKNH-UHFFFAOYSA-M iron chloride Chemical compound [Cl-].[Fe] FBAFATDZDUQKNH-UHFFFAOYSA-M 0.000 claims description 2
- RUTXIHLAWFEWGM-UHFFFAOYSA-H iron(3+) sulfate Chemical compound [Fe+3].[Fe+3].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O RUTXIHLAWFEWGM-UHFFFAOYSA-H 0.000 claims description 2
- PVFSDGKDKFSOTB-UHFFFAOYSA-K iron(3+);triacetate Chemical compound [Fe+3].CC([O-])=O.CC([O-])=O.CC([O-])=O PVFSDGKDKFSOTB-UHFFFAOYSA-K 0.000 claims description 2
- 229910000360 iron(III) sulfate Inorganic materials 0.000 claims description 2
- YOYLLRBMGQRFTN-SMCOLXIQSA-N norbuprenorphine Chemical compound C([C@@H](NCC1)[C@]23CC[C@]4([C@H](C3)C(C)(O)C(C)(C)C)OC)C3=CC=C(O)C5=C3[C@@]21[C@H]4O5 YOYLLRBMGQRFTN-SMCOLXIQSA-N 0.000 claims description 2
- 239000001301 oxygen Substances 0.000 claims description 2
- 229910052760 oxygen Inorganic materials 0.000 claims description 2
- 229910052700 potassium Inorganic materials 0.000 claims description 2
- 239000011591 potassium Substances 0.000 claims description 2
- 239000013049 sediment Substances 0.000 claims description 2
- YONPGGFAJWQGJC-UHFFFAOYSA-K titanium(iii) chloride Chemical compound Cl[Ti](Cl)Cl YONPGGFAJWQGJC-UHFFFAOYSA-K 0.000 claims description 2
- HHDOORYZQSEMGM-UHFFFAOYSA-L potassium;oxalate;titanium(4+) Chemical compound [K+].[Ti+4].[O-]C(=O)C([O-])=O HHDOORYZQSEMGM-UHFFFAOYSA-L 0.000 claims 1
- 238000002360 preparation method Methods 0.000 abstract description 8
- 238000001354 calcination Methods 0.000 abstract description 3
- 238000005265 energy consumption Methods 0.000 abstract description 3
- 238000005245 sintering Methods 0.000 abstract description 3
- 239000002086 nanomaterial Substances 0.000 abstract description 2
- 239000002245 particle Substances 0.000 abstract description 2
- 238000001179 sorption measurement Methods 0.000 abstract description 2
- CXKWCBBOMKCUKX-UHFFFAOYSA-M methylene blue Chemical compound [Cl-].C1=CC(N(C)C)=CC2=[S+]C3=CC(N(C)C)=CC=C3N=C21 CXKWCBBOMKCUKX-UHFFFAOYSA-M 0.000 description 31
- 229960000907 methylthioninium chloride Drugs 0.000 description 31
- WXNZTHHGJRFXKQ-UHFFFAOYSA-N 4-chlorophenol Chemical compound OC1=CC=C(Cl)C=C1 WXNZTHHGJRFXKQ-UHFFFAOYSA-N 0.000 description 12
- 229940090668 parachlorophenol Drugs 0.000 description 12
- 239000000243 solution Substances 0.000 description 12
- KWYUFKZDYYNOTN-UHFFFAOYSA-M Potassium hydroxide Chemical compound [OH-].[K+] KWYUFKZDYYNOTN-UHFFFAOYSA-M 0.000 description 9
- 238000003837 high-temperature calcination Methods 0.000 description 9
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 8
- 229910001200 Ferrotitanium Inorganic materials 0.000 description 7
- 239000003344 environmental pollutant Substances 0.000 description 7
- 231100000719 pollutant Toxicity 0.000 description 7
- XLYOFNOQVPJJNP-UHFFFAOYSA-M hydroxide Chemical compound [OH-] XLYOFNOQVPJJNP-UHFFFAOYSA-M 0.000 description 6
- 230000001699 photocatalysis Effects 0.000 description 6
- 239000007788 liquid Substances 0.000 description 5
- 239000003795 chemical substances by application Substances 0.000 description 4
- 230000000694 effects Effects 0.000 description 4
- 230000015572 biosynthetic process Effects 0.000 description 3
- 235000013339 cereals Nutrition 0.000 description 3
- 239000000975 dye Substances 0.000 description 3
- 229910052751 metal Inorganic materials 0.000 description 3
- 239000002184 metal Substances 0.000 description 3
- -1 organic base tetraethyl ammonium hydroxide Chemical class 0.000 description 3
- 238000007146 photocatalysis Methods 0.000 description 3
- 238000013033 photocatalytic degradation reaction Methods 0.000 description 3
- 238000003786 synthesis reaction Methods 0.000 description 3
- ISPYQTSUDJAMAB-UHFFFAOYSA-N 2-chlorophenol Chemical compound OC1=CC=CC=C1Cl ISPYQTSUDJAMAB-UHFFFAOYSA-N 0.000 description 2
- MHAJPDPJQMAIIY-UHFFFAOYSA-N Hydrogen peroxide Chemical compound OO MHAJPDPJQMAIIY-UHFFFAOYSA-N 0.000 description 2
- 238000002441 X-ray diffraction Methods 0.000 description 2
- 238000002835 absorbance Methods 0.000 description 2
- 239000002253 acid Substances 0.000 description 2
- 230000009286 beneficial effect Effects 0.000 description 2
- 125000000484 butyl group Chemical group [H]C([*])([H])C([H])([H])C([H])([H])C([H])([H])[H] 0.000 description 2
- 230000000593 degrading effect Effects 0.000 description 2
- 238000005374 membrane filtration Methods 0.000 description 2
- 238000013032 photocatalytic reaction Methods 0.000 description 2
- 150000003839 salts Chemical class 0.000 description 2
- 238000002336 sorption--desorption measurement Methods 0.000 description 2
- 239000002351 wastewater Substances 0.000 description 2
- ZAMOUSCENKQFHK-UHFFFAOYSA-N Chlorine atom Chemical compound [Cl] ZAMOUSCENKQFHK-UHFFFAOYSA-N 0.000 description 1
- 239000002841 Lewis acid Substances 0.000 description 1
- 240000007594 Oryza sativa Species 0.000 description 1
- 235000007164 Oryza sativa Nutrition 0.000 description 1
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 1
- ISWSIDIOOBJBQZ-UHFFFAOYSA-N Phenol Chemical compound OC1=CC=CC=C1 ISWSIDIOOBJBQZ-UHFFFAOYSA-N 0.000 description 1
- 230000010748 Photoabsorption Effects 0.000 description 1
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 1
- 239000005864 Sulphur Substances 0.000 description 1
- 238000009303 advanced oxidation process reaction Methods 0.000 description 1
