CN108285591A - Mould proof wall patch and its preparation method - Google Patents

Mould proof wall patch and its preparation method Download PDF

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Publication number
CN108285591A
CN108285591A CN201710012293.9A CN201710012293A CN108285591A CN 108285591 A CN108285591 A CN 108285591A CN 201710012293 A CN201710012293 A CN 201710012293A CN 108285591 A CN108285591 A CN 108285591A
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China
Prior art keywords
mould proof
glass fibre
proof wall
wall patch
resin
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CN201710012293.9A
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Chinese (zh)
Inventor
简金木
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Individual
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Individual
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Priority to CN201710012293.9A priority Critical patent/CN108285591A/en
Publication of CN108285591A publication Critical patent/CN108285591A/en
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    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L27/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers
    • C08L27/02—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L27/04—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Compositions of derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08L27/06—Homopolymers or copolymers of vinyl chloride
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/02—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments
    • B32B17/04—Layered products essentially comprising sheet glass, or glass, slag, or like fibres in the form of fibres or filaments bonded with or embedded in a plastic substance
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B17/00—Layered products essentially comprising sheet glass, or glass, slag, or like fibres
    • B32B17/06—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material
    • B32B17/10—Layered products essentially comprising sheet glass, or glass, slag, or like fibres comprising glass as the main or only constituent of a layer, next to another layer of a specific material of synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/30—Layered products comprising a layer of synthetic resin comprising vinyl (co)polymers; comprising acrylic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B27/00—Layered products comprising a layer of synthetic resin
    • B32B27/36—Layered products comprising a layer of synthetic resin comprising polyesters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J9/00—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof
    • C08J9/04—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent
    • C08J9/06—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent
    • C08J9/10—Working-up of macromolecular substances to porous or cellular articles or materials; After-treatment thereof using blowing gases generated by a previously added blowing agent by a chemical blowing agent developing nitrogen, the blowing agent being a compound containing a nitrogen-to-nitrogen bond
    • C08J9/102—Azo-compounds
    • C08J9/103—Azodicarbonamide
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L33/00—Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
    • C08L33/04—Homopolymers or copolymers of esters
    • C08L33/06—Homopolymers or copolymers of esters of esters containing only carbon, hydrogen and oxygen, which oxygen atoms are present only as part of the carboxyl radical
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    • B32B2255/00—Coating on the layer surface
    • B32B2255/10—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer
    • B32B2255/102—Coating on the layer surface on synthetic resin layer or on natural or synthetic rubber layer synthetic resin or rubber layer being a foamed layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/02—Composition of the impregnated, bonded or embedded layer
    • B32B2260/021—Fibrous or filamentary layer
    • B—PERFORMING OPERATIONS; TRANSPORTING
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    • B32B2260/00—Layered product comprising an impregnated, embedded, or bonded layer wherein the layer comprises an impregnation, embedding, or binder material
    • B32B2260/04—Impregnation, embedding, or binder material
    • B32B2260/046—Synthetic resin
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2262/00—Composition or structural features of fibres which form a fibrous or filamentary layer or are present as additives
    • B32B2262/10—Inorganic fibres
    • B32B2262/101—Glass fibres
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0221—Vinyl resin
    • B32B2266/0228—Aromatic vinyl resin, e.g. styrenic (co)polymers
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
    • B32B2266/0214—Materials belonging to B32B27/00
    • B32B2266/0221—Vinyl resin
    • B32B2266/0235—Vinyl halide, e.g. PVC, PVDC, PVF, PVDF
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2266/00—Composition of foam
    • B32B2266/02—Organic
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    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/10—Properties of the layers or laminate having particular acoustical properties
    • B32B2307/102—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/304—Insulating
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/30—Properties of the layers or laminate having particular thermal properties
    • B32B2307/306—Resistant to heat
    • B32B2307/3065—Flame resistant or retardant, fire resistant or retardant
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2307/00—Properties of the layers or laminate
    • B32B2307/70—Other properties
    • B32B2307/714—Inert, i.e. inert to chemical degradation, corrosion
    • B32B2307/7145—Rot proof, resistant to bacteria, mildew, mould, fungi
    • B—PERFORMING OPERATIONS; TRANSPORTING
    • B32—LAYERED PRODUCTS
    • B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
    • B32B2607/00—Walls, panels
    • B32B2607/02—Wall papers, wall coverings
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2203/00—Foams characterized by the expanding agent
    • C08J2203/04—N2 releasing, ex azodicarbonamide or nitroso compound
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2327/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers
    • C08J2327/02—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment
    • C08J2327/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a halogen; Derivatives of such polymers not modified by chemical after-treatment containing chlorine atoms
    • C08J2327/06—Homopolymers or copolymers of vinyl chloride
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2425/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an aromatic carbocyclic ring; Derivatives of such polymers
    • C08J2425/02—Homopolymers or copolymers of hydrocarbons
    • C08J2425/04—Homopolymers or copolymers of styrene
    • C08J2425/06—Polystyrene
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08J—WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H
    • C08J2433/00—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers
    • C08J2433/04—Characterised by the use of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Derivatives of such polymers esters
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00—Properties
    • C08L2201/02—Flame or fire retardant/resistant
    • C—CHEMISTRY; METALLURGY
    • C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00—Polymer mixtures characterised by other features
    • C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • General Chemical & Material Sciences (AREA)
  • Engineering & Computer Science (AREA)
  • Materials Engineering (AREA)
  • Finishing Walls (AREA)

