CN108273978A - A kind of reinforcement composite metal structures and its forming method and application - Google Patents

A kind of reinforcement composite metal structures and its forming method and application Download PDF

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Publication number
CN108273978A
CN108273978A CN201810260130.7A CN201810260130A CN108273978A CN 108273978 A CN108273978 A CN 108273978A CN 201810260130 A CN201810260130 A CN 201810260130A CN 108273978 A CN108273978 A CN 108273978A
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CN
China
Prior art keywords
reinforcing component
base metal
base
metal
reinforcement
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CN201810260130.7A
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Chinese (zh)
Inventor
黄利敏
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Dongguan City Strong Wild Mstar Technology Ltd
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Dongguan City Strong Wild Mstar Technology Ltd
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Priority to CN201810260130.7A priority Critical patent/CN108273978A/en
Publication of CN108273978A publication Critical patent/CN108273978A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D19/00Casting in, on, or around objects which form part of the product
    • B22D19/02Casting in, on, or around objects which form part of the product for making reinforced articles
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B22CASTING; POWDER METALLURGY
    • B22DCASTING OF METALS; CASTING OF OTHER SUBSTANCES BY THE SAME PROCESSES OR DEVICES
    • B22D27/00Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting
    • B22D27/09Treating the metal in the mould while it is molten or ductile ; Pressure or vacuum casting by using pressure

Abstract

The invention discloses a kind of reinforcement composite metal structures, including base metal structure and reinforcing component, the reinforcing component is connected to embed, outsourcing, penetrate, in a manner of part connection or transition connection with the base metal material;The reinforcing component includes one or more reinforced structure parts, and it is 5 100% that each independent reinforced structure part, which is contained in the ratio in the base metal structure,;The reinforced structure part has compatible predetermined shape according to base metal structure feature, and the regional area of progress reinforcement is needed in the base metal structure.The present invention is by the way of embedded prefabricated reinforcing component; prefabricated reinforcing component is set to realize that depth is combined with non-crystaline amorphous metal matrix; using which product be bent or impact and generate power when; the structure mutually supported is formed between prefabricated reinforcing component and non-crystaline amorphous metal part; within the elastic range of non-crystaline amorphous metal part, electronic component or other parts to interiors of products form duplicate protection.