- QVGXLLKOCUKJST-UHFFFAOYSA-N atomic oxygen Chemical compound [O] QVGXLLKOCUKJST-UHFFFAOYSA-N 0.000 description 1
- 238000006555 catalytic reaction Methods 0.000 description 1
- 239000000460 chlorine Substances 0.000 description 1
- 229910052801 chlorine Inorganic materials 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 238000001514 detection method Methods 0.000 description 1
- 238000009826 distribution Methods 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 239000007772 electrode material Substances 0.000 description 1
- 238000004134 energy conservation Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 235000019441 ethanol Nutrition 0.000 description 1
- 125000005909 ethyl alcohol group Chemical group 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- IMBKASBLAKCLEM-UHFFFAOYSA-L ferrous ammonium sulfate (anhydrous) Chemical compound [NH4+].[NH4+].[Fe+2].[O-]S([O-])(=O)=O.[O-]S([O-])(=O)=O IMBKASBLAKCLEM-UHFFFAOYSA-L 0.000 description 1
- 238000011049 filling Methods 0.000 description 1
- 239000008187 granular material Substances 0.000 description 1
- 238000000227 grinding Methods 0.000 description 1
- 239000001257 hydrogen Substances 0.000 description 1
- 229910052739 hydrogen Inorganic materials 0.000 description 1
- 125000004435 hydrogen atom Chemical class [H]* 0.000 description 1
- 238000009776 industrial production Methods 0.000 description 1
- 150000007517 lewis acids Chemical group 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 230000013011 mating Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 150000004706 metal oxides Chemical class 0.000 description 1
- MCPLVIGCWWTHFH-UHFFFAOYSA-L methyl blue Chemical compound [Na+].[Na+].C1=CC(S(=O)(=O)[O-])=CC=C1NC1=CC=C(C(=C2C=CC(C=C2)=[NH+]C=2C=CC(=CC=2)S([O-])(=O)=O)C=2C=CC(NC=3C=CC(=CC=3)S([O-])(=O)=O)=CC=2)C=C1 MCPLVIGCWWTHFH-UHFFFAOYSA-L 0.000 description 1
- 125000000325 methylidene group Chemical group [H]C([H])=* 0.000 description 1
- 238000002156 mixing Methods 0.000 description 1
- 239000002135 nanosheet Substances 0.000 description 1
- 231100000252 nontoxic Toxicity 0.000 description 1
- 230000003000 nontoxic effect Effects 0.000 description 1
- SUJHBAWCOQPZCU-UHFFFAOYSA-N oxalic acid;potassium;titanium Chemical compound [K].[Ti].OC(=O)C(O)=O SUJHBAWCOQPZCU-UHFFFAOYSA-N 0.000 description 1
- 230000003647 oxidation Effects 0.000 description 1
- 238000007254 oxidation reaction Methods 0.000 description 1
- DCKVFVYPWDKYDN-UHFFFAOYSA-L oxygen(2-);titanium(4+);sulfate Chemical group [O-2].[Ti+4].[O-]S([O-])(=O)=O DCKVFVYPWDKYDN-UHFFFAOYSA-L 0.000 description 1
- 230000002688 persistence Effects 0.000 description 1
- 239000002957 persistent organic pollutant Substances 0.000 description 1
- 239000000575 pesticide Substances 0.000 description 1
- 239000011941 photocatalyst Substances 0.000 description 1
- 238000006303 photolysis reaction Methods 0.000 description 1
- 230000015843 photosynthesis, light reaction Effects 0.000 description 1
- 238000000634 powder X-ray diffraction Methods 0.000 description 1
- 238000001556 precipitation Methods 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 235000009566 rice Nutrition 0.000 description 1
- 238000007789 sealing Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000004088 simulation Methods 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 229910000348 titanium sulfate Inorganic materials 0.000 description 1
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium(II) oxide Chemical compound [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 1
- 238000000870 ultraviolet spectroscopy Methods 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
- 229910052724 xenon Inorganic materials 0.000 description 1
- FHNFHKCVQCLJFQ-UHFFFAOYSA-N xenon atom Chemical compound [Xe] FHNFHKCVQCLJFQ-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01G—COMPOUNDS CONTAINING METALS NOT COVERED BY SUBCLASSES C01D OR C01F
- C01G49/00—Compounds of iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J23/00—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
- B01J23/70—Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00 of the iron group metals or copper
- B01J23/74—Iron group metals
- B01J23/745—Iron
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/30—Catalysts, in general, characterised by their form or physical properties characterised by their physical properties
- B01J35/39—Photocatalytic properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B01—PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
- B01J—CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
- B01J35/00—Catalysts, in general, characterised by their form or physical properties
- B01J35/60—Catalysts, in general, characterised by their form or physical properties characterised by their surface properties or porosity
- B01J35/61—Surface area
- B01J35/612—Surface area less than 10 m2/g
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/30—Treatment of water, waste water, or sewage by irradiation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/725—Treatment of water, waste water, or sewage by oxidation by catalytic oxidation
-
- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F1/00—Treatment of water, waste water, or sewage
- C02F1/72—Treatment of water, waste water, or sewage by oxidation
- C02F1/78—Treatment of water, waste water, or sewage by oxidation with ozone
