CN108276912A - 一种水性溶剂防腐漆 - Google Patents

一种水性溶剂防腐漆 Download PDF

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CN108276912A
CN108276912A CN201810071454.6A CN201810071454A CN108276912A CN 108276912 A CN108276912 A CN 108276912A CN 201810071454 A CN201810071454 A CN 201810071454A CN 108276912 A CN108276912 A CN 108276912A
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杨录真
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Woodpecker Qi Ye Group Co ltd
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    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D201/00Coating compositions based on unspecified macromolecular compounds
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • C09D5/025Preservatives, e.g. antimicrobial agents
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/02Emulsion paints including aerosols
    • C09D5/024Emulsion paints including aerosols characterised by the additives
    • C09D5/028Pigments; Filters
    • CCHEMISTRY; METALLURGY
    • C09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
    • C09DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
    • C09D5/00Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
    • C09D5/08Anti-corrosive paints
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/20Oxides; Hydroxides
    • C08K3/22Oxides; Hydroxides of metals
    • C08K2003/2237Oxides; Hydroxides of metals of titanium
    • C08K2003/2241Titanium dioxide
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    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08KUse of inorganic or non-macromolecular organic substances as compounding ingredients
    • C08K3/00Use of inorganic substances as compounding ingredients
    • C08K3/18Oxygen-containing compounds, e.g. metal carbonyls
    • C08K3/24Acids; Salts thereof
    • C08K3/26Carbonates; Bicarbonates
    • C08K2003/265Calcium, strontium or barium carbonate
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    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Life Sciences & Earth Sciences (AREA)
  • Engineering & Computer Science (AREA)
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Abstract

本发明提出的是一种水性溶剂防腐漆。原料选择与配比:水,KSF‑20防腐剂,羟乙基醚纤维素,AMP‑95多功能助剂,X405润湿剂,涂料分散剂,SN‑5027分散剂,759消泡剂,MT—217膨润土,803钛白粉,DB‑80高岭土,800目重质碳酸钙,791F乳液,成膜助剂,M3防霉剂,A208消泡剂,2020流平剂,205防腐剂,丙二醇和TT‑935增稠剂,经过混合搅拌成为水溶剂防腐漆。本发明使用水性溶剂制成防腐漆,所以对环境与人体没有伤害,具有安全和环保的优点。适宜作为水性防腐漆应用。