Description

A kind of reinforcement composite metal structures and its forming method and application
Technical field
The invention belongs to metallic composite fields, and in particular to a kind of composite metal structures with reinforcing function and its Forming method and application.
Background technology
Metal material is most-often used one of material in national product life, has high intensity, high rigidity, appearance tactile impression The advantages that good, has very extensive application foundation in fields such as building, military project, aerospace, 3C electronics, daily necessities.Amorphous Alloy material is a kind of novel metal material of high speed development in recent years, has high specific strength, specific modulus, higher hard Degree, wear-resisting and corrosion resistance, are applied in fields such as aerospace, motor racing product, consumer electronics and cause to get over Carry out more concerns.But due to the unique microcosmos structure characteristic of non-crystaline amorphous metal, non-crystaline amorphous metal itself is made not have plastic deformation Or plastic deformation ability is relatively low, after arrival elastic limit and the characteristic of failure fracture also limits its application range.For The above situation has a large amount of research work to improve the moulding index of non-crystaline amorphous metal, such as generates interior raw reinforcing by constituent adjustment The modes such as phase, surface stress processing, face coat, but cannot achieve the effect that ideal.
As application number 200880105518.4 is entitled《For by the method in glass insert one earth subsidence to metal edge frame And the electronic equipment produced》Patent in the scheme that proposes:Transparent component is positioned in mold, then by the amorphous of liquid State alloy is injected into above-mentioned mold, then makes amorphous alloy hardening to make amorphous alloy and transparent component form one Component.The preparation method of raw hardening constituent is same or similar with above-mentioned technical proposal in non-crystaline amorphous metal in the prior art, is profit Integral component is formed with the heterogeneous component different from non-crystaline amorphous metal material and non-crystaline amorphous metal, using being placed in amorphous in a mold in advance Either heterogeneous component is then injected into liquid or softening another composition of state to alloy, is finally made using techniques such as die casting, hot pressing Integral component is formed, and heterogeneous component constitutes the interior raw hardening constituent in amorphous alloy structure.
Above-mentioned technical proposal in many documents and patent although disclosed, and carried out to it there are many researcher The improvement more refined, such as increases the mode of connection structure, but is not used widely but in practical manufacturing technology, The reason is that the interior raw hardening constituent in above-mentioned technology is distributed since each position cooling rate of product is variant to exist The uncontrollable situation of even property, the integration product produced is during by die casting or thermal stress, interior raw reinforcing It is mutually difficult to uniformly meet with stresses, it is inconsistent so as to cause degree of strain, the phenomenon that easily producing fracture.It is difficult to gram for above-mentioned The shortcomings that taking, it was also proposed that the technical solution of some relevant surface stresses processing and face coat, is in non-crystaline amorphous metal Surface forms the structure of resistance to deformation, thinks to offset thermal stress whereby, reduces the influence that pressure internally gives birth to hardening constituent, but in product Actual crack pattern under, surface stress processing and the technique effect that can generate of face coat are very limited, and surface is answered Power processing and face coat structure are new technical process, and the difficulty of whole technique processing is greatly improved after increasing, from And the cost of the product prepared is directly improved, more limit the application of this technology.
Invention content
In order to solve the deficiencies in the prior art, the present invention provides it is a kind of using reinforcing component to needed in structure into The base metal structure of row reinforcement carries out the reinforcement composite metal structures of privileged site reinforcing.
Institute of the invention technique effect to be achieved is realized by following scheme:
The reinforcement composite metal structures provided in the present invention, it is characterised in that:
Including base metal structure and reinforcing component, the reinforcing component is connected to embed, outsourcing, penetrate, partly or mistake The mode for crossing connection is connected with the base metal material;The reinforcing component includes one or more reinforced structure parts, each only It is 5-100% that vertical reinforced structure part, which is contained in the ratio in the base metal structure,;
The reinforced structure part has compatible predetermined shape according to base metal structure feature, and is set to the base metal The regional area of progress reinforcement is needed in structure.
The ratio that heretofore described reinforced structure part is contained in the base metal structure refers to for 5-100%:Reinforcement The external surface area that structural member is embedded in the base metal structure accounts for the ratio of total external surface area.When the reinforced structure part includes When ratio in the base metal structure is 100%, as embedded structure.
Further, the base metal structure material is amorphous alloy material, including zirconium-base amorphous alloy, titanium-based amorphous It is alloy, cu-based amorphous alloys, Fe-based amorphous alloy, al based amorphous alloy, magnesium base amorphous alloy, cobalt base amorphous alloy, Ni-based non- One or more combinations in peritectic alloy, rare-earth-base amorphous alloy.
Further, the reinforcing component material is simple metal pure metals, ferroalloy materials, aluminum alloy materials, magnesium conjunction Golden material, Cu alloy material, titanium alloy material, Zirconium alloy material, zinc alloy material, ceramic material, cermet material, fiber The combination of one or more of material, high temperature resistant plastic material.
Further, the reinforcing component material is oxidation identical with the base metal structure material master alloying ingredient Object ceramics, carbide ceramics or carbide ceramics;The reinforcing component material is carbide-base ceramics, nitride fund Belong to one kind in ceramics, boride-base cerment, silicide based ceramic metal;The reinforcing component material is carbon fiber, stone One kind in black fiber, silicon carbide fibre, polycrystalline mullite fibre, alumina fibre, Zirconium oxide fibre, alumina silicate fibre.
Further, the reinforced structure part is strip, and to embed, outsourcing, penetrate, partly connection or transition connect Mode is connected with the border structure of the base metal structure;The reinforced structure part is dog-ear shape, to embed, outsourcing, penetrate, The mode of part connection or transition connection is connected with the side of the base metal structure, corner structure;The reinforced structure part is Ring-type, the loop configuration to embed, outsourcing, penetrate, in a manner of part connection or transition connection with the base metal structure It is connected.