Abstract

The present invention relates to mould proof wall patch and its preparation method, the mould proof wall patch includes mould proof substrate and pattern layer；The mould proof substrate includes the resin of glass fibre and the cladding glass fibre；The pattern layer is set on the surface of the mould proof substrate.The present invention mould proof wall patch preparation method the step of include：Glass fibre described in leaching is in the resin, the step of to obtain the mould proof substrate；And the setting pattern layer is on the surface of the mould proof substrate, to obtain the step of mould proof wall pastes.Mould proof wall patch of the present invention has the advantages that be not easy mouldy and can maintain good decorative effect, have the long life, do not influence environmental sanitation.

Description

Mould proof wall patch and its preparation method
Technical field
The present invention is pasted about wall and its preparation method, espespecially mould proof wall patch and its preparation method.
Background technology
Wall patch is a kind of interior wall being used for covering and decorating the buildings such as household, office block, coffee shop, department store The upholstery material in face.The wall patch of the prior art includes paper wood and pattern layer, and pattern layer is set on the medial surface of paper wood, Pattern layer has decorative pattern, color or pattern etc..In use, wall patch is by being set to sticking together on the lateral surface of paper wood or on metope Layer and stick together and be fixed on metope, to by decorative pattern, color or the pattern in pattern layer achieve the purpose that decorated wall surface and effect Fruit.
However, in use when the prior art wall patch often with the contact with moisture in context, such as：In air Moisture, the moisture by being appeared in wall, the liquid etc. sticked in wall of splashing accidentally.Since the wall patch of the prior art is made with paper wood To carry the base material of pattern layer, and paper wood has the characteristic of adsorption moisture, and Gu Bi is affixed on will generate hair after a period of use Mould phenomenon not only influences the decorative effect of pattern layer and the service life of wall patch, also affects the interior space Environmental sanitation.
Invention content
The shortcomings that in view of the above-mentioned prior art, is not easy mouldy and can maintain well to fill the purpose of the present invention is to provide one kind Decorations effect, with the long life and do not influence environmental sanitation mould proof wall patch.
To reach goal of the invention above-mentioned, the technological means that the present invention is taken is that the mould proof wall patch is enabled to include mould proof base Plate and pattern layer.The mould proof substrate includes the resin of glass fibre and the cladding glass fibre；And the pattern layer is set It is placed on the surface of the mould proof substrate.
It is preferred that the pattern layer is obtained by expanded material, the expanded material includes link stuff and foaming Agent, the link stuff are selected from the group of following composition：Polyvinyl chloride (polyvinyl chloride), polyacrylate (polyacrylate), polystyrene (polystyrene) and other high molecule plastics, the foaming agent can be two formyl of azo Amine (azodicarbonamide), azodiisobutyronitrile (azobisisobutyronitrile) or other foaming agents.
It is preferred that on the basis of the total weight of the link stuff and the foaming agent, the link stuff is 97 weight hundred Divide than (wt%) to 100wt%, the foaming agent is 0wt% to 3wt%.
It is preferred that the expanded material also includes pigment, the pigment can be titanium dioxide, violet pigment and/or indigo plant Color pigment.More preferably, the pigment includes titanium dioxide, violet pigment and blue pigment.
It is preferred that on the basis of the total weight of the link stuff, the foaming agent and the pigment, the link stuff is 88wt% to 95wt%, the foaming agent are 0wt% to 3wt%, and the pigment is 5wt% to 9wt%.
It is preferred that the pattern layer includes foaming layer and color layer, the foaming layer is by the expanded material institute It is made, and the foaming layer is arranged between the color layer and the mould proof substrate.
It is preferred that the raw material of the glass fibre is selected from the group of following composition：Kaolin (kaolinite), stone Lime stone (limestone), silica sand (silica), colemanite (colemanite), fluorite (fluorite), saltcake (mirabilite), sode ash (soda ash), iron oxide (ferric oxide) and wherein two or more mixtures.
It is preferred that the resin includes polymethyl methacrylate (polymethylmethacrylate).
Pass through the technological means using the mould proof substrate for containing glass fibre as the base material of carrying pattern layer, the present invention Mould proof substrate at least have following advantages：
One, after long-time use, it not only may insure the decorative effect of pattern layer, also can avoid the shadows such as mould, bacterium Ring multiplying for the biology of environmental sanitation and health, that is, can maintain good decorative effect, with length with being not easy mouldy Service life and the advantages of do not influence environmental sanitation；And