Description

一种水性溶剂防腐漆
技术领域
本发明提出的是涂料领域的漆,具体地说是一种水性溶剂防腐漆。
背景技术
目前所使用的防腐漆均为油性漆,由油溶性物质与稀释剂组合,该种漆通过溶剂挥发而固化,因此对环境有污染,对人体有损害,环保性能差。
发明内容
为了制造水性溶剂的防腐漆,本发明提出了一种水性溶剂防腐漆。该防腐漆用选择原料与水组合制成水性防腐漆,解决水性溶剂防腐漆的技术问题。
本发明解决技术问题所采用的方案是:
原料选择与配比:水 283.48千克,KSF-20防腐剂 2.20千克,羟乙基醚纤维素 3.30千克,AMP-95多功能助剂 2.20千克,X405润湿剂 3.30千克,涂料分散剂 3.30千克,SN-5027分散剂 5.49千克,759消泡剂 1.65千克,MT—217膨润土 1.10千克,803钛白粉 164.84千克,DB-80高岭土 32.97千克,800目重质碳酸钙 54.95千克,791F乳液 375.82千克,成膜助剂 27.47千克,M3 防霉剂 3.30千克,A208消泡剂1.65千克,2020流平剂3.30千克,205防腐剂2.20千克,丙二醇 23.08千克,TT-935增稠剂 2.20千克,经过混合搅拌成为水溶剂防腐漆。
积极效果,本发明使用水性溶剂制成防腐漆,所以对环境与人体没有伤害,具有安全和环保的优点。适宜作为水性防腐漆应用。
具体实施方式
原料选择与配比:水 283.48千克,KSF-20防腐剂 2.20千克,羟乙基醚纤维素3.30千克,AMP-95多功能助剂 2.20千克,X405润湿剂 3.30千克,涂料分散剂 3.30千克,SN-5027分散剂 5.49千克,759消泡剂 1.65千克,MT—217膨润土 1.10千克,803钛白粉164.84千克,DB-80高岭土 32.97千克,800目重质碳酸钙 54.95千克,791F乳液 375.82千克,成膜助剂 27.47千克,M3 防霉剂 3.30千克,A208消泡剂1.65千克,2020流平剂3.30千克,205防腐剂2.20千克,丙二醇 23.08千克,TT-935增稠剂 2.20千克,经过混合搅拌成为水溶剂防腐漆。
原料的性能:
所述KSF-20防腐剂用KSF-20防腐时可减少增稠剂的加入量,降低生产成本。系列研究和使用证明:KSF-20新型涂料防腐剂是一种综合性能非常优秀的防腐剂;KSF-20的杀菌防腐效果超过常规的以二价金属离子稳定的卡松防腐剂;KSF-20的热稳定性高;KSF-20对涂料乳液没有任何影响,不会引起涂料结块;KSF-20使用可节约大量增稠剂,降低使用成本,改善涂料的流变特性;KSF-20是一款复合型防腐剂,可有效抵御涂料中有害微生物的抗药性。KSF-20不含甲醛和有机溶剂,环保安全。
所述HBR250纤维素为一系列的微黄粉末产品,易于被分散及溶解在冷水及热水中,形成不同粘度的水溶液.按化学结构来看,它们是不同链条长度的纤维素衍生物,由醚化反应得到羟乙基醚而取得一些优良的物理和化学性质。可作为增稠剂和流变性改良剂,保护胶液、水份保存剂、稳定剂和悬浮助剂,在一些特别需要用非离子型物质的场合被广泛采用。
所述AMP-95多功能助剂是一种多功能胺助剂,调节乳液胶黏剂的pH值很稳定,还有湿润、分散的作用。多功能助剂AMP-95含有5%的水份-2-氨基-2-甲基-1-丙醇,是目前少数具有低分子量和高碱性的工业胺之一。AMP-95可以作为各种类型乳胶漆的多功能助剂,在配方中用AMP-95作为强力共分散剂可以防止颜料再凝聚。同时,多功能助剂AMP-95对漆层的所有性能贡献出显著的优越性。
所述X-405润湿剂应用在乳液聚合,油漆和涂料,地板蜡、蜡化乳液。
所述5100分散剂为涂料分散剂。
所述SN-5027分散剂是润湿分散剂。
所述759消泡剂为油性有机硅。
所述MT—217膨润土,是改性精制而成的膨润土。
所述803钛白粉白色粉末,不溶于水,无生理毒性,化学性能稳定,表面经硅、铝包膜及有机处理后具有卓越的颜色性能,白度、亮度、光泽好;遮盖力和流动性强,具有极佳的耐候性和抗粉化性能。主要用途:水性和溶剂性外用涂料、家电罩漆、塑料、橡胶、油墨、高级纸张和蜡纸以及皮革饰面料、化妆品等。
所述DB-80高岭土为煅烧高岭土。
所述791F乳液主要成分中油性成分有烃类或酯类、高碳醇、脂肪酸等。表面活性剂有脂肪酸皂,非离子活性剂。水性成分有精制水、低碳醇、多元醇、水溶性高分子化合物等。
所述M3 防霉剂是有机抗菌剂、防霉剂、抗藻剂。
所述208M消泡剂是链状季铵化合物和烷基二甲基苄基氯化铵的混合物。用作硬面消毒剂、清洁剂中的有效活性成分,或用于某些工业水水处理剂。具有广谱高效的杀菌灭藻性,如病毒、细菌、藻类。这个第四代季铵盐化合物尤其对硬水和有机土壤具有强力的杀菌作用。
所述2020流平剂是高分子聚酯类流变改性剂。适用于各种乳液的水性涂料及水性工业漆,改善流动、流平性,施工抗飞溅等。
所述205防腐剂杀菌力强,抑菌时间长;长期使用不会产生抗药性;价格低,用量少,无毒、无色、无嗅,使用安全,抗高温,适用范围广;其他助剂配伍性好;对金属无腐蚀性,易溶于水;投加无泡沫;对环境没有污染 。
所述TT-935增稠剂可用作水性涂料的首选增稠剂或协同增稠剂。在相对低的用量下,可以有效改善中剪切粘度。单独选用作为增稠剂与中高分子量的纤维素增稠剂相比,涂料的流动性和流平性能得到改善。
特点:
本漆是水溶性的防腐漆,组分中的791F多元醇乳液为成膜物,成膜物与多种填料与防腐剂、增稠剂、助剂等组合,能够产生防腐的作用。由于791F多元醇乳液具有水溶性,后干防水性,所以能够使用水作为溶剂进行稀释。
所以本漆具有在先水溶性和防腐性。

Claims (1)

1.一种水性溶剂防腐漆,其特征是:
原料选择与配比:水 283.48千克,KSF-20防腐剂 2.20千克,羟乙基醚纤维素 3.30千克,AMP-95多功能助剂 2.20千克,X405润湿剂 3.30千克,涂料分散剂 3.30千克,SN-5027分散剂 5.49千克,759消泡剂 1.65千克,MT—217膨润土 1.10千克,803钛白粉 164.84千克,DB-80高岭土 32.97千克,800目重质碳酸钙 54.95千克,791F乳液 375.82千克,成膜助剂 27.47千克,M3 防霉剂 3.30千克,A208消泡剂1.65千克,2020流平剂3.30千克,205防腐剂2.20千克,丙二醇 23.08千克,TT-935增稠剂 2.20千克,经过混合搅拌成为水溶剂防腐漆。
CN201810071454.6A 2018-01-25 2018-01-25 一种水性溶剂防腐漆 Pending CN108276912A (zh)

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Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105419540A (zh) * 2015-12-25 2016-03-23 广州市福田化学工业涂料有限公司 一种反射隔热涂料及其制备方法
CN107022267A (zh) * 2017-06-01 2017-08-08 信阳天意节能技术股份有限公司 一种水性涂料及其制备方法
CN107384208A (zh) * 2016-05-15 2017-11-24 谢菊荣 一种驱蚊涂料

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN105419540A (zh) * 2015-12-25 2016-03-23 广州市福田化学工业涂料有限公司 一种反射隔热涂料及其制备方法
CN107384208A (zh) * 2016-05-15 2017-11-24 谢菊荣 一种驱蚊涂料
CN107022267A (zh) * 2017-06-01 2017-08-08 信阳天意节能技术股份有限公司 一种水性涂料及其制备方法

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Application publication date: 20180713