Further, the reinforced structure part is set at the base metal structure corners;The reinforced structure part includes The first support portion compatible with the base metal structure corners shape and the second support portion, first support portion with it is described Reinforcing rib is equipped between second support portion.
Further, the transition connection type be equipped with transition piece as intermediate connection carrier respectively with the master that is connected Body metal structure and reinforcing component;The transition piece material is amorphous alloy material.
A kind of forming method of above-mentioned reinforcement composite metal structures is also provided in the present invention, is included the following steps:
Reinforcing component is installed in the setting position in mold by S01;
Base metal construction materials are injected in mold and are combined with reinforcing component by S02, and granting cavity pressure makes its molding, are constituted Required reinforcement composite metal structures.
Reinforcement composite metal structures in the present invention can be applied in 3C Product, and further, the 3C Product at least has There are one side, and be connected with electronic component, the 3C Product position that is connected with the electronic component is answered for the reinforcement Close the base metal structure or reinforcing component in metal structure.
The present invention has the following advantages:
1, the reinforcement composite metal structures in the present invention can realize the base metal knot for needing to carry out reinforcement to special stress area Structure carries out privileged site reinforcing.
2, the reinforcement composite metal structures in the present invention are preferably applied to using non-crystaline amorphous metal part as base metal structural wood In the structural member of matter.
3, the present invention makes prefabricated reinforcing component be realized with non-crystaline amorphous metal matrix deep by the way of embedded prefabricated reinforcing component Degree combines, the product using which be bent or impact and generate power when, prefabricated reinforcing component and non-crystaline amorphous metal The structure mutually supported is formed between part, within the elastic range of non-crystaline amorphous metal part, electronic component to interiors of products or Person's other parts form duplicate protection;When the power born is more than the elastic limit of non-crystaline amorphous metal part, as base metal After the non-crystaline amorphous metal part of structure is broken, since inside is comprising with plastic material(Reinforcing component)Support, plasticity material Material can further keep out impact, to generate the protection for being plastically deformed and exchanging for internal structure.Comparison uses merely non- Product of the peritectic alloy part as frame, the reinforcement composite metal structures in the present invention program prevent one-shot to be produced to product Raw destructive direct failure completely provides the sustainable upgrading used to internal structure and protects.
Description of the drawings
Fig. 1 is the application schematic diagram of reinforcement composite metal structures in the present invention;
Fig. 2 is second of application schematic diagram of reinforcement composite metal structures in the present invention;
Fig. 3 is the third application schematic diagram of reinforcement composite metal structures in the present invention;
Fig. 4 is the 4th kind of application schematic diagram of reinforcement composite metal structures in the present invention;
Fig. 5 is the 5th kind of application schematic diagram of reinforcement composite metal structures in the present invention;
Fig. 6 is the 6th kind of application schematic diagram of reinforcement composite metal structures in the present invention.
Specific implementation mode
The present invention will be described in detail with reference to the accompanying drawings and examples.
Reinforcement in the embodiment of the present invention meets metal structure and is applied in 3C Product.
Embodiment 1
It is as shown in Fig. 1 a kind of application of reinforcement composite metal structures in the present invention, the structure is as product outline border into enforcement With can be applied on the frame structures such as smart mobile phone, tablet computer, communication products.
The structure includes base metal frame structure 101(Zirconium-base amorphous alloy product)And reinforced structure part 102, at this In embodiment, reinforced structure part 102 is the similar frame structure being embedded in outline border 101.In actual manufacturing process, When reinforced structure part 102 is integral part, uneven, therefore this implementation that is easy to cause in process raw material injection pressure process Reinforced structure part 102 is preferably set to two symmetrical half-frame structure splicings in example, or is set as four strip knots being oppositely arranged two-by-two Structure forms the shape and structure of reinforced structure part 102.
Reinforced structure in the embodiment is equally applicable to the product that base metal frame structure is annular mount structure, therewith Compatible reinforced structure part is set as compatible cyclic structure or is spliced to form cyclic structure.
Embodiment 2
It is as shown in Fig. 2 another application of reinforcement composite metal structures in the present invention, difference from Example 1 is, The structure includes base metal frame structure 201(Zirconium-base amorphous alloy product)And reinforcing component, the reinforcing component are distribution In the dog-ear shape structural member 202,203,204,205 of 201 4 edges of frame structure.In tower structure, base metal Four edge of structure is the region for being most susceptible to outer force effect and deforming, such as smart mobile phone edge in fall-down test Impaired deformation most serious, therefore independent reinforced structure is arranged in edge has extraordinary protection effect for tower structure Fruit.
Embodiment 3
It is as shown in Fig. 3 another application of reinforcement composite metal structures in the present invention, which includes base metal frame Structure 301(Magnesium base amorphous alloy product)And reinforced structure part 302, the reinforced structure part 302 is to embed the shape of compound outsourcing Formula carries out reinforcement to frame structure 301.It can be seen that by attached drawing, the vertical structure that reinforced structure part 302 is set to both sides penetrates frame Structure 301, intermediate horizontal stripe structure connect both sides vertical structure, are integrally formed reinforced structure part, i.e. reinforced structure part 302 and gold Belong to the connection of 301 part of frame structure.