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2002/00—Crystal-structural characteristics
- C01P2002/70—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data
- C01P2002/72—Crystal-structural characteristics defined by measured X-ray, neutron or electron diffraction data by d-values or two theta-values, e.g. as X-ray diagram
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/01—Particle morphology depicted by an image
- C01P2004/03—Particle morphology depicted by an image obtained by SEM
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/20—Particle morphology extending in two dimensions, e.g. plate-like
- C01P2004/22—Particle morphology extending in two dimensions, e.g. plate-like with a polygonal circumferential shape
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- C—CHEMISTRY; METALLURGY
- C01—INORGANIC CHEMISTRY
- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/62—Submicrometer sized, i.e. from 0.1-1 micrometer
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
- C01P2004/00—Particle morphology
- C01P2004/60—Particles characterised by their size
- C01P2004/64—Nanometer sized, i.e. from 1-100 nanometer
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- C01P—INDEXING SCHEME RELATING TO STRUCTURAL AND PHYSICAL ASPECTS OF SOLID INORGANIC COMPOUNDS
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- C01P2006/12—Surface area
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- C—CHEMISTRY; METALLURGY
- C02—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F—TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
- C02F2305/00—Use of specific compounds during water treatment
- C02F2305/10—Photocatalysts
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- Chemical Kinetics & Catalysis (AREA)
- Environmental & Geological Engineering (AREA)
- Water Supply & Treatment (AREA)
- Life Sciences & Earth Sciences (AREA)
- Hydrology & Water Resources (AREA)
- Materials Engineering (AREA)
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Abstract
A kind of synthetic method of hexagon iron titanate nanometer sheet material and application, the present invention relates to technical field of nano material, more particularly to the synthetic method of a kind of hexagon iron titanate nanometer sheet material and application.The invention solves existing calcining preparation method, that there are grain sizes is big, and easy-sintering, Adsorption is few, and the technical issues of huge energy consumption.Method：By titanium salt and iron salt dissolved in deionized water, organic base is added, precipitating reagent is prepared and is added in titanium salt and iron salt solutions, generate iron hydroxide titanium precursors, heating in water heating kettle is transferred to and obtains hexagon iron titanate nanometer sheet material.The material is made in lower reaction temperature and in the shorter reaction time, and crystallinity is high, and pattern is clear, uniform particle sizes, has good application and industrialization prospect.The present invention is used to prepare a kind of hexagon iron titanate nanometer sheet material, and as in degradation of contaminant in degradation of contaminant in catalyst application under visible light degradation of contaminant, catalytic ozonation and heterogeneous class Fenton.
Description
Technical field
The present invention relates to technical field of nano material, more particularly to a kind of synthesis side of hexagon iron titanate nanometer sheet material
Method and application.
Background technology
The metal oxide semiconductor of perovskite structure is environmental-friendly because having stable structure, and safety height etc. is universal special
Property, it is widely used in industrial production at present.And other special characteristics that it has, if photo absorption performance is strong, capacity is big, recycles the longevity
Life is long etc. so that it can be applied to photocatalysis, electrode material, in the development field of battery material.
The native metal element overwhelming majority in perovskite structure is that stable, new multicomponent Ca-Ti ore type is compound
Oxide can be formed by replacing or adulterating position, thus with stable physical and chemical performance.Wherein iron titanate
(FeTiO3) as one kind commonly used in perovskite family, have and prepares raw material and be easy to get, safe and non-toxic, environmental-friendly, band
The features such as gap is moderate, and photo-catalysis capability is strong, and surface metal active sites are more can realize a variety of photocatalysis and other water process with it
Purposes, such as photolysis water hydrogen, photo-catalyst, photocatalytic pollutant degradation etc..Additionally due to metatitanic acid iron surface is with abundant
Metal active centres, surface hydroxyl and surface strong lewis acid position isoreactivity point, while can also be applied to various advanced
Oxidation process, such as catalytic ozonation in the water treatment procedures such as heterogeneous class Fenton, there is tremendous economic effect and society to imitate
Benefit.In the prior art, the iron titanate of most of synthesis is all made by high-temperature calcination, and grain size is big, easy-sintering, surface-active
Position is few, and huge energy consumption.