Two, the practical characteristic such as good fire prevention, corrosion-resistant, anti-moth, heat-insulated and sound insulation.
The present invention separately provides a kind of preparation method of mould proof wall patch, and step includes：
Leaching glass fibre is in resin, to obtain mould proof substrate；
Pattern layer is set on the surface of the mould proof substrate, is pasted with obtaining the mould proof wall.
It is preferred that the leaching glass fibre is in resin, to obtain mould proof substrate the step of includes：By the glass Fiber leaching obtains the step of attaching the glass fibre of the resin in the resin；And with 150 DEG C to 250 DEG C The glass fibre of the resin is attached described in drying temperature drying, the step of to obtain the mould proof substrate.
It is preferred that the setting pattern layer is on the surface of the mould proof substrate, to obtain the step of the mould proof wall patch Suddenly include：Expanded material is coated on the surface of the mould proof substrate, obtains the mould proof substrate for being coated with the expanded material The step of；Under conditions of 200 DEG C to 250 DEG C of blowing temperature, the expanded material is enabled to foam to form foaming layer in described anti- Step on mould substrate；And color printing and embossing are sequentially carried out to form the pattern layer to the surface of the foaming layer And the step of obtaining the mould proof wall patch.
It is preferred that the setting pattern layer is on the surface of the mould proof substrate, to obtain the step of the mould proof wall patch Suddenly include：Cylinder printing (rotary screen printing) described expanded material on the surface of the mould proof substrate, obtains The printing layer that must foam is in the step on the mould proof substrate；And under conditions of 200 DEG C to 250 DEG C of blowing temperature, institute is enabled Foaming printing layer foaming is stated to form the pattern layer, to obtain the step of mould proof wall pastes.
It is preferred that the expanded material includes link stuff and foaming agent, the link stuff is selected from following composition Group：Polyvinyl chloride, polyacrylate, polystyrene and other high molecule plastics, the foaming agent can be：Azodicarbonamide Or other foaming agents.
It is preferred that the expanded material also includes pigment.
It is preferred that the raw material of the glass fibre is selected from the group of following composition：It is kaolin, lime stone, silica sand, hard Line borate, fluorite, saltcake, sode ash, iron oxide and wherein two or more mixtures.
It is preferred that the resin includes polymethyl methacrylate.
Based on above-mentioned technological means, the preparation method of mould proof substrate of the invention has to be made still protects after long-time use The advantages of having good decorative effect and can avoid the mould proof substrate of mould, bacterium multiplied, and the mould proof substrate is also with good It is good prevent fires, be corrosion-resistant, anti-moth, the practical characteristic such as heat-insulated and sound insulation, thus with a wide range of applications.
Description of the drawings
Fig. 1 is the partial side diagrammatic cross-section that the mould proof wall of the embodiment of the present invention 1 pastes；
Fig. 2 is the flow chart for the preparation method that the mould proof wall of the embodiment of the present invention 1 pastes；And
Fig. 3 is setting foaming layer and the color layer for the preparation method that the mould proof wall of the embodiment of the present invention 1 pastes in the of mould proof substrate Schematic diagram on one surface；
Figure label has following meaning：
10：Mould proof substrate；11：First surface；12：Second surface；13：Glass fibre；14：Resin；20：Pattern layer；21： Foaming layer；22：Color layer；23：Lines area.
Specific implementation mode
Embodiment 1：Mould proof wall patch and its preparation method
Refering to Figure 1, in this present embodiment, mould proof wall of the invention patch includes mould proof substrate 10 and pattern layer 20, the mould proof substrate 10 includes first surface 11, position in contrast to the second surface 12 of the first surface 11, glass fibers Dimension 13 and the resin 14 for coating the glass fibre 13, the pattern layer 20 are set on the first surface 11.
As shown in Figs.1 and 2, the preparation method of the mould proof wall patch of the present embodiment includes leaching glass fibre 13 in resin To obtain the step S1 of mould proof substrate 10 in 14；And setting pattern layer 20 on the first surface 11 of the mould proof substrate 10 with Obtain the step S2 of the mould proof wall patch.
As shown in Figs.1 and 2, the step of leaching glass fibre 13 obtains mould proof substrate 10 in resin 14 Details are as follows by S1：By 13 leaching of the glass fibre in the resin 14, the glass fibre for attaching the resin 14 is obtained 13.The glass fibre 13 for attaching the resin 14 is dried with 200 DEG C of drying temperature, 45 seconds drying times again, To remove the moisture on the glass fibre 13 for attaching the resin 14, and obtain plexiglas fiber composite board. Then, the plexiglas fiber composite board is cut, to obtain the mould proof substrate 10.