In this embodiment, the mode of transition connection can also be used, transition connection type is specially to be equipped with transition piece As centre connection carrier respectively with base metal structure and the reinforcing component of being connected, such as in the present embodiment, both sides are tied vertically Structure can be set as excessive connector, and material uses non-crystaline amorphous metal material identical with base metal structure, and horizontal stripe structure is as only Vertical reinforced structure.Transition connection type is chiefly used in product structure design that redundant space can not be arranged to accommodate reinforced structure Product, more and more lightening to 3C Product, miniaturization trend are consistent very much.
Embodiment 4
It is as shown in Fig. 4 the improvement plan for corner structure progress reinforcement.
Reinforced structure part includes and base metal structure 401(Magnesium base amorphous alloy product)Corner shape compatible first Support portion 402 and the second support portion 403 are equipped with reinforcing rib 404 between first support portion 402 and the second support portion 403.The reinforcement The I-shaped structure of the whole similar deformation of structural member, the raw material of reinforced structure part are not only more saved using such design, and And extraordinary reinforcing effect can be obtained by the design of reinforcing rib.
In actual use, the shape of the first support portion 402 and the second support portion 403 can be modified with the need, Angle, the quantity of reinforcing rib can also be set according to actual demand, and integral structure can be selected with reinforcing rib in support portion, can also divide It opens up vertical.
Embodiment 5
Embodiment 5 as shown in Fig. 5 is the structure to carrying out independent reinforcement on the inside of corner, including base metal structure 501(Aluminium base Non-crystaline amorphous metal product)Reinforced structure part compatible with corner structure 502.
Embodiment 6
Embodiment 6 as shown in Fig. 6 is the structure to carrying out independent reinforcement on the outside of corner, including base metal structure 601(Aluminium base Non-crystaline amorphous metal product)Reinforced structure part compatible with corner structure 602.
The forming method of reinforcement composite metal structures is identical in the embodiment of the present invention, and steps are as follows:
Reinforcing component is installed in the setting position in mold by S01;
Base metal construction materials are injected in mold and are combined with reinforcing component by S02, and granting cavity pressure makes its molding, are constituted Required reinforcement composite metal structures.
In the present invention, other than structure has an impact the reinforcing effect of reinforcement composite metal structures, the selection of material Also there is very big influence.
Base metal structural wood is of fine quality to be selected as amorphous alloy material, including zirconium-base amorphous alloy, titanium-based amorphous alloy, copper-based It is non-crystaline amorphous metal, Fe-based amorphous alloy, al based amorphous alloy, magnesium base amorphous alloy, cobalt base amorphous alloy, ni-based amorphous alloy, dilute One or more combinations in soil matrix non-crystaline amorphous metal.The unique microcosmos structure characteristic of non-crystaline amorphous metal, makes non-crystaline amorphous metal itself no Have plastic deformation or plastic deformation ability is relatively low, after arrival elastic limit and the characteristic of failure fracture also limits it and answers Use range.Non-crystaline amorphous metal and metal similar with non-crystaline amorphous metal mechanical property can be overcome using the reinforced structure in the present invention The disadvantages mentioned above of material, carry out the later base metal structure of reinforcement is enhanced in weakness, and manufactured product can obtain The more excellent test data than traditional metal materials.
The selection of reinforcing component material carries out optimum selecting, preferably simple metal pure metals, ferroalloy according to actual demand Material, aluminum alloy materials, magnesium alloy materials, Cu alloy material, titanium alloy material, Zirconium alloy material, zinc alloy material, ceramic material The combination of one or more of material, cermet material, fibrous material, high temperature resistant plastic material.Metal material, such as metal Pure metals, ferroalloy materials, aluminum alloy materials, magnesium alloy materials, Cu alloy material, titanium alloy material, Zirconium alloy material, zinc The advantages of alloy material, is in forming process and the rheology ratio after the fusion temperature of base metal structure material and fusing More similar, die-casting process easy to use is molded, difficulty is lower for industrialization manufacture, homogeneity of technical process more To be apparent, yield is high.
The hardness at reinforcement position is then made to be obviously improved using ceramic material, simultaneously because ceramic surface has hole knot Structure can combine more closely with base metal material, while ceramic material appearance is more special, using outsourcing, penetrates, portion When the modes such as connection being divided to carry out reinforcement, the part of exposing can compare special appearance processing, keep overall appearance special, increase The surcharge of product.Ceramic material oxide ceramics preferably identical with base metal structure material master alloying ingredient, carbonization Object ceramics or carbide ceramics, can be combined more closely with base metal structure, such as zirconium-base amorphous alloy Base metal material, using ZrC, ZrN, ZrO2Ceramics are used as supporting material;For the base metal material of al based amorphous alloy, Using Al2O3Ceramics are used as supporting material.
Cermet material equally can also reach superior effect as reinforced structure part material, it is preferred to use carbide One kind in based ceramic metal, nitride based ceramic metal, boride-base cerment, silicide based ceramic metal, hardness height, It is tightly combined with base metal structure, and with metal and ceramic two kinds of surface structures, is conducive to the design of product overall appearance.
As the preferred of reinforced structure part material, elasticity more preferably fibrous material or high temperature resistant plastic cement material also can be used Material, particularly preferred fibrous material, including carbon fiber, graphite fibre, silicon carbide fibre, polycrystalline mullite fibre, alumina fibre, One kind in Zirconium oxide fibre, alumina silicate fibre.Fibrous material, if polycrystalline mullite fibre tolerable temperature is up to up to 1300 DEG C More than, molding is simple, of low cost, it is often more important that the use of fibrous material can effectively reduce the weight of bulk metal component Amount, achievees the purpose that lightweight product.
Finally, it should be noted that above example be only to illustrate the embodiment of the present invention technical solution rather than to its into Row limitation, although the embodiment of the present invention is described in detail with reference to preferred embodiment, those skilled in the art It should be understood that the technical solution of the embodiment of the present invention can be still modified or replaced equivalently, and these are changed or wait The range of modified technical solution disengaging technical solution of the embodiment of the present invention cannot also be made with replacement.