Invention content
The invention solves existing calcining preparation method, that there are grain sizes is big, and easy-sintering, Adsorption is few, and huge energy consumption
The technical issues of, and synthetic method and the application of a kind of hexagon iron titanate nanometer sheet material are provided.
A kind of synthetic method of hexagon iron titanate nanometer sheet material, specifically carries out according to the following steps：
One, titanium salt and molysite are put into deionized water and are dissolved, obtain titanium salt and iron salt solutions,
Two, organic base is added in the titanium salt and iron salt solutions that step 1 obtains, obtains mixed liquor；
Three, caustic alkali is put into deionized water and is dissolved, obtain precipitating reagent；
Four, the precipitating reagent that step 3 obtains is added in the mixed liquor that step 2 obtains, reaction generates hydroxide ferrotitanium
Presoma；
Five, the presoma that step 4 obtains is transferred in water heating kettle, is heated, carry out hydro-thermal reaction, washing and drying obtains
The hexagon iron titanate nanometer sheet material.
The hexagon iron titanate nanometer sheet material is as in catalyst under visible light degradation of contaminant, catalytic ozonation
Application in degradation of contaminant and heterogeneous class Fenton in degradation of contaminant.
The beneficial effects of the invention are as follows：Hydro-thermal method is a kind of material preparation method of green energy conservation, and this method is using sealing
The form of heating generates pressure in reaction kettle, therefore can be obtained the preferable nanometer sheet of crystallinity at a lower temperature
Material, and since reaction carries out in the liquid phase, the material granule and grain size generated is all relatively uniform, and specific surface area is larger,
Active sites are abundant.Pattern control is added in hydroxide ion reacts precipitation process with titanium salt and iron salt solutions in the present invention
Preparation can generate strong mating reaction so that iron hydroxide titanium precursors are according to certain orientation with iron hydroxide titanium precursors
Growth, final crystallization generate hexagon iron titanate nanometer sheet material.The material can be in lower reaction temperature and shorter anti-
Seasonable interior obtained, crystallinity is high, and pattern is clear, uniform particle sizes, has good application and industrialization prospect.
The present invention proposes a kind of synthetic method of simple, maneuverable hexagon iron titanate nanometer sheet material.This method
Using a step hydrothermal synthesis method, iron titanate nanometer sheet pattern is carried out by adjusting the concentration of organic base pattern controlling agent in synthesis
Regulation and control, compared with common iron titanate calcining preparation method, the iron titanate nanometer sheet material of present invention gained is without numerous excessively
Trivial grinding is sized mixing, and in the case of high-temperature calcination, only realizes iron titanate nanometer by the way that organic base pattern controlling agent is simply added
The regulation and control of piece pattern obtain even size distribution, the nanometer sheet of pattern complete display.Six sides obtained by above-mentioned preparation method
Shape iron titanate nanometer sheet material can be applied to catalyzing and degrading pollutant by visible light, catalytic ozonation degradation of contaminant and it is non-
Similar Fenton degradation of contaminant.Pass through N2Adsorption/desorption characterizes, and measures hexagon iron titanate nanometer sheet material prepared by the present invention
Specific surface area is 12.2m2/ g, boundary and corner angle are clear, and for diameter in 500nm or so, thickness is 50nm or so.This hair prepared
The hexagon iron titanate nanometer sheet material of bright preparation can remove about 75% parachlorophenol at 90 minutes；240 minutes degradable
About 80% methylene blue.
The present invention is used to prepare a kind of hexagon iron titanate nanometer sheet material, the hexagon iron titanate nanometer sheet material conduct
Catalyst is applied in degradation of contaminant, catalytic ozonation under visible light and is degraded in degradation of contaminant and heterogeneous class Fenton
In pollutant.
Description of the drawings
Fig. 1 is the X-ray diffraction spectrogram of hexagon iron titanate nanometer sheet material prepared by embodiment one；
Fig. 2 is the scanning electron microscope (SEM) photograph of hexagon iron titanate nanometer sheet material prepared by embodiment one；
Fig. 3 is the curve graph in photocatalytic pollutant degradation system Methylene Blue concentration and reaction time, wherein ■ generations
The degradation rate of methylene blue when table is not added with catalyst, ● represent methylene blue when iron titanate made from commercially available high-temperature calcination is added
Degradation rate, ▲ represent be added embodiment 1 in prepare hexagon iron titanate nanometer sheet material when methylene blue degradation rate；
Fig. 4 is the curve graph of parachlorophenol TOC concentration and reaction time in catalytic ozonation pollution degradation objects system,
Wherein ■ represents the TOC degradation rates of chlorophenol when being not added with catalyst, ● it represents and iron titanate made from commercially available high-temperature calcination is added
When parachlorophenol TOC degradation rate, ▲ represent be added embodiment one prepare hexagon iron titanate nanometer sheet material when to chlorine
The degradation rate of the TOC of phenol；
Fig. 5 is the curve graph in heterogeneous class Fenton pollution degradation objects system Methylene Blue concentration and reaction time,
Middle ■ represents the degradation rate of methylene blue when being not added with catalyst, ● it represents sub- when iron titanate made from commercially available high-temperature calcination is added
The degradation rate of methyl blue, the degradation of methylene blue when hexagon iron titanate nanometer sheet material prepared by embodiment one is added in ▲ representative
Rate.