Shown in please referring to Fig.1 to Fig.3, the setting pattern layer 20 on the first surface 11 of the mould proof substrate 10 to obtain Obtaining the step S2 that the mould proof wall pastes, details are as follows：Expanded material is coated on the first surface 11 of the mould proof substrate 10, Obtain the mould proof substrate for being coated with the expanded material.Later, in 200 DEG C of blowing temperature and the item of 1 minute foamed time Under part, the expanded material is enabled to foam to form foaming layer 21 on the mould proof substrate 10.Come again, to the table of the foaming layer 21 Face carries out color printing to form color layer 22 on the surface of the foaming layer 21.Next, to the color layer 22 and institute It states foaming layer 21 to be embossed to form lines area 23 on the color layer 22 and foaming layer 21, and obtains the pattern layer 20 And the mould proof substrate with the pattern layer.Then, the mould proof substrate with pattern layer is cut, it is described mould proof to obtain Wall pastes.Wherein, the pattern layer 20 includes the color layer 22, the foaming layer 21 and the lines area 23.
In this present embodiment, the resin 14 is polymethyl methacrylate, is produced by TaiWan, China Chan Xie companies And its model P104.The glass fibre 13 be by kaolin, lime stone, silica sand, colemanite, fluorite, saltcake, sode ash and Obtained by iron oxide.The expanded material includes link stuff and foaming agent, and the link stuff is polyvinyl chloride, the foaming agent Azodicarbonamide and its model AC3000F, the weight of the link stuff and the foaming agent are produced for Kunyang company of South Korea Ratio is 100：1.
In use, prior to coated and molded mucigel on the second surface 12 of the mould proof substrate 10, then pass through the viscose Layer sticks in the mould proof wall patch on metope, that is, the attaching of the mould proof wall patch is completed, to be reached by the pattern layer 20 To beautification and the effect of decorated wall surface.Also it may be selected in coated and molded mucigel on metope, then enable the mould proof wall patch with described The mode that the second surface 12 of mould proof substrate 10 is mutually sticked with the mucigel sticks on metope, so completes the mould proof wall patch Attaching.
Since the mould proof substrate 10 includes the resin 14 of the glass fibre 13 and the cladding glass substrate, therefore institute It states mould proof substrate 10 and is not easy to absorb aqueous vapor in ambient enviroment.And the mould proof wall patch is schemed using the mould proof substrate 10 as carrying The base material of pattern layer 20, therefore in after a period of use, the mould proof wall patch is less prone to mouldy phenomenon of making moist.Accordingly, described Mould proof wall patch not only may insure the presentation of the decorative effect using rear pattern layer 20 for a long time, also can avoid mould, bacterium etc. Influence multiplying for the biology of environmental sanitation and health.
Further, since the glass fibre 13 have good heat resistance, noninflammability, chemical resistance, it is anti-moth, every Heat, sound insulation and electrical insulating property, and the mould proof wall patch is using the mould proof substrate 10 containing the glass fibre 13 as carrying pattern The base material of layer 20, therefore the mould proof wall patch has many advantages, such as good fire prevention, corrosion-resistant, anti-moth, heat-insulated and sound insulation.
Embodiment 2：The preparation method of mould proof wall patch
The preparation method of mould proof wall patch of the present embodiment and the preparation method that the mould proof wall of embodiment 1 pastes are generally same.The present embodiment it is mould proof Preparation method that the mould proof wall of preparation method and the embodiment 1 of wall patch pastes the difference is that：Pattern layer is set in the of the mould proof substrate To obtain the step of mould proof wall pastes on one surface.
The present embodiment mould proof wall patch preparation method setting pattern layer on the first surface of the mould proof substrate with acquisition The step of mould proof wall patch, details are as follows：(rotary screen printing) technology is printed by the foaming material with cylinder Material is printed on the first surface of the mould proof substrate, obtains foaming printing layer on the mould proof substrate.Later, in 200 DEG C Blowing temperature and 1 minute foamed time under conditions of, it is the pattern layer and to obtain to enable the foaming printing layer foaming Obtain the mould proof substrate with pattern layer.Then, the mould proof substrate with pattern layer is cut, it is described mould proof to obtain Wall pastes.And in this present embodiment, the expanded material also includes pigment in addition to including link stuff and foaming agent, described The weight ratio of link stuff, the foaming agent and the pigment is 100：1：0.02.
In conclusion the mould proof wall patch of the present invention not only can maintain good decorative effect, with length with being not easy mouldy Service life and the advantages of do not influence environmental sanitation other than, also there is good fire prevention, corrosion-resistant, anti-moth, heat-insulated and sound insulation etc. Characteristic can meet the decoration demand of the building of a variety of different purposes, therefore with a wide range of applications.