Claims (10)

1. a kind of reinforcement composite metal structures, it is characterised in that:
Including base metal structure and reinforcing component, the reinforcing component is connected to embed, outsourcing, penetrate, partly or mistake The mode for crossing connection is connected with the base metal material;The reinforcing component includes one or more reinforced structure parts, each only It is 5-100% that vertical reinforced structure part, which is contained in the ratio in the base metal structure,;
The reinforced structure part has compatible predetermined shape according to base metal structure feature, and is set to the base metal The regional area of progress reinforcement is needed in structure.
2. reinforcement composite metal structures as described in claim 1, it is characterised in that:The base metal structure material is closed for amorphous Golden material, including zirconium-base amorphous alloy, titanium-based amorphous alloy, cu-based amorphous alloys, Fe-based amorphous alloy, al based amorphous alloy, One or more combinations in magnesium base amorphous alloy, cobalt base amorphous alloy, ni-based amorphous alloy, rare-earth-base amorphous alloy.
3. reinforcement composite metal structures as described in claim 1, it is characterised in that:The reinforcing component material is simple metal simple substance Material, ferroalloy materials, aluminum alloy materials, magnesium alloy materials, Cu alloy material, titanium alloy material, Zirconium alloy material, kirsite The combination of one or more of material, ceramic material, cermet material, fibrous material, high temperature resistant plastic material.
4. reinforcement composite metal structures as claimed in claim 3, it is characterised in that:The reinforcing component material be and the main body The identical oxide ceramics of metal structure material master alloying ingredient, carbide ceramics or carbide ceramics;The reinforcing component Material is in carbide-base ceramics, nitride based ceramic metal, boride-base cerment, silicide based ceramic metal It is a kind of;The reinforcing component material be carbon fiber, graphite fibre, silicon carbide fibre, polycrystalline mullite fibre, alumina fibre, One kind in Zirconium oxide fibre, alumina silicate fibre.
5. reinforcement composite metal structures as described in claim 1, it is characterised in that:The reinforced structure part is strip, to embed, Outsourcing, penetrate, part connection or transition connection mode be connected with the border structure of the base metal structure;The reinforcement Structural member be dog-ear shape, embed, outsourcing, penetrate, part connection or transition connect in a manner of and the base metal structure Side, corner structure be connected;The reinforced structure part is ring-type, and to embed, outsourcing, penetrate, partly connection or transition connect Mode is connected with the loop configuration of the base metal structure.
6. reinforcement composite metal structures as described in claim 1, it is characterised in that:The reinforced structure part is set to main body gold Belong at structure corners;The reinforced structure part include the first support portion compatible with the base metal structure corners shape and Second support portion is equipped with reinforcing rib between first support portion and second support portion.
7. reinforcement composite metal structures as described in claim 1, it is characterised in that:The transition connection type is to connect equipped with transition Fitting as intermediate connection carrier respectively with base metal structure and the reinforcing component of being connected;The transition piece material is non- Peritectic alloy material.
8. a kind of forming method of the reinforcement composite metal structures as described in claim 1-7 is any, it is characterised in that including as follows Step:
Reinforcing component is installed in the setting position in mold by S01;
Base metal construction materials are injected in mold and are combined with reinforcing component by S02, and granting cavity pressure makes its molding, are constituted Required reinforcement composite metal structures.
9. a kind of 3C Product, it is characterised in that:The product includes the reinforcement composition metal knot as described in claim 1-7 is any Structure.
10. 3C Product as claimed in claim 9, it is characterised in that:The 3C Product at least has there are one side, and with electronics member Device is connected, and the 3C Product is connected position with the electronic component for the base metal in the reinforcement composite metal structures Structure or reinforcing component.
CN201810260130.7A 2018-03-27 2018-03-27 A kind of reinforcement composite metal structures and its forming method and application Pending CN108273978A (en)