Specific implementation mode
Technical solution of the present invention is not limited to the specific implementation mode of act set forth below, further include each specific implementation mode it
Between arbitrary combination.
Specific implementation mode one：A kind of synthetic method of hexagon iron titanate nanometer sheet material of present embodiment, feature
It is that this method specifically carries out according to the following steps：
One, titanium salt and molysite are put into deionized water and are dissolved, obtain titanium salt and iron salt solutions,
Two, organic base is added in the titanium salt and iron salt solutions that step 1 obtains, obtains mixed liquor；
Three, caustic alkali is put into deionized water and is dissolved, obtain precipitating reagent；
Four, the precipitating reagent that step 3 obtains is added in the mixed liquor that step 2 obtains, reaction generates hydroxide ferrotitanium
Presoma；
Five, the presoma that step 4 obtains is transferred in water heating kettle, is heated, carry out hydro-thermal reaction, washing and drying obtains
The hexagon iron titanate nanometer sheet material.
Specific implementation mode two：The present embodiment is different from the first embodiment in that：Titanium salt is metatitanic acid in step 1
Four butyl esters, titanyl sulfate, hexafluorotitanic acid, potassium fluotitanate, ammonium titanium fluoride, tetraethyl titanate, titanium tetrachloride, titanium trichloride or oxalic acid
Titanium potassium.It is other same as the specific embodiment one.
Specific implementation mode three：The present embodiment is different from the first and the second embodiment in that：Molysite is in step 1
Ferric nitrate, iron chloride, frerrous chloride, ferric sulfate, ferrous sulfate, ferric acetate, ferrous oxalate or iron ammonium sulfate.It is other with it is specific
Embodiment one or two is identical.
Specific implementation mode four：Unlike one of present embodiment and specific implementation mode one to three：Have in step 2
Machine alkali is tetramethylammonium hydroxide, tetraethyl ammonium hydroxide or tetrapropylammonium hydroxide.Other and specific implementation mode one to three
One of it is identical.
Specific implementation mode five：Unlike one of present embodiment and specific implementation mode one to four：Step 3 causticity
The amount ratio of hydroxyl and organic base in step 2 is 1mol: 1mmol~20mmol in alkali.It is other with specific implementation mode one to
One of four is identical.
Specific implementation mode six：Unlike one of present embodiment and specific implementation mode one to five：Step 3 causticity
The amount ratio of molysite is 1mol: 1mmol~20mmol in hydroxyl and step 1 in alkali, hydroxyl and step in step 3 caustic alkali
The amount ratio of titanium salt is 1mol: 1mmol~20mmol in rapid one.It is other identical as one of specific implementation mode one to five.
Specific implementation mode seven：Unlike one of present embodiment and specific implementation mode one to six：Iron in step 1
Salt is ferrous sulfate, concentration of iron 10mmol/L.It is other identical as one of specific implementation mode one to six.
Specific implementation mode eight：Unlike one of present embodiment and specific implementation mode one to seven：Titanium in step 1
Salt is titanium sulfate, a concentration of 10mmol/L of titanium.It is other identical as one of specific implementation mode one to seven.
Specific implementation mode nine：Unlike one of present embodiment and specific implementation mode one to eight：Have in step 2
Machine alkali is tetramethylammonium hydroxide, a concentration of 10mmol/L.It is other identical as one of specific implementation mode one to eight.
Specific implementation mode ten：Unlike one of present embodiment and specific implementation mode one to nine：Step 3 causticity
Hydroxyl is 1~5mol in alkali.It is other identical as one of specific implementation mode one to nine.
Specific implementation mode 11：Unlike one of present embodiment and specific implementation mode one to ten：Step 3 is severe
Property alkali be potassium hydroxide, a concentration of 4mol/L.It is other identical as one of specific implementation mode one to ten.
Specific implementation mode 12：Present embodiment is unlike specific implementation mode one to one of 11：Step 5
Middle hydrothermal temperature be 160~220 DEG C, the hydro-thermal reaction time be 12~for 24 hours.It is other with specific implementation mode one to 11 it
One is identical.
Specific implementation mode 13：Present embodiment is unlike specific implementation mode one to one of 12：Step 5
Middle hydrothermal temperature is 180 DEG C, the hydro-thermal reaction time 18h.It is other identical as specific implementation mode one to one of 12.
Specific implementation mode 14：Present embodiment is unlike specific implementation mode one to one of 13：Step 5
The product that middle hydro-thermal reaction obtains is precipitated using gravity or centrifugal treating, by obtained sediment through deionized water and absolute ethyl alcohol
The process of washing.It is other identical as specific implementation mode one to one of 13.