Claims (10)

1. a kind of mould proof wall patch, wherein including：
Mould proof substrate, wherein including the resin of glass fibre and the cladding glass fibre；And
Pattern layer is set on the surface of the mould proof substrate.
2. mould proof wall patch according to claim 1, wherein the pattern layer is obtained by expanded material, the foaming material Material includes link stuff and foaming agent, and the link stuff is selected from the group of following composition：Polyvinyl chloride, polyacrylate and poly- Styrene, the foaming agent include azodicarbonamide or azodiisobutyronitrile.
3. mould proof wall patch according to claim 2, wherein the expanded material includes pigment.
4. mould proof wall patch according to claim 2, wherein the pattern layer includes foaming layer and color layer, the foaming Layer is obtained by the expanded material, and the foaming layer is arranged between the color layer and the mould proof substrate.
5. mould proof wall patch according to any one of claim 1 to 4, wherein the raw material of the glass fibre is selected from following The group of composition：Kaolin, lime stone, silica sand, colemanite, fluorite, saltcake, sode ash, iron oxide and wherein two or more Mixture.
6. mould proof wall patch according to any one of claim 1 to 4, wherein the resin includes poly-methyl methacrylate Ester.
7. a kind of preparation method of mould proof wall patch, step include：
Leaching glass fibre is in resin, to obtain mould proof substrate；And
Pattern layer is set on the surface of the mould proof substrate, is pasted with obtaining the mould proof wall.
8. the preparation method of mould proof wall patch according to claim 7, wherein the leaching glass fibre is in resin, to obtain The step of mould proof substrate includes：
By the glass fibre leaching in the resin, the glass fibre for attaching the resin is obtained；And
The glass fibre of the resin is attached described in drying temperature drying with 150 DEG C to 250 DEG C, it is described mould proof to obtain Substrate.
9. the preparation method of mould proof wall patch according to claim 7 or 8, wherein the raw material of the glass fibre is selected from following structure At group：Kaolin, lime stone, silica sand, colemanite, fluorite, saltcake, sode ash, iron oxide and wherein two or more mixed Close object.
10. the preparation method of mould proof wall patch according to claim 7 or 8, wherein the resin includes polymethyl methacrylate.
CN201710012293.9A 2017-01-09 2017-01-09 Mould proof wall patch and its preparation method Pending CN108285591A (en)

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Citations (3)

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Publication number Priority date Publication date Assignee Title
CN201027244Y (en) * 2006-12-15 2008-02-27 王修俊 Nonwoven gridding cloth
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Publication number Priority date Publication date Assignee Title
CN201027244Y (en) * 2006-12-15 2008-02-27 王修俊 Nonwoven gridding cloth
CN204163305U (en) * 2014-09-09 2015-02-18 浙江贝思德壁纸制造有限公司 A kind of MULTILAYER COMPOSITE foaming wallpaper
CN105756301A (en) * 2014-12-20 2016-07-13 刘良贵 Preparation method of glass fiber wall cloth for outdoor decoration

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