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Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030062811A1 (en) * 2001-06-07 2003-04-03 Atakan Peker Metal frame for electronic hardware and flat panel displays
US20050100726A1 (en) * 2003-11-07 2005-05-12 General Electric Company Integral composite structural material
CN101829844A (en) * 2009-03-11 2010-09-15 中国科学院金属研究所 Friction stir connecting method of amorphous alloy and different metal materials
CN102430745A (en) * 2011-08-18 2012-05-02 比亚迪股份有限公司 Method for combining amorphous alloy and heterogeneous material and complex
CN104307906A (en) * 2014-10-17 2015-01-28 深圳市锆安材料科技有限公司 Composite forming method of amorphous alloy and non-amorphous alloy
CN106756131A (en) * 2016-12-19 2017-05-31 深圳市锆安材料科技有限公司 A kind of non-crystaline amorphous metal part processing method
CN107043898A (en) * 2017-06-12 2017-08-15 宋佳 Amorphous axis body and preparation method thereof
CN208230832U (en) * 2018-03-27 2018-12-14 东莞市坚野材料科技有限公司 A kind of reinforcement composite metal structures

Patent Citations (8)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
US20030062811A1 (en) * 2001-06-07 2003-04-03 Atakan Peker Metal frame for electronic hardware and flat panel displays
US20050100726A1 (en) * 2003-11-07 2005-05-12 General Electric Company Integral composite structural material
CN101829844A (en) * 2009-03-11 2010-09-15 中国科学院金属研究所 Friction stir connecting method of amorphous alloy and different metal materials
CN102430745A (en) * 2011-08-18 2012-05-02 比亚迪股份有限公司 Method for combining amorphous alloy and heterogeneous material and complex
CN104307906A (en) * 2014-10-17 2015-01-28 深圳市锆安材料科技有限公司 Composite forming method of amorphous alloy and non-amorphous alloy
CN106756131A (en) * 2016-12-19 2017-05-31 深圳市锆安材料科技有限公司 A kind of non-crystaline amorphous metal part processing method
CN107043898A (en) * 2017-06-12 2017-08-15 宋佳 Amorphous axis body and preparation method thereof
CN208230832U (en) * 2018-03-27 2018-12-14 东莞市坚野材料科技有限公司 A kind of reinforcement composite metal structures

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