Specific implementation mode 15：Present embodiment is unlike specific implementation mode one to one of 14：Step 5
The washing process for the product that middle hydro-thermal reaction obtains is 2 absolute ethyl alcohols, 3 deionized waters.Other and specific implementation mode one
It is identical to one of 14.
Specific implementation mode 16：A kind of hexagon iron titanate nanometer sheet material described in specific implementation mode one, which is used as, urges
Agent degradation of contaminant in degradation of contaminant and heterogeneous class Fenton in degradation of contaminant, catalytic ozonation under visible light
In application.
Beneficial effects of the present invention are verified using following embodiment：
Embodiment one：
A kind of synthetic method of hexagon iron titanate nanometer sheet material of the present embodiment, it is characterised in that this method specifically by with
Lower step carries out：
One, butyl titanate and ferrous sulfate are put into deionized water and are dissolved, obtain titanium salt and iron salt solutions；Wherein titanium
Sour four butyl esters a concentration of 10mmol/L, a concentration of 10mmol/L of ferrous sulfate；
Two, organic base tetraethyl ammonium hydroxide is added in the titanium salt and iron salt solutions that step 1 obtains, is mixed
Liquid；Wherein a concentration of 10mmol/L of tetraethyl ammonium hydroxide；
Three, caustic alkali potassium hydroxide is put into deionized water and is dissolved, obtain precipitating reagent；Concentration of potassium hydroxide is 5mol/
L；
Four, the precipitating reagent that step 3 obtains is added in the mixed liquor that step 2 obtains, reaction generates hydroxide ferrotitanium
Presoma；
Five, the presoma that step 4 obtains is transferred in water heating kettle, is heated, carry out hydro-thermal reaction, hydrothermal temperature
It it is 180 DEG C, the hydro-thermal reaction time 16h, washing and drying obtains the hexagon iron titanate nanometer sheet material.
Hexagon iron titanate nanometer sheet material manufactured in the present embodiment is characterized：Pass through N2Adsorption/desorption characterizes, and surveys
It is 12.2m to obtain specific surface area2/g.It is tested by power spectrum, the results showed that catalysis material hexagon iron titanate nanometer sheet material is made
Element ratio be shown in Table 1：
Table 1
Prove that the catalyst material is rich in ferrotitanium activated centre, and the element ratio of ferrotitanium oxygen and iron titanate (FeTiO3) kiss
It closes.Powder x-ray diffraction (XRD) is carried out to obtained hexagon iron titanate nanometer sheet material to detect, the results are shown in Figure 1,
Peak in figure and iron titanate (FeTiO3) JCPDS cards 71-1140 exactly match, had no in figure other miscellaneous peaks presence, explanation
Prepared hexagon iron titanate nanometer sheet material is pure iron titanate (FeTiO3), the diffraction maximum in figure is sharp, and diffracted intensity is high,
Illustrate that prepared hexagon iron titanate nanometer sheet material crystallinity is high.Fig. 2 is the hexagon iron titanate nanometer sheet material prepared
Scanning electron microscope (SEM) photograph, it can be seen from the figure that iron titanate (FeTiO obtained3) it is hexagonal nanosheet, boundary and corner angle are clear
Clear, for diameter in 500nm or so, thickness is 50nm or so.
The photocatalytic pollutant degradation effect of obtained hexagon iron titanate nanometer sheet material in the present embodiment：
Hexagon iron titanate nanometer sheet material manufactured in the present embodiment is put into photocatalytic reaction device, reaction condition is
PH=6.8, catalyst concn 1g/L.Using methylene blue solution simulating pollution object as waste water from dyestuff, measure 100mL's every time
50mg/L methylene blue solutions carry out photocatalytic degradation under the irradiation of 500W xenon lamps in beaker to it, often react 30 minutes
Methylene blue solution is taken in beaker afterwards, takes liquid to be added in cuvette after membrane filtration, uses UV spectrophotometer measuring
The photocatalytic degradation curve of methylene blue solution reaction can be obtained in the absorbance of methylene blue solution (see Fig. 3).In figure 3, ■
The degradation rate of methylene blue when being not added with catalyst is represented, ● represent methylene when iron titanate made from commercially available high-temperature calcination is added
Blue degradation rate, the degradation rate of methylene blue when the hexagon iron titanate nanometer sheet material prepared in embodiment 1 is added in ▲ representative.
Fig. 3 the result shows that, when reacted between be 300 minutes when, not plus catalyst in the case of methylene blue it is non-degradable, commercially available high temperature is forged
Iron titanate made from burning method can degrade at 300 minutes about 45% methylene blue, and the hexagon titanium prepared in embodiment 1
Sour iron nanometer sheet material can make methylene blue decolourize completely at 300 minutes.
The catalytic ozonation degradation of contaminant effect of obtained hexagon iron titanate nanometer sheet material in the present embodiment
Identical in three specifications, the commercially available high temperature for filling homogenous quantities in the cylindrical reactor that effective volume is 1.5L respectively is forged
Hexagon iron titanate nanometer sheet material and be added without catalyst prepared by iron titanate made from burning method, embodiment one, identical
Parachlorophenol simulation micro-polluted water (parachlorophenol concentration 30mg/L) is handled, process conditions under the conditions of operating parameter：Instead
It is 20 degrees Celsius, pH 6.8, ozone dosage 3mg/min to answer temperature, 90 minutes reaction time.
Different catalytic ozonation agent catalytic effects are shown in Fig. 4.In Fig. 4, ■ represents the TOC drops of chlorophenol when being not added with catalyst
Solution rate, ● the degradation rate of the TOC of parachlorophenol when iron titanate made from commercially available high-temperature calcination is added is represented, ▲ represent addition in fact
The degradation rate of the TOC of parachlorophenol when applying the hexagon iron titanate nanometer sheet material of the preparation of example one.Fig. 4 the result shows that, work as reaction
When time is 90 minutes, plus in the case of catalyst the degradation rate of the TOC of parachlorophenol not can only achieve 15%, and commercially available high temperature is forged
Iron titanate made from burning method can remove about 40% parachlorophenol at 90 minutes, and the iron titanate prepared in embodiment 1 is received
Rice sheet material can remove about 75% parachlorophenol at 90 minutes.
The heterogeneous class Fenton oxidation degradation of contaminant effect of obtained hexagon iron titanate nanometer sheet material in the present embodiment
Fruit：
Hexagon iron titanate nanometer sheet material prepared by embodiment one is put into photocatalytic reaction device, reaction condition is
PH=3, catalyst concn 1g/L.Using methylene blue solution simulating pollution object as waste water from dyestuff, measure 100mL's every time
50mg/L methylene blue solutions are in beaker, and the hydrogen peroxide that 10mmol/L is added carries out it heterogeneous class Fenton degradation, per anti-
After answering 30 minutes, methylene blue solution is taken in beaker, takes liquid to be added in cuvette after membrane filtration, with ultraviolet spectrometry light
The absorbance of degree meter detection methylene blue solution, can be obtained the photocatalytic degradation curve of methylene blue solution reaction (see Fig. 5).
In Fig. 5, ■ represents the degradation rate of methylene blue when being not added with catalyst, ● it represents and iron titanate made from commercially available high-temperature calcination is added
When methylene blue degradation rate, ▲ represent methylene blue when hexagon iron titanate nanometer sheet material prepared by embodiment one is added
Degradation rate.Fig. 5 the result shows that, when reacted between be 240 minutes when, not plus catalyst in the case of methylene blue it is almost non-degradable,
Iron titanate made from commercially available high-temperature calcination can degrade at 240 minutes about 40% methylene blue, and made in embodiment 1
Standby hexagon iron titanate nanometer sheet material degradable about 80% methylene blue at 240 minutes.
In the above experiment, pollutant is not intended to limit the present invention using dyestuff methylene blue and parachlorophenol
The pollutant of degradation is methylene blue and parachlorophenol, and method of the invention is suitable for all kinds of dyestuffs of degrading, pesticide and other
Persistence organic pollutant etc..
Embodiment two：
A kind of synthetic method of hexagon iron titanate nanometer sheet material of the present embodiment, it is characterised in that this method specifically by with
Lower step carries out：
One, titanyl sulfate and iron ammonium sulfate are put into deionized water and are dissolved, obtain titanium salt and iron salt solutions；Wherein sulphur
Sour a concentration of 2mmol/L of oxygen titanium, ferrous ammonium sulfate concentration 2mmol/L；
Two, organic base tetraethyl ammonium hydroxide is added in the titanium salt and iron salt solutions that step 1 obtains, is mixed
Liquid；Wherein a concentration of 5mmol/L of tetraethyl ammonium hydroxide；
Three, caustic alkali sodium hydroxide is put into deionized water and is dissolved, obtain precipitating reagent；Naoh concentration is 1mol/
L；
Four, the precipitating reagent that step 3 obtains is added in the mixed liquor that step 2 obtains, reaction generates hydroxide ferrotitanium
Presoma；
Five, the presoma that step 4 obtains is transferred in water heating kettle, is heated, carry out hydro-thermal reaction, hydrothermal temperature
It it is 200 DEG C, the hydro-thermal reaction time 12h, washing and drying obtains the hexagon iron titanate nanometer sheet material.
Embodiment three：
A kind of synthetic method of hexagon iron titanate nanometer sheet material of the present embodiment, it is characterised in that this method specifically by with
Lower step carries out：
One, titanium tetrachloride and ferrous oxalate are put into deionized water and are dissolved, obtain titanium salt and iron salt solutions；Wherein tetrachloro
Change a concentration of 20mmol/L of titanium, a concentration of 20mmol/L of ferrous oxalate；
Two, organic base tetrapropylammonium hydroxide is added in the titanium salt and iron salt solutions that step 1 obtains, is mixed
Liquid；Wherein a concentration of 40mmol/L of tetrapropylammonium hydroxide；
Three, caustic alkali sodium hydroxide is put into deionized water and is dissolved, obtain precipitating reagent；Naoh concentration is 2mol/
L；
Four, the precipitating reagent that step 3 obtains is added in the mixed liquor that step 2 obtains, reaction generates hydroxide ferrotitanium
Presoma；
Five, the presoma that step 4 obtains is transferred in water heating kettle, is heated, carry out hydro-thermal reaction, hydrothermal temperature
It it is 160 DEG C, the hydro-thermal reaction time is for 24 hours that washing and drying obtains the hexagon iron titanate nanometer sheet material.
Claims (10)
1. a kind of synthetic method of hexagon iron titanate nanometer sheet material, it is characterised in that this method specifically according to the following steps into
Row：
One, titanium salt and molysite are put into deionized water and are dissolved, obtain titanium salt and iron salt solutions,
Two, organic base is added in the titanium salt and iron salt solutions that step 1 obtains, obtains mixed liquor；
Three, caustic alkali is put into deionized water and is dissolved, obtain precipitating reagent；
Four, the precipitating reagent that step 3 obtains is added in the mixed liquor that step 2 obtains, reaction generates iron hydroxide titanium precursor
Body；
Five, the presoma that step 4 obtains is transferred in water heating kettle, is heated, carry out hydro-thermal reaction, washing and drying obtains described
Hexagon iron titanate nanometer sheet material.
2. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
In one titanium salt be butyl titanate, titanyl sulfate, hexafluorotitanic acid, potassium fluotitanate, ammonium titanium fluoride, tetraethyl titanate, titanium tetrachloride,
Titanium trichloride or titanium potassium oxalate.
3. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
Molysite is ferric nitrate, iron chloride, frerrous chloride, ferric sulfate, ferrous sulfate, ferric acetate, ferrous oxalate or iron ammonium sulfate in one.
4. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
Organic base is tetramethylammonium hydroxide, tetraethyl ammonium hydroxide or tetrapropylammonium hydroxide in two.
5. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
The amount ratio of hydroxyl and organic base in step 2 is 1mol: 1mmol~20mmol in three caustic alkali.
6. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
The amount ratio of molysite is 1mol: 1mmol~20mmol in hydroxyl and step 1 in three caustic alkali, hydrogen-oxygen in step 3 caustic alkali
The amount ratio of root and titanium salt in step 1 is 1mol: 1mmol~20mmol.
7. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
Hydroxyl is 1~5mol in three caustic alkali.
8. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
In five hydrothermal temperature be 160~220 DEG C, the hydro-thermal reaction time be 12~for 24 hours.
9. a kind of synthetic method of hexagon iron titanate nanometer sheet material according to claim 1, it is characterised in that step
The product that hydro-thermal reaction obtains in five is precipitated using gravity or centrifugal treating, by obtained sediment through deionized water and anhydrous second
The process of alcohol washing.
10. a kind of application of hexagon iron titanate nanometer sheet material as described in claim 1, it is characterised in that the hexagon titanium
Sour iron nanometer sheet material as degradation of contaminant in catalyst under visible light degradation of contaminant, catalytic ozonation and it is non-
Application in similar Fenton in degradation of contaminant.
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| CN110841640A (en) * | 2019-11-22 | 2020-02-28 | 福州大学 | Two-dimensional titanium ferrite nanosheet, preparation method thereof and application thereof in hydrogen sulfide selective catalytic oxidation |
| CN113797928A (en) * | 2021-11-16 | 2021-12-17 | 北京大臻科技有限公司 | Ortho-para hydrogen conversion catalyst for liquid hydrogen conversion and preparation method thereof |
| CN115155609A (en) * | 2022-06-22 | 2022-10-11 | 广东中膜科技有限公司 | Manganese-doped iron titanate granular ozone catalyst and preparation method and application thereof |
| CN115463658A (en) * | 2022-09-14 | 2022-12-13 | 广东卓信环境科技股份有限公司 | Preparation method and application of perovskite/sludge carbon composite catalyst |
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| CN102092782A (en) * | 2011-04-01 | 2011-06-15 | 福州大学 | Hydrothermal one-step synthesis method of cadmium titanate |
| CN102471861A (en) * | 2009-07-07 | 2012-05-23 | 苏舍美特科公司 | Iron-based spray material, method for producing a spray material, thermal spray layer, and spraying method |
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| JPH01298028A (en) * | 1988-05-25 | 1989-12-01 | Toda Kogyo Corp | Illumenite powder and production thereof |
| CN102471861A (en) * | 2009-07-07 | 2012-05-23 | 苏舍美特科公司 | Iron-based spray material, method for producing a spray material, thermal spray layer, and spraying method |
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| CN110841640A (en) * | 2019-11-22 | 2020-02-28 | 福州大学 | Two-dimensional titanium ferrite nanosheet, preparation method thereof and application thereof in hydrogen sulfide selective catalytic oxidation |
| CN113797928A (en) * | 2021-11-16 | 2021-12-17 | 北京大臻科技有限公司 | Ortho-para hydrogen conversion catalyst for liquid hydrogen conversion and preparation method thereof |
| CN115155609A (en) * | 2022-06-22 | 2022-10-11 | 广东中膜科技有限公司 | Manganese-doped iron titanate granular ozone catalyst and preparation method and application thereof |
| CN115155609B (en) * | 2022-06-22 | 2024-03-01 | 广东中膜科技有限公司 | Manganese-doped ferric titanate granular ozone catalyst and preparation method and application thereof |
| CN115463658A (en) * | 2022-09-14 | 2022-12-13 | 广东卓信环境科技股份有限公司 | Preparation method and application of perovskite/sludge carbon composite catalyst |
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